JP3496228B2 - High corrosion resistance, high workability, ultra-high tensile cold rolled steel sheet, and method for producing the same - Google Patents

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention is suitable for pressing, overhanging, light drawing, etc., and of the steel sheets required to have corrosion resistance after painting, it is mainly applied to strength members such as bumper parts and door guard bar parts. Strength (TS) is about 80
TECHNICAL FIELD The present invention relates to an ultra-high-strength cold-rolled steel sheet exceeding kgf / mm ² and a method for producing the same.

[0002]

2. Description of the Related Art In recent years, in order to improve the safety of automobiles and reduce their weight, T has been used as a strength member for bumpers, door guard bars and the like.
High-strength cold-rolled steel sheets with S exceeding 60 kgf / mm ² are often used. The properties required for these steel sheets are not only high strength but also excellent ductility and bendability (good local ductility). Further, in the case of reducing the weight, since the thickness is reduced, it is necessary to perform surface treatment to improve the corrosion resistance from the viewpoint of reliability.

As a steel sheet which meets such a demand, for example, a steel sheet which is structurally strengthened in a low temperature transformation phase as disclosed in Japanese Patent Publication No. 3-21608 is known. However, this also has good bend formability but insufficient ductility. In addition, as a steel sheet with excellent ductility, a large amount of retained austenite (approximately 10%
There is a so-called TRIP steel whose purpose is to improve the ductility by making it exist in the above), but this is a high C steel metallurgically and it is difficult to perform welding including spot welding. , So-called "delayed fracture" that occurs when the amount of retained austenite is increased to improve ductility
I have a problem.

[0004]

The steel sheet produced by the above-mentioned conventional technique cannot satisfy all the conditions of high strength, high ductility, high local ductility and excellent delayed fracture resistance. The first problem to be solved by the present invention is to develop a thin steel sheet that satisfies all the above requirements. Further, it is necessary to deal with the demand for improvement in corrosion resistance corresponding to the reduction in thickness by performing an appropriate surface treatment.

Therefore, an object of the present invention is to solve the above-mentioned drawbacks of the prior art and to provide an ultra-high tensile cold-rolled steel sheet having high corrosion resistance and good workability, and a method for producing the same.

[0006]

The inventors of the present invention have a basic composition of an aluminum killed steel in which a relatively large amount of Mn is added to a low C steel, and if necessary Si, Cr, Mo, P, B, Cu,
It has been found that a steel sheet having high strength and high local ductility can be produced by using a steel sheet to which Ni, V, Ti and Nb are selectively added and mainly strengthened by microstructural strengthening by a low temperature transformation phase. Furthermore, it is effective to form a solid lubricating coating containing a powdered lubricant to compensate for the deterioration of workability due to the increase in strength, and a lubricating coating is formed to ensure coatability in the coating process after processing. It has been found that it is effective to form a chromate layer having an alkali-eluting chromium content of 5 mg / m ² or less before coating. Further, according to the content of the present invention, it was also found that the so-called "delayed fracture" characteristic, which is related to hydrogen in steel, can be sufficiently dealt with in an actual use environment.

