JP3337553B2 - Lipstick overcoat - Google Patents
Lipstick overcoatInfo
- Publication number
- JP3337553B2 JP3337553B2 JP11085894A JP11085894A JP3337553B2 JP 3337553 B2 JP3337553 B2 JP 3337553B2 JP 11085894 A JP11085894 A JP 11085894A JP 11085894 A JP11085894 A JP 11085894A JP 3337553 B2 JP3337553 B2 JP 3337553B2
- Authority
- JP
- Japan
- Prior art keywords
- lipstick
- weight
- water
- powder
- perfluoropolyether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 41
- 239000000843 powder Substances 0.000 claims description 36
- 239000000377 silicon dioxide Substances 0.000 claims description 19
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 18
- 239000010702 perfluoropolyether Substances 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 12
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 9
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 9
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 7
- 229910052731 fluorine Inorganic materials 0.000 claims description 2
- 125000001153 fluoro group Chemical group F* 0.000 claims description 2
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims description 2
- 101001031591 Mus musculus Heart- and neural crest derivatives-expressed protein 2 Proteins 0.000 claims 1
- 230000000694 effects Effects 0.000 description 30
- 239000002537 cosmetic Substances 0.000 description 17
- 239000003921 oil Substances 0.000 description 14
- 235000019198 oils Nutrition 0.000 description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 11
- 239000008346 aqueous phase Substances 0.000 description 8
- 230000002688 persistence Effects 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- -1 perfluoro groups Chemical group 0.000 description 7
- 239000012071 phase Substances 0.000 description 6
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 229910002012 Aerosil® Inorganic materials 0.000 description 3
- 238000002845 discoloration Methods 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- 230000000740 bleeding effect Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 235000010724 Wisteria floribunda Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000005661 hydrophobic surface Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 235000019871 vegetable fat Nutrition 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
【０００１】[0001]
【産業上の利用分野】本発明は、口紅オーバーコートに
関し、更に詳細には、口紅を塗布した上に塗布すること
により口紅の化粧効果の持続性を改善し、食器等への付
着を抑える口紅オーバーコートに関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a lipstick overcoat, and more particularly, to a lipstick which improves the persistence of the lipstick's cosmetic effect by being applied on a lipstick and suppresses adhesion to dishes and the like. Regarding overcoat.
【０００２】[0002]
【従来の技術】口紅オーバーコートは、口紅の化粧効果
の持続性、光沢の改善等を目的とした商品として提供さ
れている。2. Description of the Related Art A lipstick overcoat is provided as a product for the purpose of maintaining the cosmetic effect of lipstick, improving gloss, and the like.
【０００３】従来、口紅オーバーコートとしては、水系
又はアルコール系に、セルロース系高分子化合物、ビニ
ル系樹脂、アクリル系樹脂等の高分子化合物やメチルフ
ェニルポリシロキサンなどを配合し、配合した高分子化
合物などの特性を利用するものや、油分を混合した粉体
を主成分とした粉末状若しくはプレス状のものが知られ
ている（特公昭６１−１２８８３号公報、特開昭６１−
２４５１２号公報）。Conventionally, a lipstick overcoat has been prepared by blending a polymer compound such as a cellulose polymer compound, a vinyl resin, an acrylic resin, methylphenylpolysiloxane, etc., with an aqueous or alcoholic compound. There are known those utilizing characteristics such as the above, and those in the form of a powder or a press mainly comprising a powder mixed with an oil (Japanese Patent Publication No. 61-12883, Japanese Patent Application Laid-Open No. 61-1986).
No. 24512).
【０００４】しかしながら、従来の口紅オーバーコート
は、口紅の食器等への付着（色うつり）を防ぐには充分
満足できるものではなかった。また、粉末状のものは塗
布の仕方により効果にムラがでてしまうとともに、高分
子化合物等を配合するタイプのものは使用時におけるべ
たつきがあり、官能面においても問題があった。[0004] However, the conventional lipstick overcoat has not been sufficiently satisfactory to prevent the lipstick from adhering to tableware or the like (color change). In addition, the powdery material has uneven effects depending on the method of application, and the type in which a polymer compound or the like is blended has stickiness at the time of use, and also has a problem in the sense of function.
【０００５】このため、口紅の化粧効果の持続性を改善
し、口紅の色うつりを抑えることができ、しかも使用性
に優れた口紅オーバーコートが望まれている。[0005] Therefore, there is a demand for a lipstick overcoat which can improve the persistence of the cosmetic effect of the lipstick, suppress the discoloration of the lipstick, and have excellent usability.
