JP3419337B2 - Method of firing magnetic core - Google Patents
Method of firing magnetic coreInfo
- Publication number
- JP3419337B2 JP3419337B2 JP06426099A JP6426099A JP3419337B2 JP 3419337 B2 JP3419337 B2 JP 3419337B2 JP 06426099 A JP06426099 A JP 06426099A JP 6426099 A JP6426099 A JP 6426099A JP 3419337 B2 JP3419337 B2 JP 3419337B2
- Authority
- JP
- Japan
- Prior art keywords
- flat ring
- shaped molded
- powder
- firing
- magnetic core
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Landscapes
- Magnetic Ceramics (AREA)
- Powder Metallurgy (AREA)
- Soft Magnetic Materials (AREA)
Description
【発明の詳細な説明】
【0001】
【発明の属する技術分野】本発明は、磁性体コアの焼成
方法に関し、特に、ノイズ除去部品等のコアとして使用
される偏平リング状磁性体コアの焼成方法に関する。
【0002】
【従来の技術】ノイズ除去部品等のコアとして、図5に
示すような偏平リング状磁性体コア21が知られてい
る。この磁性体コア21は、偏平状貫通孔22にフラッ
トケーブル等の信号線を挿通することにより、信号線を
伝搬する高周波ノイズを除去する。磁性体コア21は、
その横断面の長辺寸法L=10〜100mm、短辺寸法
T=1〜10mm、貫通孔22の短辺寸法t=0.3〜
8mmの範囲の寸法を有するものが多く使用されてい
る。このような磁性体コア21の焼成方法としては、従
来より、例えば図5に示すような方法が一般に周知であ
る。
【0003】すなわち、図5に示す焼成方法は、偏平状
貫通孔22を有するフェライト材料からなる偏平リング
状成形体21を、その貫通孔22の軸方向が垂直になる
ように、一端側の開口面で焼成用容器(図示せず)の内
部に立てて焼成する方法である。このとき、偏平リング
状成形体21は互いに離隔して配置され、隣接する偏平
リング状成形体21同士が焼成時にくっつかないように
工夫される。形成体21がくっつくと両者間で化学反応
が起こったり、くっついた成形体21を機械的衝撃力を
加えて外すときに欠けやクラックが生じる等の不具合が
発生するからである。
【0004】
【発明が解決しようとする課題】ところで、従来の磁性
体コアの焼成方法は、成形体21のサイズが大きい場合
には、焼成用容器内に成形体21を離隔して垂直に立て
る作業は比較的容易であった。また、僅かな振動や衝撃
が加わっても、偏平リング状成形体21は傾斜せず、隣
接する偏平リング状成形体21同士が焼成時にくっつく
等の不具合は発生しにくかった。
【0005】しかしながら、近年、磁性体コアの薄型
化、小型化により、サイズの小さい偏平リング状成形体
21を離隔して垂直に立てた状態で焼成することが多く
なってきた。この場合、サイズの小さい偏平リング状成
形体21を1個毎に離隔して垂直に立てる作業は煩雑で
手間がかかるという問題があった。また、偏平リング状
成形体21のサイズが小さいと、僅かな振動が加わって
も、偏平リング状成形体21が傾斜し、隣接する偏平リ
ング状成形体21に接触してそれらの間で化学反応が生
じたり、くっつきや欠け、外観からは発見が困難なひび
割れ等が生じ、良品率が低下したり、製品の信頼性が低
下するといった問題があった。
【0006】本発明の目的は、焼成を高い信頼性で行な
うことができ、しかも量産性の優れた磁性体コアの焼成
方法を提供することにある。
【0007】
【課題を解決するための手段及び作用】前記目的を達成
するため、本発明に係る磁性体コアの焼成方法は、磁性
体材料からなる複数の偏平リング状成形体の表面に、粒
径が1000μm以下のものを含む有機材料からなる粉
