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JP3566348B2 - A method and an apparatus for collecting and granulating a waste resin molded product, and a method for manufacturing a wooden synthetic board using the collected resin material. - Google Patents
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JP3566348B2 - A method and an apparatus for collecting and granulating a waste resin molded product, and a method for manufacturing a wooden synthetic board using the collected resin material. - Google Patents

A method and an apparatus for collecting and granulating a waste resin molded product, and a method for manufacturing a wooden synthetic board using the collected resin material. Download PDF

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JP3566348B2
JP3566348B2 JP22531894A JP22531894A JP3566348B2 JP 3566348 B2 JP3566348 B2 JP 3566348B2 JP 22531894 A JP22531894 A JP 22531894A JP 22531894 A JP22531894 A JP 22531894A JP 3566348 B2 JP3566348 B2 JP 3566348B2
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resin material
waste
crushing
processed
agricultural film
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JPH08169015A (en
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貞夫 西堀
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アイン・エンジニアリング株式会社
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Priority to JP22531894A priority Critical patent/JP3566348B2/en
Priority to TW84107974A priority patent/TW297794B/zh
Priority to KR1019950026396A priority patent/KR100324034B1/en
Priority to GB9603293A priority patent/GB2310213B/en
Priority claimed from AU45618/96A external-priority patent/AU713358B2/en
Priority to US08/606,318 priority patent/US5738286A/en
Priority to NL1002520A priority patent/NL1002520C2/en
Priority to PT101842A priority patent/PT101842B/en
Priority to DE1996108703 priority patent/DE19608703A1/en
Priority to FR9603068A priority patent/FR2745730B1/en
Priority to BE9600247A priority patent/BE1010083A3/en
Publication of JPH08169015A publication Critical patent/JPH08169015A/en
Publication of JP3566348B2 publication Critical patent/JP3566348B2/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02Separating plastics from other materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C13/00Disintegrating by mills having rotary beater elements ; Hammer mills
    • B02C13/22Disintegrating by mills having rotary beater elements ; Hammer mills with intermeshing pins ; Pin Disk Mills
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C18/00Disintegrating by knives or other cutting or tearing members which chop material into fragments
    • B02C18/06Disintegrating by knives or other cutting or tearing members which chop material into fragments with rotating knives
    • B02C18/14Disintegrating by knives or other cutting or tearing members which chop material into fragments with rotating knives within horizontal containers
    • B02C18/148Disintegrating by knives or other cutting or tearing members which chop material into fragments with rotating knives within horizontal containers specially adapted for disintegrating plastics, e.g. cinematographic films
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B07SEPARATING SOLIDS FROM SOLIDS; SORTING
    • B07BSEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
    • B07B7/00Selective separation of solid materials carried by, or dispersed in, gas currents
    • B07B7/06Selective separation of solid materials carried by, or dispersed in, gas currents by impingement against sieves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/04Disintegrating plastics, e.g. by milling
    • B29B17/0412Disintegrating plastics, e.g. by milling to large particles, e.g. beads, granules, flakes, slices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02Separating plastics from other materials
    • B29B2017/0213Specific separating techniques
    • B29B2017/0217Mechanical separating techniques; devices therefor
    • B29B2017/0224Screens, sieves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02Separating plastics from other materials
    • B29B2017/0213Specific separating techniques
    • B29B2017/0268Separation of metals
    • B29B2017/0272Magnetic separation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/04Polymers of ethylene
    • B29K2023/06PE, i.e. polyethylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/10Polymers of propylene
    • B29K2023/12PP, i.e. polypropylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2027/00Use of polyvinylhalogenides or derivatives thereof as moulding material
    • B29K2027/06PVC, i.e. polyvinylchloride
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2069/00Use of PC, i.e. polycarbonates or derivatives thereof, as moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/065Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts containing impurities
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2705/00Use of metals, their alloys or their compounds, for preformed parts, e.g. for inserts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2709/00Use of inorganic materials not provided for in groups B29K2703/00 - B29K2707/00, for preformed parts, e.g. for inserts
    • B29K2709/08Glass
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2007/00Flat articles, e.g. films or sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2007/00Flat articles, e.g. films or sheets
    • B29L2007/002Panels; Plates; Sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2007/00Flat articles, e.g. films or sheets
    • B29L2007/008Wide strips, e.g. films, webs
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/52Mechanical processing of waste for the recovery of materials, e.g. crushing, shredding, separation or disassembly
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S241/00Solid material comminution or disintegration
    • Y10S241/38Solid waste disposal

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  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Dry Formation Of Fiberboard And The Like (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Processing Of Solid Wastes (AREA)

Description

【0001】
【産業上の利用分野】
本発明は、廃棄樹脂成形品の回収・造粒方法及び装置並びに前記回収樹脂材料を用いた木質合成板の製造方法に関するものである。
【0002】
詳しくは、本発明の適用分野として、農業などで使用済みのプラスチックフィルム廃棄物、例えばポリ塩化ビニル、ポリエチレン、ポリ酢酸ビニル、ポリオレフィンなど所謂施設園芸、農業におけるビニールハウスやその他の栽培用の農産物の種子や苗などの被蓋に使用され、また、他の用途に使用され廃棄された使用済のフィルムあるいはシートを形成する熱可塑性樹脂製のフィルムもしくはシート(本明細書において、「廃農フィルム」という)を処理対象にして、この廃棄樹脂成形品を粗砕もしくは広義において破砕して複数の被処理小片化した上で、各被処理小片のフィルムやシートに付着した雨水、露、農薬、泥、土、砂、草の根、金属、農産物(葉、茎等)、ガラスの破片、ゴミ等の付着物を分離かつ除去し、素材化された樹脂材料として回収し、且つ造粒する方法。併せて、この素材化された樹脂材料を整粒して所定粒径範囲内の整粒物としての素材化された整粒樹脂材料として回収・造粒することにより、該回収・造粒され素材化された樹脂材料をそのまま成形し、あるいはペレットに成形加工して再利用を図り得るようにした方法およびこれらの方法を実施する装置並びに前記回収樹脂材料を用いた木質合成板の製造方法に係るものである。
【0003】
【従来の技術】
従来この種廃棄樹脂成形品である廃農フィルムを形成するポリ塩化ビニル(軟質PVC)、ポリエチレン等のフィルム或いはポリカーボネイト(PC)等の樹脂でなるシートは、使用による経年劣化あるいは暴風雨により枠体から脱落するなどして、農薬、泥、土、砂、金属、農産物(葉、茎等)、ガラスの破片、ゴミ等の付着物が付着し透明度を無くすため順次交換されており、これら交換もしくは廃棄するために収集された廃農フィルムは、付着物を水洗浄した後、乾燥し、微粉砕して、ブロー成形などで、木杭の代替品などとして成形され再利用されていた。
【0004】
また、前記廃農フィルムは、それぞれに耐水性、耐候性に優れ、腐敗し難いなどの特長を有する反面、例えば、廃棄処分のための焼却炉による焼却に際しては、多量の有害ガスとか排煙などを発生して社会環境上、好ましくないことがよく知られている。加えて、焼却時に溶融された樹脂材料が炉内に付着して該炉自体を損傷するおそれがあるなどの不利を有している。そこで、この不利を避けるために樹脂成形品を地中に埋設処理したとしても、長期間に亘って腐敗せずに残存することから、環境破壊の一因になるものとされている。
【0005】
一方、この種の樹脂資材に関しては、資源的にも年々枯渇化の傾向にあり、使用後の樹脂材料を廃棄せずに再利用することが要請かつ認識されている。
【0006】
【発明が解決しようとする課題】
従来、廃農フィルムは、表面の付着物を水洗浄して再生処理されていたが、この処理には大量の水を必要とする洗浄工程と乾燥工程が必須であるので、前記水洗浄処理及び乾燥処理に多大な設備を要し、水資源及びエネルギー資源を浪費するという問題点があった。
【0007】
特に、前記廃農フィルムには農薬が付着している場合が通常であるが、このフィルムやシートを水洗いして洗浄しても農薬を含んでいる洗浄液は河川等を汚染するため浄化処理しなければ排水できず、浄化処理の設備及び運転費は高価となり、そのため殆どの廃農フィルムは、再利用されることなく廃棄処分されていた。
【0008】
〔目的〕
本発明は叙上の問題点を解決するために開発されたもので、比較的簡単かつ容易な手段により、処理対象の樹脂成形品としての廃農フィルムから、農薬、泥、土、砂、金属、農産物(葉、茎等)、ガラスの破片、ゴミ等の付着物を分離かつ除去し、かつこれを所定の粒径範囲内に整粒され素材化された樹脂材料として効率良く・造粒し、再利用し得るようにした回収・造粒方法および装置並びに前記回収樹脂材料を用いた木質合成板の製造方法を提供することを目的とする。
【0009】
【課題を解決するための手段】
上記目的を達成するために、本発明の廃棄樹脂成形品の回収・造粒方法においては、廃棄樹脂成形品から付着物を分離し、樹脂材料を回収する方法であって、廃農フィルムを、処理対象とし、この廃農フィルムを複数の各被処理小片に粗砕する工程と、
前記粗砕された個々の被処理小片に対して衝撃摩砕力を付加し、前記被処理小片に付着する付着物を微粉砕して樹脂材料と付着物とに分離すると共に樹脂材料を整粒し素材化された回収樹脂材料とする工程とを少なくとも含む方法であり、
また、前記粗砕工程に先立ち、
