JP3188965B2 - Method for producing meat product to which docosahexaenoic acid is added - Google Patents
Method for producing meat product to which docosahexaenoic acid is addedInfo
- Publication number
- JP3188965B2 JP3188965B2 JP10597093A JP10597093A JP3188965B2 JP 3188965 B2 JP3188965 B2 JP 3188965B2 JP 10597093 A JP10597093 A JP 10597093A JP 10597093 A JP10597093 A JP 10597093A JP 3188965 B2 JP3188965 B2 JP 3188965B2
- Authority
- JP
- Japan
- Prior art keywords
- meat
- added
- salting
- acid
- docosahexaenoic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- MBMBGCFOFBJSGT-KUBAVDMBSA-N all-cis-docosa-4,7,10,13,16,19-hexaenoic acid Chemical compound CC\C=C/C\C=C/C\C=C/C\C=C/C\C=C/C\C=C/CCC(O)=O MBMBGCFOFBJSGT-KUBAVDMBSA-N 0.000 title claims description 37
- 235000020669 docosahexaenoic acid Nutrition 0.000 title claims description 27
- 235000013622 meat product Nutrition 0.000 title claims description 22
- 238000004519 manufacturing process Methods 0.000 title claims description 16
- 229940090949 docosahexaenoic acid Drugs 0.000 title claims description 10
- 235000013372 meat Nutrition 0.000 claims description 21
- 238000009938 salting Methods 0.000 claims description 17
- 230000032683 aging Effects 0.000 claims description 16
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 8
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims description 4
- 229940072107 ascorbate Drugs 0.000 claims description 4
- 235000010323 ascorbic acid Nutrition 0.000 claims description 4
- 239000011668 ascorbic acid Substances 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 235000020995 raw meat Nutrition 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 3
- 230000005070 ripening Effects 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 11
- 229930195729 fatty acid Natural products 0.000 description 11
- 239000000194 fatty acid Substances 0.000 description 11
- 150000004665 fatty acids Chemical class 0.000 description 11
- 235000021323 fish oil Nutrition 0.000 description 11
- 235000015277 pork Nutrition 0.000 description 10
- 239000000203 mixture Substances 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- 238000000034 method Methods 0.000 description 8
- 235000020673 eicosapentaenoic acid Nutrition 0.000 description 6
- 239000012467 final product Substances 0.000 description 6
- 235000019688 fish Nutrition 0.000 description 6
- 235000020777 polyunsaturated fatty acids Nutrition 0.000 description 6
- 230000001953 sensory effect Effects 0.000 description 6
- 241000251468 Actinopterygii Species 0.000 description 5
- 239000003925 fat Substances 0.000 description 5
- 239000000796 flavoring agent Substances 0.000 description 5
- 235000019634 flavors Nutrition 0.000 description 5
- 244000144972 livestock Species 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 102220547770 Inducible T-cell costimulator_A23L_mutation Human genes 0.000 description 4
- YZXBAPSDXZZRGB-DOFZRALJSA-N arachidonic acid Chemical compound CCCCC\C=C/C\C=C/C\C=C/C\C=C/CCCC(O)=O YZXBAPSDXZZRGB-DOFZRALJSA-N 0.000 description 4
- 235000019197 fats Nutrition 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 235000013580 sausages Nutrition 0.000 description 4
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 4
- 241001494479 Pecora Species 0.000 description 3
- 229920000388 Polyphosphate Polymers 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- JAZBEHYOTPTENJ-JLNKQSITSA-N all-cis-5,8,11,14,17-icosapentaenoic acid Chemical compound CC\C=C/C\C=C/C\C=C/C\C=C/C\C=C/CCCC(O)=O JAZBEHYOTPTENJ-JLNKQSITSA-N 0.000 description 3
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 229960005135 eicosapentaenoic acid Drugs 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 239000001205 polyphosphate Substances 0.000 description 3
- 235000011176 polyphosphates Nutrition 0.000 description 3
- 235000013599 spices Nutrition 0.000 description 3
- YUFFSWGQGVEMMI-JLNKQSITSA-N (7Z,10Z,13Z,16Z,19Z)-docosapentaenoic acid Chemical compound CC\C=C/C\C=C/C\C=C/C\C=C/C\C=C/CCCCCC(O)=O YUFFSWGQGVEMMI-JLNKQSITSA-N 0.000 description 2
- 235000021294 Docosapentaenoic acid Nutrition 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- 230000002159 abnormal effect Effects 0.000 description 2
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 2
- 235000021342 arachidonic acid Nutrition 0.000 description 2
- 229940114079 arachidonic acid Drugs 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000032050 esterification Effects 0.000 description 2
- 238000005886 esterification reaction Methods 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 238000004817 gas chromatography Methods 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 238000011081 inoculation Methods 0.000 description 2
- 210000000936 intestine Anatomy 0.000 description 2
- 229960004488 linolenic acid Drugs 0.000 description 2