体を付与し、前記偏平リング状成形体の偏平状貫通孔の
軸方向が垂直になるように複数の前記偏平リング状成形
体を近接して整列配置した後、互いに隣接する偏平リン
グ状成形体間に前記粉体を介在させた状態で前記偏平リ
ング状成形体を焼成するとともに、該焼成により前記粉
体を構成する有機材料を気化させる。
【0008】以上の方法により、偏平リング状成形体の
表面に付与された粉体は、互いに隣接する偏平リング状
成形体間に介在してスペーサとして機能する。従って、
偏平リング状成形体を積み重ねてセットすることがで
き、セッティング作業が容易になる。そして、偏平リン
グ状成形体が焼成される際、隣接する偏平リング状成形
体同士が直接に接触しなくなり、それらの間で反応が生
じたり、くっつきや欠けが生じるという不具合が解消さ
れる。
【0009】
【発明の実施の形態】以下に、本発明に係る磁性体コア
の焼成方法の実施の形態について添付の図面を参照して
説明する。
【0010】図1に示すように、複数の偏平リング状成
形体1を用意する。偏平リング状成形体1は、バインダ
等と混練したフェライト等の磁性体材料粉末を、偏平状
貫通孔2を有する偏平リング状に成形してなるものであ
る。偏平リング状成形体1の各々は、その貫通孔2の軸
方向が水平になるように寝かされる。次に、図1に矢印
Aで示すように、偏平リング状成形体1の上から粉体を
むらなく振りかける。該粉体は、粒径が1000μm以
下のものを含み、有機材料又は無機材料からなるもので
ある。有機材料としては、焼成工程で気化してしまう材
料が好ましく、具体的には、ポリビニールアルコール系
やセルロース系の合成樹脂材料、小麦粉や片栗粉等の天
然有機材料等が用いられる。無機材料としては、焼成工
程で偏平リング状成形体1と化学反応しない材料が好ま
しく、具体的には、アルミナやジルコニア等が用いられ
る。
【0011】ところで、粉体の粒径が1000μmを越
えると、粉体と偏平リング状成形体1とのなじみが悪く
なり、後工程で偏平リング状成形体1を垂直に立てたと
きに粉体が偏平リング状成形体1の表面から落ち易く、
偏平リング状成形体1のセッティングの作業性が低下す
る。ただし、粒径が1000μmを越える粉体に、10
00μm以下の粒径のものを混合することにより、前記
の作業性の低下は改善される。
【0012】一方、粒径が20μm以下の粉体は、偏平
リング状成形体1のくっつきを防止するスペーサとして
の機能は多少劣るものの、互いにくっついている偏平リ
ング状成形体1に軽く機械的衝撃を与えることにより、
簡単に分離させることができる。
【0013】次いで、図2に示すように、粉体が振りか
けられて表面に粉体が付着した偏平リング状成形体1
を、その各軸方向を水平に揃えて一定数、積み重ねる。
積み重ねられた状態の偏平リング状成形体1は、相互間
に粉体が介在している。その後、図3に示すように、偏
平リング状成形体1を積み重ね状態を保持したまま各軸
方向が垂直になるようにして、偏平リング状成形体1と
化学反応しない無機粉体(例えば高純度のアルミナ粉体
もしくはジルコニア粉体)を敷き詰めた焼成用容器(図
示せず)の内部に、整列配置する。なお、偏平リング状
成形体1の形状や、焼成用容器の材質によっては、焼成
用容器に無機粉体を敷く必要がない場合もある。
【0014】この後、垂直に立てた偏平リング状成形体
1が倒れないように、図4に示すように、高純度アルミ
ナもしくはジルコニア等のバー3を偏平リング状成形体
1の側面に添える。このようにセットされた偏平リング
状成形体1は、焼成炉内で焼成される。こうして、偏平
リング状成形体1を焼成してなる磁性体コアが得られ
る。
【0015】以上の焼成方法により、偏平リング状成形
体1の表面に付与された粉体は、互いに隣接する偏平リ
ング状成形体1間に介在してスペーサとして機能する。
従って、偏平リング状成形体1を積み重ねてセットする
ことができ、セッティング作業が容易になる。そして、
偏平リング状成形体1が焼成される際、隣接する偏平リ
ング状成形体1同士が直接に接触しなくなり、それらの
間で反応が生じたり、くっつきや欠けが生じるという不
具合を解消することができる。
【0016】なお、本発明は、前記実施形態に限定され
るものではなく、本発明の要旨の範囲内で種々の構成と
することができる。例えば、前記実施形態では、粉体を
