Deprecated: The each() function is deprecated. This message will be suppressed on further calls in /home/zhenxiangba/zhenxiangba.com/public_html/phproxy-improved-master/index.php on line 456
JP3555050B2 - Apparatus and method for continuous cleaning of oil-containing sludge - Google Patents
[go: Go Back, main page]

JP3555050B2 - Apparatus and method for continuous cleaning of oil-containing sludge - Google Patents

Apparatus and method for continuous cleaning of oil-containing sludge Download PDF

Info

Publication number
JP3555050B2
JP3555050B2 JP00961296A JP961296A JP3555050B2 JP 3555050 B2 JP3555050 B2 JP 3555050B2 JP 00961296 A JP00961296 A JP 00961296A JP 961296 A JP961296 A JP 961296A JP 3555050 B2 JP3555050 B2 JP 3555050B2
Authority
JP
Japan
Prior art keywords
oil
sludge
water
discharge port
containing sludge
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP00961296A
Other languages
Japanese (ja)
Other versions
JPH09192694A (en
Inventor
雅和 岩渕
進誠 熊本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shimizu Corp
Original Assignee
Shimizu Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shimizu Corp filed Critical Shimizu Corp
Priority to JP00961296A priority Critical patent/JP3555050B2/en
Publication of JPH09192694A publication Critical patent/JPH09192694A/en
Application granted granted Critical
Publication of JP3555050B2 publication Critical patent/JP3555050B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Landscapes

  • Treatment Of Sludge (AREA)

