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JP3386909B2 - Manufacturing method of magnetic recording medium - Google Patents
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JP3386909B2 - Manufacturing method of magnetic recording medium - Google Patents

Manufacturing method of magnetic recording medium

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Publication number
JP3386909B2
JP3386909B2 JP33449594A JP33449594A JP3386909B2 JP 3386909 B2 JP3386909 B2 JP 3386909B2 JP 33449594 A JP33449594 A JP 33449594A JP 33449594 A JP33449594 A JP 33449594A JP 3386909 B2 JP3386909 B2 JP 3386909B2
Authority
JP
Japan
Prior art keywords
conductive
substrate
numbered
substrates
odd
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP33449594A
Other languages
Japanese (ja)
Other versions
JPH08171719A (en
Inventor
智雄 茂
保志 真壁
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical Corp
Original Assignee
Mitsubishi Chemical Corp
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Filing date
Publication date
Application filed by Mitsubishi Chemical Corp filed Critical Mitsubishi Chemical Corp
Priority to JP33449594A priority Critical patent/JP3386909B2/en
Publication of JPH08171719A publication Critical patent/JPH08171719A/en
Application granted granted Critical
Publication of JP3386909B2 publication Critical patent/JP3386909B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Manufacturing Of Magnetic Record Carriers (AREA)

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は磁気記録媒体の製造方法
に関する。詳しくは、本発明は、磁気記録媒体の非磁性
基板(導電性基板)の表面加工処理を行なうことで表面
特性を改善して、浮上特性、潤滑性、及び、耐摩耗性に
優れた磁気記録媒体を製造する方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method of manufacturing a magnetic recording medium. More specifically, the present invention improves the surface characteristics of a non-magnetic substrate (conductive substrate) of a magnetic recording medium by improving the surface characteristics of the magnetic recording medium, resulting in magnetic recording excellent in floating characteristics, lubricity and wear resistance. A method for manufacturing a medium.

【0002】[0002]

【従来の技術】近年、コンピュータ等の情報処理技術の
発達に伴い、その外部記憶装置として磁気ディスク等の
磁気記録媒体が用いられている。従来、磁気記録媒体と
しては、アルミニウム合金基板にアルマイト処理やNi
−Pメッキ等の非磁性メッキ処理を施した非磁性基板
に、Cr等の下地層を被覆し、次いで、Co系合金の磁性
薄膜層を被覆し、更に炭素質の保護膜を被覆したものが
使用されている。
2. Description of the Related Art In recent years, with the development of information processing technology for computers and the like, magnetic recording media such as magnetic disks have been used as external storage devices. Conventionally, as a magnetic recording medium, an aluminum alloy substrate is subjected to alumite treatment or Ni.
A non-magnetic substrate that has been subjected to a non-magnetic plating treatment such as P plating is coated with an underlayer of Cr or the like, then with a magnetic thin film layer of a Co-based alloy, and then with a carbonaceous protective film. It is used.

【0003】上記磁気記録媒体(以下、磁気ディスクと
呼ぶ)では、その高密度化に伴い磁気ディスクと磁気ヘ
ッドとの間隔、即ちヘッドの浮上量がますます小さくな
り、最近では0.15μm程度以下となっている。このよう
に小さな浮上量では、磁気ディスク面に突起が存在する
と、時にヘッドクラッシュを招いてディスク表面を傷つ
けるおそれがある。また、ヘッドクラッシュに至らない
微小な突起の存在であっても、情報の読み書きの際に種
々のエラーを引き起こす原因となり得る。
In the above magnetic recording medium (hereinafter referred to as a magnetic disk), the distance between the magnetic disk and the magnetic head, that is, the flying height of the head, has become smaller as the density of the magnetic recording medium has increased, and recently, it is about 0.15 μm or less. Has become. With such a small flying height, if there is a protrusion on the surface of the magnetic disk, there is a risk of causing head crash and damaging the disk surface. Moreover, even the presence of minute projections that do not cause head crash can cause various errors when reading and writing information.

【0004】一方、磁気ディスクは、その大容量化及び
高密度化と並行して小型化も進められており、スピンド
ル回転用の駆動モータも益々小型化されている。このた
め、駆動モータのトルクが不足する場合があり、磁気ヘ
ッドが磁気ディスク面に固着したまま浮上しないという
現象も生じやすい。上記のような磁気ヘッドのクラッシ
ュや固着を防止するために、従来から、磁気ディスク表
面をポリッシュ加工した後に、更にディスク表面に微細
な溝を形成する表面加工処理(以下、テクスチャ加工と
呼ぶ)が行なわれている。テクスチャ加工は、磁気ヘッ
ドと磁気ディスク表面との接触抵抗を小さくするのに特
に有効である。
On the other hand, the magnetic disk is being miniaturized in parallel with the increase in capacity and density, and the drive motor for rotating the spindle is becoming smaller and smaller. For this reason, the torque of the drive motor may be insufficient, and the phenomenon that the magnetic head does not fly while being fixed to the magnetic disk surface is likely to occur. In order to prevent the magnetic head from crashing or sticking as described above, conventionally, a surface processing treatment (hereinafter, referred to as texturing) of further forming fine grooves on the disk surface after polishing the magnetic disk surface has been performed. Has been done. Texture processing is particularly effective in reducing the contact resistance between the magnetic head and the magnetic disk surface.

【0005】[0005]

【発明が解決しようとする課題】上記の如く、テクスチ
ャ加工により、磁気ディスクにおけるヘッドの浮上特性
の改善が図られているものの、磁気ディスクに要請され
る性能には未だ充分に応えてはいない。ところで、特開
平4−95221号公報には、上記要請に応えるため
に、テクスチャ加工に引き続き、磁気ディスクの洗浄を
行ない、更にケミカルエッチングを施す表面処理技術が
提案されている。
As described above, although the flying characteristics of the head in the magnetic disk have been improved by the texture processing, the performance required for the magnetic disk has not yet been sufficiently met. By the way, in order to meet the above-mentioned demand, Japanese Unexamined Patent Publication (Kokai) No. 4-95221 proposes a surface treatment technique in which the magnetic disk is washed, and then chemical etching is further performed after the texturing.

【0006】しかし、ケミカルエッチングによる処理で
は、一般に、エッチング条件の選択によって表面状態を
精度よく制御することは困難であり、また、エッチング
後の表面が不均一になりやすいという問題がある。
However, in the chemical etching treatment, it is generally difficult to accurately control the surface condition by selecting the etching conditions, and the surface after etching tends to be non-uniform.

