JP3555849B2 - Detergent composition - Google Patents
Detergent composition Download PDFInfo
- Publication number
- JP3555849B2 JP3555849B2 JP23020999A JP23020999A JP3555849B2 JP 3555849 B2 JP3555849 B2 JP 3555849B2 JP 23020999 A JP23020999 A JP 23020999A JP 23020999 A JP23020999 A JP 23020999A JP 3555849 B2 JP3555849 B2 JP 3555849B2
- Authority
- JP
- Japan
- Prior art keywords
- methyltaurine
- general formula
- saturated
- hydrocarbon group
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims description 34
- 239000003599 detergent Substances 0.000 title claims description 22
- SUZRRICLUFMAQD-UHFFFAOYSA-N N-methyltaurine Natural products CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 claims description 50
- -1 N-methyltaurine alkali metal salt Chemical class 0.000 claims description 40
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 25
- 229930195734 saturated hydrocarbon Natural products 0.000 claims description 24
- 229910052783 alkali metal Inorganic materials 0.000 claims description 23
- 229930195735 unsaturated hydrocarbon Natural products 0.000 claims description 22
- 125000004432 carbon atom Chemical group C* 0.000 claims description 21
- 229920006395 saturated elastomer Polymers 0.000 claims description 21
- 239000003513 alkali Substances 0.000 claims description 12
- 150000001447 alkali salts Chemical class 0.000 claims description 12
- 238000004140 cleaning Methods 0.000 claims description 12
- 150000001340 alkali metals Chemical class 0.000 claims description 11
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 11
- NAWXUBYGYWOOIX-SFHVURJKSA-N (2s)-2-[[4-[2-(2,4-diaminoquinazolin-6-yl)ethyl]benzoyl]amino]-4-methylidenepentanedioic acid Chemical compound C1=CC2=NC(N)=NC(N)=C2C=C1CCC1=CC=C(C(=O)N[C@@H](CC(=C)C(O)=O)C(O)=O)C=C1 NAWXUBYGYWOOIX-SFHVURJKSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 238000005187 foaming Methods 0.000 description 16
- 150000001875 compounds Chemical class 0.000 description 15
- 239000000523 sample Substances 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 239000008213 purified water Substances 0.000 description 6
- 239000002453 shampoo Substances 0.000 description 6
- 239000006260 foam Substances 0.000 description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- 239000002280 amphoteric surfactant Substances 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 239000012459 cleaning agent Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- BJRNKVDFDLYUGJ-RMPHRYRLSA-N hydroquinone O-beta-D-glucopyranoside Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1OC1=CC=C(O)C=C1 BJRNKVDFDLYUGJ-RMPHRYRLSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- LDMOEFOXLIZJOW-UHFFFAOYSA-N 1-dodecanesulfonic acid Chemical compound CCCCCCCCCCCCS(O)(=O)=O LDMOEFOXLIZJOW-UHFFFAOYSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000195955 Equisetum hyemale Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- KDXKERNSBIXSRK-YFKPBYRVSA-N L-lysine Chemical compound NCCCC[C@H](N)C(O)=O KDXKERNSBIXSRK-YFKPBYRVSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 1