Description

【0001】
【発明の属する技術分野】
本発明は、原油流出事故などで発生する高濃度に油で汚染された土壌や製油所などで発生する含油スラッジを連続的に処理して汚泥を清浄化するとともに油分を回収する装置および方法に関する。
【0002】
【従来の技術】
原油タンカーなどが航行中に油漏出事故を起こし、浮遊した原油が陸に漂着して広範囲に土砂を汚染する事件が時おり発生する。また、油田の事故や争乱によって大量の原油が流出し、例えば油含有率が20%を越える高い濃度で広範囲に土砂が汚染される場合もある。このような場合には大量の油で汚染された土砂を可及的速やかに清浄化することが望まれる。また製油所の原油タンクなどは、消防法の定めるところにより7年に1回の解放検査が行われる。この際には、タンク内の原油を抜き取って内部の清掃が行われるが、その結果大量の含油スラッジが排出される。その排出量は、例えば20万バーレル/日の能力を有する製油所においては毎年約5000トンに及ぶ。これらの含油スラッジも相当量の原油が含まれていてそのまま廃棄しては環境汚染が著しいので、清浄化処理が求められる。従来これらの油汚染土砂や含油スラッジなどの含油汚泥は、焼却、ガス化または埋設などにより清浄化されている。
【0003】
【発明が解決しようとする課題】
しかし、これら焼却、ガス化、埋設などの清浄化方法は、いずれも莫大な経費がかかるうえに、廃ガスの発生や土壌汚染などの二次環境障害をもたらすので望ましい方法ではない。そこで、これらに代わる処理方法として生物的処理が考えられたが、処理速度が遅いため広大な処理面積と長大な時間が必要となり大量処理には不適当である。しかも、これらのいずれの処理方法によっても、油は回収されず消失することになるので資源節約の観点からも問題である。
【0004】
そこで、本発明者らは先に油汚染土壌または含油スラッジから油分を溶剤で抽出し、油相と固相とに分離し、固相を水洗して清浄化する方法を提案した(特願平7−118811号および特願平7−337086号参照)。これらの方法によれば油汚染土壌または含油スラッジの清浄化が低コストで実現できるばかりでなく、分離した油分が回収利用できるので資源節約の観点からも有利である。ただし、これらの方法を実施するに際して、上記の提案では装置が回分式とされていたため大量処理には不向きであった。本発明は、この問題を解決するためになされたものであって、従ってその目的は、油汚染土砂や含油スラッジなどの含油汚泥を連続的に処理して汚泥を清浄化するとともに油分を回収する装置および方法を提供することにある。
【0005】
【課題を解決するための手段】
上記の課題を解決するために本発明は、多孔性の周面を有する回転筒体がその回転軸を傾斜して外筒内に回転自在に配置され、この回転筒体の上端部に、含油汚泥を供給する含油汚泥供給口が形成され、下端部に脱油汚泥排出口が形成され、前記外筒に、外筒内に水を供給する水供給口と、この水と液液分離が可能でこの水より低比重の溶剤を供給する溶剤供給口と、外筒内で液液分離された水相を排出する水相排出口と、外筒内で液液分離された油相を排出する油相排出口とが設けられた含油汚泥の連続清浄化装置を提供する。
ここで含油汚泥とは、油汚染土砂および含油スラッジを含む含油泥状物の総称である。
【0006】
前記の外筒には、加熱手段が設けられていることが好ましい。前記の脱油汚泥排出口には、汚泥掻出し手段が設けられていることが好ましい。または前記の脱油汚泥排出口には、排出された汚泥を上方に搬送する水密性の搬送手段が連結されていることが好ましい。また、前記の脱油汚泥排出口から排出される汚泥を脱水する連続脱水装置が付設されていることが好ましい。
【0007】
本発明はまた、前記の含油汚泥の連続清浄化装置を用いて含油汚泥を清浄化するに際して、前記回転筒体を回転し、回転筒体の含油汚泥供給口に含油汚泥を連続的に供給し、水供給口と溶剤供給口とから外筒内にそれぞれ水と溶剤とを供給し、水相排出口と油相排出口とからそれぞれ、水相と油相との界面が回転筒体の周面を横切る位置に保たれるように液液分離した水相と油相とを排出し、かつ脱油汚泥排出口から、脱油され含水した汚泥を連続的に排出する含油汚泥の連続清浄化方法を提供する。
【0008】
上記において、外筒内の油相は、50℃〜100℃の温度範囲内に加温することが好ましい。脱油汚泥排出口から連続的に排出された含水汚泥は、付設された連続脱水装置を用いて連続的に脱水することが好ましい。前記の外筒の水供給口からは、界面活性剤を含む水を供給することが好ましい。
【0009】
【発明の実施の形態】
以下、本発明の実施形態について、実施例により図面を用いて説明する。
(実施例1)
図1において、符号10は、本発明の含油汚泥の連続清浄化装置(以下、単に「本装置」という)の一実施例を示している。本装置10は、金網製の周面を有する回転筒体1がその回転軸を傾斜して外筒2内に回転自在に配置され、この回転筒体1の上端部には含油汚泥OSを供給する含油汚泥供給口3が形成され、下端部には脱油汚泥排出口4が形成され、外筒2に、この外筒内に水Wを供給する水供給口7と、この水と液液分離が可能でこの水より低比重の溶剤Sを供給する溶剤供給口5と、外筒内で液液分離された水相WPを排出する水相排出口8と、外筒内で液液分離された油相OPを排出する油相排出口6とが設けられてなっている。この脱油汚泥排出口4には、図示しないが着脱自在の蓋部材が装着されている。
【0010】
また本装置10において、含油汚泥供給口3には回転筒体1に含油汚泥OSを供給するためのホッパー11が挿入され、外筒2の外面は、外筒2内の油相OPと水相WPの温度を50℃〜100℃の範囲内に保つことができる温水ジャケット12で被われている。本装置10には、脱油汚泥排出口4から排出される含水汚泥WSを連続的に脱水するための振動フルイ20が付設されている。
【0011】
次に、本装置10を用いて含油汚泥OSを清浄化する方法の一実施形態について説明する。
先ず本装置10の脱油汚泥排出口4に蓋部材(図示せず)を装着し、回転筒体1を適当な速度で回転するとともに、水供給口7から界面活性剤の水溶液Wを、また溶剤供給口5からケロシンまたはライトガスオイルなど引火点が高く水より低比重でかつ水と液液分離が可能な溶剤Sを供給し、水相排出口8からは外筒2内で液液分離した水相WPを、油相排出口6からは液液分離した油相WPをそれぞれ適当な速度で排出する。これによって、外筒2内で液液分離された水相WPと油相OPとの界面Lは、回転筒体1の周面を横切る位置に保たれるようになる。ジャケット12に温水を通して外筒2内の水相WPと油相OPの温度を50℃〜100℃の範囲内の適当な温度に調節する。
【0012】
この状態で、発生現場から搬入された含油汚泥OSをホッパー11に供給する。含油汚泥OSは、ホッパー11から回転筒体1の含油汚泥供給口3に連続的に導入され、傾斜した回転筒体1内を旋回しながら下方に移動する。この間に含油汚泥OSは高められた温度の油相OPと接触し、汚泥に含まれた油分が油相OPに抽出される。回転筒体1内を更に下方に移動した汚泥は、界面Lを越えて水相WPに至り、界面活性剤水溶液と接触し旋回攪拌されることによって洗浄され、汚泥の表面に付着した油相OPは水相WP中に乳化または分散され汚泥から除去される。洗浄された含水汚泥WSは、脱油汚泥排出口4の近傍に次第に蓄積される。
【0013】
含水汚泥WSが脱油汚泥排出口4の近傍に適量蓄積されたとき、脱油汚泥排出口4の蓋部材を除去する。これによって、脱油汚泥排出口4の近傍に蓄積された汚泥は、順次、連続的に脱油汚泥排出口4から排出され、しかも、外筒2内の油相OPや水相WPが脱油汚泥排出口4から流出せず、界面Lが一定に保たれるようになる。
【0014】
脱油汚泥排出口4から排出された含水汚泥WSは、付設された振動フルイ20のフルイ面に落とされ、振動によって脱水されるとともに排出端から排出され、清浄化汚泥CSとして回収される。振動フルイ20によって分離された水相WPは、本装置10内の水相WPと同様に油分を乳化または分散して含んでいるので、本装置10の水相排出口8から排出される水相WPと合体され、図示しない排水処理工程に送られる。
【0015】
水相WPは、図示しない排水処理工程において、公知の方法によって乳化または分散が破壊され、油相と水相とに分離され、油相は本装置10の油相排出口6から排出される油相OPと合体される。分離された水相は、界面活性剤を添加して本体10の水供給口7に供給水Wとして循環使用することもでき、または通常の廃水処理を施して放出してもよい。
【0016】
本装置10の油相排出口6から排出される油相OPと上記の排水処理工程において分離された油相は、いずれも含油汚泥OS中の油分とケロシンまたはライトガスオイルなどの溶剤Sとからなるものであるから、例えば製油所などにおいては原料の一部として製油工程に戻すこともでき、また燃料などとして有効に利用することもできる。振動フルイ20によって脱水されて得られた清浄化汚泥CSは、生物学的処理を施し、または施さずに地中に埋め戻すなどの処理を行うことができる。
【0017】
本装置10の回転筒体1の周面を形成する金網の孔径は、処理する含油汚泥OSの固形分粒子の粒径に依存して選択される。要は、油相OPおよび水相WPが容易に通過し得て、含油汚泥OSの固形分粒子が回転筒体1の外側へ流出しない程度の孔径を選択すればよい。これによって、回転筒体1内で旋回攪拌されている汚泥粒子に新鮮な溶剤Sおよび水Wが接触し、抽出効果および洗浄効果が向上する。
【0018】
回転筒体1の傾斜角は特に限定されるものではないが、水平からの傾斜角が小さければ汚泥の回転軸方向の移動速度が遅くなるので抽出効果および洗浄効果は向上するが、処理速度は低下する。傾斜角が大となればその逆の効果が現れるので、対象とする含油汚泥OSの含油率や脱油の難易性などを考慮して傾斜角を決定することが好ましい。
【0019】
本装置10内における油相OP(および水相WP)の温度は、用いる溶剤の種類や、それに伴う法的規制などによって好適範囲が決まる。一般には50℃〜100℃の範囲内、更には60℃〜70℃の範囲内とすることが好ましい。50℃未満では含油汚泥OSに固着した油分が膨潤し難く、抽出に長時間を要する場合があり、100℃を越えると溶剤の揮発損が増大するとともに法的規制が強化されることによって設備費が嵩むなどの不利益が生じる。
【0020】
溶剤Sには、必要に応じて油溶性の界面活性剤を浸透剤または膨潤剤などとして添加することもできる。これらの油溶性界面活性剤は、含油汚泥OSの内部にまで溶剤を浸透させ、固着した油分を膨潤させる効果があるので抽出効率を向上させることができる。
【0021】
本装置10の水供給口7に供給する水Wは、単純水であってもよいが、界面活性剤水溶液であることが更に好ましい。界面活性剤は、固相に付着した油分を水中に分散させ、かつ再付着を防止するために有効である。用いる界面活性剤の種類は、油分を効果的に水に分散し得るものであれば、特に限定されない。ただし、生物分解性かつ無リンであることが好ましい。その好適な例としては、石ケン、高級アルコール系界面活性剤、α−オレフィンスルホン酸系界面活性剤などの陰イオン界面活性剤、多価アルコール脂肪酸エステル系界面活性剤、ポリオキシエチレン系界面活性剤、ソルビタンポリオキシエチレン系界面活性剤、ポリオキシエチレンプロピレン系界面活性剤、脂肪酸アルキロールアミド系界面活性剤などの非イオン系界面活性剤などを挙げることができる。
【0022】
上記の実施形態においては、含水汚泥WSの脱水に振動フルイ20を用いたが、脱水装置はこれに限定されるものではなく、他の公知の連続固液分離装置、例えば上排式、底排式、または横置き式の連続遠心分離機や連続式遠心デカンターまたは超遠心デカンターなども好適に用いることができる。
【0023】
以上説明した本発明の方法によれば、含油汚泥OSから油分を含まない清浄化汚泥CSが連続的に得られ、しかも分離された油分は有効に利用することができる。上記の方法は、溶剤として石油精製工場などで容易に得られるケロシンまたはライトガスオイルなどの安価でしかも再使用可能な油剤を用いることができ、高温高圧を要しないので、消耗材コストもエネルギーコストも僅少であり、しかも工程の安全性が高い。
【0024】
(実施例2)
図2に示す実施例2の本装置30は、脱油汚泥排出口に汚泥掻出し手段が設けられている以外は実施例1のものと同様である。以下、実施例1と共通の要素は同一の符号を用い、説明を省略する。
【0025】
実施例2において、回転筒体1の下端部に形成された脱油汚泥排出口31は、回転筒体1と同軸の円筒状をなして外筒2の下端面から水密かつ回転自在に突出し、その内部にスクリュー機構32が挿入されている。このスクリュー機構32は、回転自在の片持ち軸33の周囲にラセン羽34が形成されてなり、この片持ち軸33の基部には、脱油汚泥排出口31の開口端31aを塞ぐ蓋部材35が装着されている。このスクリュー機構32は、図示しない手段によって回転筒体1の回転軸心上を前後に移動できるようになっている。
【0026】
本装置30は、運転に先だって、スクリュー機構32を蓋部材35が開口端31aと密着するように回転筒体1側に押しつけられている。この状態で、開口端31aは閉塞され、また回転筒体1を回転すると、スクリュー機構32は回転筒体1と一緒に回転するので、スクリュー羽34は脱油汚泥排出口31に対して相対的に静止している。
【0027】
脱油汚泥排出口31が蓋部材35によって閉塞された状態で回転筒体1を回転するとともに、図1に示した実施例1と同様に、水供給口7から界面活性剤の水溶液Wを、また溶剤供給口5からケロシンまたはライトガスオイルなど引火点が高く水より低比重でかつ水と液液分離が可能な溶剤Sを供給し、水相排出口8からは水相WPを、油相排出口6からは油相WPをそれぞれ適当な速度で排出すると、脱油汚泥排出口31が閉塞されているので、外筒2内で水相WPと油相OPとが液液分離してその界面Lが回転筒体1の周面を横切る位置に保たれるようになる。ジャケット12に温水を通して外筒2内の水相WPと油相OPの温度を50℃〜100℃の範囲内の適当な温度に調節する。
【0028】
次に、発生現場から搬入された含油汚泥OSをホッパー11に供給する。含油汚泥OSは、ホッパー11から回転筒体1の含油汚泥供給口3に連続的に導入され、傾斜した回転筒体1内を旋回しながら下方に移動する。この間に含油汚泥OSは高められた温度の油相OPと接触し、汚泥に含まれた油分が油相OPに抽出される。回転筒体1内を更に下方に移動した汚泥は、界面Lを越えて水相WPに至り、界面活性剤水溶液と接触し旋回攪拌されることによって洗浄され、汚泥の表面に付着した油相OPは水相WP中に乳化または分散され汚泥から除去される。洗浄された含水汚泥WSは、脱油汚泥排出口31の近傍に次第に蓄積される。
【0029】
含水汚泥WSが脱油汚泥排出口31の近傍に適量蓄積されたとき、スクリュー機構32を蓋部材35が開口端31aから離れる方向に移動する。またスクリュー機構32を、脱油汚泥排出口31の近傍に蓄積された含水汚泥WSがスクリュー羽34によって掻き出される回転方向に、脱油汚泥排出口31に対して相対的に適度な回転速度で回転する。これによって、脱油汚泥排出口31近傍に蓄積された汚泥は順次、連続的に脱油汚泥排出口の開口端31aから排出される。このとき、外筒2内の油相OPや水相WPは脱油汚泥排出口31から流出せず、界面Lは運転中ほぼ一定に保たれる。
【0030】
脱油汚泥排出口31から排出された含水汚泥WSは、実施例1に示した振動フルイまたは連続遠心分離機などを用いて連続的に脱水され、清浄化汚泥CSとして回収される。実施例2のスクリュー機構32を用いれば、運転中に脱油汚泥排出口31から油相OPや水相WPが流出することなく、しかも脱油汚泥排出口31の近傍に蓄積された含水汚泥WSを好適な速度で円滑に連続的に開口端31aから排出することができる。
【0031】
(実施例3)
図3に示す実施例3の本装置40は、脱油汚泥排出口41に、排出された汚泥を上方に搬送する水密性の搬送手段42が設けられている以外は実施例1のものと同様である。
実施例3において、回転筒体1の下端部に形成された脱油汚泥排出口41は、回転筒体1と同軸の円筒状をなして外筒2の下端面から水密にかつ回転自在に突出し、その端末は解放されて、垂直に立設されたリフト機構42の基部挿入口43に水密にかつ回転自在に連結されている。
【0032】
リフト機構42は、直立した有底筒体44中にこれと同軸的にスクリュー軸45が、モーター46によって回転駆動されるように装着され、このスクリュー軸45の周囲にラセン羽47が形成され、また有底筒体44の頂部には頂部排出口48が形成されてなっている。このリフト機構42は、ラセン羽47の回転によって、基部挿入口43から供給された含水汚泥WSを外筒2の頂部高さより高い位置に配設された頂部排出口48まで搬送するようになっている。
【0033】
本装置40は、水供給口7から界面活性剤の水溶液Wを供給すると、水溶液Wは外筒2と有底筒体44の内部に同一水準の水面を形成する。次に溶剤供給口5からケロシンまたはライトガスオイルなど引火点が高く水より低比重でかつ水と液液分離が可能な溶剤Sを供給し、水相排出口8からは水相WPを、油相排出口6からは油相WPをそれぞれ適当な速度で排出すると、外筒2内で水相WPと油相OPとの界面Lが回転筒体1の周面を横切る位置に保たれるとともに、有底筒体44内にこの界面Lより油相WPの液深に対応する高さだけ高い水面(図示せず)が形成される。
