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JP3518945B2 - How to clean coin batteries - Google Patents
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JP3518945B2 - How to clean coin batteries - Google Patents

How to clean coin batteries

Info

Publication number
JP3518945B2
JP3518945B2 JP11478996A JP11478996A JP3518945B2 JP 3518945 B2 JP3518945 B2 JP 3518945B2 JP 11478996 A JP11478996 A JP 11478996A JP 11478996 A JP11478996 A JP 11478996A JP 3518945 B2 JP3518945 B2 JP 3518945B2
Authority
JP
Japan
Prior art keywords
battery
electrode terminal
cleaning
negative electrode
positive electrode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP11478996A
Other languages
Japanese (ja)
Other versions
JPH09306511A (en
Inventor
純一 清水
貴 小屋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FDK Twicell Co Ltd
Original Assignee
Toshiba Battery Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Battery Co Ltd filed Critical Toshiba Battery Co Ltd
Priority to JP11478996A priority Critical patent/JP3518945B2/en
Publication of JPH09306511A publication Critical patent/JPH09306511A/en
Application granted granted Critical
Publication of JP3518945B2 publication Critical patent/JP3518945B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • Y02E60/12

Landscapes

  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
  • Primary Cells (AREA)

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は、電解液に非水電解
液を用いたコイン形電池の洗浄方法に関するものであ
る。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a coin-type battery cleaning method using a non-aqueous electrolyte as an electrolyte.

【0002】[0002]

【従来の技術】コイン形非水電解液電池では、負極とし
てリチウム金属、或いはリチウムイオンを吸蔵放出可能
な負極材料が、リチウムイオン伝導性電解液としては、
炭酸プロピレン、炭酸エチレン、1,2−ジメトキシエ
タン、γ−ブチロラクトン、テトラヒドロフラン等の有
機溶剤中に、例えば、LiClO4 ,LiBF4 ,Li
AsF6 ,LiPF6 等のリチウム塩を溶解させてなる
非水電解液が、さらに正極活物質としては主にバナジウ
ム酸化物,コバルト酸化物,マンガン酸化物等の化合物
が、それぞれ用いられている。
2. Description of the Related Art In coin type non-aqueous electrolyte batteries, lithium metal as a negative electrode or a negative electrode material capable of inserting and extracting lithium ions is used as a lithium ion conductive electrolytic solution.
In an organic solvent such as propylene carbonate, ethylene carbonate, 1,2-dimethoxyethane, γ-butyrolactone and tetrahydrofuran, for example, LiClO 4 , LiBF 4 , Li
A non-aqueous electrolyte prepared by dissolving a lithium salt such as AsF 6 or LiPF 6 is used, and compounds such as vanadium oxide, cobalt oxide, and manganese oxide are mainly used as the positive electrode active material.

【0003】ところで、非水電解液を使用する場合は、
電気伝導度が低いため、電池中に電解液を十分に入れる
必要がある。また、非水電解液系は水溶液系と違って、
クリーピング特性がなく、電解液で封口部が濡れていて
も進行性を示さないため、電解液を過剰に注液させて電
池組立を実施している。そのため、電池封口時に電解液
が溢れ出てしまっている。これによって、電池組立後に
電池外周面に付着した電解液中のリチウム塩の影響によ
り錆が発生し、電池機能を低下させるほか、電解液に含
まれているリチウム塩が結晶化し、負極端子平面部,正
極端子平面部等に析出したり、不揮発溶媒による汚染等
で電池外観の鮮麗さを失ってしまうことがある。そのた
め洗浄を行いこれらの発生を防いでいた。
By the way, when using a non-aqueous electrolyte,
Since the electric conductivity is low, it is necessary to sufficiently fill the battery with the electrolytic solution. Also, unlike the aqueous system, the non-aqueous electrolyte system is
Since it has no creeping property and does not show progress even when the sealing portion is wet with the electrolytic solution, the electrolytic solution is excessively injected to assemble the battery. Therefore, the electrolyte solution overflows when the battery is sealed. As a result, rust is generated due to the effect of the lithium salt in the electrolyte that has adhered to the outer peripheral surface of the battery after the battery is assembled, and the battery function is degraded. However, the appearance of the battery may be lost due to deposition on the flat surface of the positive electrode terminal or contamination with a non-volatile solvent. Therefore, cleaning was performed to prevent these occurrences.