- 239000004472 Lysine Substances 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 1
- KCFRUUYAXCDZNZ-UHFFFAOYSA-N N-dodecanoyltaurine Chemical compound CCCCCCCCCCCC(=O)NCCS(O)(=O)=O KCFRUUYAXCDZNZ-UHFFFAOYSA-N 0.000 description 1
- 241000736199 Paeonia Species 0.000 description 1
- 235000006484 Paeonia officinalis Nutrition 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 229960000271 arbutin Drugs 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 239000012632 extractable Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229930182478 glucoside Natural products 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000000845 maltitol Substances 0.000 description 1
- 235000010449 maltitol Nutrition 0.000 description 1
- 229940035436 maltitol Drugs 0.000 description 1
- 125000002960 margaryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- BJRNKVDFDLYUGJ-UHFFFAOYSA-N p-hydroxyphenyl beta-D-alloside Natural products OC1C(O)C(O)C(CO)OC1OC1=CC=C(O)C=C1 BJRNKVDFDLYUGJ-UHFFFAOYSA-N 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000012488 sample solution Substances 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- GYDJEQRTZSCIOI-LJGSYFOKSA-N tranexamic acid Chemical compound NC[C@H]1CC[C@H](C(O)=O)CC1 GYDJEQRTZSCIOI-LJGSYFOKSA-N 0.000 description 1
- 229960000401 tranexamic acid Drugs 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Description
【０００１】
【発明の属する技術分野】
本発明は洗浄剤組成物に関し、特に泡立ちが良く、使用後にぬめり感を生じない洗浄剤組成物に関する。
【０００２】
【従来の技術】
従来、泡立ちや使用性の観点から、クレンジングフォーム、ボディーシャンプー、シャンプーなどの洗浄料にアルキル硫酸塩が用いられてきた。特にアルキル硫酸塩で洗浄した髪はきしみ感を伴わないため、シャンプーでは古くから主基剤として利用されている。一方、クレンジングフォームやボディーシャンプーにも使用されているが、主基剤としてではなく、起泡力を付与する助剤として主に使用されている。これは、使用感触にぬめり感を生じるためであり、アルキル硫酸塩にもさっぱり感を付与できれば応用範囲がさらに広がる。
【０００３】
【発明が解決しようとする課題】
上述のように、アルキル硫酸塩は泡立ちが良いという優れた特性を有するので、さっぱり感を付与することができれば、シャンプー以外の洗浄料にも主基剤として使用することにより、泡立ちの良い洗浄料を得ることができる。
【０００４】
そこで本発明の目的は、泡立ちが良く、使用後にぬめり感を生じない洗浄剤組成物を提供することを目的とする。
【０００５】
【課題を解決するための手段】
すなわち、本発明は、下記一般式（１）で表されるＮ−アシルメチルタウリンのＮ−メチルタウリンアルカリ金属塩を必須成分として配合することを特徴とする洗浄剤組成物を提供する。
【化１１】
Ｒ−ＣＯ−Ｎ（ＣＨ３）−ＣＨ２−ＣＨ２−ＳＯ３ −Ｈ２Ｎ＋（ＣＨ３）−ＣＨ２−ＣＨ２−ＳＯ３ −Ｘ＋ （１）
（但し、式中Ｒは炭素数７〜２３の飽和又は不飽和の炭化水素基、Ｘはアルカリ金属を表す。）
【０００６】
また、本発明は、下記一般式（２）で表されるＮ−アシルメチルタウリンのＮ−メチルタウリン有機アルカリ塩を必須成分として配合することを特徴とする洗浄剤組成物を提供する。
【化１２】
Ｒ−ＣＯ−Ｎ（ＣＨ３）−ＣＨ２−ＣＨ２−ＳＯ３ −Ｈ２Ｎ＋（ＣＨ３）−ＣＨ２−ＣＨ２−ＳＯ３ −Ｙ＋ （２）
（但し、式中Ｒは炭素数７〜２３の飽和又は不飽和の炭化水素基、Ｙは有機アルカリを表す。）
【０００７】
また、本発明は、下記一般式（３）で表されるＮ−アシルタウリンのＮ−メチルタウリンアルカリ金属塩を必須成分として配合することを特徴とする洗浄剤組成物を提供する。
【化１３】
Ｒ−ＣＯ−ＮＨ−ＣＨ２−ＣＨ２−ＳＯ３ −Ｈ２Ｎ＋（ＣＨ３）−ＣＨ２−ＣＨ２−ＳＯ３ −Ｘ＋ （３）
（但し、式中Ｒは炭素数７〜２３の飽和又は不飽和の炭化水素基、Ｘはアルカリ金属を表す。）
【０００８】
また、本発明は、下記一般式（４）で表されるＮ−アシルタウリンのＮ−メチルタウリン有機アルカリ塩を必須成分として配合することを特徴とする洗浄剤組成物を提供する。
【化１４】
Ｒ−ＣＯ−ＮＨ−ＣＨ２−ＣＨ２−ＳＯ３ −Ｈ２Ｎ＋（ＣＨ３）−ＣＨ２−ＣＨ２−ＳＯ３ −Ｙ＋ （４）
（但し、式中Ｒは炭素数７〜２３の飽和又は不飽和の炭化水素基、Ｙは有機アルカリを表す。）
【０００９】
また、本発明は、下記一般式（５）で表されるアルキル硫酸エステルのＮ−メチルタウリンアルカリ金属塩を必須成分として配合することを特徴とする洗浄剤組成物を提供する。