上記廃農フィルムを複数の破砕片に破砕する工程を少なくとも含む方法である。 前記粗砕された個々の被処理小片に対して衝撃摩砕力を付加し、前記被処理小片に付着する付着物を微粉砕して樹脂材料と付着物とに分離すると共に樹脂材料を整粒し素材化された回収樹脂材料とする工程を複数回にわたり反復することができる。
【0010】
本発明の廃棄樹脂成形品の回収・造粒装置においては、
上記廃農フィルムを複数の各被処理小片に粗砕する粗砕手段と、
前記被処理小片の供給投入口部に中心部を連通した固定円盤上にあって、複数の回転軌跡上で各固定ピンを順次に植設した固定側分離・分級・整粒手段と、
前記固定円盤に対向して回転駆動可能に設けた可動円盤上にあって、前記各固定ピンとは異なる複数の回転軌跡上で各可動ピンを順次に植設した可動側分離・分級・整粒手段と、
前記各固定ピンと各可動ピンとの組み合せ外周部にあって、所望粒度以下に分離された付着物を任意に排出するための排出口に連通した分級手段、および所望粒度以上の回収樹脂材料を取出し口に取出す取出し手段とを備え、
前記各固定ピンと各可動ピンとの相互間で衝撃摩砕力により、樹脂材料と付着物を分離・分級し、前記樹脂材料を整粒し得るように構成した分離・分級・整粒手段とから成ることを特徴とする。さらに、
上記構成に加え、
処理対象である廃農フィルムを最初に複数の破砕片に破砕する破砕手段を付加したものである。
【0011】
前記取出し口部に取出される被処理小片を、前記供給投入口部に還流させるように、前記取出し口部と前記供給投入口部を連通することができる。
【0012】
さらに、本発明の前記回収樹脂材料を用いた木質合成板の製造方法においては、
回収樹脂材料25〜80wt%に対して、含有水分量を15wt%以内とし平均粒径20メッシュ以下、好ましくは、60〜150メッシュのセルロース系破砕物20〜75wt%を混合し、加熱、練成し、スクリューをもって成形ダイへ押出し、この押出し生地を、内壁面にフッ素樹脂のシートを貼設又はフッ素樹脂をコーティングした成形ダイの成形部へ押出して所定の肉厚に成形し且つ前記成形部で徐冷して押出し成形すると共に、この成形板の押出し力に抗する抑制力を加えて前記成形部内の押出し生地の密度を高くしたことを特徴とする。前記配合例は、好ましくは、
前記回収樹脂材料25〜80wt%に対して、含有水分量を15wt%以内とし平均粒径20メッシュ以下のセルロース系破砕物20〜75wt%を可塑材を添加せずに、混合し、加熱、練成することができる。また、
前記回収樹脂材料を20〜40wt%、好ましくは25〜30wt%の軟質塩化ビニルとし、バージンの硬質塩化ビニル10〜30wt%、好ましくは15〜20wt%、含有水分量を15wt%以内、好ましくは、3〜5wt%とし平均粒径80メッシュ以下の木粉40〜60wt%、好ましくは、45〜50wt%を混合することができる。
【0013】
さらに、前記回収樹脂材料が、ポリエチレンから成り含有水分量を15wt%以内、好ましくは、3〜5wt%とし平均粒径150メッシュ以下の木粉40〜60wt%好ましくは45〜50wt%に対し、ポリエチレンを10〜60wt%、好ましくは45〜50wt%混合したものとすることができる。
【0014】
【作用】
廃農フィルムは破砕手段により複数の破砕片に破砕され、前記破砕された破砕片、あるいは、廃農フィルムが直接粗砕手段により、複数の各被処理小片に粗砕され、ついで、これら複数の各被処理小片を1回又は複数回にわたり分離・分級・整粒手段の供給投入口部から供給させることにより、各固定ピンと各可動ピンとの相互間で、衝撃摩砕力により樹脂材料を粉砕・造粒して研磨かつ整粒すると共に、所望粒度以下の付着物を分離し、任意に区分けして排出口に排出でき、かつ所望粒度以上の回収樹脂材料を取出し口から取出し得る。
【0015】
回収樹脂材料25〜80wt%に対して、含有水分量を15wt%以内とし平均粒径20メッシュ以下のセルロース系破砕物20〜75wt%は押出機で加熱、混練されスクリューで吐出口から押出し生地となって成形ダイの導入部へ押出される。
【0016】
まず、押出し生地は導入部で加熱保温されて流動性を維持され良好な混練状態を保ちながら成形部の成形室内へ押出される。成形室の内壁面は摩擦係数が小さいフッ素樹脂のシートを貼設又はフッ素樹脂をコーティングされているので、この内壁面を通過する押出し生地内のセルロース系破砕物は大きな抵抗を受けることなく円滑に流動するので、比較的低温で、均一で高密度の混練状態を保ちながら押出される。この成形室内を押出される過程で押出し生地が冷却され成形板が成形される。フッ素樹脂は金属に比べ熱伝導係数が低いので、押出し生地は徐冷され、冷却による歪みが少なくなり、歪みの少ない均一で高密度の製品としての成形板である木質合成板が成形される。
【0017】
さらに、押出機により加えられる成形板への押出し力に、ブレーキ手段により抑制力を加え、この成形板を介して成形室内の押出し生地に対して前記押出し力に対する抗力を加える。例えば、成形板の表裏面を挟持して圧接する一対を成すピンチローラの一方の軸端に設けたブレーキドラムに摩擦体を圧接することにより、このブレーキドラムの回転を抑制し、成形板の押出し力により回転するピンチローラの回転が抑制され、このピンチローラは成形板にその押出し力に抗する抑制力を加える。
【0018】
すると、前記抑制力は成形板を介して成形部及び導入部内の押出し生地に、押出機により加えられる成形室内の押出し生地の押出し力に対して抗力を与えることにより、成形室内の押出し生地の全体がより一層密度が均一で高密度になる。したがって、廃農フィルムによって多量のセルロース系破砕物を含んだより一層均一高密度な木質合成板が成形される。
【0019】
【実施例】
実施例について図面を参照して説明する。
【0020】
樹脂材料の処理方法及び装置の実施例
(対象廃棄樹脂成形品)
対象廃棄樹脂成形品としてはポリ塩化ビニル(PVC;軟質)などで成る使用済の廃農フィルムであり、この廃農フィルムの表面には農薬、泥、土、砂、金属、農産物(葉や茎等)、ガラスの破片、ゴミ等の付着物が付着している。この使用済の廃農フィルムは、廃棄あるいは、業者により収集される際、ロール状に巻かれたものもあり得るが、殆どはグシャグシャに丸めた大きな塊状となっている。
【0021】
以下、この廃農フィルム塊状物から軟質PVCなど樹脂材料を回収する手段について説明する。
【0022】
処理方法
図1に示すように、〔破砕工程〕、〔粗砕工程〕、〔分離、分級、整粒工程〕から成る。
【0023】
工程1〔破砕工程〕
廃棄された農業用ビニールハウスの軟質PVCフィルムを、図1に示すような破砕手段110を用いて適当な大きさの断片に切断、もしくは広義に破砕し、例えば15×50mm程度の大きさの破砕片81を形成する。
【0024】
〔破砕手段〕
破砕手段は被破砕物を破砕して適当な大きさの破砕片を形成するもので、本実施例において、便宜上「クラッシャ」という。
【0025】
図1に「クラッシャ」の一例を示す。クラッシャ110は、上部に被破砕物の投入口を有するクラッシャ本体内に互いに内向きに回転する2軸を平行に設け、各軸に複数枚の回転刃を所定間隔に設けると共に、各軸の各回転刃外周で互いに噛み合って且つ各回転刃の外周面に等角度を成すよう突設した3個の爪刃で収集した廃農フィルムの塊を適宜大の断片からなる破砕片に切断するように設けられている。
【0026】
上部の投入口から投入された廃棄樹脂成形品である農業用ビニールハウスの軟質PVCフィルムから成る廃農フィルムの塊は、互いに内向きに回転する2軸の回転刃の爪刃により内部に引き込まれ、噛み合った状態で回転する回転刃の外周エッジ間に、連続的に作用する剪断力でスリットしながら引き込みのときに作用する圧縮力によって破砕され切断され、破砕片81が形成される。この破砕片81は前記2軸の回転刃の下方に設けた排出口から排出される。この時点では各破砕片81の表面には、前述した農薬や泥等の付着物が付着し、略黒色を呈している。
【0027】
なお、破砕手段は、上記のクラッシャに限定されず、例えば、(株)ホーライ社製のガイナックスクラッシャ、又は(株)奈良機械製作所製のロールクラッシャ等、種々のモノカッタ、シュレッダー、クラッシャ等の破砕手段を用いることができる。
【0028】
工程2〔粗砕工程〕
前述した工程1〔破砕工程〕における破砕手段で、15×50mm程度の大きさに形成された破砕片81を、図1に示すような粗砕手段を用いて、さらに細かく切断、もしくは広義には破砕して、例えば2×15mm程度の長方形あるいは10×10mm程度の正方形ないしその他不定形であるが、一辺が10mm程度以下の大きさの被処理小片82を形成する。この時点においても前述した工程1〔破砕工程〕と同様、各被処理小片82の表面には前述した農薬や泥等の付着物が付着している。
【0029】
〔粗砕手段〕
粗砕手段は破砕片81を切断、粗砕して適当な大きさの被処理小片82を形成するもので、本実施例において、便宜上「カッタミル」という。
【0030】
図2に粗砕手段の一例であるカッタミル120を示す。
【0031】
121はカッタミル本体で、上面開口を有する円筒形を成すケーシングであり、前記開口を開閉自在な蓋122で被蓋する。前記蓋122はカッタミル本体121内に被粗砕物である破砕片81を投入する投入口123を備えている。
【0032】
また、前記カッタミル本体121内にはカッタミル本体121の底面に軸承されて図示せざる回転駆動手段で水平方向に回転するカッタ支持体124を設け、このカッタ支持体124の外周に上下方向に長い回転刃125を3枚設け、これらの3枚の回転刃125はカッタ支持体124の回転方向で120度の等角度を成すように配設し、3枚の回転刃125の刃先は同一の回転軌跡上に位置している。さらに、前記3枚の回転刃125の刃先の回転軌跡に対して僅かな隙間を介して二の固定刃126を回転刃125の刃先の回転軌跡の略対称位置にカッタミル本体121に固定し、二の固定刃126とカッタ支持体124と回転刃125とでカッタミル本体121内を二分し、投入室127と粗砕室128を形成する。前記蓋122の投入口123は前記投入室127に連通する。なお、二の固定刃126と回転刃125とのクリアランスは被粗砕物を所望の大きさに切断、もしくは広義には破砕できるよう自在に調整できる。本実施例のクリアランスは0.2〜0.3mmmである。また、粗砕室128は前記二の固定刃126間を回転刃125の回転軌跡の周囲を囲むようにメッシュのスクリーン129で仕切っている。なお、スクリーン129は、本実施例では一辺が10mm程度の大きさの被処理小片82が通過できるメッシュで形成している。また、粗砕室128のカッタミル本体121の下端には前記被処理小片82を排出する排出口を設けている。
【0033】
以上のカッタミル120において、蓋122の投入口123から前述した工程1〔破砕工程〕のクラッシャ110で形成した15×50mm程度の大きさの破砕片81を投入し、図示せざる回転駆動手段でカッタ支持体124を回転すると、破砕片81はカッタ支持体124の回転刃125と固定刃126間でスクリーン129を経て形状、面積は、不定であるが、略全量が、2×15mm程度の長方形あるいは10×10mm程度以下の方形ないし不定形で、一辺が10mm程度以下の大きさの被処理小片82に形成され前記排出口から次工程へ排出される。
【0034】
なお、粗砕手段は、上記のカッタミルに限定されず、例えば、(株)ホーライ社製のハードクラッシャのように、回転刃125の回転軸は水平方向に設けられ、二の固定刃126間のスクリーン129は下方に設けられているものもある。この時点では各粗砕片81の表面には、前述した農薬や泥等の付着物がやや脱落するが、略不透明の薄い黒色を呈している。
【0035】
工程3〔分離、分級、整粒工程〕
前述した工程2〔粗砕工程〕における粗砕手段で、一辺が10mm程度以下の長方形ないしは不定形の大きさに形成され、農薬、泥、土、砂、金属、農産物(葉や茎等)、ガラスの破片、ゴミ等が表面に付着している軟質PVCのフィルムの各被処理小片82に衝撃摩砕力を付加して、一辺が1〜2mm以下の長方形ないしは不定形の大きさに粉砕し、前記各被処理小片82から樹脂材料を直径1mmで長さ10mm程度の大きさ、あるいは一辺が2〜5mm程度の長方形ないしは円筒状に丸められた形状その他不定形の大きさに造粒、研磨、整粒する。同時に、各被処理小片82の表面から付着物を前記衝撃摩砕力により微粉砕して分離し、且つ、前記粉砕された付着物と軟質PVCとを分級し、廃農フィルムから軟質PVC等の樹脂を樹脂材料として回収する。
【0036】
上記工程は、必要に応じて任意回数反復して行うことができる。
【0037】
〔分離・分級・整粒手段〕
分離・分級・整粒手段は前述したように、廃棄樹脂成形品の軟質PVCフィルムの被処理小片82を粉砕・研磨・整粒すると共に、前記フィルムの整粒物に対して前記フィルムの表面の付着物をより細かく粉砕して前記付着物をフィルムから分離・分級し、被処理小片82から樹脂材料を造粒ないし整粒する手段で、本実施例において、便宜上「ピンミル」という。
【0038】
図3および図4において、ピンミル130は、固定円盤131の中心部に各被処理小片82を投入する供給投入口132を連通開口させ、前記固定円盤131に固定端板133を研磨・整粒空間155を隔てゝ対向させ、前記固定円盤131に固定端板133のそれぞれの外周端縁を周側板135で固定する。前記研磨・整粒空間155内には回転横軸142によって回転駆動される可動円盤141を設け、回転横軸142は各軸受143,143によって枢支されている。前記回転横軸142は、図示せざるモータ等の回転駆動手段により回転駆動される。
【0039】
そして、前記固定円盤131上には、複数の同心円上の(可動円板141に対する相対的な)回転軌跡a(図4)上で各固定ピン134を順次に植設され、一方、前記可動円盤141上には、前記各固定ピン134とは異なる複数の回転軌跡b上で交互に入り込む可動ピン144を順次に植設して、これらの固定、可動の各ピン134,144の相互間で衝撃摩砕力により粉砕あるいは研磨、整粒作用を得られるように位置する。さらに、可動円盤141の外周側で前記周側板135との間には、排出空間156を隔てゝ所望径の細孔をパンチング形成した所定メッシュのスクリーン151を周設させ、排出空間156の下方に排出口152を設ける。なお、前記排出口152に図1に示すようにピンミル130にブロワー157を連通する。なお、本実施例では前記スクリーン151は直径1mmのメッシュであるが、通常直径1mm以下、好ましくは直径0.7mmのメッシュである。
【0040】
また、研磨・整粒空間155のスクリーン151内の下部に取出口153を設け、取出口153に開閉制御のためのプラグバルブ154を配設する。なお、前記取出口153に図1に示すようにピンミル130内のエアーを吸引するブロワー158を連通し、このブロワー158を介して供給投入口132へ連通している。
【0041】
従って、上記のピンミル130では、図示せざる回転駆動手段により回転横軸142を回転して可動円盤141を回転し、各被処理小片82を供給投入口132に供給すると、各被処理小片82は、研磨・整粒空間155の中心部にあって、固定、可動の各ピン134,144の相互間で衝撃摩砕力により粉砕あるいは研磨、整粒作用と遠心作用とを合わせて受けることになり、衝撃摩砕力を受けて、次第に粉砕あるいは研磨、整粒されながら外周側に接近する。この過程において各被処理小片82の軟質PVCフィルムの表面に付着している農薬、泥、土、砂、金属、農産物(葉や茎等)、ガラスの破片、ゴミ等の付着物は一辺が1mm以下の不定形に細かく粉砕され、一方、樹脂材料たる軟質PVCフィルムは直径1mmで長さ10mm程度の大きさ、あるいは一辺が2〜5mm程度の長方形ないしは円筒形その他の不定形に研磨、整粒されて回収樹脂材料が形成される。この間被処理小片82中樹脂材料の一部は一辺が1mm以下の長方形ないしは不定形の大きさに微粉砕された微粉になるものもある。
【0042】
粉砕された付着物及び被処理小片82中の軟質PVCフィルムの一部は、各可動ピン144の遠心作用によりスクリーン151を通過して、排出空間156内に分級された後、排出口152からブロワー157を経て外部へ吸引、排出される。この廃棄付着物は、後述成形時に回収樹脂材料に混合してもよい。
【0043】
一方、研磨、整粒された軟質PVCフィルムの整粒樹脂材料及びスクリーン151を通過しない大きさの付着物は、スクリーン151内に留まるが、プラグバルブ154を開放した状態で、取出口153と供給投入口132とをブロアー158を介して連通しているので、取出口153から取出される整粒樹脂材料及びスクリーン151を通過しない大きさの付着物は供給投入口132に還流され、前記硝子、金属などの付着物はスクリーン151を通過可能に微粉砕され、前述したように排出口152から外部へ排出される。しかし、軟質PVCフィルムの整粒樹脂材料は還流されるとはいえ、スクリーン151を通過するほどには細かく研磨、整粒されないで大部分がスクリーン151内に残される。
【0044】
この整粒された回収樹脂材料はプラグバルブ154を開けて取出口153から回収樹脂材料として取りだされる。この手段としては、取出口153から回収樹脂材料を掻きだすことができ、あるいは前記ブロワー158と供給投入口132への連通管を分岐して取出口を有する分岐管を設け、この分岐管の取出口を開閉する電磁弁と前記連通管の下流側を開閉する電磁弁を設け、これらの二の電磁弁を交互に開閉するように設け、あるいは、両分岐管に三方電磁弁を設け、前記連通管の下流側を電磁弁で閉塞し且つ前記分岐管の取出口を開放し、さらには前記排出口152も閉塞し、ブロワー158によりスクリーン151内に残された整粒樹脂材料を吸引し分岐管の取出口から回収することもできる。この場合、前記廃棄付着物及び付着物と同程度に微粉砕された一部の軟質PVCフィルム粉を外部へ排出した後に行なう。
【0045】
回収樹脂材料は、略透明若しくは半透明の無色もしくは、薄い白色を呈していた。
なお、上記ブロワー158とは代替的に、もしくはこれと共に、前記ピンミル130の研磨・整粒空間155内に、圧縮空気を送り込み、固定端板133に穿設した孔部よりパイプを介して連通する供給投入口部へ前記スクリーン151を通過できない大きさの付着物を還流させてもよい。
【0046】