【0007】本発明者らは、磁気ディスクにおけるヘッ
ドの浮上特性を更に改善すべく鋭意検討した結果、基板
面にテクスチャ加工を施した後に、基板表面を電解液中
で電解処理することにより(第1の方法)、基板表面が
改善されることを見出し、これを特願平4−33166
5号において先に提案した。
As a result of intensive studies to further improve the flying characteristics of the head in a magnetic disk, the present inventors have found that after the substrate surface is textured, the substrate surface is electrolytically treated in an electrolytic solution ( 1 method), and found that the surface of the substrate is improved.
Proposed earlier in No. 5.

【0008】ところが、上記第1の方法で複数の基板を
同時に電解処理する際には、電解処理により生ずる基板
のエッチング量が各基板によって異なり、また、同じ基
板においても面内方向でエッチング量が異なるという問
題点が判明した。そこで、本発明者らは、更に、電解液
中で基板の両面に対向して対向電極(陰極板)を設け、
基板と対向電極との間に直流電圧を印加して電解処理を
行なうことにより(第2の方法)、かかる問題が解決で
きることを見出し、特願平6−14335号において提
案した。
However, when a plurality of substrates are simultaneously electrolytically treated by the above-mentioned first method, the etching amount of the substrate generated by the electrolytic treatment differs depending on each substrate, and even the same substrate has an etching amount in the in-plane direction. It turned out to be a different problem. Therefore, the present inventors have further provided counter electrodes (cathode plates) on the opposite sides of the substrate in the electrolytic solution,
It was found that this problem could be solved by applying a DC voltage between the substrate and the counter electrode to carry out electrolytic treatment (second method), and proposed it in Japanese Patent Application No. 6-14335.

【0009】しかし、上記第2の方法によると、製品の
品質向上は可能になるものの、同時に処理する基板の枚
数と同程度の枚数の対向電極を電解液中に配置する必要
がある。このため、この方法を工業的規模で実施する
と、電極のためのコストがかさみ、また、電極と基板と
が交互に配置されるので、多数の基板の電解処理に際し
てその処理効率が必ずしもよくないという事情があっ
た。
However, according to the second method, although the quality of the product can be improved, it is necessary to dispose as many counter electrodes in the electrolytic solution as the number of substrates to be processed at the same time. Therefore, if this method is carried out on an industrial scale, the cost for the electrodes is high, and since the electrodes and the substrates are alternately arranged, the treatment efficiency is not always good in the electrolytic treatment of a large number of substrates. There was a circumstance.

【0010】本発明は、上記に鑑み、磁気記録媒体の基
板のテクスチャ加工の後の処理について、良好な品質の
基板面を得ると共に、工業的規模で且つ低コストで実施
できる、磁気記録媒体の製造方法を提供することを目的
とする。
In view of the above, the present invention provides a magnetic recording medium which can be processed on an industrial scale and at low cost while obtaining a substrate surface of good quality for the treatment after the texturing of the substrate of the magnetic recording medium. It is intended to provide a manufacturing method.

【0011】[0011]

【課題を解決するための手段】本発明者らは、磁気記録
媒体の製造方法において、テクスチャ加工後の基板の電
解処理に際して、工業的規模で有利に実施することが可
能な方法につき鋭意検討を重ねた結果、本発明に想到し
これを完成するに至った。
DISCLOSURE OF THE INVENTION The inventors of the present invention have earnestly studied a method of manufacturing a magnetic recording medium, which can be advantageously carried out on an industrial scale in electrolytically treating a substrate after texture processing. As a result of repeating, the present invention was conceived and completed.

【0012】本発明の磁気記録媒体の製造方法は、導電
性基板にテクスチャ加工を施すテクスチャ加工工程と、
該導電性基板の表面に少なくとも磁性層を形成する薄膜
形成工程とを有する磁気記録媒体の製造方法において、
前記テクスチャ加工工程と薄膜形成工程との間に、導電
性基板を電解液中で処理する電解処理工程を有し、該電
解処理工程は、複数の導電性基板を基板面と直交方向に
順次に並べて電解液中に配置し、順次に数えて奇数番目
の導電性基板と偶数番目の導電性基板との間に交番電圧
を印加して行なわれることを特徴とする。
A method of manufacturing a magnetic recording medium according to the present invention comprises a texture processing step of texture-processing a conductive substrate,
A method of manufacturing a magnetic recording medium, comprising a thin film forming step of forming at least a magnetic layer on the surface of the conductive substrate,
Between the texture processing step and the thin film forming step, there is an electrolytic treatment step of treating a conductive substrate in an electrolytic solution, and the electrolytic treatment step sequentially processes a plurality of conductive substrates in a direction orthogonal to the substrate surface. It is characterized in that they are arranged side by side in the electrolytic solution, and an alternating voltage is applied between the odd-numbered conductive substrate and the even-numbered conductive substrate which are sequentially counted.

【0013】ここで、本発明方法で製造される磁気記録
媒体には特に制限はなく、導電性基板をテクスチャ加工
で処理することにより製造される磁気記録媒体であれば
いかなる磁気記録媒体でもよい。導電性基板としては、
基板全体が導電性でなくとも、その表面全体が導電性で
あれば足りる。また、本発明における薄膜形成工程は、
一般には下地膜及び磁性膜の形成を含む。
Here, the magnetic recording medium manufactured by the method of the present invention is not particularly limited, and any magnetic recording medium can be used as long as it is a magnetic recording medium manufactured by processing a conductive substrate by texture processing. As a conductive substrate,
Even if the entire substrate is not conductive, it is sufficient if the entire surface thereof is conductive. In addition, the thin film forming step in the present invention,
Generally, this includes formation of a base film and a magnetic film.

【0014】上記交番電圧が、奇数番目の導電性基板に
電気的に接触すると共に偶数番目の導電性基板とは電気
的に絶縁されて該奇数番目及び偶数番目の各導電性基板
を支持する第1の導電性支持部材と、偶数番目の導電性
基板に電気的に接触すると共に奇数番目の導電性基板と
は電気的に絶縁されて該偶数番目及び奇数番目の各導電
性基板を支持する第2の導電性支持部材との間に印加さ
れるように構成することが好ましい。この場合、支持部
材が交番電圧の印加のための部材をも兼ねるため、本発
明方法を実施する装置が簡素化される。
The alternating voltage electrically contacts the odd-numbered conductive substrates and is electrically insulated from the even-numbered conductive substrates to support the odd-numbered and even-numbered conductive substrates. A first electrically conductive support member and an even numbered electrically conductive substrate are electrically contacted with each other, and an odd numbered electrically conductive substrate is electrically insulated to support the even numbered and odd numbered electrically conductive substrates; It is preferable that it is configured to be applied between the two conductive supporting members. In this case, the supporting member also serves as a member for applying an alternating voltage, so that the apparatus for carrying out the method of the present invention is simplified.