【０００６】さらにパーフルオロポリエーテルにシリカ
アルミナ等の粉末を分散させ、パーフルオロポリエーテ
ルの撥油性により、２次付着を防ぐ効果を狙ったものも
ある（特開平５−２２１８２９号公報）。しかし、この
技術は化粧効果の持続性の改善効果、口紅の色うつりを
抑える効果、使用性の向上効果はあるものの、パーフル
オロポリエーテル中への粉末の分散が困難なため両者は
分離しやすく、そのため室温であっても、チューブから
出す時に、パーフルオロポリエーテルのみが出て来ると
いう問題や、口紅上への塗布後にも経時的にシリカ粉末
が分離して口紅が白く粉をふいたようになったり、著し
くマット状になる等の問題がある。Further, there is a method in which powder such as silica alumina is dispersed in perfluoropolyether to prevent the secondary adhesion due to the oil repellency of perfluoropolyether (JP-A-5-221829). However, although this technology has the effect of improving the persistence of the cosmetic effect, suppressing the discoloration of lipstick, and improving the usability, it is difficult to disperse the powder in perfluoropolyether, so that both are easily separated. Therefore, even at room temperature, there is a problem that only the perfluoropolyether comes out when the tube is taken out of the tube, and the silica powder separates with time after application on the lipstick, and the lipstick becomes white and dusts. There is a problem such as becoming matte or remarkably mat-like.
【０００７】[0007]
【発明が解決しようとする課題】本発明は、化粧効果の
持続性、口紅の色うつりを抑え、使用性に優れ、しか
も、チューブから出す時に、パーフルオロポリエーテル
のみが出て来るという問題や、口紅上への塗布後にも経
時的にシリカ粉末が分離して口紅が白く粉をふくことが
ない口紅オーバーコートを提供することを目的とする。DISCLOSURE OF THE INVENTION The present invention has the problem of maintaining the cosmetic effect, suppressing the discoloration of lipstick, being excellent in usability, and having the problem that only perfluoropolyether comes out when the tube is taken out. It is another object of the present invention to provide a lipstick overcoat in which silica powder is separated over time even after application on the lipstick, and the lipstick is white and does not wipe the powder.
【０００８】[0008]
【課題を解決するための手段】上記課題を解決するため
の口紅オーバーコートは、内相に化学式１に示す平均ｎ
＝２６〜６００のジメチルポリシロキサン及び／又は化
学式２に示すパーフルオロポリエーテルを口紅オーバー
コート組成物全体の２〜８０重量％、外相に水及びシリ
カ粉末及び／又はアルミナ粉末を含有し、 シリカ粉末及
び／又はアルミナ粉末の含有量が口紅オーバーコート組
成物全体の０．５〜１０重量％であることを特徴とする
水中油型の口紅オーバーコートである。Means for Solving the Problems A lipstick overcoat for solving the above-mentioned problems has an internal phase having an average n represented by the formula (1).
= 26-600 dimethylpolysiloxane and / or perfluoropolyether of formula 2 over lipstick
2 to 80% by weight of the entire coating composition, containing water and silica powder and / or alumina powder in the external phase,
And / or alumina powder content of lipstick overcoat
An oil-in-water type lipstick overcoat characterized by being 0.5 to 10% by weight of the whole composition .
【０００９】[0009]
【化３】 Embedded image
【００１０】[0010]
【化４】 （式中、Ｒ1 、Ｒ2 、Ｒ3 、Ｒ4 及びＲ5 は同一又は異
なって、それぞれフッ素原子、パーフルオロアルキル基
又はオキシパーフルオロアルキル基を示し、ｐ、ｑ及び
ｒは分子量５００〜１０，０００を与える０以上の整数
を示す。但し、ｐ＝ｑ＝ｒ＝０となることはない。）Embedded image Wherein R 1 , R 2 , R 3 , R 4 and R 5 are the same or different and each represent a fluorine atom, a perfluoroalkyl group or an oxyperfluoroalkyl group, and p, q and r have a molecular weight of 500 to An integer of 0 or more giving 10,000 is provided, provided that p = q = r = 0.)
【００１１】[0011]
【作用】本発明では、水相中にシリカ粉末及び／又はア
ルミナ粉末を含有しているため、塗布後の粉末の吸油性
によって口紅の流動油分を固化させ、化粧効果を持続さ
せることができる。According to the present invention, since the silica powder and / or the alumina powder are contained in the aqueous phase, the fluid oil of the lipstick can be solidified by the oil absorption of the powder after application, and the cosmetic effect can be maintained.
【００１２】ただ、水相中にシリカ粉末及び／又はアル
ミナ粉末を含有させただけでは粉末の白浮きが起こり、
さらに口紅がマット状になる。これを防ぐため、本発明
では、内相として口紅となじみにくいジメチルポリシロ
キサン及び／又はパーフルオロポリエーテルを油分とし
て配合することによりペースト状の形態を得ることがで
き、これにより口紅の化粧効果の持続性を改善し、口紅
の食器等への付着及び色にじみを抑え、しかも簡便に使
用することができる口紅オーバーコートが得られる。However, if the silica powder and / or the alumina powder are simply contained in the aqueous phase, whitening of the powder occurs,
In addition, the lipstick becomes mat-like. In order to prevent this, in the present invention, a paste-like form can be obtained by blending dimethylpolysiloxane and / or perfluoropolyether which is hardly compatible with lipstick as an internal phase as an oil component, whereby the cosmetic effect of lipstick can be obtained. A lipstick overcoat can be obtained which improves the persistence, suppresses adhesion of lipstick to tableware and the like and suppresses color bleeding, and can be used easily.