The present invention has been made based on the above findings. That is, according to the first aspect of the present invention, C
: 0.02-0.30 wt%, Mn: 0.20-3.
50 wt%, Al: 0.100 wt% or less, balance Fe
And unavoidable impurities, the ferrite phase is structurally 3% or less in terms of area, and the amount of adhesion of metal Cr to the surface of the steel sheet consisting of the balance bainite or martensite.
40 to 200 mg / m ² in conversion and alkali elution C
The chromate-treated layer having an r content of 5 mg / m ² or less, and the amount of adhesion on the upper layer is 0.1 to 5.0 g / m ² , and the inorganic lubricating particles and / or the organic lubricating particles are each 0.0
5-30wt%, 0.05-20wt%, 0.0 in total
Provided is a super-high-strength cold-rolled steel sheet having high corrosion resistance and high workability, which is obtained by forming a solid lubricating coating layer containing 5 to 40 wt%. In particular, C: 0.02-0.30 wt%, Mn:
The basic composition is 0.20 to 3.50 wt% and Al: 0.100 wt% or less, and Si: 0.100 to 1.00.
500 wt%, Cr: 0.100 to 1.000 wt%,
Mo: 0.100 to 1.000 wt%, P: 0.02
0 to 0.100 wt%, B: 5 to 100 ppm, C
u: 0.05-1.000 wt%, Ni: 0.05-
0.500 wt%, V: 0.010 to 0.200 wt
%, Ti: 0.010 to 0.200 wt%, and N
b: contains 1 or 2 or more kinds of components selected from the group consisting of 0.010 to 0.100 wt%, the balance being Fe and inevitable impurities, and the ferrite phase being structurally 3% or less in area ratio And a chromate-treated layer having an adhesion amount of 40 to 200 mg / m ² in terms of metal Cr and an alkali-eluting Cr content of 5 mg / m ² or less on the surface of the steel sheet consisting of the balance bainite or martensite, and an upper layer thereof. Has an adhesion amount of 0.1 to 5.0 g / m ² and an inorganic lubricating particle and / or an organic lubricating particle of 0.05 to 5.0 g / m ² , respectively.
30 wt%, 0.05-20 wt%, total 0.05-
Provided is a high-corrosion-resistant, high-workability ultrahigh-strength cold-rolled steel sheet formed by forming a solid lubricating coating layer containing 40 wt%.

Here, it is preferable that the chromate-treated layer is an electrolytic chromate-treated layer or a coating-type chromate-treated layer, and the substrate of the solid lubricating coating is an alkali-soluble precoat wax or an acrylic copolymer resin.
The inorganic lubricating particles are molybdenum disulfide and / or boron nitride powder having an average particle size of 20 μm or less, and the organic lubricating particles have an average particle size of 20 μm or less and a melting point of 7
It is preferably a wax having a temperature of 0 ° C. or higher.

According to the second aspect of the present invention, a steel having the above chemical composition is made into a slab by a continuous casting method, hot rolled and cold rolled, and then a continuous annealing method at 800 ° C. or higher to 900 ° C. 400 ℃ at a cooling rate of 30 ℃ / s or more after holding in the following temperature range for 10 s or more and less than 180 s
The cold-rolled steel sheet is rapidly cooled to a temperature range of 250 ° C. or higher below to obtain a cold-rolled steel sheet that has been degreased, washed, and dried, and has an adhesion amount of 40 to 200 mg / m ² in terms of metal Cr and an alkali-eluting Cr content. After forming a chromate-treated layer having an amount of 5 mg / m ² or less, inorganic lubricating particles and / or organic lubricating particles are added in an amount of 0.05 to 30 wt.
%, 0.05 to 20 wt%, total 0.05 to 40 wt
% Solid lubricant coating layer content is 0.1-5.0g
The method for producing an ultra-high-strength cold-rolled steel sheet having high corrosion resistance and high workability is provided, which is characterized in that the cold-rolled steel sheet is coated at a rate of / m ² .

Here, the formation of the chromate-treated layer is as follows.
Electrolytic chromate treatment and subsequent 80-250 ℃
Or the formation of the chromate-treated layer is carried out by coating-type chromate treatment and subsequent 100-
It is preferable that the drying is carried out at 250 ° C. and further chromate stabilization treatment.

[0011]

The present invention will be described in more detail below. First,
The reason for limiting the range of chemical components in steel in the present invention will be described.

[C] C is an important element for increasing the strength. As in the present invention, when it is desired to utilize the structural strengthening by the low temperature transformation phase, the amount of C added is at least 0.0
2 wt% is required. Further, if added in excess of 0.30 wt%, weldability becomes almost impossible, and in addition, the amount of retained austenite increases extremely and "delayed fracture" occurs.
The characteristics are significantly deteriorated. Therefore, 0.02 wt% or more of 0.
It was set to 30 wt% or less.

[Mn] Mn is an extremely important element for stably obtaining a low temperature transformation phase. If it is less than 0.20 wt%, it is not possible to obtain a sufficient amount of low temperature transformation phase for strength increase under normal continuous annealing conditions. However, if it is added in excess of 3.50 wt%, the strength increase in the final cold-rolled sheet will be saturated, and the hot-rolled base sheet will be significantly hardened to cause inconvenience during production, and at the same time, the cost will be increased. Therefore, Mn
The added amount was Mn: 0.20 wt% or more and 3.50 wt% or less.

