JP3377503B2 - Glass melting furnace for high level radioactive liquid waste - Google Patents
Glass melting furnace for high level radioactive liquid wasteInfo
- Publication number
- JP3377503B2 JP3377503B2 JP2000197889A JP2000197889A JP3377503B2 JP 3377503 B2 JP3377503 B2 JP 3377503B2 JP 2000197889 A JP2000197889 A JP 2000197889A JP 2000197889 A JP2000197889 A JP 2000197889A JP 3377503 B2 JP3377503 B2 JP 3377503B2
- Authority
- JP
- Japan
- Prior art keywords
- furnace
- hole
- bottom electrode
- brick
- glass melting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
- C03B5/16—Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
- C03B5/20—Bridges, shoes, throats, or other devices for withholding dirt, foam, or batch
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
- C03B5/16—Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
- C03B5/26—Outlets, e.g. drains, siphons; Overflows, e.g. for supplying the float tank, tweels
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Melting And Manufacturing (AREA)
Description
【発明の詳細な説明】
【0001】
【発明の属する技術分野】本発明は、高レベル放射性廃
液をガラス固化する際に用いられるガラス溶融炉に関す
るものである。
【0002】
【従来の技術】使用済み核燃料の再処理後に生ずる高レ
ベル放射性廃液は、極めて高い放射線と崩壊熱を有して
おり、液体のままでは処分が困難であることから、図3
及び図4に示すような構造をしたガラス溶融炉1内に送
られ、ここでほう珪酸ガラス等のガラス原料と共に高温
で溶かし合わされながらキャニスタcと称される耐食性
のステンレス容器内に詰め込まれてガラス固化体として
安定化された後、一定期間自然冷却されてから地中深く
地層処分することが計画されている。
【0003】図示するように、このガラス溶融炉1は、
炉本体2の内底部を漏斗状(四角錐状)に窄めると共に
その最下端部に炉2内の溶融ガラスを流下する流下孔3
を有する底部電極4を備え、さらにその内部に一対の主
電極5,5と補助電極6,6とを備えた構造となってい
る。
【0004】そして、この炉本体2の天井壁に設けられ
た投入口7から高レベル放射性廃液とガラス原料を投入
した後、先ず、主電極5,5間に電流を流すことでその
表層部付近の高レベル放射性廃液とガラス原料とを十分
に溶かし合わせ、次に、その下部に位置する補助電極
6,6間に電気を流してその下層部の高レベル放射性廃
液とガラス原料とを溶かし合わせ、最後に、底部電極4
と主電極5,5間に電気を流して全体を溶融した後、そ
の流下孔3から延びる流下ノズル8をその周囲の電熱コ
イル9で加熱してその内部に詰まっている固化ガラスを
溶かして抜き出すことで炉2内の溶融ガラスをその下部
に位置しているキャニスタc内に流下させてその内部に
ガラス固化体として密閉収容するようになっている。
【0005】尚、この溶融炉1内で発生したガスはオフ
ガスとして排気口7aから排気され、図示しないHEP
Aフィルター等で放射性物質が完全に捕集除去されて無
害化された後、大気中に放出されるようになっている。
【0006】
【発明が解決しようとする課題】ところで、このガラス
溶融炉1を構成する炉本体2、特にその内壁はその性質
上耐熱性に優れた耐火煉瓦で形成されているが、繰り返
し加わる熱衝撃によってクラックが発生し、その一部が
煉瓦屑として脱落して図6に示すように流下孔3側に流
下してその流下孔3を閉塞することが考えられる。
【0007】そのため、図5に示すようにその流下孔d
の周囲はその壁面に沿って傾斜させるのではなく平坦部
に形成されており、この平坦部で煉瓦屑の落下をくい止
めることで煉瓦屑による流下孔3を閉塞を防止するよう
な構造となっている。
【0008】しかしながら、この流下孔3の周囲(底部
電極4頂部)を平坦部に形成すると、溶融過程において
高レベル放射性廃液中から析出したルテニウムやパラジ
ウム等といった比重の大きい金属スラッジ(金属酸化
