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JP3552304B2 - Rock wool molding medium - Google Patents
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JP3552304B2 - Rock wool molding medium - Google Patents

Rock wool molding medium Download PDF

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Publication number
JP3552304B2
JP3552304B2 JP26610694A JP26610694A JP3552304B2 JP 3552304 B2 JP3552304 B2 JP 3552304B2 JP 26610694 A JP26610694 A JP 26610694A JP 26610694 A JP26610694 A JP 26610694A JP 3552304 B2 JP3552304 B2 JP 3552304B2
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JP
Japan
Prior art keywords
rock wool
granulated
adhesive
molding medium
medium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP26610694A
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Japanese (ja)
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JPH08103159A (en
Inventor
勤治 高橋
敏夫 小菅
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nitto Boseki Co Ltd
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Nitto Boseki Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Priority to JP26610694A priority Critical patent/JP3552304B2/en
Publication of JPH08103159A publication Critical patent/JPH08103159A/en
Application granted granted Critical
Publication of JP3552304B2 publication Critical patent/JP3552304B2/en
Anticipated expiration legal-status Critical
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Classifications

    • Y02P60/216

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  • Cultivation Of Plants (AREA)
  • Hydroponics (AREA)

Description

【0001】
【産業上の利用分野】
本発明は、野菜等のハウス栽培や道路などの傾斜土壌側面に草木を植え付ける栽培用培地に関する。
【0002】
【従来の技術】
従来、粒状化ロックウールは野菜等の培地として平箱に敷き詰めたり、実開平2−36956に示されるように粒状化ロックウールを袋状物に入れて使用されている。平箱に敷き詰める方法は粒状化ロックウールを詰め込んだ袋から取り出し均一な厚さに敷き詰めるので粒状化ロックウールの微粉が汗ばんだ皮膚を刺激したり、マスクをするなど大変な困難と手間の掛かる作業方法である。また実開平2−36956に示される方法では粒状化ロックウールの微粉による問題は解決されるが道路などの傾斜土壌側面に用いると袋状物の中の粒状化ロックウールが袋内でより低い位置に自由に移動するため傾斜側面に沿って均一な厚さを保つことができず播種や定植に支障を来すなどの問題がある。
【0003】
【発明が解決しようとする課題】
本発明は前記問題を解決し、粒状化ロックウールの優れた保水性および通気性を維持すると共に粉塵の立たない取扱い性の良いロックウール成型培地を提供することを課題とする。
【0004】
【課題を解決するための手段】
前記課題を解決する、請求項1の発明は、粒状化ロックウールが互いに接着剤で結合しているロックウール成型培地であり、刺激感がなく取扱い性が良いことを特徴とする。
【0005】
請求項2の発明は、接着剤で結合した粒状化ロックウールが通根性不織布に貼着しているロックウール成型培地であり、粒状化ロックウールの移動がなく取扱い性がよい。また、保水性が良く作物の根部に適するとともに柔軟性を有することを特徴とする。
【0006】
請求項3の発明は、接着剤で結合した粒状化ロックウールが不通根性不織布に貼着しているロックウール成型培地である。
【0007】
以下本発明について説明する。
本発明の粒状化ロックウールはスラグ、珪酸質岩石、玄武岩、石灰石等の原料を溶融、繊維化、集綿、積層したロックウールをグラニュレーター等の設備によって所定量かきとり次いでかきとったロックウールをトロンメル等の設備により回転させながら所定の径に粒状化したもの、またはハンマーミル、リファイナー等で5〜30mmの大きさとし、ニーダー、ブレンダー等で所定の径に粒状化したものである。本発明のロックウール成型培地に用いられる粒径は1〜25mm、嵩密度は0.08〜0.27g/cmであり、好ましくは粒径は2〜7mm、嵩密度は0.13〜0.15g/cmである。その理由は粒径が1mmより小さいと気層が減少するなどの欠点があり、25mmより大きいと液層が減少するためである。また嵩密度が0.08g/cmより小さいと粒状が崩れやすく、0.27g/cmより大きいと根の伸長を妨げることと、単位面積当たりの使用量が増加し栽培資材費が上昇するためである。
【0008】
粒状化ロックウールの結合に使用される接着剤としては澱粉、ポリビニルアルコール等の水溶性接着剤、SBR、CR等の合成ゴム系接着剤、フェノール樹脂、メラミン樹脂等の熱硬化型または熱可塑性の接着剤が使用される。
【0009】
粒状化ロックウールへの接着剤の塗布方法としては以下の方法がある
接着剤溶液を粒状化ロックウールに含浸混合し乾燥硬化する方法。この方法には澱粉、ポリビニルアルコール等の水溶性接着剤が適する。使用量は粒状化ロックウール100重量部に対し8〜13重量部である。この方法で得られるロックウール成型培地は硬く板状であるのでトマト、キュウリ、イチゴ等の果菜類やバラ、ガーベラ等の切花類に使用する栽培床に適する。
【0010】
接着剤溶液を粒状化ロックウールに吹き付け乾燥硬化する方法。この方法には水溶性接着剤、合成ゴム系接着剤、熱硬化型接着剤いずれも使用できるがSBR、CR等の合成ゴム系接着剤を溶剤に溶解または分散して霧状で吹き付ける場合には他の接着剤に比べ柔軟性のあるロックウール成型培地が得られる。該ロックウール成型培地は芝、牧草、傾斜土壌側面の緑化等に使用するのに適する。
【0011】
スラグ、珪酸質岩石、玄武岩、石灰石等の原料を溶融、繊維化する際接着剤をロックウール繊維に吹き付け、該接着剤が未硬化の状態で粒状化しその後で乾燥硬化する方法。この方法にはフェノール樹脂、メラミン樹脂等の熱硬化型接着剤が適する。該方法で得られるロックウール成型培地は良好な保水性、通気性及び柔軟性を有するので芝、牧草、傾斜土壌側面の緑化等に使用するのに適する。
【0012】
請求項2の発明に使用される通根性布帛とは粒状化ロックウール培地で伸長した植物の根が布帛を通して大地等に根を張ることができる布帛である。該布帛は織布であっても不織布であっても根を通すと共に粒状化ロックウールが容易に飛び出てこなければよい。通根性布帛としては透光率80%以上の布帛でたとえばユニチカ(株)のパスライト等がある。また、実開平2−36956号に記載される布帛の細孔の径が500〜1000μmであることも1つの指標である。
【0013】