【００１３】[0013]
【実施態様例】以下に本発明の実施態様例を構成要件ご
とに説明する。DESCRIPTION OF THE PREFERRED EMBODIMENTS Embodiments of the present invention will be described below for each component.
【００１４】Ａ：（内相：油分） （ジメチルポリシロキサン）ジメチルポリシロキサンは
一般式は上記化学式１で表わされるものであり、ｎ＝２
６〜６００である。A: (Internal phase: oil) (Dimethylpolysiloxane) The dimethylpolysiloxane has the general formula represented by the above chemical formula 1, and n = 2
6 to 600.
【００１５】粘度は２０ｃｓ〜５０００ｃｓが好まし
い。中でも使用性時におけるのびや口唇とのなじみの点
から粘度が１００〜１０００ｃｓがより好ましい。The viscosity is preferably from 20 cs to 5000 cs. Above all, the viscosity is more preferably from 100 to 1000 cs from the viewpoint of spreading and compatibility with the lips during use.
【００１６】具体的には、信越シリコーン社のＫＦ９６
Ａ−２０ｃｓ、１００ｃｓ、３００ｃｓ、１０００ｃ
ｓ、５０００ｃｓ、東レダウコーニング・シリコーン社
のＳＨ２００ｃ−２０ｃｓ、５０ｃｓ、１００ｃｓ、２
００ｃｓ、３５０ｃｓ、５００ｃｓ、１０００ｃｓ、３
０００ｃｓ、５０００ｃｓがこれにあたる。Specifically, Shin-Etsu Silicone KF96
A-20cs, 100cs, 300cs, 1000c
s, 5000 cs, Toray Dow Corning Silicone SH200c-20cs, 50cs, 100cs, 2
00cs, 350cs, 500cs, 1000cs, 3
000 cs and 5000 cs correspond to this.
【００１７】（パーフルオロポリエーテル）本発明に使
用されるパーフルオロポリエーテルは、上記化学式２の
一般式で表わされるものである。(Perfluoropolyether) The perfluoropolyether used in the present invention is represented by the above general formula (2).
【００１８】なお、化学式２において、カッコ内に示さ
れる各パーフルオロ基はこの順で並んでいる必要はな
く、またランダム重合でもブロック重合でもかまわな
い。かかるパーフルオロポリエーテルとしては、特に粘
度が５〜５，０００ｃＳｔの液体状のものが好ましく、
例えば、次の化学式３で表わされるＦＯＮＢＬＩＮ Ｈ
Ｃ−０４（平均分子量１，５００）、ＦＯＮＢＬＩＮ
ＨＣ−２５（平均分子量３，２００）及びＦＯＮＢＬＩ
Ｎ ＨＣ−Ｒ（平均分子量６，６００）（以上モンテフ
ロス社製）や、次の化学式４で表わされるテムナムＳ−
２０（平均分子量２５，０００）、テムナムＳ−６５
（平均分子量、４５００）、テムナムＳ−１００（平均
分子量５，６００）及びテムナムＳ−２００（平均分子
量８，４００）（以上ダイキン工業社製）などの市販品
を使用することができる。In chemical formula 2, the perfluoro groups shown in parentheses need not be arranged in this order, and may be random polymerization or block polymerization. As the perfluoropolyether, a liquid having a viscosity of 5 to 5,000 cSt is particularly preferable.
For example, FONBLIN H represented by the following chemical formula 3
C-04 (average molecular weight 1,500), FONBLIN
HC-25 (average molecular weight 3,200) and FONBLI
NHHC-R (average molecular weight 6,600) (manufactured by Montefros) and Temnum S- represented by the following chemical formula 4
20 (average molecular weight 25,000), Temnum S-65
Commercially available products such as (average molecular weight 4,500), Temnum S-100 (average molecular weight 5,600) and Temnum S-200 (average molecular weight 8,400) (all manufactured by Daikin Industries, Ltd.) can be used.
【００１９】[0019]
【化５】 （式中、ｍ及びｎは分子量が５００〜１０，０００とな
る数を示し、ｎ／ｍは０．２〜２である。）Embedded image (In the formula, m and n each represent a number having a molecular weight of 500 to 10,000, and n / m is 0.2 to 2.)
