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JP3341531B2 - Rocker arm made of high-strength Fe-base cast alloy - Google Patents
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JP3341531B2 - Rocker arm made of high-strength Fe-base cast alloy - Google Patents

Rocker arm made of high-strength Fe-base cast alloy

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Publication number
JP3341531B2
JP3341531B2 JP11917695A JP11917695A JP3341531B2 JP 3341531 B2 JP3341531 B2 JP 3341531B2 JP 11917695 A JP11917695 A JP 11917695A JP 11917695 A JP11917695 A JP 11917695A JP 3341531 B2 JP3341531 B2 JP 3341531B2
Authority
JP
Japan
Prior art keywords
rocker arm
cast alloy
strength
carbonitride
arm made
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP11917695A
Other languages
Japanese (ja)
Other versions
JPH08291358A (en
Inventor
三郎 脇田
善郎 中畠
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Materials Corp
Original Assignee
Mitsubishi Materials Corp
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Filing date
Publication date
Application filed by Mitsubishi Materials Corp filed Critical Mitsubishi Materials Corp
Priority to JP11917695A priority Critical patent/JP3341531B2/en
Publication of JPH08291358A publication Critical patent/JPH08291358A/en
Application granted granted Critical
Publication of JP3341531B2 publication Critical patent/JP3341531B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】この発明は、高強度を有するFe
基鋳造合金製ロッカーアームに関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention
The present invention relates to a rocker arm made of a base cast alloy.

【0002】[0002]

【従来の技術】従来、内燃機関の構造部材であるロッカ
ーアームには、強度、靭性、および耐摩耗性が要求され
ることから、これらの特性を具備したFe基鋳造合金が
用いられている。また、これらの特性を具備したFe基
鋳造合金製ロッカーアームとして、例えば特開昭64−
11941号公報に記載される通り、重量%(質量%)
で[以下、%は重量%(質量%)を示す]、 C:2〜4%、 Cr:10〜25%、 Mo:1〜10%、 Si:0.1〜2%、 Mn:0.1〜2%、 Co:0.1〜2%、 W:0.1〜2%、 Ni:0.1〜3%、 を含有し、残りがFeと不可避不純物からなる組成を有
するFe基鋳造合金で構成されたロッカーアームが知ら
れている。
2. Description of the Related Art Conventionally, since a rocker arm, which is a structural member of an internal combustion engine, is required to have strength, toughness, and wear resistance, an Fe-based cast alloy having these characteristics has been used. Further, as a rocker arm made of an Fe-based cast alloy having these characteristics, for example, Japanese Patent Application Laid-Open No.
As described in JP 11941, weight% (% by mass)
[Hereinafter,% indicates weight% (mass%)], C: 2 to 4%, Cr: 10 to 25%, Mo: 1 to 10%, Si: 0.1 to 2%, Mn: 0.1 to 2%. Fe-based casting containing 1 to 2%, Co: 0.1 to 2%, W: 0.1 to 2%, Ni: 0.1 to 3%, with the balance being Fe and inevitable impurities. Rocker arms made of an alloy are known.

【0003】[0003]

【発明が解決しようとする課題】一方、近年の内燃機関
の高出力化および軽量に伴ない、ロッカーアームにも小
型化および薄肉化が要求されるようになっているが、上
記の従来Fe基鋳造合金製ロッカーアームはじめ、その
他多くのロッカーアームの場合、いずれもすぐれた靭性
と耐摩耗性を有するものの、十分な強度を具備するもの
でないため、これらの要求に満足に対応することができ
ない。
On the other hand, with the recent increase in output and weight of the internal combustion engine, the rocker arm has also been required to be smaller and thinner. Many rocker arms, such as a rocker arm made of a cast alloy, have excellent toughness and wear resistance, but do not have sufficient strength, and thus cannot satisfy these requirements satisfactorily.