【0034】
回転筒体1を回転し、発生現場から搬入された含油汚泥OSをホッパー11に供給する。含油汚泥OSは、ホッパー11から回転筒体1の含油汚泥供給口3に連続的に導入され、傾斜した回転筒体1内を旋回しながら下方に移動する。この間に含油汚泥OSは高められた温度の油相OPと接触し、汚泥に含まれた油分が油相OPに抽出される。回転筒体1内を更に下方に移動した汚泥は、界面Lを越えて水相WPに至り、界面活性剤水溶液と接触し旋回攪拌されることによって洗浄され、汚泥の表面に付着した油相OPは水相WP中に乳化または分散され汚泥から除去される。洗浄された含水汚泥WSは、脱油汚泥排出口41の近傍に次第に蓄積される。
【0035】
脱油汚泥排出口41の近傍に蓄積された含水汚泥WSは、回転が付与されているので脱油汚泥排出口41を下方に自走し、基部挿入口43から有底筒体44内に導入され、回転するラセン羽47によって、有底筒体44内の水位を越えて上方に搬送され、頂部排出口48から排出される。これによって、脱油汚泥排出口41近傍に蓄積された汚泥が順次、連続的に頂部排出口48から排出され、しかも、外筒2内の油相OPや水相WPは頂部排出口48から流出し得ないので、界面Lは運転中一定に保たれる。
【0036】
頂部排出口48から排出された含水汚泥WSは、必要なら実施例1に示した振動フルイまたは連続遠心分離機などを用いて連続的に脱水され、清浄化汚泥CSとして回収される。実施例3のリフト機構42を用いれば、運転中に脱油汚泥排出口41を通して油相OPや水相WPが流出することなく、しかも脱油汚泥排出口4の近傍に蓄積された含水汚泥WSは、好適な速度で円滑にかつ連続的に頂部排出口48から排出される。
上記のリフト機構は、ラセン羽47によるスクリューコンベア型のもののほか、水密な塔屋内に設けられたバケットコンベア型のものなどであってもよい。
【0037】
【発明の効果】
本発明の含油汚泥の連続清浄化装置は、多孔性の周面を有する回転筒体がその回転軸を傾斜して外筒内に回転自在に配置され、この回転筒体の上端部に、含油汚泥を供給する含油汚泥供給口が形成され、下端部に脱油汚泥排出口が形成され、前記外筒に、水より低比重でかつ水と液液分離が可能な溶剤を供給する溶剤供給口と、外筒内で液液分離された油相を排出する油相排出口と、外筒内に水を供給する水供給口と、外筒内で液液分離された水相を排出する水相排出口とが設けられたものであるので、この回転筒体を回転し、回転筒体の含油汚泥供給口に含油汚泥を連続的に供給し、水供給口と溶剤供給口とから外筒内にそれぞれ水と溶剤とを供給し、水相排出口と油相排出口とからそれぞれ、水相と油相との界面が回転筒体の周面を横切る位置に保たれるように液液分離した水相と油相とを排出し、かつ脱油汚泥排出口から、脱油され含水した汚泥を連続的に排出することによって、含油汚泥から油分を含まない清浄化汚泥が連続的に得られ、しかも分離された油分は有効に利用することができるようになる。上記の本発明の方法は、含油汚泥の大量清浄化に好適であるばかりでなく、溶剤として石油精製工場などで容易に得られるケロシンまたはライトガスオイルなどの安価でしかも再使用可能な油剤を用いることができ、高温高圧を要しないので、消耗材コストもエネルギーコストも僅少であり、しかも工程の安全性が高い利点がある。
【図面の簡単な説明】
【図1】本発明の含油汚泥の連続清浄化装置の一実施例およびこれを用いた一実施形態を示す断面図である。
【図2】本発明の含油汚泥の連続清浄化装置の他の一実施例およびこれを用いた一実施形態を示す部分断面図である。
【図3】本発明の含油汚泥の連続清浄化装置の更に他の一実施例およびこれを用いた一実施形態を示す断面図である。
【符号の説明】
1……回転筒体
2……外筒
3……含油汚泥供給口
4……脱油汚泥排出口
5……溶剤供給口
6……油相排出口
7……水供給口
8……水相排出口
10……本発明の含油汚泥の連続清浄化装置
20……連続脱水装置
OS……含油汚泥
WS……含水汚泥
CS……清浄化汚泥
S……溶剤
W……水
OP……油相
WP……水相
L……界面
[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to an apparatus and a method for continuously treating oil-containing sludge generated in highly contaminated oil-contaminated soil or oil refineries generated in a crude oil spill accident to purify sludge and collect oil. .
[0002]
[Prior art]
Occasionally, an oil spill accident occurs while a crude oil tanker or the like is navigating, and floating oil drifts to land and contaminates a wide range of earth and sand. In addition, a large amount of crude oil is spilled due to an oil field accident or conflict, and the earth and sand may be widely contaminated at a high concentration, for example, an oil content exceeding 20%. In such a case, it is desired to clean the soil contaminated with a large amount of oil as quickly as possible. Oil refinery tanks at refineries are subject to release inspections every seven years, as required by the Fire Service Law. At this time, the crude oil in the tank is extracted and the inside is cleaned. As a result, a large amount of oil-containing sludge is discharged. Its emissions reach, for example, about 5,000 tonnes per year in a refinery with a capacity of 200,000 barrels / day. Since these oil-containing sludges also contain a considerable amount of crude oil and are discarded as they are, the environmental pollution is remarkable, so that a cleaning treatment is required. Conventionally, oil-containing sludge such as oil-contaminated soil and oil-containing sludge has been purified by incineration, gasification or burial.
[0003]
[Problems to be solved by the invention]
However, these cleaning methods such as incineration, gasification, and burial are not desirable methods because they require enormous costs and cause secondary environmental obstacles such as generation of waste gas and soil pollution. Therefore, biological processing has been considered as an alternative processing method. However, since the processing speed is slow, a large processing area and a long time are required, which is unsuitable for mass processing. In addition, any of these treatment methods causes oil to be lost without being collected, which is a problem from the viewpoint of resource saving.
[0004]
Therefore, the present inventors have previously proposed a method of extracting oil from oil-contaminated soil or oil-containing sludge with a solvent, separating the oil into a solid phase and a solid phase, and washing the solid phase with water to purify it (Japanese Patent Application No. Hei. 7-118811 and Japanese Patent Application No. 7-337086). According to these methods, not only can oil-contaminated soil or oil-containing sludge be purified at low cost, but also the separated oil can be recovered and used, which is advantageous from the viewpoint of resource saving. However, in implementing these methods, the above proposal was not suitable for mass processing because the apparatus was of a batch type. The present invention has been made to solve this problem, and its object is to continuously treat oil-containing sludge such as oil-contaminated earth and sand or oil-containing sludge to purify sludge and collect oil. It is to provide an apparatus and a method.
[0005]
[Means for Solving the Problems]
In order to solve the above-mentioned problems, the present invention provides a rotary cylinder having a porous peripheral surface, which is rotatably disposed in an outer cylinder by inclining its rotation axis, and having an oil-impregnated upper end portion. An oil-containing sludge supply port for supplying sludge is formed, a deoiled sludge discharge port is formed at the lower end, and a water supply port for supplying water into the outer cylinder, and the water and liquid-liquid separation are possible. A solvent supply port for supplying a solvent having a specific gravity lower than that of water, an aqueous phase discharge port for discharging a liquid phase liquid-liquid separated in the outer cylinder, and discharging an oil phase liquid-liquid separated in the outer cylinder. Provided is an apparatus for continuously cleaning oil-containing sludge provided with an oil phase discharge port.
Here, the oil-containing sludge is a general term for oil-containing mud including oil-contaminated soil and oil-containing sludge.
[0006]
Preferably, the outer cylinder is provided with a heating means. It is preferable that a sludge scraping means is provided at the deoiled sludge discharge port. Alternatively, it is preferable that a watertight conveying means for conveying the discharged sludge upward is connected to the deoiled sludge discharge port. Further, it is preferable that a continuous dewatering device for dewatering the sludge discharged from the deoiled sludge discharge port is provided.
[0007]
In the present invention, when the oil-containing sludge is purified using the oil-containing sludge continuous cleaning device, the rotary cylinder is rotated, and the oil-containing sludge is continuously supplied to the oil-containing sludge supply port of the rotary cylinder. Water and the solvent are supplied into the outer cylinder through the water supply port and the solvent supply port, respectively. Continuous purification of oil-bearing sludge by discharging the water and oil phases separated by liquid and liquid so as to be kept at a position crossing the surface, and continuously discharging the deoiled and water-containing sludge from the deoiling sludge outlet. Provide a way.
[0008]
In the above, it is preferable that the oil phase in the outer cylinder is heated within a temperature range of 50C to 100C. It is preferable that the hydrous sludge continuously discharged from the deoiled sludge discharge port be continuously dewatered by using an attached continuous dewatering device. It is preferable to supply water containing a surfactant from the water supply port of the outer cylinder.