【００２０】[0020]
【化６】 （式中、ｌは４〜５００の数を示す。） なお、ジメチルポリシロキサンと、パーフルオロポリエ
ーテルとはいずれか一種含有せしめてもよいが、両者を
同時に含有せしめてもよい。 （含有量）これらの油分は２〜８０重量％が配合される
（８０％以上では、ｏ／ｗ乳化が不可能である。）。さ
らに塗布後の艶（光沢）のより一層の向上の点で油分は
５〜８０重量％が好ましく、また、使用性のなめらかさ
を良くするためには５〜７０重量％がさらに好ましい。Embedded image (In the formula, 1 represents a number of 4 to 500.) In addition, any one of dimethylpolysiloxane and perfluoropolyether may be contained, or both may be contained simultaneously. (Content) These oils are blended in an amount of 2 to 80% by weight (above 80%, o / w emulsification is impossible). Further, the oil content is preferably 5 to 80% by weight from the viewpoint of further improving the gloss (gloss) after coating, and more preferably 5 to 70% by weight to improve the smoothness of use.
【００２１】また外相の水相中に含まれるシリカ粉末及
びアルミナ粉末は、通常の化粧料に用いられるものであ
ればよく、例えばサイロイド５５（富士デヴィソン化学
（株）製、エロジール２００、３００、Ｒ−９７２、Ｒ
９７４（不二化成（株）製）、アルミナＡＫＳ−Ｇ、Ａ
ＫＰ−３０、ＫＰ−ＧＭ（住友化学（株）製）等を好適
に使用することができる。The silica powder and the alumina powder contained in the external aqueous phase may be those used in ordinary cosmetics. For example, SYLOID 55 (manufactured by Fuji Devison Chemical Co., Ltd., Esilyl 200, 300, R −972, R
974 (Fuji Kasei Co., Ltd.), alumina AKS-G, A
KP-30, KP-GM (manufactured by Sumitomo Chemical Co., Ltd.) and the like can be suitably used.
【００２２】Ｂ：（外相：水相） 外相は、水及びシリカ粉末及び／又はアルミナ粉末を含
有する。B: (External phase: aqueous phase) The external phase contains water and silica powder and / or alumina powder.
【００２３】シリカ粉末及びアルミナ粉末は、単独又は
２種以上を組合わせて用いることができ、全組成中に
０．５〜１０重量％とする。１〜１０重量％がより好ま
しく、１〜５重量％がさらに好ましい。The silica powder and the alumina powder can be used alone or in combination of two or more, and should be 0.5 to 10% by weight in the total composition . 1 to 10% by weight is more preferable, and 1 to 5% by weight is further preferable.
【００２４】０．５重量％未満では著しい効果が得られ
ず、また、１０重量％を超えると硬度が高くなり塗布し
づらくなる。５重量％以下において塗布のし易さの向上
効果がある。If the amount is less than 0.5% by weight, a remarkable effect cannot be obtained, and if it exceeds 10% by weight, the hardness becomes high and the coating becomes difficult. At 5% by weight or less, there is an effect of improving the ease of application.
【００２５】なお、アエロジルＲ−９７２、Ｒ９７４に
代表される疏水性表面を持つシリカ粉末及びアルミナ粉
末はそのままでは水中に分散させることが難かしい。し
かしまず適量のエタノールまたは多価アルコール等に湿
潤させた後、これに水を加えながら撹拌分散を行う方法
を用いることにより、容易に水相中に分散させることが
できる。なお、この方法も本発明者らが新たに発見した
ものである。It is difficult to disperse silica powder and alumina powder having a hydrophobic surface typified by Aerosil R-972 and R974 as they are in water. However, it can be easily dispersed in the aqueous phase by using a method in which it is first wetted with an appropriate amount of ethanol or polyhydric alcohol and then stirred and dispersed while adding water thereto. This method has also been newly discovered by the present inventors.
【００２６】また、本発明の口紅コートは乳化のために
水相中に水溶性乳化剤を配合することができる。水溶性
乳化剤は一般に化粧品用に用いられるものであれば、何
でもよい。The lipstick coat of the present invention can contain a water-soluble emulsifier in an aqueous phase for emulsification. Any water-soluble emulsifier may be used as long as it is generally used for cosmetics.
【００２７】（選択的成分等）また、本発明の口紅オー
バーコートは、上記成分でペースト状の形態を取るが、
使用性にチキリトロピー性を付与し、はじきを低減させ
るために水相に各種水膨潤性粘度鉱物や水溶性高分子を
配合することができる。これら増粘剤は、一般に化粧品
用に用いるものであれば何でもよく、一種もしくは二種
以上用いられる。(Selective components, etc.) The lipstick overcoat of the present invention takes the form of a paste with the above components.
Various water-swellable viscosity minerals and water-soluble polymers can be added to the aqueous phase in order to impart thixotropy to the usability and reduce repellency. Any of these thickeners may be used as long as they are generally used for cosmetics, and one or more of them may be used.