- 150000002632 lipids Chemical class 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 235000002020 sage Nutrition 0.000 description 2
- 235000010378 sodium ascorbate Nutrition 0.000 description 2
- 229960005055 sodium ascorbate Drugs 0.000 description 2
- PPASLZSBLFJQEF-RKJRWTFHSA-M sodium ascorbate Substances [Na+].OC[C@@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RKJRWTFHSA-M 0.000 description 2
- 235000010288 sodium nitrite Nutrition 0.000 description 2
- PPASLZSBLFJQEF-RXSVEWSESA-M sodium-L-ascorbate Chemical compound [Na+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RXSVEWSESA-M 0.000 description 2
- 235000019640 taste Nutrition 0.000 description 2
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 2
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 2
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 241000962514 Alosa chrysochloris Species 0.000 description 1
- 241000972773 Aulopiformes Species 0.000 description 1
- 241000283690 Bos taurus Species 0.000 description 1
- 206010006187 Breast cancer Diseases 0.000 description 1
- 208000026310 Breast neoplasm Diseases 0.000 description 1
- 101100394230 Caenorhabditis elegans ham-1 gene Proteins 0.000 description 1
- 101100394231 Caenorhabditis elegans ham-2 gene Proteins 0.000 description 1
- 241000238366 Cephalopoda Species 0.000 description 1
- 241000555825 Clupeidae Species 0.000 description 1
- 241001149724 Cololabis adocetus Species 0.000 description 1
- 206010009944 Colon cancer Diseases 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 206010020772 Hypertension Diseases 0.000 description 1
- 150000000996 L-ascorbic acids Chemical class 0.000 description 1
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 1
- 101100045395 Mus musculus Tap1 gene Proteins 0.000 description 1
- 101100045406 Mus musculus Tap2 gene Proteins 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 241001274189 Pomatomus saltatrix Species 0.000 description 1
- 241000269821 Scombridae Species 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 241001504592 Trachurus trachurus Species 0.000 description 1
- 230000005856 abnormality Effects 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- -1 amino acid compounds Chemical class 0.000 description 1
- 230000003042 antagnostic effect Effects 0.000 description 1
- 235000019606 astringent taste Nutrition 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- SECPZKHBENQXJG-UHFFFAOYSA-N cis-palmitoleic acid Natural products CCCCCCC=CCCCCCCCC(O)=O SECPZKHBENQXJG-UHFFFAOYSA-N 0.000 description 1
- 208000029742 colonic neoplasm Diseases 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 230000037213 diet Effects 0.000 description 1
- 230000002526 effect on cardiovascular system Effects 0.000 description 1
- 150000002066 eicosanoids Chemical class 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000004626 essential fatty acids Nutrition 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- VZCCETWTMQHEPK-UHFFFAOYSA-N gamma-Linolensaeure Natural products CCCCCC=CCC=CCC=CCCCCC(O)=O VZCCETWTMQHEPK-UHFFFAOYSA-N 0.000 description 1
- VZCCETWTMQHEPK-QNEBEIHSSA-N gamma-linolenic acid Chemical compound CCCCC\C=C/C\C=C/C\C=C/CCCCC(O)=O VZCCETWTMQHEPK-QNEBEIHSSA-N 0.000 description 1
- 235000020664 gamma-linolenic acid Nutrition 0.000 description 1
- 229960002733 gamolenic acid Drugs 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 235000020993 ground meat Nutrition 0.000 description 1
- FUKUFMFMCZIRNT-UHFFFAOYSA-N hydron;methanol;chloride Chemical compound Cl.OC FUKUFMFMCZIRNT-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 229940106134 krill oil Drugs 0.000 description 1
- 235000020778 linoleic acid Nutrition 0.000 description 1
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 235000020640 mackerel Nutrition 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000020660 omega-3 fatty acid Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 150000003904 phospholipids Chemical class 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000003908 quality control method Methods 0.000 description 1
- 150000003248 quinolines Chemical class 0.000 description 1
- 235000019515 salmon Nutrition 0.000 description 1
- NNNVXFKZMRGJPM-KHPPLWFESA-N sapienic acid Chemical compound CCCCCCCCC\C=C/CCCCC(O)=O NNNVXFKZMRGJPM-KHPPLWFESA-N 0.000 description 1
- 235000019512 sardine Nutrition 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000004809 thin layer chromatography Methods 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
Landscapes
- Coloring Foods And Improving Nutritive Qualities (AREA)
- Meat, Egg Or Seafood Products (AREA)
Description
【0001】[0001]
【産業上の利用分野】本発明はn−3系の高度不飽和脂
肪酸であるドコサヘキサエン酸(以下DHAと略す。)
を添加した食肉製品の製造方法に関し、更に詳しくは、
脂肪含量が5〜40重量%の畜肉原料に対してドコサヘ
キサエン酸0.01〜3.0重量%を含む食肉製品の製
造方法に関するものである。The present invention relates to docosahexaenoic acid (hereinafter abbreviated as DHA) which is an n-3 type highly unsaturated fatty acid.
