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JP3672635B2 - Dipping tube for molten steel processing equipment - Google Patents
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JP3672635B2 - Dipping tube for molten steel processing equipment - Google Patents

Dipping tube for molten steel processing equipment Download PDF

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Publication number
JP3672635B2
JP3672635B2 JP24511595A JP24511595A JP3672635B2 JP 3672635 B2 JP3672635 B2 JP 3672635B2 JP 24511595 A JP24511595 A JP 24511595A JP 24511595 A JP24511595 A JP 24511595A JP 3672635 B2 JP3672635 B2 JP 3672635B2
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JP
Japan
Prior art keywords
refractory
dip tube
molten steel
carbon
steel processing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP24511595A
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Japanese (ja)
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JPH0967612A (en
Inventor
正彦 天野
保彦 吉村
邦昭 田口
昭弘 土成
秀雄 伊藤
宏 高垣
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Krosaki Harima Corp
Original Assignee
Nippon Steel Corp
Krosaki Harima Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Corp, Krosaki Harima Corp filed Critical Nippon Steel Corp
Priority to JP24511595A priority Critical patent/JP3672635B2/en
Publication of JPH0967612A publication Critical patent/JPH0967612A/en
Application granted granted Critical
Publication of JP3672635B2 publication Critical patent/JP3672635B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Description

