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JP3628862B2 - Antioxidant liquid level sealing method - Google Patents
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JP3628862B2 - Antioxidant liquid level sealing method - Google Patents

Antioxidant liquid level sealing method Download PDF

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Publication number
JP3628862B2
JP3628862B2 JP36908597A JP36908597A JP3628862B2 JP 3628862 B2 JP3628862 B2 JP 3628862B2 JP 36908597 A JP36908597 A JP 36908597A JP 36908597 A JP36908597 A JP 36908597A JP 3628862 B2 JP3628862 B2 JP 3628862B2
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Prior art keywords
tank
liquid
protected
frame
volatile fluid
Prior art date
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Expired - Fee Related
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JP36908597A
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JPH11193089A (en
Inventor
利博 山手
雅朗 小田川
紀行 高橋
俊明 石瀬
淳 大宅
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Takenaka Corp
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Takenaka Corp
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/16Preventing evaporation or oxidation of non-metallic liquids by applying a floating layer, e.g. of microballoons

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)

Description

【0001】
【発明の属する技術分野】
本発明は、液面から浸入して液中に拡散する酸素を防いで、湧水、排水等に含まれる鉄イオン等の被酸化性物質の酸化を抑制し、配管及び系統機器の閉塞を防止する酸化防止液面シール法であって、特に、シール材として用いる不揮発性流体が槽乃至タンクの内壁面に付着しないようにした酸化防止液面シール法に関する。
【0002】
【従来の技術】
従来、湧水、排水等の送水系統では、槽乃至タンク内の貯水に水面から空気中の酸素が溶解浸入して水中深く拡散することから、水中に含まれている鉄イオン等の濃度が高い場合には当該成分がその酸素によって酸化されて、コロイド状の酸化物となり、これが送水用の配管等を閉塞して、大きな障害となることが度々あった。
そのため、従来は、次のような防止対策が講じられている。
▲1▼ 配管等を定期的にクリーニングする。
▲2▼ 薬品処理等によって水中の被酸化性物質を沈殿除去する。
▲3▼ 送水系統の槽乃至タンク内において、空気に触れる水面を次の(a) 〜(c) の遮蔽手段で覆い、空気中から浸入する酸素を遮断して、酸化を防止する。
(a) 油等(特開昭54‐81661号公報)
(b) 多数の浮子ボール等(特公平5‐79596 号公報)
(c) 浮屋根等(特開平2‐85188 号公報)
【0003】
【発明が解決しようとする課題】
しかし、これら防止対策には、未だ次のような種々の問題点がある。
▲1▼の場合、クリーニングに手間やコストがかかるだけでなく、その間、運転中の各種装置を停止させなければならないなど、施設の運用面に支障が生ずる。
▲2▼の場合、水中被酸化性物質に応じた添加制御技術及び薬品による二次汚染等の問題があり、特に、湧水等の量が多い場合や被酸化性物質の濃度が高い時は対策が困難である。また、薬品コストにも問題がある。
▲3▼の場合、(a) にあっては、水面の上下の変動に伴いその油等が槽乃至タンクの内周壁に付着するため、その油等の実効量が低下してシール性能が悪化し、かつ、内周壁や槽内の設備(梯子、配管等)が汚れてこれが貯水の水質を悪化させる原因となることがあり、更には、メンテナンスの手間もかかる。(b) にあっては、浮子ボール等の間の隙間で水面が空気に触れ、空気中から浸入する酸素を十分遮断できない欠点があり、また、(c) にあっては、急激な水の出入りや地震等で水面が揺動した際に、浮屋根等が部分的に空中に持ち上げられて、内側に空気を抱き込むことがあり、空気中から浸入する酸素を十分遮断できない欠点がある。
【0004】
本発明は、これらの問題点を解決しようとするものであり、槽乃至タンク内における湧水、排水等の液体の液面を、的確なシール性を有しかつ廉価で二次汚染等のないシール材により適正にシールして、液面から浸入する酸素を十分に阻止し、併せて、そのシール材として用いる不揮発性流体を、浮枠で囲うことにより該不揮発性流体が槽乃至タンクの内壁面に付着しないようにして、該付着による不揮発性流体の実効量の低下及びこれに伴うシール性能の悪化を防止して貯留液体の酸化を的確に阻止するとともに、内周壁の汚れ及びこれに伴う貯留液体の性状の悪化を防止しようとするものである。
【0005】
【課題を解決するための手段】
上記目的達成のため、請求項1の発明は、酸化防止を要する湧水、排水、その他の保護対象液体1を貯留する槽乃至タンク2内に、該槽乃至タンクの内周壁に遊嵌させてかつその保護対象液体1の液面に浮かせて浮枠3を内装し、該浮枠内にその保護対象液体1の液面を覆う不揮発性流体4による被膜5を設けたことを特徴とする。
【0006】
請求項2の発明は、酸化防止を要する湧水、排水、その他の保護対象液体1を貯留する槽乃至タンク2内に、該槽乃至タンクの内周壁に遊嵌させてかつその保護対象液体1の液面に浮かせて浮枠3を内装し、該浮枠内にその保護対象液体1の液面に浮遊させて多数の小さな浮子6を配するとともに、これらの浮子の隙間を不揮発性流体4により包覆したことを特徴とする。
【0007】
【発明の実施の形態】
図1は、請求項1の発明に係る実施の形態を示している。
図において、1は、酸化防止を要する湧水、排水等の保護対象液体、2は、該保護対象液体を貯留する角形の槽乃至タンク、3は、該槽乃至タンク内に保護対象液体の液面に浮かせて内装した浮枠、4は、該浮枠内に配した不揮発性流体、5は、保護対象液体の液面を覆った不揮発性流体による被膜である。
【0007】
浮枠3は、浮力を有する合成樹脂、木等の細い板を方形に組み、槽乃至タンク2の内周面に近接させて遊嵌した主枠8と、浮力を有する合成樹脂、木等で筒状に形成し、その槽乃至タンク内へ上方から真っ直ぐに挿入した給水管、排水管等の挿入配管7に近接させて遊嵌した補助枠9とから成り、いずれも上半部を空中に突出させて保護対象液体1中に浮かせるようにしている。
