JP3549609B2 - Super-hard concrete composition for joint repair work and method for producing super-hard concrete using the same - Google Patents
Super-hard concrete composition for joint repair work and method for producing super-hard concrete using the same Download PDFInfo
- Publication number
- JP3549609B2 JP3549609B2 JP8037595A JP8037595A JP3549609B2 JP 3549609 B2 JP3549609 B2 JP 3549609B2 JP 8037595 A JP8037595 A JP 8037595A JP 8037595 A JP8037595 A JP 8037595A JP 3549609 B2 JP3549609 B2 JP 3549609B2
- Authority
- JP
- Japan
- Prior art keywords
- cement
- weight
- super
- ultra
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004567 concrete Substances 0.000 title claims description 44
- 230000008439 repair process Effects 0.000 title claims description 13
- 239000000203 mixture Substances 0.000 title claims description 11
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 239000004568 cement Substances 0.000 claims description 40
- 229910000831 Steel Inorganic materials 0.000 claims description 15
- 229910052602 gypsum Inorganic materials 0.000 claims description 15
- 239000010440 gypsum Substances 0.000 claims description 15
- 239000010959 steel Substances 0.000 claims description 15
- 238000002156 mixing Methods 0.000 claims description 13
- 239000003607 modifier Substances 0.000 claims description 13
- 239000000835 fiber Substances 0.000 claims description 10
- XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000003463 adsorbent Substances 0.000 claims description 3
- 238000004080 punching Methods 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 18
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 15
- 239000000292 calcium oxide Substances 0.000 description 9
- 235000012255 calcium oxide Nutrition 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 8
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 235000015165 citric acid Nutrition 0.000 description 5
- 230000005484 gravity Effects 0.000 description 5
- 239000004576 sand Substances 0.000 description 5
- 239000011398 Portland cement Substances 0.000 description 4
- 238000005056 compaction Methods 0.000 description 4
- 238000001723 curing Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 229910000027 potassium carbonate Inorganic materials 0.000 description 3
- 239000000176 sodium gluconate Substances 0.000 description 3
- 235000012207 sodium gluconate Nutrition 0.000 description 3
- 229940005574 sodium gluconate Drugs 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- 229910001570 bauxite Inorganic materials 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 239000013065 commercial product Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000012615 aggregate Substances 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 150000004683 dihydrates Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