【0015】また、上記各導電性支持部材が夫々、導電
性基板の配列方向に延びる導電性支持棒と、各導電性基
板に対応して導電性支持棒上に配列される複数の導電性
係止部材とを備え、該導電性係止部材は、導電性基板の
外周縁に当接する当接部を有すると共に、対応する導電
性基板と導電性支持部材との電気的な接触又は絶縁に対
応して、導電性支持部材と電気的に接続され又は絶縁さ
れる構成が好ましい。この場合、導電性支持部材の構成
が更に簡素化される。当接部としては、例えば、基板外
周部の形状及び寸法に対応して形成される溝により構成
する。
Further, each of the conductive supporting members extends in the direction in which the conductive substrates are arranged, and a plurality of conductive members arranged on the conductive supporting rods corresponding to the conductive substrates. A stop member, and the conductive locking member has an abutting portion that abuts an outer peripheral edge of the conductive substrate, and supports electrical contact or insulation between the corresponding conductive substrate and the conductive support member. It is preferable that the conductive support member is electrically connected to or insulated from the conductive support member. In this case, the structure of the conductive support member is further simplified. The contact portion is, for example, a groove formed corresponding to the shape and size of the outer peripheral portion of the substrate.

【0016】[0016]

【好適な実施の態様】以下、更に、本発明をその好適な
実施の態様に基づいて詳細に説明する。
BEST MODE FOR CARRYING OUT THE INVENTION The present invention will be described in detail below based on its preferred embodiments.

【0017】本発明における磁気記録媒体の導電性基板
としては、一般にアルミニウム合金からなるディスク状
基板が用いられ、通常、該アルミニウム基板を所定の厚
さに加工した後に、その表面を鏡面加工してから、非磁
性金属、例えばNi−P合金又はNi−Cu−P合金を無
電解メッキ処理により被着し、約5〜20μmの膜厚の
表面層を形成する。次いで、この表面層上に表面加工処
理を行ない、特定の面粗さに仕上げた表面加工層を形成
する。この表面加工処理として、まず、例えば表面層に
ポリッシュ加工を施し、次いでテクスチャ加工を施した
後に、本発明方法に従い、基板表面を電解液中で電解処
理する。
A disk-shaped substrate made of an aluminum alloy is generally used as the conductive substrate of the magnetic recording medium in the present invention. Usually, the aluminum substrate is processed to a predetermined thickness and then the surface thereof is mirror-finished. Then, a non-magnetic metal such as a Ni-P alloy or a Ni-Cu-P alloy is deposited by electroless plating to form a surface layer having a thickness of about 5 to 20 μm. Then, a surface processing is performed on this surface layer to form a surface processed layer having a specific surface roughness. As this surface processing treatment, for example, the surface layer is first subjected to polishing processing and then to texture processing, and then the substrate surface is subjected to electrolytic treatment in an electrolytic solution according to the method of the present invention.

【0018】ここで、ポリッシュ加工としては、例え
ば、表面に遊離砥粒を付着させて染み込ませたポリッシ
ュパッドの間に基板を挟み込み、界面活性剤水溶液等の
研磨液を補給しながら行う。通常、2〜5μm程度のポ
リッシュ加工を行なって基板の表面を平均表面粗さRa
が50Å(オングストローム)以下、望ましくは30Å以下
に鏡面仕上げする。遊離砥粒としては、代表的には、ア
ルミナ系スラリーのポリプラ700やポリプラ103(共に
(株)フジミインコーポレーテッドの登録商標)、ダイ
ヤモンド系スラリー、SiC系スラリー等が用いられ
る。ポリッシュパッドとしては、代表的には、Surfin10
0やSurfinXXX-5(共に(株)フジミインコーポレーテッ
ドの登録商標)等の発泡ウレタン等が用いられる。
Here, the polishing process is carried out, for example, by sandwiching the substrate between polishing pads having free abrasive grains adhered to the surface and impregnated with the polishing pads, and replenishing a polishing liquid such as a surfactant aqueous solution. Usually, the surface of the substrate is polished to a mean surface roughness Ra by performing polishing processing of about 2 to 5 μm.
Is less than 50Å (Angstrom), preferably less than 30Å. As the free abrasive grains, typically, an alumina-based slurry, such as Polypla 700 and Polypla 103 (both are registered trademarks of Fujimi Incorporated), a diamond-based slurry, and a SiC-based slurry are used. As a polishing pad, typically, Surfin10
For example, urethane foam such as 0 and Surfin XXX-5 (both are registered trademarks of Fujimi Incorporated) is used.

【0019】また、テクスチャ加工としては、例えば、
2500〜6000#程度のアルミナ砥粒を担持した研磨テープ
を使用し、上記ポリッシュ加工を施した基板面に対して
この研磨テープを加工ローラで押圧して、基板の円周方
向に平均表面粗さRaが20Å以上、望ましくは30〜300
Å、更に望ましくは50〜15Åの範囲の微細な溝若しくは
凹凸を精度よく形成するものであり、このテクスチャ加
工により、磁気ヘッドと磁気記録媒体との間での吸着が
防止でき、CSS特性が改善され、更に、磁気記録媒体
の磁気異方性が良好となる。
Further, as the texture processing, for example,
Use a polishing tape that carries about 2500 to 6000 # alumina abrasive grains, press the polishing tape against the polished substrate surface with a processing roller, and measure the average surface roughness in the circumferential direction of the substrate. Ra is 20Å or more, preferably 30 to 300
Å, more preferably, it forms fine grooves or irregularities in the range of 50 to 15Å with high precision. By this texture processing, adsorption between the magnetic head and the magnetic recording medium can be prevented, and CSS characteristics are improved. In addition, the magnetic anisotropy of the magnetic recording medium is improved.

【0020】本発明方法では、テクスチャ加工を施した
基板表面を電解液中で電解処理する際に、複数の導電性
(非磁性)基板を基板面と直交方向に順次に並べて電解
液中に配置し、順次に数えて奇数番目の導電性基板と偶
数番目の導電性基板との間に交番電圧を印加すること
で、各導電性基板を電解液中で処理する。その後、薄膜
形成工程により下地層及び磁性層を形成する。
In the method of the present invention, when the textured substrate surface is electrolytically treated in the electrolytic solution, a plurality of conductive (non-magnetic) substrates are sequentially arranged in the direction orthogonal to the substrate surface and arranged in the electrolytic solution. Then, by sequentially applying an alternating voltage between the odd-numbered conductive substrates and the even-numbered conductive substrates, the conductive substrates are treated in the electrolytic solution. After that, an underlayer and a magnetic layer are formed by a thin film forming process.