【0001】
【発明の属する技術分野】
本発明は、溶鋼処理装置用浸漬管の構造に関するものである。
【0002】
【従来の技術】
製鉄産業におけるRH式、DH式などの真空脱ガス装置やCAS装置などの溶鋼処理装置に装着される浸漬管は、溶鋼流の作用、溶鋼上に浮遊するスラグとの反応、熱サイクルによる剥落などによって消耗が著しい。そして、消耗代が少なくなった浸漬管はフランジ部から取り外され、別途準備された浸漬管と交換される。
【0003】
溶鋼処理装置用浸漬管は、外周部に付着したスラグの厚みが増大すると、例えば浸漬管が並列しているRH式真空脱ガス装置においては、浸漬管同士が接着し、浸漬管の交換が容易でなくなる。
また、浸漬管はこのスラグの付着で外径が増し、取鍋内への浸漬が困難になるという問題がある。
そこで、外周部へのスラグ付着を防止する手段として、例えば特開平7−51821号公報に見られるとおり、スラグライン部にカーボン含有耐火物を配設することが提案されている。
【0004】
【発明が解決しようとする課題】
カーボン含有耐火物は、カーボンのスラグに対する濡れ性の悪さからスラグが付着し難く、これをスラグライン部に配設したことで上記従来のスラグ付着の問題を解決することができる。しかし、このカーボン含有耐火物とそれ以外の部分の耐火物との境界部に、材質の相違によって生じた目地開きに溶鋼が侵入し、浸漬管内部の金属製円筒や耐火物支持金物の損傷、さらには目地部から下方の耐火物が脱落するという問題があった。
本発明は、浸漬管における上記従来の問題を解決することを目的とする。
【0005】
【課題を解決するための手段】
本発明は、金属製円筒の内周部および外周部に耐火物層を設けた溶鋼処理装置用浸漬管において、外周部の耐火物層として、スラグライン部にカーボン3〜50wt%含有の定形耐火物を配列すると共に、前記の定形耐火物の下端を浸漬管の周方向に交互の長短構造とし、かつ、外周の前記定形耐火物以外の部分を不定形耐火物としたことを特徴とする溶鋼処理装置用浸漬管である。また、前記の浸漬管構造において、外周のスラグライン部およびその上方をカーボン含有の定形耐火物にした溶鋼処理装置用浸漬管。さらに、スラグライン部に配列したカーボン3〜50wt%含有の定形耐火物の、下端部における高さ方向の長短差が20〜60mmである溶鋼処理装置用浸漬管である。
【0006】
【作用】
浸漬管は溶鋼中に浸漬し使用されるために、下方が熱膨張によって広がり、耐火物層がこの広がりに追随しないため、スラグライン部に定形耐火物を設けた構造では、定形耐火物と不定形耐火物との境界部に水平方向の目地開きを生じ、しかもこの目地開き幅が大きいために、耐火物支持金物の損傷や目地部から下方の耐火物の脱落を招きやすい。しかも、カーボン含有の定形耐火物は、カーボン含有によって表面の摩擦係数が小さく、しかも他の耐火物と焼結性に劣ることから、耐火物の脱落が特に生じやすい。
【0007】
これに対し本発明の浸漬管は、スラグライン部に設けた定形耐火物とその下方の不定形耐火物との境界が凹凸になっていることから、浸漬管の下方が熱膨張で拡がりを生じた場合、前記の境界に生じる水平方向の目地開きは、定形耐火物の長短構造に合わせて、浸漬管の周方向に交互に上下の不連続となる。しかも、境界の垂直目地の摩擦抵抗で水平方向の目地開きを最小限に留めることができる。その結果、目地部からの溶鋼侵入による支持金物の損傷や、浸漬管下方の耐火物の脱落といった事故は皆無となる。
【0008】
【実施例】
図面に示す実施例に基づいて、本発明をさらに詳細に説明する。
図1の部分断面図(右半分が断面)において、金属製円筒(1)は外周および内周の耐火物層(4)、(3)の骨格としての役割をもつ。その上端には、一般に浸漬管を着脱自在にするためのフランジ(2)を備えている。内周耐火物層(3)は不定形耐火物でもよいが、耐食性の面から定形耐火物が好ましい。
【0009】
外周耐火物層(4)として、スラグライン部にカーボン含有の定形耐火物(5)を周方向に配列する。この定形耐火物(5)の支持は、下方の不定形耐火物(6)に頼ってもよいが、支持金物(7)で上下端を押さえるのが好ましい。
スラグライン部の定形耐火物(5)の個数は、浸漬管のサイズなどに合わせて適宜決定する。また、高さ方向のサイズは、スラグラインが湯面の高さの変化に応じて推移するので、余裕をもって一定の幅を取る。
【0010】
本発明では、この外周耐火物層(4)における定形耐火物(5)の下端を浸漬管の周方向に交互に長短構造とする。下端部における高さ方向の長短の差は、好ましくは20〜60mm程度とする。
図では、定形耐火物(5)を外周上下方向に一個ごとに交互に長短構造としているが、これに限らず、長尺あるいは短尺を例えば二個ごとなど、複数ごとに長短構造にしてもよい。また、長尺と短尺の定形耐火物の幅を互いに異なるものにしてもよい。
【0011】
スラグライン部のカーボン含有の定形耐火物(5)は、カーボンを含有する例えばマグネシア−カーボン質、スピネル−カーボン質、マグネシア−スピネル−カーボン質、アルミナ−カーボン質、アルミナ−炭化珪素−カーボン質などの焼成品または不焼成品とする。カーボン含有量は、十分なスラグ付着防止の効果を得るために3〜50wt%、望ましくは5〜30wt%とする。3wt%未満ではスラグの付着防止の効果が不十分となり、50wt%を超えるとカーボンの酸化によって組織強度の低下を招く。
【0012】
定形耐火物(5)の下方に設ける不定形耐火物(6)の具体的な材質は限定されるものではなく、例えばアルミナ質、アルミナ−スピネル質、アルミナ−マグネシア質、アルミナ−マグネシア−スピネル質、マグネシア質、マグネシア−カルシア質などのキャスタブル耐火物とする。図では省略するが、不定形耐火物(6)の支持のために、金属製円筒(1)にスタッドを立設させることが好ましい。
【0013】
図2は他の実施例を示し、外周耐火物層(4)における定形耐火物(5)の高さ方向の長さをスラグライン部だけでなく、その上方に伸ばしたものである。
また、図には示していないが、例えば特開平6−145768号公報に見られるように下方外周にテーパーを設けた浸漬管にも本願発明を適用することができる。
【0014】
実機試験として、内径500×外径1000×高さ1000mmのRH真空脱ガス装置用浸漬管において、内周耐火物を焼成マグネシア−クロム質定形耐火物とし、外周耐火物には、スラグライン部に鱗状黒鉛を20wt%含有する不焼成マグネシア−カーボン質定形耐火物を設け、その下部および上部はアルミナ−マグネシア質キャスタブル耐火物とした。
また、前記の不焼成マグネシア−カーボン質耐火物の下端は、浸漬管の周方向に交互に長短構造にした。長尺と短尺との高さ方向の長さの差は、50mmとした。
【0015】
こうして得られた本発明実施例の浸漬管と、外周の定形耐火物の下端を一直線上にした以外は本発明実施例と同じ構造にした従来の浸漬管とを比較試験した。その結果、従来の浸漬管では下部の広がりにともなって外周の定形耐火物とその下方の不定形耐火物との境界に水平に連続した目地開きが生じ、しかもその目地幅が大きいために、溶鋼侵入が原因で33チャージ使用後には不定形耐火物の脱落によって寿命となった。これに対し、本発明実施例による浸漬管は、外周の定形耐火物とその下方の不定形耐火物との境界の目地が不連続で、しかも目地幅は小さく、160チャージで使用を中止したが、その間、下方の不定形耐火物の脱落は認められなかった。
【0016】
【発明の効果】
本発明は以上に説明したように、スラグライン部に設けたカーボン含有定形耐火物の下端を浸漬管の周方向に交互に長短構造としたことにより、浸漬管の下方の広がりに伴う目地開きを抑制すると共に、耐火物の脱落を防止する。その結果、スラグライン部におけるカーボン含有定形耐火物がもつスラグ付着防止の効果がいかんなく発揮され、浸漬管全体の耐用性が格段に向上する。
【図面の簡単な説明】
【図1】本発明の実施例を示す部分断面図である。
【図2】本発明の他の実施例を示す部分断面図である。
【符号の説明】
1 金属製円筒
2 フランジ
3 内周耐火物層
4 外周耐火物層
5 カーボン含有の定形耐火物
6 不定形耐火物
7 支持金物
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a structure of a dip tube for a molten steel processing apparatus.
[0002]
[Prior art]
Immersion pipes installed in molten steel processing equipment such as RH and DH vacuum degassing equipment and CAS equipment in the steel industry are affected by the flow of molten steel, reaction with slag floating on the molten steel, and peeling due to thermal cycling. Depending on the consumption. Then, the dip tube having a reduced consumption allowance is removed from the flange portion and replaced with a separately prepared dip tube.
[0003]
When the thickness of the slag adhering to the outer peripheral portion of the dip tube for molten steel processing equipment increases, for example, in the RH type vacuum degassing device in which the dip tubes are arranged in parallel, the dip tubes adhere to each other and the dip tube can be easily replaced. Not.
Further, the dip tube has a problem that the outer diameter increases due to the adhesion of the slag, and it becomes difficult to immerse in the ladle.
Therefore, as a means for preventing the slag from adhering to the outer peripheral portion, it has been proposed to dispose a carbon-containing refractory in the slag line portion as seen in, for example, JP-A-7-51821.
