JP3422090B2 - Silver halide photographic materials - Google Patents

Description

DETAILED DESCRIPTION OF THE INVENTION [0001] BACKGROUND OF THE INVENTION 1. Field of the Invention
Silver halide photographic materialsWhen, A phosphor that emits UV light
Form an image in combination withMethodAbout
You. In addition, the present invention provides good photographic
High performance silver halide photographic materialImage shape using
MethodAbout. [0002] 2. Description of the Related Art Tabular grains having a high silver chloride content
There are many prior arts. (111) plane as main plane
Examples of tabular grains having the same include, for example,
No. 8326, No. 64-8325, No. 64-8324
No., JP-A-1-250943, JP-B-3-14328
No., Tokuhei 4-81782, Tokuhei 5-40298
And JP-A-5-39459 and JP-A-5-12696, and
63-213836, 63-218938, 6
3-281149 and JP-A-62-218959 are described above.
I can do it. Also, tabular grains having a (100) plane as a main plane
Japanese Patent Application Laid-Open No. H5-204073 discloses a prior art of the device.
JP-A-51-88017, JP-A-63-24238, etc.
Is raised. In particular, Japanese Patent Application Laid-Open No.
There is a description about silver-containing {100} flat plate,
In image formation with light, the sharpness is not enough
Was. The present inventors have conducted intensive studies and found that the UV light exposure region
Less light scattering and more light to silver bromide
Use of tabular grains with high permeability and high silver chloride content
Are effective in enhancing the sharpness of the image.
I came out. However, this alone is a halation
Or a photosensitive material having a photosensitive layer on both sides of the photosensitive material
The image is blurred due to the over-light, and the sharpness is reduced. this
For the effects of halation and crossover light, salt
Tabular grains having a high silver halide content have smaller light absorption coefficients.
In addition, the high light transmittance has a rather large effect.
It becomes. Therefore, by using an ultraviolet absorber together,
And found that excellent sharpness can be obtained.
Was. In such a configuration, the spectral sensitizing dye
And no need for crossover cut dye
Processing solution by pigment, dye and its decomposed product in replenishment process
Problems such as stains and coloring of the photosensitive material due to remaining in the photosensitive material may occur.
It was found that the ideal system could be constructed. [0003] SUMMARY OF THE INVENTION The present invention is excellent in sharpness.
Silver halide photosensitive materialImage forming method usedOffer
To provide. Further, the present invention provides a rapid, low replenishment process.
Silver halide photographic light-sensitive material with excellent adequacyImage using
Forming methodIs to provide. [0004] The object of the present invention is to completely solve the above-mentioned problems.
At least 50% of the projected area has a silver chloride content of 20% or less.
The silver chloride-containing flat surface having an average aspect ratio of 2 or more
Silver halide photographic photosensitive material containing tabular grain emulsion and ultraviolet absorber
materialIs increased by X-ray absorption fluorescence having an emission peak in the ultraviolet region.
Image forming method characterized by using in combination with paper
LawAchieved by The present invention will be described in detail below.
I do. Halo containing at least a dispersion medium and silver halide grains
In the silver halide emulsion, the total projection surface of the silver halide grains
50% or more of the product, preferably 60% to 100%, more preferably
Preferably 70-100% Cl^- Content of 20 mol% or more,
Preferably 30 mol% to 100%, more preferably 40 mol%
-100 mol%, more preferably 50-100 mol%
Where the main plane is a (100) or (111) plane
Particles. Here, the tabular grains are defined as having an aspect ratio (direct
(Diameter / thickness) larger than 1. Main plane is flat
Refers to the largest outer surface of the particle. The thickness of the tabular grains is 0.3
5 μm or less, preferably 0.05-0.3 μm
And more preferably 0.05 to 0.25 μm. Average ass
The pect ratio is 2 or more, preferably 2 to 25, more preferably
Is 5 to 20. Here, the diameter refers to the projection of the tabular grains.
The diameter of a circle having an area equal to the shadow area is given.
Refers to the distance between two principal planes. What is the average aspect ratio?
It is the average of the aspect ratio of the plate-like particles. [0005] The present inventionUse for(111) face of emulsion
For the nucleation of an emulsion having a principal plane of
No. 8326, No. 64-8325, No. 64-8324
No., JP-A-1-250943, JP-B-3-14328
No., Tokuhei 4-81782, Tokuhei 5-40298
And JP-A-5-39459 and JP-A-5-12696, and
63-213836, 63-218938, 6
3-281149, JP-A-62-218959, etc.
It is described in detail, and the (100) plane is
Japanese Patent Application Laid-Open No. 5-204 discloses a prior art of tabular grains.
073, JP-A-51-88017, JP-A-63-2
No. 4238, Japanese Patent Application No. 5-264059, etc.
I have. In the present invention, these prior arts are described.
Any nucleation method described can be used.
The present inventionUse forPhysical ripening in the presence of silver halide fine grains
(Fine particles dissolve and substrate particles grow)
The lengthening method is described below. Fine particle emulsion addition method
In this case, the diameter is 0.15 μm or less, preferably 0.1 μm or less.
Below, more preferably Ag having a diameter of 0.06 to 0.006 μm
X fine grain emulsion was added, and the plate was
Grow particles. The fine grain emulsion is added continuously.
And it can be added continuously. The fine
The grain emulsion was mixed with AgNO in a mixer provided near the reaction vessel._Three
Solution and X^- Supply salt solution and prepare continuously, immediately
It can be added continuously to the reaction vessel, or another
Continuous or continuous after batch preparation of containers
It can also be added. The fine grain emulsion is added in a liquid state.
Can also be added as a dry powder
Wear. The dry powder is mixed with water just before addition and liquefied
It can also be added. Add the fine particles within 20 minutes
It is preferable to add in a manner that disappears, and 10 seconds to 10
Minutes are more preferred. As the disappearance time increases,
It is not preferable because ripening occurs and the particle size increases.
No. Therefore, it is preferable not to add the whole amount at once. The fine
Preferably, the particles are substantially free of high twin particles
No. Here, a multiple twin particle means a twin plane per particle.
Refers to particles having two or more sheets. Substantially not included
The ratio of the number of double twin particles is 5% or less, preferably 1% or less.
More preferably, it indicates 0.1% or less. Furthermore, single twin particles
Is preferably not substantially contained. Further spiraling
It is preferred that it does not substantially contain a position. Where practically
Not including is in accordance with the above rules. The halogen composition of the fine particles is AgCl, Ag
Br, AgBrl (I^- The content is preferably 10 mol% or less.
And more preferably 5 mol% or less) and two kinds thereof.
This is the above mixed crystal. Other detailsJP-A-6-0593
No. 60 (Japanese Patent Application No. 04-214109)Refer to the description of
can do. Total amount of fine particles added is halogenated
20% or more of the silver amount is required, preferably 40% or less.
Above, more preferably, it is 50% or more and 98% or less.