For the production method of meat products with added, more in detail,
The present invention relates to a method for producing a meat product containing docosahexaenoic acid in an amount of 0.01 to 3.0% by weight with respect to a raw meat material having a fat content of 5 to 40% by weight.
【0002】[0002]
【従来技術】ハムやソーセージの食肉製品の原料となる
畜肉の高度不飽和脂肪酸は通常n−6系(例えは、リノ
−ル酸、γ−リノレン酸、アラキドン酸等)が大部分を
占め、海産生物に特有のn−3系(例えは、α−リノレ
ン酸、イコサペンタエン酸、ドコサペンタエン酸、ドコ
サヘキサエン酸等)は殆ど含まれていない。このn−6
系及びn−3系の高度不飽和脂肪酸は、いずれも必須脂
肪酸で、エイコサノイド前駆体として互いに拮抗する作
用を有していることが知られている。2. Description of the Related Art Normally, the majority of highly unsaturated fatty acids of meat used as raw materials for meat products such as ham and sausage are n-6 type (for example, linoleic acid, γ-linolenic acid, arachidonic acid, etc.). The n-3 series (eg, α-linolenic acid, icosapentaenoic acid, docosapentaenoic acid, docosahexaenoic acid, etc.) unique to marine products is hardly contained. This n-6
It is known that both polyunsaturated fatty acids and n-3 polyunsaturated fatty acids are essential fatty acids and have an antagonistic action as eicosanoid precursors.
【0003】これらの高度不飽和脂肪酸は食生活におい
てそれぞれ十分摂取可能であるが、海産生物由来の食品
には特有の臭味があることから、肉類を中心とする食生
活に片寄る場合が多く、ともすればn−3系の高度不飽
和脂肪酸が不足しがちである。この高度不飽和脂肪酸系
列の摂取アンバランスは、高血圧、心臓病の循環器系疾
患や乳癌、大腸癌などの疾病の要因となることが指摘さ
れている。[0003] These polyunsaturated fatty acids can be sufficiently ingested in the diet, but foods derived from marine products often have a peculiar smell, and thus are often biased toward eating mainly meat. In many cases, n-3 type polyunsaturated fatty acids tend to be insufficient. It has been pointed out that the imbalance of the intake of the polyunsaturated fatty acid series becomes a cause of diseases such as hypertension, cardiovascular circulatory system diseases, breast cancer and colon cancer.
【0004】そこで、n−3系の高度不飽和脂肪酸であ
るイコサペンタエン酸(以下EPAと略す。)やDHA
を含む食肉製品の開発が行われている。例えば、豚肉
に魚油と魚肉すり身を混ぜてポ−クソ−セ−ジを作る技
術(特開昭60−98963号)あるいは豚の飼料中
に魚油を添加して飼育することにより豚肉にEPAやD
HAを多く含ませるようにする技術(特開平2−227
052号)などがある。[0004] Therefore, n-type polyunsaturated fatty acids such as icosapentaenoic acid (hereinafter abbreviated as EPA) and DHA.
The development of meat products including For example, pork is mixed with fish oil and fish ground meat to produce pork sage (Japanese Patent Laid-Open No. 60-98633), or pork is supplemented with fish oil and bred with EPA or D.
Technology for increasing the amount of HA (Japanese Unexamined Patent Publication No. 2-227)
052).