請求項3の発明に使用される不通根性布帛とは粒状化ロックウール培地で伸長した植物の根が布帛を通さない布帛である。該布帛は織布であっても不織布であっても根及び粒状化ロックウールが容易に飛び出てこなければよい。不通根性布帛としては透光率60%未満の布帛でたとえばユニチカ(株)のラブシート20507FLD等がある。また、実開平2−36956号に記載される布帛の細孔の径が10μm以下であることも1つの指標である。また布帛に銅化合物等の薬品を塗布して根がでないようにしてもよい。この場合は布帛の細孔の径は10μmよりある程度大きくてもよい。
【0014】
通根性布帛または不通根性布帛への粒状化ロックウールの貼着は粒状化ロックウールを接着剤で結合するのと同時にしてもよいし、粒状化ロックウールを接着剤で結合した後通根性布帛または不通根性布帛と接着剤によって貼着してもよい。
【0015】
【作用】
本発明のロックウール成型培地は粒状化ロックウールと粒状化ロックウールが接着剤によって結合されているので傾斜地に施工しても粒状化ロックウールが低い位置に移動することはなく、通根性布帛または不通根性布帛を貼着したものは特にその取扱いが便利であり作業能率が著しく向上する。さらに接着剤の塗布の方法等によって硬い板状のものからフレキシブルなものまで自由に選択製造できるので傾斜地、屋根上、屋上等等その場に最も適した状態で野菜や草木を生育することができる。
【0016】
【実施例】
[実施例1]
公知の方法でスラグを主とする原料を溶融繊維化し粒状化して得た粒状化ロックウール(粒径2〜7mm、嵩密度0.13g/cm)100重量部、澱粉(三晶(株)製 商品名グアパック)10重量部、水7000重量部をニーダーで5分間ミキシングした後、厚さ20mm、巾300mm、長さ600mmの型枠に入れ水分率150%とした後85℃で乾燥し厚さ20mm、巾300mm、長さ600mm嵩密度0.37g/cmの本発明のロックウール成型培地を得た。
【0017】
[実施例2]
市販の巾300mmの通根性不織布(ユニチカ(株)製 パスライト透光率85%)を速度1m/minで移動し、その上から粒状化ロックウール(粒径2〜7mm、嵩密度0.13g/cm)を2.5kg/minの割合で落下させながら該粒状化ロックウールに対し合成ゴム系接着剤(コニシ(株)製 商品名 GZ−5)を20g/m(固形分)の割合で吹き付け厚さ30mmの本発明のロックウール成型培地を得た。
【0018】
[実施例3]
市販の巾300mmの不通根性不織布(ユニチカ(株)製 ラブシート20507FLD 透光率45%)を速度1m/minで移動し、その上から粒状化ロックウール(粒径2〜7mm、嵩密度0.13g/cm)を2.5kg/minの割合で落下させながら該粒状化ロックウールに対し合成ゴム系接着剤(コニシ(株)製 商品名 GZ−5)を20g/m(固形分)の割合で吹き付け厚さ30mmの本発明のロックウール成型培地を得た。
【0019】
[実施例4]
公知の方法でスラグを主とする原料を溶融繊維化し粒状化して得た粒状化ロックウール(粒径2〜7mm、嵩密度0.13g/cm)1kgをブレンダーに入れ、バインダー(組成:フエノール樹脂20重量%(群栄化学(株)製)、界面活性剤5重量%(松本油脂(株)製)、水75重量%)80mlを吹き付けながら十分にブレンドし、厚さ30mm、巾300mm、長さ10mに成型し、250℃で13分間乾燥硬化して本発明のロックウール成型培地を得た。
【0020】
[実施例5]
公知の方法でスラグを主とする原料を溶融し繊維化する際ロックウール繊維にバインダー(組成:フエノール樹脂20重量%(群栄化学(株)製)、界面活性剤5重量%(松本油脂(株)製)、水75重量%)をロックウール繊維重量の2.5重量%(固形分)を吹き付け、バインダーが未硬化の状態で粒径10mm以下にリファイナーで切断し、さらにブレンダーで十分に粒状化した後厚さ30mm、巾300mm、長さ10mに成型し、250℃で13分間硬化し本発明のロックウール成型培地を得た。
【0021】
[試験]
実施例2で得た本願発明のロックウール成型培地(厚さ30mm、巾300mm、長さ10m)に硫酸アンモニア1g/リットルの培養液10リットルを灌水し、発芽させたケンタッキー・31・フェスキュー(サカタの種)6gを播種した。温室で育苗をおこない、培地底面より根が伸長した時点で傾斜角30°の土壌側面に培地を張り付け、釘で四隅を固定し水を灌水した。
2週間後傾斜地の上部の根も下部の根と同様に土壌内に伸長しており、傾斜地の上部であっても粒状化ロックウールが移動することなく培地として有効に働いていることが確認された。
【0022】
【発明の効果】
本発明のロックウール成型培地は、実施例1〜5に示すように粒状化ロックウールが互いに接着剤で結合されているので粒状化ロックウールのもつ優れた通気性および保水性を維持しながら板状あるいはシート状で取扱うことができさらにロックウールの粉塵の発生が少ないので極めて優れた作業性が得られる。また本発明のロックウール成型培地は板状の硬いものから柔軟性に富むものと施工する基盤に適応したものが選べ、傾斜地でも培地が均一な厚さを保持するので播種や定植に支障を来すことはない。さらに必要に応じて不通根性不織布あるいは通根性不織布に粒状化ロックウールを貼り合わせたロックウール成型培地をもちいると取扱い性はより優れるし、施工する基盤に植物が根を下ろした方がよい場合あるいは悪い場合にそれぞれ適応させて用いることができる効果がある。
[0001]
[Industrial applications]
TECHNICAL FIELD The present invention relates to a culture medium for cultivating greenhouses such as vegetables or planting plants on sloped side surfaces such as a road.
[0002]
[Prior art]
Conventionally, granulated rock wool has been used as a medium for vegetables or the like, spread over a flat box, or granulated rock wool in a bag as shown in Japanese Utility Model Application Laid-Open No. 2-36956. The method of laying in a flat box is to take out from the bag packed with granulated rock wool and spread it to a uniform thickness, so that fine powder of granulated rock wool irritates sweaty skin, masks, etc. Is the way. In the method disclosed in Japanese Utility Model Application Laid-Open No. 2-36956, the problem caused by the fine powder of the granulated rock wool can be solved. In addition, there is a problem that it is not possible to maintain a uniform thickness along the inclined side surface because it moves freely, and sowing and planting are hindered.
[0003]
[Problems to be solved by the invention]
An object of the present invention is to solve the above problems and to provide a rock wool molding medium which maintains excellent water retention and air permeability of granulated rock wool and is easy to handle without dust.
[0004]
[Means for Solving the Problems]
The invention of claim 1, which solves the above-mentioned problem, is a rock wool molding medium in which granulated rock wool is bonded to each other with an adhesive, and is characterized by having no irritating feeling and good handleability.