【００２８】さらに、本発明においては、前記必須成分
のほか、通常の化粧料に用いられる成分、例えば炭化水
素、高級脂肪酸エステル、動植物油脂、等の化粧品用油
剤、界面活性剤、酸化防止剤、香料、色素、アルコー
ル、多価アルコール、防腐剤、紫外線吸収剤、保湿剤、
水等を本発明の効果を損なわない範囲で適宜配合するこ
とができる。Furthermore, in the present invention, in addition to the above essential components, components used in ordinary cosmetics, for example, cosmetic oils such as hydrocarbons, higher fatty acid esters, animal and vegetable fats and oils, surfactants, antioxidants, Fragrance, pigment, alcohol, polyhydric alcohol, preservative, ultraviolet absorber, humectant,
Water and the like can be appropriately added as long as the effects of the present invention are not impaired.
【００２９】[0029]
【実施例】次に実施例を挙げて本発明を更に説明する
が、本発明はこれらの実施例に限定されるものではな
い。EXAMPLES The present invention will be further described with reference to examples, but the present invention is not limited to these examples.
【００３０】（実施例１〜６、比較例１〜４）表１に示
す組成の口紅オーバーコートを以下の方法により作製し
た。Examples 1 to 6 and Comparative Examples 1 to 4 Lipstick overcoats having the compositions shown in Table 1 were prepared by the following methods.
【００３１】実施例１〜実施例６ エタノールにポリオキシエチレン（１５モル付加）ラウ
リルエーテルを加熱溶解した後水を加え、さらにディス
パーで分散した。水膨潤性粘度鉱物を加える場合はここ
に添加し、さらにディスパーで分散した。そこに油分を
添加し、十分にディスパーで分散した。Examples 1 to 6 Polyoxyethylene (addition of 15 mol) lauryl ether was dissolved in ethanol by heating, water was added, and the mixture was dispersed with a disper. When a water-swellable viscosity mineral was added, it was added here and further dispersed with a disper. The oil was added thereto and sufficiently dispersed with a disper.
【００３２】比較例１、比較例２ 水中にポリオキシエチレン（１５モル付加）ラウリルエ
ーテルを加熱溶解しその後、油分を撹拌添加した。Comparative Examples 1 and 2 Polyoxyethylene (addition of 15 mol) lauryl ether was dissolved in water by heating, and then the oil was added with stirring.
【００３３】比較例３ エタノールにポリオキシエチレン（１５モル付加）ラウ
リルエ−テルを加熱溶解した後シリカを湿潤分散させ、
水を加え、さらにディスパーで分散した。そこに油分を
添加し、十分にディスパーで分散した。Comparative Example 3 Polyoxyethylene (addition of 15 mol) lauryl ether was dissolved in ethanol by heating, and silica was wet-dispersed.
Water was added and further dispersed with a disper. The oil was added thereto and sufficiently dispersed with a disper.
【００３４】比較例４ 水にエタノールを添加し、あとは比較例１、比較例２と
同様とした。Comparative Example 4 Ethanol was added to water, and the rest was the same as Comparative Examples 1 and 2.
【００３５】[0035]
【表１】 ＊１：ＫＦ９６Ａ３００ ＊２：ＫＦ９６Ａ１００ ＊３：ＫＦ９６Ａ１０００ ＊４：シリカ（アエロジルＲ９７２） ＊５：アルミナ（アルミナＡＫＳ） ＊６：適量 （比較例５）下記の処方を下記の製法により口紅オーバ
ーコートを製造した。[Table 1] * 1: KF96A300 * 2: KF96A100 * 3: KF96A1000 * 4: Silica (Aerosil R972) * 5: Alumina (Alumina AKS) * 6: Appropriate amount (Comparative Example 5) A lipstick overcoat is manufactured by the following method using the following formulation. did.
【００３６】 （処方） （重量％） （１）パーフルオロポリエーテル （ＦＯＭＢＬＩＮ ＨＣ−２５） ９８．８ （２）シリカ（エロジール３００） １．０ （３）赤色２０２号 ０．１ （４）香料 ０．１ （製法）成分（１）に成分（２）〜（４）を添加し、均
一に混合して口紅オーバーコートを製造した。実施例１
〜６及び比較例１〜５の口紅オーバーコートについて色
うつり防止効果および化粧効果の持続性さらに使用性を
以下の試験方法により評価した。評価結果を表２に示
す。(Formulation) (% by weight) (1) Perfluoropolyether (FOMBLIN HC-25) 98.8 (2) Silica (Ezil 300) 1.0 (3) Red No. 202 0.1 (4) Fragrance 0.1 (Production method) The components (2) to (4) were added to the component (1) and mixed uniformly to produce a lipstick overcoat. Example 1
The lipstick overcoats of Comparative Examples 1 to 6 and Comparative Examples 1 to 5 were evaluated for the effect of preventing color fogging, the persistence of the cosmetic effect, and the usability by the following test methods. Table 2 shows the evaluation results.