【0005】しかしながら、EPAやDHAを濃縮した
魚油は、製造原料に由来する魚臭を伴い、また構成脂肪
酸の不飽和結合が酸化されやすく、加工工程、保存期間
中に酸敗を起こし、甚だしい場合には酸味や渋味をお
び、かつ着色するいわゆる油やけまで進むことが知られ
ている。このため、の方法では魚肉すり身を混ぜなけ
れば畜肉と風味が合わず不快臭を感じること、では豚
の飼料中に酸化されやすい魚油を添加する必要がありそ
の品質管理に問題点があること等、残された課題が多
い。[0005] However, fish oil concentrated with EPA or DHA is accompanied by fishy odor derived from the raw materials for production, and the unsaturated bonds of the constituent fatty acids are easily oxidized, causing rancidity during the processing step and the storage period. It is known that the soybeans have a sourness and astringency and proceed to a so-called oily burn that is colored. For this reason, if the method of (1) does not mix fish meat, the meat and flavor do not match and the unpleasant odor is felt, and (3) it is necessary to add fish oil which is easily oxidized to pig feed, and there is a problem in quality control. There are many issues left.
【0006】[0006]
【発明が解決しようとする課題】本発明はこのような課
題を解決し、食肉製品としての本来の味を損ねることな
く、DHAを添加した食肉製品の製造方法を提供するこ
とにある。SUMMARY OF THE INVENTION It is an object of the present invention to solve the above problems and to provide a method for producing a meat product to which DHA is added without impairing the original taste of the meat product.
【0007】[0007]
【課題を解決するための手段】本発明者らは、上記の課
題を達成するために鋭意検討を重ねた結果、本発明を完
成するに至った。すなわち本発明は、畜肉を原料とする
食肉製品の製造方法であって、畜肉の塩漬・熟成工程前
あるいは該工程後に、特定量のDHAを添加することに
よって、魚臭および酸敗臭の発生を防止することを特徴
とする食肉製品の製造方法に関するものである。Means for Solving the Problems The inventors of the present invention have made intensive studies to achieve the above object, and as a result, have completed the present invention. That is, the present invention relates to a method for producing a meat product using livestock meat as a raw material, wherein a specific amount of DHA is added before or after the salting and aging process of the livestock meat to reduce the generation of fishy odor and rancidity. The present invention relates to a method for producing a meat product characterized in that the meat product is prevented.
【0008】本発明に用いるDHAとは、遊離酸をはじ
め、その塩、エステル、グリセリド、リン脂質、コリン
化合物、アスコルビン酸化合物、アミノ酸化合物等を意
味するもので、DHAを含む魚油としては、好ましくは
総脂肪酸中のDHAの占める割合が10%以上のものが
良く、このようなものの例を上げるとイワシ、サバ、ア
ジ、サケ、サンマなどの青背魚より抽出した魚油、マグ
ロやカツオなどの大型海産魚の眼窩脂肪由来の魚油、微
生物由来の油脂、オキアミ油、タラやイカ肝臓より抽出
した海産物由来の油脂などが好ましい例として挙げられ
る。[0008] DHA used in the present invention means free acids, salts thereof, esters, glycerides, phospholipids, choline compounds, ascorbic acid compounds, amino acid compounds and the like, and is preferably used as a fish oil containing DHA. It is better that the ratio of DHA in total fatty acids is 10% or more. For example, fish oil extracted from blue fish such as sardines, mackerel, horse mackerel, salmon, saury, tuna and skipjack Preferred examples include fish oil derived from orbital fat of a large marine fish, oil derived from microorganisms, krill oil, marine derived oil extracted from cod and squid liver, and the like.
【0009】また、本発明に用いる食肉製品とは豚、
牛、羊等の畜肉を原料としたハムやソーセージ等を意味
するものである。これらの食肉製品には、亜硝酸塩、ア
スコルビン酸塩、食塩、香辛料、ポリリン酸塩等の慣用
の添加物を加えることができる。[0009] The meat product used in the present invention is pig,
It refers to ham, sausage, etc. made from livestock meat such as cows and sheep. Conventional additives such as nitrite, ascorbate, salt, spices and polyphosphates can be added to these meat products.