物)が流出し難くなり、その平坦部上に堆積してその傾
斜面に沿って成長し、やがて補助電極6あるいは主電極
5まで到達して電流の短絡を招いてその機能を喪失して
しまうといった不都合が考えられる。
【0009】そこで、本発明はこのような課題を有効に
解決するために案出されたものであり、その目的は、金
属スラッジの流下を円滑にすると共に、煉瓦屑による閉
塞を未然に防止することができる新規な高レベル放射性
廃液のガラス溶融炉を提供するものである。
【0010】
【課題を解決するための手段】上記課題を解決するため
に本発明は、耐火煉瓦からなる炉本体の内底部を漏斗状
に窄めると共にその最下端部に底部電極を備え、その底
部電極の中央部に炉内の溶融ガラスを流下する流下孔を
備え、上記底部電極の上面をその流下孔を中心として漏
斗状に窄ませると共に、その底部電極の上部に上記耐火
煉瓦の煉瓦屑によるその流下孔の閉塞を防止すべく煉瓦
屑受けを備えた高レベル放射性廃液のガラス溶融炉にお
いて、上記煉瓦屑受けが、上記底部電極上に一定の間隔
を隔てて浮いた状態で支持され中央部に上記流下孔より
も径小の通過孔を有する筒状の屑受け本体と、上記通過
孔を上記流下孔上に略同軸上に位置させるように上記屑
受け本体を炉壁側から水平に支持する棒状の支持部材と
を備えたものである。
【0011】金属スラッジの流下を円滑に行うことがで
きると共に、煉瓦屑による流下孔の閉塞を確実に防止す
ることができる。
【0012】
【発明の実施の形態】次に、本発明を実施する好適一形
態を添付図面を参照しながら説明する。
【0013】図1は本発明に係るガラス溶融炉1の炉内
底部付近を示したものであり、図中2は炉本体、4はそ
の炉内底部に設けられた底部電極、3はこの底部電極4
の中央部に設けられた流下孔、10はこの底部電極4上
に設けられた煉瓦屑受けである。
【0014】図示するように、この底部電極4は、その
上面4aが流下孔3を中心として漏斗状に窪んでおり、
炉本体2の傾斜面(炉壁面)2aとそれぞれ連続した面
一の構造となっている。
【0015】一方、煉瓦屑受け10は、耐熱性の非金属
材料、例えばセラミック等から形成されており、中央部
に通過孔11を有する円筒状の屑受け本体12と、この
屑受け本体12の側面から放射状に広がる複数本(本実
施の形態にあっては4本)の支持部材13,13,1
3,13とから形成されている。
【0016】そして、この支持部材13,13,13,
13の先端部は、それぞれ炉本体2の傾斜面(炉壁面)
2a側に接することで円筒状の屑受け本体12が底部電
極4上に一定の間隔を隔てて浮いた状態で支持されると
共に、その通過孔11が底部電極4側の流下孔3上に略
同軸上に位置した状態となっている。
【0017】また、この屑受け本体12側の通過孔11
の孔径A1及び屑受け本体12と炉本体2の傾斜面(炉
壁面)2aとの隙間A2は、底部電極4側の流下孔3の
孔径Bよりも小さくなっており、これらを通過した煉瓦
屑は、その殆どが流下孔3を通過して流下されるように
なっている。
【0018】従って、このような構造をした本発明のガ
ラス溶融炉1にあっては、底部電極4の上面が炉本体2
の傾斜面(炉壁面)2aとそれぞれ連続するように漏斗
状に窪んだ構造となっているため、溶融時に発生した金
属スラッジが炉本体2の傾斜面(炉壁面)2aに沿って
流下孔3側にスムーズに流れ落ちるようになる。このた
め、従来構造のように炉底部(底部電極4上)に金属ス
ラッジが溜まることがなくなり、短絡などの不都合を確
実に回避することができる。
【0019】また、この底部電極4上に煉瓦屑受け10
を設けたことから、仮に流下孔3を閉塞するような大き
な煉瓦屑が脱落してきても、これが煉瓦屑受け5で捕捉
されて流下孔3まで達することがなくなるため、煉瓦屑
による流下孔3の閉塞といった不都合も確実に防止する
ことができる。
【0020】尚、炉本体2内に送り込まれる高レベル放
射性廃液は予め濾過処理等されてその固形物が除去され
ているため、この流下孔3を閉塞する固形物は、その殆
どが炉内で発生する煉瓦屑であるため、煉瓦屑以外の固
形物を考慮する必要性は乏しい。
【0021】
【発明の効果】以上要するに本発明によれば、金属スラ
ッジの流下を円滑に行うことができると共に、流下孔の
閉塞を招く煉瓦屑を未然に捕捉することができる。この
結果、金属スラッジによる短絡と煉瓦屑による流下孔の
閉塞を確実に回避することができるため、ガラス溶融処
理工程における安定性及び信頼性が大幅に向上する等と
いった優れた効果を発揮することができる。Description: BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a glass melting furnace used for vitrifying high-level radioactive liquid waste. [0002] High-level radioactive liquid waste generated after reprocessing of spent nuclear fuel has extremely high radiation and decay heat, and is difficult to dispose of as a liquid.