The Cl content of the fine particles is preferably 10% or more, more preferably
More preferably, it is 50% or more and 100% or less. [0008] The dispersion medium during nucleation, ripening and growth
For this purpose, a conventionally known dispersion medium for an AgX emulsion can be used.
But the methionine content is preferably 0-50 μm
G / g, more preferably 0-30 μmol / g gelatin
Can be preferably used. The gelatin is matured and matured
When used for long time, thinner than uniform diameter size distribution
Tabular grains are formed, which is preferable. In addition, Tokiko Sho 52
-16365, The Photographic Society of Japan, 29 (1), 1
7, 22 (1966), same 30 volumes (1), 10, 19
(1967), Vol. 30 (2), 17 (1967)
), 33 (3), 24 (1967).
A polymer can be preferably used as a dispersion medium. Fine
The pH during growth by adding particles must be 2.0 or more.
However, it is preferably 6 or more and 10 or less. More preferably, p
H6 or more and 9 or less. Also, pCl must be 1.0 or more
However, 1.6 or more is preferable. More preferably
2.0 or more and 3.0 or less are preferable. These growth conditions
Is particularly suitable for tabular grains having a (100) plane as a main plane.
Is particularly preferred. Here, pCl is defined as
Activity of Cl ion [Cl^-For pCl = -log [Cl^-] Is defined by T.H.James, THE THEORY OF THE RHOTO
GRAPHIC PROCESS 4th edition
I have. If the pH falls below 2.0, an example
For example, in the case of tabular grains having a (100) plane as the main plane,
Direction growth is suppressed, the aspect ratio is reduced, and the emulsion
Covering power tends to be low and low sensitivity
Would. When the pH is 2.0 or more, the lateral growth rate
And high covering power with high aspect ratio
Although a light emulsion is obtained, fog is high and sensitivity is easily lowered. p
When Cl becomes 1.0 or less, growth in the vertical direction is promoted.
The aspect ratio is reduced, and the covering power of the emulsion is reduced.
And low sensitivity. pCl is over 1.6
Becomes higher and the covering power increases
However, fog is high and it is easy to reduce sensitivity. At this time,
When substrate particles are grown with silver halide fine particles,
Fog is low and high feeling even when the top and / or pCl is 1.6 or more
And higher covering power with higher aspect ratio
Become. [0010] The present inventionUse forMonodispersity of emulsion
Is described in JP-A-59-745481 regarding the degree of monodispersion.
Considering the coefficient of variation defined by the method of
Lower is preferable, and 5% or more and 25% or less are preferable. Especially hard
5% or more and 15% or less is preferred when using it as a light-sensitive material.
New Selenium, which is a preferred sensitizing method for the present invention,
Tellurium sensitization will be described. These are used alone
Or may be used in combination. In particular, these preferred uses
Examples of use and examples of compounds are described in, for example, JP-A-3-116132,
5-113635, 5-165136, 5-
No. 165137, 5-134345, etc.
It is as it is. Selenium particularly preferably used
Examples of the sensitizer include those described in JP-A-5-165137.
Compounds represented by general formula (I) or (II) and
Listed Compound Examples I-1 to I-20, II-1 to II-19
Can be mentioned. For tellurium sensitizers, see
Represented by the general formulas (IV) and (V) of
And the compound examples IV-1 to IV-2 described therein
2 and V-1 to V-16. The present inventionUse forOf tabular grains containing silver chloride
For the formation, Japanese Patent Application Laid-Open Nos.
139440, JP-A-4-139441 and U.S. Pat.
No. 5,104,786 for multiple coaxial nozzles
Mix immediately before the aqueous halogen solution and the aqueous silver nitrate solution
Nucleation and growth by addition into reaction vessel
Can be preferably performed. Next, the UV absorber
explain about. In the present invention, the ultraviolet absorber is publicly available.
Any known UV absorber can be used
You. Preferably represented by the following general formulas (I) to (VII)
Compound. [0013] Embedded image Where R₁₀₁, R₁₀₂, R₁₀₃, R₁₀₄,
R₁₀₅May be the same or different
Element, halogen, alkyl group, cycloalkyl group, alkyl
Luoxy group, aryl group, aryloxy group, alkenyl
Group, nitro group, carboxyl group, sulfonic group or
Represents a droxy group. [0015] Embedded image Where R₁₁₁~ R₁₁₅Are the same but different
May be hydrogen, halogen, alkyl group, aryl
Group, alkyloxy group, aryloxy group, alkylthio
O group, arylthio group, amino group, alkylamino group,
Dialkylamino group, arylamino group, hydroxy
Group, cyano group, nitro group, carbamoyl group, alkyl
Rubamoyl group, arylcarbamoyl group, alkyl sulf
Honyl group, arylsulfonyl group, sulfamoyl group,
Alkylsulfamoyl group, arylsulfamoyl
Group, alkyl sulfonamide group, aryl sulfonamide
Group, carboxyl group, sulfonic group, alkyl carb
A nyloxy group or an alkyloxycarbonyl group,
R₁₁₆Is hydrogen or an alkyl group, and X₁₁And Y₁₁Ha
Ano group, -COOR₁₁₇, -CONHR₁₁₇, -COR
₁₁₇, -SO_TwoR₁₁₇, -SO_TwoNHR₁₁₇And R
₁₁₇Represents an alkyl group or an aryl group. Also, X₁₁
And Y₁₁May be linked to form a 5- to 7-membered ring. [0017] Embedded image In the formula, R₁₂₁~ R₁₂₆Are the same but different
Hydrogen atom, halogen, alkyl group,
Reel group, alkyloxy group, aryloxy group,
Kirthio, arylthio, amino, hydroxy
Group, cyano group, nitro group, alkylacylamino group,
Reel acylamino group, alkylcarbamoyl group, ant
Carbamoyl group, alkyl sulfonamide group, ant
Sulfonamide group, alkylsulfamoyl group,
Reel sulfamoyl group, carboxyl group, sulfonic acid
Group, alkylcarbonyloxy group or alkyloxyca
Represents a rubonyl group. X_{twenty one}Is -CO- or -COO
Represents-. [0019] Embedded image Where R₁₃₁, R₁₃₂Are the same but different
May be a hydrogen atom, an alkyl group, an aryl group, or
A non-metallic element necessary to form a 5- or 6-membered ring
X represents a child group₃₁, Y₃₁May be the same or different
X in the general formula [II]₁₁, Y₁₁Is synonymous with [0021] Embedded image Where R₁₄₁~ R₁₄₆Are the same but different
May be represented by the general formula [II]₁₁₀~ R₁₁₄
Is synonymous with₁₄₇, R₁₄₈Is the same or different
Often represents a hydrogen atom, an alkyl group or an aryl group. [0023] Embedded image Where R₁₅₁~ R₁₅₄Are the same but different
May be a hydrogen atom, an alkyl group, an aryl group.