偏平リング状成形体に振りかけるようにしたが、吹き付
け等により粉体を偏平リング状成形体に強制的に付着さ
せるようにしてもよい。
【0017】
【実施例】長辺寸法L=22.8mm、短辺寸法T=
2.8mm、長さ=12.0mmの外形寸法を有し、か
つ、貫通孔2の長辺寸法=18.7mm、短辺寸法t=
0.7mmの偏平リング状成形体1(図1参照)を用意
した。この偏平リング状成形体1はNiZn系フェライ
ト材料からなる。また、粉体として以下の表1に示す種
々のものを用意した。そして、偏平リング状成形体1を
その貫通孔2の軸方向が水平になるように寝かした後、
上から表1に示したそれぞれの粉体を網の容器に入れて
むらなく振りかけた。次いで、振りかけた粉体を介在さ
せ、各軸方向が垂直となるように偏平リング状成形体1
を積み重ねた。
【0018】この後、偏平リング状成形体1を、ジルコ
ニア粉を敷き詰めた焼成用容器内に、一列当たり32
個、これを5列並べ、ジルコニア製のバー3を添わせ
た。こうして偏平リング状成形体1をセットした焼成用
容器を各実施例毎に30サンプル(偏平リング状成形体
1の数で4800個)用意し、1000〜1200℃の
電気炉で焼成した。焼成後の磁性体コアのくっつき発生
率及び不良率の評価結果を表1に示す(実施例1〜実施
例8)。なお、表1には、比較のために、従来の焼成方
法で焼成した磁性体コアの評価結果も合わせて記載して
いる(比較例)。
【0019】
【表1】
【0020】表1で、実施例3のセルロース系粉体を用
いて焼成した場合、並びに実施例8の平均粒径が40μ
mの高純度アルミナ粉体を用いて焼成した場合には、そ
れぞれ15%及び14%の磁性体コアにくっつきが発生
した。しかし、両者とも、くっついている磁性体コアに
軽く機械的衝撃を与えると、簡単に分離させることがで
き、その品質も合格のレベルに達しており、不良率は0
%であった。
【0021】
【発明の効果】以上の説明からも明らかなように、本発
明によれば、偏平リング状成形体の表面に付与された粉
体は、互いに隣接する偏平リング状成形体間に介在して
スペーサとして機能する。従って、偏平リング状成形体
を積み重ねてセットすることができ、セッティング作業
が容易になる。そして、偏平リング状成形体が焼成され
る際、隣接する偏平リング状成形体同士が直接に接触し
なくなり、それらの間で反応が生じたり、くっつきや欠
けが生じるという不具合を解消することができる。この
結果、磁性体コアの焼成を高い信頼性を有して効率よく
行うことができるばかりでなく、良品率も大幅に向上す
る。Description: BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method of firing a magnetic core, and more particularly, to a method of firing a flat ring-shaped magnetic core used as a core of a noise removing component or the like. About. 2. Description of the Related Art A flat ring-shaped magnetic core 21 as shown in FIG. 5 is known as a core of a noise removing component or the like. The magnetic core 21 removes high-frequency noise propagating through the signal line by inserting a signal line such as a flat cable into the flat through hole 22. The magnetic core 21
The long side dimension L of the cross section is 10 to 100 mm, the short side dimension T is 1 to 10 mm, and the short side dimension t of the through hole 22 is 0.3 to 0.3 mm.