Landscapes
- Curing Cements, Concrete, And Artificial Stone (AREA)
Description
【0001】
【産業上の利用分野】
本発明は、既設のコンクリートに新規なコンクリートを打継ぎ、コンクリート構造物を補強する打継ぎ補修工事用の超速硬コンクリート組成物及びそれを用いた超速硬コンクリートの製造方法に関する。
【0002】
【従来の技術とその課題】
従来、コンクリートは、適切な設計や施工を行えば、安全で耐久性のある構造物を構築できる特徴を有しており、補修のいらないメンテナンスフリーの材料と言われていた。
【0003】
しかしながら、近年、コンクリートの早期劣化により耐久性低下が顕在化したコンクリート構造物、あるいは、設計時に想定もされなかった繰り返し荷重の増加等により損傷を受けたコンクリート構造物等が多くなり、これらを補修する必要性が増大している。
【0004】
これらの補修を必要とするコンクリート構造物の補修工法として、劣化した部分をはつり取った既設の旧コンクリートの上面に、緊急を要する場合は、新コンクリートとして超速硬コンクリートを打設し、新旧コンクリートを一体化させ、全体的にコンクリートの厚みを増加したコンクリートの増厚を行うことによりコンクリートを補修する工法が採られている。
この場合、新たに打ち継ぐ新コンクリートの旧コンクリートへの付着強度が重要であり、新コンクリートの付着強度が高く、新旧コンクリートが一体化して、コンクリート厚が増厚されてはじめて補修効果が発揮される。
【0005】
しかしながら、従来は、打ち継がれた新コンクリートにひび割れが発生しやすいため、新旧コンクリートを一体化しても、その増厚効果は減少するという課題があった。
【0006】
近年、高速道路が我々の生活に占める役割の重要性が、質的に、また、量的に増大してきている。
一方、自動車交通の予想以上の伸びと車両の大型化や重量化に伴い、設計時には予想もされなかった損傷を道路構造物は被っている。
特に、高速道路の、鋼材を使用した橋梁のRC床版、即ち、鋼橋のRC床版の損傷は橋梁全体に渡って発生している状況であり、これらに対する早急の対策が求められている。
【0007】
この現象は、東名高速、名神高速、東北道、中央道、及び中国道の各高速道路をはじめ、一般国道にも見られている。
特に、東名高速道路の鋼橋のRC床版は、昭和30年代〜40年代にかけて着工されたものであり、現行の規準による設計に比べ、床版の支点間隔が広いうえに床版厚が薄く主筋と直角方向の鉄筋量が少ない構造になっており、その鋼橋のRC床版の損傷は大きなものである。
【0008】
これら、鋼橋のRC床版の損傷に対し有効な補強工法として、床版上面増厚工事が行われている。
【0009】
東名高速道路では、床版上面増厚工事を、例えば、9日間連続して昼夜1車線の交通規制をして集中的に施工を行うため、超速硬セメントなどを使用し、練り混ぜをはじめとする材料供給を含む全ての作業を交通規制内の道路本線上で実施している。
【0010】
しかしながら、従来の超速硬セメントは、練り上がりコンクリートのスランプロスが大きく、また、硬化体を形成する水和物の生成が早いため、既設の床版コンクリートとの付着強度が十分に得られない等の課題があった。
【0011】
さらに、従来の超速硬セメントを使用した場合、超速硬コンクリートの硬化体にひび割れが発生する等の課題があった。
【0012】
本発明者は、このような現状に鑑み種々検討した結果、特定の材料を使用することにより、作業時間が確保され、十分な振動締固め作業が可能となり、高付着強度でひび割れ抵抗性の高い打継ぎ補修工事用の超速硬コンクリートの製造が可能であるとの知見を得て本発明を完成するに至った。
【0013】
【課題を解決するための手段】
即ち、本発明は、セメント、非晶質カルシウムアルミネート、セッコウ類、及び凝結調整剤を含有してなり、凝結調整剤が、セメント、非晶質カルシウムアルミネート、セッコウ類、及び凝結調整剤からなる超速硬セメント 100 重量部中、 0.05 〜 1.0 重量部である超速硬セメントと、骨材と、必要に応じ鋼繊維とを配合してなる、吸着剤のない打継ぎ補修工事用の超速硬コンクリート組成物であり、該超速硬コンクリート組成物と水とを混合してなる打継ぎ補修工事用の超速硬コンクリートの製造方法である。
【0014】
以下、本発明を詳しく説明する。
【0015】
本発明では、セメント、非晶質カルシウムアルミネート、セッコウ類、及び凝結調整剤を含有する超速硬セメントと、骨材と、必要に応じ鋼繊維とを配合してなる打継ぎ補修工事用の超速硬コンクリート組成物を用いる。
【0016】
ここで超速硬セメントとは、急硬セメントと凝結調整剤を配合するものであり、急硬セメントとは、セメントと急硬成分を含有するものであり、急硬成分とは、非晶質カルシウムアルミネートとセッコウ類からなるものである。
【0017】
本発明で使用するセメントとしては、普通、早強、又は超早強等の各種ポルトランドセメント、これらポルトランドセメントに高炉スラグ等のシリカ質を混合した各種混合セメント等が使用可能であり、これらのうち早強ポルトランドセメントの使用が好ましい。
【0018】
本発明で使用する非晶質カルシウムアルミネート(以下A−CAという)とは、生石灰等のCaO原料と、ボーキサイト等のAl2O3原料を溶融して生成するもので、具体的には、12CaO・7Al2O3、3CaO・Al2O3、又はCaO・Al2O3等に対応する鉱物を主成分とする非晶質の鉱物が挙げられる。
A−CAのうちでも、初期強度発現性が優れていることから、12CaO・7Al2O3を主成分とするものや、CaO・Al2O3を主成分とするものが好ましい。