[Al] Al needs to be added as a deoxidizing agent, but there is no reason to set the lower limit, as long as the oxygen content in the steel can be sufficiently reduced by another method. A standard method is about 0.005 wt%. Also, the upper limit is determined by the prevention of surface defects due to alumina clusters,
It is about 0.100 wt%.

[Si] Si is auxiliary used as a strengthening element. A strengthening effect is exhibited by the addition of 0.100 wt% or more. On the other hand, if added in excess of 1.500 wt%, the hot-rolled base plate is significantly hardened, which is a great obstacle to cold rolling. Therefore, it is set to 0.100 wt% or more and 1.500 wt% or less.

[Cr] Cr has a great effect of improving hardenability,
It is effective in further strengthening the effect of Mn and increasing the strength. This effect becomes remarkable when 0.100 wt% or more is added.
Even if added over 000 wt%, the effect is almost saturated,
It only increases the cost of alloying elements. Therefore 0.1
It was set to be 00 wt% or more and 1.000 wt% or less.

[Mo] Mo also has a great effect of improving hardenability,
Effective for increasing strength. Such an effect is 0.100.
It becomes remarkable with addition of wt% or more. But 1.000wt
Even if it is added in excess of%, the effect tends to be saturated and further increases in cost. Therefore, the amount of Mo added is 0.10.
It was set to 0 wt% or more and 1.000 wt% or less.

[P] P is an inexpensive strengthening element and can strengthen steel without deterioration of ductility. The effect becomes remarkable when 0.02 wt% or more is added, and the low temperature toughness deteriorates when it exceeds 0.100 wt%. Therefore 0.02 wt% or more 0.10
It was set to 0 wt% or less.

[B] B improves the hardenability by adding a small amount, and is therefore effective in preventing the formation of ferrite particularly during cooling after continuous annealing and obtaining a highly uniform structure. This effect becomes remarkable when 5 ppm or more is added, and even when 100 ppm or more is added, the effect is saturated. Therefore, the amount of B added is 5
-100 ppm.

[Cu] Cu is effective for improving strength and corrosion resistance, but if it is less than 0.05 wt%, its effect is not sufficient, and if it exceeds 1.0 wt%, there is a risk of hot cracking. It was limited to the range of 0.05 to 1.0 wt%.

[Ni] Ni is effective in making the structure finer and improving the toughness at low temperatures. The addition of 0.05 wt% or more has the effect of improving the structure, but the addition of more than 0.500 wt% saturates the effect, resulting in an increase in cost. Therefore, the amount of Ni added is set to 0.05 wt% or more and 0.500 wt% or less.

[V] V is effective for increasing strength through precipitation strengthening by carbonitrides. Addition of 0.010 wt% or more has an effect of increasing strength, and addition of more than 0.200 wt% leads to saturation of effect and increase in cost.

[Ti] Ti is similar to V, and its suitable range is 0.010 wt% or more and 0.200 wt% or less.

[Nb] Nb is similar to V and Ti,
The effect tends to saturate in the lower addition range. The optimum range is 0.010 wt% or more and 0.100 w
It is t% or less.

The cold-rolled steel sheet having these compositions is formed into a slab by a conventional method, and is subjected to hot rolling, cold rolling, and continuous annealing to form a cold-rolled steel sheet, which is a resin for forming a solid lubricating coating layer containing chromate treatment and lubricating particles. The coating is applied. The process up to annealing is not particularly limited, but in the annealing, since the ferrite phase is structurally 3% or less in area ratio and the balance is a uniform structure consisting of bainite or martensite, It is necessary to perform high temperature annealing and rapid cooling heat treatment. That is, 90 at 800 ° C or higher
By holding in the temperature range of 0 ° C or less for 10 seconds or more and less than 180 seconds, an original structure with sufficient hardenability is formed, and further 400 ° C or less and 250 ° C or more at a cooling rate of 30 ° C / s or more. The desired structure described above can be finally obtained by quenching to the temperature range of.

Next, the functions of the chromate layer and the solid lubricating coating layer formed on the steel sheet will be described.