【００３７】（試験方法） ・色うつり防止効果：口唇に口紅を２回塗布し、その上
に口紅オーバーコートを塗布した。そこにガラス板を押
しつけ、色うつりを評価した。色うつり防止効果の優れ
ているものを○、やや効果のあるものを△、効果のない
ものを×として評価した。(Test method)-Effect of preventing color shift: Lipstick was applied twice to the lips, and a lipstick overcoat was applied thereon. A glass plate was pressed against the glass plate to evaluate color shift. Those having an excellent effect of preventing color fogging were evaluated as ○, those having some effect were evaluated as Δ, and those having no effect were evaluated as ×.
【００３８】・化粧効果の持続性：パネラーに通常の生
活をしてもらい、唇に口紅を塗布し、その上に口紅オー
バーコートを塗布し、半日後の化粧もちを評価した。効
果の優れているものを○、やや効果のあるものを△、効
果のないものを×として評価した。なお、化粧もちの一
つとして、いわゆるにじみのないこと、すなわち経時的
に口紅の輪郭が不鮮明になることがないことをも評価の
中に含んだ。Sustainability of makeup effect: A panelist was allowed to live a normal life, lipstick was applied to the lips, and a lipstick overcoat was applied thereon, and the makeup stay after half a day was evaluated. Those with excellent effects were evaluated as ○, those with some effects were evaluated as Δ, and those with no effect were evaluated as ×. In addition, as one of the makeup stickiness, what is called no bleeding, that is, the contour of the lipstick does not become unclear over time was also included in the evaluation.
【００３９】・使用性：口紅を塗布し、その上に実施例
又は比較例の口紅オーバーコートを塗布し、塗布のしや
すさ、化粧膜の均一性等の使用性を評価した。使用性が
良好なものを○、やや問題はあるが使用可能なものを
△、全く使用できないものを×として評価した。Usability: A lipstick was applied, and a lipstick overcoat of Example or Comparative Example was applied thereon, and the usability such as ease of application and uniformity of a cosmetic film was evaluated. Those with good usability were evaluated as ○, those with some problems but usable were evaluated as Δ, and those with no use were evaluated as x.
【００４０】[0040]
【表２】 ：口びるに弾かれた。 ：口びるのまわりに白い粉浮きが生じた。 ：口びるにやや弾かれた。 ：分離及び口紅に白い粉浮きが生じた。表２に示す結
果から明らかなように、色移り防止効果、化粧効果の持
続性、使用性のいずれにおいても優れた結果を示した。[Table 2] A: It was flipped. : White powder floating around mouth. : Slightly flicked. : Separation and white powder floating on the lipstick. As is clear from the results shown in Table 2, excellent results were exhibited in any of the color transfer prevention effect, the persistence of the cosmetic effect, and the usability.
【００４１】（実施例７）本例では、化学式１に示すジ
メチルポリシロキサン及び／又は化学式２に示すパーフ
ルオロポリエーテルの含有量と各種特性との関係、ま
た、シリカ粉末及び／又はアルミナ粉末の含有量と各種
特性との関係について調べた。(Example 7) In this example, the relationship between the content of dimethylpolysiloxane represented by the chemical formula 1 and / or the perfluoropolyether represented by the chemical formula 2 and various characteristics, and the relationship between the silica powder and / or the alumina powder The relationship between the content and various properties was investigated.
【００４２】表３に示す組成の口紅オーバーコートのサ
ンプルを以下の方法により作製した。表３及び表４にお
いてサンプル１、３、４は比較例、サンプル２、５は実
施例である。 A sample of a lipstick overcoat having the composition shown in Table 3 was prepared by the following method. Table 3 and Table 4
Samples 1, 3, and 4 are comparative examples, and samples 2 and 5 are actual.
This is an example.
【００４３】まず、エタノールにポリオキシエチレン
（１５モル付加）ラウリルエーテルを加熱溶解した後水
を加え、さらにディスパーで分散した。水膨潤性粘度鉱
物を加える場合はここに添加し、さらにディスパーで分
散した。そこに油分を添加し、十分にディスパーで分散
した。First, polyoxyethylene (addition of 15 mol) lauryl ether was dissolved in ethanol by heating, water was added, and the mixture was further dispersed with a disper. When a water-swellable viscosity mineral was added, it was added here and further dispersed with a disper. The oil was added thereto and sufficiently dispersed with a disper.
【００４４】[0044]
【表３】 ＊１：ＫＦ９６Ａ３００ ＊２：ＫＦ９６Ａ１００ ＊３：ＫＦ９６Ａ１０００ ＊４：シリカ（アエロジルＲ９７２） ＊５：アルミナ（アルミナＡＫＳ） ＊６：適量 次に、サンプル１〜５の口紅オーバーコートについて色
うつり防止効果および化粧効果の持続性さらに使用性を
前述と同様の方法の試験方法により評価した。評価結果
を表４に示す。[Table 3] * 1: KF96A300 * 2: KF96A100 * 3: KF96A1000 * 4: Silica (Aerosil R972) * 5: Alumina (Alumina AKS) * 6: Suitable amount The persistence of the effect and the usability were evaluated by the same test method as described above. Table 4 shows the evaluation results.
