JP3390904B2 - Porous odor deodorant - Google Patents

Description

Description: BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to livestock agriculture, industry,
The present invention relates to a deodorant used in various treatment plants, sewage systems, general homes, construction sites, construction sites, and other environmental odor removal and deodorization fields, and a method for producing the same. 2. Description of the Related Art Conventional deodorants are those having a single odor effect, being surrounded by an odor film, or utilizing an adsorption effect. [0003] For example, an enzyme / bacterial agent is a method in which filth is decomposed by a protease. In addition, it is a method of breeding bacteria and decomposing and digesting filth. [0004] Fragrances are a method of camouflaging odors with a strong scent. In other words, it is a method of masking the smell with a fragrance. [0005] The coating agent is a method of coating the surface of the odorous substance to prevent the odor from scattering. Since fungicides are bactericidal,
The purpose of the present invention is to suppress enzymes and bacteria (rot bacteria) that decompose into night soil and to prevent the generation of odorous gas. The neutralizing agent is a method in which an iron component agent is mainly used, which is put into a toilet bowl, and since septic manure is alkaline, an acidic one is used to neutralize and extinguish. The adsorbent is a method of absorbing the generated odorous gas. [0007] However, when an enzyme or a bacterial agent is used, it cannot be deodorized in the air, and the odorous gas such as odorless anhydrous carbon dioxide and carbon dioxide gas recurs after dispersing the filth. . In addition, if a foreign substance is mixed in, it will die and, on the contrary, emit a more stench. Further, there is a disadvantage that one of the alkali and the acid does not disappear. [0008] In addition, when a fragrance is used, masking with a fragrance is not a fundamental solution, and the fragrance causes a breeding of various bacteria and a secondary pollution due to a malfunction of the septic tank. There are drawbacks. Further, when a coating agent is used, the smell is covered with oil or only the source of the smell is covered, so that there is a problem that fundamental deodorization is not caused and the function of the septic tank is impaired by oil components. . In addition, when a disinfectant is used, aerobic and anaerobic microorganisms are killed, which causes a malfunction of the septic tank and causes red tide and crop standing, which causes secondary problems. [0010] On the other hand, when a neutralizing agent is used, the method of neutralization relates to an acidic / alkaline combined odor or an unknown odor with respect to a homogeneous odor. There is a disadvantage that it cannot be processed. Furthermore, when an adsorbent is used, only the odor is absorbed and the odor is not decomposed. Further, a treatment after the adsorption and the saturation state is required. In particular, there is a disadvantage that adsorption of a low molecular weight system cannot be performed. As described above, in masking deodorization, an odor is masked by using an aromatic agent such as a fragrance, but bromine cannot be decomposed. In the neutralization deodorization, a plurality of off-flavors such as ethyl mercaptan and camphor are present at the same time to neutralize the odors odorously, and the odors cannot be decomposed. In the desulfurization deodorization, only the sulfur odor is removed using an iron compound such as ferric hydroxide, and is effective only for a single odor. In the neutralization deodorization, utilizing the ion exchange action,
This method absorbs odors by passing bromine gas through an aqueous solution of acid or alkali, so it is an effective method for amine-based and hydrogen sulfide-based gases. Need to take appropriate measures. [0015] Oxidation reduction deodorization is a method of converting odorous bromine by oxidation or reduction using a reaction tank in which caustic soda, peroxide, etc. are used. You will bear a heavy burden. In the adsorption deodorization, the method of physically adsorbing odors on the surface of an individual has a limit in saturation, and there is no decomposition of the odors themselves. Biological deodorization can be roughly classified into two types, one using an effective microorganism and one using an enzyme, but cannot deal with odorous substances in the atmosphere. [0018] The present invention has been made in view of the above conventional method, an organic compound having a variety of inorganic Motoya hydroxyl its components and dehydroabietic
By constituted by Chin acid, inorganic or remembering assimilable
It is an object of the present invention to provide a deodorant capable of coping with both organic components and acid and alkali odors, and capable of deodorizing in response to all kinds of odors, and a method for producing the same. The deodorant according to the present invention comprises:
Organism and aviation having hydroxyl group for decomposing odorous substances
It is mainly composed of porous soil containing ethnic acid . Diatomaceous earth is a typical example of the soil used in the present invention. Ammonia as an inorganic substance in this soil
Those containing nitrogen , silicon, iron, copper, manganese and the like are used. The organic substance for decomposing the odorant is water.
An organic material having an acid group 1.3 cineole, borneol, terpenes, pantothenic acid, folic acid, humic acid, pectinase, other cellulases, having a carboxyl group