なお、主枠8は、槽乃至タンク2が大型の場合には図2に示すように複数の分割体から形成してもよい。これらの分割体は、連結させる必要はないが、場合により連結一体化させてもよい。
【0008】
浮枠内に配した被膜5用の不揮発性流体4としては、オイル、流動パラフィン等がよい。
【0009】
図3、図4は、請求項2の発明に係る実施の形態を示している。
図において、1は、酸化防止を要する湧水、排水等の保護対象液体、2は、該保護対象液体を貯留する角形の槽乃至タンク、3は、該槽乃至タンク内に保護対象液体の液面に浮かせて内装した浮枠、6は、該浮枠内にその保護対象液体の液面に浮遊させて配した多数の小さな浮子であり、これらの浮子の隙間を不揮発性流体4により包覆している。
【0010】
浮枠3は、浮力を有する合成樹脂、木等の断面円形の部材で方形の枠体10に形成し、該枠体を槽乃至タンク2の内周面に近接させて遊嵌し、かつ、上半部を空中に突出させて保護対象液体中に浮かせるようにしている。なお、枠体10は、中空の部材によるものでもよく、また、剛性の材質のものでも、或いは、柔軟性の材質のものでもよい。
【0011】
浮子6は、浮力を有する合成樹脂、木等により半球状に形成したものである。この場合、球体のように回転することがないので、回転によって空気が取り込まれるようなことはない。なお、中空のものでも、中実のものでもよい。また、剛性の材質のものでも、或いは、柔軟性の材質のものでもよい。回転等によって空気が取り込まれるようなことがなけれれば、球状、その他の形状としてもよいことは勿論である。
これらの浮子の隙間を包覆する不揮発性流体4は、図1の場合と同様、オイル、流動パラフィン等がよい。
【0013】
実験によれば、いずれの場合にあっても、浮枠3により不揮発性流体4が槽乃至タンク2の内周壁に付着するのを防止でき、しかも、液面を90%以上シールすることができ、保護対象液体1が約10〜20mg/lの鉄イオンを含み透視度10〜35cmで赤水状態を呈する水を、透視度50cm以上の清澄な水質に改善できるとともに、鉄イオンがコロイド及びその集合体となって管壁に付着する作用を抑制でき、配管系統の各種機器等の閉塞防止効果を得ることができた。
【0012】
【発明の効果】
請求項1及び請求項2の発明によれば、槽乃至タンク2内において、湧水、排水等の保護対象液体1に対する液面のシールに、シール性のよい不揮発性流体4を使用しているが、この不揮発性流体4は、浮枠3の囲成内部に配されているので、該浮枠3により遮断されて槽乃至タンク2の内壁面には達せず、したがって、その保護対象液体1の液面が上下に変動してもその槽乃至タンク2の内壁面には付着せず、該付着による不揮発性流体4の実効量の低下も、これによるシール性能の悪化も生じず、また、内周壁を汚すことも、これがその保護対象液体1の性状を悪化させることもない。
そして、請求項1の発明によれば、不揮発性流体4の被膜5により、また、請求項2の発明によれば、多数の浮子6とそれらの浮子の隙間を包覆する不揮発性流体4とにより、湧水、排水等の保護対象液体1の液面を90%以上的確にシールすることができ、しかも、それらは液面が揺動してもシールが破れることなく液面の変化に追随するとともに、その揺動を不揮発性流体4の粘性により抑制して空気を抱き込むようなことはなく、したがって、その保護対象液体1に液面から浸入しようとする酸素を十分に阻止することができ、その保護対象液体1に含まれる鉄イオン等被酸化性物質の酸化を適正に抑制できて、配管及び系統機器の閉塞を十分に防止することができる。勿論、施設のクリーニング等を必要とせず、そのための手間や経費はかからず、運転中の系統機器を停止させる必要もないから施設の運用面で支障が生じることもない。
更に、浮枠3、浮子6としては、合成樹脂製、木製等のものを、また、不揮発性流体4としては、オイル、流動パラフィン等を用いることができて、貯留液体の二次汚染等が生じることはなく、コストを低く抑えることができる。
【図面の簡単な説明】
【図1】請求項1の発明に係る実施の形態を示す縦断側面図である。
【図2】同実施の形態における変形例を示す截断斜視図である。
【図3】請求項2の発明に係る実施の形態を示す要部の縦断側面図である。
【図4】同実施の形態における要部の截断斜視図である。
【符号の説明】
1…保護対象液体 2…槽乃至タンク
3…浮枠 4…不揮発性流体
5…被膜 6…浮子
7…挿入配管 8…主枠
9…補助枠 10…枠体
[0001]
BACKGROUND OF THE INVENTION
The present invention prevents oxygen from entering the liquid surface and diffusing into the liquid, suppressing oxidation of oxidizable substances such as iron ions contained in spring water, drainage, etc., and preventing clogging of piping and system equipment In particular, the present invention relates to an antioxidant liquid level sealing method in which a non-volatile fluid used as a sealing material does not adhere to the inner wall surface of a tank or a tank.
[0002]
[Prior art]
Conventionally, in water supply systems such as spring water and drainage, oxygen in the air dissolves and infiltrates from the water surface into the water stored in the tank or tank and diffuses deeply into the water, so the concentration of iron ions etc. contained in the water is high In some cases, the component is oxidized by the oxygen to form a colloidal oxide, which often clogs the water supply piping and the like, which is a major obstacle.
Therefore, conventionally, the following preventive measures have been taken.
(1) Periodically clean the piping.
(2) Precipitate and remove oxidizable substances in water by chemical treatment.
(3) In the tank or tank of the water supply system, the surface of water that comes into contact with air is covered with the following shielding means (a) to (c) to block oxygen entering from the air and prevent oxidation.
(A) Oil, etc. (Japanese Patent Laid-Open No. 54-81661)