【化１５】
Ｒ−Ｏ−ＳＯ３ −Ｈ２Ｎ＋（ＣＨ３）−ＣＨ２−ＣＨ２−ＳＯ３ −Ｘ＋ （５）
（但し、式中Ｒは炭素数７〜２３の飽和又は不飽和の炭化水素基、Ｘはアルカリ金属を表す。）
【００１０】
また、本発明は、下記一般式（６）で表されるアルキル硫酸エステルのＮ−メチルタウリン有機アルカリ塩を必須成分として配合することを特徴とする洗浄剤組成物を提供する。
【化１６】
Ｒ−Ｏ−ＳＯ３ −Ｈ２Ｎ＋（ＣＨ３）−ＣＨ２−ＣＨ２−ＳＯ３ −Ｙ＋ （６）
（但し、式中Ｒは炭素数７〜２３の飽和又は不飽和の炭化水素基、Ｙは有機アルカリを表す。）
【００１１】
また、本発明は、下記一般式（７）で表されるアルキルエーテル硫酸エステルのＮ−メチルタウリンアルカリ金属塩を必須成分として配合することを特徴とする洗浄剤組成物を提供する。
【化１７】
Ｒ−Ｏ（ＣＨ２ＣＨ２Ｏ）ｎＳＯ３ −Ｈ２Ｎ＋（ＣＨ３）−ＣＨ２−ＣＨ２−ＳＯ３ −Ｘ＋ （７）
（但し、式中Ｒは炭素数７〜２３の飽和又は不飽和の炭化水素基、ｎは１〜４０の整数、Ｘはアルカリ金属を表す。）
【００１２】
また、本発明は、下記一般式（８）で表されるアルキルエーテル硫酸エステルのＮ−メチルタウリン有機アルカリ塩を必須成分として配合することを特徴とする洗浄剤組成物を提供する。
【化１８】
Ｒ−Ｏ（ＣＨ２ＣＨ２Ｏ）ｎＳＯ３ −Ｈ２Ｎ＋（ＣＨ３）−ＣＨ２−ＣＨ２−ＳＯ３ −Ｙ＋ （８）
（但し、式中Ｒは炭素数７〜２３の飽和又は不飽和の炭化水素基、ｎは１〜４０の整数、Ｙは有機アルカリを表す。）
【００１３】
また、本発明は、下記一般式（９）で表されるアルキルスルホン酸のＮ−メチルタウリンアルカリ金属塩を必須成分として配合することを特徴とする洗浄剤組成物を提供する。
【化１９】
Ｒ−ＳＯ３ −Ｈ２Ｎ＋（ＣＨ３）−ＣＨ２−ＣＨ２−ＳＯ３ −Ｘ＋ （９）
（但し、式中Ｒは炭素数７〜２３の飽和又は不飽和の炭化水素基、Ｘはアルカリ金属を表す。）
【００１４】
また、本発明は、下記一般式（１０）で表されるアルキルスルホン酸のＮ−メチルタウリン有機アルカリ塩を必須成分として配合することを特徴とする洗浄剤組成物を提供する。
【化２０】
Ｒ−ＳＯ３ −Ｈ２Ｎ＋（ＣＨ３）−ＣＨ２−ＣＨ２−ＳＯ３ −Ｙ＋ （１０）
（但し、式中Ｒは炭素数７〜２３の飽和又は不飽和の炭化水素基、Ｙは有機アルカリを表す。）
【００１５】
【発明の実施の形態】
以下、本発明を詳細に説明する。
【００１６】
本発明の洗浄剤組成物に必須成分として配合する上記一般式（１）〜（１０）で表される化合物において、式中のＲは炭素数７〜２３の飽和又は不飽和の炭化水素基を表す。その具体例としては、例えば、ヘプチル基、オクチル基、ノニル基、デシル基、ウンデシル基、ドデシル基、トリデシル基、テトラデシル基、ペンタデシル基、ヘキサデシル基、ヘプタデシル基、オクタデシル基、テトラエイコシル基などの直鎖状飽和炭化水素基、２−エチルヘプタデシル基、２−エチルペンチル基などの分岐飽和炭化水素基、８−ヘプタデセニル基、オレイル基、４，６−オクタデカジエテニル基などの直鎖不飽和炭化水素基、２−メチルオクタデカ−６−エテニル基などの分岐不飽和炭化水素基などが挙げられる。
【００１７】
また、上記一般式（１）、（３）、（５）、（７）及び（９）において、Ｘはナトリウム、カリウム、リチウム等のアルカリ金属を表し、上記一般式（２）、（４）、（６）、（８）及び（１０）において、Ｙはトリエタノールアミン、ジエタノールアミン、リジン等の有機アルカリを表す。
【００１８】
本発明の洗浄剤組成物に必須成分として配合する上記一般式（１）〜（１０）で表される化合物の具体例としては、各式に対応して以下のものが挙げられる。
一般式（１）：Ｎ−ラウロイルメチルタウリンＮ−メチルタウリンナトリウム
一般式（２）：Ｎ−ラウロイルメチルタウリンＮ−メチルタウリントリエタノールアミン
一般式（３）：Ｎ−ラウロイルタウリンＮ−メチルタウリンナトリウム
一般式（４）：Ｎ−ラウロイルタウリンＮ−メチルタウリントリエタノールアミン
一般式（５）：ラウリル硫酸エステルＮ−メチルタウリンナトリウム
一般式（６）：ラウリル硫酸エステルＮ−メチルタウリントリエタノールアミン
一般式（７）：ポリオキシエチレンラウリルエーテル硫酸エステルＮ−メチルタウリンナトリウム
一般式（８）：ポリオキシエチレンラウリルエーテル硫酸エステルＮ−メチルタウリントリエタノールアミン
一般式（９）：ラウリルスルホン酸Ｎ−メチルタウリンナトリウム
一般式（１０）：ラウリルスルホン酸Ｎ−メチルタウリントリエタノールアミン
【００１９】
本発明の洗浄剤組成物に必須成分として配合する上記一般式（１）〜（１０）で表される化合物の配合量としては、０．５〜９０重量％が好ましい。より好ましくは５〜４０重量％であり、この範囲で調製した洗浄剤組成物は、本発明の効果をより顕著に得ることができる。配合量が０．５重量％未満では本発明の効果は得られにくく、配合量が９０重量％を越えると水への溶解性が悪くなるなどの不都合な点があり、好ましくない。
【００２０】
本発明の洗浄剤組成物に必須成分として配合する上記一般式（１）〜（１０）で表される化合物の製造方法としては、約８０℃にてＮ−アシルメチルタウリン、Ｎ−アシルタウリン、アルキル硫酸エステル、アルキルエーテル硫酸エステル又はアルキルスルホン酸を溶解し、これにＮ−メチルタウリンアルカリ金属塩又はＮ−メチルタウリン有機アルカリ塩の水溶液を撹拌しながら加えるか、Ｎ−メチルタウリン水溶液と他のアルカリの水溶液をそれぞれ別々に撹拌しながら加える方法などがある。
【００２１】
本発明の洗浄剤組成物とは、あるものに対して、洗浄作用を発揮できる組成物を言い、洗浄されるべきものは制限されないが、好ましくは、化粧品、医薬部外品など身体に適用される洗浄剤を指し、上記必須成分に加えて必要により、通常洗浄剤組成物に含まれる石鹸、アルキル硫酸エステル（塩）、ポリオキシエチレンアルキルエーテル硫酸（塩）、ヒドロキシアルキルエーテルカルボン酸（塩）などのアニオン界面活性剤、イミダゾリン系両性界面活性剤、ベタイン系両性界面活性剤などの両性界面活性剤、ポリオキシエチレンアルキルエーテル、ポリオキシエチレン脂肪酸エステル、ショ糖脂肪酸エステル、アルキルグルコシド、マルチトールヒドロキシ脂肪族エーテルなどの非イオン界面活性剤、トリメチルアルキルアンモニウムクロライドなどのカチオン界面活性剤、グリセリン、１，３−ブチレングリコール、ジプロピレングリコールなどの保湿剤、センブリ、シャクヤク、イリス、スギナなどの植物抽出成分、トラネキサム酸、アルブチンなどの薬剤、香料、防腐剤など他の成分を適宜配合することができる。