4 is fed into a glass melting furnace 1 having a structure as shown in FIG. 4, where it is packed with a glass material such as borosilicate glass in a corrosion-resistant stainless steel container called a canister c while being melted at a high temperature. It is planned that after being stabilized as a solid, it will be naturally cooled for a certain period of time and then disposed of deep underground. As shown in the figure, this glass melting furnace 1
The inner bottom of the furnace main body 2 is narrowed in a funnel shape (square pyramid shape), and a flow-down hole 3 for flowing molten glass in the furnace 2 at its lowermost end.
And a pair of main electrodes 5 and 5 and auxiliary electrodes 6 and 6 provided therein. After the high-level radioactive liquid waste and the glass raw material are introduced from an inlet 7 provided on the ceiling wall of the furnace main body 2, first, an electric current is applied between the main electrodes 5 and 5 so that the vicinity of the surface layer is obtained. Fully dissolve the high-level radioactive liquid waste and the glass raw material, and then apply electricity between the auxiliary electrodes 6 and 6 located therebelow to melt the high-level radioactive liquid waste and the glass raw material in the lower layer thereof, Finally, the bottom electrode 4
Then, electricity is passed between the main electrodes 5 and 5 to melt the whole, and then the downflow nozzle 8 extending from the downflow hole 3 is heated by the surrounding electric heating coil 9 to melt and extract the solidified glass clogged therein. As a result, the molten glass in the furnace 2 is caused to flow down into the canister c located below the furnace 2 and is hermetically contained therein as a vitrified body. [0005] The gas generated in the melting furnace 1 is exhausted as an off-gas from an exhaust port 7a.
The radioactive material is completely collected and removed by an A filter or the like, rendered harmless, and then released into the atmosphere. The furnace body 2 of the glass melting furnace 1, particularly the inner wall thereof, is made of a refractory brick which is excellent in heat resistance in nature. It is conceivable that a crack is generated by the impact and a part of the crack falls off as brick waste and flows down to the downflow hole 3 side as shown in FIG. For this reason, as shown in FIG.
Is formed not in a slope along the wall surface but in a flat portion. The flat portion has a structure in which the falling down of the brick dust is prevented by blocking the fall of the brick dust. I have. However, when the periphery of the flow-down hole 3 (the top of the bottom electrode 4) is formed as a flat portion, a metal sludge (metal oxide) having a high specific gravity such as ruthenium or palladium deposited from a high-level radioactive waste liquid in a melting process. Is difficult to flow out, accumulates on the flat portion, grows along the inclined surface, and eventually reaches the auxiliary electrode 6 or the main electrode 5 to cause a short-circuit of current and lose its function. Can be considered. Accordingly, the present invention has been devised to effectively solve such a problem, and has as its object to smooth the flow of metal sludge and to prevent blockage by brick debris. To provide a novel high-level radioactive liquid waste glass melting furnace. [0010] In order to solve the above-mentioned problems, the present invention provides a furnace body made of a refractory brick, which has a funnel-shaped inner bottom and a bottom electrode at the lowermost end thereof. the falling hole flowing down the molten glass in the furnace to the central portion <br/> Bei example of the bottom electrode, causes deflate the funnel-shaped upper surface of the bottom electrode about its falling hole, the top of the bottom electrode Contact in the glass melting furnace of high-level radioactive liquid waste having a brick scrap receiving in order to prevent blockage of the flow-down hole by brick scraps of the refractory bricks
The brick debris receiver is spaced at a certain distance above the bottom electrode.
Is supported in a floating state with a gap from the downflow hole at the center.
A cylindrical waste receiving body having a small diameter passage hole and
The waste is positioned so that the hole is positioned substantially coaxially on the downflow hole.