【0004】従来の洗浄は、図3に示す如く電池1の負
極端子平面部、または、正極端子平面部が上に向くよう
にコンベアー3と水平になるように電池1を置き、電池
1が吹き飛ばされない程度の水圧をかけたノズル4から
温水シャワー5で洗浄を行い、さらにその電池1が吹き
飛ばされない程度の圧力のエアーを吹き付けて、電池外
周、または、表面等に付着した水分を吹き飛ばす洗浄を
行っていた。
In the conventional cleaning, as shown in FIG. 3, the battery 1 is placed so that the flat surface of the negative terminal of the battery 1 or the flat surface of the positive terminal faces the conveyor 3 so that the flat surface thereof faces upward, and the battery 1 is blown off. Cleaning is performed with a hot water shower 5 from a nozzle 4 to which water pressure that is not applied is blown, and then air with a pressure that does not blow the battery 1 is blown to blow away water adhering to the battery periphery or the surface. Was there.

【0005】また、図4の如く電池1の負極端子平面
部、または、正極端子平面部が上に向くように専用治具
2Aで電池を一列、もしくは、複数列に並べ、温水7の
洗浄液の入った超音波洗浄槽6の中に浸漬させるという
方法も行っていた。
Further, as shown in FIG. 4, the batteries are arranged in one row or in a plurality of rows by a dedicated jig 2A so that the flat surface of the negative electrode terminal or the flat surface of the positive electrode terminal faces upward. A method of immersing it in the ultrasonic cleaning tank 6 contained therein has also been performed.

【0006】しかし、これらの洗浄方法では電池の片側
は洗浄することができても、負極端子,正極端子の両面
を洗浄することができなかった。そこで、両面を洗浄す
る場合は、負極端子、または、正極端子の洗浄が終わっ
た電池の上下方向を180°反転させて、再度洗浄機に
投入し両面を洗浄する等の方法をとっていた。
However, with these cleaning methods, although one side of the battery can be cleaned, both sides of the negative electrode terminal and the positive electrode terminal cannot be cleaned. Therefore, in the case of cleaning both sides, a method of reversing the up-down direction of the battery after cleaning the negative electrode terminal or the positive electrode terminal by 180 ° and re-inserting it in a cleaning machine to wash both surfaces has been adopted.

【0007】しかし、従来の洗浄方法では一度に負極端
子,正極端子のどちらか一方の洗浄しか行えないため、
片面を洗い汚染された洗浄液が反対側に流れ込み、反対
面はかえって汚れがひどくなってしまっていることがあ
る。そこで、最終的な仕上として電池をガーゼ等で手拭
きを行い、錆の発生、及び、リチウム塩の結晶析出等を
防いでいた。
However, since the conventional cleaning method can clean only one of the negative electrode terminal and the positive electrode terminal at a time,
One side may be washed, and the contaminated cleaning fluid may flow to the other side, and the other side may be rather dirty. Therefore, as a final finish, the battery was hand-wipe with gauze or the like to prevent the formation of rust and the precipitation of lithium salt crystals.

【0008】[0008]

【発明が解決しようとする課題】本発明は、上記事情に
鑑みてなされたもので、電池の洗浄工程において、電池
の負極端子及び正極端子を同時に洗浄できるようにする
と共に、洗浄後に手拭きなどの手作業をなくし作業の効
率化を図ることを目的とする。
SUMMARY OF THE INVENTION The present invention has been made in view of the above circumstances, and makes it possible to simultaneously wash the negative electrode terminal and the positive electrode terminal of a battery in the process of cleaning the battery, and to use hand-wiping after cleaning. The purpose is to eliminate manual work and improve work efficiency.

【0009】[0009]

【課題を解決するための手段】上記目的を達成するため
に、本発明は、非水電解液を有するコイン形電池の洗浄
方法において、負極端子平面部および正極端子平面部を
垂直方向として電池を立て、負極端子平面部および正極
端子平面部に略平行面内で電池を回転させながら洗浄
水を吹き付けて洗浄を行うことを特徴とする。
In order to achieve the above object, the present invention provides a method for cleaning a coin-type battery having a non-aqueous electrolytic solution, in which the battery has a negative electrode terminal flat surface portion and a positive electrode terminal flat surface portion in a vertical direction. Stand, negative electrode terminal flat surface and positive electrode
It is characterized in that washing water is sprayed while rotating the battery in a plane substantially parallel to the terminal flat portion to perform washing.