A−CAの粉末度は、ブレーン値で3,000cm2/g以上が好ましく、4,000〜8,000cm2/gがより好ましい。3,000cm2/g未満では、急硬性が、特に、初期強度の発現性が悪くなる場合がある。
【0019】
本発明で使用するセッコウ類としては、各種セッコウ、例えば、無水、半水、及び二水の各種セッコウの一種又は二種以上が使用可能である。このうち、II型の無水セッコウの使用は強度発現性の面から最も好ましい。
セッコウ類の粉末度は、ブレーン値で4,000cm2/g以上が好ましく、5,000〜9,000cm2/gが高強度発現性の面からより好ましい。4,000cm2/g未満では初期強度発現性が悪くなる場合があり、また、硬化後の膨張が大きくなる場合もある。
セッコウ類の使用量は、A−CA100重量部に対して、50〜300重量部が好ましく、80〜150重量部がより好ましい。50重量部未満では作業時間が確保できず、300重量部を超えると、急硬性が、特に、初期強度の発現性が悪くなる場合、例えば、コンクリートにおいて3時間で240kgf/cm2以上の強度が得にくい場合がある。
【0020】
本発明では、A−CAとセッコウ類を急硬成分として使用する。
急硬成分の使用量は、セメントと急硬成分からなる急硬セメント100重量部中、5〜50重量部が好ましく、20〜30重量部がより好ましい。急硬成分が5重量部未満では強度が不足し、50重量部を超えると作業時間が極端に短縮される場合がある。
【0021】
本発明で使用する凝結調整剤としては、クエン酸、グルコン酸、酒石酸、及びリンゴ酸等のオキシカルボン酸又はそれらのナトリウム、カリウム、及びカルシウム塩等の水溶性塩であり、これらの二種以上を併用することは好ましい。
凝結調整剤の使用量は、超速硬セメント100重量部中、0.05〜1.0重量部であり、0.1〜1.0重量部が好ましい。0.05重量部未満では瞬結して振動締固めに必要な作業時間がとれず、1.0重量部を超えると作業時間が長すぎ、初期強度の発現も悪くなる場合がある。
【0022】
本発明で使用する骨材としては、川砂や川砂利の他、砕砂や砕石等の天然の骨材が挙げられ、そのうち標準粒度範囲に入る骨材の使用が好ましい。
粗骨材の最大寸法は、強度向上、乾燥収縮量の低減、及び振動締固め時の作業性等を考慮して、20〜25mmが好ましい。
【0023】
本発明に使用する鋼繊維としては、特に限定されるものではないが、例えば、土木学会規準「コンクリート用鋼繊維」に適合した鋼繊維を使用する。長さは20〜60mmのものの使用が好ましい。
鋼繊維の使用量は、超速硬コンクリート組成物100容積部中、1.0〜1.5容積部が好ましい。1.0容積部未満では、鋼繊維の混入効果がなく、1.5容積部を超えると作業性が悪くなる場合がある。
【0024】
各材料の混合方法は、安定した品質の超速硬コンクリートを、中断することなく、連続で、一定した練混ぜ速度で供給できれば、特に、限定されるものではなく、連続式やバッチ式のいずれの混合方法も可能である。例えば、超速硬セメント、砂、砂利、及び必要に応じ鋼繊維を連続供給し、スクリュー型オーガーで練り混ぜる方法や、現場バッチ式ミキサで、超速硬セメント、砂、砂利、及び必要に応じ鋼繊維を練り混ぜる方法などが可能である。
また、各材料を同時に混合することも可能であり、凝結調整剤を別に添加することも可能である。
打設方法や養生方法は、特に限定されるものではなく、通常の方法が可能である。
【0025】
【実施例】
以下、本発明を実施例によってさらに詳しく説明する。
【0026】
実施例1
CaO原料とAl2O3原料を電気炉で溶融後、急冷して得られたCaO・Al2O3クリンカーをポットミルで、ブレーン値5,000cm2/gに粉砕してCaO・Al2O3のA−CAを調製した。
調製したA−CA100重量部とセッコウ類100重量部を混合して得た急硬成分を、セメントと急硬成分との合計100重量部に対して、表1に示すように混合して急硬セメントを調製した。
この急硬セメント96.9重量部と、炭酸カリウム2.5重量部、クエン酸0.4重量部、及びグルコン酸ナトリウム0.2重量部からなる凝結調整剤とを混合し、超速硬セメントを調製した。
この超速硬セメント100重量部に、細骨材150重量部と水35重量部配合し、ASTMC305 の規定のモルタルミキサで練り混ぜ、20℃恒温室で凝結時間と圧縮強度を測定した。結果を表1に併記する。
【0027】
<使用材料>
セメント :電気化学工業社製、早強ポルトランドセメント、比重3.12
CaO原料 :市販生石灰
Al2O3原料 :市販ボーキサイト
セッコウ類:II型無水セッコウ、市販品、ブレーン値6,000cm2/g、比重2.90
炭酸カリウム:和光純薬工業社製、試薬1級
クエン酸 :和光純薬工業社製、試薬1級
グルコン酸ナトリウム:和光純薬工業社製、試薬1級
細骨材 :新潟県姫川産川砂、比重2.63
【0028】
<試験方法>
凝結時間 :20℃の恒温室でASTM C403 に準じて測定
圧縮強度 :4×4×16cmの供試体の注水2時間後の圧縮強度を、JIS R 5201に準じて測定
【0029】
【表1】
【0030】
実施例2
急硬セメント100重量部中の急硬成分を30重量部とし、急硬成分中のA−CA100重量部に対するセッコウ類の割合を表2に示すように配合したこと以外は実施例1と同様に行った。結果を表2に併記する。
【0031】
【表2】
【0032】
実施例3
急硬セメント100重量部中の急硬成分の配合量を30重量部として、凝結調整剤としてクエン酸を表3に示すように配合したこと以外は実施例1と同様に行った。結果を表3に併記する。
【0033】
【表3】
【0034】
実施例4
急硬セメント100重量部中の急硬成分を30重量部とし、この急硬セメント96.9重量部と、炭酸カリウム2.5重量部、クエン酸0.4重量部、及びグルコン酸ナトリウム0.2重量部からなる凝結調製剤とを混合し、超速硬セメントを調製した。