一例として、前述した構造のピンミル130の実験機を用いて、このピンミル130に600gの各被処理小片82を投入し、前記可動円盤141を40Hz,1900rpmの回転速度で回転すると、2分間で各被処理小片82の全重量の約90wt%を直径若しくは、幅1.2mm以下、長さ3〜7mm程度の略円筒形に丸められ、又は方形のものがやや捻転した不定形の樹脂材料として回収され、残りの約10wt%は前記付着物の粉砕屑及び樹脂材料たる軟質PVCフィルムの粉砕粉であった。このように廃棄樹脂成形品から多量の整粒された樹脂材料を短時間で回収できた。なお、このピンミル130の処理能力を向上させるにはピンミル130を大型にすれば良い。
【0047】
また、前記可動円盤141の回転速度は低速にした方が、各被処理小片82の廃棄樹脂成形品の主成分樹脂である軟質PVCフィルムは細かく研磨、整粒されず、一方、各被処理小片82の表面に付着している農薬、泥、土、砂、金属、農産物(葉や茎等)、ガラスの破片、ゴミ等の付着物は取出口153からブロワー158を経て供給投入口132へ還流され、再び衝撃摩砕力により粉砕、研磨作用を受けてさらに微粉砕されるので、廃農フィルムの樹脂材料である軟質PVCフィルム等をスクリーン151のメッシュ以上の大きさに研磨、整粒できる範囲内で可能な限り低速にした方がよく、例えば可動円盤141の回転速度を1200rpmにすることができる。
【0048】
尚、上述実施例においては、PVCフィルムを主な例として説明したが、他の樹脂材料、ポリエチレン、ポリカーボネイト等の場合も同様にして整粒樹脂材料として回収することができる。
【0049】
なお、上記の樹脂材料の処理方法以外に、収集された廃農フィルムの状態、例えば、ロール状に巻かれているか、汚染の状況がどの程度かに応じて上記の各工程1,2のうち、各工程の順序を逆にし、あるいは、工程1を省略して樹脂材料を回収することができる。
【0050】
成形工程
本発明で得られた回収樹脂材料は、押出機等の成形機へ直接投入して他の成形品に成形することも、成形用樹脂素材の形態であるペレットに成形することもでき、あるいは回収樹脂材料と同質のバージンの樹脂材料とを混練し、例えば軟質PVCの場合はバージンの硬質PVCを混練してペレットを形成することも、他の成形品に成形することもでき、さらには木質合成板の原料とすることもできる。
【0051】
以下に本発明の回収樹脂材料を用いて木質合成板を製造する手段について説明する。
【0052】
各原料の混入容量は、目的とする耐摩耗特性などの諸特性に合わせて適宜決定されるものであるが、本発明においては、前述の成形時における種々の弊害が除去されることから多量に混入することができる。
【0053】
PETの場合は、木粉は最大で60wt%まで混入されるが、木粉の混入割合は20〜55wt%が良い。
【0054】
回収樹脂材料がPVCのとき、木粉の混入割合は30〜60wt%、好ましくは45〜55wt%である。
【0055】
一例として、前記軟質のPVCである回収樹脂材料30wt%にバージンの硬質塩化ビニルペレット19wt%そして、含有水分量を5wt%以内とし平均粒径80メッシュ以下の木粉51wt%を混入しスクリューをもって成形ダイへ押出した押出し生地を徐冷し、且つ、この押出し生地に押出し力に抗する抑制力を加えて木粉類をベースとした成形樹脂製品たる木質合成板を押出機を用いて成形する。
【0056】
硬質PVCを添加するのは、所望の硬度を得るためであり、回収樹脂材料は、可塑剤に代替され、本願発明方法によれば、可塑剤を省略できる。
【0057】
また、樹脂材料が、ポリエチレンから成る廃農フィルムの場合には、含有水分量を5wt%以内とし平均粒径150メッシュ以下の、木粉51wt%に対し、回収樹脂材料たるポリエチレンを49wt%を混入し、スクリューをもって成形ダイへ押出した押出し生地を徐冷し、且つ、この押出し生地に押出し力に抗する抑制力を加えて同様に、木質合成板を成形することができる。
【0058】
この場合、バージンのポリエチレン及び可塑材の添加は、不要である。
【0059】
以下、木質合成板の製造実施例を示す。
図5において、70は単軸押出機であるが、一般に押出機は通常スクリュー形であり、単軸押出機と多軸押出機があり、この変形又はこれらが組み合わせた構造を持つものがあり、本発明にはいずれの押出機をも使用することができる。
【0060】
図5において、71はスクリューで、単軸型であり、このスクリュー71はギヤ減速機72を介して図示せざるモータによって駆動され、バレル74内で回転する。この回転するスクリュー71でホッパ73から投入されたセルロース系破砕物と回収樹脂材料が混練されながらスクリュー71の前方へ押出される。バレル74の外面にはバンドヒータ75を設けており、このバンドヒータ75によりバレル74内のセルロース系破砕物と樹脂が加熱されスクリュー71の溝に沿って前方へ移送されながら漸次溶融しセルロース系破砕物と樹脂が練成される。そしてスクリーン76及びアダプタ77を経てアダプタ77の押出ダイ78から成形ダイ10へ押出し生地79として押出される。
【0061】
ホッパ73内に投入する原材料はセルロース系破砕物と回収樹脂材料であり、特に木粉の粒径を回収樹脂材料とのなじみを良好とし、成形押し出し時における木粉の摩擦抵抗を減じ成形機の損耗、毀損の防止を図ることより、20〜300メッシュ、好ましくは、20(篩下)〜150メッシュ(篩上)とする微細な粉末状とし、成形時における木酸ガスを揮散し、水蒸気あるいは気泡発生のおそれをなくし、表面の肌荒れを防止する意図からその含有水分量を15wt%以内、好ましくは11wt%以内、理想的には3〜5wt%の範囲内としたものである。
【0062】
図6において、10は成形ダイで、いわゆるTダイ式の成形ダイに類似の形状を成しており、押出機70の断面方形の押出ダイ78から吐出された押出し生地79を加熱保温して押出し生地79の流動性を維持しながら押出す導入部11と、導入部11から押出された押出し生地79を幅広で所定の肉厚の板状に成形する成形室22を有する成形部21から成る。
【0063】
前記導入部11は、導入孔12および導入室13を備え、直径約65mmの断面円形を成す押出ダイ78から幅910mm、高さ12mmの細長の矩形状の断面を成す成形室22の入口へと急激に断面変形している。そして押出ダイ78から成形室22の入口までの距離(導入部11の押出し方向の距離)は約200mmである。
【0064】
12は導入孔で、成形ダイ10内に成形ダイ10の幅方向に形成され、縦断面を図5に示すように断面楕円形に膨出形成され、前記押出ダイ78とほぼ同等もしくは若干大きく形成し、横断面の形状は図6に示すように成形ダイ10の幅方向に湾曲しており、その両端が成形室22の入口の矩形状の断面の長手方向の両端に及んで、いわゆるコート・ハンガー型に形成されており、この導入孔12の長手方向の略中央位置で押出機70の押出ダイ78に連通している。また、前記導入孔12から成形室22の入口までの間は、縦断面が徐々に狭くなる方向に断面三角形を成す導入室13で連通している。
【0065】
14はヒータで、電熱ヒータ等の加熱手段で前記導入孔12と導入室13の周壁外周に設けてもよいが、実施例では、加熱効果に優れているという点で、前記周壁内に設けられ、導入孔12及び導入室13内を流動する押出し生地79を加熱保温し、押出し生地79の流動性を維持する。
【0066】
成形ダイ10の幅方向の縦断面で幅910mm、高さ12mmの細長の矩形状の断面を成し、成形室22の入口からダイ出口23までの距離(成形部21の押出し方向の距離)は500mmである。
【0067】
前記成形室22の上下左右の四方の内壁面は厚さ0.25mmのフッ素樹脂でなるシート24を貼設している。この他に、成形室22の上下左右の四方の内壁面にフッ素樹脂を直接表面コーティングすることもできるが、交換が容易でありフッ素樹脂のコーティング加工が容易で耐久性に富むという点で、フッ素樹脂のシート24を貼設することが特に好ましい。
【0068】
また、25は冷却管で、成形ダイ10の成形部11を冷却する冷却手段の一例を示すもので、成形室22の上下の成形ダイ10内に成形部21の押出し方向に適当な間隔毎に挿通して配管し、この冷却管25に常温の水又は70〜80℃程度までの水あるいは油等の冷却媒体たる冷却液を供給して成形室22内の押出し生地79を冷却する。
【0069】
15は案内板で、図7に示すように、平面で短辺約200mm、長辺約850mm、高さ約100mmの左右対称の台形形状を成す厚さ7mmの板であり、この案内板15の全外表面に0.1〜0.5mm厚のテフロン等のフッ素樹脂でなるシートを貼設したものである。なお、案内板15の外表面にフッ素樹脂を直接コーティングしても良く、フッ素樹脂のシートを貼設又はフッ素樹脂をコーティングする方法は、前述した成形ダイ10の成形室22内に設けたシート24と同様である。この案内板15を高さ12mm、幅900mmを成す前記導入孔12a内に、該導入孔12aの幅方向で両端に25mmづつの間隔を有するよう略中央に位置させ、さらに案内板15の後端縁を導入孔12aの後端壁面に略平行間隔を有するように位置させ、この案内板15を成形ダイ10aに4個のボルト27で導入孔12aの下面に固定する。したがって案内板15の上面と導入孔12aの上面との間に5mmの隙間が形成される。
【0070】
なお、案内板15は、その板厚を導入孔12aの高さに応じて導入孔12aの高さの70%以下の寸法に形成し、案内板15の幅は導入孔12aの幅の約70〜95%の長さを有するよう形成することが好ましい。
【0071】
また、案内板15は、案内板15の上下面に導入孔12aの上下面と同程度の隙間を設けるよう導入孔12aの高さ方向の略中央に位置させることもできる。本実施例の案内板15を導入孔12aの高さ方向の略中央に位置させるとすれば、高さ方向で上下に2.5mmづつの隙間を成すよう導入孔12aの高さ方向の略中央に位置させ、この案内板15を成形ダイ10aに4個の段付きピンで螺着、固定する。
【0072】
押出し生地79は導入部11で加熱保温されて流動性を維持され良好な混練状態を保ちながら、案内板15を設けた場合には、該案内板により導入部11内で、原料によっては、押出し生地79が押し出し方向で、中央部と端部で異なる線膨張をして分子配向を異にすることを防ぎ、線膨張の均質化を図り、分子配向を制御して、成形部21の成形室22内へ均等に拡散され、均一な密度で押出される。成形室22の内壁面は摩擦係数が小さいフッ素樹脂のシート24を貼設又はフッ素樹脂をコーティングされているので、この内壁面を通過する押出し生地79内のセルロース系破砕物は大きな抵抗を受けることなく円滑に流動するので、比較的低温で、均一で高密度の混練状態を保ちながら押出される。この成形室22内を押出される過程で押出し生地79が常温ないし60℃から90℃の水または油などの冷却媒体により徐冷・冷却され成形板29が成形される。フッ素樹脂は金属に比べ熱伝導係数が低いので、押出し生地79は徐冷され、冷却による歪みが少なくなり、歪みの少ない均一で高密度の製品としての成形板29である木質合成板が成形される。
【0073】
図8及び図9において、3本の自在ピンチローラ31bの軸の両端を軸承する軸受34aをそれぞれ、軸受固定フレーム36に固定し、固定ピンチローラ31aを各軸に設けた歯車116と、この歯車116に噛合する歯車117で連動し、3本の固定ピンチローラ31aのうち1本の固定ピンチローラ31aの軸にパウダブレーキ115の入力軸を連結する。パウダブレーキ115は、いわゆる電磁ブレーキであり、摩擦トルクを電気的に微妙に調整できるものである。
【0074】
さらに、軸受固定フレーム36にフレーム114を立設し、このフレーム114の壁面にガイド溝を備えたブロック状のガイド体1192本をそれぞれ、該ガイド体119の軸線方向を上下方向に向けて略平行に設け、各3本の自在ピンチローラ31bの軸の両端を軸承する軸受34bを前記ガイド体119のガイド溝に沿って上下動自在に設け、前記軸受34bをそれぞれ、フレーム114の上面に設けた3本のエアシリンダ118のロッドの先端に連結する。
【0075】
したがって、シリンダ118の作動により、3本の自在ピンチローラ31bをそれぞれ、成形板29を介して固定ピンチローラ31aに加圧し、3本の固定ピンチローラ31aの内1本の固定ピンチローラ31aの軸はパウダブレーキ115により回転を抑制され、この固定ピンチローラ31aの軸に設けた歯車116が他の2本の固定ピンチローラ31a,31aの軸に設けた歯車116,116に歯車117,117を介して噛合しているので、3本の固定ピンチローラ31aにはパウダブレーキ115の摩擦トルクによる同一の回転抑制力が作用する。
【0076】
ちなみに、パウダブレーキ115により固定ピンチローラ31aの回転を抑制する摩擦トルクは、成形する成形板29の板厚により調整する。
【0077】
したがって、パウダブレーキ115の摩擦トルクは成形板29の押出し力に対する抑制力と成り、成形ダイ10及び10aの導入部11内の押出し生地79をより一層高密度で均一な状態にし、この均一で高密度の押出し生地79は押出機70による押出し生地79の押出し力により前記ブレーキ手段30aの抑制力に抗して前進し、成形室22内で冷却され成形板29が成形される。この成形板29はパウダブレーキ115の抑制力に抗して前記固定ピンチローラ31a及び自在ピンチローラ31bを回転させながら前進する。
【0078】
前記抑制力は成形板29を介して成形部21及び導入部11内の押出し生地79に、押出機により加えられる成形室22内の押出し生地79の押出し力に対して抗力を与えることにより、前述したような成形板29に抑制力を加えない場合と比べると、成形室22内の押出し生地79の全体がより一層密度が均一で高密度になる。したがって、多量のセルロース系破砕物を含んだより一層均一高密度な木質合成板が成形される。
【0079】
この後、前記製品としての成形板29である木質合成板をカッター、シャーリング、鋸盤等の切断機で所望の長さで切断する。薄肉の成形板29であればカッターなどの切断機を使用し、12mmなどの厚肉の成形板29であればシャーリング、鋸盤等の切断機で切断する。
【0080】
【表1】

Figure 0003566348
【0081】
以上の製品としての成形板29である木質合成板 W:910mm、H:12mmを鋸盤により1820mm毎に切断し、重量18kgのベージュ色のコクリートパネルとして用いる木質合成板を得た。なお、肉厚10〜12mm程度の木質合成板は、車両用内外装の板、机やテーブル、食器棚等の家具材料など他の用途にも使用される。
【0082】
なお、成形ダイ10の高さを20〜30mmとすることによって、肉厚20〜30mmの木質合成板が成形され、この木質合成板は床板や他の用途の板材として使用される。したがって、成形される木質合成板の肉厚は上記の実施例に限定されない。
【0083】
【表2】
Figure 0003566348
【0084】
以上の製品としての成形板29である木質合成板 W:910mm、H:3mmをシャーリングにより1820mm毎に切断し、重量4.5kgの木質合成板を得る。
【0085】
このような薄板は、各種建築材料、家具材料、機器パーツ等として広範囲な使用目的に向けた素材となる。例えば、上記の薄板の木質合成板は、家屋の室内装飾用の化粧板などの建築材として使用され、あるいは約300mm四方の大きさに加工してフロアリングブロックなどの床材として使用される。さらに、他の用途として、自動車の車内の内装材として、例えば、運転席のメータパネル周りの化粧板、トランスミッション周囲の化粧板、その他の車内の壁面の化粧板として使用され、高級感を得ることができる。機器パーツとしては電気機器等のボックスパネルや他の機器の化粧板として使用される。
【0086】
尚、用途により剛性が必要のないときは、前掲バージンの硬質PVCの混入添加は不要である。
【0087】
【発明の効果】
本発明は、以上説明したように構成されているので、以下に記載されるような効果を奏する。
【0088】
比較的簡単かつ容易な手段により、衝撃摩砕力のみで処理対象の樹脂成形品としての廃農フィルムから、農薬、泥、土、砂、金属、農産物(葉、茎等)、ガラスの破片、ゴミ等の付着物を分離かつ除去し、かつこれを所定の粒径範囲内に整粒され素材化された樹脂材料として効率良く・造粒し、再利用し得るようにした。
【0089】
したがって、従来、行われていた廃農フィルムの水洗浄処理に要した大量の水及び乾燥処理における多大な設備を不要とし、省資源に寄与することができた。
【0090】
特に、水洗浄の廃水による河川の汚染を防止することができ、廃水の浄化処理の設備及び運転費のコストを省くことが可能となった。
【0091】
押出し生地を、内壁面にフッ素樹脂のシートを貼設又はフッ素樹脂をコーティングした成形ダイの成形部へ押出して所定の肉厚に成形し且つ前記成形部で冷却したので、フッ素樹脂は熱伝導係数が低いため徐冷効果があり、その結果、押出し生地が冷却するときに生じる歪みを少なくすることができた。したがって、成形板を補正ロール等で歪みを矯正するなどの矯正を必要としない内部残留応力が少ない高品質の木質合成板を成形することができた。
【0092】
成形ダイより押出された成形板に、成形板の押出し力に抗する抑制力を加えて成形ダイの成形部内の押出し生地の密度を高くしたので、より一層密度が均一で高密度の木質合成板を押出成形することができた。
【図面の簡単な説明】
【図1】この発明の処理対象の一例である廃農フィルムの回収・造粒方法の基本的な第1の実施例方法を適用した場合の概要を原理的かつ模式的に示す処理工程の系統説明図である。
【図2】本発明の実施例に使用するカッタミル(破砕手段)の要部を示す全体斜視図である。
【図3】同上実施例方法に用いられる研磨・整粒装置の概要構成を模式的に示す縦断面図である。
【図4】図3における研磨・整粒作用を説明するための正面図である。
【図5】本発明の実施例に使用する押出機の要部断面を示す全体正面図である。
【図6】本発明の実施例の成形ダイの縦断面を示す正面図である。
【図7】本発明の実施例の成形ダイの要部断面を示す平面図である。
【図8】本発明の実施例のブレーキ手段の要部断面を示す平面図である。
【図9】図8の矢視N−N線の縦断面図である。
【符号の説明】
10 成形ダイ
11 導入部
12 導入孔
13 導入室
14 ヒータ
15 案内板
16 スクリーン部
17 アダプタ
18 流入口
19 押出ダイ
21 成形部
22 成形室
23 ダイ出口
24 シート(フッ素樹脂の)
25 冷却管
29 成形板
30 ブレーキ手段
31a 固定ピンチローラ
31b 自在ピンチローラ
34,34a,34b 軸受
36 軸受固定フレーム
70 押出機
71 スクリュー
72 ギヤ減速機
73 ホッパ
74 バレル
75 バンドヒータ
76 スクリーン
77 アダプタ
78 押出ダイ
