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JP3645331B2 - Method for manufacturing enamel member - Google Patents
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JP3645331B2 - Method for manufacturing enamel member - Google Patents

Method for manufacturing enamel member Download PDF

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Publication number
JP3645331B2
JP3645331B2 JP27309495A JP27309495A JP3645331B2 JP 3645331 B2 JP3645331 B2 JP 3645331B2 JP 27309495 A JP27309495 A JP 27309495A JP 27309495 A JP27309495 A JP 27309495A JP 3645331 B2 JP3645331 B2 JP 3645331B2
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Japan
Prior art keywords
transfer sheet
photographic transfer
photographic
enamel
stage
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP27309495A
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Japanese (ja)
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JPH09111477A (en
Inventor
国寿 斎藤
忠則 松尾
光夫 花村
洋 郷古
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Hitachi Building Systems Co Ltd
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Hitachi Building Systems Co Ltd
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Priority to JP27309495A priority Critical patent/JP3645331B2/en
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  • Cage And Drive Apparatuses For Elevators (AREA)
  • Glass Compositions (AREA)

Description

【0001】
【発明の属する技術分野】
本発明は表面にカラー転写シートを焼成して成るホーロー部材の製造方法に関する。
【0002】
【従来の技術】
一般に、ホーローの持つ堅牢さと意匠的な優位性を活かし、エレベーター用乗かご側板等の種々の分野でホーロー部材が使用されており、例えば、特願平3−332816号にはホーロー板を用いたエレベーター用乗かご側板の製造方法が提案されている。
従来のこの種のホーロー部材は、所定厚さの素地金属板を製缶作業によって所定の形状に成し、その表面の脱脂および酸洗いなどの表面処理を行なった後、ニッケルメッキを施し、その後、三段階の焼成作業を繰り返していた。この三段階の焼成作業とは、先ず、一段階目としてニッケルメッキを施した素地金属板の表面に釉薬を下塗りし乾燥させて焼成し、二段階目として釉薬を中塗りし乾燥させて焼成し、三段階目として釉薬を上塗りし乾燥させて焼成するものである。
【0003】
一方、特開平5−318990号公報には、陶器等の表面の美観性および意匠性を高めるために、陶器等の表面にカラーの写真転写シートを焼成するようにしたものが記載されている。
【0004】
【発明が解決しようとする課題】
本件発明者等は、ホーロー部材に高級意匠感を与えるために、ホーロー部材表面にカラーの写真転写シートを焼成することを検討した。しかしながら、これまでの経験に基づいて、ホーロー部材表面に写真転写シートを貼付け、乾燥後に1時間あたり100°Cの温度上昇率で4〜5時間かけて400〜550°Cまで焼成温度を上昇させて焼成し、一旦常温に戻した後、分のオーダーで650〜800°Cまで急激に温度上昇させて本焼成していたが、極め細かい写真画像を再現できないことが分かった。
【0005】
本発明の目的とするところは、写真転写シートを用いて極め細かいカラー写真画像を再現できるようにしたホーロー部材の製造方法を提供するにある。
【0006】
【課題を解決するための手段】
本発明は上記目的を達成するために、素地部材の表面にホーロー層を焼成し、その上に写真転写シートを貼付け、乾燥させて焼成させるホーロー部材の製造方法において、上記写真転写シートを貼付ける貼付け部を、白色のコーティングカバーを施して白色にした後、上記写真転写シートの焼成を、緩やかな温度上昇特性を持つ第一段階焼成と、常温に戻すことなくこの第一段階焼成に連続して上記第一段階焼成よりも急速で高い温度に上昇させる第二段階焼成とで行なうようにしたことを特徴とする。
【0007】
本発明によるホーロー部材の製造方法は、上述の素地部材に白色のカバーコーティングを施した上に、写真転写シートを焼成するようにしたため、カバーコーティングの影響を受けずに写真転写シートの色を確実に再現して極め細かな絵や模様等を転写することができるようになった。
【0008】
【発明の実施の形態】
以下、本発明の実施の形態を図面によって説明する。図1は本発明の一実施の形態によるホーロー部材としてホーロー板の製造方法を示すフローチャートである。図中、左側は写真転写シートの製造工程を示し、右側はホーロー板の製造工程と、その後のホーロー板へ写真転写シートを焼成する工程を示している。先ず、ホーロー板の製作について説明すると、工程S1で所定厚さ、例えば0.35〜0.5mmの素地金属板を製缶作業によって所定の形状に成し、工程S2でその表面の脱脂および酸洗いなどの表面処理を行なった後、工程S3でニッケルメッキを施し、その後、一段階目の焼成作業として、ニッケルメッキを施した素地金属板の表面に工程S4でグランドコーティングの釉薬を下塗りし、工程S5で乾燥させてから工程S6として約800°Cで焼成する。通常、このグランドコーティングは黒色である。続いて二段階目の焼成作業として、工程S7で白色のコーティングカバーの釉薬を中塗りし工程S8として乾燥させてから、工程S9として約800°C5〜10分間焼成する。
【0009】
一方、写真転写シートの製造工程は、予め工程S20として写真プリントもしくはネガあるいはポジフィルムを準備し、これを工程S21でトリミング色分解する。つまり、写真プリントもしくはネガあるいはポジフィルムとして準備された原画を色の三原色(イエロー、マゼンダ、シアン)とブラックに色分解する。その後、工程S22でトリミング色分解して製作した製版を得るが、これは原画の色数に関係なくイエロー版、マゼンダ版、シアン版、ブラック版の一律4枚となり、これらの重なりによって原画の色を再現する。顔料としてイエロー版はプラセオジウム、マゼンダ版は包金、シアン版はコバルト、ブラック版はマンガンを混ぜて使用し、これらを保持する薄膜としてポリエステルフィルムを用い、これら各製版を印刷して工程S23で写真転写シートを得る。次に、工程S24として写真転写シートの表面に、例えばウレタンをコーティングして写真転写シート保護膜を形成し、写真転写シートが完成する。この写真転写シート保護膜は、その後の写真転写シートの表面の傷付きを防止するので、後述する全工程終了後における写真転写シートの表面をより美しく、原画を忠実に再現するのに寄与する。
【0010】
次に、工程S10に示すように白色のコーティングカバー4によってホーロー板上を白色にした貼付け部3に写真転写シートを水貼りし24時間乾燥させる。その後、工程S11として写真転写シート用焼成を行なう。この写真転写シート用焼成工程は、少なくとも二段階の温度上昇特性で常温に戻すことなくほぼ連続して行なうのが特徴である。つまり、図2に示すように、写真転写シート用焼成工程における第一段階焼成の温度上昇特性1は、上述した写真転写シートを構成するフィルムやインクが完全に溶解するものであり、写真転写シート用焼成工程における第二段階焼成の温度上昇特性2は、写真転写シートが焼き上がりガラス化させるものである。より具体的には、第一段階焼成においては焼成温度を急激に上昇させるのではなく、例えば、5時間かけて500〜650°Cまで時間当たり100°C程度の上昇率で徐々に上昇させる温度上昇特性とし、続く第二段階焼成においては常温に戻すことなくほぼ連続して第一段階焼成の温度上昇特性よりも急激な温度上昇特性、例えば1時間で700〜800°Cまで上昇させる温度上昇特性としている。この第二段階焼成の上昇温度は、エレベータ用側板として一般に使用される素地金属板の厚みが0.5mm1.6mmであるなら740〜760°Cとすれば良く、素地金属板の条件を考慮して決定すると良い。
【0011】
その後、工程S12で写真転写シートの貼付け部3を除いて表面の仕上げ指定色に対応する釉薬を上塗りし、工程S13として乾燥させてから工程S14として約720〜740°Cで約10分間焼成する。その後、工程S15あるいは上述した写真転写シート用焼成工程後にフラッキスコーティングを行なうが、これはホーロー板と同じ艶を確保し、また写真転写シートの耐摩耗性を向上させる目的で、透明の釉薬を写真転写シート部の表面にコーティングするものである。このとき、既にウレタンをコーティングした写真転写シートの保護膜は上述の写真転写シート用焼成工程で融解し蒸発しており、写真転写シートの表面はフラッキスコーティングによって艶出しされ耐摩耗性が与えられて、美しさを保持することができる。