[0005]
The invention according to claim 2 is a rock wool molding medium in which granulated rock wool bonded with an adhesive is stuck to a root-permeable nonwoven fabric, and there is no movement of the granulated rock wool, and the handleability is good. It is also characterized by good water retention and suitable for the roots of crops and having flexibility.
[0006]
The invention of claim 3 is a rock wool molding medium in which granulated rock wool bonded with an adhesive is stuck to a non-conductive nonwoven fabric.
[0007]
Hereinafter, the present invention will be described.
The granulated rock wool of the present invention is obtained by melting a raw material such as slag, siliceous rock, basalt, and limestone, fibrillating, collecting, laminating rock wool with a granulator or the like to a predetermined amount, and then scraping the rock wool. It is granulated to a predetermined diameter while rotating by equipment such as trommel, or granulated to a predetermined diameter by a hammer mill, refiner, or the like, and granulated to a predetermined diameter by a kneader, blender, or the like. The particle size used in the rock wool molding medium of the present invention is 1 to 25 mm, the bulk density is 0.08 to 0.27 g / cm 3 , preferably the particle size is 2 to 7 mm, and the bulk density is 0.13 to 0. .15 g / cm 3 . The reason for this is that if the particle size is smaller than 1 mm, there is a disadvantage that the gas phase decreases, and if it is larger than 25 mm, the liquid layer decreases. When the bulk density is less than 0.08 g / cm 3 , the granularity is easily broken, and when the bulk density is more than 0.27 g / cm 3 , the elongation of roots is hindered, the amount used per unit area increases, and the cost of cultivation materials increases. That's why.
[0008]
Adhesives used for bonding granulated rock wool include starch, water-soluble adhesives such as polyvinyl alcohol, synthetic rubber-based adhesives such as SBR and CR, and thermosetting or thermoplastic materials such as phenolic resins and melamine resins. An adhesive is used.
[0009]
The following methods can be used to apply the adhesive to the granulated rock wool: a method in which an adhesive solution is impregnated into the granulated rock wool, mixed, and dried and cured. A water-soluble adhesive such as starch or polyvinyl alcohol is suitable for this method. The amount used is 8 to 13 parts by weight based on 100 parts by weight of granulated rock wool. Since the rock wool molding medium obtained by this method is hard and plate-shaped, it is suitable for cultivation beds used for fruits and vegetables such as tomato, cucumber and strawberry, and cut flowers such as rose and gerbera.
[0010]
A method in which an adhesive solution is sprayed on granulated rock wool and dried and cured. In this method, any of a water-soluble adhesive, a synthetic rubber adhesive, and a thermosetting adhesive can be used. However, when a synthetic rubber adhesive such as SBR or CR is dissolved or dispersed in a solvent and sprayed in a mist state, A rock wool molding medium that is more flexible than other adhesives can be obtained. The rock wool molding medium is suitable for use in turf, pasture, greening of sloped soil side and the like.
[0011]
When melting and fibrillating raw materials such as slag, siliceous rock, basalt, and limestone, an adhesive is sprayed on rock wool fibers, the adhesive is granulated in an uncured state, and then dried and cured. Thermosetting adhesives such as phenolic resins and melamine resins are suitable for this method. The rock wool molding medium obtained by this method has good water retention, air permeability, and flexibility, and thus is suitable for use in turf, grass, greening of sloped soil side surfaces, and the like.
