JP3492264B2 - Slow release nitrogen fertilizer using waste cocoons - Google Patents
Slow release nitrogen fertilizer using waste cocoonsInfo
- Publication number
- JP3492264B2 JP3492264B2 JP34273199A JP34273199A JP3492264B2 JP 3492264 B2 JP3492264 B2 JP 3492264B2 JP 34273199 A JP34273199 A JP 34273199A JP 34273199 A JP34273199 A JP 34273199A JP 3492264 B2 JP3492264 B2 JP 3492264B2
- Authority
- JP
- Japan
- Prior art keywords
- waste
- cocoons
- slow
- nitrogen fertilizer
- fertilizer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000002699 waste material Substances 0.000 title claims description 16
- 239000000618 nitrogen fertilizer Substances 0.000 title claims description 7
- 238000000034 method Methods 0.000 claims description 11
- 239000007864 aqueous solution Substances 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 8
- 238000007654 immersion Methods 0.000 claims description 4
- 239000011260 aqueous acid Substances 0.000 claims description 2
- 239000000243 solution Substances 0.000 claims description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 18
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 16
- 239000002689 soil Substances 0.000 description 15
- 239000003337 fertilizer Substances 0.000 description 13
- 238000012360 testing method Methods 0.000 description 10
- 238000000354 decomposition reaction Methods 0.000 description 9
- 229910052757 nitrogen Inorganic materials 0.000 description 9
- 230000000694 effects Effects 0.000 description 5
- 108090000623 proteins and genes Proteins 0.000 description 4
- 102000004169 proteins and genes Human genes 0.000 description 4
- 108010022355 Fibroins Proteins 0.000 description 3
- 235000008585 Pinus thunbergii Nutrition 0.000 description 3
- 241000218686 Pinus thunbergii Species 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 230000004720 fertilization Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 239000010902 straw Substances 0.000 description 2
- 238000004383 yellowing Methods 0.000 description 2
- 235000005638 Austrian pine Nutrition 0.000 description 1
- 235000009024 Ceanothus sanguineus Nutrition 0.000 description 1
- 229920002101 Chitin Polymers 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 240000003553 Leptospermum scoparium Species 0.000 description 1
- 235000015459 Lycium barbarum Nutrition 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 235000008565 Pinus banksiana Nutrition 0.000 description 1
- 235000013264 Pinus jeffreyi Nutrition 0.000 description 1
- 235000008578 Pinus strobus Nutrition 0.000 description 1
- 235000014030 Podocarpus spicatus Nutrition 0.000 description 1
- MMDJDBSEMBIJBB-UHFFFAOYSA-N [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] Chemical compound [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] MMDJDBSEMBIJBB-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000033558 biomineral tissue development Effects 0.000 description 1
- 238000009933 burial Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000010413 gardening Methods 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 235000017985 rocky mountain lodgepole pine Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/20—Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
Landscapes
- Fertilizers (AREA)
- Fertilizing (AREA)
Description
【0001】[0001]
【発明の属する技術分野】本発明は窒素肥料及びその施
肥方法に関する。TECHNICAL FIELD The present invention relates to a nitrogen fertilizer and a method for applying the same.
【0002】[0002]
【従来の技術】木本類による緑化工においては、頻繁な
施肥作業を予定することは現実的でない。そのため従来
は、木本類を植栽するに際して、土壌中に予め多量の肥
料を埋設しておくか、或いは、肥料に樹脂をコーティン
グして緩効性とした肥料が用いられてきた。2. Description of the Related Art It is not realistic to plan frequent fertilization in tree planting using wood. Therefore, conventionally, when planting woody plants, a large amount of fertilizer has been buried in the soil in advance, or a fertilizer having a slow-release effect by coating the fertilizer with a resin has been used.
【0003】[0003]
【発明が解決しようとする課題】しかし、一般の窒素系
無機質肥料を一度に多施することは、濃度障害及び硝酸
態窒素(NO3 −−N)の流亡による肥料の損失や環境
(水質)汚染などの理由から望ましくない。[SUMMARY OF THE INVENTION However, the multi-Hodokosuru at a time generally of nitrogen-based mineral fertilizers, concentration disorders and nitrate nitrogen (NO 3 - -N) runoff due fertilizer losses and environmental (water) Not desirable for reasons such as contamination.
【0004】また、樹脂をコーティングしたものは、コ
ストが大幅に上昇する上、樹脂の環境に対する影響が心
配され、緑化という環境保護行為に反するものとなるお
それがある。[0004] Further, the resin-coated product significantly increases the cost, and there is a concern that the resin may affect the environment, which may be contrary to the environmental protection act of greening.