【００２２】
【実施例】
以下、実施例によって本発明をさらに詳細に説明する。なお、本発明は以下の実施例に限定されるものではない。
【００２３】
（試験例）
本発明に用いる前記一般式（１）〜（１０）で表される化合物について、泡立ち試験及び実使用試験を行った。
【００２４】
１．振とう法による泡立ち試験
７０ｐｐｍの塩化カルシウムを溶解したイオン交換水に各試料を０．５重量％の割合で溶かした後、塩酸でｐＨ７．０に調整した。各試料液を３０℃に保ち、２０ｍｌを内径３ｃｍ、高さ２０ｃｍのすり栓付きネスラー管に入れ、振り子式振とう器により１秒間に１回の割合で９０°ずつ傾けた。１分後に装置から取り外し、泡の高さを測定した。また、泡の高さが半分になるまでの時間（持続時間）も計測した。
【００２５】
（官能による実使用試験）
パネル５０名を用いて実使用試験を行った。実使用試験は、各試料の１０％水溶液１０ｍｌをとり、３０秒間手洗いを行い、その使用感及び水洗後の使用感触について、表１に示した評価基準に基づき、５段階で評価した。その平均点を５０名の総合評価とした。
【００２６】
【表１】
○：評価点の平均３〜３．９
△：評価点の平均２〜２．９
×：評価点の平均１〜１．９
【００２７】
（試験試料１、２、比較試料１〜３）
表２に示す各化合物（試験試料１、２はそれぞれ一般式（１）、（２）で表される化合物に対応）を試料とし、各試料について泡立ち試験及び実使用試験を行った。その結果を表３に示す。
【００２８】
【表２】
【表３】
（試験試料３、４、比較試料４〜６）
表４に示す各化合物（試験試料３、４はそれぞれ一般式（３）、（４）で表される化合物に対応）を試料とし、各試料について泡立ち試験及び実使用試験を行った。その結果を表５に示す。
【００３１】
【表４】
【表５】
（試験試料５、６、比較試料７〜９）
表６に示す各化合物（試験試料５、６はそれぞれ一般式（５）、（６）で表される化合物に対応）を試料とし、各試料について泡立ち試験及び実使用試験を行った。その結果を表７に示す。
【００３４】
【表６】
【表７】
（試験試料７、８、比較試料１０〜１２）
表８に示す各化合物（試験試料７、８はそれぞれ一般式（７）、（８）で表される化合物に対応）を試料とし、各試料について泡立ち試験及び実使用試験を行った。その結果を表９に示す。
【００３７】
【表８】
【表９】
（試験試料９、１０、比較試料１３〜１５）
表１０に示す各化合物（試験試料９、１０はそれぞれ一般式（９）、（１０）で表される化合物に対応）を試料とし、各試料について泡立ち試験及び実使用試験を行った。その結果を表１１に示す。
【００４０】
【表１０】
【表１１】
以上の結果より、試験試料は比較試料に比べ泡立ち及び泡の持続性に優れ、使用後のぬめり感も生じないことが分かった。
【００４３】
次に、本発明に係る洗浄剤組成物の具体的な実施例を示す。なお、各種成分の配合量は重量％である。
【００４４】
精製水を７０℃に加熱し、他成分を加え均一に溶解した後、冷却する。
【００４５】
精製水を７０℃に加熱し、他成分を加え均一に溶解した後、冷却する。
【００４７】
精製水を７０℃に加熱し、他成分を加え均一に溶解した後、冷却する。
【００４８】
精製水を７０℃に加熱し、他成分を加え均一に溶解した後、冷却する。
【００４９】
精製水を７０℃に加熱し、他成分を加え均一に溶解した後、冷却する。
【００５０】
精製水を７０℃に加熱し、他成分を加え均一に溶解した後、冷却する。
【００５１】
実施例１〜７は、いずれも起泡性に優れ、使用後のぬめり感もなく使用性に優れていた。
【００５２】
【発明の効果】
以上説明したように本発明の洗浄剤組成物は、Ｎ−アシルメチルタウリン、Ｎ−アシルタウリン、アルキル硫酸エステル、アルキルエーテル硫酸エステル若しくはアルキルスルホン酸のＮ−メチルタウリンアルカリ金属塩又はＮ−メチルタウリン有機アルカリ塩を必須成分として配合することにより、泡立ちが良く、使用後にぬめり感を生じない使用性に優れている。[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a cleaning composition, and more particularly to a cleaning composition which has good foaming and does not give a slimy feeling after use.
[0002]
[Prior art]
Conventionally, from the viewpoints of foaming and usability, alkyl sulfates have been used in cleansing foams, body shampoos, shampoos, and other cleaning agents. In particular, shampoos have long been used as main bases in shampoos since hair washed with alkyl sulfates does not have a squeaky feeling. On the other hand, it is also used in cleansing foams and body shampoos, but is mainly used not as a main base but as an auxiliary agent for imparting foaming power. This is because a slimy feeling is generated in the use feeling, and if a refreshing feeling can be imparted to the alkyl sulfate, the application range is further expanded.
[0003]
[Problems to be solved by the invention]
As described above, alkyl sulfates have an excellent property that foaming is good, so that if a refreshing feeling can be imparted, by using as a main base also a cleaning agent other than shampoo, a cleaning agent with good foaming can be obtained. Can be obtained.