【0012】
この写真転写シート用焼成工程により、写真転写シートを構成するフィルムやインクを完全に溶解させると共に、粒子状の状態からガラス化させて写真転写シートを焼き上げることができ、写真転写シートを定着させると共に、その極め細かな絵や模様等を再現できることが実験によって明らかになった。また上述した写真転写シート用焼成工程を行なわない場合、内部にクラックが発生し写真転写シートの美しさを損なう場合があった。これは、写真転写シート用焼成工程における第一段階焼成の上昇温度付近で焼成を止めて常温に戻してしまうと、ホーロー釉薬が丁度軟化し始める温度領域で素地金属薄板が既に膨張したのが、常温に戻されて素地金属薄板の膨張が元に戻るとき、ホーロー層が押しつぶされる現象が発生するためと考えられる。この現象は、第一段階焼成の上昇温度付近では表面に現れず、例えば、第二段階焼成の温度上昇を与えることなく工程を進めて工程S16の本焼成で約800度の温度を加えた場合、ホーロー層の最上面が融けて内部にクラックが現れてくるが、上述したように少なくとも二段階の温度上昇特性で常温に戻すことなくほぼ連続して行なう写真転写シート用焼成工程によってクラックの発生を防止することができるようになった。しかも、ホーロー板における写真転写シートの貼付け部1aを白色のコーティングカバー4としたため、写真転写シートは一層忠実に原画の色を再現することができ、非常に美しい写真転写シート付きホーロー板を得ることができるようになった。
【0013】
尚、上述の実施の形態では、エレベータ用側板となるホーロー板に写真転写シートを焼成したが、板状体に限らず他の形状のホーロー部材に採用することができる。
【0014】
【発明の効果】
以上説明したように本発明によるホーロー部材の製造方法は、写真転写シートを貼付ける下地のコーティングカバーとして白色のものを用いたため、写真転写シートは一層忠実に原画の色や極め細かな絵や模様等を再現することができ、非常に美しい転写を行なうことができるようになった。
【図面の簡単な説明】
【図1】本発明の一実施の形態によるホーロー部材の製造方法による製造工程を示すフローチャートである。
【図2】図1に示したホーロー部材の製造方法による写真転写シート用焼成工程の温度上昇特性図である。
【符号の説明】
1,2 温度上昇特性
3 貼付け部
4 コーティングカバー
S11 写真転写シート用焼成工程
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a method for manufacturing a hollow member formed by firing a color transfer sheet on the surface.
[0002]
[Prior art]
In general, enamel members are used in various fields such as elevator car side plates, taking advantage of the robustness and design superiority of enamels. For example, enamel plates are used in Japanese Patent Application No. 3-332816. A method of manufacturing an elevator car side plate has been proposed.
This type of conventional enamel member is made by forming a base metal plate having a predetermined thickness into a predetermined shape by a can making operation, performing surface treatment such as degreasing and pickling on the surface, and then performing nickel plating, The three-stage firing operation was repeated. The three-stage firing operation is as follows. First, the surface of the nickel-plated base metal plate is first coated with a glaze and dried, and then the second stage is coated with a glaze and dried. In the third stage, the glaze is overcoated, dried and baked.
[0003]
On the other hand, Japanese Patent Application Laid-Open No. 5-318990 describes that a color photographic transfer sheet is baked on the surface of a pottery or the like in order to enhance the aesthetics and design of the surface of the pottery or the like.
[0004]
[Problems to be solved by the invention]
The inventors of the present invention examined firing a color photographic transfer sheet on the surface of a hollow member in order to give a high-class design feeling to the hollow member. However, based on past experience, a photographic transfer sheet is pasted on the enamel member surface, and after drying, the firing temperature is increased to 400 to 550 ° C. over 4 to 5 hours at a temperature increase rate of 100 ° C. per hour. After firing and returning to room temperature, the temperature was rapidly increased to 650 to 800 ° C. on the order of minutes, and the main firing was carried out. However, it was found that an extremely fine photographic image could not be reproduced.
[0005]
An object of the present invention is to provide a method for producing an enamel member that can reproduce an extremely fine color photographic image using a photographic transfer sheet.
[0006]
[Means for Solving the Problems]
In order to achieve the above object, the present invention provides a method for producing a hollow member in which a hollow layer is fired on the surface of a substrate member, a photographic transfer sheet is pasted thereon, dried and fired, and the photographic transfer sheet is pasted. After applying the white coating cover to the pasting part to make it white, the above-mentioned photographic transfer sheet is fired in a first-stage firing having a moderate temperature rise characteristic and this first-stage firing without returning to room temperature. Thus, the second stage firing is performed at a temperature higher than that of the first stage firing .
[0007]
In the method for manufacturing an enamel member according to the present invention, the above-mentioned base member is coated with a white cover coating, and the photographic transfer sheet is baked, so that the color of the photographic transfer sheet is ensured without being affected by the cover coating. It is now possible to reproduce very fine pictures and patterns.