[0009]
BEST MODE FOR CARRYING OUT THE INVENTION
Hereinafter, embodiments of the present invention will be described with reference to the drawings using examples.
(Example 1)
In FIG. 1, reference numeral 10 indicates an embodiment of the continuous apparatus for cleaning oil-containing sludge of the present invention (hereinafter, simply referred to as “the present apparatus”). In this apparatus 10, a rotary cylinder 1 having a peripheral surface made of a wire mesh is rotatably disposed in an outer cylinder 2 with its rotation axis inclined, and an oil-containing sludge OS is supplied to an upper end portion of the rotary cylinder 1. An oil-containing sludge supply port 3 is formed at the lower end, and a deoiled sludge discharge port 4 is formed at the lower end. A water supply port 7 for supplying water W into the outer cylinder 2 is provided. A solvent supply port 5 for supplying a solvent S capable of separation and having a lower specific gravity than this water, an aqueous phase outlet 8 for discharging the aqueous phase WP separated in the outer cylinder, and a liquid / liquid separation in the outer cylinder. And an oil phase discharge port 6 for discharging the oil phase OP. Although not shown, a detachable lid member is attached to the deoiled sludge discharge port 4.
[0010]
Further, in the present apparatus 10, a hopper 11 for supplying the oil-containing sludge OS to the rotary cylinder 1 is inserted into the oil-containing sludge supply port 3, and the outer surface of the outer cylinder 2 has an oil phase OP and an aqueous phase inside the outer cylinder 2. The WP is covered with a warm water jacket 12 that can maintain the temperature of the WP within a range of 50C to 100C. The device 10 is provided with a vibrating screen 20 for continuously dewatering the hydrous sludge WS discharged from the deoiled sludge discharge port 4.
[0011]
Next, an embodiment of a method for cleaning the oil-containing sludge OS using the present apparatus 10 will be described.
First, a cover member (not shown) is attached to the deoiled sludge discharge port 4 of the present apparatus 10, and the rotary cylinder 1 is rotated at an appropriate speed. A solvent S, such as kerosene or light gas oil, having a high flash point, a lower specific gravity than water, and capable of separating liquid and liquid from water is supplied from the solvent supply port 5, and liquid-liquid separation is performed from the aqueous phase discharge port 8 in the outer cylinder 2. The separated aqueous phase WP is discharged from the oil phase discharge port 6 at an appropriate speed. As a result, the interface L between the aqueous phase WP and the oil phase OP separated into liquid and liquid in the outer cylinder 2 is maintained at a position crossing the peripheral surface of the rotary cylinder 1. Hot water is passed through the jacket 12 to adjust the temperature of the water phase WP and the oil phase OP in the outer cylinder 2 to an appropriate temperature in the range of 50C to 100C.
[0012]
In this state, the oil-containing sludge OS carried in from the generation site is supplied to the hopper 11. The oil-containing sludge OS is continuously introduced from the hopper 11 into the oil-containing sludge supply port 3 of the rotary cylinder 1, and moves downward while rotating inside the inclined rotary cylinder 1. During this time, the oil-containing sludge OS comes into contact with the oil phase OP at an increased temperature, and the oil contained in the sludge is extracted into the oil phase OP. The sludge that has moved further downward in the rotary cylinder 1 reaches the aqueous phase WP over the interface L, is washed by being swirled and stirred in contact with the aqueous surfactant solution, and the oil phase OP adhered to the surface of the sludge. Is emulsified or dispersed in the aqueous phase WP and removed from the sludge. The washed hydrous sludge WS is gradually accumulated in the vicinity of the deoiled sludge outlet 4.
[0013]
When an appropriate amount of the hydrated sludge WS is accumulated in the vicinity of the deoiled sludge outlet 4, the cover member of the deoiled sludge outlet 4 is removed. Thereby, the sludge accumulated near the deoiled sludge discharge port 4 is sequentially and continuously discharged from the deoiled sludge discharge port 4, and furthermore, the oil phase OP and the water phase WP in the outer cylinder 2 are deoiled. The interface L does not flow out from the sludge discharge port 4 and the interface L is kept constant.
[0014]
The hydrous sludge WS discharged from the deoiled sludge discharge port 4 is dropped on the sieve surface of the attached vibrating screen 20, dewatered by vibration, discharged from the discharge end, and collected as purified sludge CS. Since the water phase WP separated by the vibrating screen 20 contains emulsified or dispersed oil like the water phase WP in the present apparatus 10, the aqueous phase WP discharged from the water phase outlet 8 of the present apparatus 10 It is combined with the WP and sent to a wastewater treatment step (not shown).
[0015]
The water phase WP is destroyed in a known manner by emulsification or dispersion in a wastewater treatment step (not shown), separated into an oil phase and an aqueous phase, and the oil phase is discharged from the oil phase discharge port 6 of the apparatus 10. Combined with phase OP. The separated aqueous phase can be circulated and used as the supply water W to the water supply port 7 of the main body 10 by adding a surfactant, or can be discharged by performing a normal wastewater treatment.
[0016]
Both the oil phase OP discharged from the oil phase discharge port 6 of the present apparatus 10 and the oil phase separated in the above-mentioned wastewater treatment step are composed of the oil in the oil-containing sludge OS and the solvent S such as kerosene or light gas oil. Therefore, for example, in a refinery or the like, it can be returned to the oil refining process as a part of the raw material, and can be effectively used as fuel or the like. The purified sludge CS obtained by being dehydrated by the vibrating screen 20 may be subjected to a biological treatment, or may be subjected to a treatment such as being buried in the ground without being subjected to the biological treatment.
[0017]
The hole diameter of the wire mesh forming the peripheral surface of the rotary cylinder 1 of the present apparatus 10 is selected depending on the particle size of the solid particles of the oil-containing sludge OS to be treated. The point is that it is sufficient to select a pore size that allows the oil phase OP and the water phase WP to easily pass through and does not allow the solid particles of the oil-containing sludge OS to flow out of the rotary cylinder 1. As a result, the fresh solvent S and the water W come into contact with the sludge particles swirled and agitated in the rotary cylinder 1, and the extraction effect and the washing effect are improved.
[0018]
The inclination angle of the rotary cylinder 1 is not particularly limited, but if the inclination angle from the horizontal is small, the moving speed of the sludge in the rotation axis direction becomes slow, so that the extraction effect and the washing effect are improved. descend. When the inclination angle is large, the opposite effect appears. Therefore, it is preferable to determine the inclination angle in consideration of the oil content of the target oil-containing sludge OS and the difficulty of deoiling.