[0004]
[Problems to be solved by the invention]
The carbon-containing refractory is difficult to adhere to slag due to poor wettability of carbon to slag, and by arranging this in the slag line portion, the above-mentioned conventional slag adhesion problem can be solved. However, at the boundary between this carbon-containing refractory and the other refractories, molten steel penetrates into the joint opening caused by the difference in material, and damage to the metal cylinder and refractory support hardware inside the dip tube, Furthermore, there was a problem that the refractory below was dropped from the joint.
An object of the present invention is to solve the above-mentioned conventional problems in dip tubes.
[0005]
[Means for Solving the Problems]
The present invention relates to a dip tube for a molten steel processing apparatus in which a refractory layer is provided on an inner peripheral portion and an outer peripheral portion of a metal cylinder, and as a refractory layer on the outer peripheral portion, a slag line portion containing carbon of 3 to 50 wt. In addition to arranging the objects, the lower end portion of the above-mentioned regular refractory has an alternately long and short structure in the circumferential direction of the dip tube, and the outer portion other than the above-mentioned regular refractory is an irregular refractory. It is a dip tube for molten steel processing equipment. Moreover, in the above-mentioned dip tube structure, a dip tube for a molten steel processing apparatus in which a slag line part on the outer periphery and the upper side thereof are formed into a carbon-containing shaped refractory . Furthermore, it is the dip tube for molten steel processing apparatuses whose length difference in the height direction in the lower end part of the shaped refractories containing 3 to 50 wt% of carbon arranged in the slag line part is 20 to 60 mm .
[0006]
[Action]
Since the dip tube is used by being immersed in molten steel, the lower part expands due to thermal expansion, and the refractory layer does not follow this expansion.Therefore, in the structure in which the regular refractory is provided in the slag line part, A horizontal joint opening is generated at the boundary with the fixed refractory, and the joint opening width is large, and thus the refractory supporting metal is easily damaged and the refractory below is easily dropped from the joint. Moreover, the carbon-containing regular refractory has a small surface friction coefficient due to the carbon content, and is inferior in sinterability with other refractories, so that the refractory is particularly likely to fall off.
[0007]
On the other hand, the dip tube of the present invention has an uneven boundary between the regular refractory provided in the slag line part and the amorphous refractory below the refractory, so that the lower part of the dip tube expands due to thermal expansion. In this case, the horizontal joint opening generated at the boundary is alternately discontinuous up and down in the circumferential direction of the dip tube in accordance with the long and short structure of the regular refractory. Moreover, horizontal joint opening can be minimized by the frictional resistance of the vertical joint at the boundary. As a result, there are no accidents such as damage to the support metal due to the intrusion of molten steel from the joints, and dropping of the refractory under the dip tube.
[0008]
【Example】
The invention will be described in more detail on the basis of the embodiments shown in the drawings.
In the partial cross-sectional view of FIG. 1 (the right half is a cross section), the metal cylinder (1) serves as a skeleton of the outer and inner refractory layers (4) and (3). The upper end is generally provided with a flange (2) for making the dip tube detachable. The inner refractory layer (3) may be an irregular refractory, but a regular refractory is preferred from the standpoint of corrosion resistance.
[0009]
As the outer periphery refractory layer (4), carbon-containing shaped refractories (5) are arranged in the circumferential direction in the slag line portion. The support of the regular refractory (5) may depend on the lower amorphous refractory (6), but it is preferable to hold the upper and lower ends with the support hardware (7).
The number of the regular refractories (5) in the slag line portion is appropriately determined according to the size of the dip tube. Moreover, since the slag line changes according to the change of the height of the hot water surface, the size in the height direction takes a certain width with a margin.
[0010]