【0005】本発明はこのような課題を解決するために
成されたものであり、その目的とするところは、自然素
材のみを用いた緩効性窒素肥料を提供することにある。The present invention has been made to solve such problems, and an object thereof is to provide a slow-release nitrogen fertilizer using only natural materials.
【0006】[0006]
【課題を解決するための手段及び効果】上記課題を解決
するために成された本発明に係る施肥方法は、酸水溶液
中に浸漬する処理を施した屑繭を土中に埋設することを
特徴とするものである。Means and Effects for Solving the Problems The fertilizing method according to the present invention made to solve the above problems is an aqueous acid solution.
It is characterized in that waste cocoons that have been immersed therein are buried in the soil.
【0007】屑繭は絹タンパク質から構成されるが、タ
ンパク質が土中で分解することにより無機態窒素(アン
モニア、硝酸等)となり、肥効を表す。なお、絹タンパ
ク質は約15%程度の窒素を含有している。The cocoon is composed of silk protein, which decomposes in the soil to become inorganic nitrogen (ammonia, nitric acid, etc.) and exhibits a fertilizing effect. Silk protein contains about 15% nitrogen.
【0008】ここで、絹タンパク質の土中における分解
速度は遅く、特にその主成分であるフィブロインは高い
結晶性のために分解速度が非常に遅い。従って、屑繭を
土中に埋設しておくことにより、緩効性窒素肥料として
非常に長期に亘り濃度障害のない持続的な窒素供給が可
能となる。[0008] Here, the decomposition rate of silk protein in soil is slow, and in particular, fibroin, which is the main component thereof, has a very low decomposition rate due to its high crystallinity. Therefore, by burying waste cocoons in the soil, it becomes possible to provide a continuous nitrogen supply as a slow-release nitrogen fertilizer for a very long time without concentration disturbance.
【0009】また、屑繭を蛹と共に埋設してもよい。蛹
はタンパク質及びキチンを含んでおり、これも分解する
ことにより無機態窒素となる。蛹は繭(フィブロイン)
よりもかなり分解速度が高いため、それらを一緒に埋設
することにより速効・緩効双方の効果を同時に得ること
ができる。Further, the waste cocoons may be embedded together with the pupae. Pupae contain proteins and chitin, which also decompose to inorganic nitrogen. Chrysalis are cocoons (fibroin)
Since the decomposition rate is much higher than that, it is possible to obtain both fast-acting and slow-acting effects by embedding them together.
【0010】絹糸生産の際に発生する屑繭(及び蛹)
は、絹繊維業界におけるいわゆる産業廃棄物であり、廃
棄物処理場の設置がますます困難となりつつある現在、
その処理が大きな問題となっている。本発明は、このよ
うに廃棄物として扱われるものを原料として再利用する
ものであり、この点でも環境保護に寄与するものであ
る。Waste cocoons (and pupae) generated during silk production
Is a so-called industrial waste in the silk fiber industry, and it is becoming more and more difficult to set up a waste treatment plant,
The processing is a big problem. The present invention reuses the material treated as waste as a raw material, and also contributes to environmental protection in this respect.
【0011】 なお、土中に埋設する前に、屑繭を酸水
溶液中に浸漬するという処理を施す。この処理により、
繭の土中における分解速度が高まることから、処理に際
しての条件(酸濃度、温度、浸漬時間等)を適宜調節す
ることにより、所望の緩効性能(或いは速効性能)を実
現することができるようになる。Before burying the cocoon in the soil, a treatment of immersing the waste cocoon in an acid aqueous solution is performed . By this process,
Since the rate of decomposition of cocoon in soil increases, it is possible to achieve the desired slow-release performance (or quick-release performance) by appropriately adjusting the conditions (acid concentration, temperature, immersion time, etc.) during the treatment. become.
【0012】 土中に埋設するに際しては、酸水溶液中
に浸漬する処理を施した屑繭(又は、蛹入り屑繭)を予
めシート状にしておくことにより取り扱いが非常に簡単
となり、植林等の際の施肥能率が大幅に向上する。When burying in the soil, in an acid aqueous solution
By preliminarily making a sheet-shaped waste cocoon (or pupae-containing waste cocoon) that has been soaked in, the handling becomes very easy, and the fertilization efficiency at the time of tree planting etc. is greatly improved.