And R₁₅₁And R₁₅₄Together form a double bond
May be R₁₅₁And R₁₅₄Together form a double bond
When forming, R₁₅₂And R₁₅₃Is connected to a benzene ring
Alternatively, a naphthalene ring may be formed. R₁₅₅Is alkyl
A group or an aryl group;₄₁Is an oxygen atom, a sulfur atom
, Ethylene group, = NR₁₅₆Or = C (R₁₅₇) (R
₁₅₈), And R_FifteenRepresents an alkyl group or an aryl group
Then R₁₅₇, R₁₅₈May be the same or different, and hydrogen
R represents an atom or an alkyl group;₁₅₇And R₁₅₈Connect with
May form a 5- or 6-membered ring. n is 0 or 1
Express. X₄₁, Y₄₁May be the same or different, general
X in formula [II]₁₁, Y₁₁Is synonymous with n is 0 or
Represents 1. [0025] Embedded image Where X₇₁, Y₇₁, Z₇₁Are replaced independently
Or an unsubstituted alkyl group, aryl group,
Represents an xy group, an aryloxy group or a heterocyclic group.
Where X₇₁, Y₇₁, Z₇₁At least one of them has the general formula (V
III). [0027] Embedded imageWhere R₈₁, R₈₂Are each independently a hydrogen atom,
Halogen atom, substituted or unsubstituted alkyl group,
Loalkyl, aryl, alkyloxy, aryl
Represents a luoxy group. In the general formulas [I] to [VIII], R₁₀₁
~ R₁₀₅, R₁₁₁~ R₁₁₇, R₁₂₁~ R₁₂₆, R₁₃₁,
R₁₃₂, R₁₄₁~ R₁₄₈, R₁₅₁~ R₁₅₅, R₈₁,
R₈₂, X ₇₁, Y₇₁And Z₇₁In each group represented by
The kill group preferably has 1 to 20 carbon atoms and has a substituent [for example,
Hydroxy, cyano, nitro, halogen (e.g.
For example, chlorine, bromine, fluorine), alkoxy group (for example,
Methoxy, ethoxy, butoxy, octyloxy),
Leyloxy group (eg phenoxy), ester group (eg
For example, methoxycarbonyl, ethoxycarbonyl, octane
Tyloxycarbonyl, dodecyloxycarbonyl),
Carbonyloxy group (for example, ethylcarbonyloxy
, Heptylcarbonyloxy, phenylcarbonyloxy
Xy), an amino group (for example, dimethylamino, ethyl
Amino, diethylamino), aryl groups (eg, phenyl
), Carbonamido group (for example, methylcarbonyl
Amide, phenylcarbonylamide), carbamoyl group
(Eg, unsubstituted carbamoyl, methylcarbamoy
, Ethylcarbamoyl, phenylcarbamoyl),
A rufonamide group (for example, methanesulfonamide,
Zensulfonamide), sulfamoyl group (for example,
Tylsulfamoyl, phenylsulfamoyl, methyl
Octylaminosulfonyl), cyano group, carboxyl
Group, sulfonic acid group]. In particular,
Methyl, ethyl, propyl, iso-propyl, butyric
, Sec-butyl, t-butyl, pentyl, t-pen
Tyl, hexyl, octyl, 2-ethylhexyl, t-
Octyl, decyl, dodecyl, hexadecyl, octade
Groups such as sil, benzyl, phenethyl and the above substituents
These groups can be mentioned. As the cycloalkyl group, cyclopropyl
, Cyclopentyl, cyclohexyl, bicyclo [2,
2,2] an octyl group and a substituent described for an alkyl group
These groups can be mentioned. Aryl group
Is preferably a group having 6 to 10 carbon atoms and a substituent [for example,
Alkyl groups (methyl, ethyl, propyl, iso-pro
Pill, butyl, sec-butyl, t-butyl, pliers
, T-pentyl, octyl, decyl, dodecyl, tet
Radecyl, hexadecyl) and the above alkyl groups
And the above-mentioned substituents].
Specific examples of the aryl group include phenyl and naphthyl groups.
Can be mentioned. As the alkenyl group, 2-butenyl, 3
-Butenyl, oleyl groups, which are
The group mentioned as a substituent which the alkyl group may have
It may be substituted. As the heterocyclic group, at least one nitrogen atom
5- or 6-membered heterocyclic ring having an atom, an oxygen atom or a sulfur atom
Group is preferable, and a substituent which the alkyl group may have
Or a group which the aryl group may have as a substituent
It may have the alkyl group mentioned above. Specifically
Represents a piperidine ring, a pyrrolidine ring, a morpholine ring,
Ring, tetrahydrofuran ring, thiophene ring, pyrrole
Ring, pyrazole ring, benzimidazole ring, benzox
Sazole ring, benzothiazole ring, benzotriazole
Ring, triazine ring, indolenine ring, indole ring,
Groups such as a torazole ring and an isoxazolone ring,
These groups having a substituent can be mentioned. X₁₁And Y₁₁5-7 members formed by connecting
Rings include rhodanine, hydantoin, thiazolidinedi
On, isoxazolone, pyrazolidinedione, indane
A ring such as an union and a group which the heterocyclic group may have
These groups having the substituents mentioned above may be mentioned.
it can. R₁₅₇And R₁₅₈5 connected by
Is a cyclopentane ring, a cyclohexane ring as a 6-membered ring
Can be mentioned. R₁₀₁~ R₁₀₅, R₁₁₁~ R
₁₁₅, R₁₂₁~ R₁₂₆, R₈₁, R₈₂Halogen represented by
Examples of chlorine atoms include chlorine, bromine, and fluorine.
Wear. Hereinafter, ultraviolet rays represented by the general formulas [I] to [VI]
Specific examples of the absorbent are illustrated, but the present invention is not limited to these.
It is not something to be done. [0035] Embedded image[0036] Embedded image[0037] Embedded image[0038] Embedded image[0039] Embedded image[0040] Embedded image[0041] Embedded image[0042] Embedded image[0043] Embedded image[0044] Embedded image[0045] Embedded image[0046] Embedded image[0047] Embedded image[0048] Embedded image The compound represented by the general formula [I] used in the present invention
2- (2'-hydroxyphenyl) benzotriazole
UV absorbers can be solid or liquid at room temperature.
However, a liquid is preferred. Specific examples of liquid
Japanese Patent Publication Nos. 55-36984 and 55-12587 and
No. 58-214152. General formula [I]
For details on the UV absorber represented by
No. 58-221844, No. 59-46646, No.
59-109055, JP-A-6-82962, JP
Nos. 36-10466, 42-26187, 48
Nos. -5496 and 48-41572; U.S. Pat.
754,919, 4,220,711, etc.
Have been. The ultraviolet absorbent of the general formula [II] is disclosed in JP-B-48
No. 31255, No. 50-10726, U.S. Pat.
No. 2,719,086, No. 3,214,463, No.
3,284,203 and 3,698,707
It can be synthesized according to the method listed or described.
it can. UV absorber represented by the general formula [III]
Is disclosed in U.S. Pat. No. 3,707,375, JP-B-48-30.