【0004】[0004]

【課題を解決するための手段】そこで、本発明者等は、
特に上記の従来Fe基鋳造合金製ロッカーアームに着目
し、これの強度向上をはかるべく研究を行なった結果、
上記の従来Fe基鋳造合金製ロッカーアームを構成する
Fe基鋳造合金は、図2に金属顕微鏡による組織写真
(倍率:500倍)の模写図で例示されるように、鋳造
時に晶出した相対的に塊状の共晶炭化物と、焼入れおよ
び焼戻しの熱処理で針状に析出した析出炭化物がマルテ
ンサイト素地に分散分布した組織をもつが、このFe基
鋳造合金に合金成分としてN成分およびB成分を含有さ
せると、このN成分およびB成分は共晶炭窒硼化物およ
び析出炭窒硼化物として晶出および析出し、これらの共
晶炭窒硼化物および析出炭窒硼化物の長手方向の長さは
50μm以下と微細であり、これによって強度が著しく
向上するようになるという研究結果を得たのである。
Means for Solving the Problems Accordingly, the present inventors have
In particular, focusing on the rocker arm made of the conventional Fe-based cast alloy described above, as a result of conducting research to improve the strength thereof,
As shown in FIG. 2, the Fe-based cast alloy constituting the rocker arm made of the conventional Fe-based cast alloy has a relative crystallized during casting, as exemplified by a micrograph of a structure photograph (magnification: 500 times) obtained by a metallurgical microscope. It has a structure in which massive eutectic carbides and needle-like precipitated carbides formed by heat treatment of quenching and tempering are dispersed and distributed in a martensitic matrix. The Fe-base cast alloy contains N and B components as alloy components. Then, the N component and the B component are crystallized and precipitated as a eutectic carbonitride and a precipitated carbonitride, and the longitudinal length of the eutectic carbonitride and the precipitated carbonitride is Research results have shown that the fineness is as small as 50 μm or less, which significantly improves the strength.

【0005】この発明は、上記の研究結果にもとづいて
なされたものであって、 C:2〜4%、 Si:0.1〜2%、 Mn:0.1〜2%、 Cr:10〜25%、 Moおよび/またはW:0.1〜10%、 N:0.01〜1%、 B:0.001〜0.1%、 を含有し、さらに必要に応じて、 Niおよび/またはCo:0.1〜5%、 を含有し、残りがFeと不可避不純物からなる組成、並
びにマルテンサイト素地に、いずれも長手方向の長さが
50μm以下の共晶炭窒硼化物と析出炭窒硼化物が分散
分布した組織を有するFe基鋳造合金で構成してなる、
高強度を有し、かつ靭性および耐摩耗性にもすぐれたF
e基鋳造合金製ロッカーアームに特徴を有するものであ
る。
[0005] The present invention has been made based on the above research results, C: 2 to 4%, Si: 0.1 to 2%, Mn: 0.1 to 2%, Cr: 10 to 10% 25%, Mo and / or W: 0.1 to 10%, N: 0.01 to 1%, B: 0.001 to 0.1%, and if necessary, Ni and / or Co: 0.1 to 5%, with the balance consisting of Fe and unavoidable impurities, and a martensitic matrix having a eutectic carbonitride and a precipitated carbonitride having a longitudinal length of 50 μm or less. It is composed of an Fe-based casting alloy having a structure in which boride is dispersed and distributed,
F with high strength and excellent toughness and wear resistance
It is characterized by a rocker arm made of e-base cast alloy.

【0006】つぎに、この発明のロッカーアームにおい
て、これを構成するFe基鋳造合金の成分組成を上記の
通りに限定した理由を説明する。 (a) C C成分には、一部が素地のマルテンサイトを形成して強
度を向上させるほか、残りが強度低下の原因になる針状
の析出炭化物を形成することなく、長手方向の長さでい
ずれも50μm以下、望ましくは30μm以下の析出炭
窒硼化物および共晶炭窒硼化物を形成して、前記マルテ
ンサイト素地によってもたらされる高強度を低下させる
ことなく、耐摩耗性を向上させる作用があるが、その含
有量が2%未満では前記作用に所望の効果が得られず、
一方その含有量が4%を越えると靭性が低下するように
なることから、その含有量を2〜4%、望ましくは3〜
3.6%と定めた。
Next, the reason why the component composition of the Fe-based cast alloy constituting the rocker arm of the present invention is limited as described above will be described. (A) C In addition to improving the strength by partially forming the base martensite, the C component has a length in the longitudinal direction without forming needle-like precipitated carbides that cause a decrease in strength. In any case, the effect of forming a precipitated carbonitride and a eutectic carbonitride of 50 μm or less, desirably 30 μm or less, and improving wear resistance without lowering the high strength provided by the martensite matrix. However, if the content is less than 2%, the desired effect cannot be obtained in the above-mentioned action,
On the other hand, if the content exceeds 4%, the toughness decreases, so the content is 2 to 4%, preferably 3 to 4%.
It was determined to be 3.6%.