【0021】本発明の特に好適な実施態様の一例を図1
〜図3を参照して説明する。図1は、基板を電解処理す
る様子を模式的に示す、基板面方向に見た電解槽内の立
面図である。図1において、符号1は、図面上で左端か
ら順次に数えて奇数番目の基板を、符号2は偶数番目の
基板を夫々示している。各基板1、2は、電解液3が満
たされた電解槽5内に、その基板面と直交方向に多数が
並んで配列される。符号4はAC電源であり、その一方
のライン6が奇数番目の各基板1に、他方のライン7が
偶数番目の各基板2に、夫々図示しない支持部材を介し
て接続されている。
One example of a particularly preferred embodiment of the present invention is shown in FIG.
~ It demonstrates with reference to FIG. FIG. 1 is an elevational view of the inside of the electrolytic cell as viewed in the direction of the substrate surface, schematically showing how the substrate is subjected to electrolytic treatment. In FIG. 1, reference numeral 1 denotes an odd-numbered substrate sequentially counted from the left end in the drawing, and reference numeral 2 denotes an even-numbered substrate. A large number of the substrates 1 and 2 are arranged in an electrolytic bath 5 filled with the electrolytic solution 3 in a direction orthogonal to the substrate surface. Reference numeral 4 is an AC power source, and one line 6 thereof is connected to each odd-numbered substrate 1 and the other line 7 is connected to each even-numbered substrate 2 via a supporting member (not shown).

【0022】AC電源4からは、所定周波数(例えば2
0Hz)の矩形波から成る交番電圧が出力される。従っ
て、奇数番目の基板1及びこれに対向する偶数番目の基
板2が夫々交互に陽極又は陰極の電極板として機能し、
対向する基板間1、2を交番電流が流れることにより、
各基板1、2の電解処理が可能となる。この電界処理に
より、基板表面の突起やバリがエッチングにより除去さ
れ、基板表面が滑らかな表面状態に仕上げられる。
From the AC power source 4, a predetermined frequency (for example, 2
An alternating voltage composed of a rectangular wave of 0 Hz is output. Therefore, the odd-numbered substrates 1 and the even-numbered substrates 2 facing the odd-numbered substrates 1 alternately function as an electrode plate of an anode or a cathode,
By the alternating current flowing between the opposing substrates 1, 2,
The electrolytic treatment of each of the substrates 1 and 2 becomes possible. By this electric field treatment, protrusions and burrs on the substrate surface are removed by etching, and the substrate surface is finished in a smooth surface state.

【0023】図2は、電解槽内での基板の支持状況を示
す、基板面と直交方向に見た基板の正面図であり、ま
た、図3は図2のA−A’矢視図である。図2は、奇数
番目及び偶数番目の基板1、2に共通の図として描かれ
ており、各ディスク状基板1、2は夫々、ディスクの円
周方向に相互に離隔してこれを受け止めるように配置さ
れた3つの支持部材11、12、13によって、ディス
ク外周縁部の3点で支持される。なお、支持部材の数は
2以上、任意の数が選定されるものの、基板の挿入及び
取り外し等の取扱いの便宜のために3点以上が好まし
い。
FIG. 2 is a front view of the substrate viewed in a direction orthogonal to the substrate surface, showing the supporting condition of the substrate in the electrolytic cell, and FIG. 3 is a view taken along the line AA 'in FIG. is there. FIG. 2 is drawn as a diagram common to the odd-numbered and even-numbered substrates 1 and 2, so that the disc-shaped substrates 1 and 2 are spaced apart from each other in the circumferential direction of the disc to receive them. The three support members 11, 12 and 13 thus arranged support the disk at three points on the outer peripheral edge thereof. The number of the supporting members is 2 or more, and an arbitrary number is selected, but 3 or more is preferable for convenience of handling such as insertion and removal of the substrate.

【0024】第1及び第2の支持部材11及び12は、
何れも導電性支持部材、例えば金属部材として構成され
ており、図3に示すように、基板の外周部近傍に基板の
配列方向に延びる導電性支持棒14と、この導電性支持
棒14に電気的に接触しつつ支持される第1の係止部材
15と、導電性支持棒14に電気的に絶縁されつつ支持
される第2の係止部材17とから構成される。各係止部
材15、17は、例えば金属材料から成り、略ソロバン
玉形状に形成され、導電性支持棒14に挿入される中空
穴を有すると共に、外周面が環状溝18として形成され
ている。環状溝18はその溝底部が基板1、2の外周面
に当接して、導電性基板1、2を垂直方向及び水平方向
に支持すると共にこれと電気的に接触している。
The first and second support members 11 and 12 are
Each of them is configured as a conductive support member, for example, a metal member. As shown in FIG. 3, a conductive support rod 14 extending in the arrangement direction of the substrates near the outer peripheral portion of the substrate, and the conductive support rods 14 are electrically connected to each other. The first locking member 15 is supported while being in contact with each other, and the second locking member 17 is supported by the conductive support rod 14 while being electrically insulated. Each of the locking members 15 and 17 is made of, for example, a metal material, is formed in a substantially abacus ball shape, has a hollow hole to be inserted into the conductive support rod 14, and has an outer peripheral surface formed as an annular groove 18. The bottom of the annular groove 18 is in contact with the outer peripheral surfaces of the substrates 1 and 2 to support the conductive substrates 1 and 2 in the vertical direction and the horizontal direction and to make electrical contact with them.

【0025】第1の係止部材15は、ネジ19によっ
て、導電性支持棒14に電気的及び機械的に結合されて
いる。第2の係止部材17は、例えばテフロン等の絶縁
材16を介して導電性支持棒14から絶縁されつつこれ
に支持されている。なお、図2に示した第3の支持部材
13は、導電性支持部材11、12と同様な導電性支持
棒及び第2の係止部材を有する絶縁性の支持部材であ
り、各導電性基板1、2を単に機械的に支持する。
The first locking member 15 is electrically and mechanically connected to the conductive support rod 14 by a screw 19. The second locking member 17 is insulated from and supported by the conductive support rod 14 via an insulating material 16 such as Teflon. The third support member 13 shown in FIG. 2 is an insulating support member having the same conductive support rods and second locking members as the conductive support members 11 and 12, and each conductive substrate Only mechanically support 1,2.