No. 492, JP-A-47-10537 and JP-A-58-111.
No. 942, No. 59-19945, No. 63-53544
Or synthesized according to the described method.
Can be The ultraviolet absorber represented by the general formula [IV] is
JP-A-51-56620 and JP-A-53-128333,
Synthesized according to the method described in JP-A-58-181040 and the like.
Can be The ultraviolet absorber represented by the general formula [V] is
British Patent No. 1,198,337, JP-A-63-535
No. 44 etc. or according to the described method
Can be achieved. The ultraviolet absorber represented by the general formula [VI] is
U.S. Pat. No. 4,360,588, JP-A-63-535
No. 44 etc. or according to the described method
Can be achieved. UV represented by the general formula [VII]
The line absorber is disclosed in JP-A-46-3335, European Patent No. 520
No. 938A1 can be synthesized.
You. [0055] Embedded image[0056] Embedded image[0057] Embedded image[0058] Embedded imageThese ultraviolet absorbers are fine powders (fine crystals)
Particles) as a solid dispersion. these
The fine (crystalline) particle solid dispersion of
(Water, alcohol, etc.) in the presence of a dispersant
Means for refinement (for example, ball mill, vibrating ball mill,
Planetary ball mill, sand mill, colloid mill, jet
Mill, roller mill)
You. The fine (crystalline) particles of the UV absorber are dispersed in the dispersion
After dissolving in a suitable solvent using a surfactant,
Method of Precipitating Microcrystals by Adding to X-ray Absorber Poor Solvent
Or by controlling the pH,
Dissolve the absorbent, then change the pH to microcrystallize
It can be obtained by utilizing a method. UV absorber
The layer containing the fine powder of
Disperse fine (crystal) particles of X-ray absorber in a suitable binder
As a solid dispersion of nearly uniform particles
After preparation, it is coated on the desired support by
Can be provided. Also dissociated UV absorber
Is applied in the form of salt and then overcoated with acidic gelatin.
By using the method of obtaining dispersion fixation at the time of application by
It can also be provided. The binder is photosensitive milk
Hydrophilic colloid that can be used for the agent layer and the non-photosensitive layer
Is not particularly limited as long as it is usually gelatin or synthetic.
A polymer is used. As a surfactant for dispersion, publicly available
Known surfactants can be used.
On- and amphoteric surfactants are preferred. Especially anionic
And / or the use of nonionic surfactants is preferred. The fine particles of the ultraviolet absorber in the solid dispersion are:
Average particle diameter 0.005 μm to 10 μm, preferably,
0.01 μm to 1 μm, more preferably 0.01 μm
It is preferably about 0.5 μm. The ultraviolet absorbent of the present invention may be water or
Water-miscible organic solvents such as alcohols (methanol
, Ethanol, propanol, fluorinated alcohol
), Ketones (acetone, methyl ethyl ketone), di
Methyl formamide, dimethyl sulfoxide, methyl
It can also be used by dissolving it in Lusolve or the like. In addition,
Dibutyl phthalate by the well-known emulsification dispersion method
Rate, tricresyl phosphate, glyceryl tri
Oils such as acetate or diethyl phthalate,
Or to a polymer such as polybutylacrylamide,
Using an auxiliary solvent such as ethyl acetate or cyclohexanone
It can be dissolved and mechanically produced and used as an emulsified dispersion.
Wear. Alternatively, a method known as a solid dispersion method is used.
The hydrazine derivative powder is ball milled in water,
Dispersed by colloid mill or ultrasonic wave
You can also. Alternatively, it is described in JP-A-63-23738.
Disperse and use by the micelle dispersion method described
Can also. As a place to add the ultraviolet absorber of the present invention,
Although not particularly limited, a silver halide emulsion layer, an intermediate layer,
It may be a gelatin layer such as a layer, or may be in a support.
The addition amount is 1 to 500 mg / m^TwoEspecially 3 to 100 mg /
m^TwoIt is preferable that As the support, PEN is preferably used.
be able to. However, it is not limited to this.
Polyethylene-2,6-naphthalate is used as PEN.
preferable. Polyethylene-2,6-naphtha referred to in the present invention
Rate means that the repeating structural unit is substantially ethylene-
Consists of 2,6-naphthalenedicarboxylate units
Polyethylene that is not copolymerized.
Not only 2,6-naphthalenedicarboxylate but also repetition
10% or less, preferably 5% or less of the number of structural units
Copolymers and other polymers modified with the components of
And mixtures thereof. Polyethylene-
2,6-naphthalate is naphthalene-2,6-dicarbo
Acid, or a functional derivative thereof, and ethylene glycol
Or its functional derivative in the presence of a catalyst
Synthesized by binding under reaction conditions
Is polyethylene-2,6-naphthalate according to the present invention.
The polymerization of polyethylene-2,6-naphthalate
One or more suitable third components (modifiers) before completion
Add Copolymerized or mixed polyester
It may be. Suitable third components include divalent S
Compounds having a ter-forming functional group, such as oxalic acid,
Pinic acid, phthalic acid, isophthalic acid, terephthalic acid, naph
Taren-2,7-dicarboxylic acid, succinic acid, diphenyl
Dicarboxylic acids such as ether dicarboxylic acids or the like
Primary alkyl ester, p-oxybenzoic acid, p-oxy
An oxycarboxylic acid such as ethoxybenzoic acid, or
Lower alkyl ester or propylene glycol
And dihydric alcohols such as trimethylene glycol
The compound of the following. Polyethylene-2,6-naphtha
Rate or its modified polymer is, for example, benzoic acid, benzene
Zoylbenzoic acid, benzyloxybenzoic acid, methoxy
By monofunctional compounds such as alkylene glycol
Terminal hydroxyl and / or carboxyl groups were blocked.
Or a small amount of grease, for example.
Trifunctional and tetrafunctional such as serine and pentaerythritol
Substantially linear copolymers are obtained with steal-forming compounds
It may be modified within the range. The present inventionUse forParticularly effective as a photosensitive material
Is exerted on at least one layer on each side of the support.
In the case of having a silver halide emulsion layer. The present invention
When applied to a light-sensitive material having an emulsion on both sides of the support,
In addition to the above-mentioned effects, it is possible to obtain high-quality and sharp images.
, And further reduce the amount of replenishment in the development process.
Unexpectedly does not contaminate tanks and rollers when
Effect can also be achieved. As a chemical sensitization method
Gold sensitization with loose gold compounds or iridium, platinum, b
Sensitization method using metals such asdium and palladiumSomeOr sulfur-containing
Sulfur sensitization using compounds, tin salts, polyamides
Sensitization with selenium compounds,
Lulu compound sensitization, or a combination of two or more of these
Matching can be used. Tabular silver halide grains
As a method of manufacturing, a method known in the art may be appropriately combined.