この超速硬セメントを用いて、W/C=37%、s/a=55%で、表4に示す配合のコンクリートを調製し、圧縮強度と付着強度を測定した。結果を表4に併記する。
同様に調製したコンクリートを打設し、3日後にその表面のひび割れの有無を観察した。結果を表4に併記する。
【0035】
<使用材料>
粗骨材 :新潟県姫川産川砂利、Gmax=25mm、比重2.66
鋼繊維 :市販品、φ0.6×30mm、比重7.85
【0036】
<試験方法>
圧縮強度 :φ10×20cmの供試体を用い、20℃の封緘養生3時間後、JIS A 1108に準じて測定
付着強度 :建研式付着試験機を使用し、φ10×6cmの供試体で7日後測定
【0037】
【表4】
【0038】
【発明の効果】
本発明により、作業時間が確保されるために十分な振動締固め作業が可能となり、高付着強度でひび割れ抵抗性の高い打継ぎ補修工事用の超速硬コンクリートを製造することができた。[0001]
[Industrial applications]
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a super-hard concrete composition for joint repair work for joining new concrete to existing concrete and reinforcing a concrete structure, and a method for producing a super-hard concrete using the same.
[0002]
[Prior art and its problems]
Conventionally, concrete has a feature of being able to construct a safe and durable structure if properly designed and constructed, and has been called a maintenance-free material requiring no repair.
[0003]
However, in recent years, concrete structures with reduced durability due to early deterioration of concrete, or concrete structures that have been damaged due to an increase in repeated loads that were not assumed at the time of design have increased, and these have been repaired. The need to do so is increasing.
[0004]
As a method of repairing concrete structures that require these repairs, if urgently needed, cast ultra-high-speed hardened concrete as new concrete on the upper surface of the existing concrete where the deteriorated parts have been removed and A method of repairing concrete by integrating the concrete and increasing the thickness of the concrete as a whole has been adopted.
In this case, the bond strength of the new concrete to be newly joined to the old concrete is important, the bond strength of the new concrete is high, the old and new concretes are integrated, and the repair effect is exhibited only when the concrete thickness is increased. .
[0005]
However, in the past, cracks are likely to occur in the new concrete that has been inherited, and there has been a problem that the thickening effect of the old and new concretes is reduced even if they are integrated.
[0006]
In recent years, the importance of the role of highways in our lives has been increasing qualitatively and quantitatively.
On the other hand, road structures have suffered damage that was not anticipated at the time of design due to the unexpected increase in vehicle traffic and the increase in size and weight of vehicles.
In particular, the RC slabs of bridges using steel materials on expressways, that is, RC slabs of steel bridges, are being damaged throughout the entire bridge, and urgent countermeasures are required. .