In the present invention, the lower end of the regular refractory (5) in the outer peripheral refractory layer (4) has a long and short structure alternately in the circumferential direction of the dip tube. The difference in length in the height direction at the lower end is preferably about 20 to 60 mm.
In the figure, the regular refractory (5) has a long and short structure alternately in the vertical direction of the outer periphery. However, the present invention is not limited to this, and the long or short length may be long or short, for example, every two pieces. . Further, the widths of the long and short shaped refractories may be different from each other.
[0011]
The carbon-containing shaped refractory (5) in the slag line portion contains carbon, for example, magnesia-carbon, spinel-carbon, magnesia-spinel-carbon, alumina-carbon, alumina-silicon carbide-carbon, etc. Fired product or non-fired product. The carbon content is 3 to 50 wt%, preferably 5 to 30 wt%, in order to obtain a sufficient slag adhesion preventing effect. If it is less than 3 wt%, the effect of preventing the adhesion of slag will be insufficient, and if it exceeds 50 wt%, the strength of the structure will be reduced by the oxidation of carbon.
[0012]
The specific material of the amorphous refractory (6) provided below the regular refractory (5) is not limited. For example, alumina, alumina-spinel, alumina-magnesia, alumina-magnesia-spinel , Castable refractories such as magnesia, magnesia-calcia. Although not shown in the figure, it is preferable that a stud is erected on the metal cylinder (1) in order to support the irregular refractory (6).
[0013]
FIG. 2 shows another embodiment, in which the length in the height direction of the regular refractory (5) in the outer peripheral refractory layer (4) is extended not only to the slag line portion but also to the upper side thereof.
Although not shown in the figure, the present invention can also be applied to a dip tube having a taper on its outer periphery as disclosed in, for example, Japanese Patent Laid-Open No. 6-145768.
[0014]
As an actual machine test, in an immersion pipe for an RH vacuum degassing apparatus having an inner diameter of 500 × an outer diameter of 1000 × a height of 1000 mm, the inner peripheral refractory is a fired magnesia-chromium shaped refractory, and the outer peripheral refractory has A non-fired magnesia-carbonaceous refractory containing 20% by weight of scaly graphite was provided, and the lower and upper portions thereof were alumina-magnesia castable refractories.
Further, the lower end of the unfired magnesia-carbon refractory was made to have a long and short structure alternately in the circumferential direction of the dip tube. The difference in length in the height direction between the long and short was 50 mm.
[0015]
The dip tube of the present invention example thus obtained was compared with a conventional dip tube having the same structure as that of the present invention example except that the lower end of the outer peripheral shaped refractory was aligned. As a result, in the conventional dip tube, as the lower part expands, a horizontally continuous joint opening occurs at the boundary between the outer peripheral shaped refractory and the lower shaped refractory, and the joint width is large. Due to the intrusion, after 33 charges were used, the service life was reached by dropping off the irregular refractory. In contrast, the dip tube according to the embodiment of the present invention has a discontinuous joint at the boundary between the outer periphery of the regular refractory and the amorphous refractory below it, and the joint width is small. In the meantime, the falling of the amorphous refractory below was not observed.
[0016]
【The invention's effect】
In the present invention, as described above, the lower end of the carbon-containing shaped refractory provided in the slag line portion has a long and short structure alternately in the circumferential direction of the dip tube, thereby opening joints along with the downward spread of the dip tube. Suppresses and prevents refractories from falling off. As a result, the slag adhesion preventing effect of the carbon-containing regular refractory in the slag line portion is exhibited and the durability of the entire dip tube is greatly improved.
[Brief description of the drawings]
FIG. 1 is a partial sectional view showing an embodiment of the present invention.
FIG. 2 is a partial cross-sectional view showing another embodiment of the present invention.
[Explanation of symbols]
1 Metal cylinder 2 Flange 3 Inner peripheral refractory layer 4 Outer peripheral refractory layer 5 Carbon-containing regular refractory 6 Amorphous refractory 7 Support metal