79 押出し生地
81 破砕片
82 被処理小片
110 クラッシャ
114 フレーム
115 パウダブレーキ
116 歯車
117 歯車
118 シリンダ
119 ガイド体
120 カッタミル
121 カッタミル本体
122 蓋
123 投入口
124 カッタ支持体
125 回転刃
126 固定刃
127 投入室
128 粗砕室
129 スクリーン
130 研磨・整粒装置(ピンミル)
131 固定円盤
132 供給投入口
133 固定端板
134 固定ピン
135 周側板
141 可動円盤
142 回転横軸
143 軸受
144 可動ピン
151 篩網
152 排出口
153 取出口
154 プラグバルブ
155 研磨・整粒空間
156 排出空間
158 ブロワー[0001]
[Industrial applications]
The present invention relates to a method and an apparatus for collecting and granulating a waste resin molded product, and a method for manufacturing a wooden synthetic board using the collected resin material.
[0002]
Specifically, as an application field of the present invention, waste plastic film used in agriculture, for example, polyvinyl chloride, polyethylene, polyvinyl acetate, so-called facility horticulture such as polyolefin, greenhouses in agriculture and other agricultural products for cultivation. A film or sheet made of a thermoplastic resin that is used for covering a seed or a seedling and that forms a used film or sheet that has been used and discarded for another use (in the present specification, “waste agricultural film” This waste resin molded product is roughly crushed or crushed in a broad sense into a plurality of pieces to be treated, and rainwater, dew, agricultural chemicals, and mud attached to the film or sheet of each piece to be treated. Separation and removal of deposits such as soil, sand, grass roots, metals, agricultural products (leaves, stems, etc.), glass fragments, garbage, etc. It recovered, and a method of granulating a fee. At the same time, the collected resin material is sized, and the collected and granulated material is collected and granulated as a sized resin material as a sized product within a predetermined particle size range. The present invention relates to a method for molding a resin material as it is, or a method for forming a pellet so that it can be reused, an apparatus for performing these methods, and a method for producing a wood composite board using the recovered resin material. Things.
[0003]
[Prior art]
Conventionally, a film made of polyvinyl chloride (soft PVC) or polyethylene or a sheet made of a resin such as polycarbonate (PC), which forms a waste agricultural film which is a waste resin molded product of this kind, is removed from the frame due to aging or storms due to use. Due to the falling off, pesticides, mud, soil, sand, metal, agricultural products (leaves, stems, etc.), glass fragments, garbage, and other deposits are attached, and they are sequentially replaced to lose transparency. These are replaced or discarded The waste agriculture film collected for washing was washed with water, dried, finely pulverized, blow-molded, etc., and formed and reused as a substitute for wood piles.
[0004]
In addition, the waste agriculture film has excellent characteristics such as water resistance, weather resistance, and decay resistance.However, for example, when incinerated by an incinerator for disposal, a large amount of harmful gas or smoke is discharged. It is well known that the occurrence of unfavorable social environment. In addition, there is a disadvantage that the resin material melted during incineration may adhere to the inside of the furnace and damage the furnace itself. Therefore, even if a resin molded product is buried underground to avoid this disadvantage, it remains without decay for a long period of time, and is considered to be a cause of environmental destruction.
[0005]
On the other hand, with respect to this kind of resin material, there is a tendency for resources to be depleted year by year, and it has been requested and recognized that a used resin material is reused without being discarded.
[0006]
[Problems to be solved by the invention]
Conventionally, waste agriculture film has been subjected to a regeneration treatment by washing the adhered substance on the surface with water, but this treatment requires a washing step and a drying step that require a large amount of water. There is a problem that a large amount of equipment is required for the drying treatment, and water resources and energy resources are wasted.
[0007]
In particular, the waste agricultural film usually has pesticides attached thereto, but even if the film or sheet is washed with water and washed, the cleaning liquid containing the pesticide must contaminate rivers and the like, so that it must be purified. If wastewater could not be discharged, the purification equipment and operating costs would be expensive, and most of the waste agricultural films were discarded without being reused.
[0008]
〔Purpose〕
The present invention has been developed in order to solve the above-mentioned problems, and by relatively simple and easy means, from waste agricultural film as a resin molded article to be treated, pesticides, mud, soil, sand, metal Separation and removal of deposits such as agricultural products (leaves, stems, etc.), glass shards, dust, etc., and efficiently granulating them as a resin material sized and made into a material with a predetermined particle size range It is an object of the present invention to provide a method and apparatus for recovering and granulating so that it can be reused, and a method for manufacturing a wooden synthetic board using the recovered resin material.
[0009]
[Means for Solving the Problems]
In order to achieve the above object, in the method for collecting and granulating a waste resin molded article of the present invention, a method for separating adhered substances from the waste resin molded article and recovering the resin material, the waste agricultural film, A process of subjecting the waste agricultural film to a plurality of small pieces to be treated,
Said relative granulated by individual fragments to be processed by adding a collision撃摩striking force, the resin material integer with the comminuted deposits adhering to the fragments to be processed is separated into a deposit resin material At least a step of forming a recovered resin material that has been made into a material by granulation,
Prior to the crushing step,
This is a method including at least a step of crushing the waste agricultural film into a plurality of crushed pieces. An impact milling force is applied to each of the coarsely crushed small pieces to be treated, and fine particles of the adhered matter adhering to the small pieces to be treated are separated into resin material and adhered matter, and the resin material is sized. The process of forming the recovered resin material into a material can be repeated a plurality of times.
[0010]
In the waste resin molded product collection and granulation apparatus of the present invention,
Crushing means for crushing the waste agricultural film into a plurality of small pieces to be treated,
Fixed side separation, classification, and sizing means on a fixed disk having a central portion communicating with the supply inlet of the small piece to be processed, and sequentially mounting each fixed pin on a plurality of rotation trajectories,
Movable side separation / classification / granulation means on a movable disk provided rotatably opposed to the fixed disk, wherein each movable pin is sequentially implanted on a plurality of rotation trajectories different from each of the fixed pins. When,
Classification means, which is provided on the outer periphery of the combination of each fixed pin and each movable pin, and communicates with a discharge port for arbitrarily discharging deposits separated to a desired particle size or less, and a discharge port for collecting a collected resin material having a desired particle size or more Extraction means for extracting
Separation, classification and sizing means configured to separate and classify the resin material and the attached matter by the impact grinding force between the fixed pins and the movable pins, and to size the resin material. It is characterized by the following. further,
In addition to the above configuration,
A crushing means for crushing a waste agricultural film to be processed into a plurality of crushed pieces first is added.