The chromate layer has the effect of securing the adhesion between the steel sheet and the resin layer, that is, the solid lubricating coating layer, and improving the corrosion resistance, but if the amount of adhesion is less than 40 mg / m ^{2 in} terms of metal chromium, the effect is sufficient. Not 200 mg / m ²
Since the effects are saturated and it is uneconomical when the amount of adhesion exceeds, the range is limited to 40 to 200 mg / m ² .

When the alkali-eluting chromium content in the chromium layer exceeds 5 mg / m ² , there is a risk of degrading the chemical conversion treatment solution due to chromium elution into the chemical conversion treatment solution, which is a pretreatment for coating. 5mg / m ²
Limited to:

The chromate layer is preferably obtained by subjecting an electrolytic chromate layer or a coating type chromate layer to a stabilization treatment.

In the present invention, the second layer on the chromate layer
The layer is a solid lubricating coating layer containing inorganic lubricating particles and / or organic lubricating particles in a coating composed mainly of a precoat wax or an acrylic resin copolymer.

As the inorganic lubricating particles, one or a mixture of molybdenum disulfide and boron nitride powder is used, for example.

If the amount of these lubricating particles is too small, the lubricating effect will be small, and if they are excessive, the viscosity of the lubricating coating will be increased and the coating operation will be inconvenient, so the content is limited to 0.05 to 30 wt%.

Particles having an average particle size of more than 20 μm have poor dispersibility and deteriorate the uniformity after coating, resulting in poor processability. Therefore, the average particle size is limited to 20 μm or less.

As the organic lubricating particles, either synthetic wax or natural wax may be used. However, if the wax has a melting point of less than 70 ° C., it is difficult to disperse it in the base wax, and the viscosity in the extreme pressure state is small and the lubricating effect is high. Melting point 70 because not enough
Limited to above ℃.

The addition amount and average particle size are each 0.05 to 20 w for the same reason as the above inorganic lubricating particles.
t% and the average particle size are limited to 20 μm or less.

When the inorganic lubricating particles and the organic lubricating particles are used in combination, the limit of the amount added increases to 40% by weight, but if the amount is more than 40% by weight, the coating work will be inconvenient and 0.0 will result.
It was limited to 5 to 40 wt%.

[0037]

EXAMPLES The present invention will be specifically described below based on examples. (Example) Steel having a chemical composition shown in Table 1 was slabed by a continuous casting method,
A slab reheating temperature of 1250 ° C., a finish rolling temperature of 830 ° C., and a hot rolling coiling temperature of 540 ° C. A hot rolled mother plate having a thickness of 2.6 mm was pickled and cold rolled to obtain a cold rolled plate of 1.4 mm. Furthermore, in a continuous annealing furnace, soaking condition of 840 ° C.-60 s, 3
A cold rolled annealed plate was prepared by quenching to 320 ° C. at an average cooling rate of 0 ° C./s. The steel sheet coil is subjected to a series of treatments such as alkali degreasing with a color line, water washing / drying → electrolytic chromate treatment, water washing / drying or coating type chromate coating / drying with a roll coater → application of a solid coating agent containing lubricating particles (immersion method). A sample was prepared.

Table 2 shows the mechanical properties of the steel sheet samples, Table 3 shows the chromate treatment conditions and chromate stabilization treatment conditions, and Table 4 shows the solid lubricating coating composition and coating amount. The chromate, inorganic lubricant, organic lubricant and solid lubricant coating agent used are as follows.

(Chromate) Electrolytic chromate: All electrolytic chromate treatments are electrolytic treatment followed by washing and drying Liquid composition: CrO ₃ 30 g / l, Na ₂ SiF ₆ 1 g
/ L Electrolysis conditions: current density 5 A / dm ² , electrolysis time 8 seconds (40
mg / m ² ) Electrolysis 1 10 A / dm ² , electrolysis time 8 seconds (80 mg / m ² ) electrolysis 2 10 A / dm ² , electrolysis time 12 seconds (120 mg / m ² ) electrolysis 3 10 A / dm ² , electrolysis time 16 Second (160 mg / m ² ) Electrolysis 4 () Target weight per unit coating type Chromate A: Silica-free 4513H (Nippon Parkerizing Co., Ltd.) Coating type Chromate B: Silica addition Cosmer 150
(Made by Kansai Paint Co., Ltd.)