[0007]
This phenomenon has also been observed on general highways, including the Tomei Expressway, the Meishin Expressway, the Tohoku Expressway, the Chuo Expressway, and the Chugoku Expressway.
In particular, the RC slab of the steel bridge on the Tomei Expressway was constructed during the 1950s and 1940s. Compared with the current standard design, the slab spacing of the slab was wider and the slab thickness was thinner. The structure has a small amount of rebar in the direction perpendicular to the main rebar, and the RC slab of the steel bridge is greatly damaged.
[0008]
As an effective reinforcement method for the damage to the RC slab of the steel bridge, the slab upper surface thickening work is performed.
[0009]
On the Tomei Expressway, to increase the thickness of the deck slab, for example, to control traffic on one lane day and night for nine consecutive days and to concentrate on it, use super-rapid hardening cement and mix it together. All operations, including material supply, are performed on the main roads within the traffic regulations.
[0010]
However, conventional ultra-rapid hardening cement has a large slump loss of the concrete after being kneaded, and a hydrate that forms a hardened body is generated quickly, so that sufficient bonding strength with the existing floor slab concrete cannot be obtained. There were challenges.
[0011]
Furthermore, when the conventional super-rapid hardening cement is used, there is a problem that cracks occur in the hardened body of the super-rapid hardening concrete.
[0012]
The present inventor has conducted various studies in view of such a current situation, and as a result of using a specific material, working time is secured, sufficient vibration compaction work is possible, and high adhesion strength and high crack resistance are achieved. The present inventors have found that it is possible to manufacture ultra-fast-hardened concrete for joint repair work, and have completed the present invention.
[0013]
[Means for Solving the Problems]
That is, the present invention comprises a cement, an amorphous calcium aluminate, gypsum, and a setting modifier, and the setting modifier is a cement, an amorphous calcium aluminate, a gypsum, and a setting modifier. ultrarapid cement in 100 parts by weight of a super-quick cement Ru 0.05-1.0 part by weight der, and aggregate, by blending the if necessary steel fibers, ultra fast curing for punching splicing repair work without adsorbent This is a method for producing a super-hardened concrete for a joint repair work, which is a concrete composition, which is obtained by mixing the super-hardened concrete composition with water.
[0014]
Hereinafter, the present invention will be described in detail.
[0015]
In the present invention, an ultra-high-speed cement for joint repair work comprising blending cement, amorphous calcium aluminate, gypsum, and an ultra-fast-hardening cement containing a setting modifier, aggregate, and steel fiber as necessary. A hard concrete composition is used.
[0016]
Here, the ultra-rapidly hardened cement is a compounding of a rapidly hardened cement and a setting modifier, and the rapidly hardened cement contains cement and a rapidly hardened component. It is composed of aluminate and gypsum.
[0017]
As the cement used in the present invention, various Portland cements, such as ordinary, fast-strength, or ultra-high-strength, various mixed cements obtained by mixing siliceous materials such as blast furnace slag with these Portland cements can be used. The use of early strength Portland cement is preferred.
[0018]
The amorphous calcium aluminate (A-CA) used in the present invention is produced by melting a CaO raw material such as quicklime and an Al 2 O 3 raw material such as bauxite. 12CaO · 7Al 2 O 3, 3CaO · Al 2 O 3, or amorphous minerals include mainly composed of minerals corresponding to CaO · Al 2 O 3 or the like.
Among A-CA, since the initial strength development is excellent, as the main component 12CaO · 7Al 2 O 3 and, as a main component CaO · Al 2 O 3 is preferred.
Fineness of A-CA is preferably 3,000 cm 2 / g or more in Blaine value, 4,000~8,000cm 2 / g is more preferable. If it is less than 3,000 cm 2 / g, rapid hardening, particularly, the development of initial strength may be deteriorated.
[0019]
As gypsum used in the present invention, various gypsums, for example, one or more of various gypsums of anhydrous, hemihydrate, and dihydrate can be used. Of these, the use of type II anhydrous gypsum is most preferable from the viewpoint of strength development.
The fineness of the gypsum is preferably 4,000 cm 2 / g or more in terms of Blaine value, and more preferably 5,000 to 9,000 cm 2 / g in terms of high strength. If it is less than 4,000 cm 2 / g, the initial strength expression may be poor, and the expansion after curing may be large.