[0019]
The preferred range of the temperature of the oil phase OP (and the aqueous phase WP) in the present apparatus 10 is determined by the type of the solvent to be used and the legal regulations accompanying it. Generally, the temperature is preferably in the range of 50C to 100C, more preferably in the range of 60C to 70C. If the temperature is lower than 50 ° C., the oil fixed to the oil-containing sludge OS does not easily swell, and it may take a long time to extract the oil. Disadvantages such as bulkiness.
[0020]
If necessary, an oil-soluble surfactant can be added to the solvent S as a penetrant or a swelling agent. These oil-soluble surfactants have the effect of allowing the solvent to penetrate into the oil-containing sludge OS and swelling the fixed oil component, so that the extraction efficiency can be improved.
[0021]
The water W supplied to the water supply port 7 of the device 10 may be simple water, but is more preferably an aqueous surfactant solution. Surfactants are effective for dispersing oil adhering to the solid phase in water and preventing re-adhesion. The type of the surfactant used is not particularly limited as long as the oil can be effectively dispersed in water. However, it is preferably biodegradable and phosphorus-free. Preferable examples thereof include soaps, higher alcohol surfactants, anionic surfactants such as α-olefin sulfonic acid surfactants, polyhydric alcohol fatty acid ester surfactants, and polyoxyethylene surfactants. And nonionic surfactants such as sorbitan polyoxyethylene surfactants, polyoxyethylene propylene surfactants, and fatty acid alkylolamide surfactants.
[0022]
In the above embodiment, the vibrating sieve 20 was used for dehydrating the hydrous sludge WS. However, the dewatering device is not limited to this, and other known continuous solid-liquid separation devices, for example, a top discharge type, a bottom discharge type A type or horizontal type continuous centrifuge, a continuous centrifugal decanter, an ultracentrifugal decanter, or the like can also be suitably used.
[0023]
According to the method of the present invention described above, the purified sludge CS containing no oil can be continuously obtained from the oil-containing sludge OS, and the separated oil can be effectively used. The above method can use an inexpensive and reusable oil agent such as kerosene or light gas oil easily obtained in petroleum refining factories and the like as a solvent, and does not require high temperature and high pressure. And the safety of the process is high.
[0024]
(Example 2)
The present apparatus 30 of the second embodiment shown in FIG. 2 is the same as that of the first embodiment except that sludge scraping means is provided at the deoiled sludge discharge port. Hereinafter, the same elements as those in the first embodiment are denoted by the same reference numerals, and description thereof will be omitted.
[0025]
In the second embodiment, the deoiled sludge discharge port 31 formed at the lower end of the rotary cylinder 1 has a cylindrical shape coaxial with the rotary cylinder 1 and projects from the lower end surface of the outer cylinder 2 in a watertight and rotatable manner, The screw mechanism 32 is inserted therein. The screw mechanism 32 has a spiral wing 34 formed around a rotatable cantilever shaft 33, and a lid member 35 for closing the opening end 31 a of the deoiled sludge discharge port 31 at the base of the cantilever shaft 33. Is installed. The screw mechanism 32 can be moved back and forth on the rotation axis of the rotary cylinder 1 by means not shown.
[0026]
Prior to the operation of the device 30, the screw mechanism 32 is pressed against the rotary cylinder 1 so that the lid member 35 is in close contact with the opening end 31a. In this state, the opening end 31 a is closed, and when the rotary cylinder 1 is rotated, the screw mechanism 32 rotates together with the rotary cylinder 1, so that the screw blades 34 are moved relative to the deoiled sludge discharge port 31. Is stationary.
[0027]
While rotating the rotary cylinder 1 in a state where the deoiled sludge discharge port 31 is closed by the lid member 35, the aqueous solution W of the surfactant is discharged from the water supply port 7 as in the first embodiment shown in FIG. A solvent S such as kerosene or light gas oil, which has a higher flash point and a lower specific gravity than water and is capable of separating liquid and liquid from water, is supplied from a solvent supply port 5. When the oil phase WP is discharged from the discharge port 6 at an appropriate speed, the deoiled sludge discharge port 31 is closed, so that the water phase WP and the oil phase OP are separated into liquid and liquid in the outer cylinder 2. The interface L is maintained at a position crossing the peripheral surface of the rotary cylinder 1. Hot water is passed through the jacket 12 to adjust the temperature of the water phase WP and the oil phase OP in the outer cylinder 2 to an appropriate temperature in the range of 50C to 100C.
[0028]
Next, the oil-containing sludge OS carried in from the generation site is supplied to the hopper 11. The oil-containing sludge OS is continuously introduced from the hopper 11 into the oil-containing sludge supply port 3 of the rotary cylinder 1, and moves downward while rotating inside the inclined rotary cylinder 1. During this time, the oil-containing sludge OS comes into contact with the oil phase OP at an increased temperature, and the oil contained in the sludge is extracted into the oil phase OP. The sludge that has moved further downward in the rotary cylinder 1 reaches the aqueous phase WP over the interface L, is washed by being swirled and stirred in contact with the aqueous surfactant solution, and the oil phase OP adhered to the surface of the sludge. Is emulsified or dispersed in the aqueous phase WP and removed from the sludge. The washed hydrous sludge WS is gradually accumulated near the deoiled sludge outlet 31.
[0029]
When a suitable amount of the hydrated sludge WS is accumulated in the vicinity of the deoiled sludge discharge port 31, the screw mechanism 32 moves in a direction in which the lid member 35 moves away from the opening end 31a. Further, the screw mechanism 32 is rotated at an appropriate rotation speed relative to the deoiled sludge discharge port 31 in the rotation direction in which the hydrous sludge WS accumulated near the deoiled sludge discharge port 31 is scraped out by the screw blades 34. Rotate. As a result, the sludge accumulated near the deoiled sludge outlet 31 is sequentially and continuously discharged from the open end 31a of the deoiled sludge outlet. At this time, the oil phase OP and the water phase WP in the outer cylinder 2 do not flow out of the deoiled sludge discharge port 31, and the interface L is kept substantially constant during operation.
[0030]
The hydrous sludge WS discharged from the deoiled sludge discharge port 31 is continuously dehydrated by using the vibrating sieve or the continuous centrifuge shown in the first embodiment, and is recovered as the purified sludge CS. When the screw mechanism 32 of the second embodiment is used, the oil phase OP and the aqueous phase WP do not flow out of the deoiled sludge discharge port 31 during operation, and the hydrated sludge WS accumulated near the deoiled sludge discharge port 31 is operated. At a suitable speed can be smoothly and continuously discharged from the open end 31a.
[0031]
(Example 3)