(Solid Lubricant Coating Agent) (Base Wax Agent) Based on the commercially available precoat wax Caolube W2 (manufactured by Kao Corporation), 6
The above steel sheet (150 × 220 m) heated to 60 ° C. in molten wax prepared by melting at 0 ° C. and adding and mixing inorganic lubricating powder and / or organic lubricating powder
m) was immersed, pulled up, air-cooled and dried.

The coating amount was arbitrarily adjusted by adjusting the dipping / pulling speed and the air cooling / drying speed. The coating amount was measured from the weight difference between the plate before coating and the plate after coating. The lubricating powder was crushed with a ball mill in advance, and the particle size was arbitrarily adjusted before use. The particle size was measured by forming the lubricating coating on a glass plate and observing directly with an optical microscope.

(Alkali-eluting coating agent) A commercially available alkali-soluble polymer lubricating coating agent Millbond MC-560J (manufactured by NOF Corporation) was used as a base, and an inorganic lubricating powder and / or an organic lubricating powder was added thereto and mixed. The composition adjusted to the composition shown in Table 4 was used.

Since this agent is a water-based paint, it may be difficult to uniformly disperse it for a long time depending on the type of wax.
Immediately after vigorous stirring, the steel sheet was dipped, applied and dried to obtain a uniformly dispersed coating film. The drying was carried out by hot air drying at 80 ° C., and the coating amount was adjusted by changing the amount of water added to the coating solution. The measurement of the coating amount and the adjustment of the lubricating powder are the same as above.

The waxes shown in Table 4 were as follows. Wax 1 San Nopco SN Wax 22-SF Wax 2 San Nopco SL 506 Wax 3 Yasuhara Yushi Kogyo Arrow Wax Wax 4 Same as above Wax with reduced crushing time Wax 5 Nippon Oil Co., Ltd. PO Wax H-10

(Evaluation of Workability) The workability of the steel sheet was evaluated by the limiting drawing ratio by a cylindrical drawing test with a punch diameter of 33 mmφ.

(Evaluation of Bare Corrosion Resistance) Bare corrosion resistance was measured by degreasing, washing and drying each of the three manufactured steel plates cut into 70 × 150 mm, and then performing a salt spray test (5% NaCl, 35 ° C.,
For 500 hours), the maximum erosion depth on the surface of the test piece was measured and evaluated. ⊚: Maximum erosion depth of 0.05 mm or less ○: 0.05 to 0.1 mm Δ: 0.1 to 0.5 mm ×: 0.5 mm or more

(Paintability and corrosion resistance after coating) As for the paintability, 10 sheets each of 70 × 150 mm of the steel sheet were pretreated under standard conditions of degreasing, surface conditioning and chemical conversion treatment, and then Power Top U- manufactured by Nippon Paint Co., Ltd. 600 at 20V with a coating voltage of 200V
The outer appearance was visually evaluated by applying a μm electrodeposition coating. Degreasing liquid (FC4460 manufactured by Nippon Parkerizing Co., Ltd.) Surface conditioning liquid (PL404 manufactured by Nippon Parkerizing Co., Ltd.)
0) Chemical conversion treatment liquid (PBL302 manufactured by Nippon Parkerizing Co., Ltd.)
0) Further, after performing a cross-cycle corrosion test after inserting a cross-cut into the above-mentioned five coated steel plates using a cutter knife, the coating bulge width and the maximum erosion depth of the cross-cut portion were measured and evaluated. Corrosion test cycle: salt spray (5% NaCl, 35 ° C,
6 hr) → 50 ° C., 2 hr drying → RH 95%, 50 ° C.,
15 hours (wet atmosphere) → natural drying for 1 hour, this cycle was performed for 15 cycles. The alkali-eluting chromium was measured by immersing the test piece after chromate treatment in alkali degreasing liquid (FC4460) 60 ° C. for 5 minutes, and measuring the C before and after the immersion.
The amount of r adhered was determined by measuring by fluorescent X-ray analysis. ○: Maximum blistering width less than 1 mm △: 1-3 mm ×: 3 mm or more ◎: Maximum erosion depth less than 0.05 mm ○: 0.05 to 0.1 mm △: 0.1 to 0.3 mm ×: 3 mm or more