Those having dimensions in the range of 8 mm are often used. As a method for sintering the magnetic core 21, for example, a method as shown in FIG. 5 is generally known. [0005] That is, in the firing method shown in FIG. 5, a flat ring-shaped molded body 21 made of a ferrite material having a flat through hole 22 is opened at one end so that the axial direction of the through hole 22 is vertical. This is a method in which the surface is set inside a firing container (not shown) and fired. At this time, the flat ring-shaped molded bodies 21 are arranged so as to be separated from each other, and are designed so that the adjacent flat ring-shaped molded bodies 21 do not stick to each other during firing. This is because if the formed bodies 21 stick together, a chemical reaction occurs between them, and defects such as chipping or cracking occur when the bonded formed body 21 is removed by applying a mechanical impact force. [0004] In the conventional method of firing a magnetic core, when the size of the molded body 21 is large, the molded body 21 is set up vertically in a firing container at a distance. The work was relatively easy. Further, even when a slight vibration or impact is applied, the flat ring-shaped molded body 21 does not tilt, and problems such as the adjacent flat ring-shaped molded bodies 21 sticking to each other during firing are unlikely to occur. However, in recent years, due to the thinning and miniaturization of the magnetic core, firing of the small-sized flat ring-shaped molded body 21 in a state of being vertically erected is increasing. In this case, there is a problem that the work of vertically standing the small flat ring-shaped molded bodies 21 with a small size apart from each other is complicated and troublesome. Also, if the size of the flat ring-shaped molded body 21 is small, even if a slight vibration is applied, the flat ring-shaped molded body 21 is inclined and comes into contact with the adjacent flat ring-shaped molded body 21 to cause a chemical reaction between them. There is a problem that sticking or chipping occurs, cracks and the like that are difficult to detect from the appearance occur, and the yield rate decreases and product reliability decreases. An object of the present invention is to provide a method for firing a magnetic core which can be fired with high reliability and which is excellent in mass productivity. [0007] In order to achieve the above object, a method for firing a magnetic core according to the present invention comprises the steps of: providing a surface of a plurality of flat ring-shaped molded bodies made of a magnetic material;
A powder made of an organic material including one having a diameter of 1000 μm or less is applied , and the plurality of flat ring-shaped molded bodies are brought close to each other such that the axial direction of the flat through-holes of the flat ring-shaped molded body is vertical. after aligning, with firing the flat ring-shaped molded product while interposing the powder between flat ring-shaped molded bodies adjacent to each other, the powder by the sintering
The organic materials that make up the body are vaporized . According to the above method, the powder applied to the surface of the flat ring-shaped molded product functions as a spacer by being interposed between adjacent flat ring-shaped molded products. Therefore,
The flat ring-shaped moldings can be stacked and set, which facilitates the setting operation. Then, when the flat ring-shaped molded body is fired, the adjacent flat ring-shaped molded bodies do not come into direct contact with each other, and the problem that a reaction occurs between them and sticking or chipping occurs is solved. Embodiments of a method for firing a magnetic core according to the present invention will be described below with reference to the accompanying drawings. As shown in FIG. 1, a plurality of flat ring-shaped moldings 1 are prepared. The flat ring-shaped molded body 1 is formed by molding magnetic material powder such as ferrite kneaded with a binder or the like into a flat ring shape having flat through holes 2. Each of the flat ring-shaped molded bodies 1 is laid so that the axial direction of the through hole 2 is horizontal. Next, as shown by an arrow A in FIG. 1, the powder is sprinkled evenly over the flat ring-shaped molded body 1. The powder contains particles having a particle size of 1000 μm or less, and is made of an organic material or an inorganic material. As the organic material, a material that evaporates in the firing step is preferable, and specifically, a polyvinyl alcohol-based or cellulose-based synthetic resin material, or a natural organic material such as flour or potato starch is used. As the inorganic material, a material that does not chemically react with the flat ring-shaped molded body 1 in the firing step is preferable, and specifically, alumina, zirconia, or the like is used. If the particle size of the powder exceeds 1000 μm, the powder and the flat ring-shaped molded product 1 become less compatible with each other. Easily fall off the surface of the flat ring-shaped molded body 1,
The workability of setting the flat ring-shaped molded body 1 is reduced. However, for powder having a particle size exceeding 1000 μm, 10
By mixing those having a particle size of not more than 00 μm, the above-mentioned decrease in workability is improved. On the other hand, powder having a particle size of 20 μm or less has a slightly inferior function as a spacer for preventing the flat ring-shaped molded product 1 from sticking to each other, but has a light mechanical impact on the flat ring-shaped molded product 1 attached to each other. By giving
It can be easily separated. Next, as shown in FIG. 2, the powder is sprinkled and the flat ring-shaped compact 1 having the powder adhered to the surface is formed.