【0007】(b) Si Si成分には、脱酸作用のほか、溶湯の流動性を増大さ
せて鋳造性を向上させる作用があるが、その含有量が
0.1%未満では前記作用に所望の効果が得られず、一
方その含有量が2%を越えると靭性が低下するようにな
ることから、その含有量を0.1〜2%、望ましくは
0.5〜1.5%と定めた。
(B) Si In addition to the deoxidizing action, the Si component has the action of increasing the fluidity of the molten metal and improving the castability. If the content is less than 0.1%, the Si component is not desirable. Is not obtained, while if the content exceeds 2%, the toughness decreases. Therefore, the content is set to 0.1 to 2%, preferably 0.5 to 1.5%. Was.

【0008】(c) Mn Mn成分には、脱酸作用のほか、素地に固溶して靭性を
向上させる作用があるが、その含有量が0.1%未満で
は前記作用に所望の効果が得られず、一方その含有量が
2%を越えると耐摩耗性が低下するようになることか
ら、その含有量を0.1〜2%、望ましくは0.4〜
1.1%と定めた。
(C) Mn The Mn component has an effect of improving the toughness by forming a solid solution in the base material in addition to a deoxidizing effect. On the other hand, if the content exceeds 2%, the abrasion resistance decreases, so the content is 0.1 to 2%, preferably 0.4 to 2%.
It was determined to be 1.1%.

【0009】(d) Cr Cr成分には、MoおよびW、さらにNおよびB成分と
ともに炭窒硼化物を形成して耐摩耗性を向上させる作用
があるが、その含有量が10%未満では前記作用に所望
の効果が得られず、一方その含有量が25%を越えると
靭性が低下するようになることから、その含有量を10
〜25%、望ましくは15〜20%と定めた。
(D) Cr The Cr component has an effect of forming a carbonitride with Mo and W, and also N and B components to improve wear resistance. If the desired effect is not obtained, the toughness will be reduced if the content exceeds 25%.
-25%, preferably 15-20%.

【0010】(e) MoおよびW これらの成分には、上記の通り共晶炭窒硼化物および析
出炭窒硼化物を形成して、耐摩耗性を向上させるほか、
素地に固溶して強度を向上させる作用があるが、その含
有量が0.1%未満では前記作用に所望の効果が得られ
ず、一方その含有量が10%を越えると靭性が低下する
ようになることから、その含有量を0.1〜10%、望
ましくは1〜5%と定めた。
(E) Mo and W These components form a eutectic carbonitride and a precipitated carbonitride as described above to improve wear resistance.
There is an effect of improving the strength by forming a solid solution in the base material, but if the content is less than 0.1%, the desired effect cannot be obtained, whereas if the content exceeds 10%, the toughness is reduced. Therefore, the content was determined to be 0.1 to 10%, preferably 1 to 5%.

【0011】(f) N N成分には、上記の通り、B成分と共に長手方向の長さ
で50μm以下、望ましくは30μm以下の共晶炭窒硼
化物および析出炭窒硼化物を形成してマルテンサイト素
地によってもたらされる高強度を損なうことなく耐摩耗
性を向上させる作用があるが、その含有量がN:0.0
1%未満では、特に析出炭窒硼化物あるいは析出炭窒硼
化物の長手方向の長さが50μmを越えて成長するよう
になって、所望の高強度を確保することができなくな
り、一方その含有量が1%を越えると靭性が低下するよ
うになることから、その含有量を0.01〜1%、望ま
しくは0.2〜0.6%と定めた。
(F) NN As described above, the NN component forms a eutectic carbonitride and a precipitated carbonitride having a longitudinal length of 50 μm or less, preferably 30 μm or less together with the component B to form a martensite. It has the effect of improving the wear resistance without impairing the high strength provided by the site substrate, but its content is N: 0.0
If it is less than 1%, in particular, the length of the precipitated carbonitride or the carbonitride exceeds the length of 50 μm, and the desired high strength cannot be secured. If the amount exceeds 1%, the toughness will decrease. Therefore, the content is set to 0.01 to 1%, preferably 0.2 to 0.6%.