This can be achieved by doing The present inventionUse forSilver of photosensitive material
The amount is preferably 0.5 g / m^Two~ 5g / m^Two(One side
More preferably 1 g / m^Two~ 3.4 g / m^Two(On one side)
It is. 5 g / m for rapid processing^TwoDo not exceed
Is preferred. The present inventionUse forEach used for photosensitive material
There is no particular limitation on the seed additive.
Use those described in the following corresponding portions of
Can be       Item Applicable section 1. The silver halide emulsion and 6 from the lower right column on page 8 of JP-A-2-68539     From the production line to the 12th line in the upper right column on page 10 of the same. 2. Chemical sensitization method: From page 10, upper right column, line 13 to lower left column, line 16 of the same. 3. Antifoggant / stable page 10, lower left column, line 17 to page 11, upper left column 7,     From the second row of the drug and the lower left column of page 3 to the lower left column of page 4                           . 4. Spectral sensitizing dyes, page 4, lower right column, line 4 to page 8, lower right column. 5. Surfactants and antistatics, page 11, top left column, line 14 to page 12, top left column 9,     Stopper line. 6. Matting agent, slip agent, page 12, top left column, line 10 to top right column, line 10.     Plasticizer Same as page 14, lower left column, line 10 to lower right column, line 1. 7. Hydrophilic colloid, page 12, line 11, upper right column to line 16, lower left column. 8. Hardening agent: From page 17, lower left column, line 17 to page 13, upper right column, 6                           Line. 9. Supporting substance: From page 7, line 7 to line 20 in the upper right column. 10. Dyes and mordants Same as above, page 13, lower left column, line 1 to page 14, lower left column, line 9                           Eye. The present inventionUse forImages using photosensitive materials
As a forming method, it is preferable that the thickness be 400 nm or less.
Method of forming an image in combination with a phosphor having a peak
Is good. More preferably, the main peak is at 380 nm or less.
It is preferable to form an image in combination with a fluorescent material. 4
The screen having a main emission peak at 00 nm or less is disclosed in
Nos. 6-11804 and WO93 / 01521.
Clean is used, but it is not limited to this
No. The replenishment rate of the processing solution is 10 cc / 4 or less.
It is preferable, but more preferably 5cc / 4 cut or less.
The effect appears greatly. As used in the developer of the present invention
Corbic acid or a derivative thereof is disclosed in JP-A-5-165.
No. 161 and the compound represented by the general formula (I)
Compound Examples I-1 to I-8, II-9 to II- described herein
12 is particularly preferred. Used in the developer used in the present invention
Ascorbic acids are endiol type (Endiol),
Enaminol (Endaminol), Endamine (Endiam
in), thiol-enol (Thiol-Enol) and enami
Enthiol type (Enamin-Thiol) is generally used as a compound.
Are known. Examples of these compounds are described in U.S. Pat.
88,549, and JP-A-62-237443.
It is listed. The synthesis method of these ascorbic acids is also good.
It is well known, for example, co-authored by Tsuguo Nomura and Hirohisa Omura,
Kuton's Chemistry "(Uchida Lao Tsuruho Shinsha 1969)
Has been stated. Ascorbic acids used in the present invention
Is an alkali such as lithium, sodium, potassium, etc.
It can also be used in the form of a metal salt. These ascorbic acids
Are from 1 to 100 g per liter of developer, preferably
It is preferable to use 5 to 80 g. In the present invention, especially together with ascorbic acids
1-phenyl-3-pyrazolidones or p-aminophen
It is preferable to use phenols in combination. 3 used in the present invention
1-phenyl-3 as a pyrazolidone-based developing agent
-Pyrazolidone, 1-phenyl-4,4-dimethyl-3
-Pyrazolidone, 1-phenyl-4-methyl-4-hydride
Roxymethyl-3-pyrazolidone, 1-phenyl-4,
4-dihydroxymethyl-3-pyrazolidone, 1-fe
Nyl-5-methyl-3-pyrazolidone, 1-p-amino
Phenyl-4,4-dimethyl-3-pyrazolidone, 1-
p-tolyl-4,4-dimethyl-3-pyrazolidone, 1
-P-tolyl-4-methyl-4-hydroxymethyl-3
-Pyrazolidone and the like. Developing agent is usually 0.001
Used in an amount of from mol / l to 1.2 mol / l
Preferably. P-Aminophenol used in the present invention
N-methyl-p-aminophenol as a developing agent
, P-aminophenol, N- (β-hydroxyethyl
) -P-aminophenol, N- (4-hydroxyphenyl)
Enyl) glycine, 2-methyl-p-aminophenol
And p-benzylaminophenol, among which
N-methyl-p-aminophenol is also preferred. The alkaline agent used for setting the pH includes
Sodium hydroxide, potassium hydroxide, sodium carbonate,
Potassium carbonate, tertiary sodium phosphate, tertiary potassium phosphate
PH adjusters such as um. Used in the developer of the present invention
Sodium sulfite, sulfite
Potassium, lithium sulfite, ammonium sulfite, bisulfite
Examples include sodium sulfate and potassium metabisulfite. Sub
Sulfate is 0.01 mol / l or more, especially 0.02 mol
Or more per liter. The upper limit is 2.5 mol
Per liter is preferred. In addition, L.F.A.
Ison, Photographic Processing Chemis
Tree, 22 of the Focal Press (1966)
6-229, U.S. Pat. No. 2,193,015;
2,592,364, JP-A-48-64933, etc.
May be used. Generally, a pH buffer or the like is used in the developer.
Use boric acid compounds (eg boric acid, borax)
But in the developer containing ascorbic acids of the present invention.
Preferably does not substantially contain a boric acid compound.
Ascorbic acid-containing developer contains boric acid compound
And the packaging material of the present invention in combination with the packaging material having a low oxygen permeability.
The effect of the invention cannot be obtained. Boration in the system of the invention
The relationship between the presence or absence of the compound and the effect is completely unexpected.
Was. The method for preparing the treating agent used in the present invention includes
JP-A-61-177132, JP-A-3-134666
And the method described in JP-A-3-67258
Can be. Replenishing method of developer as processing method of the present invention
As the method described in Japanese Patent Application No. 4-54131.
be able to. Dry to Dry for less than 100 seconds
To avoid development unevenness peculiar to rapid processing.
Described in JP-A-63-151943.
Roller made of such rubber as the roller at the exit of the developing tank
It is applied to Japanese Patent Application Laid-Open No. 63-151944.
Stir the developer in the developer tank as described.
The discharge flow rate to 10 m / min or more.
It is described in JP-A-63-264758.
In this way, at least during the development process,
More preferably. The method for developing a light-sensitive material of the present invention includes
The true photosensitive material is not particularly limited, and is a general black and white photosensitive material.
Fees are mainly used. Especially photographic materials for laser light sources
And printing photographic materials, medical X-ray photographic materials,
Medical indirect X-ray material, CRT image recording material,
It can also be used for photographic film, general photography materials, etc.
You. Hereinafter, the present invention will be described in detail with reference to examples. [0073] 【Example】 Example 1 Preparation of (100) Tabular emulsion A 1582 ml of an aqueous gelatin solution (gelatin-1) was placed in a reaction vessel.