[0004]
Accordingly, an object of the present invention is to provide a detergent composition which has good foaming and does not cause a slimy feeling after use.
[0005]
[Means for Solving the Problems]
That is, the present invention provides a detergent composition comprising, as an essential component, an N-methyltaurine alkali metal salt of N-acylmethyltaurine represented by the following general formula (1).
Embedded image
R-CO-N (CH 3 ) -CH 2 -CH 2 -SO 3 - H 2 N + (CH 3) -CH 2 -CH 2 -SO 3 - X + (1)
(Where R represents a saturated or unsaturated hydrocarbon group having 7 to 23 carbon atoms, and X represents an alkali metal).
[0006]
Further, the present invention provides a detergent composition characterized by comprising as an essential component an N-methyltaurine organic alkali salt of N-acylmethyltaurine represented by the following general formula (2).
Embedded image
R-CO-N (CH 3 ) -CH 2 -CH 2 -SO 3 - H 2 N + (CH 3) -CH 2 -CH 2 -SO 3 - Y + (2)
(Where R represents a saturated or unsaturated hydrocarbon group having 7 to 23 carbon atoms, and Y represents an organic alkali).
[0007]
Further, the present invention provides a detergent composition comprising an N-methyltaurine alkali metal salt of N-acyltaurine represented by the following general formula (3) as an essential component.
Embedded image
R-CO-NH-CH 2 -CH 2 -SO 3 - H 2 N + (CH 3) -CH 2 -CH 2 -SO 3 - X + (3)
(Where R represents a saturated or unsaturated hydrocarbon group having 7 to 23 carbon atoms, and X represents an alkali metal).
[0008]
Further, the present invention provides a detergent composition characterized by comprising an organic alkali salt of N-methyltaurine represented by the following general formula (4) as an essential component.
Embedded image
R-CO-NH-CH 2 -CH 2 -SO 3 - H 2 N + (CH 3) -CH 2 -CH 2 -SO 3 - Y + (4)
(Where R represents a saturated or unsaturated hydrocarbon group having 7 to 23 carbon atoms, and Y represents an organic alkali).
[0009]
Further, the present invention provides a detergent composition characterized by comprising an alkali metal salt of N-methyltaurine of an alkyl sulfate represented by the following general formula (5) as an essential component.
Embedded image
R-O-SO 3 - H 2 N + (CH 3) -CH 2 -CH 2 -SO 3 - X + (5)
(Where R represents a saturated or unsaturated hydrocarbon group having 7 to 23 carbon atoms, and X represents an alkali metal).
[0010]
Further, the present invention provides a detergent composition characterized by comprising as an essential component an organic alkali salt of N-methyltaurine of an alkyl sulfate represented by the following general formula (6).
Embedded image
R-O-SO 3 - H 2 N + (CH 3) -CH 2 -CH 2 -SO 3 - Y + (6)
(Where R represents a saturated or unsaturated hydrocarbon group having 7 to 23 carbon atoms, and Y represents an organic alkali).
[0011]
Further, the present invention provides a detergent composition characterized by comprising as an essential component an N-methyltaurine alkali metal salt of an alkyl ether sulfate represented by the following general formula (7).
Embedded image
R-O (CH 2 CH 2 O) n SO 3 - H 2 N + (CH 3) -CH 2 -CH 2 -SO 3 - X + (7)
(Where R represents a saturated or unsaturated hydrocarbon group having 7 to 23 carbon atoms, n represents an integer of 1 to 40, and X represents an alkali metal).
[0012]
Further, the present invention provides a detergent composition characterized by comprising as an essential component an organic alkali salt of N-methyltaurine of an alkyl ether sulfate represented by the following general formula (8).
Embedded image
R-O (CH 2 CH 2 O) n SO 3 - H 2 N + (CH 3) -CH 2 -CH 2 -SO 3 - Y + (8)
(Where R represents a saturated or unsaturated hydrocarbon group having 7 to 23 carbon atoms, n represents an integer of 1 to 40, and Y represents an organic alkali).
[0013]
Further, the present invention provides a detergent composition comprising an alkali metal salt of alkyl sulfonic acid represented by the following general formula (9) as an essential component.
Embedded image
R-SO 3 - H 2 N + (CH 3) -CH 2 -CH 2 -SO 3 - X + (9)
(Where R represents a saturated or unsaturated hydrocarbon group having 7 to 23 carbon atoms, and X represents an alkali metal).
[0014]
Further, the present invention provides a detergent composition characterized by comprising an organic alkali salt of N-methyltaurine of an alkylsulfonic acid represented by the following general formula (10) as an essential component.
Embedded image
R-SO 3 - H 2 N + (CH 3) -CH 2 -CH 2 -SO 3 - Y + (10)
(Where R represents a saturated or unsaturated hydrocarbon group having 7 to 23 carbon atoms, and Y represents an organic alkali).
[0015]
BEST MODE FOR CARRYING OUT THE INVENTION
Hereinafter, the present invention will be described in detail.
[0016]
In the compounds represented by the above general formulas (1) to (10) to be blended as an essential component in the cleaning composition of the present invention, R in the formula represents a saturated or unsaturated hydrocarbon group having 7 to 23 carbon atoms. Represent. Specific examples thereof include, for example, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, tetraeicosyl, and the like. Branched saturated hydrocarbon groups such as a linear saturated hydrocarbon group, 2-ethylheptadecyl group and 2-ethylpentyl group; linear unsaturated groups such as 8-heptadecenyl group, oleyl group and 4,6-octadecadiethenyl group. And a branched unsaturated hydrocarbon group such as a saturated hydrocarbon group and a 2-methyloctadec-6-ethenyl group.