【0012】(g) B B成分には、上記の通り、N成分と共に共晶炭窒硼化物
および析出炭窒硼化物を形成して、耐摩耗性を向上さ
せ、かつ結晶粒を微細化して強度を向上させる作用があ
るが、その含有量が0.001%未満では前記作用に所
望の効果が得られず、一方その含有量が0.1%を越え
ると靭性が低下するようになることから、その含有量を
0.001〜0.1%、望ましくは0.01〜0.08
%と定めた。
(G) BB In the B component, as described above, a eutectic carbonitride and a precipitated carbonitride are formed together with the N component to improve wear resistance and to refine crystal grains. It has the effect of improving the strength, but if its content is less than 0.001%, the desired effect cannot be obtained, whereas if its content exceeds 0.1%, the toughness will decrease. From 0.001 to 0.1%, preferably 0.01 to 0.08
%.

【0013】(h) NiおよびCo これらの成分には、素地に固溶してマルテンサイト変態
を促進させ、もって強度を一段と向上させる作用がある
ので、必要に応じて含有されるが、その含有量が0.1
%未満では前記作用に所望の向上効果が得られず、一方
その含有量が5%を越えてもより一層の強度向上効果は
得られず、経済性を考慮して、その含有量を0.1〜5
%、望ましくは1〜3%と定めた。
(H) Ni and Co Since these components have a function of dissolving in the base material to promote martensitic transformation and thereby further improving the strength, they are contained as necessary. Quantity is 0.1
If the content is less than 5%, the desired effect of improving the effect cannot be obtained. On the other hand, if the content exceeds 5%, no further effect of improving the strength can be obtained. 1-5
%, Preferably 1-3%.

【0014】なお、この発明のロッカーアームを構成す
るFe基鋳造合金における共晶および析出炭窒硼化物の
長手方向の長さは、上記の通り基本的にはN成分の含有
量によって調整されるが、その長さが50μmを越える
と強度が急激に低下し、所望の高強度を確保することが
できないことから、その長手方向の長さを50μm以
下、望ましくは30μm以下に定めたのである。
The longitudinal length of the eutectic and precipitated carbonitride in the Fe-base cast alloy constituting the rocker arm of the present invention is basically adjusted by the content of the N component as described above. However, if the length exceeds 50 μm, the strength sharply decreases and a desired high strength cannot be ensured. Therefore, the length in the longitudinal direction is set to 50 μm or less, preferably 30 μm or less.

【0015】[0015]

【実施例】つぎに、この発明のFe基鋳造合金製ロッカ
ーアームを実施例により具体的に説明する。通常の高周
波溶解炉を用い、それぞれ表1に示される成分組成をも
ったFe基合金溶湯を調製し、ロストワックス鋳型に鋳
造し、放冷した後、大気中、900℃に1時間保持後油
焼入れと、同じく大気中、600℃に0.5時間保持後
放冷の焼戻しの熱処理を施すことにより図3(a)に正
面図で、同(b)に底面図で示される形状を有し、かつ
長さが45mmの寸法をもった本発明Fe基鋳造合金製ロ
ッカーアーム(以下、本発明ロッカーアームという)1
〜7および従来Fe基鋳造合金製ロッカーアーム(以
下、従来ロッカーアムという)1〜13をそれぞれ製造
した。
Next, a rocker arm made of an Fe-based cast alloy according to the present invention will be described in detail with reference to examples. Using a conventional high-frequency melting furnace, a Fe-base alloy melt having the component composition shown in Table 1 was prepared, cast into a lost wax mold, allowed to cool, and then held at 900 ° C. in the atmosphere for 1 hour, followed by oiling. 3A is a front view, and FIG. 3B is a bottom view. And a rocker arm made of an Fe-based cast alloy of the present invention having a length of 45 mm (hereinafter referred to as the rocker arm of the present invention) 1
To 7 and conventional rocker arms made of a Fe-based cast alloy (hereinafter referred to as conventional rocker arms) 1 to 13, respectively.