[0012]
The root-permeable cloth used in the second aspect of the present invention is a cloth in which the roots of a plant grown on a granulated rock wool medium can set roots on the ground through the cloth. Regardless of whether the fabric is a woven fabric or a nonwoven fabric, it is sufficient that the rock wool passes through the roots and the granulated rock wool does not easily come out. As the root-permeable cloth, there is a cloth having a light transmittance of 80% or more, for example, Pathlight of Unitika Co., Ltd. Another index is that the diameter of the pores of the fabric described in Japanese Utility Model Application Laid-Open No. 2-36956 is 500 to 1000 μm.
[0013]
The impervious root cloth used in the invention of claim 3 is a cloth that does not allow the root of a plant elongated in a granulated rock wool medium to pass through the cloth. The fabric may be a woven fabric or a non-woven fabric as long as the roots and granulated rock wool do not easily come out. The non-conductive cloth having a light transmittance of less than 60% includes, for example, Lovesheet 20507 FLD manufactured by Unitika Ltd. Another index is that the pore diameter of the fabric described in Japanese Utility Model Application Laid-Open No. 2-36956 is 10 μm or less. Alternatively, a chemical such as a copper compound may be applied to the cloth to prevent roots. In this case, the diameter of the pores of the fabric may be somewhat larger than 10 μm.
[0014]
The application of the granulated rock wool to the root-permeable fabric or the impervious root fabric may be performed at the same time as bonding the granulated rock wool with an adhesive or after bonding the granulated rock wool with an adhesive. Alternatively, it may be adhered to an impervious fabric with an adhesive.
[0015]
[Action]
Since the rock wool molding medium of the present invention has granulated rock wool and granulated rock wool bonded by an adhesive, the granulated rock wool does not move to a lower position even when applied on an inclined ground, and the root-containing cloth or Those to which the impervious fabric is adhered are particularly convenient to handle and work efficiency is remarkably improved. Furthermore, it is possible to freely select and manufacture from a hard plate to a flexible one by a method of applying an adhesive, so that vegetables and plants can be grown in a state most suitable for the place such as a slope, a roof, a roof, etc. .
[0016]
【Example】
[Example 1]
100 parts by weight of granulated rock wool (particle diameter: 2 to 7 mm, bulk density: 0.13 g / cm 3 ) obtained by melting and granulating a raw material mainly composed of slag by a known method, starch (Sansei Co., Ltd.) After mixing 10 parts by weight and 7,000 parts by weight of water in a kneader for 5 minutes, put in a mold having a thickness of 20 mm, a width of 300 mm, and a length of 600 mm to a moisture content of 150%, and then dry at 85 ° C. A rock wool molding medium of the present invention having a thickness of 20 mm, a width of 300 mm, a length of 600 mm and a bulk density of 0.37 g / cm 3 was obtained.
[0017]
[Example 2]
A commercially available 300 mm-wide root-permeable nonwoven fabric (passlight transmittance: 85%, manufactured by Unitika Ltd.) is moved at a speed of 1 m / min, and granulated rock wool (particle size: 2 to 7 mm, bulk density: 0.13 g) is moved from above. / Cm 3 ) at a rate of 2.5 kg / min while applying a synthetic rubber-based adhesive (trade name: GZ-5, manufactured by Konishi Co., Ltd.) to the granulated rock wool at a rate of 20 g / m 2 (solid content). A rock wool molding medium of the present invention having a sprayed thickness of 30 mm was obtained at a given ratio.
[0018]
[Example 3]