[0017]
In the general formulas (1), (3), (5), (7), and (9), X represents an alkali metal such as sodium, potassium, and lithium, and the general formulas (2), (4) , (6), (8) and (10), Y represents an organic alkali such as triethanolamine, diethanolamine and lysine.
[0018]
Specific examples of the compounds represented by the above general formulas (1) to (10) to be blended as essential components in the cleaning composition of the present invention include the following corresponding to each formula.
General formula (1): N-lauroyl methyl taurine N-methyl taurine sodium General formula (2): N-lauroyl methyl taurine N-methyl taurine triethanolamine General formula (3): N-lauroyl taurine N-methyl taurine sodium general Formula (4): N-lauroyltaurine N-methyltaurine triethanolamine General formula (5): Lauryl sulfate N-methyltaurine sodium General formula (6): Lauryl sulfate N-methyltaurine triethanolamine General formula (7 ): Polyoxyethylene lauryl ether sulfate N-methyltaurine sodium General formula (8): Polyoxyethylene lauryl ether sulfate N-methyltaurine triethanolamine General formula (9): N-methyltaurine sodium lauryl sulfonate Formula (10): lauryl sulfonate N- methyl taurine triethanolamine [0019]
The compounding amount of the compounds represented by the above general formulas (1) to (10) to be added as an essential component to the cleaning composition of the present invention is preferably 0.5 to 90% by weight. The content is more preferably 5 to 40% by weight, and the cleaning composition prepared in this range can more remarkably obtain the effects of the present invention. When the amount is less than 0.5% by weight, the effect of the present invention is hardly obtained, and when the amount exceeds 90% by weight, there are disadvantages such as poor solubility in water.
[0020]
As a method for producing the compounds represented by the above general formulas (1) to (10) to be blended as an essential component in the detergent composition of the present invention, N-acylmethyltaurine, N-acyltaurine, An alkyl sulfate, an alkyl ether sulfate or an alkyl sulfonic acid is dissolved and an aqueous solution of an alkali metal salt of N-methyltaurine or an organic alkali salt of N-methyltaurine is added thereto with stirring, or an aqueous solution of N-methyltaurine and another There is a method in which aqueous alkali solutions are separately added while stirring.
[0021]
The cleaning composition of the present invention refers to a composition capable of exerting a cleaning action on a certain substance, and the substance to be cleaned is not limited, but is preferably applied to the body such as cosmetics and quasi-drugs. Soap, alkyl sulfate (salt), polyoxyethylene alkyl ether sulfate (salt), hydroxyalkyl ether carboxylic acid (salt) usually contained in the detergent composition, if necessary, in addition to the above essential components. Amphoteric surfactants such as anionic surfactants, imidazoline-based amphoteric surfactants, betaine-based amphoteric surfactants, polyoxyethylene alkyl ether, polyoxyethylene fatty acid ester, sucrose fatty acid ester, alkyl glucoside, maltitol hydroxy Nonionic surfactants such as aliphatic ethers, Cationic surfactants such as Ride, humectants such as glycerin, 1,3-butylene glycol, dipropylene glycol, plant extractables such as assembly, peonies, iris and horsetail, drugs such as tranexamic acid, arbutin, fragrances and preservatives Other components can be appropriately blended.
[0022]
【Example】
Hereinafter, the present invention will be described in more detail with reference to examples. Note that the present invention is not limited to the following examples.
[0023]
(Test example)
The foaming test and the practical use test were performed on the compounds represented by the general formulas (1) to (10) used in the present invention.
[0024]
1. Foaming test by shaking method Each sample was dissolved in ion-exchanged water in which 70 ppm of calcium chloride was dissolved at a ratio of 0.5% by weight, and then adjusted to pH 7.0 with hydrochloric acid. Each sample solution was kept at 30 ° C., and 20 ml of the solution was placed in a Nesler tube having a 3 cm inner diameter and a height of 20 cm with a stopper, and tilted by 90 ° at a rate of once a second by a pendulum shaker. One minute later, it was removed from the device and the height of the foam was measured. The time (duration) until the height of the foam was reduced to half was also measured.
[0025]
(Actual use test by sensory)
An actual use test was performed using 50 panels. In the actual use test, 10 ml of a 10% aqueous solution of each sample was taken, hand-washed for 30 seconds, and the use feeling and the use feeling after water washing were evaluated in five steps based on the evaluation criteria shown in Table 1. The average score was used as a comprehensive evaluation by 50 people.
[0026]
[Table 1]
：: Average of evaluation points 3 to 3.9
Δ: Average of evaluation points 2 to 2.9
×: Average of evaluation points 1 to 1.9
[0027]
(Test samples 1 and 2, Comparative samples 1 to 3)
Each compound shown in Table 2 (the test samples 1 and 2 correspond to the compounds represented by the general formulas (1) and (2), respectively) was used as a sample, and a foaming test and an actual use test were performed on each sample. Table 3 shows the results.
[0028]
[Table 2]
[Table 3]
(Test samples 3, 4 and Comparative samples 4 to 6)
Each compound shown in Table 4 (test samples 3 and 4 correspond to the compounds represented by general formulas (3) and (4), respectively) was used as a sample, and a foaming test and an actual use test were performed on each sample. Table 5 shows the results.
[0031]
[Table 4]
[Table 5]
(Test samples 5, 6 and comparative samples 7 to 9)
Each compound shown in Table 6 (test samples 5 and 6 correspond to the compounds represented by general formulas (5) and (6), respectively) was used as a sample, and a foaming test and an actual use test were performed on each sample. Table 7 shows the results.