A rod-shaped support member for horizontally supporting the receiving main body from the furnace wall side . [0011] it is possible to smoothly flow down the metals sludge, it is possible to reliably prevent clogging of falling hole by practitioners Kawarakuzu. Next, a preferred embodiment of the present invention will be described with reference to the accompanying drawings. FIG. 1 shows the vicinity of the furnace bottom of a glass melting furnace 1 according to the present invention. In the figure, reference numeral 2 denotes a furnace body, 4 denotes a bottom electrode provided on the furnace bottom, and 3 denotes this bottom. Electrode 4
A downflow hole 10 provided at the center of is a brick waste receiver provided on the bottom electrode 4. As shown in the figure, the bottom electrode 4 has a top surface 4a which is depressed in a funnel shape around the downflow hole 3.
It has a flush structure continuous with the inclined surface (furnace wall surface) 2a of the furnace body 2. On the other hand, the brick waste receiver 10 is formed of a heat-resistant non-metallic material, for example, ceramic or the like, and has a cylindrical waste receiver main body 12 having a through hole 11 in the center portion. A plurality of (four in the present embodiment) support members 13, 13, 1 extending radially from the side surface
3 and 13. The support members 13, 13, 13,
13 are the inclined surfaces (furnace wall surfaces) of the furnace body 2 respectively.
Cylindrical offcut receiving body 12 by contact with the 2a side bottom collector
It is supported in a state of being floated on the pole 4 at a predetermined interval, and the passage hole 11 is located substantially coaxially on the flow-down hole 3 on the bottom electrode 4 side. Further, the passage hole 11 on the side of the dust receiving body 12 is provided.
And the gap A2 between the dust receiving body 12 and the inclined surface (furnace wall surface) 2a of the furnace body 2 are smaller than the hole diameter B of the flow-down hole 3 on the bottom electrode 4 side, and , Most of which flows down through the downflow hole 3. Therefore, in the glass melting furnace 1 of the present invention having such a structure, the upper surface of the bottom electrode 4 is
Is formed in a funnel shape so as to be continuous with the inclined surface (furnace wall surface) 2a of the furnace main body. Flows smoothly to the side. Therefore, the metal sludge does not accumulate on the furnace bottom (on the bottom electrode 4) as in the conventional structure, and inconveniences such as a short circuit can be reliably avoided. On the bottom electrode 4, a brick dust receiver 10 is provided.
Is provided, even if large brick debris that closes the flow-down hole 3 falls off, this is caught by the brick waste receiver 5 and does not reach the flow-down hole 3. Inconvenience such as blockage can also be reliably prevented. Since the high-level radioactive liquid fed into the furnace body 2 has been filtered in advance to remove its solids, most of the solids that block the flow-down hole 3 in the furnace. Since it is generated brick waste, there is little need to consider solid matter other than brick waste. According to the above summary the present invention, it is possible to capture it is possible to perform the stream of metallic sludge smoothly, the brick scrap lead to blockage of the flow under the hole in advance. As a result, short-circuiting due to metal sludge and blockage of the flow-down hole due to brick debris can be reliably avoided. it can.
【図面の簡単な説明】
【図1】本発明に係るガラス溶融炉の底部電極付近の実
施の一形態を示す断面図である。
【図2】本発明に係るガラス溶融炉の底部電極付近の実
施の一形態を示す平面図である。
【図3】従来のガラス溶融炉の構成を示す説明図であ
る。
【図4】図3中X−X線断面図である。
【図5】図3中Y部を示す部分拡大図である。
【図6】底部電極の上面を漏斗状にした状態を示す部分
拡大図である。
【符号の説明】
2 炉本体
3 流下孔
4 底部電極
10 煉瓦屑受け
11 通過孔
12 屑受け本体