【0013】土壌中における屑繭及び蛹の分解速度を試
験した結果を図1に示す。その試験条件は次の通りであ
る。
試験土 :京都府立大学附属農場の土壌(沖積水田土壌)
試験温度:30℃(ただし、下記eのみ25℃)
試験物 :a.繭のみ
b.蛹のみ
c.1M塩酸処理した繭のみ
(97℃に保持した1M塩酸水溶液中に60分浸漬)
d.0.2M塩酸処理した繭のみ
(97℃に保持した0.2M塩酸水溶液中に60分浸漬)
e.粉末化屑繭
(特願平11-229857に記載の方法で製造したフィブロイン粉末
)
試験方法:試験土を瓶に入れ、その中に試験物を埋設し
て、畑状態で試験温度に保持した。適宜時点で土壌に含
まれる無機態窒素量を測定し、分解量(窒素無機化率)
を算出した結果が図1である。FIG. 1 shows the results of testing the decomposition rate of waste cocoons and pupae in soil. The test conditions are as follows. Test soil: Soil from Kyoto Prefectural University farm (alluvial paddy soil) Test temperature: 30 ° C (however, only e below 25 ° C) Test product: a. Cocoon only b. Pupae only c. Cocoons treated with 1M hydrochloric acid only (immersion in 1M hydrochloric acid aqueous solution kept at 97 ° C. for 60 minutes) d. Cocoons treated with 0.2 M hydrochloric acid only (immersion in 0.2 M hydrochloric acid aqueous solution kept at 97 ° C. for 60 minutes) e. Powdered cocoon (Fibroin powder produced by the method described in Japanese Patent Application No. 11-229857) Test method: A test soil was put in a bottle, the test material was embedded in the bottle, and the test temperature was maintained in a field state. Measure the amount of inorganic nitrogen contained in the soil at an appropriate time and decompose it (nitrogen mineralization rate)
The result of the calculation is shown in FIG.
【0014】図1に示されるように、繭のみの場合、分
解速度は非常に遅く約200日でも20%が分解するに
過ぎない。すなわち、この試験条件下では、すべての窒
素が無機化するにはおおよそ3年程度かかることから、
繭のみの埋設は、緑化工用緩効性肥料として非常に適し
たものとなる。As shown in FIG. 1, in the case of only cocoons, the decomposition rate is very slow, and only about 20% decomposes even after about 200 days. That is, under this test condition, it takes about 3 years for all nitrogen to be mineralized,
The burial of cocoons alone is very suitable as a slow-release fertilizer for revegetation.
【0015】一方、蛹のみの場合、数日でほとんど分解
する。従って、屑繭と蛹とを組み合わせることにより、
速効性(初期成育に有効)と緩効性の双方の性能を持つ
肥料とすることができる。On the other hand, in the case of only pupae, it almost decomposes within a few days. Therefore, by combining scrap cocoons and pupae,
The fertilizer can have both fast-acting (effective for initial growth) and slow-acting properties.
【0016】塩酸水溶液処理による分解速度向上効果も
図1に明瞭に現れている。そして、塩酸濃度を変化させ
ることにより、分解速度を調節することができることも
判明した。従って、事前に適宜の塩酸水溶液処理を施し
ておくことにより、任意の速度の緩効性肥料を製造する
ことができる。The effect of improving the decomposition rate by the treatment with the hydrochloric acid aqueous solution is clearly shown in FIG. It was also found that the decomposition rate can be adjusted by changing the hydrochloric acid concentration. Therefore, a slow-release fertilizer at an arbitrary rate can be produced by subjecting it to an appropriate hydrochloric acid aqueous solution treatment in advance.
【0017】例えば畑等には、蛹の割合を増やす、或い
は、予め酸水溶液処理を施しておくことにより、適した
肥料を調製することができる。なお、事前の酸水溶液処
理には、上記の塩酸以外の強酸(例えば硫酸)を用いて
もよい。For example, in a field or the like, a suitable fertilizer can be prepared by increasing the proportion of pupae or by treating with an acid aqueous solution in advance. Note that a strong acid other than the above-mentioned hydrochloric acid (for example, sulfuric acid) may be used for the previous acid aqueous solution treatment.