(Deionized alcohol with a methionine content of about 40 μmol / g)
Potash-processed bone gelatin) 19.5 g, HNO_Three1N solution7.
8 ml, pH 4.3), NaCl-1 solution (100 ml
13 ml of NaCl (containing 10 g of NaCl therein),
While maintaining the temperature at 0 ° C., the Ag-1 solution (AgNO
_Three20 g) and solution X-1 (NaCl in 100 ml).
7.05 g) in 15.6 ml at 62.4 ml / min
Simultaneous addition was performed. After stirring for 3 minutes, the Ag-2 solution (1
AgNO in 00ml_Three2 g) and X-2 solution (100
(containing 1.4 g of KBr in ml) at 80.6 ml / min.
8.2 ml was mixed simultaneously. After stirring for 3 minutes, Ag-
Solution 1 and solution X-1 at 62.4 ml / min.
It was mixed and added. After stirring for 2 minutes, aqueous gelatin solution 20
3 ml (gelatin-113 g, NaCl 1.3 g, Table 1)
(Including 1N NaOH solution) to bring the pH to
After the Cl was adjusted to 1.8, the temperature was raised to 75 ° C.
And then aged for 42 minutes. AgCl fine particle milk
Agent (average particle diameter 0.1 μm) 2.68 × 10^-2Mole
/ Min at a rate of AgCl addition of 20 min / min. 1 after addition
After aging for 0 minutes, a precipitant was added and the temperature was lowered to 35 ° C.
And washed down. Add an aqueous gelatin solution and p
H was adjusted to 6.0. Transmission electron microscope of a replica of the particle
A microscopic photograph image (hereinafter referred to as TEM) was observed. Got
The emulsion contains 0.44 mol% of AgBr based on silver
It was a high silver chloride (100) tabular grain. Shape characteristics of the particles
The sex values were as follows: (Total projected area / total of tabular grains having an aspect ratio greater than 1)
AgX particle projected area sum) × 100 = a₁= 90% (Average aspect ratio of tabular grains (average diameter / average thickness)
Sa)) = a_Two= 9.3 (Average diameter of tabular grains) = a_Three= 1.67 μm (Average thickness) = a_Four= 0.18 μm Preparation of (111) Tabular Emulsion B Silver chloride tabular grains were prepared as follows. Solution (1) 30 g of inert gelatin Crystal wall control agent A 0.8g [0075] Embedded image [0076] NaCl 4g H_TwoO 1750cc Solution (2) AgNO_Three       7.6g H_Two30cc with O Solution (3) NaCl 2.8g H_Two30cc with O Solution (4) AgNO_Three      24.5g H_Two96cc with O Solution (5) NaCl 0.3 g H_Two65cc with O Solution (6) AgNO_Three     101.9g H_Two400cc with O Solution (7) NaCl 37.6g H_Two400cc with O While stirring the solution (1) maintained at 35 ° C.,
And simultaneously add the solution (2) and the solution (3) over 1 minute,
The temperature of the solution was raised to 50 ° C. over 15 minutes. this
At this point, grains corresponding to about 5.7% of the total silver were formed.
Was. Next, the solution (4) and the solution (5) were mixed for 24 minutes.
And then add solution (6) and solution (7) for 40 minutes
And a silver chloride tabular emulsion was obtained. emulsion
Was washed and desalted with a sedimentation method, and then 30 g of gelatin and H_Two
O, add 2.0 g of phenoxyethanol and increase
0.8g sodium polystyrene sulfonate as a thickener
And redispersed with caustic soda to pH 6.0.
did. The emulsion thus obtained comprises:₁= 90%, a_Three=
1.55 μm, a_Four= 0.18 μm, a_Two= 8.6, yen
The (111) plane with a 19% variation coefficient of the equivalent projected area diameter
This is a silver chloride tabular emulsion. Preparation of Tabular Grain C 6.0 g of potassium bromide in 1 liter of water, average molecular weight 1
Add 75,000 g of low molecular weight gelatin at 55 ° C.
37cc of silver nitrate aqueous solution (nitric acid
Aqueous solution 3 containing 4.00 g of silver) and 5.9 g of potassium bromide
8 cc was added in 37 seconds by the double jet method. One
After adding 18.6 g of gelatin, the temperature was raised to 70 ° C.
89 cc of silver nitrate aqueous solution (9.80 g of silver nitrate) for 22 minutes
And added. Here, 7 cc of 25% ammonia aqueous solution
Addition, physical aging at the same temperature for 10 minutes, then 10
6.5 cc of a 0% acetic acid solution was added. Followed by silver nitrate 1
An aqueous solution of 53 g and an aqueous solution of potassium bromide were pAg8.5.
35 minutes by control double jet method while keeping
And added. Next, 2N potassium thiocyanate solution 1
5 cc was added. Physical ripening at the same temperature for 5 minutes
Thereafter, the temperature was lowered to 35 ° C. a₁= 95%, average projection plane
Stack diameter a_Three= 1.50 μm, thickness a_Four= 0.185μ
m, average aspect ratio a_Two= 8.1, variation coefficient of diameter 1
8.5% monodispersed pure silver bromide tabular grains were obtained. After this,
Soluble salts were removed by sedimentation. Temperature rise to 40 ° C again
30 g of gelatin and 2.35 g of phenoxyethanol
And sodium polystyrene sulfonate as thickener
0.8 g was added, and pH5 with sodium hydroxide solution and silver nitrate solution.
90 and pAg 8.00. Preparation of Tabular Grains D and E In adjusting the tabular grains C, the pAg was maintained at 8.5.
Odor when growing by the control double jet method
Mixed solution of potassium bromide and potassium chloride
Liquid, and the particle shape such as aspect ratio and particle size is flat
Silver chloride content is 17% so that it is almost the same as
Silver chlorobromide with (111) plane as the main plane
Plate emulsions D and E were prepared. The other conditions are as follows.
The conditions were the same as in the production. Preparation of silver halide emulsion F Dissolve 32 g of gelatin in 1 liter of water and heat to 53 ° C
0.3 g potassium bromide, 5 sodium chloride
g and compound [I] [0081] Embedded image After charging 46 mg, contains 80 g of silver nitrate
444 ml of aqueous solution, 45 g of potassium bromide and sodium chloride
452 ml of an aqueous solution containing 5.5 g of water
Over about 20 minutes and then add 80 g of silver nitrate
Solution containing 400 ml of potassium bromide, 46.4 g of sodium chloride
5.7 g of thorium and hexachloroiridium (III) acid
Potassium (10^-7(Mol / mol silver)
Is added by the double jet method over about 25 minutes.
With an average particle size (projected area diameter) of 0.34 μm
Rectangular monodisperse silver chlorobromide grains (coefficient of variation of projected area diameter 10
%). After desalting this emulsion by a coagulation method,
62 g of tin and 1.75 g of phenoxyethanol were added,
Adjusted to pH 6.5 and pAg 8.5. Chemical sensitization The particles A to F prepared as described above are heated to 60 ° C. while stirring.