【0010】本発明の食肉製品の製造方法のうち、ハム
を製造する場合には以下の製造方法が好ましい。すなわ
ち、脂肪含量が5〜40重量%の畜肉原料に対して、D
HA含量が0.01〜3.0%となるように、注入によ
り添加し、0〜10℃の低温域で塩漬・熟成する。塩漬
・熟成期間は好ましくは16〜168時間、より好まし
くは20〜72時間である。塩漬・熟成期間がこれより
短いと塩漬・熟成による風味に醸成が不十分となり、最
終製品に魚臭が残る。また、塩漬・熟成期間がこれより
長いと添加した油脂の酸化が起こり、最終製品に酸敗臭
等の悪影響を与える。塩漬・熟成方法は畜肉原料と酸素
との接触が少ない方法、例えば夜漬、真空タンブリング
等の公知の方法が用いられる。畜肉の熟成風味の醸成お
よび油脂の酸化防止の目的で使用する塩漬剤中の亜硝酸
塩およびアスコルビン酸塩濃度は、それぞれ10〜30
0ppmおよび0.02%〜0.5%、好ましくは15
0〜200ppmおよび0.05〜0.3%である。こ
れらの添加物は食肉製品への使用が認められ、上述の目
的に合った他の添加物と置き換えても差し支えない。塩
漬・熟成終了後、ケ−シングに充填、若しくは充填する
ことなく直ちに公知の方法で加熱処理を施すことが好ま
しい。このようにしてDHAをハムに添加させることに
より、その品質を低下させるこなく、より付加価値の高
いハムを製造することができる。[0010] Among the methods for producing meat products of the present invention, when producing ham, the following production method is preferable. That is, for a meat raw material having a fat content of 5 to 40% by weight, D
It is added by injection so that the HA content becomes 0.01 to 3.0%, and salted and ripened in a low temperature range of 0 to 10 ° C. The salting and aging period is preferably 16 to 168 hours, more preferably 20 to 72 hours. If the salting and aging period is shorter than this, brewing becomes insufficient due to the salting and aging, resulting in a fishy odor remaining in the final product. If the salting and aging period is longer than this, the added fats and oils are oxidized, which has an adverse effect such as rancidity on the final product. As the method of salting and aging, a known method such as contact with livestock meat and oxygen is small, such as pickling at night and vacuum tumbling. The nitrite and ascorbate concentrations in the salting agent used for the purpose of aging the meat aging flavor and preventing the oxidation of fats and oils are 10 to 30 respectively.
0 ppm and 0.02% to 0.5%, preferably 15 ppm
0-200 ppm and 0.05-0.3%. These additives are approved for use in meat products and can be replaced with other additives for the purposes described above. After the completion of the salting and aging, it is preferable to perform a heat treatment by a known method immediately after filling or not filling the casing. By adding DHA to ham in this way, ham with higher added value can be produced without lowering its quality.
【0011】ソーセージを製造する場合には、予め十分
に塩漬・熟成させた畜肉原料(脂肪含量:5〜40重量
%)に対して、DHA含量が0.01〜3.0%となる
ように添加し、混合後ケ−シングに充填するか、あるい
は新鮮な畜肉原料に対して、DHAを添加混合後、ケ−
シングに充填し、45〜60℃の範囲で30〜90分間
塩漬・熟成することが好ましい。これらの操作終了後、
直ちに公知の方法で加熱処理を施すことが好ましく、塩
漬・熟成に用いられる亜硝酸塩およびアスコルビン酸塩
の好ましい濃度はハムの場合と同様であり、また混合に
際しては、畜肉原料と酸素との接触を最小限に止めるこ
とが好ましい。When producing sausages, the DHA content is adjusted to 0.01 to 3.0% with respect to the raw meat (fat content: 5 to 40% by weight) which has been sufficiently salted and aged in advance. After mixing, the mixture is filled into a casing, or DHA is added to a fresh raw meat material and mixed, and then the case is mixed.
It is preferable to fill in a shingle and salt and ripen it at 45 to 60 ° C for 30 to 90 minutes. After these operations,
Immediately, it is preferable to carry out heat treatment by a known method, and the preferable concentrations of nitrite and ascorbate used for salting and aging are the same as those of ham. Is preferably minimized.
【0012】また、前記の食肉製品の原料として、魚油
を接種した家畜から得られる畜肉も使用できる。接種に
よる飼育は、従来の飼料添加による投与に対して、魚
油を使用直前まで保存しておくことができ、また短時間
の内に皮下接種することができるため酸化の問題がない
こと。飼料添加のように毎日作業を行う必要がなく、
接種は1ヶ月間に1〜10回、より好ましくは3〜6回
行えばよいこと。飼料添加により投与されるDHA量
に比較して少量ですむ、などの利点がある。皮下接種す
る魚油は、1ml〜100ml、好ましくは2ml〜50mlを
接種することが豚の健康状態及び高度不飽和脂肪酸の含
有率からみても望ましい。また接種する魚油に乳化剤や
ビタミン剤等を添加しても良い。Further, as a raw material of the meat product, meat obtained from livestock inoculated with fish oil can be used. When breeding by inoculation, fish oil can be stored until just before use, and it can be inoculated subcutaneously within a short time, compared to the conventional administration by feed addition, and there is no oxidation problem. There is no need to work every day like adding feed,
Inoculation should be performed 1 to 10 times, more preferably 3 to 6 times a month. There is an advantage that the amount of DHA is small compared to the amount of DHA administered by adding feed. The fish oil to be subcutaneously inoculated is desirably inoculated in an amount of 1 ml to 100 ml, preferably 2 ml to 50 ml in view of the health of the pig and the content of polyunsaturated fatty acids. An emulsifier, a vitamin and the like may be added to the fish oil to be inoculated.