The amount of gypsum used is preferably 50 to 300 parts by weight, more preferably 80 to 150 parts by weight, based on 100 parts by weight of A-CA. If the amount is less than 50 parts by weight, the working time cannot be secured. If the amount exceeds 300 parts by weight, rapid hardening, particularly when initial strength is poor, for example, a concrete having a strength of 240 kgf / cm 2 or more in 3 hours. It may be difficult to obtain.
[0020]
In the present invention, A-CA and gypsum are used as rapid hardening components.
The amount of the rapidly hardened component is preferably 5 to 50 parts by weight, more preferably 20 to 30 parts by weight, in 100 parts by weight of the rapidly hardened cement comprising the cement and the rapidly hardened component. If the rapid hardening component is less than 5 parts by weight, the strength is insufficient, and if it exceeds 50 parts by weight, the working time may be extremely shortened.
[0021]
Examples of the setting modifier used in the present invention include oxycarboxylic acids such as citric acid, gluconic acid, tartaric acid, and malic acid, and water-soluble salts thereof such as sodium, potassium, and calcium salts. It is preferable to use in combination.
The amount of the setting modifier to be used is 0.05 to 1.0 part by weight, preferably 0.1 to 1.0 part by weight, based on 100 parts by weight of the ultra-fast setting cement. If the amount is less than 0.05 parts by weight, the working time required for vibration compaction may not be obtained due to the instantaneous connection. If the amount exceeds 1.0 part by weight, the working time may be too long, and the initial strength may be deteriorated.
[0022]
Examples of the aggregate used in the present invention include natural aggregates such as crushed sand and crushed stone in addition to river sand and river gravel, and among them, the use of aggregates within a standard particle size range is preferable.
The maximum size of the coarse aggregate is preferably 20 to 25 mm in consideration of the improvement in strength, the reduction in the amount of drying shrinkage, the workability during compaction by vibration, and the like.
[0023]
Although the steel fiber used in the present invention is not particularly limited, for example, a steel fiber conforming to the Japan Society of Civil Engineers standard “steel fiber for concrete” is used. It is preferable to use one having a length of 20 to 60 mm.
The amount of the steel fiber used is preferably 1.0 to 1.5 parts by volume based on 100 parts by volume of the ultra-hard concrete composition. If the amount is less than 1.0 part by volume, there is no effect of mixing steel fibers, and if it exceeds 1.5 parts by volume, workability may be deteriorated.
[0024]
The mixing method of each material is not particularly limited as long as it can supply a stable quality of ultra-rapid hardened concrete continuously without interruption at a constant mixing speed, and any of a continuous type or a batch type can be used. Mixing methods are also possible. For example, a method of continuously supplying super-hardened cement, sand, gravel, and, if necessary, steel fiber and kneading with a screw type auger, or a super-high-speed hardened cement, sand, gravel, and, if necessary, And the like.
Further, each material can be mixed at the same time, and a setting regulator can be separately added.
The casting method and the curing method are not particularly limited, and ordinary methods can be used.
[0025]
【Example】
Hereinafter, the present invention will be described in more detail with reference to Examples.
[0026]
Example 1
A CaO raw material and an Al 2 O 3 raw material are melted in an electric furnace, and the CaO · Al 2 O 3 clinker obtained by quenching is pulverized by a pot mill to a Blaine value of 5,000 cm 2 / g to obtain CaO · Al 2 O 3. A-CA was prepared.
The rapidly hardened component obtained by mixing 100 parts by weight of the prepared A-CA and 100 parts by weight of gypsum was mixed and rapidly hardened as shown in Table 1 with respect to a total of 100 parts by weight of the cement and the rapidly hardened component. A cement was prepared.
96.9 parts by weight of the rapidly hardened cement, 2.5 parts by weight of potassium carbonate, 0.4 parts by weight of citric acid, and a setting modifier consisting of 0.2 parts by weight of sodium gluconate are mixed to prepare an ultra-fast-hardened cement. Prepared.
150 parts by weight of fine aggregate and 35 parts by weight of water were blended with 100 parts by weight of this ultra-hardened cement, kneaded with a mortar mixer specified by ASTM C305, and the setting time and compressive strength were measured in a constant temperature room at 20 ° C. The results are also shown in Table 1.