Chemical sensitization was performed while keeping it. First, thiosulfonic acid
Compound-I was added in an amount of 10 per mole of silver halide.^-FourMolar addition
Then, AgBr fine particles having a diameter of 0.10 μm were added to the total silver amount.
1.0 mol% with respect to
1 × 10^-6Mol / mol Ag and keep it for 22 minutes
And carried out reduction sensitization. Next, 4-hydroxy-6
Methyl-1,3,3a, 7-tetraazaindene is 3 ×
10^-FourMol / mol Ag and sensitizing dyes-1 and 2, respectively.
Added. Further calcium chloride was added. Continue
Sodium osulphate (6 × 10^-6Mol / mol Ag) and
Ren compound-I (4 × 10^-6Mol / mol Ag)
Was. Furthermore, chloroauric acid 1 × 10^-FiveAg / mol Ag / mol
Potassium ocyanate 3.0 × 10^-3Add mol / mol Ag
And cooled to 35 ° C. after 40 minutes. Thus the tone of the emulsion
(Chemical ripening) was completed. [0085] Embedded image(Preparation of emulsion coating layer) Milk subjected to chemical sensitization
Add the following chemicals per mole of silver halide
This was used as an emulsion coating solution.   ・ Gelatin (including gelatin in emulsion) 111 g   ・ Dextran (average molecular weight 39,000) 21.5 g   ・ Sodium polyacrylate (average molecular weight 400,000) 5.1 g   ・ Sodium polystyrene sulfonate (average molecular weight 600,000) 1.2 g   ・ Hardener 1,2-bis (vinylsulfonylacetamide) ethane             Adjust the amount of addition so that the swelling ratio is 230%   Compound-I 42.1 mg   ・ Compound-II 10.3 g   ・ Compound-III 0.11g   ・ Compound-IV 8.5 mg   ・ Compound-V 0.43g   ・ Compound-VI 0.004g   ・ Compound-VII 0.1 g   ・ Compound-VIII 0.1 g     Adjusted to pH 6.1 with NaOH [0087] Embedded image [0088] Embedded imageTo the above coating solution, the ultraviolet absorbing dyes -I to
III is 10mg / m per side^TwoDye emulsification so that
A sample to which the substance A was added and a sample to which no substance A was added were prepared. [0090] Embedded image (Preparation of Dye Emulsion A) Dye-I to II
20 g each, and 62.degree.
8 g, -2.8 g of -II and 333 g of ethyl acetate in 60
Dissolved at ° C. Next, sodium dodecyl sulfonate
Add 65cc of 5% aqueous solution, 94g of gelatin and 581cc of water
The mixture was emulsified and dispersed with a dissolver at 60 ° C. for 30 minutes.
Next, 2 g of the following compound-VI and 6 l of water were added.
Then, the temperature was lowered to 40 ° C. Next, Asahi Kasei ultrafiltration laboratory
Use Joule ACP1050 until the total weight is 2 kg.
, And 1 g of the compound -VI was added thereto to obtain a dye emulsion A.
did. [0092] Embedded image (Preparation of Surface Protective Layer Coating Solution) Surface Protective Layer Coating
A cloth solution was prepared such that each component had the following coating amount.   ・ Gelatin 0.780g / m^Two   ・ Sodium polyacrylate (average molecular weight 400,000) 0.035   ・ Sodium polystyrene sulfonate (average molecular weight 600,000) 0.0012   ・ Polymethyl methacrylate (average particle size: 3.7 μm) 0.072   ・ Coating aid-I 0.020   ・ Coating aid-II 0.037   ・ Coating aid-III 0.0080   ・ Coating aid-IV 0.0032   ・ Coating aid-V 0.0025   Compound-VII 0.0022   ・ Proxel 0.0010     (Adjust to pH 6.8 with NaOH) [0094] Embedded image (Preparation of Support A) Biaxially stretched thickness 1
Coated on 75 μm polyethylene terephthalate film
Perform Rona discharge and apply the first undercoating liquid with the following composition
The amount is 4.9cc / m^TwoTo become a wire converter
And dried at 185 ° C. for 1 minute. Next opposite
The first undercoat layer was similarly provided on the surface. Polyet used
0.06 wt% of Dye-IV is contained in Tylene terephthalate,
Using a dye-V containing 0.06 wt%
Was. [0096] Embedded image [0097]   ・ Butadiene-styrene copolymer latex solution     (40% solids butadiene / styrene weight ratio = 31/69) 158 cc   -Sodium 2,4-dichloro-6-hydroxy-s-triazine     41 cc of 4% salt solution   ・ Distilled water 801 cc * In the latex solution, the following compound as an emulsifying dispersant
0.4wt% based on latex solids [0098] Embedded image (Preparation of Support B)
In the same manner as above but without Dye-V
B was prepared. [0100] Embedded image (Preparation of photographic material) Prepared as described above
Simultaneous combination of previous emulsion layer and surface protective layer on support
Coating was performed on both sides by an extrusion method. Silver applied per side
Is 1.75 g / m^TwoAnd In this way, the samples in Table 1 were made.
Made. [0102] [Table 1] (Evaluation of Photographic Performance) Du Pont
Uses Ultravision First Detail (UV)
Then, adhere to both sides and expose for 0.05 seconds from both sides.
And subjected to X-ray sensitometry. Adjust exposure
Is to change the distance between the X-ray tube and the cassette.
Went better. After exposure, automatic development with the following developer and fixer
Machine processing. (Processing) Automatic developing machine: CEPROS manufactured by Fuji Film Co., Ltd.