(B) Many floating balls, etc. (Japanese Patent Publication No. 5-79596)
(C) Floating roof, etc. (Japanese Patent Laid-Open No. 2-85188)
[0003]
[Problems to be solved by the invention]
However, these preventive measures still have various problems as follows.
In the case of {circle around (1)}, not only the cleaning is troublesome and expensive, but also the various operational devices must be stopped during that time, which impedes the operation of the facility.
In the case of (2), there are problems such as addition control technology and chemical secondary contamination according to the oxidizable substances in water, especially when the amount of spring water is large or the concentration of oxidizable substances is high. Countermeasures are difficult. There is also a problem with chemical costs.
In the case of (3), in (a), since the oil etc. adheres to the inner wall of the tank or tank as the water surface fluctuates up and down, the effective amount of the oil etc. decreases and the sealing performance deteriorates. In addition, the inner peripheral wall and the equipment in the tank (ladder, piping, etc.) may become dirty, which may cause the quality of the stored water to deteriorate, and it will also require maintenance work. In (b), there is a defect that the water surface touches the air in the gap between the float balls and the like, and oxygen entering from the air cannot be sufficiently blocked. When the water surface fluctuates due to entry / exit, earthquake, etc., the floating roof or the like is partially lifted into the air, and air may be embraced inside, and there is a disadvantage that oxygen entering from the air cannot be sufficiently blocked.
[0004]
The present invention is intended to solve these problems. The liquid level of spring water, drainage, etc. in a tank or tank has an accurate sealing property and is inexpensive and free from secondary contamination. Properly seal with a sealing material to sufficiently prevent oxygen entering from the liquid surface, and at the same time, the non-volatile fluid used as the sealing material is surrounded by a floating frame so that the non-volatile fluid is contained in the tank or tank. It prevents the liquid from adhering to the wall surface, prevents the effective amount of the non-volatile fluid from lowering due to the adhesion and the accompanying deterioration of the sealing performance and accurately prevents the stored liquid from being oxidized. It is intended to prevent deterioration of the properties of the stored liquid.
[0005]
[Means for Solving the Problems]
In order to achieve the above object, the invention of claim 1 is loosely fitted in a tank or tank 2 for storing spring water, drainage, or other liquid to be protected 1 that needs to be prevented from oxidation, on the inner peripheral wall of the tank or tank. In addition, a floating frame 3 is floated on the liquid surface of the liquid 1 to be protected, and a coating 5 made of a nonvolatile fluid 4 covering the liquid surface of the liquid 1 to be protected is provided in the floating frame.
[0006]
According to the second aspect of the present invention, the protection target liquid 1 is loosely fitted to the inner peripheral wall of the tank or tank in the tank or tank 2 for storing spring water, drainage, or other protection target liquid 1 that requires oxidation prevention. A floating frame 3 is placed inside the floating frame, and a number of small floats 6 are arranged in the floating frame so as to float on the liquid surface of the liquid 1 to be protected. It is characterized by being covered by.