[0027]
<Material used>
Cement: Portland cement manufactured by Denki Kagaku Kogyo Co., Ltd., specific gravity 3.12
CaO raw material: Commercial quicklime Al 2 O 3 raw material: Commercial bauxite gypsum: Type II anhydrous gypsum, commercial product, Blaine value 6,000 cm 2 / g, specific gravity 2.90
Potassium carbonate: Wako Pure Chemical Industries, Reagent Grade 1 Citric Acid: Wako Pure Chemical Industries, Reagent Grade Sodium Gluconate: Wako Pure Chemical Industries, Reagent Grade 1 Fine Aggregate: Himekawa River Sand, Niigata Specific gravity 2.63
[0028]
<Test method>
Setting time: Measured in a constant temperature room at 20 ° C. according to ASTM C403 Compressive strength: Measured compressive strength of a 4 × 4 × 16 cm specimen 2 hours after water injection according to JIS R5201
[Table 1]
[0030]
Example 2
The same as in Example 1 except that the hardened component in the hardened component was 30 parts by weight and the ratio of gypsum to 100 parts by weight of A-CA in the hardened component was mixed as shown in Table 2. went. The results are also shown in Table 2.
[0031]
[Table 2]
[0032]
Example 3
The procedure was performed in the same manner as in Example 1 except that the amount of the rapidly hardened component in 100 parts by weight of the rapidly hardened cement was 30 parts by weight, and citric acid was compounded as a setting regulator as shown in Table 3. The results are also shown in Table 3.
[0033]
[Table 3]
[0034]
Example 4
The rapid-hardening component in 100 parts by weight of the rapid-hardening cement was 30 parts by weight, 96.9 parts by weight of the rapid-hardening cement, 2.5 parts by weight of potassium carbonate, 0.4 parts by weight of citric acid, and 0.1 part by weight of sodium gluconate. An ultra-fast setting cement was prepared by mixing with 2 parts by weight of a setting modifier.
Using this ultra-rapid hardening cement, concrete having the composition shown in Table 4 was prepared at W / C = 37% and s / a = 55%, and the compressive strength and adhesive strength were measured. The results are shown in Table 4.
Concrete prepared in the same manner was cast, and three days later, the surface was observed for cracks. The results are shown in Table 4.
[0035]
<Material used>
Coarse aggregate: Gravel from Himekawa, Niigata Prefecture, Gmax = 25 mm, specific gravity 2.66
Steel fiber: Commercial product, φ0.6 × 30 mm, specific gravity 7.85
[0036]
<Test method>
Compressive strength: Using a specimen of φ10 × 20 cm, after 3 hours of curing at 20 ° C., measured according to JIS A 1108 Adhesion strength: After 7 days with a specimen of φ10 × 6 cm using a Kenken-type adhesion tester Measurement
[Table 4]
[0038]
【The invention's effect】
ADVANTAGE OF THE INVENTION According to this invention, since the working time was ensured, sufficient vibration compaction work was attained, and it was possible to manufacture ultra-fast-hardened concrete for joint repair work having high adhesion strength and high crack resistance.