【0010】本発明では、電池の負極端子平面部および
正極端子平面部がコンベアー等の平面に対して垂直とな
るように電池を立て、負極端子平面部および正極端子平
面部に略平行面内で電池を回転させて洗浄を行うの
で、コンベアー等の面にふれる部分は側面部だけにな
る。また、電池が常に回転していることから側面部も洗
浄されるため汚染される心配もなくなる。その結果、電
池の正極端子,負極端子の両面を同時に洗浄することが
でき、且つ、汚染された洗浄液で再度、電池を汚してし
まう虞れもなくすことができる。
According to the present invention, the battery is erected so that the flat surface of the negative electrode terminal and the flat surface of the positive electrode terminal of the battery are perpendicular to the flat surface of the conveyor, and the flat surface of the negative electrode terminal and the flat surface of the positive electrode terminal are arranged.
Substantially since the washing by rotating the battery in a plane parallel to the surface portion, the portion exposed to the surface, such as conveyor will only side surface portions. In addition, since the battery is constantly rotating, the side surface is also cleaned so that there is no fear of contamination. As a result, both surfaces of the positive electrode terminal and the negative electrode terminal of the battery can be cleaned at the same time, and it is possible to eliminate the possibility of contaminating the battery again with the contaminated cleaning liquid.

【0011】また、従来は洗浄後に手拭きなどの手作業
が必要であったが、本発明ではこれも不要となり、作業
の効率化を図ることができる。洗浄に使用する洗浄水と
して40℃〜80℃の温水を使用すれば、電解液中に含
まれる有機電解液が溶解しやすくなるので、洗浄効果を
上げることができる。
Further, in the past, manual work such as hand-wiping was required after cleaning, but in the present invention, this is also unnecessary, and the work efficiency can be improved. If warm water of 40 ° C. to 80 ° C. is used as the cleaning water used for cleaning, the organic electrolytic solution contained in the electrolytic solution is easily dissolved, so that the cleaning effect can be improved.

【0012】[0012]

【発明の実施の形態】以下、本発明の実施の形態を図を
参照して説明する。図1は本発明の一実施例の洗浄方法
を示すもので図2のA−A方向からみた正面図、図2は
図1の側面図である。
BEST MODE FOR CARRYING OUT THE INVENTION Embodiments of the present invention will be described below with reference to the drawings. FIG. 1 shows a cleaning method according to an embodiment of the present invention, and is a front view seen from the direction AA of FIG. 2, and FIG. 2 is a side view of FIG.

【0013】本実施例で洗浄の対象とした電池は、負極
活物質として金属リチウム、電解液としてプロピレンカ
ーボネートおよび1,2−ジメトキシエタンの混合溶媒
にLiClO4 を溶解させたもの、正極活物質としてM
nO2 を用いたコイン形非水電解液電池である。
The battery to be cleaned in the present example was prepared by dissolving LiClO 4 in a mixed solvent of metallic lithium as a negative electrode active material, propylene carbonate and 1,2-dimethoxyethane as an electrolytic solution, and as a positive electrode active material. M
A coin type non-aqueous electrolyte battery using nO 2 .

【0014】図に示すように、封口の終了した電池1
を、負極端子平面部、正極端子平面部を垂直方向として
立たせ、負極端子平面部および正極端子平面部に略平行
面内で電池を洗浄中に一回転以上回転させることので
きる電池搬送用治具2の中に挿入する。このときの電池
搬送用治具2の進行スピードはコンベアー3の進行スピ
ードに差をつけるように設定する。これにより、電池1
を回転させることができるが、この場合、スピード差が
大きいほど、電池1の回転数が増加し、洗浄が均一化す
る。好ましくはコンベアー3の進行方向と、電池運搬用
治具2の進行方向を逆にすることによりさらにスピード
差を大きくすることができる。
As shown in the figure, the sealed battery 1
Stand with the negative electrode terminal flat portion and the positive electrode terminal flat portion in the vertical direction and are substantially parallel to the negative electrode terminal flat portion and the positive electrode terminal flat portion.
The battery is inserted into the battery transport jig 2 that can be rotated once or more during cleaning in a plane. The traveling speed of the battery conveying jig 2 at this time is set so as to be different from the traveling speed of the conveyor 3. This allows the battery 1
Can be rotated, but in this case, the larger the speed difference, the more the number of rotations of the battery 1 increases and the cleaning becomes uniform. Preferably, the speed difference can be further increased by reversing the traveling direction of the conveyor 3 and the traveling direction of the battery carrying jig 2.