[0011]
The discharge port and the supply port can be communicated with each other so that the small pieces to be processed discharged to the discharge port are returned to the supply port.
[0012]
Further, in the method for producing a wooden synthetic board using the recovered resin material of the present invention,
25-80 wt% of the recovered resin material is mixed with 20-75 wt% of a cellulose-based crushed material having an average particle size of 20 mesh or less, preferably 60-150 mesh, with a water content of 15 wt% or less, and heating and kneading. Then, the extruded fabric is extruded into a molding die with a screw and extruded into a molding portion of a molding die in which a fluororesin sheet is stuck on an inner wall surface or coated with a fluororesin, and molded into a predetermined thickness and the extruded fabric is formed by the molding portion. The extrusion is performed by gradually cooling, and the density of the extruded material in the molding section is increased by adding a suppressing force against the extrusion force of the molded plate. The formulation example is preferably
With respect to 25 to 80 wt% of the recovered resin material, 20 to 75 wt% of a cellulosic crushed product having an average water content of 15 wt% or less and an average particle size of 20 mesh or less without adding a plasticizer, mixing, heating and kneading. Can be achieved. Also,
The recovered resin material is 20 to 40% by weight, preferably 25 to 30% by weight of soft vinyl chloride, and virgin hard vinyl chloride is 10 to 30% by weight, preferably 15 to 20% by weight, and the water content is within 15% by weight, preferably, Wood powder of 40 to 60 wt%, preferably 45 to 50 wt% can be mixed with 3 to 5 wt% and an average particle size of 80 mesh or less.
[0013]
Further, the recovered resin material is made of polyethylene and has a water content of 15 wt% or less, preferably 3 to 5 wt%, and wood powder of 40 to 60 wt%, preferably 45 to 50 wt%, having an average particle size of 150 mesh or less. Can be mixed by 10 to 60 wt%, preferably 45 to 50 wt%.
[0014]
[Action]
The waste agricultural film is crushed into a plurality of crushed pieces by crushing means, and the crushed crushed pieces, or the waste agricultural film is directly crushed into a plurality of small pieces to be treated by the crushing means, and then the plurality of pieces are processed. By supplying each of the small pieces to be processed one or more times from the supply inlet of the separation / classification / granulation means, the resin material is pulverized by the impact grinding force between each fixed pin and each movable pin. In addition to granulating and polishing and sizing, deposits having a desired particle size or less can be separated, arbitrarily divided and discharged to an outlet, and a recovered resin material having a desired particle size or more can be taken out from an outlet.
[0015]
With respect to the recovered resin material of 25 to 80 wt%, the content of water is within 15 wt% and the crushed cellulosic material having an average particle size of 20 mesh or less is heated and kneaded by an extruder, and is kneaded with a dough extruded from a discharge port by a screw. And extruded into the inlet of the forming die.
[0016]
First, the extruded dough is extruded into the molding chamber of the molding section while being heated and kept warm in the introduction section to maintain fluidity and maintain a good kneading state. Since the inner wall surface of the molding chamber is coated with a fluororesin sheet with a small coefficient of friction or coated with a fluororesin, the cellulosic crushed material in the extruded fabric passing through the inner wall surface smoothly without receiving a large resistance. Since it flows, it is extruded at a relatively low temperature while maintaining a uniform and high-density kneading state. In the process of being extruded in the molding chamber, the extruded dough is cooled to form a molded plate. Since the fluororesin has a lower coefficient of thermal conductivity than metal, the extruded fabric is gradually cooled, the distortion due to cooling is reduced, and a wood composite plate is formed as a uniform and high-density product with less distortion.
[0017]
Further, a braking force is applied to the pushing force applied to the formed plate by the extruder by the brake means, and a drag force against the pushed force is applied to the extruded material in the forming chamber via the formed plate. For example, by pressing a friction body against a brake drum provided at one shaft end of a pair of pinch rollers for holding and pressing the front and back surfaces of the formed plate, the rotation of the brake drum is suppressed, and the formed plate is extruded. The rotation of the pinch roller, which is rotated by the force, is suppressed, and the pinch roller applies a suppressing force against the pushing force to the forming plate.
[0018]
Then, the above-mentioned restraining force gives the extruded dough in the forming section and the introduction section via the forming plate a resistance against the extruding force of the extruded dough in the forming chamber applied by the extruder, so that the whole of the extruded dough in the forming chamber is However, the density becomes more uniform and higher. Therefore, a more uniform and high-density woody synthetic board containing a large amount of cellulosic crushed material is formed by the waste agricultural film.
[0019]
【Example】
Embodiments will be described with reference to the drawings.
[0020]
Example of resin material processing method and apparatus (target waste resin molded product)
The target waste resin molded product is a used waste agricultural film made of polyvinyl chloride (PVC; soft) or the like, and the surface of the waste agricultural film has pesticides, mud, soil, sand, metal, agricultural products (leaves and stems). Etc.), glass fragments, dust and other deposits are attached. When the used waste agricultural film is discarded or collected by a trader, there is a possibility that the waste agricultural film may be wound into a roll, but most of the waste agricultural film is in a large lump that is rounded to a shaggy shape.
[0021]
Hereinafter, means for recovering a resin material such as soft PVC from the waste agricultural film mass will be described.
[0022]
Processing method As shown in FIG. 1, the method includes a [crushing step], a [crushing step], and a [separation, classification, sizing step].
[0023]
Process 1 [crushing process]
The soft PVC film of the discarded agricultural greenhouse is cut into pieces of an appropriate size using the crushing means 110 as shown in FIG. 1 or crushed in a broad sense, for example, crushing of about 15 × 50 mm in size. A piece 81 is formed.
[0024]
(Crushing means)
The crushing means crushes the material to be crushed to form crushed pieces of an appropriate size, and in this embodiment, is referred to as a "crusher" for convenience.
[0025]
FIG. 1 shows an example of the “crusher”. The crusher 110 is provided with two axes rotating inwardly in parallel in a crusher main body having an input port for crushed material at an upper part, and a plurality of rotary blades provided on each axis at a predetermined interval. In order to cut a lump of waste agricultural film collected by three claw blades that are meshed with each other on the outer periphery of the rotating blade and project from the outer peripheral surface of each rotating blade so as to form an equal angle, into crushed pieces composed of appropriately large pieces. Is provided.
[0026]
A lump of abandoned agricultural film made of a soft PVC film of an agricultural plastic greenhouse, which is a waste resin molded product introduced from the upper inlet, is drawn into the interior by claw blades of two-axis rotary blades rotating inwardly to each other. The crushed piece 81 is formed by being crushed and cut by the compressive force acting at the time of retraction while being slit by the continuously acting shear force between the outer peripheral edges of the rotating blades rotating in a meshed state. The crushed pieces 81 are discharged from a discharge port provided below the biaxial rotary blade. At this time, the above-mentioned deposits such as pesticides and mud are attached to the surface of each crushed piece 81 and have a substantially black color.
[0027]
The crushing means is not limited to the crusher described above. For example, crushing means such as various mono-cutters, shredders, crushers, etc., such as Gainax crusher manufactured by Horai Co., Ltd. or roll crusher manufactured by Nara Machinery Co., Ltd. Can be used.
[0028]
Process 2 [Coarse crushing process]
The crushed piece 81 formed in a size of about 15 × 50 mm by the crushing means in the above-described step 1 [crushing step] is further finely cut, or in a broad sense, using a crushing means as shown in FIG. By crushing, small pieces 82 to be processed having a size of, for example, a rectangle of about 2 × 15 mm, a square of about 10 × 10 mm or other irregular shape, each side of which is about 10 mm or less are formed. At this time as well, as in the above-described step 1 [crushing step], the above-mentioned deposits such as pesticides and mud are attached to the surfaces of the small pieces 82 to be processed.
[0029]
(Crushing means)
The crushing means cuts and crushes the crushed pieces 81 to form small pieces to be processed 82 of an appropriate size. In this embodiment, the crushing means is referred to as a "cutter mill" for convenience.
[0030]
FIG. 2 shows a cutter mill 120 which is an example of the crushing means.
[0031]
Reference numeral 121 denotes a cutter mill body, which is a cylindrical casing having an upper surface opening, and the opening is covered with a lid 122 which can be freely opened and closed. The lid 122 has an inlet 123 into which the crushed pieces 81 to be crushed are introduced into the cutter mill main body 121.
[0032]
Further, a cutter support 124 is provided in the cutter mill main body 121, which is rotatably supported on the bottom surface of the cutter mill main body 121 and is rotated in a horizontal direction by rotation driving means (not shown). Three blades 125 are provided, and these three rotary blades 125 are disposed so as to form an equal angle of 120 degrees in the rotation direction of the cutter support 124, and the cutting edges of the three rotary blades 125 have the same rotation locus. Located on top. Further, the two fixed blades 126 are fixed to the cutter mill body 121 at a position substantially symmetrical to the rotation locus of the cutting edge of the rotary blade 125 through a slight gap with respect to the rotation locus of the cutting edge of the three rotary blades 125. The inside of the cutter mill body 121 is bisected by the fixed blade 126, the cutter support member 124, and the rotary blade 125 to form a charging chamber 127 and a crushing chamber 128. The input port 123 of the lid 122 communicates with the input chamber 127. The clearance between the second fixed blade 126 and the rotary blade 125 can be freely adjusted so that the material to be crushed can be cut into a desired size or crushed in a broad sense. The clearance of this embodiment is 0.2 to 0.3 mm. The crushing chamber 128 is partitioned by the mesh screen 129 so as to surround the periphery of the rotation locus of the rotary blade 125 between the two fixed blades 126. In this embodiment, the screen 129 is formed of a mesh through which a small piece 82 having a side of about 10 mm can pass. Further, a discharge port for discharging the small piece to be processed 82 is provided at a lower end of the cutter mill main body 121 of the crushing chamber 128.
[0033]
In the above-mentioned cutter mill 120, the crushed pieces 81 having a size of about 15 × 50 mm formed by the crusher 110 in the above-mentioned step 1 [crushing step] are introduced from the inlet 123 of the lid 122, and the cutter is driven by a rotation driving means (not shown). When the support 124 is rotated, the crushed pieces 81 are indeterminate in shape and area through the screen 129 between the rotary blade 125 and the fixed blade 126 of the cutter support 124, but almost all of the crushed pieces 81 are rectangular or approximately 2 × 15 mm. A small or irregular shaped piece 82 having a size of about 10 × 10 mm or less and a side of about 10 mm or less is formed and discharged from the discharge port to the next process.
[0034]
The crushing means is not limited to the above-mentioned cutter mill. For example, like a hard crusher manufactured by Horai Co., Ltd., the rotating shaft of the rotating blade 125 is provided in the horizontal direction, and Some screens 129 are provided below. At this point, the above-mentioned deposits such as pesticides and mud are slightly dropped on the surface of each crushed piece 81, but they are almost opaque and light black.
[0035]
Process 3 [separation, classification, sizing process]
In the crushing means in the above-mentioned step 2 [crushing step], each side is formed in a rectangular or irregular size of about 10 mm or less, and pesticides, mud, soil, sand, metal, agricultural products (leaves and stems), An impact grinding force is applied to each of the small pieces 82 to be treated of the soft PVC film on the surface of which glass fragments, dust, etc. are adhered, and crushed into a rectangular or irregular shape having a side of 1 to 2 mm or less. The resin material is granulated and polished from each of the small pieces 82 to a size of about 1 mm in diameter and about 10 mm in length, or a rectangular or cylindrical shape having a side of about 2 to 5 mm or other irregular size. And sizing. At the same time, the attached matter is finely pulverized and separated from the surface of each of the small pieces 82 by the impact milling force, and the pulverized attached matter and the soft PVC are classified. The resin is recovered as a resin material.
[0036]
The above steps can be repeated any number of times as needed.
[0037]
(Separation, classification, and sizing)
As described above, the separation / classification / granulation means pulverizes, grinds and polishes the small pieces 82 to be treated of the soft PVC film of the waste resin molded product, and also adjusts the surface of the film with respect to the sized material of the film. This is a means for separating and classifying the attached matter from the film by finely pulverizing the attached matter and granulating or sizing the resin material from the small pieces 82 to be treated. In the present embodiment, this is referred to as a “pin mill” for convenience.
[0038]
3 and 4, a pin mill 130 has a central portion of a fixed disk 131, which is provided with a supply inlet 132 through which small pieces 82 to be processed are introduced, and a fixed end plate 133 is provided on the fixed disk 131 for polishing and sizing. The outer peripheral edges of the fixed end plate 133 are fixed to the fixed disk 131 by the peripheral side plate 135. A movable disk 141 that is driven to rotate by a rotating horizontal shaft 142 is provided in the polishing and sizing space 155, and the rotating horizontal shaft 142 is pivotally supported by bearings 143 and 143. The rotation horizontal shaft 142 is rotationally driven by a rotation driving means such as a motor (not shown).