The apparatus 40 of the third embodiment shown in FIG. 3 is the same as that of the first embodiment except that a drainage sludge discharge port 41 is provided with a watertight conveying means 42 for conveying the discharged sludge upward. It is.
In the third embodiment, the deoiled sludge discharge port 41 formed at the lower end of the rotary cylinder 1 has a cylindrical shape coaxial with the rotary cylinder 1 and protrudes from the lower end surface of the outer cylinder 2 in a watertight and rotatable manner. The terminal is released and connected to the base insertion opening 43 of the vertically rising lift mechanism 42 in a watertight and rotatable manner.
[0032]
The lift mechanism 42 is mounted so that a screw shaft 45 is coaxially mounted in an upright bottomed cylindrical body 44 so as to be rotationally driven by a motor 46, and a spiral blade 47 is formed around the screw shaft 45. A top outlet 48 is formed at the top of the bottomed cylindrical body 44. The lift mechanism 42 conveys the hydrous sludge WS supplied from the base insertion port 43 to the top discharge port 48 provided at a position higher than the top height of the outer cylinder 2 by the rotation of the spiral blade 47. I have.
[0033]
When the present apparatus 40 supplies the aqueous solution W of the surfactant from the water supply port 7, the aqueous solution W forms the same level of the water surface inside the outer cylinder 2 and the bottomed cylinder 44. Next, a solvent S, such as kerosene or light gas oil, having a high flash point and a lower specific gravity than water and capable of separating liquid and liquid from water, is supplied from the solvent supply port 5, and the aqueous phase WP is supplied from the aqueous phase discharge port 8 to When the oil phase WP is discharged from the phase discharge port 6 at an appropriate speed, the interface L between the water phase WP and the oil phase OP in the outer cylinder 2 is maintained at a position crossing the peripheral surface of the rotary cylinder 1. A water surface (not shown) higher than the interface L by a height corresponding to the liquid depth of the oil phase WP is formed in the bottomed cylinder 44.
[0034]
The rotary cylinder 1 is rotated, and the oil-containing sludge OS carried in from the generation site is supplied to the hopper 11. The oil-containing sludge OS is continuously introduced from the hopper 11 into the oil-containing sludge supply port 3 of the rotary cylinder 1, and moves downward while rotating inside the inclined rotary cylinder 1. During this time, the oil-containing sludge OS comes into contact with the oil phase OP at an increased temperature, and the oil contained in the sludge is extracted into the oil phase OP. The sludge that has moved further downward in the rotary cylinder 1 reaches the aqueous phase WP over the interface L, is washed by being swirled and stirred in contact with the aqueous surfactant solution, and the oil phase OP adhered to the surface of the sludge. Is emulsified or dispersed in the aqueous phase WP and removed from the sludge. The washed hydrous sludge WS is gradually accumulated in the vicinity of the deoiled sludge outlet 41.
[0035]
The hydrated sludge WS accumulated near the deoiled sludge discharge port 41 is self-propelled downward through the deoiled sludge discharge port 41 due to rotation, and is introduced into the bottomed cylindrical body 44 from the base insertion port 43. Then, the water is conveyed upward beyond the water level in the bottomed cylindrical body 44 by the rotating spiral blades 47 and discharged from the top discharge port 48. As a result, the sludge accumulated near the deoiled sludge discharge port 41 is sequentially and continuously discharged from the top discharge port 48, and the oil phase OP and the water phase WP in the outer cylinder 2 flow out from the top discharge port 48. The interface L is kept constant during operation.
[0036]
The hydrous sludge WS discharged from the top discharge port 48 is continuously dewatered by using the vibrating screen or the continuous centrifugal separator shown in Embodiment 1 if necessary, and is recovered as the purified sludge CS. If the lift mechanism 42 of the third embodiment is used, the oil phase OP and the aqueous phase WP do not flow out through the deoiled sludge discharge port 41 during operation, and the wet sludge WS accumulated near the deoiled sludge discharge port 4. Is smoothly and continuously discharged from the top discharge port 48 at a suitable speed.
The lift mechanism described above may be a screw conveyor type provided with a spiral blade 47 or a bucket conveyor type provided in a watertight tower.
[0037]
【The invention's effect】
In the continuous cleaning apparatus for oil-containing sludge of the present invention, a rotary cylinder having a porous peripheral surface is rotatably disposed in an outer cylinder by inclining its rotation axis. An oil-containing sludge supply port for supplying sludge is formed, a deoiled sludge discharge port is formed at the lower end, and a solvent supply port for supplying a solvent having a lower specific gravity than water and capable of separating liquid and liquid from the outer cylinder. And an oil phase discharge port for discharging the oil phase liquid-liquid separated in the outer cylinder, a water supply port for supplying water to the outer cylinder, and water for discharging the liquid phase liquid-liquid separated in the outer cylinder. The rotary cylinder is rotated so that the oil-containing sludge is continuously supplied to the oil-containing sludge supply port of the rotary cylinder, and the outer cylinder is supplied from the water supply port and the solvent supply port. Water and solvent are supplied to the inside, respectively. The oil phase is discharged from the oil-containing sludge by discharging the water phase and oil phase that have been separated into liquid and liquid so that they are kept in position, and continuously discharging the deoiled and water-containing sludge from the deoiling sludge outlet. Clean sludge can be continuously obtained, and the separated oil can be effectively used. The above-described method of the present invention is not only suitable for large-scale purification of oil-containing sludge, but also uses an inexpensive and reusable oil agent such as kerosene or light gas oil easily obtained in a petroleum refining plant or the like as a solvent. Since high temperature and high pressure are not required, there is an advantage that consumable costs and energy costs are small, and process safety is high.
[Brief description of the drawings]
FIG. 1 is a cross-sectional view showing one example of an apparatus for continuously cleaning oil-containing sludge of the present invention and an embodiment using the same.
FIG. 2 is a partial sectional view showing another example of the continuous cleaning apparatus for oil-containing sludge of the present invention and an embodiment using the same.
FIG. 3 is a cross-sectional view showing still another example of the continuous cleaning apparatus for oil-containing sludge of the present invention and an embodiment using the same.
[Explanation of symbols]
1 Rotating cylinder 2 Outer cylinder 3 Oil-containing sludge supply port 4 Deoiled sludge discharge port 5 Solvent supply port 6 Oil phase discharge port 7 Water supply port 8 Water phase Discharge port 10: Continuous cleaning apparatus 20 for oil-containing sludge of the present invention 20 Continuous dewatering apparatus OS: Oil-containing sludge WS: Water-containing sludge CS: Cleaned sludge S: Solvent W: Water OP: Oil phase WP: water phase L: interface