【００４５】[0045]
【表４】 ：乳化できず、調製不可。 ：水相が硬くなり、均一に塗布できない。[Table 4] : Cannot be emulsified and cannot be prepared. : The aqueous phase becomes hard and cannot be applied uniformly.
【００４６】表４に示す結果から明らかなように、サン
プル２において、ジメチルポリシロキサン及びパーフル
オロポリエーテルを二種用いた場合も色移り防止効果、
化粧効果の持続性、使用性のいずれにおいても優れた結
果を示した。As is evident from the results shown in Table 4 , the effect of preventing color transfer was also observed when two kinds of dimethylpolysiloxane and perfluoropolyether were used in Sample 2 .
Excellent results were shown in both the persistence of the cosmetic effect and the usability.
【００４７】また、ジメチルポリシロキサン及び／また
はパーフルオロポリエーテルを本発明の限定範囲（２〜
８０重量％）配合したもの（前述の実施例の評価結果）
は範囲外のもの（前述の比較例３及びサンプル１）に比
べ優れた効果があることがわかった。Further, dimethylpolysiloxane and / or perfluoropolyether may be used in the limited range of the present invention (2 to 2).
80% by weight) (Evaluation result of the above-mentioned example)
Was found to be more effective than those out of the range (Comparative Example 3 and Sample 1 described above).
【００４８】さらに、シリカ粉末及び／又はアルミナ粉
末の配合量については、０．５〜１０重量％配合した場
合、優れた効果があることがわかった。[0048] Further, for the amount of silica powder and / or alumina powder, 0. 5-10 If you wt% blend was found to have superior effects.
【００４９】[0049]
【発明の効果】請求項１に係る発明によれば、化粧効果
の持続性、口紅の色うつりを抑え、しかも、チューブか
ら出す時に、パーフルオロポリエーテルのみが出て来る
という問題や、口紅上への塗布後にも経時的にシリカ粉
末が分離して口紅が白く粉をふくことがないがない口紅
オーバーコートを提供することができる。請求項２に係
る発明によれば、上記効果に加えさらに使用性に優れた
口紅オーバーコートを提供することができる。 Effect of the Invention According to the invention according to claim 1, sustained cosmetic effect, suppress the lipstick color being viewed as the teeth may, when issuing from the tube, and a problem that emerges only perfluoropolyether, lipstick A lipstick overcoat can be provided in which the silica powder separates over time even after application onto the lipstick and the lipstick is white and does not wipe the powder. Claim 2
According to the present invention, in addition to the above effects, further excellent usability
A lipstick overcoat can be provided.
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 平７−316017（ＪＰ，Ａ) 特開 平７−196448（ＪＰ，Ａ) 特開 平７−145020（ＪＰ，Ａ) 特開 平７−53328（ＪＰ，Ａ) 特開 平７−53327（ＪＰ，Ａ) 特開 平５−221829（ＪＰ，Ａ) (58)調査した分野(Int.Cl.7，ＤＢ名) A61K 7/00 - 7/50 ──────────────────────────────────────────────────続 き Continuation of the front page (56) References JP-A-7-316017 (JP, A) JP-A-7-196448 (JP, A) JP-A-7-145020 (JP, A) JP-A-7- 53328 (JP, A) JP-A-7-53327 (JP, A) JP-A-5-221829 (JP, A) (58) Fields investigated (Int. Cl. 7 , DB name) A61K 7/00-7 / 50
Claims (2)
００のジメチルポリシロキサン及び／又は化学式２に示
すパーフルオロポリエーテルを口紅オーバーコート組成
物全体の２〜８０重量％、外相に水及びシリカ粉末及び
／又はアルミナ粉末を含有し、 シリカ粉末及び／又はアルミナ粉末の含有量が口紅オー
バーコート組成物全体の０．５〜１０重量％ であること
を特徴とする水中油型の口紅オーバーコート。 【化１】 【化２】 （式中、Ｒ1 、Ｒ2 、Ｒ3 、Ｒ4 及びＲ5 は同一又は異
なって、それぞれフッ素原子、パーフルオロアルキル基
又はオキシパーフルオロアルキル基を示し、ｐ、ｑ及び
ｒは分子量５００〜１０，０００を与える０以上の整数
を示す。但し、ｐ＝ｑ＝ｒ＝０となることはない。）1. The average n = 26 to 6 shown in the chemical formula 1 in the internal phase.
00 and / or as shown in Formula 2.