【0013】原料である畜肉中の脂肪酸は、常法によ
り、例えば塩酸−メタノール法等によりメチルエステル
化すると、エステル結合しているあらゆる脂肪酸誘導体
の脂肪酸組成をガスクロマトグラフィ−で分析できる。
また、畜肉から有機溶剤などを用いて抽出し、シリカゲ
ル薄層クロマトグラフィ−にて脂質を分画した後、各々
の脂質の構成脂肪酸を同様にして分析できる。Fatty acid in animal meat, which is a raw material, is subjected to methyl esterification by a conventional method, for example, a hydrochloric acid-methanol method or the like, and the fatty acid composition of any fatty acid derivative having an ester bond can be analyzed by gas chromatography.
In addition, after extraction from animal meat using an organic solvent or the like and fractionation of lipids by silica gel thin layer chromatography, the constituent fatty acids of each lipid can be analyzed in the same manner.
【0014】上述の方法により、本発明の製造方法によ
って製造される食肉製品の中の構成脂肪酸は、ドコサヘ
キサエン酸(C22:6)、ドコサペンタエン酸
(C22:5)、イコサペンタエン酸(C20:5)、アラキド
ン酸(C20:4)、リノレン酸(C18:3)、リノール酸
(C18:2)、オレイン酸(C18:1)、ステアリン酸(C
18:0)、ヘキサデセン酸(C16:1)、パルミチン酸(C
16:0)などであることがわかった。以下、実施例により
本発明をさらに詳細に説明する。According to the above-mentioned method, the constituent fatty acids in the meat product produced by the production method of the present invention are docosahexaenoic acid (C 22: 6 ), docosapentaenoic acid (C 22: 5 ), and icosapentaenoic acid (C 20: 5 ), arachidonic acid (C 20: 4 ), linolenic acid (C 18: 3 ), linoleic acid (C 18: 2 ), oleic acid (C 18: 1 ), stearic acid (C
18: 0 ), hexadecenoic acid (C16 : 1 ), palmitic acid (C
16: 0 ). Hereinafter, the present invention will be described in more detail with reference to examples.
【0015】[0015]
実施例1 ロ−スハムの製造1 脂肪含量が10%の豚ロ−ス肉に、表1に示す組成の注
射液を30%注入後、7℃で48時間塩漬・熟成した。
塩漬・熟成終了後、ケ−シングに充填し、直ちに常法通
り加熱処理した。Example 1 Production of Loin Ham 1 Pork loin having a fat content of 10% was injected with 30% of an injection having the composition shown in Table 1 and then salted and aged at 7 ° C. for 48 hours.
After completion of the salting and aging, the mixture was filled in a casing and immediately heat-treated as usual.
【0016】[0016]
【表1】 [Table 1]
【0017】最終製品の官能検査結果を表2に示した。
DHAの添加量が3%以下の場合に、風味、外観に品質
の低下は認められなかった。Table 2 shows the sensory test results of the final product.
When the amount of DHA added was 3% or less, no deterioration in flavor or appearance was observed.
【0018】[0018]
【表2】表2 官能検査結果 ───────────────────────── DHA含量 0.8% 1.5% 3.0% 3.8% ───────────────────────── 魚臭の有無 無し 無し 無し 有り 外観の異常 無し 無し 無し 有り ─────────────────────────[Table 2] Table 2 Sensory test results D DHA content 0.8% 1.5% 3.0% 3.8% ──────有無 Fishy odor No No No No Yes Abnormal appearance No No No No Yes ──────────────── ─────────
【0019】実施例2 ロ−スハムの製造2 脂肪含量が10%の豚ロ−ス肉に、表1に示したNo.
3の注射液を30%注入後、7℃で12、16、24、
72、168および192時間塩漬・熟成した。塩漬・
熟成終了後、ケ−シングに充填し、直ちに常法通り加熱
処理した。Example 2 Production of Loin Ham 2 Pork loin meat having a fat content of 10% was mixed with No.
After injecting 30% of the injection solution of No. 3, 12, 16, 24,
Salted and aged for 72, 168 and 192 hours. Salted
After the ripening was completed, it was filled in a casing and immediately heat-treated as usual.
【0020】最終製品の官能検査結果を表3に示した。
風味および外観に異常が認められないロ−スハムは、1
6〜168時間の塩漬・熟成を行うことで製造すること
ができた。Table 3 shows the sensory test results of the final product.