Claims (9)

多孔性の周面を有する回転筒体がその回転軸を傾斜して外筒内に回転自在に配置され、この回転筒体の上端部に、含油汚泥を供給する含油汚泥供給口が形成され、下端部に脱油汚泥排出口が形成され、
前記外筒に、外筒内に水を供給する水供給口と、この水と液液分離が可能でこの水より低比重の溶剤を供給する溶剤供給口と、外筒内で液液分離された水相を排出する水相排出口と、外筒内で液液分離された油相を排出する油相排出口とが設けられた含油汚泥の連続清浄化装置。
A rotary cylinder having a porous peripheral surface is rotatably disposed in the outer cylinder with its rotation axis inclined, and an oil-containing sludge supply port for supplying oil-containing sludge is formed at an upper end of the rotary cylinder, A deoiled sludge outlet is formed at the lower end,
The outer cylinder, a water supply port for supplying water into the outer cylinder, a solvent supply port for supplying a solvent having a lower specific gravity than the water and capable of liquid-liquid separation, and a liquid-liquid separation in the outer cylinder. A continuous apparatus for purifying oil-bearing sludge, comprising an aqueous phase discharge port for discharging an aqueous phase, and an oil phase discharge port for discharging an oil phase liquid-liquid separated in an outer cylinder.
前記の外筒に加熱手段が設けられた請求項1に記載の含油汚泥の連続清浄化装置。The apparatus for continuously cleaning oil-containing sludge according to claim 1, wherein a heating means is provided in the outer cylinder. 前記の脱油汚泥排出口に、汚泥掻出し手段が設けられた請求項1に記載の含油汚泥の連続清浄化装置。The continuous cleaning apparatus for oil-containing sludge according to claim 1, wherein a sludge scraping means is provided at the deoiled sludge discharge port. 前記の脱油汚泥排出口に、排出された汚泥を上方に搬送する水密性の搬送手段が連結された請求項1に記載の含油汚泥の連続清浄化装置。2. The continuous apparatus for purifying oil-containing sludge according to claim 1, wherein a water-tight conveying means for conveying the discharged sludge upward is connected to the deoiled sludge discharge port. 3. 前記の脱油汚泥排出口から排出される汚泥を脱水する連続脱水装置が付設された請求項1に記載の含油汚泥の連続清浄化装置。The continuous cleaning device for oil-containing sludge according to claim 1, further comprising a continuous dewatering device for dewatering the sludge discharged from the deoiled sludge discharge port. 請求項1に記載の含油汚泥の連続清浄化装置を用いて含油汚泥を清浄化するに際して、前記回転筒体を回転し、回転筒体の含油汚泥供給口に含油汚泥を連続的に供給し、水供給口と溶剤供給口とから外筒内にそれぞれ水と溶剤とを供給し、水相排出口と油相排出口とからそれぞれ、水相と油相との界面が回転筒体の周面を横切る位置に保たれるように液液分離した水相と油相とを排出し、かつ脱油汚泥排出口から、脱油され含水した汚泥を連続的に排出する含油汚泥の連続清浄化方法。When cleaning the oil-containing sludge using the oil-containing sludge continuous cleaning device according to claim 1, the rotary cylinder is rotated, and the oil-containing sludge is continuously supplied to the oil-containing sludge supply port of the rotary cylinder. Water and solvent are supplied into the outer cylinder from the water supply port and the solvent supply port, respectively, and the interface between the water phase and the oil phase is formed from the water phase discharge port and the oil phase discharge port, respectively, on the peripheral surface of the rotary cylinder. A method for continuously cleaning oil-bearing sludge, which discharges the aqueous phase and oil phase separated into liquid and liquid so as to be kept at a position crossing the oil-removing sludge, and continuously discharges the deoiled and water-containing sludge from a deoiling sludge outlet. . 外筒内の油相を、50℃〜100℃の温度範囲内に加温する請求項6に記載の含油汚泥の連続清浄化方法。The method for continuously cleaning oil-containing sludge according to claim 6, wherein the oil phase in the outer cylinder is heated within a temperature range of 50C to 100C. 脱油汚泥排出口から連続的に排出された含水汚泥を、付設された連続脱水装置を用いて連続的に脱水する請求項6に記載の含油汚泥の連続清浄化方法。The method for continuously cleaning oil-containing sludge according to claim 6, wherein the water-containing sludge continuously discharged from the deoiled sludge discharge port is continuously dewatered by using an attached continuous dewatering device. 前記外筒の水供給口から界面活性剤を含む水を供給する請求項6に記載の含油汚泥の連続清浄化方法。The method for continuously cleaning oil-containing sludge according to claim 6, wherein water containing a surfactant is supplied from a water supply port of the outer cylinder.
JP00961296A 1996-01-23 1996-01-23 Apparatus and method for continuous cleaning of oil-containing sludge Expired - Fee Related JP3555050B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP00961296A JP3555050B2 (en) 1996-01-23 1996-01-23 Apparatus and method for continuous cleaning of oil-containing sludge