【0015】次に、電池運搬用治具2の負極端子側,正
極端子側の両側に配置されたシャワー用ノズル4から6
0℃の温水シャワー5を電池1全体に吹き付ける。この
ときの洗浄水の温度は、40℃〜80℃が望ましい。更
に望ましくは、50℃〜70℃がより洗浄効果が大きく
あらわれる。これは、40℃以下の水温の場合は、電解
液が溶けにくくなってしまい、80℃以上の水温の場合
は、電解液が熱により分解されて電池性能が低下してし
まうからである。
Next, shower nozzles 4 to 6 arranged on both sides of the battery transport jig 2 on the negative electrode terminal side and the positive electrode terminal side.
A 0 ° C. hot water shower 5 is sprayed on the entire battery 1. The temperature of the washing water at this time is preferably 40 ° C to 80 ° C. More desirably, 50 ° C. to 70 ° C. is more effective in cleaning. This is because when the water temperature is 40 ° C. or lower, the electrolytic solution becomes difficult to dissolve, and when the water temperature is 80 ° C. or higher, the electrolytic solution is decomposed by heat and the battery performance deteriorates.

【0016】(比較例1)図3の如く電池負極端子平坦
部が上向きになるようにコンベアー3に電池1を置き、
電池が吹き飛ばない程度の水圧をかけた60℃の温水シ
ャワー5で洗浄を行い、さらに電池1が吹き飛ばない程
度の圧力をかけたエアーを吹き付けて洗浄を行った。
(Comparative Example 1) As shown in FIG. 3, the battery 1 was placed on the conveyor 3 so that the flat portion of the battery negative electrode terminal faced upward.
Cleaning was performed with a hot water shower 5 at 60 ° C. which was applied with a water pressure such that the battery was not blown off, and further air was applied so that the battery 1 was not blown off.

【0017】(比較例2)図4の如く電池負極端子平坦
部が上向きになるように専用治具2Aに電池1を複数列
並べ、水温60℃の温水7を入れた超音波洗浄槽6に浸
漬させて洗浄を行った。
(Comparative Example 2) As shown in FIG. 4, the batteries 1 are arranged in a plurality of rows on the special jig 2A so that the flat portion of the negative electrode terminal of the battery faces upward, and the ultrasonic cleaning tank 6 is filled with hot water 7 having a water temperature of 60 ° C. It was immersed and washed.

【0018】ここで、本実施例及び比較例1,比較例2
について、洗浄後60℃の槽に貯蔵したときのリチウム
塩の発生数を表1に示す。評価条件は、60℃−10日
間貯蔵、目視検査結果である。
Here, the present embodiment and Comparative Examples 1 and 2
Table 1 shows the number of generated lithium salts when stored in a tank at 60 ° C. after washing. The evaluation conditions are 60 ° C.-10 days storage and visual inspection results.

【0019】[0019]

【表1】 [Table 1]

【0020】電池が十分に洗浄されていないと、60℃
の高温貯蔵を行うことにより電解液中の電解質がリチウ
ム塩となって負極端子,正極端子等に析出するが、本発
明の洗浄方法を用いた実施例1では、従来の洗浄方法の
比較例1,比較例2に比べ負極端子,正極端子等にリチ
ウム塩の付着物がないことが確認された。
If the battery is not thoroughly washed,
The electrolyte in the electrolytic solution becomes a lithium salt and deposits on the negative electrode terminal, the positive electrode terminal, etc. by performing the high temperature storage of Example 1. In Example 1 using the cleaning method of the present invention, Comparative Example 1 of the conventional cleaning method is used. It was confirmed that there was no deposit of lithium salt on the negative electrode terminal, the positive electrode terminal, etc., as compared with Comparative Example 2.