【0026】AC電源4からの電流は、例えば第1の導
電性支持部材11の支持棒14を経由して、この支持棒
14と電気的に接触している第1の係止部材15に流入
し、更に、第1の係止部材の環状溝18表面を経て、対
応する奇数番目の導電性基板1の外周縁から当該基板に
与えられる。次いで、電解液を経由して対向する偶数番
目の基板2から、同様にして、第2の導電性支持部材1
2を経由してAC電源に還流する。電圧極性が反転する
と、同様にこれと逆方向に流れる。このように、奇数番
目の基板1とこれに対向する偶数番目の基板2とは相互
に対向する対向電極を構成する。これにより、各基板の
電解処理が可能となる。
The current from the AC power source 4 flows into the first locking member 15 which is in electrical contact with the support rod 14 via the support rod 14 of the first conductive support member 11, for example. Further, the electric charges are given to the substrate from the outer peripheral edge of the corresponding odd-numbered conductive substrate 1 via the surface of the annular groove 18 of the first locking member. Then, from the even-numbered substrates 2 facing each other via the electrolytic solution, the second conductive support member 1 is similarly formed.
Return to AC power via 2. When the voltage polarity is reversed, it similarly flows in the opposite direction. Thus, the odd-numbered substrates 1 and the even-numbered substrates 2 facing the odd-numbered substrates 1 form counter electrodes facing each other. This enables electrolytic treatment of each substrate.

【0027】上記において、絶縁のための第2の係止部
材17それ自体をテフロン等の絶縁材料で形成すること
も考えられるが、このようにすると、電解処理中に係止
部材17に気泡が付着し、支持部材近傍の基板面が気泡
によりマスキングされ、エッチングムラが発生すること
となり好ましくない。
In the above, it is conceivable that the second locking member 17 for insulation itself is made of an insulating material such as Teflon. However, in this case, bubbles are generated in the locking member 17 during the electrolytic treatment. Adhesion is caused and the surface of the substrate in the vicinity of the supporting member is masked by air bubbles, resulting in uneven etching, which is not preferable.

【0028】本発明方法では、上記のように、好ましく
は酸性溶液の電解液中において、基板に流れる電流が特
定の波形となるように交番電圧を印加して、テクスチャ
加工を施した基板表面の電解処理を行なう。ここで、電
解液としては、例えば、硫酸、硝酸、塩酸、クロム酸、
リン酸、シュウ酸、酢酸等の1種又は2種以上を組み合
わせた0.5〜40重量%、望ましくは1〜30重量%の範囲の
濃度の水溶液が用いられ、特にリン酸水溶液が好適であ
る。電解処理の条件としては、液温が10〜70℃、平均電
流密度が50mA/cm2以下、好ましくは0.1〜50mA/cm2
更に好ましくは0.5〜45mA/cm2、電解時間が1〜400秒、
好ましくは2〜200秒、電気量(平均電流密度と電解時間
の積)が10〜1000mA・秒/cm2、好ましくは50〜600mA・
秒/cm2の範囲が選ばれる。
In the method of the present invention, as described above, preferably in an electrolytic solution of an acidic solution, an alternating voltage is applied so that the current flowing through the substrate has a specific waveform, and the surface of the textured substrate is treated. Perform electrolytic treatment. Here, as the electrolytic solution, for example, sulfuric acid, nitric acid, hydrochloric acid, chromic acid,
An aqueous solution having a concentration in the range of 0.5 to 40% by weight, preferably 1 to 30% by weight, which is a combination of one or more of phosphoric acid, oxalic acid, acetic acid and the like is used, and an aqueous phosphoric acid solution is particularly preferable. The conditions of the electrolytic treatment include a liquid temperature of 10 to 70 ° C. and an average current density of 50 mA / cm 2 or less, preferably 0.1 to 50 mA / cm 2 ,
More preferably 0.5 to 45 mA / cm 2 , electrolysis time 1 to 400 seconds,
Preferably 2 to 200 seconds, the amount of electricity (product of average current density and electrolysis time) is 10 to 1000 mA · sec / cm 2 , preferably 50 to 600 mA ·
The range of seconds / cm 2 is chosen.

【0029】電解エッチングに使用される電流として
は、正負の極性、即ち陽極、陰極の極性を交互に変える
交番電流、例えば正弦波の単相交流、或いは、矩形波、
3角波、台形波等の交番電流が挙げられる。
The electric current used for the electrolytic etching is an alternating current having positive and negative polarities, that is, alternating polarities of the anode and the cathode, such as a sinusoidal single-phase alternating current or a rectangular wave.
An alternating current such as a triangular wave or a trapezoidal wave may be used.

【0030】図4(a)〜(d)に電解エッチング処理
に用いられる電流波形の例を示した。正弦波(a)、矩
形波(b)、台形波(c)、及び、三角波(d)が例示
されている。交番電流の周波数は、好ましくは0.1〜500
Hz、更に好ましくは0.1〜300Hzの範囲内として実施さ
れる。かかる波形の交番電流を用いた場合に、夫々の基
板における陽極時電気量(QA)と陰極時電気量(Q
C)との比(QA/QC)として、0〜2.0、好ましくは
0.8〜1.5、更に好ましくは0.9〜1.1の範囲が選ばれる。
FIGS. 4A to 4D show examples of current waveforms used in the electrolytic etching process. A sine wave (a), a rectangular wave (b), a trapezoidal wave (c), and a triangular wave (d) are illustrated. The frequency of the alternating current is preferably 0.1 to 500.
It is carried out within the range of Hz, more preferably 0.1 to 300 Hz. When an alternating current having such a waveform is used, the amount of electricity at the anode (QA) and the amount of electricity at the cathode (QA) in each substrate are
The ratio (QA / QC) with C) is 0 to 2.0, preferably
The range of 0.8 to 1.5, more preferably 0.9 to 1.1 is selected.

【0031】本発明方法を用いて、高濃度電解液、例え
ば15重量(wt)%以上のリン酸水溶液の電解液で多数
の基板を電解エッチング処理した場合には、基板間のエ
ッチング量のばらつきが小さく、且つ、電磁変換特性の
指標である基板外周面のモジュレーションが大幅に改善
され、磁気ディスクの性能が向上する。
When a large number of substrates are electrolytically etched by using the method of the present invention with a high-concentration electrolytic solution, for example, an electrolytic solution of a phosphoric acid aqueous solution of 15% by weight (wt)% or more, variations in etching amount among the substrates are caused. Is small, and the modulation of the outer peripheral surface of the substrate, which is an index of electromagnetic conversion characteristics, is significantly improved, and the performance of the magnetic disk is improved.

【0032】また、本発明においては、上記した電解処
理によって、テクスチャ加工後の基板表面のピットの発
生を抑制しつつ、基板表面の突起やバリ等をエッチング
により除去するので、基板表面を滑らかな表面状態と
し、得られた磁気ディスクにおいてヘッドの浮上特性や
CSS特性が大幅に改善され、且つ、保磁力等の磁気特
性も向上する。
Further, in the present invention, the electrolytic treatment described above suppresses the generation of pits on the substrate surface after texture processing, and removes protrusions, burrs and the like on the substrate surface by etching, so that the substrate surface is smooth. With the surface state, in the obtained magnetic disk, the flying characteristics and CSS characteristics of the head are significantly improved, and the magnetic characteristics such as coercive force are also improved.