【0016】ついで、これらのロッカーアームについ
て、図4に概略説明図で示される通り、ロッカーアーム
の底面先端部に形成された凹みにC型固定工具の曲げ先
端部を装着して図示の状態とし、ロッカーアームの底面
他方端部に上方から23kgf /sec の速度で荷重をか
け、ロッカーアーム破断時の荷重(破壊荷重)を測定す
る静的破壊試験を行ない、この測定結果にて強度を評価
した。これらの結果を表2に示した。また、これらのロ
ッカーアームについて、シャルピー衝撃値およびロック
ウェル硬さ(Cスケール)を測定し、靭性と耐摩耗性を
評価した。これらの測定結果も表2に示した。
Next, as shown in the schematic explanatory view of FIG. 4, these rocker arms are fitted with a bent tip portion of a C-shaped fixing tool in a recess formed at the tip end of the bottom surface of the rocker arm, as shown in FIG. 4. A load was applied to the other end of the bottom surface of the rocker arm from above at a speed of 23 kgf / sec, and a static destruction test was performed to measure the load (breaking load) when the rocker arm was broken, and the strength was evaluated based on the measurement results. . Table 2 shows the results. Further, for these rocker arms, Charpy impact value and Rockwell hardness (C scale) were measured to evaluate toughness and wear resistance. The results of these measurements are also shown in Table 2.

【0017】[0017]

【表1】 [Table 1]

【0018】[0018]

【表2】 [Table 2]

【0019】[0019]

【発明の効果】表1,2に示される結果から、本発明ロ
ッカーアーム1〜7は、従来ロッカーアーム1〜13と
同等のすぐれた靭性(シャルピー衝撃値)と耐摩耗性を
有し、かつこれより一段と高い強度をもつことが明らか
である。上述のように、この発明のFe基鋳造合金製ロ
ッカーアームは、高強度を有し、さらに靭性および耐摩
耗性にもすぐれているので、これの小型化および薄肉化
に十分満足に対応することができるものである。
From the results shown in Tables 1 and 2, the rocker arms 1 to 7 of the present invention have excellent toughness (Charpy impact value) and wear resistance equivalent to those of the conventional rocker arms 1 to 13, and It is clear that it has a higher strength than this. As described above, the rocker arm made of an Fe-based cast alloy according to the present invention has high strength, and is also excellent in toughness and wear resistance. Can be done.

【図面の簡単な説明】[Brief description of the drawings]

【図1】従来Fe基鋳造合金製ロッカーアームを構成す
るFe基鋳造合金の代表的組織を示す組織模写図であ
る。
FIG. 1 is a schematic structural view showing a typical structure of an Fe-based cast alloy constituting a rocker arm made of a conventional Fe-based cast alloy.

【図2】ロッカーアームの正面図(a)および底面図
(b)である。
FIG. 2 is a front view (a) and a bottom view (b) of a rocker arm.

【図3】ロッカーアームの静的破壊試験の概略説明図で
ある。
FIG. 3 is a schematic explanatory diagram of a rocker arm static breakdown test.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI F01L 1/18 F01L 1/18 M (56)参考文献 特開 昭48−19421(JP,A) 特開 平6−200354(JP,A) 特開 平5−279809(JP,A) 特開 昭59−211553(JP,A) 特開 昭63−290243(JP,A) 特開 平6−220573(JP,A) 特開 平2−64210(JP,A) 特開 昭63−303030(JP,A) 特開 平2−149638(JP,A) 特開 昭60−234947(JP,A) (58)調査した分野(Int.Cl.7,DB名) C22C 37/08 C22C 37/00 C22C 38/00 302 C22C 38/38 C22C 38/58 F01L 1/18 ──────────────────────────────────────────────────続 き Continuation of the front page (51) Int.Cl. 7 Identification code FI F01L 1/18 F01L 1/18 M (56) References JP-A-48-19421 (JP, A) JP-A-6-200354 ( JP, A) JP-A-5-279809 (JP, A) JP-A-59-211553 (JP, A) JP-A-63-290243 (JP, A) JP-A-6-220573 (JP, A) JP JP-A-2-64210 (JP, A) JP-A-63-303030 (JP, A) JP-A-2-149638 (JP, A) JP-A-60-234947 (JP, A) (58) Fields investigated (Int) .Cl. 7 , DB name) C22C 37/08 C22C 37/00 C22C 38/00 302 C22C 38/38 C22C 38/58 F01L 1/18