[0039]
On the fixed disk 131, each fixed pin 134 is sequentially implanted on a plurality of concentric rotation trajectories a (relative to the movable disk 141) (FIG. 4). On the 141, movable pins 144 alternately entering on a plurality of rotation trajectories b different from the fixed pins 134 are sequentially implanted, and an impact is applied between the fixed and movable pins 134 and 144. It is positioned so that a grinding, polishing, and sizing action can be obtained by a grinding force. Further, a screen 151 having a predetermined mesh formed by punching pores having a desired diameter is provided around the outer peripheral side of the movable disk 141 and the peripheral side plate 135 with a discharge space 156 therebetween. An outlet 152 is provided. In addition, as shown in FIG. 1, a blower 157 is connected to the discharge port 152 to the pin mill 130. In this embodiment, the screen 151 is a mesh having a diameter of 1 mm, but is usually a mesh having a diameter of 1 mm or less, preferably a mesh having a diameter of 0.7 mm.
[0040]
Further, an outlet 153 is provided in the lower part of the screen 151 of the polishing and sizing space 155, and a plug valve 154 for opening and closing control is provided in the outlet 153. As shown in FIG. 1, a blower 158 for sucking air in the pin mill 130 communicates with the outlet 153, and the blower 158 communicates with the supply inlet 132.
[0041]
Therefore, in the above-described pin mill 130, when the rotating horizontal shaft 142 is rotated by the rotation driving means (not shown) to rotate the movable disk 141 and supply the small pieces 82 to be supplied to the supply inlet 132, the small pieces 82 are processed. In the center of the polishing and sizing space 155, the fixed and movable pins 134 and 144 are subjected to crushing or polishing by an impact crushing force, a sizing and centrifugal action together. Under the impact grinding force, it gradually approaches the outer periphery while being crushed or polished and sized. In this process, the attached matter such as pesticides, mud, soil, sand, metal, agricultural products (leaves and stems), glass fragments, garbage, and the like attached to the surface of the soft PVC film of each of the small pieces 82 to be processed has a side of 1 mm. The following irregular shape is finely ground, while the soft PVC film as a resin material is polished and sized to a rectangular or cylindrical shape with a diameter of about 1 mm and a length of about 10 mm, or a side of about 2 to 5 mm, or other irregular shapes. Thus, a recovered resin material is formed. During this time, some of the resin material in the small piece to be processed 82 becomes fine powder finely pulverized to a rectangular or irregular shape having a side of 1 mm or less.
[0042]
The pulverized deposit and a part of the soft PVC film in the small piece to be processed 82 pass through the screen 151 by the centrifugal action of each movable pin 144 and are classified into the discharge space 156. It is sucked and discharged to the outside via 157. This waste deposit may be mixed with the recovered resin material at the time of molding described below.
[0043]
On the other hand, the polished and sized soft PVC film sized resin material and the deposits not passing through the screen 151 remain in the screen 151, but are supplied to the outlet 153 with the plug valve 154 opened. Since the inlet 132 is communicated with the inlet 132 via the blower 158, the sized resin material taken out from the outlet 153 and the deposits not passing through the screen 151 are returned to the feed inlet 132, and the glass, Deposits such as metal are finely pulverized so that they can pass through the screen 151, and are discharged to the outside from the discharge port 152 as described above. However, although the sizing resin material of the soft PVC film is refluxed, most of the soft sizing material is not polished and sieved so as to pass through the screen 151, and most of the sizing resin material remains in the screen 151.
[0044]
The sized collected resin material is taken out from the outlet 153 by opening the plug valve 154 as the collected resin material. As this means, the recovered resin material can be scraped from the outlet 153 or a branch pipe having an outlet by branching the communication pipe between the blower 158 and the supply inlet 132 is provided. An electromagnetic valve for opening and closing the outlet and an electromagnetic valve for opening and closing the downstream side of the communication pipe are provided, and these two electromagnetic valves are provided so as to be opened and closed alternately, or a three-way electromagnetic valve is provided for both branch pipes, The downstream side of the pipe is closed by an electromagnetic valve and the outlet of the branch pipe is opened, and the outlet 152 is also closed. The blower 158 sucks the sized resin material remaining in the screen 151 and branches the pipe. Can also be collected from the outlet. In this case, the process is performed after the waste deposits and a part of the soft PVC film powder pulverized to the same degree as the deposits are discharged to the outside.
[0045]
The recovered resin material was substantially transparent or translucent colorless or pale white.
Alternatively or in addition to the blower 158, compressed air is sent into the polishing and sizing space 155 of the pin mill 130, and communicates via a pipe through a hole formed in the fixed end plate 133. Deposits of a size that cannot pass through the screen 151 may be returned to the supply inlet.
[0046]
As an example, using a test machine of the pin mill 130 having the above-described structure, 600 g of each piece 82 to be processed is put into the pin mill 130, and the movable disk 141 is rotated at 40 Hz and a rotation speed of 1900 rpm. Approximately 90 wt% of the total weight of the small piece 82 to be processed is recovered as an irregular resin material in which a diameter or a width of 1.2 mm or less and a length of about 3 to 7 mm are rounded into a substantially cylindrical shape, or a square shape is slightly twisted. The remaining about 10% by weight was crushed particles of the deposits and crushed powder of a soft PVC film as a resin material. Thus, a large amount of sized resin material could be recovered from the waste resin molded product in a short time. In order to improve the processing capability of the pin mill 130, the size of the pin mill 130 may be increased.
[0047]
When the rotational speed of the movable disk 141 is set to be low, the soft PVC film, which is the main resin of the discarded resin molded product of each of the small pieces to be processed 82, is not finely polished and sized. Attached substances such as pesticides, mud, soil, sand, metal, agricultural products (leaves and stems), glass fragments, dust and the like adhering to the surface of 82 are returned from the outlet 153 to the supply inlet 132 via the blower 158. Then, it is pulverized again by the impact attrition force and further pulverized by the polishing action, so that the soft PVC film or the like, which is a resin material of the waste agricultural film, can be polished and sized to a size larger than the mesh of the screen 151. The rotational speed of the movable disk 141 can be set to 1200 rpm, for example.
[0048]
In the above-described embodiment, the PVC film has been described as a main example. However, other resin materials, such as polyethylene and polycarbonate, can be similarly collected as a sized resin material.
[0049]
In addition, in addition to the above-described method of treating the resin material, the state of the collected waste agricultural film, for example, whether it is wound in a roll or the degree of the contamination, The resin material can be recovered by reversing the order of each step or omitting step 1.
[0050]
Molding process The recovered resin material obtained in the present invention can be directly injected into a molding machine such as an extruder to be molded into another molded product, or can be molded into a pellet in the form of a molding resin material, Alternatively, the recovered resin material and a virgin resin material of the same quality are kneaded, and for example, in the case of soft PVC, virgin hard PVC can be kneaded to form pellets, or formed into another molded product. It can also be used as a raw material for wooden synthetic boards.
[0051]
Hereinafter, means for producing a wooden synthetic board using the recovered resin material of the present invention will be described.
[0052]
The mixing capacity of each raw material is appropriately determined in accordance with various characteristics such as the desired wear resistance characteristics. However, in the present invention, a large amount is removed because the various adverse effects at the time of the above-described molding are removed. Can be mixed.
[0053]
In the case of PET, wood flour is mixed up to 60 wt% at maximum, but the mixing ratio of wood flour is preferably 20 to 55 wt%.
[0054]
When the recovered resin material is PVC, the mixing ratio of the wood powder is 30 to 60 wt%, preferably 45 to 55 wt%.
[0055]
As an example, 30 wt% of the recovered resin material, which is the soft PVC, is mixed with 19 wt% of virgin hard vinyl chloride pellets, and mixed with 51 wt% of wood powder having an average particle size of 80 mesh or less with a water content of 5 wt% or less and formed with a screw. The extruded dough extruded into the die is gradually cooled, and a suppressing force against the extruding force is applied to the extruded dough to form a woody synthetic board as a molded resin product based on wood flour using an extruder.
[0056]
The purpose of adding the hard PVC is to obtain a desired hardness, and the recovered resin material is replaced with a plasticizer. According to the method of the present invention, the plasticizer can be omitted.
[0057]
In the case where the resin material is a waste agricultural film made of polyethylene, 49 wt% of polyethylene as a recovered resin material is mixed with 51 wt% of wood powder having an average water content of 5 wt% or less and an average particle size of 150 mesh or less. Then, the extruded dough extruded to the forming die with the screw is gradually cooled, and a suppressing force against the extruding force is applied to the extruded dough to similarly form a wood composite board.
[0058]
In this case, the addition of virgin polyethylene and plasticizer is unnecessary.
[0059]
Hereinafter, a production example of a wood composite board will be described.
In FIG. 5, reference numeral 70 denotes a single-screw extruder. Generally, the extruder is usually of a screw type, and there are a single-screw extruder and a multi-screw extruder, and some have a modification or a combination thereof. Any extruder can be used in the present invention.
[0060]
In FIG. 5, reference numeral 71 denotes a screw, which is a single shaft type. The screw 71 is driven by a motor (not shown) via a gear reducer 72 and rotates in a barrel 74. The rotating screw 71 extrudes the cellulosic crushed material and the recovered resin material fed from the hopper 73 toward the front of the screw 71 while being kneaded. A band heater 75 is provided on the outer surface of the barrel 74, and the cellulosic crushed material and the resin in the barrel 74 are heated by the band heater 75, and gradually melted while being transferred forward along the groove of the screw 71 to crush the cellulosic crushed material. The material and the resin are kneaded. Then, the extruded material 79 is extruded from the extrusion die 78 of the adapter 77 to the forming die 10 via the screen 76 and the adapter 77.
[0061]
The raw materials put into the hopper 73 are a crushed cellulosic material and a recovered resin material. In particular, the particle size of the wood powder is used to improve the compatibility with the recovered resin material. In order to prevent abrasion and damage, the powder is formed into a fine powder having a size of 20 to 300 mesh, preferably 20 (below the sieve) to 150 mesh (above the sieve). The water content is set to 15 wt% or less, preferably 11 wt% or less, and ideally 3 to 5 wt% in order to eliminate the possibility of bubbles and prevent surface roughening.
[0062]
In FIG. 6, reference numeral 10 denotes a forming die, which has a shape similar to a so-called T-die forming die, and extrudes extruded material 79 discharged from an extrusion die 78 having a rectangular cross section of an extruder 70 by heating and keeping the temperature. It comprises an introduction section 11 for extruding the dough 79 while maintaining the fluidity of the dough 79, and a molding section 21 having a molding chamber 22 for molding the extruded dough 79 extruded from the introduction section 11 into a wide and plate-shaped sheet having a predetermined thickness.
[0063]
The introduction section 11 includes an introduction hole 12 and an introduction chamber 13, and extends from an extrusion die 78 having a circular section with a diameter of about 65 mm to an entrance of a molding chamber 22 having an elongated rectangular section with a width of 910 mm and a height of 12 mm. The cross section is sharply deformed. The distance from the extrusion die 78 to the entrance of the molding chamber 22 (the distance in the extrusion direction of the introduction section 11) is about 200 mm.
[0064]
Reference numeral 12 denotes an introduction hole, which is formed in the forming die 10 in the width direction of the forming die 10, and has a longitudinal section which is bulged to have an elliptical cross section as shown in FIG. The shape of the cross section is curved in the width direction of the forming die 10 as shown in FIG. 6, and both ends thereof extend to both ends in the longitudinal direction of the rectangular cross section of the entrance of the forming chamber 22, so-called coat / die. It is formed in a hanger shape and communicates with an extrusion die 78 of an extruder 70 at a substantially central position in the longitudinal direction of the introduction hole 12. In addition, a space between the introduction hole 12 and the entrance of the molding chamber 22 is communicated with an introduction chamber 13 having a triangular cross section in a direction in which a longitudinal section gradually narrows.
[0065]
Reference numeral 14 denotes a heater, which may be provided on the outer periphery of the peripheral wall of the introduction hole 12 and the introduction chamber 13 by a heating means such as an electric heater. However, in the embodiment, the heater is provided in the peripheral wall in that the heating effect is excellent. The extruded dough 79 flowing through the introduction hole 12 and the introduction chamber 13 is heated and kept warm to maintain the fluidity of the extruded dough 79.
[0066]
A vertical cross section in the width direction of the forming die 10 has an elongated rectangular cross section with a width of 910 mm and a height of 12 mm, and the distance from the inlet of the forming chamber 22 to the die outlet 23 (the distance in the extrusion direction of the forming unit 21) is 500 mm.
[0067]
A sheet 24 made of a fluororesin having a thickness of 0.25 mm is attached to the inner walls of the molding chamber 22 on the four sides of the upper, lower, left and right sides. Alternatively, fluorocarbon resin can be directly coated on the inner walls of the upper, lower, left and right sides of the molding chamber 22. However, the fluorocarbon resin is easily exchangeable, is easily coated with fluorocarbon resin, and has high durability. It is particularly preferable to attach a resin sheet 24.
[0068]
Reference numeral 25 denotes a cooling pipe, which is an example of a cooling means for cooling the forming part 11 of the forming die 10. The extruded fabric 79 in the molding chamber 22 is cooled by supplying cooling water such as water at room temperature or water or oil up to about 70 to 80 ° C. as a cooling medium into the cooling pipe 25.