(Evaluation of Delayed Fracture Property) The delayed fracture property was obtained by processing a manufactured steel plate into a disc of 40 mmφ, forming a conical cup with a ball head punch having a punch diameter of 22 mm, and immersing it in a 5% NaCl aqueous solution. It was evaluated by the time until cracking occurred. When the immersion time is equivalent to 7 days and no crack is generated, it can be determined that there is no problem in practical use. It can be said that the steel of the present invention is a very useful steel sheet practically without causing delayed fracture even when TS exceeds 120 kgf / mm ² . Evaluation x: Cracking occurred within 1 day Δ: Cracking occurred within 1 to 7 days ◯: Cracking did not occur for 7 days or more Table 5 shows the results of these evaluation tests.

As is clear from the results of Tables 1 to 5, the steels of the present invention all exhibit excellent mechanical properties, workability, corrosion resistance and paintability. On the other hand, in Comparative Example 1-a, sufficient corrosion resistance and paintability were not obtained due to insufficient chromate adhesion. In Comparative Example 2-a, the amount of alkali-soluble chromium in the chromate layer is large, and thus the coatability is deteriorated.

In Comparative Examples 3-a, 4-a, 5-a and 6-a, sufficient workability cannot be obtained because the lubricating powder, wax or the coating amount in the lubricating coating is insufficient. Comparative Examples 7-a, 8
-A, 9-a, 10-a, 11-a, 12-a cannot be uniformly applied because the lubricant is excessive or excessive, and sufficient processability is obtained because the coating film falls off during processing. Since it is not possible and even before the pretreatment, it is not uniform, the paintability is deteriorated. In Comparative Example 13-a, since the wax has a low melting point, sufficient processability cannot be obtained.

In Comparative Examples 1 to 17, sufficient workability, corrosion resistance and paintability were not obtained even if chromate treatment and lubricating coating treatment were applied.

[0052]

[Table 1]

[0053]

[Table 2]

[0054]

[Table 3]

[0055]

[Table 4]

[0056]

[Table 5]

[0057]

[Table 6]

[0058]

[Table 7]

[0059]

[Table 8]

[0060]

[Table 9]

[0061]

[Table 10]

[0062]

[Table 11]

[0063]

[Table 12]

[0064]

[Table 13]

[0065]

[Table 14]

[0066]

As described above, according to the present invention,
Since an ultra-high-strength steel sheet having excellent workability and corrosion resistance and a TS of 80 kgf / mm ² or more can be produced by a simple chromate treatment and a treatment of a resin containing lubricating particles, a superior material can be supplied at a lower cost. According to this process, TS is 1
Even if it exceeds 20 kgf / mm ² , it can be put to practical use with high reliability without causing delayed fracture. Further, conventionally, the plating applied to improve the corrosion resistance had a problem of making recycling of the steel sheet difficult, but it can be said that the ultrathin coating as in the present invention causes no problem in recyclability.

─────────────────────────────────────────────────── ─── Continuation of the front page (56) Reference JP-A-3-277742 (JP, A) JP-A-4-130189 (JP, A) JP-A-60-103185 (JP, A) JP-A-62-1 74051 (JP, A) Patent 3217890 (JP, B2) (58) Fields investigated (Int.Cl. ⁷ , DB name) C22C 38/00-38/60 C23C 22 / 24,28 / 00

Claims (9)