Claims (3)

金属製円筒の内周部および外周部に耐火物層を設けた溶鋼処理装置用浸漬管において、外周部の耐火物層として、スラグライン部にカーボン3〜50wt%含有の定形耐火物を配列すると共に、前記の定形耐火物の下端を浸漬管の周方向に交互の長短構造とし、かつ、外周の前記定形耐火物以外の部分を不定形耐火物としたことを特徴とする溶鋼処理装置用浸漬管。In a dip tube for a molten steel processing apparatus provided with a refractory layer on the inner and outer peripheries of a metal cylinder, as a refractory layer on the outer periphery, a regular refractory containing 3 to 50 wt% carbon is arranged in the slag line portion. And the lower end portion of the above-mentioned regular refractory has an alternately long and short structure in the circumferential direction of the dip tube, and the outer portion other than the above-mentioned regular refractory is an irregular refractory. Immersion tube. 外周のスラグライン部およびその上方をカーボン含有の定形耐火物にした請求項1記載の溶鋼処理装置用浸漬管。  The dip tube for a molten steel processing apparatus according to claim 1, wherein the outer peripheral slag line part and the upper part thereof are carbon-containing shaped refractories. スラグライン部に配列したカーボン3〜50wt%含有の定形耐火物の、下端部における高さ方向の長短差が20〜60mmである請求項1または2記載の溶鋼処理装置用浸漬管。The dip tube for a molten steel processing apparatus according to claim 1 or 2, wherein the length difference in the height direction at the lower end portion of the shaped refractory containing 3 to 50 wt% of carbon arranged in the slag line portion is 20 to 60 mm.
JP24511595A 1995-08-31 1995-08-31 Dipping tube for molten steel processing equipment Expired - Fee Related JP3672635B2 (en)

Priority Applications (1)

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JP24511595A JP3672635B2 (en) 1995-08-31 1995-08-31 Dipping tube for molten steel processing equipment

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Application Number Priority Date Filing Date Title
JP24511595A JP3672635B2 (en) 1995-08-31 1995-08-31 Dipping tube for molten steel processing equipment

Publications (2)

Publication Number Publication Date
JPH0967612A JPH0967612A (en) 1997-03-11
JP3672635B2 true JP3672635B2 (en) 2005-07-20

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