[0069]
As shown in FIG. 7, a guide plate 15 is a plate having a thickness of 7 mm which forms a symmetrical trapezoidal shape with a short side of about 200 mm, a long side of about 850 mm, and a height of about 100 mm as shown in FIG. A sheet made of a fluororesin such as Teflon having a thickness of 0.1 to 0.5 mm is attached to the entire outer surface. The outer surface of the guide plate 15 may be directly coated with a fluororesin. The method of attaching a fluororesin sheet or coating the fluororesin is performed by the sheet 24 provided in the molding chamber 22 of the molding die 10 described above. Is the same as The guide plate 15 is positioned at the center of the introduction hole 12a having a height of 12 mm and a width of 900 mm so as to have an interval of 25 mm at both ends in the width direction of the introduction hole 12a. The edge is positioned so as to have a substantially parallel interval to the rear end wall surface of the introduction hole 12a, and the guide plate 15 is fixed to the lower surface of the introduction hole 12a with four bolts 27 on the forming die 10a. Therefore, a gap of 5 mm is formed between the upper surface of the guide plate 15 and the upper surface of the introduction hole 12a.
[0070]
The guide plate 15 is formed such that its thickness is 70% or less of the height of the introduction hole 12a in accordance with the height of the introduction hole 12a, and the width of the guide plate 15 is about 70% of the width of the introduction hole 12a. Preferably, it is formed to have a length of up to 95%.
[0071]
In addition, the guide plate 15 can be positioned substantially at the center in the height direction of the introduction hole 12a so that the upper and lower surfaces of the guide plate 15 are provided with the same gap as the upper and lower surfaces of the introduction hole 12a. If the guide plate 15 of the present embodiment is positioned substantially at the center in the height direction of the introduction hole 12a, the center of the introduction hole 12a in the height direction is formed so as to form a gap of 2.5 mm vertically in the height direction. The guide plate 15 is screwed and fixed to the forming die 10a with four stepped pins.
[0072]
When the extruded dough 79 is heated and maintained in the introduction section 11 to maintain the fluidity and maintain a good kneading state, and when the guide plate 15 is provided, the extruded dough 79 is extruded by the guide plate in the introduction section 11 depending on the raw material. In the extrusion direction, the material 79 is prevented from undergoing different linear expansions at the center portion and the end portions, thereby preventing the molecular orientation from being different, achieving uniform linear expansion, controlling the molecular orientation, and forming the molding chamber of the forming portion 21. 22 and is extruded at a uniform density. Since the inner wall surface of the molding chamber 22 is coated with a fluororesin sheet 24 having a small coefficient of friction or coated with a fluororesin, the cellulosic crushed material in the extruded fabric 79 passing through the inner wall surface receives a large resistance. It is extruded at a relatively low temperature while maintaining a uniform and high-density kneading state. In the process of being extruded in the molding chamber 22, the extruded material 79 is gradually cooled and cooled by a cooling medium such as water or oil at room temperature to 60 ° C. to 90 ° C. to form the molded plate 29. Since the fluororesin has a lower coefficient of thermal conductivity than metal, the extruded dough 79 is gradually cooled, the distortion due to cooling is reduced, and a wood composite plate as a molded plate 29 as a uniform and high-density product with less distortion is formed. You.
[0073]
8 and 9, a bearing 34 a for bearing both ends of the shaft of the three free pinch rollers 31 b is fixed to a bearing fixing frame 36, respectively, and a gear 116 provided with the fixed pinch roller 31 a on each shaft; The input shaft of the powder brake 115 is connected to the shaft of one of the three fixed pinch rollers 31a in cooperation with the gear 117 meshing with the gear 116. The powder brake 115 is a so-called electromagnetic brake, and can finely adjust the friction torque electrically.
[0074]
Further, a frame 114 is erected on the bearing fixing frame 36, and 1192 block-shaped guide members provided with guide grooves on the wall surface of the frame 114 are substantially parallel to each other with the axial direction of the guide member 119 being oriented in the vertical direction. , And bearings 34b for bearing both ends of the shafts of the three free pinch rollers 31b are provided movably up and down along the guide grooves of the guide body 119, and the bearings 34b are respectively provided on the upper surface of the frame 114. The three air cylinders 118 are connected to the tips of the rods.
[0075]
Therefore, by the operation of the cylinder 118, the three free pinch rollers 31b are each pressed against the fixed pinch roller 31a via the forming plate 29, and the axis of one fixed pinch roller 31a among the three fixed pinch rollers 31a is pressed. The rotation of the pinch roller 31a is suppressed by the powder brake 115, and the gear 116 provided on the shaft of the fixed pinch roller 31a is connected to the gears 116, 116 provided on the shafts of the other two fixed pinch rollers 31a, 31a via the gears 117, 117. The three pinch rollers 31a have the same rotation suppressing force due to the friction torque of the powder brake 115.
[0076]
Incidentally, the friction torque for suppressing the rotation of the fixed pinch roller 31a by the powder brake 115 is adjusted by the thickness of the forming plate 29 to be formed.
[0077]
Therefore, the friction torque of the powder brake 115 serves as a suppressing force against the pushing force of the forming plate 29, and makes the extruded material 79 in the introduction portion 11 of the forming dies 10 and 10a more dense and uniform. The extruded dough 79 having the density is advanced by the extruding force of the extruded dough 79 by the extruder 70 against the restraining force of the brake means 30a, and cooled in the forming chamber 22 to form the formed plate 29. The forming plate 29 advances while rotating the fixed pinch roller 31a and the free pinch roller 31b against the restraining force of the powder brake 115.
[0078]
The above-described suppressing force is applied to the extruded dough 79 in the forming part 21 and the introduction part 11 via the forming plate 29 by giving a resistance to the extruding force of the extruded dough 79 in the forming chamber 22 applied by the extruder. As compared with the case where the suppressing force is not applied to the forming plate 29 as described above, the entire extruded material 79 in the forming chamber 22 has a further uniform and high density. Therefore, a more uniform and high-density woody synthetic board containing a large amount of cellulosic crushed material is formed.
[0079]
Thereafter, the wood composite board, which is the molded board 29 as the product, is cut into a desired length by a cutting machine such as a cutter, a shearing machine or a sawing machine. A cutting machine such as a cutter is used for a thin molded plate 29, and a cutting machine such as a shearing machine or a sawing machine is used for a thick molded plate 29 of 12 mm or the like.
[0080]
[Table 1]
Figure 0003566348
[0081]
A wood composite board W: 910 mm and H: 12 mm, which is the molded board 29 as the above product, was cut into 1820 mm pieces by a saw to obtain a wood composite board used as a beige cocrete panel weighing 18 kg. The wooden composite board having a thickness of about 10 to 12 mm is also used for other purposes such as interior and exterior boards for vehicles, furniture materials such as desks, tables, cupboards, and the like.
[0082]
In addition, by setting the height of the forming die 10 to 20 to 30 mm, a wooden composite board having a thickness of 20 to 30 mm is formed, and this wooden composite board is used as a floorboard or a board for other uses. Therefore, the thickness of the wood composite board to be formed is not limited to the above embodiment.
[0083]
[Table 2]
Figure 0003566348
[0084]
A woody synthetic board W: 910 mm and H: 3 mm, which is the molded board 29 as the above product, is cut at every 1820 mm by shearing to obtain a woody synthetic board weighing 4.5 kg.
[0085]
Such a thin plate is a material for a wide range of usage purposes as various building materials, furniture materials, equipment parts and the like. For example, the above-mentioned thin wooden synthetic board is used as a building material such as a decorative board for interior decoration of a house, or processed into a size of about 300 mm square to be used as a floor material such as a flooring block. Furthermore, it is used as an interior material inside a car, for example, as a decorative panel around a meter panel in a driver's seat, a decorative panel around a transmission, and a decorative panel on other wall surfaces in a vehicle, to obtain a sense of quality. Can be. As a device part, it is used as a box panel of an electric device or the like or a decorative plate of another device.
[0086]
In addition, when rigidity is not required depending on the use, it is not necessary to mix and add the above-mentioned virgin hard PVC.
[0087]
【The invention's effect】
The present invention is configured as described above, and has the following effects.
[0088]
By relatively simple and easy means, from waste agricultural film as a resin molded article to be treated only by impact attrition, pesticides, mud, soil, sand, metal, agricultural products (leaves, stems, etc.), glass fragments, Deposits such as dust are separated and removed, and the particles are efficiently granulated as a resin material sized to a predetermined particle size range and made into a material so that it can be reused.
[0089]
Therefore, a large amount of water required for the water washing treatment of the waste agricultural film, which has been conventionally performed, and a large amount of equipment for the drying treatment are not required, thereby contributing to resource saving.
[0090]
In particular, it is possible to prevent the river from being polluted by the wastewater from the water washing, and it is possible to reduce the cost of the equipment and the operating cost for the purification treatment of the wastewater.
[0091]
The extruded fabric is extruded into a molding part of a molding die in which a sheet of fluororesin is stuck on the inner wall surface or coated with fluororesin and molded to a predetermined thickness and cooled in the molding part. , There was a slow cooling effect, and as a result, distortion generated when the extruded dough was cooled could be reduced. Therefore, it was possible to form a high-quality wood composite board with little internal residual stress that does not require correction such as correcting the distortion of the formed board with a correction roll or the like.
[0092]
The density of the extruded material in the molding part of the molding die was increased by adding a suppressing force against the extrusion force of the molding plate to the molding plate extruded from the molding die. Could be extruded.
[Brief description of the drawings]
BRIEF DESCRIPTION OF DRAWINGS FIG. 1 is a system of processing steps showing, in principle and schematically, an outline of a case in which a first embodiment of a method for collecting and granulating waste agricultural film, which is an example of a processing target of the present invention, is applied. FIG.
FIG. 2 is an overall perspective view showing a main part of a cutter mill (crushing means) used in the embodiment of the present invention.
FIG. 3 is a longitudinal sectional view schematically showing a schematic configuration of a polishing and sizing apparatus used in the method of the embodiment.
FIG. 4 is a front view for explaining a polishing and sizing operation in FIG. 3;
FIG. 5 is an overall front view showing a cross section of a main part of an extruder used in an embodiment of the present invention.
FIG. 6 is a front view showing a vertical section of a forming die according to an example of the present invention.
FIG. 7 is a plan view showing a cross section of a main part of a forming die according to an example of the present invention.
FIG. 8 is a plan view showing a cross section of a main part of the brake means according to the embodiment of the present invention.
FIG. 9 is a vertical sectional view taken along line NN of FIG. 8;
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 10 Forming die 11 Introducing part 12 Introducing hole 13 Introducing chamber 14 Heater 15 Guide plate 16 Screen part 17 Adapter 18 Inlet 19 Extrusion die 21 Molding part 22 Molding chamber 23 Die outlet 24 Sheet (of fluororesin)
25 Cooling pipe 29 Forming plate 30 Brake means 31a Fixed pinch roller 31b Free pinch rollers 34, 34a, 34b Bearing 36 Bearing fixed frame 70 Extruder 71 Screw 72 Gear reducer 73 Hopper 74 Barrel 75 Band heater 76 Screen 77 Adapter 78 Extrusion die 79 Extruded dough 81 Crushed piece 82 Piece to be processed 110 Crusher 114 Frame 115 Powder brake 116 Gear 117 Gear 118 Cylinder 119 Guide body 120 Cutter mill 121 Cutter mill main body 122 Lid 123 Input port 124 Cutter support 125 Rotary blade 126 Fixed blade 127 Input chamber 128 Crushing room 129 Screen 130 Polishing and sizing machine (pin mill)
131 Fixed disk 132 Supply inlet 133 Fixed end plate 134 Fixed pin 135 Peripheral side plate 141 Movable disk 142 Rotating horizontal shaft 143 Bearing 144 Movable pin 151 Sieve mesh 152 Outlet 153 Outlet 154 Plug valve 155 Polishing / granulation space 156 Drainage space 158 blower

Claims (10)

廃棄樹脂成形品から付着物を分離し、樹脂材料を回収する方法であって、
処理対象を、廃農フィルムとし、この廃農フィルムを複数の各被処理小片に粗砕する工程と、
前記粗砕された個々の被処理小片に対して衝撃摩砕力を付加し、前記被処理小片に付着する付着物を微粉砕して樹脂材料と付着物とに分離すると共に前記樹脂材料を整粒し素材化された回収樹脂材料とする工程とを少なくとも含む廃棄樹脂成形品の回収・造粒方法。
A method for separating adhering matter from a waste resin molded product and recovering a resin material,
The process is a waste agricultural film, a step of coarsely crushing this waste agricultural film into a plurality of small pieces to be processed,
Said resin material together with said relative granulated by individual fragments to be processed by adding a collision撃摩striking force to separate the to the resin material deposits comminuted adhering to the fragments to be processed deposits and sieved to materials of it has been recovered resin material with at least comprising recovering and granulating method of waste resin molded article and a step of.