【0033】なお、電解エッチング処理の終了後に、必
要に応じて、下地層及び磁性層の積層に先立って、再度
テクスチャ加工を施す仕上処理を行なってもよい。この
テクスチャ加工は、例えば、遊離砥粒をセルロース製不
織布等の基材表面に付着させて染み込ませたもの、或い
は、アルミナ等の砥粒の比較的細かいものを担持したテ
ープ等を基板面に押圧して行なうことが出来る。
If necessary, after the electrolytic etching treatment, a finishing treatment may be carried out to re-texture before laminating the underlayer and the magnetic layer. This texturing is, for example, a method in which loose abrasive grains are adhered to the surface of a substrate such as a cellulose nonwoven fabric and impregnated, or a tape carrying a relatively fine abrasive grain such as alumina is pressed against the substrate surface. You can do it.

【0034】上記電解処理を施した基板表面上に第2次
下地層としてクロム(Cr)をスパッタリングにより形
成する。このCr下地層の膜厚は通常50〜2000Åの範囲
である。このような基板のCr下地層上に形成される金
属磁性薄膜層としては、Co−Cr、Co−Ni、Co−Cr
−X、Co−Ni−X、Co−W−X等で表わされるCo系
合金の磁性薄膜層が好適である。ここでXとしては、L
i、Si、Ca、Ti、V、Cr、Ni、As、Y、Zr、N
b、Mo、Ru、Rh、Ag、Sb、Hf、Ta、W、Re、O
s、Ir、Pt、Au、La、Ce、Pr、Nd、Pm、Sm、及
び、Euよりなる群から選ばれた1種又は2種以上の元
素が挙げられる。このようなCo系合金から成る金属磁
性薄膜層は、通常、スパッタリング等の手段によって基
板の下地層上に被着形成される。この金属磁性薄膜層の
膜厚は、一般に、100〜1000Åの範囲である。
Chromium (Cr) is formed as a secondary underlayer on the surface of the substrate that has been subjected to the electrolytic treatment by sputtering. The film thickness of this Cr underlayer is usually in the range of 50 to 2000Å. As the metal magnetic thin film layer formed on the Cr underlayer of such a substrate, Co-Cr, Co-Ni, Co-Cr are available.
A magnetic thin film layer of a Co-based alloy represented by -X, Co-Ni-X, Co-W-X or the like is preferable. Where X is L
i, Si, Ca, Ti, V, Cr, Ni, As, Y, Zr, N
b, Mo, Ru, Rh, Ag, Sb, Hf, Ta, W, Re, O
Examples include one or more elements selected from the group consisting of s, Ir, Pt, Au, La, Ce, Pr, Nd, Pm, Sm, and Eu. Such a metal magnetic thin film layer made of a Co-based alloy is usually deposited and formed on the underlayer of the substrate by means such as sputtering. The thickness of the metal magnetic thin film layer is generally in the range of 100 to 1000Å.

【0035】金属磁性薄膜上には、好ましくは炭素質膜
から成る保護薄膜層が形成される。炭素質保護薄膜層
は、通常、アルゴン(Ar)、ヘリウム(He)等の希ガ
スの雰囲気下又はこれに加えて少量の水素の存在下で、
カーボンをターゲットとして行うスパッタリングにより
形成され、アモルファス状カーボン膜や水素化カーボン
膜等として被着形成される。この保護薄膜層の膜厚は、
通常50〜500Åの範囲である。また、摩擦係数を更に小
さくするために、保護薄膜上に更に潤滑膜を形成しても
よい。
A protective thin film layer, preferably a carbonaceous film, is formed on the metal magnetic thin film. The carbonaceous protective thin film layer is usually used in the presence of a rare gas such as argon (Ar) or helium (He) or in the presence of a small amount of hydrogen.
It is formed by sputtering using carbon as a target, and is deposited as an amorphous carbon film or a hydrogenated carbon film. The thickness of this protective thin film layer is
It is usually in the range of 50 to 500Å. Further, in order to further reduce the coefficient of friction, a lubricating film may be further formed on the protective thin film.

【0036】[0036]

【作用】本発明の製造方法によると、各基板に対して所
望の電解処理が精度よく且つ均一に行なわれるので製品
の品質が良好であり、また、各基板自体が電極として作
用するので、基板毎に電極を配置する必要がなく、電極
板を省くことにより、各基板の取扱いも容易となる。
According to the manufacturing method of the present invention, the desired electrolytic treatment is performed accurately and uniformly on each substrate, so that the quality of the product is good, and since each substrate itself acts as an electrode, It is not necessary to dispose electrodes for each, and by omitting the electrode plate, each substrate can be handled easily.

【0037】一般に直流電解では基板は常に陽極であ
り、基板表面にはNi−Pの容出反応と同時に陽極酸化
反応が起る。一方、基板に交番電流を流して電解処理を
行う場合には、基板は電流波形に応じて交互に陽極及び
陰極となる。陽極時の基板表面にはNi−Pの容出反応
と同時に陽極酸化反応が起り、陰極時の基板表面にはH
2ガスの発生反応が起る。即ち、交番電流による電解処
理では、陰極時に基板表面で発生する水素により、陽極
時に基板表面で発生した酸素が消費され、直流電解に比
べて基板表面が酸化しにくい。また、陰極時に発生する
2ガスによるバブリングによって基板表面近傍の粘性
層(Niリン酸塩の飽和溶液と推測される)の攪拌が行
なわれることから、基板表面のエッチングレートの面内
均一化を促進し、更にバブリングによる基板表面の洗浄
効果が期待できる。
Generally, in direct current electrolysis, the substrate is always an anode, and the Ni-P elution reaction and the anodization reaction simultaneously occur on the substrate surface. On the other hand, when an alternating current is applied to the substrate for electrolytic treatment, the substrate becomes the anode and the cathode alternately according to the current waveform. Ni-P elution reaction and anodic oxidation reaction occur simultaneously on the substrate surface at the time of anode, and H
2 Gas generation reaction occurs. That is, in the electrolysis treatment using the alternating current, hydrogen generated on the substrate surface at the time of cathode consumes oxygen generated on the substrate surface at the time of anode, and the substrate surface is less likely to be oxidized than in direct current electrolysis. In addition, since the viscous layer near the substrate surface (presumed to be a saturated solution of Ni phosphate) is agitated by bubbling with H 2 gas generated at the cathode, the etching rate on the substrate surface is made uniform. It is expected that the effect of promoting the cleaning and further cleaning the substrate surface by bubbling can be expected.