Roast ham with no abnormality in flavor and appearance is 1
It could be produced by salting and aging for 6 to 168 hours.
【0021】[0021]
【表3】表3 官能検査結果 ───────────────────────── 塩漬・熟成時間 12 16 24 72 168 192 ───────────────────────── 魚臭の有無 有り 無し 無し 無し 無し 有り 外観の異常 無し 無し 無し 無し 無し 有り ─────────────────────────[Table 3] Table 3 Sensory test results ───────────────────────── Salting and aging time 12 16 24 72 168 192 ─────有無 Fish odor Yes Yes No No No No Yes Abnormal appearance No No No No No No Yes ─────────── ──────────────
【0022】実施例3 ポ−クソ−セ−ジの製造1 5mmのプレ−トでミンチした1000gの豚ウデ肉
に、食塩18g、亜硝酸ナトリウム0.2g、アスコル
ビン酸ナトリウム1gおよびポリリン酸塩3gを添加混
合し、5℃で48時間塩漬・熟成した。塩漬・熟成終了
後、3mmのプレ−トでミンチした200gの豚脂肪、
8gの香辛料および、DHAをその含量が3.0%とな
る量、順次添加し、真空下で5分間混合した。混合後羊
腸に充填し、直ちに常法通り加熱処理した。Example 3 Preparation of poxo-sage 15 To 1000 g of pork meat minced with a 15 mm plate were added 18 g of salt, 0.2 g of sodium nitrite, 1 g of sodium ascorbate and 3 g of polyphosphate. Was added, mixed and salted and aged at 5 ° C. for 48 hours. After salting and aging, 200 g of pork fat minced with 3 mm plate,
8 g of spice and DHA were added in an amount to give a content of 3.0%, and mixed under vacuum for 5 minutes. After mixing, it was filled into sheep intestine and immediately heat-treated as usual.
【0023】官能検査の結果、最終製品には魚臭等の異
味・異臭は認められず、また、外観も良好であった。As a result of the sensory test, no unpleasant taste or odor such as fish odor was observed in the final product, and the appearance was good.
【0024】実施例4 ポ−クソ−セ−ジの製造2 新鮮な豚ウデ肉1000g、豚脂肪200g、食塩18
g、亜硝酸ナトリウム0.2g、アスコルビン酸ナトリ
ウム1g、ポリリン酸塩3gおよび香辛料8gをサイレ
ントカッタ−内で細切混合し、さらにDHAをその含量
が0%(対照区)および2.3%(試験区)となるよう
に添加・混合した。この混合物を羊腸に充填し、50℃
で30分間および60℃で10分間塩漬・熟成後、直ち
に常法通り加熱処理した。Example 4 Preparation of pork sage 2 Fresh pork meat 1000 g, pork fat 200 g, salt 18
g, 0.2 g of sodium nitrite, 1 g of sodium ascorbate, 3 g of polyphosphate and 8 g of spices were minced and mixed in a silent cutter, and the content of DHA was 0% (control) and 2.3% (control). (Test zone). Fill this mixture into sheep intestine,
For 30 minutes and at 60 ° C. for 10 minutes, and then immediately heat-treated as usual.
【0025】官能検査の結果、最終製品の風味、外観に
対照区と試験区との間で差は認められなかった。表4に
はこれらの脂肪酸組成を示した。なお、脂肪酸組成は常
法によりメチルエステル化した後、ガスクロマトグラフ
ィ−により測定した。As a result of the sensory test, no difference was observed in the flavor and appearance of the final product between the control group and the test group. Table 4 shows the composition of these fatty acids. The fatty acid composition was measured by gas chromatography after methyl esterification by a conventional method.
【0026】[0026]
【表4】表4 ポ−クソ−セ−ジの脂肪酸組成(%) ────────────────── 脂肪酸 対照区 試験区 ────────────────── C16:0 21.52 21.16 C16:1 3.19 3.28 C18:0 12.28 11.97 C18:1 43.56 42.82 C18:2 10.94 10.02 C20:4 - 0.63 C20:5 - 0.63 C22:6 - 2.37 ──────────────────[Table 4] Fatty acid composition of poxo-sage (%) 脂肪酸 Fatty acid control plot Test plot ──────── ────────── C 16: 0 21.52 21.16 C 16: 1 3.19 3.28 C 18: 0 12.28 11.97 C 18: 1 43.56 42.82 C 18: 2 10.94 10.02 C 20: 4-0.63 C 20: 5 -0.63 C 22: 6-2.37 ──────────────────
【0027】[0027]
【発明の効果】脂肪含量が5〜40重量%の畜肉原料に
対して、ドコサヘキサエン酸0.01〜3.0重量%を
加えた本発明により製造されるハムやソーセージなどの
食肉製品は、魚臭・異臭が認められず、また、外観も良
好である。このように、本発明により、より付加価値の
高い食肉製品を製造することができる。EFFECT OF THE INVENTION Meat products such as ham and sausage produced by the present invention in which 0.01 to 3.0% by weight of docosahexaenoic acid are added to a raw material of meat having a fat content of 5 to 40% by weight are fish. No odor or odor is observed, and the appearance is good. Thus, according to the present invention, a meat product with higher added value can be manufactured.