It consists of a combination of abietic acid . Among the above-mentioned organic substances having a hydroxyl group, folic acid and humic acid are the main components for decomposing odorous substances. Borneol and mosquitoes
Abietic acid having a ruboxyl group is a volatile substance and positively neutralizes and deodorizes odorous substances such as toluene and thinner. Cellulase is effective against fecal odor in manure. The method for producing a deodorizing agent according to the present invention, organisms and carboxy having a hydroxyl group for decomposing odorous product
Porous soil containing abietic acid having a hydroxyl group is formed into a granular or powdery material having a predetermined hardness, or is fired at a suitable temperature as a molded article to form a ceramic or dried to form a molded article. In order to obtain an odor deodorant. The deodorant used in the present invention has a granular or powdery form or a molded article whose hardness is determined according to the intended use. For example, if the deodorant can withstand temporary use rather than long-term use, In some cases, simply high-pressure treatment is sufficient without firing, and in some cases, simple drying treatment is sufficient. The porous odor deodorant may have any shape as long as the surface area can be secured. The odorous substance having a large ionization tendency, for example, a mineral ion, especially a divalent iron ion, is oxidized in the adsorbent and becomes a complex to form an atomic group with the unsaturated compound. Deodorizes by reacting with ammonia to form an ammine complex ion. What is sulfur odor?
Creates e-S and deodorizes. For example, the hydrogen sulfide odor is H ₂ S → Na
_{Like 2} S + H ₂ O, the oxidizing and reducing reaction of odorous components and the mineral elements contained at the same time react preferentially with high molecular substances rather than low molecular substances, so fatty acids of high molecular odors are adsorbed and decomposed. Is done. For example, in the case of low-molecular sulfide molecules, hydrogen sulfide, and sulfur containing S, they are directly bonded to metal ions and eliminated. A chemical reaction formula for a typical odor is shown below. N (CH3) 3 → (CH3) 3 NO + Na + (amine) (CH3 SH) → CH3 SNa + H2 O (mercaptan) HCl → NaCl + H + ↑ NH3 ammonia Fe2 ++ 6NH3 → [Fe (N
H3) 6] 2+ (CH3) 3N trimethylamine Fe2 ++ 6 (C
H3) 3N → [Fe <N (CH3)> 6] 2 + CH3SH Methylmercaptan Fe2 ++ CH3S
H → Fe-S + CH4 (methane) H2 S Hydrogen sulfide Fe2 ++ H2 S → Fe-S + 2
H + (oxidized to water) Bacteria, Staphylococcus aureus, Streptococcus staphylococci, and Escherichia coli are also treated with hydroxyl organic substances (pantothenic acid, folic acid, humic acid, etc.) and abietic acid having a carboxyl group . The eradication effect was obtained. The hydroxyl group of phenol displaces hydrogen and metal to form and decompose the salt phenoxide. R O H → R O
M [0028] [Example] as a main component in Example 1 folic acid and humic acid, and 1,3-cineol, borneol, terpenes, abietic acid, pantothenic acid, pectinase, an organism that for the additional inclusion of cellulase, inorganic body Ammonia nitrogen, silicon, iron, copper,
The resulting mixture was mixed in a diatomaceous earth clay containing manganese and the like and subjected to high temperature or high pressure treatment to obtain a porous odor deodorant having a desired hardness. Table 1 shows the results of applying the porous odor deodorant thus obtained to pig farms, fish intestinal bone odor, organic solvents, human urine odor, and gray water. Comparative Example A pig farm similar to that of Example 1 using an enzyme / bacterial agent, a fragrance, a coating agent, a bactericide, a neutralizing agent, and an adsorbent, a fish iliac odor, an organic solvent, a human odor and gray water. Are shown in Table 1. [Table 1] As can be seen from the above description, the present invention can simultaneously remove acidic and alkaline malodorous harmful substances by a decomposition reaction. Decomposition of an unknown complex odor is immediately performed, and the odor itself can be converted to an odorless substance by an air reduction method. Therefore, according to the present invention, it is harmless to humans and animals,
It is possible to deodorize at a speed of a second, and after decomposing and decomposing, those that have been directly discarded can be effectively used as fertilizer. In addition, maggots and boula are lost. The deodorant according to the present invention can be applied in both gas and water. Furthermore, in the present invention, in the components, hydrocarbons, phenols,
Reactions such as neutralization, adsorption, oxidation-reduction, and addition act on active substances such as folic acid and various inorganic substances such as Fe in a complex manner to deodorize. Further, the deodorant according to the present invention is not necessarily subjected to high-temperature treatment. For example, when it is used for a short period of time, it can be applied in a state of high-pressure treatment or simply dried.

Continuation of front page (56) References JP-A-5-277167 (JP, A) JP-A-8-164192 (JP, A) JP-A-8-66464 (JP, A) JP-A-63-203161 (JP) JP-A-63-84618 (JP, A) JP-A-63-28336 (JP, A) JP-A-49-35542 (JP, A) JP-A-61-209039 (JP, A) (58) Field surveyed (Int. Cl. ⁷ , DB name) A61L 9/00-9/22

Claims (1)

(57) [Claims 1] A composition containing folic acid and humic acid as main components, and
1.3-Cineol, borneol, terpene, punt
Formic acid, pectinase, cellulase and abietic acid
Includes organic substances and inorganic substances
Porous diatomaceous earth containing elemental, silicon, iron, copper and manganese
Deodorization of porous odor characterized by mixing
Agent.