[0008]
DETAILED DESCRIPTION OF THE INVENTION
Embodiments of the present invention will be described below with reference to the drawings. FIG. 1 is a flowchart showing a method for manufacturing a hollow plate as a hollow member according to an embodiment of the present invention. In the figure, the left side shows a photographic transfer sheet manufacturing process, and the right side shows a hollow plate manufacturing process and a subsequent step of baking the photographic transfer sheet on the enamel plate. First, the production of the enamel plate will be described. In step S1, a base metal plate having a predetermined thickness, for example, 0.35 to 0.5 mm is formed into a predetermined shape by a can making operation, and in step S2, the surface is degreased and acidified. After performing surface treatment such as washing, nickel plating is performed in step S3, and then, as a first stage baking operation, a ground coating glaze is primed on the surface of the nickel-plated base metal plate in step S4, After drying in step S5, baking is performed at about 800 ° C. as step S6. This ground coating is usually black. Then the fired working second stage, is dried as a step S8 Shi coating medium glaze white coating covers at step S7, the Firing 5 to 10 minutes at about 800 ° C as a step S9.
[0009]
On the other hand, in the photographic transfer sheet manufacturing process, a photographic print or negative or positive film is prepared in advance as step S20, and this is subjected to trimming color separation in step S21. In other words, an original image prepared as a photographic print, negative or positive film is separated into three primary colors (yellow, magenta, cyan) and black. Thereafter, in step S22, trimming color separation is performed to obtain a plate making, which is a uniform four sheets of yellow, magenta, cyan, and black plates regardless of the number of colors of the original image. To reproduce. The yellow plate is praseodymium, the magenta plate is a metallurgy, the cyan plate is cobalt, the black plate is mixed with manganese, the polyester film is used as a thin film to hold them, and each plate is printed and photographed in step S23. Obtain a transfer sheet. Next, in step S24, for example, urethane is coated on the surface of the photographic transfer sheet to form a photographic transfer sheet protective film, thereby completing the photographic transfer sheet. Since this photographic transfer sheet protective film prevents the surface of the photographic transfer sheet from being scratched thereafter, the photographic transfer sheet protective film contributes to more beautiful reproduction of the surface of the photographic transfer sheet after the completion of all the steps described below and faithful reproduction of the original image.
[0010]
Next, as shown in step S10, the photographic transfer sheet is affixed with water to the affixing portion 3 where the enamel plate is whitened by the white coating cover 4, and dried for 24 hours. Then, baking for photographic transfer sheets is performed as Step S11. This photographic transfer sheet firing step is characterized by being carried out almost continuously without returning to room temperature with at least two stages of temperature rise characteristics. That is, as shown in FIG. 2, the temperature increase characteristic 1 of the first stage baking in the photographic transfer sheet baking step is that the film and ink constituting the photographic transfer sheet described above are completely dissolved. The temperature rise characteristic 2 of the second stage baking in the baking process is that the photographic transfer sheet is baked and vitrified. More specifically, in the first stage firing, the firing temperature is not rapidly increased, but is gradually increased at a rate of about 100 ° C. per hour from 500 to 650 ° C. over 5 hours, for example. In the subsequent second stage firing, the temperature rise characteristic is substantially more rapid than the temperature rise characteristic of the first stage firing in the subsequent second stage firing, for example, a temperature rise that increases to 700 to 800 ° C. in one hour. It is characteristic . Increasing the temperature of the second stage calcination of this may be the thickness of the base metal plate 0.5mm and a 1.6mm in which Great 740~ 760 ° C that is commonly used as the side plate elevators, the condition of the base metal plate It is good to decide in consideration of