A commercially available non-conductive nonwoven fabric having a width of 300 mm (Lab sheet 20507 FLD manufactured by Unitika Ltd., light transmittance: 45%) is moved at a speed of 1 m / min, and granulated rock wool (particle size: 2 to 7 mm, bulk density: 0. 13 g / cm 3 ) at a rate of 2.5 kg / min while applying a synthetic rubber-based adhesive (trade name: GZ-5, manufactured by Konishi Co., Ltd.) to the granulated rock wool at 20 g / m 2 (solid content). To obtain a rock wool molding medium of the present invention having a sprayed thickness of 30 mm.
[0019]
[Example 4]
1 kg of granulated rock wool (particle diameter: 2 to 7 mm, bulk density: 0.13 g / cm 3 ) obtained by melting and fibrillating a raw material mainly composed of slag by a known method is put into a blender, and a binder (composition: phenol) Resin 20% by weight (manufactured by Gunei Chemical Co., Ltd.), surfactant 5% by weight (manufactured by Matsumoto Yushi Co., Ltd.), water 75% by weight) are sufficiently blended while spraying, and are 30 mm thick, 300 mm wide. It was molded to a length of 10 m and dried and cured at 250 ° C. for 13 minutes to obtain a rock wool molding medium of the present invention.
[0020]
[Example 5]
When a raw material mainly composed of slag is melted and fiberized by a known method, a binder (composition: 20% by weight of a phenolic resin (manufactured by Gunei Chemical Co., Ltd.)) and 5% by weight of a surfactant (Matsumoto Yushi ( Co., Ltd.) and water (75% by weight) are sprayed with 2.5% by weight (solid content) of the weight of rock wool fiber, cut with a refiner to a particle size of 10 mm or less in an uncured state, and then sufficiently mixed with a blender. After granulation, the mixture was molded into a thickness of 30 mm, a width of 300 mm, and a length of 10 m, and cured at 250 ° C. for 13 minutes to obtain a rock wool molding medium of the present invention.
[0021]
[test]
A Kentucky 31 fescue (10 g) was sprinkled with 10 g of a culture solution of 1 g / l of ammonium sulfate and germinated on the rock wool molding medium (thickness 30 mm, width 300 mm, length 10 m) of the present invention obtained in Example 2 and germinated. 6 g of Sakata seeds were sown. The seedlings were raised in a greenhouse, and when the roots extended from the bottom of the medium, the medium was attached to the side of the soil at an inclination angle of 30 °, and the four corners were fixed with nails and watered.
Two weeks later, the upper roots of the sloping land also extended into the soil like the lower roots, and it was confirmed that even in the upper part of the sloping ground, the granulated rock wool was effectively working as a medium without moving. Was.
[0022]
【The invention's effect】
As shown in Examples 1 to 5, the rock wool molding medium of the present invention uses a plate while maintaining the excellent air permeability and water retention of the granulated rock wool because the granulated rock wool is bonded to each other with an adhesive. It can be handled in the form of a sheet or a sheet, and the generation of dust from rock wool is small, so that extremely excellent workability can be obtained. In addition, the rock wool molded medium of the present invention can be selected from a plate-shaped hard medium having a high flexibility and a medium adapted to the base to be constructed. Since the medium maintains a uniform thickness even on an inclined ground, it may hinder seeding and planting. Never do. In addition, when using a non-woven nonwoven fabric or a rock wool molding medium in which granulated rock wool is bonded to a non-conductive nonwoven fabric as necessary, handleability is more excellent, and when it is better for plants to take root on the foundation to be constructed Alternatively, there is an effect that each case can be adapted and used in a bad case.