Are stacked in a fixed number with their axial directions aligned horizontally.
Powder is interposed between the flat ring-shaped molded bodies 1 in the stacked state. Thereafter, as shown in FIG. 3, the flat ring-shaped compacts 1 are maintained in a stacked state, and the respective axes are oriented vertically, so that inorganic powder that does not chemically react with the flat ring-shaped compacts 1 (for example, high purity (Alumina powder or zirconia powder) are arranged and arranged inside a firing container (not shown). Depending on the shape of the flat ring-shaped molded body 1 and the material of the firing container, it may not be necessary to spread the inorganic powder in the firing container. Thereafter, as shown in FIG. 4, a bar 3 of high-purity alumina or zirconia is attached to the side surface of the flat ring-shaped molded body 1 so as to prevent the flat ring-shaped molded body 1 standing upright from falling down. The flat ring-shaped molded body 1 set in this way is fired in a firing furnace. Thus, a magnetic core obtained by firing the flat ring-shaped molded body 1 is obtained. The powder applied to the surface of the flat ring-shaped molded product 1 by the above firing method functions as a spacer by being interposed between the adjacent flat ring-shaped molded products 1.
Therefore, the flat ring-shaped molded bodies 1 can be stacked and set, and the setting operation becomes easy. And
When the flat ring-shaped molded product 1 is fired, the adjacent flat ring-shaped molded products 1 do not come into direct contact with each other, and a problem that a reaction occurs between them and sticking or chipping occurs can be solved. . It should be noted that the present invention is not limited to the above-described embodiment, and may have various configurations within the scope of the present invention. For example, in the above embodiment, the powder is sprinkled on the flat ring-shaped compact, but the powder may be forcibly adhered to the flat ring-shaped compact by spraying or the like. EXAMPLE Long dimension L = 22.8 mm, short dimension T =
It has an outer dimension of 2.8 mm, length = 12.0 mm, and the long side dimension of the through hole 2 = 18.7 mm, the short side dimension t =
A 0.7 mm flat ring-shaped molded product 1 (see FIG. 1) was prepared. The flat ring-shaped molded body 1 is made of a NiZn-based ferrite material. Various powders shown in Table 1 below were prepared as powders. Then, after laying the flat ring-shaped molded body 1 so that the axial direction of the through hole 2 is horizontal,
Each powder shown in Table 1 from above was placed in a net container and sprinkled evenly. Next, the flat ring-shaped molded product 1 is interposed with the sprinkled powder so that each axial direction is vertical.
Piled up. After that, the flat ring-shaped molded product 1 is placed in a firing container covered with zirconia powder for 32 rows per line.
The pieces were arranged in five rows, and a bar 3 made of zirconia was attached. In this way, 30 samples (4800 flat ring-shaped molded bodies 1) of firing containers in each of which the flat ring-shaped molded bodies 1 were set were prepared and fired in an electric furnace at 1000 to 1200 ° C. Table 1 shows the evaluation results of the sticking occurrence rate and the defective rate of the magnetic core after firing (Examples 1 to 8). For comparison, Table 1 also shows the evaluation results of the magnetic cores fired by the conventional firing method (Comparative Example). [Table 1] In Table 1, when the calcined product was prepared using the cellulosic powder of Example 3, and the average particle size of Example 8 was 40 μm.
When baking was performed using high-purity alumina powder of m, the magnetic cores of 15% and 14% respectively adhered to each other. However, in both cases, when a light mechanical shock is applied to the attached magnetic cores, the magnetic cores can be easily separated, the quality thereof has reached a passing level, and the defect rate is 0%.
%Met. As is clear from the above description, according to the present invention, the powder applied to the surface of the flat ring-shaped compact is interposed between the adjacent flat ring-shaped compacts. To function as a spacer. Therefore, the flat ring-shaped molded bodies can be stacked and set, and the setting operation becomes easy. Then, when the flat ring-shaped molded body is fired, the adjacent flat ring-shaped molded bodies do not come into direct contact with each other, and a reaction between them or a problem of sticking or chipping can be solved. . As a result, not only can the magnetic core be fired efficiently with high reliability, but also the yield rate can be significantly improved.