[0011]
Thereafter, overcoated with a glaze that corresponds to the finishing designated color of the surface except the attaching portion 3 adhered Photo transfer sheet in step S12, about 10 minutes after drying the step S13 as a step S14 at approximately seven hundred twenty to seven hundred forty ° C or Bake. Thereafter, a flux coating is performed after the step S15 or the above-described calcination process for the photographic transfer sheet. For the purpose of ensuring the same gloss as the enamel plate and improving the abrasion resistance of the photographic transfer sheet, a transparent glaze is used. The surface of the photographic transfer sheet is coated. At this time, the protective film of the photographic transfer sheet already coated with urethane is melted and evaporated in the above-mentioned baking process for the photographic transfer sheet, and the surface of the photographic transfer sheet is polished by the flax coating to provide wear resistance. And can retain beauty.
[0012]
This baking process for a photographic transfer sheet completely dissolves the film and ink constituting the photographic transfer sheet, and also allows the photographic transfer sheet to be baked by vitrification from a particulate state, while fixing the photographic transfer sheet Experiments have revealed that it is possible to reproduce such fine pictures and patterns. Further, when the above-described calcination process for a photographic transfer sheet is not performed, cracks may occur inside and the beauty of the photographic transfer sheet may be impaired. This is because the base metal sheet has already expanded in the temperature range where the enamel glaze just begins to soften when the baking is stopped near the rising temperature of the first stage baking in the baking process for the photographic transfer sheet and returned to room temperature. This is considered to be due to the phenomenon that the enamel layer is crushed when the expansion of the base metal sheet is restored to the normal temperature. This phenomenon does not appear on the surface in the vicinity of the rising temperature of the first stage baking, for example, when the process is advanced without increasing the temperature of the second stage baking and a temperature of about 800 degrees is applied in the main baking of step S16. The top surface of the enamel layer melts and cracks appear inside. However, as described above, cracks are generated by the baking process for photographic transfer sheets that is performed almost continuously without returning to room temperature with at least two stages of temperature rise characteristics. Can now be prevented. Moreover, since the white transfer cover 4 is used as the photographic transfer sheet affixing portion 1a on the enamel plate, the photo transfer sheet can reproduce the color of the original image more faithfully and obtain a very beautiful enamel plate with a photo transfer sheet. Can now.
[0013]
In the above-described embodiment, the photographic transfer sheet is fired on the enamel plate serving as the elevator side plate. However, the photo transfer sheet is not limited to the plate-like body, and can be employed for enamel members having other shapes.
[0014]
【The invention's effect】
As described above, the enamel member manufacturing method according to the present invention uses a white cover as a base coating cover on which the photographic transfer sheet is pasted, so that the photographic transfer sheet more faithfully reproduces the color of the original image and the finely detailed picture or pattern. Etc. can be reproduced, and a very beautiful transfer can be performed.
[Brief description of the drawings]
FIG. 1 is a flowchart showing a manufacturing process according to a method for manufacturing a hollow member according to an embodiment of the present invention.
FIG. 2 is a temperature rise characteristic diagram of a photographic transfer sheet baking step according to the enamel member manufacturing method shown in FIG. 1;
[Explanation of symbols]
1, 2 Temperature rise characteristics 3 Pasting part 4 Coating cover S11 Baking process for photographic transfer sheet