PerfluoropolyetherLipstick overcoat composition
The whole thing2 to 80% by weight, water and silica powder in the external phase and
// Contains alumina powderAnd When the content of silica powder and / or alumina powder is
0.5 to 10% by weight of the entire bar coat composition Being
Oil-in-water lipstick overcoat characterized by the following. Embedded imageEmbedded image(Where R1, RTwo, RThree, RFourAnd RFiveAre the same or different
Are each a fluorine atom, a perfluoroalkyl group
Or represents an oxyperfluoroalkyl group, p, q and
r is an integer of 0 or more giving a molecular weight of 500 to 10,000
Is shown. However, there is no case where p = q = r = 0. )
パーフルオロポリエーテルを口紅オーバーコート組成物Perfluoropolyether lipstick overcoat composition
全体の５〜７０重量％含有することを特徴とする請求項Claims: It is contained in an amount of 5 to 70% by weight of the whole.
１記載の水中油型の口紅オーバーコート。2. The oil-in-water lipstick overcoat according to 1.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11085894A JP3337553B2 (en) | 1994-05-25 | 1994-05-25 | Lipstick overcoat |
| FR9506194A FR2720273B1 (en) | 1994-05-25 | 1995-05-24 | Lipstick covering layer composition. |
| US08/451,089 US5750094A (en) | 1994-05-24 | 1995-05-25 | Lipstick overcoat composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11085894A JP3337553B2 (en) | 1994-05-25 | 1994-05-25 | Lipstick overcoat |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH07316016A JPH07316016A (en) | 1995-12-05 |
| JP3337553B2 true JP3337553B2 (en) | 2002-10-21 |
Family
ID=14546464
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11085894A Expired - Fee Related JP3337553B2 (en) | 1994-05-24 | 1994-05-25 | Lipstick overcoat |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3337553B2 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101756885B1 (en) | 2010-02-05 | 2017-07-11 | 가부시키가이샤 시세이도 | Makeup cosmetic and makeup kit comprising makeup cosmetic and top coating agent |
| JP7672843B2 (en) * | 2021-03-05 | 2025-05-08 | 株式会社 資生堂 | Oil-in-water lip cosmetic |
| WO2022215492A1 (en) * | 2021-04-06 | 2022-10-13 | 株式会社 資生堂 | Lip-coating cosmetic |
| WO2024143310A1 (en) * | 2022-12-28 | 2024-07-04 | 株式会社コーセー | Water-soluble lipstick topcoat |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3098604B2 (en) * | 1992-02-13 | 2000-10-16 | 株式会社コーセー | Lipstick overcoat |
| JPH0753328A (en) * | 1993-08-12 | 1995-02-28 | Kose Corp | Overcoat of lipstick |
| JP3364760B2 (en) * | 1993-08-12 | 2003-01-08 | 株式会社コーセー | Lipstick overcoat |
| JP3850454B2 (en) * | 1993-11-24 | 2006-11-29 | 株式会社日本色材工業研究所 | Lipstick overcoat |
| JPH07196448A (en) * | 1994-01-10 | 1995-08-01 | Isehan:Kk | Composition for suppressing spreading of rouge |
| JPH07316017A (en) * | 1994-05-25 | 1995-12-05 | Shiseido Co Ltd | Lipstick overcoat |
-
1994
- 1994-05-25 JP JP11085894A patent/JP3337553B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH07316016A (en) | 1995-12-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP3098604B2 (en) | Lipstick overcoat | |
| KR20010014322A (en) | Composition for external use | |
| EP0794759A1 (en) | Lipstick overcoat compositions comprising silicone oil and silica | |
| JP5066372B2 (en) | Aqueous two-layer cosmetic | |
| JP2005041795A (en) | Oily cosmetic for unevenness correction | |
| JPH08295614A (en) | Lipstick overcoat | |
| JP3689588B2 (en) | Composition for external use | |
| JP3337553B2 (en) | Lipstick overcoat | |
| JP3901618B2 (en) | Cosmetic for improving makeup paste | |
| JP5416371B2 (en) | Oily lip coat | |
| US5750094A (en) | Lipstick overcoat composition | |
| JP4980637B2 (en) | Oil-in-water pores / skin concealed cosmetics | |
| JP3508032B2 (en) | Cosmetics | |
| JP3364760B2 (en) | Lipstick overcoat | |
| JP3652843B2 (en) | Irregularity correction composition | |
| JP2002322030A (en) | Unevenness-correcting cosmetic | |
| JPH07316014A (en) | Make-up cosmetic | |
| JP3460098B2 (en) | Lipstick overcoat | |
| JP3456575B2 (en) | Water-in-oil emulsified cosmetic | |
| JP4801920B2 (en) | Stick cosmetics | |
| JP5562589B2 (en) | Cosmetic composition | |
| JPH07316017A (en) | Lipstick overcoat | |
| JP2004026681A (en) | Lipstick composition | |
| JP2000327547A (en) | UV protection cosmetics | |
| JPH11193214A (en) | Cleansing cosmetic |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20020724 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20080809 Year of fee payment: 6 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090809 Year of fee payment: 7 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090809 Year of fee payment: 7 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100809 Year of fee payment: 8 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100809 Year of fee payment: 8 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110809 Year of fee payment: 9 |
|
| LAPS | Cancellation because of no payment of annual fees |