廃棄樹脂成形品から付着物を分離し、樹脂材料を回収する方法であって、
処理対象を、廃農フィルムとし、この廃農フィルムを複数の破砕片に破砕する工程と、
前記破砕された破砕片を複数の各被処理小片に粗砕する工程と、
前記粗砕された個々の被処理小片に対して衝撃摩砕力を付加し、前記被処理小片に付着する付着物を微粉砕して樹脂材料と付着物とに分離すると共に前記樹脂材料を整粒し素材化された回収樹脂材料とする工程と、且つ分離された付着物を随時に除去する工程とを少なくとも含む廃棄樹脂成形品の回収・造粒方法。
A method for separating adhering matter from a waste resin molded product and recovering a resin material,
The processing target is a waste agricultural film, a step of crushing the waste agricultural film into a plurality of crushed pieces,
A step of coarsely crushing the crushed pieces into a plurality of small pieces to be treated,
Said resin material together with said relative granulated by individual fragments to be processed by adding a collision撃摩striking force to separate the to the resin material deposits comminuted adhering to the fragments to be processed deposits and process and, and the separated deposit at any time including at least collecting and granulation process of the waste resin molded article and removing the to sized to materials of have been recovered resin material.
粗砕された個々の被処理小片に対して衝撃摩砕力を付加し、前記被処理小片に付着する付着物を微粉砕して樹脂材料と付着物とに分離すると共に前記樹脂材料を整粒し素材化された回収樹脂材料とする前記工程を複数回にわたり反復することを特徴とする請求項1又は2記載の廃棄樹脂成形品の回収・造粒方法。Adding opposition撃摩striking force with respect crushed by individual fragments to be processed, the said resin material integer with comminuted deposits adhering to the fragments to be processed is separated into a resin material deposits and 3. The method for collecting and granulating a waste resin molded product according to claim 1, wherein the step of forming a recovered resin material that has been granulated into a material is repeated a plurality of times. 廃棄樹脂成形品から付着物を分離し、樹脂材料を回収する装置であって、
処理対象を、廃農フィルムとし、この廃農フィルムを複数の各被処理小片に粗砕する粗砕手段と、
前記被処理小片の供給投入口部に中心部を連通した固定円盤上にあって、複数の回転軌跡上で各固定ピンを順次に植設した固定側分離・分級・整粒手段と、
前記固定円盤に対向して回転駆動可能に設けた可動円盤上にあって、前記各固定ピンとは異なる複数の回転軌跡上で各可動ピンを順次に植設した可動側分離・分級・整粒手段と、
前記各固定ピンと各可動ピンとの組み合せ外周部にあって、分離された付着物を排出するための排出口に連通した分級手段、および所望粒度以上の回収樹脂材料を取出し口に取出す取出し手段とを備え、
前記各固定ピンと各可動ピンとの相互間で、衝撃摩砕力により樹脂材料と付着物を分離・分級し、前記樹脂材料を整粒し得るように構成した分離・分級・整粒手段とから成ることを特徴とする廃棄樹脂成形品の回収・造粒装置。
An apparatus for separating adhering matter from a waste resin molded product and recovering a resin material,
The processing target is a waste agricultural film, and a crushing means for crushing the waste agricultural film into a plurality of small pieces to be processed,
Fixed side separation, classification, and sizing means on a fixed disk having a central portion communicating with the supply inlet of the small piece to be processed, and sequentially mounting each fixed pin on a plurality of rotation trajectories,
Movable side separation / classification / granulation means on a movable disk provided rotatably opposed to the fixed disk, wherein each movable pin is sequentially implanted on a plurality of rotation trajectories different from each of the fixed pins. When,
Classification means communicating with the discharge port for discharging the separated adhered matter at the outer peripheral portion of the combination of each fixed pin and each movable pin, and take-out means for taking out the recovered resin material having a desired particle size or more to the take-out port. Prepare,
A separation / classification / grain sizing means configured to separate and classify the resin material and the deposits by the impact crushing force between the fixed pins and the movable pins, and to size the resin material. An apparatus for collecting and granulating waste resin molded products.
廃棄樹脂成形品から付着物を分離し、樹脂材料を回収する装置であって、
処理対象を、廃農フィルムとし、この廃農フィルムを複数の破砕片に破砕する破砕手段と、
前記破砕された破砕片を複数の各被処理小片に粗砕する手段と、
前記被処理小片の供給投入口部に中心部を連通させた固定円盤上にあって、複数の回転軌跡上で各固定ピンを順次に植設した固定側研磨、整粒手段と、
前記固定円盤に対向して回転駆動可能に設けた可動円盤上にあって、前記各固定ピンとは異なる複数の回転軌跡上で各可動ピンを順次に植設した可動側研磨、整粒手段と、
前記各固定ピンと各可動ピンとの組み合せ外周部にあって、所望粒度以下に分離された付着物を任意に排出するための排出口に連通した分級手段、および所望粒度以上の回収樹脂材料を取出し口に取出す取出し手段とを備え、
前記各固定ピンと各可動ピンとの相互間で、衝撃摩砕力により樹脂材料と付着物を分離・分級し、前記樹脂材料を研磨、整粒し得るように構成した分離・分級・整粒手段とから成ることを特徴とする廃棄樹脂成形品の回収・造粒装置。
An apparatus for separating adhering matter from a waste resin molded product and recovering a resin material,
The processing target is a waste agricultural film, and a crushing means for crushing the waste agricultural film into a plurality of crushed pieces,
Means for coarsely crushing the crushed pieces into a plurality of small pieces to be treated,
Fixed-side polishing on a fixed disk having a central portion communicated with the supply input port of the small piece to be processed, and each fixed pin is sequentially planted on a plurality of rotation trajectories,
On a movable disk provided rotatably opposite to the fixed disk, movable-side polishing, in which each movable pin is sequentially implanted on a plurality of rotation trajectories different from each of the fixed pins, a sizing means,
Classification means, which is provided on the outer periphery of the combination of each fixed pin and each movable pin, and communicates with a discharge port for arbitrarily discharging deposits separated to a desired particle size or less, and a discharge port for collecting a collected resin material having a desired particle size or more Extraction means for extracting
Between each of the fixed pins and each of the movable pins, to separate and classify the resin material and the attached matter by the impact grinding force, and to grind the resin material, and to classify the particle size and separation, classifying and sizing means. An apparatus for collecting and granulating waste resin molded products, comprising:
前記分離・分級・整粒手段は、取出し口部と前記供給投入口部に連通したことを特徴とする請求項4又は5に記載の廃棄樹脂成形品の回収・造粒装置。The apparatus for collecting and granulating a waste resin molded product according to claim 4 or 5, wherein the separation / classification / granulation means communicates with the discharge port and the supply port. 請求項1〜3いずれか1項記載の方法により得られた前記回収樹脂材料25〜80wt%に対して、含有水分量を15wt%以内とし平均粒径20メッシュ以下のセルロース系破砕物20〜75wt%を混合し、加熱、練成し、スクリューをもって成形ダイへ押出し、この押出し生地を、内壁面にフッ素樹脂のシートを貼設又はフッ素樹脂をコーティングした成形ダイの成形部へ押出して所定の肉厚に成形し且つ前記成形部で徐冷して押出し成形すると共に、この成形板の押出し力に抗する抑制力を加えて前記成形部内の押出し生地の密度を高くしたことを特徴とする廃農フィルムを原料とした木質合成板の製造方法。To the recovered resin material 25~80Wt% obtained by the method of claim 1 any one of claims, cellulose crushed under an average particle size of 20 mesh or less and within 15 wt% moisture content 20 75 wt% is mixed, heated, kneaded, extruded with a screw into a forming die, and the extruded dough is extruded into a forming portion of a forming die in which a fluororesin sheet is stuck on the inner wall surface or a fluororesin is coated, and then extruded. molded into thick and slowly cooled in the molding section with extrusion, characterized in that to increase the density of the extruded dough in the forming section by adding a restraining force counteracting the extrusion force of the molded plate waste A method for producing a synthetic wood board using agricultural film as a raw material . 前記回収樹脂材料25〜80wt%に対して、含有水分量を15wt%以内とし平均粒径20メッシュ以下のセルロース系破砕物20〜75wt%を可塑材を添加せずに、混合し、加熱、練成する請求項7記載の廃農フィルムを原料とした木質合成板の製造方法。With respect to 25 to 80% by weight of the recovered resin material, 20 to 75% by weight of a cellulosic crushed material having an average particle size of 20 mesh or less with no more than a plasticizer was mixed, and the mixture was heated and kneaded. A method for producing a woody synthetic board using the waste agricultural film according to claim 7 as a raw material . 前記回収樹脂材料を20〜40wt%の軟質塩化ビニールとし、バージンの硬質塩化ビニール10〜30wt%、及び含有水分量を15wt%以内とし平均粒径80メッシュ以下の木粉40〜60wt%を混合した請求項7記載の廃農フィルムを原料とした木質合成板の製造方法。The recovered resin material and 20 to 40 wt% of soft vinyl chloride, virgin hard vinyl chloride 10 to 30 wt%, and 15 wt% or more in the average particle size 80 wood flour 40~60Wt% below the mesh moisture content A method for producing a synthetic wood board using the waste agricultural film according to claim 7 as a raw material . 前記回収樹脂材料が、ポリエチレンから成り含有水分量を15wt%以内とし平均粒径150メッシュ以下の木粉40〜60wt%に対し、ポリエチレンを10〜60wt%混合した請求項7記載の廃農フィルムを原料とした木質合成板の製造方法。The recovered resin material with respect to 15 wt% or less in the average particle size of 150 mesh or less of wood flour 40~60Wt% moisture content consists of polyethylene, Haino of claim 7, wherein a mixture 10 to 60 wt% of polyethylene A method for producing a wood composite board using a film as a raw material .
JP22531894A 1994-09-20 1994-09-20 A method and an apparatus for collecting and granulating a waste resin molded product, and a method for manufacturing a wooden synthetic board using the collected resin material. Expired - Lifetime JP3566348B2 (en)

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JP22531894A JP3566348B2 (en) 1994-09-20 1994-09-20 A method and an apparatus for collecting and granulating a waste resin molded product, and a method for manufacturing a wooden synthetic board using the collected resin material.
TW84107974A TW297794B (en) 1994-09-20 1995-08-01
KR1019950026396A KR100324034B1 (en) 1994-09-20 1995-08-24 Recovery material made of waste agricultural film, method and apparatus for recovering resin material from waste agricultural film
GB9603293A GB2310213B (en) 1994-09-20 1996-02-16 Method and apparatus for recovering resin material from industrial wastes of plastic film
US08/606,318 US5738286A (en) 1994-09-20 1996-02-23 Resin material recovered from industrial wastes of plastic film, method and apparatus for recovering resin material from industrial wastes of plastic film
NL1002520A NL1002520C2 (en) 1994-09-20 1996-03-04 Method and device for recovering resin material from industrial waste from plastic film.
PT101842A PT101842B (en) 1994-09-20 1996-03-05 RESILIENT MATERIAL RECOVERED FROM INDUSTRIAL RESIDUES OF PLASTIC FILMS, METHOD AND EQUIPMENT FOR THE RECOVERY OF RESIN MATERIAL FROM INDUSTRIAL WASTE OF PLASTIC FILM
DE1996108703 DE19608703A1 (en) 1994-09-20 1996-03-06 Plastic recovered from industrial waste of plastic film and method and device for recovering plastic from industrial waste from plastic film
FR9603068A FR2745730B1 (en) 1994-09-20 1996-03-08 RESINOUS MATERIAL OBTAINED FROM INDUSTRIAL WASTE OF PLASTIC FILMS, AS WELL AS THE PROCESS AND DEVICE IMPLEMENTED FOR OBTAINING SAME
BE9600247A BE1010083A3 (en) 1994-09-20 1996-03-20 Resineuse material obtained from industrial waste plastic film, and the method and device used for obtaining.

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JP22531894A JP3566348B2 (en) 1994-09-20 1994-09-20 A method and an apparatus for collecting and granulating a waste resin molded product, and a method for manufacturing a wooden synthetic board using the collected resin material.
GB9603293A GB2310213B (en) 1994-09-20 1996-02-16 Method and apparatus for recovering resin material from industrial wastes of plastic film
AU45618/96A AU713358B2 (en) 1996-02-20 1996-02-20 Resin material recovered from industrial wastes of plastic film, method and apparatus for recovering resin material from industrial wastes of plastic film
US08/606,318 US5738286A (en) 1994-09-20 1996-02-23 Resin material recovered from industrial wastes of plastic film, method and apparatus for recovering resin material from industrial wastes of plastic film
NL1002520A NL1002520C2 (en) 1994-09-20 1996-03-04 Method and device for recovering resin material from industrial waste from plastic film.
PT101842A PT101842B (en) 1994-09-20 1996-03-05 RESILIENT MATERIAL RECOVERED FROM INDUSTRIAL RESIDUES OF PLASTIC FILMS, METHOD AND EQUIPMENT FOR THE RECOVERY OF RESIN MATERIAL FROM INDUSTRIAL WASTE OF PLASTIC FILM
DE1996108703 DE19608703A1 (en) 1994-09-20 1996-03-06 Plastic recovered from industrial waste of plastic film and method and device for recovering plastic from industrial waste from plastic film
FR9603068A FR2745730B1 (en) 1994-09-20 1996-03-08 RESINOUS MATERIAL OBTAINED FROM INDUSTRIAL WASTE OF PLASTIC FILMS, AS WELL AS THE PROCESS AND DEVICE IMPLEMENTED FOR OBTAINING SAME
BE9600247A BE1010083A3 (en) 1994-09-20 1996-03-20 Resineuse material obtained from industrial waste plastic film, and the method and device used for obtaining.

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