【0021】[0021]

【発明の効果】以上説明したように、本発明では電池の
負極端子平面部,正極端子平面部をコンベアーに対して
垂直方向に立て、負極端子平面部および正極端子平面部
略平行面内で電池を回転させながら洗浄を行ってい
るので、負極端子及び正極端子が同時に洗え、また、汚
染された電解液で再度、電池を汚してしまうことがなく
なり、さらに手拭き等の手作業を省くことができる。し
たがって、本発明によれば、洗浄効果が向上し、かつ洗
浄作業の効率化が達成される。
As described above, in the present invention, the negative electrode terminal flat surface portion and the positive electrode terminal flat surface portion of the battery are erected in the vertical direction with respect to the conveyor, and the negative electrode terminal flat surface portion and the positive electrode terminal flat surface portion are formed.
Since the cleaning is performed while rotating the battery in a plane substantially parallel to , the negative electrode terminal and the positive electrode terminal can be washed at the same time, and the contaminated electrolytic solution will not stain the battery again, and hand washing etc. It is possible to omit the manual work of. Therefore, according to the present invention, the cleaning effect is improved and the efficiency of the cleaning work is achieved.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の一実施例である洗浄方法を示すもの
で、図2のA−A方向からみた正面図。
FIG. 1 is a front view showing a cleaning method according to an embodiment of the present invention, as viewed from the direction AA of FIG.

【図2】図1の側面図。FIG. 2 is a side view of FIG.

【図3】従来のシャワー式洗浄方法を説明するための正
面図。
FIG. 3 is a front view for explaining a conventional shower-type cleaning method.

【図4】従来の超音波式洗浄方法を説明するための断面
図。
FIG. 4 is a sectional view for explaining a conventional ultrasonic cleaning method.

【符号の説明】[Explanation of symbols]

1…電池、2…電池搬送用治具、2A…専用治具、3…
コンベアー、4…シャワー用ノズル、5…温水シャワ
ー、6…超音波洗浄槽、7…温水。
1 ... Battery, 2 ... Battery transport jig, 2A ... Special jig, 3 ...
Conveyor, 4 ... Shower nozzle, 5 ... Hot water shower, 6 ... Ultrasonic cleaning tank, 7 ... Hot water.

フロントページの続き (58)調査した分野(Int.Cl.7,DB名) H01M 6/00 - 6/22 H01M 10/00 - 10/40 Continuation of front page (58) Fields surveyed (Int.Cl. 7 , DB name) H01M 6/00-6/22 H01M 10/00-10/40

Claims (3)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 非水電解液を有するコイン形電池の洗浄
方法において、電池の負極端子平面部および正極端子平
面部を垂直方向として電池を立て、負極端子平面部およ
び正極端子平面部に略平行面内で電池を回転させなが
ら洗浄水を吹き付けて洗浄を行うことを特徴とするコイ
ン形電池の洗浄方法。
1. A method for cleaning a coin-type battery having a non-aqueous electrolyte, wherein the battery is erected with the negative electrode terminal plane portion and the positive electrode terminal plane portion of the battery in the vertical direction, and the negative electrode terminal plane portion and
And a coin-shaped battery cleaning method in which cleaning water is sprayed while rotating the battery in a plane substantially parallel to the flat surface of the positive electrode terminal .
【請求項2】 洗浄水が40℃〜80℃の温水である請
求項1記載のコイン形電池の洗浄方法。
2. The method for cleaning a coin battery according to claim 1, wherein the cleaning water is hot water at 40 ° C. to 80 ° C.
【請求項3】 電池搬送用治具の中に電池を挿入してコ
ンベアー上に置き、電池搬送用治具の進行スピードとコ
ンベアー進行スピードに差をつけることによって電池を
回転させる請求項1記載のコイン形電池の洗浄方法。
3. The battery according to claim 1, wherein the battery is inserted into a battery carrying jig and placed on a conveyor, and the battery is rotated by making a difference between a moving speed of the battery carrying jig and a moving speed of the conveyor. How to clean coin-type batteries.
JP11478996A 1996-05-09 1996-05-09 How to clean coin batteries Expired - Fee Related JP3518945B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11478996A JP3518945B2 (en) 1996-05-09 1996-05-09 How to clean coin batteries

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11478996A JP3518945B2 (en) 1996-05-09 1996-05-09 How to clean coin batteries

Publications (2)

Publication Number Publication Date
JPH09306511A JPH09306511A (en) 1997-11-28
JP3518945B2 true JP3518945B2 (en) 2004-04-12

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
JP11478996A Expired - Fee Related JP3518945B2 (en) 1996-05-09 1996-05-09 How to clean coin batteries

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Country Link
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