Claims (3)

粒状化ロックウールが互いに接着剤で結合していることを特徴とするロックウール成型培地。A rock wool molding medium, wherein the granulated rock wool is bonded to each other with an adhesive. 接着剤で結合した粒状化ロックウールが通根性布帛に貼着していることを特徴とするロックウール成型培地。A rock wool molding medium, wherein granulated rock wool bonded with an adhesive is adhered to a root-permeable cloth. 接着剤で結合した粒状化ロックウールが不通根性布帛に貼着していることを特徴とするロックウール成型培地。A rock wool molding medium, characterized in that granulated rock wool bonded with an adhesive is adhered to a non-conductive fabric.
JP26610694A 1994-10-06 1994-10-06 Rock wool molding medium Expired - Fee Related JP3552304B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP26610694A JP3552304B2 (en) 1994-10-06 1994-10-06 Rock wool molding medium

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP26610694A JP3552304B2 (en) 1994-10-06 1994-10-06 Rock wool molding medium

Publications (2)

Publication Number Publication Date
JPH08103159A JPH08103159A (en) 1996-04-23
JP3552304B2 true JP3552304B2 (en) 2004-08-11

Family

ID=17426405

Family Applications (1)

Application Number Title Priority Date Filing Date
JP26610694A Expired - Fee Related JP3552304B2 (en) 1994-10-06 1994-10-06 Rock wool molding medium

Country Status (1)

Country Link
JP (1) JP3552304B2 (en)

Also Published As

Publication number Publication date
JPH08103159A (en) 1996-04-23

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