【0038】[0038]

【実施例】次に、実施例により本発明を更に説明する
が、本発明はその要旨を越えない限り以下の実施例によ
って限定されるものではない。
EXAMPLES Next, the present invention will be further described with reference to examples, but the present invention is not limited to the following examples unless it exceeds the gist thereof.

【0039】実施例1 無電解メッキ法によりNi−Pメッキを15μm程度の厚み
に施した、アルミニウム合金製で3.5インチディスク用
の基板を用意した。基板の表面をポリッシュ加工して、
その表面平均粗さ(Ra)が約20〜30Åである膜面と
し、次いで、研磨テープを用いたテクスチャ加工により
微細な溝を形成した。更に、そのディスクに遊離砥粒を
用いたテクスチャ加工を施す処理を行ない、表面平均粗
さ(Ra)が約60Å程度となるように仕上げた。次に、
図1〜図3に示した装置を用い、基板20枚をまとめて
電解処理することとした。15wt%リン酸水溶液中で、通
電電流が図4(b)に示した矩形波の交番電流となるよ
うに、奇数番目の基板と偶数番目の基板との間に印加す
る交番電圧を制御して電解処理を行なった。電解処理の
条件として、電解液の液温20℃、平均電流密度10mA/cm
2、周波数20Hz、及び、電解時間20秒を採用した。得ら
れた基板のエッチング量を図5に示す。20枚の基板エ
ッチング量平均は約3.96mg/枚で、基板間でのバラツキ
は充分に小さく、標準偏差が10.5%と良好であった。
Example 1 A substrate for a 3.5-inch disk made of an aluminum alloy, which was Ni-P plated to a thickness of about 15 μm by an electroless plating method, was prepared. Polish the surface of the substrate,
A film surface having an average surface roughness (Ra) of about 20 to 30Å was formed, and then fine grooves were formed by texturing with a polishing tape. Further, the disk was subjected to a texturing process using loose abrasive grains, and finished so that the average surface roughness (Ra) was about 60Å. next,
Using the apparatus shown in FIGS. 1 to 3, 20 substrates were collectively subjected to electrolytic treatment. In a 15 wt% phosphoric acid aqueous solution, the alternating voltage applied between the odd-numbered substrate and the even-numbered substrate is controlled so that the applied current becomes the rectangular-wave alternating current shown in FIG. 4 (b). Electrolytic treatment was performed. As the conditions for electrolytic treatment, the temperature of the electrolyte solution is 20 ° C and the average current density is 10 mA / cm.
2 , frequency 20Hz and electrolysis time 20 seconds were adopted. The etching amount of the obtained substrate is shown in FIG. The average etching amount of the 20 substrates was about 3.96 mg / sheet, the variation between the substrates was sufficiently small, and the standard deviation was good at 10.5%.

【0040】比較例1 無電解メッキ法によりNi−Pメッキを15μm程度の厚み
で施したアルミニウム合金製で3.5インチディスク用の
基板を用意した。基板の表面をポリッシュ加工して、そ
の表面平均粗さ(Ra)が約20〜30Åである膜面とし、
次いで、研磨テープを用いたテクスチャ加工により微細
な溝を形成し、表面平均粗さ(Ra)が100Å程度となる
ように仕上げた。次に、このディスク基板10枚をまと
めて、特願平6−14335号の実施例に示す方法で電
解処理することとし、上記実施例1と同容量で、図6に
示した構成の電解槽5内で基板8と電極板9とが平行平
板対向電極となるようにこれらを交互に配置し、DC電
源10から直流電圧を印加した。陰極を成す電極板9に
はディスク基板8と同形状のステンレス材を使用した。
電解処理の条件として、10wt%リン酸水溶液中で、電極
間距離12mm、液温20℃、電流密度2mA/cm2、電解時間10
0秒を採用した。電極板9からは水素が発生した。得ら
れた基板のエッチング量を図7に示す。10枚あたりの
エッチング量は平均7.13mg/枚で、基板間での標準偏差
が5.43%と良好であった。
Comparative Example 1 A substrate for a 3.5-inch disk made of an aluminum alloy plated with Ni-P to a thickness of about 15 μm by an electroless plating method was prepared. The surface of the substrate is polished to form a film surface having an average surface roughness (Ra) of about 20 to 30Å,
Next, fine grooves were formed by texturing using a polishing tape, and finishing was performed so that the average surface roughness (Ra) was about 100Å. Next, these 10 disk substrates are collectively subjected to electrolytic treatment by the method shown in the example of Japanese Patent Application No. 6-14335, and the electrolytic cell having the same capacity as that of the above-mentioned example 1 and having the configuration shown in FIG. A substrate 8 and an electrode plate 9 were alternately arranged so as to be parallel plate opposing electrodes in 5, and a DC voltage was applied from a DC power source 10. For the electrode plate 9 forming the cathode, a stainless material having the same shape as the disk substrate 8 was used.
The conditions for the electrolytic treatment are as follows: in a 10 wt% phosphoric acid aqueous solution, the distance between the electrodes is 12 mm, the liquid temperature is 20 ° C., the current density is 2 mA / cm 2 , and the electrolysis time is 10
0 seconds is adopted. Hydrogen was generated from the electrode plate 9. The etching amount of the obtained substrate is shown in FIG. The average etching amount per 10 sheets was 7.13 mg / sheet, and the standard deviation between the substrates was good at 5.43%.

【0041】上記実施例1及び比較例1の比較から判る
ように、本発明による電解処理方法は、電極板を省略し
たことにより、電極のコストを削減し且つ基板の挿入及
び取り外し等の取扱いを容易にした利点を有しながら
も、比較例1に比してさほどエッチング量のバラツキが
大きくなく、安定で良好な品質のディスクの製作を可能
としている。
As can be seen from the comparison between Example 1 and Comparative Example 1 described above, the electrolytic treatment method according to the present invention reduces the cost of the electrodes by omitting the electrode plate, and handles the insertion and removal of the substrate. Even though it has the advantage of being simplified, the variation in etching amount is not so large as compared with Comparative Example 1, and it is possible to manufacture a disk of stable and good quality.

【0042】[0042]

【発明の効果】以上説明したように、本発明の磁気記録
媒体の製造方法によると、電極に必要なコスト及び基板
の取扱い工数を低減して、磁気記録媒体の製造コストを
低減すると共に、品質が良好でそのバラツキも小さな磁
気記録媒体を製造できる顕著な効果が得られる。
As described above, according to the method of manufacturing the magnetic recording medium of the present invention, the cost required for the electrodes and the man-hours for handling the substrate are reduced, so that the manufacturing cost of the magnetic recording medium is reduced and the quality is improved. The magnetic recording medium having a good magnetic field and a small variation can be produced.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の一実施例の磁気記録媒体の製造方法を
実施する様子を示す電解槽内部の模式的立面図。
FIG. 1 is a schematic elevational view of the inside of an electrolytic cell showing how a method for manufacturing a magnetic recording medium according to an embodiment of the present invention is carried out.