(57) [Claims] 1. C: 0.02 to 0.30 wt%, Mn: 0.20 to 3.50 wt%, Al: 0.100 wt% or less, the balance being Fe and inevitable impurities , and structurally a ferrite phase. Is an area ratio of 3
% Or less, and the amount of adhesion on the surface of the steel sheet consisting of the balance bainite or martensite is 40 to 40 in terms of metal Cr.
200 mg / m ² and alkaline elution Cr content 5 mg
Chromate-treated layer having an amount of 0.1 / m ² or less and an amount of adhesion of 0.1 to 5.0 g / m ² on the upper layer, and 0.05 to 30 wt% of inorganic lubricating particles and / or organic lubricating particles, respectively.
%, 0.05 to 20 wt%, total 0.05 to 40 wt
%, High corrosion resistance, formed by forming a solid lubricating coating layer containing
High workability ultra-high tensile cold rolled steel sheet. 2. A basic composition of C: 0.02 to 0.30 wt%, Mn: 0.20 to 3.50 wt%, Al: 0.100 wt% or less, and Si: 0.100 to 1.500 wt. %, Cr: 0.100 to 1.000 wt%, Mo: 0.100 to 1.000 wt%, P: 0.020 to 0.100 wt%, B: 5 to 100 ppm, Cu: 0.05 to 1.000 wt. %, Ni: 0.05 to 0.500 wt%, V: 0.010 to 0.200 wt%, Ti: 0.010 to 0.200 wt%, and Nb: 0.010 to 0.100 wt% A steel sheet containing one or more selected components, the balance being Fe and inevitable impurities, structurally having a ferrite phase in an area ratio of 3% or less, and the balance being bainite or martensite. On the surface, the chromate treatment layer is 40~200mg / m ² and alkaline elution of Cr content at a coverage of metal Cr-equivalent is less than 5 mg / m ^2, the amount adhering to the upper layer 0.1 to 5.0 g / m
² , and 0.05 to 30 wt% and 0.05 to 20 wt% of inorganic lubricating particles and / or organic lubricating particles, respectively.
%, A high corrosion resistance, high workability ultra-high tensile cold rolled steel sheet formed by forming a solid lubricating coating layer containing 0.05 to 40 wt% in total. 3. The high corrosion resistance, high workability ultra-high tensile cold rolled steel sheet according to claim 1, wherein the chromate treatment layer is an electrolytic chromate treatment layer or a coating type chromate treatment layer. 4. The high corrosion resistance, high workability ultra-high tensile cold rolled steel sheet according to claim 1, wherein the base material of the solid lubricating coating is an alkali-soluble precoat wax or an acrylic copolymer resin. 5. The high corrosion resistance, high workability ultra-high tensile cold rolled steel sheet according to claim 1, wherein the inorganic lubricating particles are molybdenum disulfide and / or boron nitride powder having an average particle diameter of 20 μm or less. . 6. The organic lubricating particles are waxes having an average particle size of 20 μm or less and a melting point of 70 ° C. or more.
High corrosion resistance, high workability ultra-high tensile cold rolled steel sheet according to any one of 1. 7. A steel having the chemical composition according to claim 1 or 2 is formed into a slab by a continuous casting method, hot rolled and cold rolled, and then continuously annealed at 800 ° C. or higher to 900 ° C.
After holding for 10 s or more and less than 180 s in the following temperature range, 2 at 400 ° C. or less at a cooling rate of 30 ° C./s or more
A cold-rolled steel sheet is rapidly cooled to a temperature range of 50 ° C. or higher, and the degreased, washed, and dried cold-rolled steel sheet has an adhesion amount of 40 to 200 mg / m ² in terms of metal Cr and an alkali-eluting Cr content of 5 mg. / M ² or less, a chromate-treated layer is formed, and then inorganic lubricating particles and / or organic lubricating particles are added to the upper layers in an amount of 0.05 to 30 wt% and 0.0, respectively.
5 to 20 wt%, 0.05 to 40 wt% in total, a solid lubricating coating layer is applied so as to have an adhesion amount of 0.1 to 5.0 g / m ² , high corrosion resistance, high workability. For manufacturing high-strength ultrahigh-strength cold-rolled steel sheet. 8. The production of a high corrosion resistance, high workability ultra high strength cold rolled steel sheet according to claim 7, wherein the formation of the chromate treatment layer is performed by electrolytic chromate treatment and subsequent drying at 80 to 250 ° C. Method. 9. The high-corrosion resistance, high workability and ultra-high workability according to claim 7, wherein the formation of the chromate treatment layer is performed by coating type chromate treatment, followed by drying at 100 to 250 ° C. and further chromate stabilization treatment. Method of manufacturing tension cold-rolled steel sheet.