Claims (3)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8037595A JP3549609B2 (en) | 1995-04-05 | 1995-04-05 | Super-hard concrete composition for joint repair work and method for producing super-hard concrete using the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8037595A JP3549609B2 (en) | 1995-04-05 | 1995-04-05 | Super-hard concrete composition for joint repair work and method for producing super-hard concrete using the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH08277156A JPH08277156A (en) | 1996-10-22 |
| JP3549609B2 true JP3549609B2 (en) | 2004-08-04 |
Family
ID=13716539
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8037595A Expired - Lifetime JP3549609B2 (en) | 1995-04-05 | 1995-04-05 | Super-hard concrete composition for joint repair work and method for producing super-hard concrete using the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3549609B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107459327A (en) * | 2017-08-03 | 2017-12-12 | 长安大学 | Suitable for low temperature or the fast repairing concrete material of construction in minus-temperature environment |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3317429B2 (en) * | 1995-08-07 | 2002-08-26 | 住友金属鉱山株式会社 | Repair mortar |
| JP3445932B2 (en) * | 1998-04-17 | 2003-09-16 | 新東京国際空港公団 | Jointing concrete and jointing method using the joining concrete |
| JPH11310448A (en) | 1998-04-28 | 1999-11-09 | New Tokyo International Airport Authority | Concrete composition for overlaying execution and its hardened product |
| KR20000006739A (en) * | 1999-10-25 | 2000-02-07 | 박정환 | Production method of concrete using iron core |
| JP4583220B2 (en) * | 2005-03-30 | 2010-11-17 | 住友大阪セメント株式会社 | Method for improving fluidity of ultrafast hard concrete and fluidity improver for ultrafast concrete |
| JP2007320834A (en) * | 2006-06-05 | 2007-12-13 | Denki Kagaku Kogyo Kk | Ultrafast cement composition, ultrafast cement concrete composition, and ultrafast cement concrete |
| JP2007320835A (en) * | 2006-06-05 | 2007-12-13 | Denki Kagaku Kogyo Kk | Ultrafast cement composition, ultrafast cement concrete composition, and ultrafast cement concrete |
| JP6308581B2 (en) * | 2013-12-05 | 2018-04-11 | 株式会社トクヤマエムテック | Concrete composition |
-
1995
- 1995-04-05 JP JP8037595A patent/JP3549609B2/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107459327A (en) * | 2017-08-03 | 2017-12-12 | 长安大学 | Suitable for low temperature or the fast repairing concrete material of construction in minus-temperature environment |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH08277156A (en) | 1996-10-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101265066B (en) | High folding resistance road concrete material and preparing method thereof | |
| JP5577651B2 (en) | Rapid hardening cement | |
| JP3549609B2 (en) | Super-hard concrete composition for joint repair work and method for producing super-hard concrete using the same | |
| CN107793098A (en) | High-fluidity rapid repair mortar | |
| JP7085050B1 (en) | Cement admixture, hard mortar concrete material, hard mortar concrete composition, and hardened material | |
| JP2000272943A (en) | Cement admixture, cement composition, and grout material | |
| JP3122532B2 (en) | Road composition | |
| JP4462466B2 (en) | Non-shrink mortar composition and fast-curing non-shrink mortar composition | |
| CN107555919B (en) | Bridge grouting material and method for rapidly repairing bridge expansion joint by adopting same | |
| JP5877580B2 (en) | Road repair material | |
| JP4709677B2 (en) | Premix high toughness polymer cement mortar material and high toughness polymer cement mortar | |
| JP2581803B2 (en) | Cement admixture and cement composition | |
| JP4481510B2 (en) | Permeable concrete joint paste or mortar | |
| CN112601726A (en) | Hardening agent for quick-hardening concrete delivered in ready-mixed concrete mode, quick-hardening concrete material delivered in ready-mixed concrete mode, quick-hardening concrete composition delivered in ready-mixed concrete mode and preparation method thereof | |
| JP3162758B2 (en) | Cement composition and quick-setting method | |
| JP2004210557A (en) | Grout composition | |
| JP7343284B2 (en) | Rapid hardening cement, cement mortar, cement concrete, road repair materials, and road repair methods | |
| JP2005324982A (en) | Super-quick hardening cement composition | |
| JP2013139348A (en) | Fast curing composition, mortar and concrete | |
| JP4413605B2 (en) | Cement admixture and fast-curing cement composition | |
| JP2019099444A (en) | Construction method of mortar or concrete using ultra rapid hardening cement | |
| Hooton et al. | Type IL cement use in precast, prestressed concrete | |
| JP2002097051A (en) | Hydraulic composition | |
| JP7792192B2 (en) | Rapid-hardening mortar composition for use on sloped surfaces and rapid-hardening mortar for use on sloped surfaces | |
| JP5885231B2 (en) | Concrete for paving |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20040420 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20040421 |
|
| R150 | Certificate of patent (=grant) or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| S531 | Written request for registration of change of domicile |
Free format text: JAPANESE INTERMEDIATE CODE: R313531 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20080430 Year of fee payment: 4 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090430 Year of fee payment: 5 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090430 Year of fee payment: 5 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100430 Year of fee payment: 6 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100430 Year of fee payment: 6 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110430 Year of fee payment: 7 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130430 Year of fee payment: 9 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130430 Year of fee payment: 9 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20140430 Year of fee payment: 10 |
|
| EXPY | Cancellation because of completion of term |