【0018】[0018]
【発明の実施の形態】本発明に係る施肥方法の一つの実
施形態を図2に示す。これは、クロマツを植栽するため
の施工例である。すなわち、最初にわら束を置いた後、
25cm間隔にわらを層状に三段埋設し、その二段目を
設置する際に本発明に係る屑繭を置く。その結果、屑繭
は地表から約30cm下に位置する。ここに40cm間
隔でクロマツを植栽する。屑繭の埋設量は、クロマツ1
本あたり250g程度とする。本工法実施後半年で、化
成肥料による従来法に比べてクロマツの状態に明確な改
善が見られた。すなわち、従来法では窒素不足による葉
の黄化現象が見られたのに対し、本施肥法では黄化現象
は確認されず、成長量自体も優れていた。BEST MODE FOR CARRYING OUT THE INVENTION One embodiment of a fertilizing method according to the present invention is shown in FIG. This is a construction example for planting Japanese black pine. That is, after first putting a bunch of straw,
Straws are embedded in layers at 25 cm intervals in three layers, and the waste cocoons according to the present invention are placed when the second layer is installed. As a result, the cocoon is located about 30 cm below the surface of the earth. Black pine is planted here at 40 cm intervals. The amount of waste cocoons to be buried is 1
It is about 250 g per book. In the second half of the implementation of this method, a clear improvement was observed in the state of Japanese black pine compared to the conventional method using chemical fertilizer. That is, while the yellowing phenomenon of leaves due to lack of nitrogen was observed in the conventional method, the yellowing phenomenon was not confirmed in this fertilization method, and the growth amount itself was excellent.
【0019】なお、本発明に係る施肥方法或いは肥料
は、大規模な緑化工や植林ばかりではなく、茶樹、果樹
等の栽培或いは小規模な園芸にも適用することができる
のはもちろんである。The fertilizer application method or fertilizer according to the present invention can be applied not only to large-scale planting and tree planting, but also to cultivation of tea trees, fruit trees and the like or small-scale gardening.
【図1】 屑繭及び蛹の土中での分解速度の試験結果の
グラフ。FIG. 1 is a graph showing the test results of the decomposition rate of waste cocoons and pupae in soil.
【図2】 本発明に係る施肥方法の一つの実施形態を示
す施工断面図。FIG. 2 is a construction cross-sectional view showing an embodiment of a fertilizer application method according to the present invention.
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 平9−142979(JP,A) 特開 平2−302387(JP,A) 特開 平5−186904(JP,A) 特公 昭40−11335(JP,B1) (58)調査した分野(Int.Cl.7,DB名) C05B 1/00 - C05G 5/00 ─────────────────────────────────────────────────── --Continued from the front page (56) References JP-A-9-142979 (JP, A) JP-A-2-302387 (JP, A) JP-A-5-186904 (JP, A) JP-B-40- 11335 (JP, B1) (58) Fields investigated (Int.Cl. 7 , DB name) C05B 1/00-C05G 5/00
Claims (3)
を埋設することを特徴とする緩効性窒素肥料の施肥方
法。1. A method for fertilizing a slow-release nitrogen fertilizer, which comprises burying a waste cocoon that has been treated by being immersed in an acid aqueous solution .
を蛹と共に埋設することを特徴とする緩効性窒素肥料の
施肥方法。2. A method for fertilizing slow-release nitrogen fertilizer, which comprises burying cocoon cocoons that have been soaked in an aqueous acid solution together with pupae.
をシート状にしたことを特徴とする緩効性窒素肥料。3. A waste cocoon that has been treated by immersion in an acid aqueous solution.
A slow-release nitrogen fertilizer characterized by being made into a sheet .
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP34273199A JP3492264B2 (en) | 1999-12-02 | 1999-12-02 | Slow release nitrogen fertilizer using waste cocoons |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP34273199A JP3492264B2 (en) | 1999-12-02 | 1999-12-02 | Slow release nitrogen fertilizer using waste cocoons |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2001158683A JP2001158683A (en) | 2001-06-12 |
| JP3492264B2 true JP3492264B2 (en) | 2004-02-03 |
Family
ID=18356062
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP34273199A Expired - Fee Related JP3492264B2 (en) | 1999-12-02 | 1999-12-02 | Slow release nitrogen fertilizer using waste cocoons |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3492264B2 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20020033450A (en) * | 2002-04-08 | 2002-05-06 | 장영수 | Bio-stimulating fertilizer using silkworm pupae containing free amino acids. |
| CN102432364A (en) * | 2011-09-16 | 2012-05-02 | 浙江大学 | Method for preparing amino acid micro-fertilizer by using coenzyme Q10 fermented liquid |
| CN102351574A (en) * | 2011-09-16 | 2012-02-15 | 浙江大学 | Method for preparing amino acid calcium fertilizer by using coenzyme Q10 fermentation liquor |
-
1999
- 1999-12-02 JP JP34273199A patent/JP3492264B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JP2001158683A (en) | 2001-06-12 |
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