Claims (2)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 重量%(質量%)で、 C:2〜4%、 Si:0.1〜2%、 Mn:0.1〜2%、 Cr:10〜25%、 Moおよび/またはW:0.1〜10%、 N:0.01〜1%、 を含有し、さらに、 B:0.001〜0.1%、 を含有し、残りがFeと不可避不純物からなる組成、並
びにマルテンサイト素地に、いずれも長手方向の長さが
50μm以下の共晶炭窒硼化物と析出炭窒硼化物が分散
分布した組織を有するFe基鋳造合金で構成したことを
特徴とする高強度Fe基鋳造合金製ロッカーアーム。
1. wt% (mass%): C: 2 to 4%, Si: 0.1 to 2%, Mn: 0.1 to 2%, Cr: 10 to 25%, Mo and / or W : 0.1 to 10%, N: 0.01 to 1%, B: 0.001 to 0.1%, the balance being Fe and inevitable impurities, and martens A high-strength Fe-base alloy comprising a Fe-base cast alloy having a structure in which a eutectic carbonitride having a longitudinal length of 50 μm or less and a precipitated carbonitride are distributed and distributed on the site substrate. Rocker arm made of cast alloy.
【請求項2】 重量%で、 C:2〜4%、 Si:0.1〜2%、 Mn:0.1〜2%、 Cr:10〜25%、 Moおよび/またはW:0.1〜10%、 N:0.01〜1%、 を含有し、さらに、 B:0.001〜0.1%、 Niおよび/またはCo:0.1〜5%、 を含有し、残りがFeと不可避不純物からなる組成、並
びにマルテンサイト素地に、いずれも長手方向の長さが
50μm以下の共晶炭窒硼化物と析出炭窒硼化物が分散
分布した組織を有するFe基鋳造合金で構成したことを
特徴とする高強度Fe基鋳造合金製ロッカーアーム。
2.% by weight: C: 2 to 4%, Si: 0.1 to 2%, Mn: 0.1 to 2%, Cr: 10 to 25%, Mo and / or W: 0.1 -10%, N: 0.01-1%, B: 0.001-0.1%, Ni and / or Co: 0.1-5%, the balance being Fe And an Fe-based cast alloy having a structure in which a eutectic carbonitride having a longitudinal length of 50 μm or less and a precipitated carbonitride were dispersed and distributed on a martensite base and a martensite base. A rocker arm made of a high-strength Fe-based cast alloy, characterized in that:
JP11917695A 1995-04-20 1995-04-20 Rocker arm made of high-strength Fe-base cast alloy Expired - Fee Related JP3341531B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11917695A JP3341531B2 (en) 1995-04-20 1995-04-20 Rocker arm made of high-strength Fe-base cast alloy

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11917695A JP3341531B2 (en) 1995-04-20 1995-04-20 Rocker arm made of high-strength Fe-base cast alloy

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JPH08291358A JPH08291358A (en) 1996-11-05
JP3341531B2 true JP3341531B2 (en) 2002-11-05

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4482407B2 (en) * 2004-09-06 2010-06-16 株式会社神戸製鋼所 High Cr cast iron products with excellent heat crack resistance and heat treatment method for high Cr cast iron materials
JP5753365B2 (en) * 2010-10-29 2015-07-22 株式会社アーステクニカ High chrome cast iron
CN103757523A (en) * 2013-12-13 2014-04-30 芜湖金鹰机械科技开发有限公司 Boron-containing high-chromium casting ball material and preparation method thereof

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