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 昭60−98963(JP,A) 特開 昭62−163669(JP,A) 特開 平2−227052(JP,A) 特開 平6−46801(JP,A) 特公 昭39−25637(JP,B1) (58)調査した分野(Int.Cl.7,DB名) A23L 1/31 A23L 1/30 A23L 1/314 A23L 1/317 ──────────────────────────────────────────────────続 き Continuation of the front page (56) References JP-A-60-98963 (JP, A) JP-A-62-163669 (JP, A) JP-A-2-227052 (JP, A) JP-A-6-163 46801 (JP, A) JP 39-25637 (JP, B1) (58) Fields investigated (Int. Cl. 7 , DB name) A23L 1/31 A23L 1/30 A23L 1/314 A23L 1/317
Claims (4)
とする食肉製品の製造方法であって、塩漬・熟成工程前
あるいは該工程後に、該畜肉の0.01〜3.0重量%
の量のドコサヘキサエン酸を該畜肉に添加することを特
徴とする食肉製品の製造方法。1. A method for producing a meat product using meat having a fat content of 5 to 40% by weight as a raw material, wherein the meat is prepared at 0.01 to 3.0% by weight before or after the salting / aging process. %
A method for producing a meat product, comprising adding docosahexaenoic acid in an amount of docosahexaenoic acid to said meat.
前に添加し、0〜10℃の範囲で16〜168時間、若
しくは45〜60℃の範囲で30〜90分間塩漬・熟成
後、直ちに加熱処理を施すことを特徴とする請求項1記
載の食肉製品の製造方法。2. Docosahexaenoic acid is added before the salting / ripening step, and immediately after salting / ripening at 0 to 10 ° C for 16 to 168 hours or at 45 to 60 ° C for 30 to 90 minutes. The method for producing a meat product according to claim 1, wherein a heat treatment is performed.
成した畜肉原料に添加し、直ちに加熱処理を施すことを
特徴とする請求項1記載の食肉製品の製造方法。3. The method for producing a meat product according to claim 1, wherein docosahexaenoic acid is added to a sufficiently salted and aged raw meat material and immediately subjected to a heat treatment.
酸塩および0.02〜0.5%のアスコルビン酸塩の存
在下で行われることを特徴とする請求項1、2又は3記
載の食肉製品の製造方法。4. The meat as claimed in claim 1, wherein the salting and aging are carried out in the presence of 10 to 300 ppm of nitrite and 0.02 to 0.5% of ascorbate. Product manufacturing method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10597093A JP3188965B2 (en) | 1993-04-09 | 1993-04-09 | Method for producing meat product to which docosahexaenoic acid is added |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10597093A JP3188965B2 (en) | 1993-04-09 | 1993-04-09 | Method for producing meat product to which docosahexaenoic acid is added |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH06292534A JPH06292534A (en) | 1994-10-21 |
| JP3188965B2 true JP3188965B2 (en) | 2001-07-16 |
Family
ID=14421641
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10597093A Expired - Fee Related JP3188965B2 (en) | 1993-04-09 | 1993-04-09 | Method for producing meat product to which docosahexaenoic acid is added |
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| Country | Link |
|---|---|
| JP (1) | JP3188965B2 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH692263A5 (en) * | 1999-04-29 | 2002-04-30 | Europ Foodtec Gmbh | Meat products with omega-3 fatty acid and vitamin. |
| ES2316251B1 (en) * | 2006-09-22 | 2009-12-30 | Javier Santos Fernandez | PROCESS FOR THE INCORPORATION OF OMEGA3 (DHA) TO HUMAN CONSUMER MEAT PRODUCTS AND DERIVATIVES. |
| KR101420772B1 (en) * | 2013-06-28 | 2014-07-17 | 주식회사 마니커에프앤지 | A manufacturing method of low-fat chicket breast nugget including omega-3 |
-
1993
- 1993-04-09 JP JP10597093A patent/JP3188965B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH06292534A (en) | 1994-10-21 |
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