[0034]
[Table 6]
[Table 7]
(Test samples 7 and 8, Comparative samples 10 to 12)
Each compound shown in Table 8 (test samples 7 and 8 correspond to the compounds represented by general formulas (7) and (8), respectively) was used as a sample, and a foaming test and an actual use test were performed on each sample. Table 9 shows the results.
[0037]
[Table 8]
[Table 9]
(Test samples 9, 10 and Comparative samples 13 to 15)
Each compound shown in Table 10 (test samples 9 and 10 correspond to the compounds represented by general formulas (9) and (10), respectively) was used as a sample, and a foaming test and an actual use test were performed on each sample. The results are shown in Table 11.
[0040]
[Table 10]
[Table 11]
From the above results, it was found that the test sample was excellent in foaming and foam persistence as compared with the comparative sample, and did not have a slimy feeling after use.
[0043]
Next, specific examples of the cleaning composition according to the present invention will be described. In addition, the compounding quantity of various components is weight%.
[0044]
The purified water is heated to 70 ° C., the other components are added and uniformly dissolved, and then cooled.
[0045]
The purified water is heated to 70 ° C., the other components are added and uniformly dissolved, and then cooled.
[0047]
The purified water is heated to 70 ° C., the other components are added and uniformly dissolved, and then cooled.
[0048]
The purified water is heated to 70 ° C., the other components are added and uniformly dissolved, and then cooled.
[0049]
The purified water is heated to 70 ° C., the other components are added and uniformly dissolved, and then cooled.
[0050]
The purified water is heated to 70 ° C., the other components are added and uniformly dissolved, and then cooled.
[0051]
Examples 1 to 7 were all excellent in foaming properties and excellent in usability without slimy feeling after use.
[0052]
【The invention's effect】
As described above, the detergent composition of the present invention comprises N-acylmethyltaurine, N-acyltaurine, an alkyl sulfate, an alkyl ether sulfate or an alkyl sulfonic acid, an alkali metal salt of N-methyltaurine or N-methyltaurine. By blending the organic alkali salt as an essential component, the foaming is good and the usability that does not cause a slimy feeling after use is excellent.
Claims (10)
【化１】
Ｒ−ＣＯ−Ｎ（ＣＨ３）−ＣＨ２−ＣＨ２−ＳＯ３ −Ｈ２Ｎ＋（ＣＨ３）−ＣＨ２−ＣＨ２−ＳＯ３ −Ｘ＋ （１）
（但し、式中Ｒは炭素数７〜２３の飽和又は不飽和の炭化水素基、Ｘはアルカリ金属を表す。）A cleaning composition comprising an N-methyltaurine alkali metal salt of N-acylmethyltaurine represented by the following general formula (1) as an essential component.
Embedded image
R-CO-N (CH 3 ) -CH 2 -CH 2 -SO 3 - H 2 N + (CH 3) -CH 2 -CH 2 -SO 3 - X + (1)
(Where R represents a saturated or unsaturated hydrocarbon group having 7 to 23 carbon atoms, and X represents an alkali metal).
【化２】
Ｒ−ＣＯ−Ｎ（ＣＨ３）−ＣＨ２−ＣＨ２−ＳＯ３ −Ｈ２Ｎ＋（ＣＨ３）−ＣＨ２−ＣＨ２−ＳＯ３ −Ｙ＋ （２）
（但し、式中Ｒは炭素数７〜２３の飽和又は不飽和の炭化水素基、Ｙは有機アルカリを表す。）A detergent composition comprising, as an essential component, an N-methyltaurine organic alkali salt of N-acylmethyltaurine represented by the following general formula (2).
Embedded image
R-CO-N (CH 3 ) -CH 2 -CH 2 -SO 3 - H 2 N + (CH 3) -CH 2 -CH 2 -SO 3 - Y + (2)
(Where R represents a saturated or unsaturated hydrocarbon group having 7 to 23 carbon atoms, and Y represents an organic alkali).
【化３】
Ｒ−ＣＯ−ＮＨ−ＣＨ２−ＣＨ２−ＳＯ３ −Ｈ２Ｎ＋（ＣＨ３）−ＣＨ２−ＣＨ２−ＳＯ３ −Ｘ＋ （３）
（但し、式中Ｒは炭素数７〜２３の飽和又は不飽和の炭化水素基、Ｘはアルカリ金属を表す。）A detergent composition comprising, as an essential component, an N-methyltaurine alkali metal salt of N-acyltaurine represented by the following general formula (3).
Embedded image
R-CO-NH-CH 2 -CH 2 -SO 3 - H 2 N + (CH 3) -CH 2 -CH 2 -SO 3 - X + (3)
(Where R represents a saturated or unsaturated hydrocarbon group having 7 to 23 carbon atoms, and X represents an alkali metal).
【化４】
Ｒ−ＣＯ−ＮＨ−ＣＨ２−ＣＨ２−ＳＯ３ −Ｈ２Ｎ＋（ＣＨ３）−ＣＨ２−ＣＨ２−ＳＯ３ −Ｙ＋ （４）
（但し、式中Ｒは炭素数７〜２３の飽和又は不飽和の炭化水素基、Ｙは有機アルカリを表す。）A cleaning composition comprising an N-methyltaurine organic alkali salt of N-acyltaurine represented by the following general formula (4) as an essential component.