[0007]
DETAILED DESCRIPTION OF THE INVENTION
FIG. 1 shows an embodiment according to the invention of claim 1.
In the figure, 1 is a protection target liquid such as spring water or drainage that needs to be oxidized, 2 is a rectangular tank or tank that stores the protection target liquid, and 3 is a liquid of the protection target liquid in the tank or tank. A floating frame 4 is floated on the surface, 4 is a non-volatile fluid disposed in the floating frame, and 5 is a non-volatile fluid film covering the liquid surface of the liquid to be protected.
[0007]
The buoyant frame 3 is composed of a main frame 8 in which a thin plate made of synthetic resin, wood or the like having a buoyancy is squarely assembled and in close proximity to the inner peripheral surface of the tank or tank 2, and a synthetic resin having buoyancy, wood, etc. It consists of an auxiliary frame 9 formed in a cylindrical shape and loosely fitted close to the insertion pipe 7 such as a water supply pipe or drainage pipe inserted straight from above into the tank or tank, and the upper half is in the air It protrudes and floats in the liquid 1 to be protected.
The main frame 8 may be formed from a plurality of divided bodies as shown in FIG. 2 when the tank or tank 2 is large. These divided bodies do not need to be connected, but may be connected and integrated in some cases.
[0008]
As the non-volatile fluid 4 for the coating 5 disposed in the floating frame, oil, liquid paraffin or the like is preferable.
[0009]
3 and 4 show an embodiment according to the second aspect of the present invention.
In the figure, 1 is a protection target liquid such as spring water or drainage that needs to be oxidized, 2 is a rectangular tank or tank that stores the protection target liquid, and 3 is a liquid of the protection target liquid in the tank or tank. Floating frame 6, which is floated on the surface, 6 is a large number of small floats arranged on the liquid surface of the liquid to be protected in the floating frame, and the non-volatile fluid 4 covers the gaps between these floats. doing.
[0010]
The floating frame 3 is formed in a rectangular frame 10 with a circular cross-section member such as a synthetic resin having a buoyancy, wood, etc., and the frame is loosely fitted close to the inner peripheral surface of the tank or the tank 2, and The upper half protrudes into the air and floats in the liquid to be protected. The frame 10 may be a hollow member, a rigid material, or a flexible material.
[0011]
The float 6 is formed in a hemispherical shape from a synthetic resin having buoyancy, wood or the like. In this case, since it does not rotate like a sphere, air is not taken in by rotation. It may be hollow or solid. Further, a rigid material or a flexible material may be used. Of course, if the air is not taken in by rotation or the like, it may have a spherical shape or other shapes.
The non-volatile fluid 4 that covers the gaps between these floats is preferably oil, liquid paraffin, or the like as in the case of FIG.
[0013]