【図2】電解槽内での基板の支持状況を示す、基板面と
直交方向に見た模式的立面図。
FIG. 2 is a schematic elevational view showing a state of supporting a substrate in an electrolytic bath, as viewed in a direction orthogonal to the substrate surface.

【図3】図2のA−A’矢視図。FIG. 3 is a view on arrow A-A ′ of FIG.

【図4】電解エッチング処理に用いられる電流波形図。FIG. 4 is a current waveform diagram used in electrolytic etching.

【図5】実施例方法で得られた各基板におけるエッチン
グ量。
FIG. 5 shows the etching amount on each substrate obtained by the method of the example.

【図6】比較例方法を実施する電解槽内の模式的立面
図。
FIG. 6 is a schematic elevational view of the inside of an electrolytic cell for carrying out the comparative example method.

【図7】比較例方法で得られた各基板におけるエッチン
グ量。
FIG. 7 shows the etching amount on each substrate obtained by the comparative example method.

【符号の説明】[Explanation of symbols]

1 奇数番目の基板 2 偶数番目の基板 3 電解液 4 AC電源 5 電解槽 6、7 電源ライン 8 基板 9 電極板 10 DC電源 11、12 導電性支持部材 13 第3の支持部材 14 導電性支持棒 15、17 係止部材(ソロバン玉部材) 16 絶縁材 18 環状溝 1 odd-numbered board 2 Even-numbered board 3 Electrolyte 4 AC power supply 5 electrolyzer 6, 7 power line 8 substrates 9 electrode plate 10 DC power supply 11, 12 conductive support member 13 Third Support Member 14 Conductive support rod 15, 17 Locking member (Soroban ball member) 16 Insulation material 18 annular groove

───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 平5−128506(JP,A) 特開 昭54−101729(JP,A) 特開 平5−209300(JP,A) 特開 昭63−311000(JP,A) (58)調査した分野(Int.Cl.7,DB名) G11B 5/62 - 5/858 C25F 3/04 B23H 3/04 ─────────────────────────────────────────────────── --Continued from the front page (56) Reference JP-A-5-128506 (JP, A) JP-A-54-101729 (JP, A) JP-A-5-209300 (JP, A) JP-A-63- 311000 (JP, A) (58) Fields investigated (Int.Cl. 7 , DB name) G11B 5/62-5/858 C25F 3/04 B23H 3/04

Claims (2)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 導電性基板にテクスチャ加工を施すテク
スチャ加工工程と、該導電性基板の表面に少なくとも磁
性層を形成する薄膜形成工程とを有する磁気記録媒体の
製造方法において、 前記テクスチャ加工工程と薄膜形成工程との間に、導電
性基板を電解液中で処理する電解処理工程を有し、該電
解処理工程は、 複数の導電性基板を基板面と直交方向に順次に並べて電
解液中に配置し、 順次に数えて奇数番目の導電性基板と偶数番目の導電性
基板との間に交番電圧を印加して行なわれ、且つ、 前記交番電圧が、前記奇数番目の導電性基板に電気的に
接触すると共に前記偶数番目の導電性基板とは電気的に
絶縁されて該奇数番目及び偶数番目の各導電性基板を支
持する第1の導電性支持部材と、前記偶数番目の導電性
基板に電気的に接触すると共に前記奇数番目の導電性基
板とは電気的に絶縁されて該偶数番目及び奇数番目の各
導電性基板を支持する第2の導電性支持部材との間に印
加されること を特徴とする磁気記録媒体の製造方法。
1. A method of manufacturing a magnetic recording medium, comprising: a texture processing step of performing texture processing on a conductive substrate; and a thin film forming step of forming at least a magnetic layer on a surface of the conductive substrate, the texture processing step comprising: Between the thin film forming step and the electrolytic treatment step of treating the conductive substrate in the electrolytic solution, the electrolytic treatment step is performed by arranging a plurality of conductive substrates in a direction orthogonal to the substrate surface in order in the electrolytic solution. placement was carried out by applying an alternating voltage between the odd-numbered conductive substrate and the even-numbered conductive substrate counted sequentially, and, the alternating voltage, electrical said odd conductive substrate To
And to electrically connect with the even conductive substrate.
Insulated to support the odd and even conductive substrates.
A first conductive support member to hold, and the even-numbered conductive member
The odd-numbered conductive groups are in electrical contact with the substrate and
The plate is electrically insulated from the even-numbered and odd-numbered
A mark is formed between the second conductive support member supporting the conductive substrate and the second conductive support member.
A method of manufacturing a magnetic recording medium characterized by being added .
【請求項2】 前記各導電性支持部材が夫々、導電性基
板の配列方向に延びる導電性支持棒と、各導電性基板に
対応して前記導電性支持棒上に配列される複数の導電性
係止部材とを備え、 前記各導電性係止部材は、導電性基板の外周縁に当接す
る当接部を有すると共に、対応する導電性基板と前記導
電性支持部材との電気的な接触又は絶縁に対応して、前
記導電性支持部材と電気的に接続され又は絶縁される、
請求項に記載の磁気記録媒体の製造方法。
2. Each of the conductive support members extends in the direction in which the conductive substrates are arranged, and a plurality of conductive members arranged on the conductive support rods corresponding to the conductive substrates. A locking member, each of the conductive locking members has a contact portion that contacts the outer peripheral edge of the conductive substrate, and the electrical contact between the corresponding conductive substrate and the conductive support member or Corresponding to insulation, electrically connected or insulated with the conductive support member,
The method of manufacturing a magnetic recording medium according to claim 1 .
JP33449594A 1994-12-19 1994-12-19 Manufacturing method of magnetic recording medium Expired - Fee Related JP3386909B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP33449594A JP3386909B2 (en) 1994-12-19 1994-12-19 Manufacturing method of magnetic recording medium

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP33449594A JP3386909B2 (en) 1994-12-19 1994-12-19 Manufacturing method of magnetic recording medium

Publications (2)

Publication Number Publication Date
JPH08171719A JPH08171719A (en) 1996-07-02
JP3386909B2 true JP3386909B2 (en) 2003-03-17

Family

ID=18278046

Family Applications (1)

Application Number Title Priority Date Filing Date
JP33449594A Expired - Fee Related JP3386909B2 (en) 1994-12-19 1994-12-19 Manufacturing method of magnetic recording medium

Country Status (1)

Country Link
JP (1) JP3386909B2 (en)

Also Published As

Publication number Publication date
JPH08171719A (en) 1996-07-02

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