13 支持部材BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a sectional view showing an embodiment in the vicinity of a bottom electrode of a glass melting furnace according to the present invention. FIG. 2 is a plan view showing one embodiment near the bottom electrode of the glass melting furnace according to the present invention. FIG. 3 is an explanatory view showing a configuration of a conventional glass melting furnace. FIG. 4 is a sectional view taken along line XX in FIG. 3; FIG. 5 is a partially enlarged view showing a Y part in FIG. 3; FIG. 6 is a partially enlarged view showing a state in which the upper surface of the bottom electrode is funnel-shaped. [Description of Signs] 2 Furnace main body 3 Flow-down hole 4 Bottom electrode 10 Brick waste receptacle 11 Passage hole 12 Waste receptacle body 13 Support member
───────────────────────────────────────────────────── フロントページの続き (72)発明者 浅野 直紀 茨城県那珂郡東海村大字村松4番地33 核燃料サイクル開発機構東海事業所内 (72)発明者 青澤 隆之 神奈川県横浜市磯子区新中原町1番地 石川島播磨重工業株式会社 横浜エンジ ニアリングセンター内 (56)参考文献 特開 平4−161898(JP,A) 特開2000−28790(JP,A) (58)調査した分野(Int.Cl.7,DB名) G21F 9/16 C03B 5/027 ──────────────────────────────────────────────────続 き Continuing from the front page (72) Inventor Naoki Asano 4-4, Muramatsu, Oji, Tokai-mura, Naka-gun, Ibaraki Prefecture Inside the Japan Nuclear Cycle Development Institute Tokai Works (72) Inventor Takayuki Aosawa 1 Shinnakaharacho, Isogo-ku, Yokohama-shi, Kanagawa Prefecture Ishikawajima Harima Heavy Industries, Ltd. Yokohama Engineering Center (56) References JP-A-4-161898 (JP, A) JP-A-2000-28790 (JP, A) (58) Fields investigated (Int. Cl. 7 , DB Name) G21F 9/16 C03B 5/027
Claims (1)
状に窄めると共にその最下端部に底部電極を備え、その
底部電極の中央部に炉内の溶融ガラスを流下する流下孔
を備え、上記底部電極の上面をその流下孔を中心として
漏斗状に窄ませると共に、その底部電極の上部に上記耐
火煉瓦の煉瓦屑によるその流下孔の閉塞を防止すべく煉
瓦屑受けを備えた高レベル放射性廃液のガラス溶融炉に
おいて、上記煉瓦屑受けが、上記底部電極上に一定の間
隔を隔てて浮いた状態で支持され中央部に上記流下孔よ
りも径小の通過孔を有する筒状の屑受け本体と、上記通
過孔を上記流下孔上に略同軸上に位置させるように上記
屑受け本体を炉壁側から水平に支持する棒状の支持部材
とを備えたことを特徴とする高レベル放射性廃液のガラ
ス溶融炉。(57) [Claims 1] A furnace body made of a refractory brick is narrowed in a funnel shape, and a bottom electrode is provided at the lowest end thereof, and a furnace electrode is provided at the center of the bottom electrode. of example Bei a falling hole flowing down the molten glass, causes deflate the funnel-shaped upper surface of the bottom electrode about its falling hole, obstruction of the flow-down hole on the top of the bottom electrode according to the brick dust of the refractory bricks the glass melting furnace of high-level radioactive liquid waste having a brick scrap receiving to prevent
In the above, the brick waste receiver is placed on the bottom electrode for a certain time.
It is supported in a floating state with a gap between it and the downflow hole at the center.
A cylindrical debris receiving body having a passage hole with a small diameter;
So that the overhole is located substantially coaxially on the downflow hole
A rod-shaped support member that horizontally supports the waste receiving body from the furnace wall side
And a glass melting furnace for high-level radioactive liquid waste.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000197889A JP3377503B2 (en) | 2000-06-27 | 2000-06-27 | Glass melting furnace for high level radioactive liquid waste |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000197889A JP3377503B2 (en) | 2000-06-27 | 2000-06-27 | Glass melting furnace for high level radioactive liquid waste |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2002014198A JP2002014198A (en) | 2002-01-18 |
| JP3377503B2 true JP3377503B2 (en) | 2003-02-17 |
Family
ID=18696152
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000197889A Expired - Fee Related JP3377503B2 (en) | 2000-06-27 | 2000-06-27 | Glass melting furnace for high level radioactive liquid waste |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3377503B2 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4529302B2 (en) * | 2001-03-08 | 2010-08-25 | 株式会社Ihi | Bottom electrode of glass melting furnace |
| JP3848302B2 (en) * | 2003-06-04 | 2006-11-22 | 核燃料サイクル開発機構 | Glass melting furnace and operating method thereof |
| CN112194343B (en) * | 2020-10-12 | 2022-04-29 | 武汉理工大学 | A kind of unloading device for high temperature glass curing furnace |
| CN113185090B (en) * | 2021-04-16 | 2022-11-29 | 浙江荣星新材料科技有限公司 | Tail brick assembly for glass melting furnace and installation process thereof |
-
2000
- 2000-06-27 JP JP2000197889A patent/JP3377503B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JP2002014198A (en) | 2002-01-18 |
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