According to the experiment, in any case, the floating frame 3 can prevent the non-volatile fluid 4 from adhering to the inner peripheral wall of the tank or the tank 2, and the liquid level can be sealed by 90% or more. The liquid 1 to be protected contains about 10 to 20 mg / l of iron ions and exhibits a red water state with a transparency of 10 to 35 cm to a clear water quality with a transparency of 50 cm or more. The action of becoming a body and adhering to the pipe wall could be suppressed, and the effect of preventing blockage of various devices in the piping system could be obtained.
[0012]
【The invention's effect】
According to the first and second aspects of the present invention, the non-volatile fluid 4 having a good sealing property is used in the tank or the tank 2 to seal the liquid surface against the liquid 1 to be protected such as spring water and drainage. However, since the non-volatile fluid 4 is disposed inside the floating frame 3, the non-volatile fluid 4 is blocked by the floating frame 3 and does not reach the inner wall surface of the tank or the tank 2. Even if the liquid level fluctuates up and down, it does not adhere to the inner wall surface of the tank or tank 2, and the effective amount of the non-volatile fluid 4 due to the adhesion does not deteriorate, and the sealing performance does not deteriorate. The inner peripheral wall is not soiled, and this does not deteriorate the properties of the liquid 1 to be protected.
According to the invention of claim 1, the coating 5 of the non-volatile fluid 4, and according to the invention of claim 2, the non-volatile fluid 4 covering a large number of floats 6 and the gaps between these floats Therefore, it is possible to accurately seal the liquid level of the liquid 1 to be protected, such as spring water and drainage, by 90% or more, and they can follow the change of the liquid level without breaking the seal even if the liquid level fluctuates. At the same time, the oscillation is not suppressed by the viscosity of the non-volatile fluid 4 and air is not embraced. Therefore, it is possible to sufficiently prevent oxygen from entering the liquid 1 to be protected from the liquid surface. In addition, the oxidation of the oxidizable substance such as iron ions contained in the protection target liquid 1 can be appropriately suppressed, and the blockage of the piping and the system equipment can be sufficiently prevented. Of course, there is no need to clean the facility, so it does not take time and expense, and there is no need to stop the operating system equipment, so there is no problem in the operation of the facility.
Furthermore, the floating frame 3 and the float 6 can be made of synthetic resin, wood, etc., and the non-volatile fluid 4 can be made of oil, liquid paraffin, etc. It does not occur and costs can be kept low.
[Brief description of the drawings]
1 is a longitudinal side view showing an embodiment according to the invention of claim 1;
FIG. 2 is a cut perspective view showing a modification of the embodiment.
FIG. 3 is a longitudinal sectional side view of an essential part showing an embodiment according to the invention of claim 2;
FIG. 4 is a cutaway perspective view of a main part in the same embodiment.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1 ... Liquid to be protected 2 ... Tank or tank 3 ... Floating frame 4 ... Non-volatile fluid 5 ... Coating 6 ... Float 7 ... Insertion pipe 8 ... Main frame 9 ... Auxiliary frame 10 ... Frame