Claims (1)

素地部材の表面にホーロー層を焼成し、その上に写真転写シートを貼付け、乾燥させて焼成させるホーロー部材の製造方法において、上記写真転写シートを貼付ける貼付け部を、白色のコーティングカバーを施して白色にした後、上記写真転写シートの焼成を、緩やかな温度上昇特性を持つ第一段階焼成と、常温に戻すことなくこの第一段階焼成に連続して上記第一段階焼成よりも急速で高い温度に上昇させる第二段階焼成とで行なうようにしたことを特徴とするホーロー部材の製造方法。In the manufacturing method of the enamel member that bakes the enamel layer on the surface of the substrate member, pastes the photographic transfer sheet thereon, and dries and bakes it, the pasting portion to which the photographic transfer sheet is pasted is applied with a white coating cover. After the whitening, the photographic transfer sheet is fired more rapidly than the first stage baking after the first stage baking having a moderate temperature rise characteristic and the first stage baking without returning to normal temperature. A method for producing an enamel member, characterized in that the second stage firing is performed to raise the temperature .
JP27309495A 1995-10-20 1995-10-20 Method for manufacturing enamel member Expired - Fee Related JP3645331B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP27309495A JP3645331B2 (en) 1995-10-20 1995-10-20 Method for manufacturing enamel member

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP27309495A JP3645331B2 (en) 1995-10-20 1995-10-20 Method for manufacturing enamel member

Publications (2)

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JPH09111477A JPH09111477A (en) 1997-04-28
JP3645331B2 true JP3645331B2 (en) 2005-05-11

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JP27309495A Expired - Fee Related JP3645331B2 (en) 1995-10-20 1995-10-20 Method for manufacturing enamel member

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JPH09111477A (en) 1997-04-28

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