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP00961296A JP3555050B2 (en) 1996-01-23 1996-01-23 Apparatus and method for continuous cleaning of oil-containing sludge

Publications (2)

Publication Number Publication Date
JPH09192694A JPH09192694A (en) 1997-07-29
JP3555050B2 true JP3555050B2 (en) 2004-08-18

Family

ID=11725128

Family Applications (1)

Application Number Title Priority Date Filing Date
JP00961296A Expired - Fee Related JP3555050B2 (en) 1996-01-23 1996-01-23 Apparatus and method for continuous cleaning of oil-containing sludge

Country Status (1)

Country Link
JP (1) JP3555050B2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102849906B (en) * 2012-05-18 2014-06-25 北京航天试验技术研究所 Oil sludge separation apparatus and separation method
CN112958595B (en) * 2021-02-26 2022-11-22 中国石油天然气集团有限公司 Hot washing method and equipment containing oil sludge

Also Published As

Publication number Publication date
JPH09192694A (en) 1997-07-29

Similar Documents

Publication Publication Date Title
US5090498A (en) Water wash/oil wash cyclonic column tank separation system
US4336136A (en) System for processing soils contaminated by crude oils or other refined petroleum products
US5344255A (en) Oil, water and sand separator
US5225085A (en) Apparatus and process for the separation and reclamation of selected components in grease trap waste
US4424081A (en) Reconditioning soils contaminated by crude oils or other refined petroleum products
CN106630514B (en) Treatment system for oily sludge, separation equipment and treatment method thereof
US4110195A (en) Apparatus and process for extracting oil or bitumen from tar sands
KR100534067B1 (en) Soil washing method and facility for physical separation and remediation of polluted soil
US20160271531A1 (en) Process and Apparatus for Recovering Valuable or Harmful Non-Aqueous Liquids from Slurries
JPH02198686A (en) Method and device for separating and removing foreign matter from liquid stream
CA1331349C (en) Apparatus and process to separate and remove extraneous matter from a liquid stream
US5098584A (en) Method for separating oils from scum
CA2509783A1 (en) Method and apparatus for using peroxide and alkali to recover bitumen from tar sands
CN101798127B (en) Oil-containing silt treatment method and system
JP3555050B2 (en) Apparatus and method for continuous cleaning of oil-containing sludge
CN110937770A (en) Reduction treatment process for oily sludge
GB2238730A (en) Removing cuttings from drilling mud
EP0588865A1 (en) Cleaning hydrocarbon contaminated material.
JPH09176659A (en) Method for cleaning oil-containing sludge
JPH0838942A (en) Method for processing oily suspension
Svensson Use or disposal of by-products and spent material from the vegetable oil processing industry in Europe
PT89375B (en) PROCESS FOR DECONTAMINATION OF A MATERIAL AND INSTALLATION FOR THE REALIZATION OF THE REFERRED PROCESS
US4832854A (en) Apparatus and process to separate and remove extraneous matter from a liquid stream
JP2002003859A (en) Process and apparatus for separating and refining high viscous oil by evaporating waste oil of high viscous oil
JPH09192531A (en) How to clean contaminated soil

Legal Events

Date Code Title Description
A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20040406

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20040413

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20040428

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110521

Year of fee payment: 7

LAPS Cancellation because of no payment of annual fees