-Modified M and incorporated heat roller in drying zone
In this case, the transfer speed was increased to 30 seconds for Dry to Dry. Preparation of concentrate <Developer>   Parts agent A     330 g of potassium hydroxide     Potassium sulfite 630 g     Sodium sulfite 255 g     90 g of potassium carbonate     45 g boric acid     180 g of diethylene glycol     30 g of diethylenetriaminepentaacetic acid     1- (N, N-diethylamine) ethyl-5-mercapto       0.75 g of tetrazole     Hydroquinone 450 g     4-hydroxymethyl-4-methyl-1-phenyl-3-       Pyrazolidone 60 g     4125 ml with water [0105]   Parts agent B     Diethylene glycol 525 g     3,3 'dithiobishydrocinnamic acid 3 g     Glacial acetic acid 102.6g     3.75 g of 2-nitroindazole     14.5 g of 1-phenyl-3-pyrazolidone     750 ml with water [0106]   Parts agent C     Glutaraldehyde (50wt / wt%) 150 g     Potassium bromide 15 g     Potassium metabisulfite 105 g     750 ml with water [0107] <Fixer>     Ammonium thiosulfate (70 wt / vol%) 3000 ml     Ethylenediaminetetraacetic acid disodium dihydrate 0.45 g     Sodium sulfite 225 g     Boric acid 60 g     1- (N, N-diethylamine) -ethyl-5-mercap       Totetrazole 15 g     48 g of tartaric acid     Glacial acetic acid 675 g     225 g of sodium hydroxide     Sulfuric acid (36N) 58.5 g     Aluminum sulfate 150 g     6000 ml with water       pH 4.68 (Preparation of processing solution)
Was filled for each part. This container is a parts agent
A, B, C partial containers are connected together by the container itself
Is what is being done. In addition, the fixer concentration is the same
The container was filled. First, as a starter in the developing tank,
Aqueous solution 30 containing 54 g of acetic acid and 55.5 g of potassium bromide
0 ml was added. Turn the processing agent container upside down
Perforated blade of the processing liquid stock tank mounted on the side of
To break the sealing film of the cap,
The agent was filled in a stock tank. Each of these treatments
In the developing tank and fixing tank of the automatic processing machine,
The pump installed on the machine was activated and filled. Also,
Each time 8 pieces of photosensitive material are processed in terms of 4-cut size,
At the same time, the undiluted solution of the processing agent and water are mixed and
Filled. [0109] Developer Parts liquid A 51 ml Parts liquid B 10 ml Parts liquid C 10 ml 125 ml of water pH 10.50 Fixer 80 ml concentrate 120 ml of water pH 4.62 The washing tank was filled with tap water. In addition, as a scale inhibitor, actinomycetes were averaged.
Supported on pearlite having a particle size of 100 μm and an average pore size of 3 μm
0.4 g of the soaked polyethylene bottle (bottle opening
Is covered with a 300 mesh nylon cloth.
And the distribution of bacteria is possible).
Two of them are placed at the bottom of the washing tank, and one is
Submerged at the bottom of the tank (0.2 liter)
Was. The invention in the evaluation of sensitometryUse forSensitive material
Showed good results. Measurement of sharpness (MTF) M in combination with the above-mentioned screen and automatic processor processing
TF was measured. 30μm × 500μm aperture
MTF value when the spatial frequency is 1.0 cycle / mm
The optical density was evaluated at a portion where the optical density was 1.0. Table 2 shows the results. The present inventionUse forSensitive material
Shows excellent sharpness. [0113] [Table 2] Embodiment 2 Exactly the same as the light-sensitive material prepared in Example 1, except that
PEN (Polyethylene Naf) with the support adjusted as follows
When changed to tarate support, after coating,
Sometimes, the curl is small and the emulsion layer is coated on both sides.
Image blur due to crossover light
The photosensitive material could be made. Support A: commercially available polye
After melting styrene-2,6-naphthalate at 300 ° C.,
Extrude from T-die and stretch longitudinally 3.3 times at 140 ° C
Then, a 3.3-fold transverse stretching is performed, and further at 250 ° C.
Heat fixing was performed for 6 seconds to obtain a 140 μm film. Support
B: Polyethylene terephthalate and polyethylene in advance
The pellets of len-2,6-naphthalate are mixed at 150 ° C for 4 hours.
After vacuum drying for 280 hours using a twin screw extruder.
After kneading and extruding at ° C., the mixture was pelletized. This peret
The film was formed in the same manner as for the support B. Corona discharge on each support
Was done. Corona discharge treatment is Pillar solid stay
30cm width support using Tocorona treatment machine 6KVA model
At 20 m / min. At this time, read the current and voltage
The object to be treated is 0.375 KV · A · min / m^Twoof
Processing has been done. The discharge frequency during processing is 9.6 KHz,
The gap clearance between the electrode and the dielectric roll is 1.6
mm. Undercoating is performed in the same manner as in the support of Example 1.
Performed in Embodiment 3 The photographic light-sensitive materials prepared in Examples 1 and 2 were developed as follows.
The treatment was performed with the liquid. [Automatic processor processing] Fuji Photo Film is an automatic processor.
Fuji X Ray Processor CEPROS-M
The drive shaft so that the total processing time is 30 seconds
Was. The drying blow temperature was set at 55 ° C. Developer formulation   Part A     Potassium hydroxide 18.0 g     Potassium sulfite 30.0 g     Sodium carbonate 30.0 g     Diethylene glycol 10.0 g     2.0 g of diethylenetriaminepentaacetic acid     1- (N, N-diethylamino) ethyl-5-mercapto       0.1 g of tetrazole     L-ascorbic acid 43.2 g     4-hydroxymethyl-4-methyl-1-phenyl-3-       Pyrazolidone 2.0 g     300 ml with water [0116]   PartB     Triethylene glycol 45.0 g     3,3'-dithiobishydrocinnamic acid 0.2 g     Glacial acetic acid 5.0 g     0.3 g of 5-nitroindazole     3.5 g of 1-phenyl-3-pyrazolidone     60 ml with water [0117]   Part C     Glutaraldehyde (50%) 10.0 g     Potassium bromide 4.0 g     Potassium metabisulfite 10.0 g     50 ml with water PartA 300ml, PartB 60ml and PartC 50m
l to 1 liter with water and adjust to pH 10.90.
Let Part A 4.50 liters, Part B 0.90 li
Toru, Part C 0.75 liter Fujifilm
1.5 liters of liquid used in CE-DF1 bottle manufactured by Corporation
Filled for use. Development starter Acetic acid was added to the replenisher to adjust the pH to 10.20.
Was used as a development start solution. As the fixing solution, Fuji Photo Film Co., Ltd.
CE-F1 manufactured by the Company was used. Development temperature 35 ° C Fixing temperature 35 ° C Drying temperature 55 ° C Replenishment amount (both developer and fixer) 25ml / 10 × 21a
Inch (325 ml / m^Two) Each sample 10 × 12 inch size
Good performance is obtained by running 600 films.
Was done. The present inventionUse forThe combination of photosensitive material and developer
Good with no change in sensitivity of the running liquid at the start
It turns out. Embodiment 4 The light-sensitive materials of the present invention obtained in Examples 1 and 2 were
No. 804, using X-ray exposure
When an image was formed, a good X-ray image was formed.
Was confirmed.

Continuation of the front page (56) References JP-A-4-161947 (JP, A) JP-A-63-15238 (JP, A) JP-A-4-256946 (JP, A) JP-A-8-29919 (JP) JP-A-6-202282 (JP, A) JP-A-6-211813 (JP, A) JP-A-6-11804 (JP, A) International Publication 93/001521 (WO, A1) (58) Survey Field (Int.Cl. ⁷ , DB name) G03C 1/035 G03C 1/815 G03C 5/17 G21K 4/00

Claims (1)

(57) Claims: 1. A silver chloride-containing tabular grain emulsion in which at least 50% of the total projected area has a silver chloride content of 20% or more and an average aspect ratio of 2 or more, and an ultraviolet absorber Contains
The silver halide photographic material has an emission peak in the ultraviolet region.
Especially in combination with an intensifying X-ray absorbing fluorescent intensifying screen.
The image forming method to be described.