Claims (2)

酸化防止を要する湧水、排水、その他の保護対象液体1を貯留する槽乃至タンク2内に、該槽乃至タンクの内周壁に遊嵌させてかつその保護対象液体1の液面に浮かせて浮枠3を内装し、該浮枠内にその保護対象液体1の液面を覆う不揮発性流体4による被膜5を設けたことを特徴とする酸化防止液面シール法。In a tank or tank 2 that stores spring water, drainage, or other liquid to be protected that requires oxidation prevention, it is loosely fitted to the inner peripheral wall of the tank or tank and floats on the liquid surface of the liquid to be protected 1 An antioxidant liquid level sealing method characterized by comprising a frame 3 and a coating 5 made of a non-volatile fluid 4 covering the surface of the liquid 1 to be protected in the floating frame. 酸化防止を要する湧水、排水、その他の保護対象液体1を貯留する槽乃至タンク2内に、該槽乃至タンクの内周壁に遊嵌させてかつその保護対象液体1の液面に浮かせて浮枠3を内装し、該浮枠内にその保護対象液体1の液面に浮遊させて多数の小さな浮子6を配するとともに、これらの浮子の隙間を不揮発性流体4により包覆したことを特徴とする酸化防止液面シール法。In a tank or tank 2 that stores spring water, drainage, or other liquid to be protected that requires oxidation prevention, it is loosely fitted to the inner peripheral wall of the tank or tank and floats on the liquid surface of the liquid to be protected 1 An interior of the frame 3 is arranged, and a large number of small floats 6 are arranged in the floating frame so as to float on the liquid surface of the liquid 1 to be protected, and gaps between these floats are covered with a non-volatile fluid 4. Antioxidant liquid level sealing method.
JP36908597A 1997-12-26 1997-12-26 Antioxidant liquid level sealing method Expired - Fee Related JP3628862B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP36908597A JP3628862B2 (en) 1997-12-26 1997-12-26 Antioxidant liquid level sealing method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP36908597A JP3628862B2 (en) 1997-12-26 1997-12-26 Antioxidant liquid level sealing method

Publications (2)

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JPH11193089A JPH11193089A (en) 1999-07-21
JP3628862B2 true JP3628862B2 (en) 2005-03-16

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Publication number Priority date Publication date Assignee Title
JP2008119670A (en) * 2006-11-15 2008-05-29 Fuji Electric Holdings Co Ltd Sodium bisulfite storage equipment
CN101915309A (en) * 2010-07-23 2010-12-15 北京博瑞特自动计量系统股份有限公司 Steel floating roof opening sealing device used for mounting level instrument
CN101913471A (en) * 2010-07-23 2010-12-15 北京博瑞特自动计量系统股份有限公司 Aluminous floating disc opening sealing device for mounting liquid level apparatus
CN116116353A (en) * 2023-01-10 2023-05-16 杭州大地化工有限公司 Reaction kettle
CN119389584A (en) * 2024-12-31 2025-02-07 安徽鳄鱼尼卡新材料有限公司 A water-based solvent storage barrel

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