【図面の簡単な説明】
【図1】本発明に係る磁性体コアの焼成方法の一実施形
態を示す斜視図。
【図2】図1に続く工程を示す斜視図。
【図3】図2に続く工程を示す説明図。
【図4】図3に続く工程を示す斜視図。
【図5】従来の磁性体コアの焼成方法を示す斜視図。
【符号の説明】
1…偏平リング状成形体
2…偏平状貫通孔
3…バーBRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a perspective view showing one embodiment of a method for firing a magnetic core according to the present invention. FIG. 2 is a perspective view showing a step following the step shown in FIG. 1; FIG. 3 is an explanatory view showing a step following FIG. 2; FIG. 4 is an exemplary perspective view showing a step following FIG. 3; FIG. 5 is a perspective view showing a conventional method for firing a magnetic core. [Description of Signs] 1 ... Flat ring-shaped molded body 2 ... Flat through hole 3 ... Bar
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 平3−145101(JP,A) 特開 平3−199168(JP,A) (58)調査した分野(Int.Cl.7,DB名) H01F 41/02 ────────────────────────────────────────────────── ─── Continuation of the front page (56) References JP-A-3-145101 (JP, A) JP-A-3-199168 (JP, A) (58) Fields investigated (Int. Cl. 7 , DB name) H01F 41/02
Claims (1)
成形体の表面に、粒径が1000μm以下のものを含む
有機材料からなる粉体を付与し、前記偏平リング状成形
体の偏平状貫通孔の軸方向が垂直になるように複数の前
記偏平リング状成形体を近接して整列配置した後、互い
に隣接する偏平リング状成形体間に前記粉体を介在させ
た状態で前記偏平リング状成形体を焼成するとともに、
該焼成により前記粉体を構成する有機材料を気化させる
ことを特徴とする磁性体コアの焼成方法。(57) [Claims 1] The surface of a plurality of flat ring-shaped molded bodies made of a magnetic material includes those having a particle diameter of 1000 μm or less.
A powder made of an organic material is applied, and a plurality of the flat ring-shaped molded bodies are arranged close to each other so that the axial direction of the flat through-holes of the flat ring-shaped molded body is vertical, and then adjacent to each other. While firing the flat ring-shaped molded body with the powder interposed between the flat ring-shaped molded bodies ,
A method for sintering a magnetic core, wherein the organic material constituting the powder is vaporized by the sintering.
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP06426099A JP3419337B2 (en) | 1999-03-11 | 1999-03-11 | Method of firing magnetic core |
| TW089103559A TW511105B (en) | 1999-03-11 | 2000-03-01 | Method of firing magnetic core |
| CNB001033565A CN1150572C (en) | 1999-03-11 | 2000-03-02 | A method of firing a magnetic core |
| KR1020000010371A KR100359576B1 (en) | 1999-03-11 | 2000-03-02 | Method of firing magnetic core |
| US09/523,350 US6820323B1 (en) | 1999-03-11 | 2000-03-10 | Method of firing magnetic cores |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP06426099A JP3419337B2 (en) | 1999-03-11 | 1999-03-11 | Method of firing magnetic core |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2000260645A JP2000260645A (en) | 2000-09-22 |
| JP3419337B2 true JP3419337B2 (en) | 2003-06-23 |
Family
ID=13253057
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP06426099A Expired - Lifetime JP3419337B2 (en) | 1999-03-11 | 1999-03-11 | Method of firing magnetic core |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3419337B2 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009011210A1 (en) * | 2007-07-19 | 2009-01-22 | Murata Manufacturing Co., Ltd. | Method for producing ceramic sintered body |
| JP5937800B2 (en) * | 2011-09-29 | 2016-06-22 | 住友化学株式会社 | Method for manufacturing honeycomb fired body |
| CN114195528A (en) * | 2021-12-30 | 2022-03-18 | 北京七星飞行电子有限公司 | A ferrite blank sintering process |
-
1999
- 1999-03-11 JP JP06426099A patent/JP3419337B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JP2000260645A (en) | 2000-09-22 |
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