Embedded image
R-CO-NH-CH 2 -CH 2 -SO 3 - H 2 N + (CH 3) -CH 2 -CH 2 -SO 3 - Y + (4)
(Where R represents a saturated or unsaturated hydrocarbon group having 7 to 23 carbon atoms, and Y represents an organic alkali).
【化５】
Ｒ−Ｏ−ＳＯ３ −Ｈ２Ｎ＋（ＣＨ３）−ＣＨ２−ＣＨ２−ＳＯ３ −Ｘ＋ （５）
（但し、式中Ｒは炭素数７〜２３の飽和又は不飽和の炭化水素基、Ｘはアルカリ金属を表す。）A detergent composition comprising, as an essential component, an N-methyltaurine alkali metal salt of an alkyl sulfate represented by the following general formula (5).
Embedded image
R-O-SO 3 - H 2 N + (CH 3) -CH 2 -CH 2 -SO 3 - X + (5)
(Where R represents a saturated or unsaturated hydrocarbon group having 7 to 23 carbon atoms, and X represents an alkali metal).
【化６】
Ｒ−Ｏ−ＳＯ３ −Ｈ２Ｎ＋（ＣＨ３）−ＣＨ２−ＣＨ２−ＳＯ３ −Ｙ＋ （６）
（但し、式中Ｒは炭素数７〜２３の飽和又は不飽和の炭化水素基、Ｙは有機アルカリを表す。）A detergent composition comprising, as an essential component, an N-methyltaurine organic alkali salt of an alkyl sulfate represented by the following general formula (6).
Embedded image
R-O-SO 3 - H 2 N + (CH 3) -CH 2 -CH 2 -SO 3 - Y + (6)
(Where R represents a saturated or unsaturated hydrocarbon group having 7 to 23 carbon atoms, and Y represents an organic alkali).
【化７】
Ｒ−Ｏ（ＣＨ２ＣＨ２Ｏ）ｎＳＯ３ −Ｈ２Ｎ＋（ＣＨ３）−ＣＨ２−ＣＨ２−ＳＯ３ −Ｘ＋ （７）
（但し、式中Ｒは炭素数７〜２３の飽和又は不飽和の炭化水素基、ｎは１〜４０の整数、Ｘはアルカリ金属を表す。）A detergent composition comprising, as an essential component, an N-methyltaurine alkali metal salt of an alkyl ether sulfate represented by the following general formula (7).
Embedded image
R-O (CH 2 CH 2 O) n SO 3 - H 2 N + (CH 3) -CH 2 -CH 2 -SO 3 - X + (7)
(Where R represents a saturated or unsaturated hydrocarbon group having 7 to 23 carbon atoms, n represents an integer of 1 to 40, and X represents an alkali metal).
【化８】
Ｒ−Ｏ（ＣＨ２ＣＨ２Ｏ）ｎＳＯ３ −Ｈ２Ｎ＋（ＣＨ３）−ＣＨ２−ＣＨ２−ＳＯ３ −Ｙ＋ （８）
（但し、式中Ｒは炭素数７〜２３の飽和又は不飽和の炭化水素基、ｎは１〜４０の整数、Ｙは有機アルカリを表す。）A detergent composition comprising, as an essential component, an N-methyltaurine organic alkali salt of an alkyl ether sulfate represented by the following general formula (8).
Embedded image
R-O (CH 2 CH 2 O) n SO 3 - H 2 N + (CH 3) -CH 2 -CH 2 -SO 3 - Y + (8)
(Where R represents a saturated or unsaturated hydrocarbon group having 7 to 23 carbon atoms, n represents an integer of 1 to 40, and Y represents an organic alkali).
【化９】
Ｒ−ＳＯ３ −Ｈ２Ｎ＋（ＣＨ３）−ＣＨ２−ＣＨ２−ＳＯ３ −Ｘ＋ （９）
（但し、式中Ｒは炭素数７〜２３の飽和又は不飽和の炭化水素基、Ｘはアルカリ金属を表す。）A cleaning composition comprising, as an essential component, an N-methyltaurine alkali metal salt of an alkylsulfonic acid represented by the following general formula (9).
Embedded image
R-SO 3 - H 2 N + (CH 3) -CH 2 -CH 2 -SO 3 - X + (9)
(Where R represents a saturated or unsaturated hydrocarbon group having 7 to 23 carbon atoms, and X represents an alkali metal).
【化１０】
Ｒ−ＳＯ３ −Ｈ２Ｎ＋（ＣＨ３）−ＣＨ２−ＣＨ２−ＳＯ３ −Ｙ＋ （１０）
（但し、式中Ｒは炭素数７〜２３の飽和又は不飽和の炭化水素基、Ｙは有機アルカリを表す。）A detergent composition comprising, as an essential component, an organic alkali salt of N-methyltaurine of an alkylsulfonic acid represented by the following general formula (10).
Embedded image
R-SO 3 - H 2 N + (CH 3) -CH 2 -CH 2 -SO 3 - Y + (10)
(Where R represents a saturated or unsaturated hydrocarbon group having 7 to 23 carbon atoms, and Y represents an organic alkali).
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| JP4649708B2 (en) * | 2000-06-20 | 2011-03-16 | 日油株式会社 | Surfactant and detergent composition |
| JP3909038B2 (en) * | 2003-04-28 | 2007-04-25 | 株式会社資生堂 | Cleaning composition |
| JP6394358B2 (en) * | 2014-12-16 | 2018-09-26 | 日油株式会社 | Shampoo composition |
| JP7673387B2 (en) | 2020-03-27 | 2025-05-09 | 日油株式会社 | Branched fatty acid taurates and liquid detergents |
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