JP3690630B2 - Free-cutting aluminum alloy - Google Patents
Free-cutting aluminum alloy Download PDFInfo
- Publication number
- JP3690630B2 JP3690630B2 JP36732097A JP36732097A JP3690630B2 JP 3690630 B2 JP3690630 B2 JP 3690630B2 JP 36732097 A JP36732097 A JP 36732097A JP 36732097 A JP36732097 A JP 36732097A JP 3690630 B2 JP3690630 B2 JP 3690630B2
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- JP
- Japan
- Prior art keywords
- mass
- machinability
- aluminum alloy
- alloy
- extruded
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 229910000838 Al alloy Inorganic materials 0.000 title claims description 14
- 239000000956 alloy Substances 0.000 claims description 15
- 238000005260 corrosion Methods 0.000 claims description 11
- 230000007797 corrosion Effects 0.000 claims description 11
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims description 3
- 229910045601 alloy Inorganic materials 0.000 description 13
- 230000000694 effects Effects 0.000 description 9
- 238000001125 extrusion Methods 0.000 description 6
- 229910052745 lead Inorganic materials 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 229910052797 bismuth Inorganic materials 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 150000002739 metals Chemical class 0.000 description 4
- 229910052718 tin Inorganic materials 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000013078 crystal Substances 0.000 description 2
- 238000001192 hot extrusion Methods 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 229910019018 Mg 2 Si Inorganic materials 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Images
Landscapes
- Extrusion Of Metal (AREA)
Description
【0001】
【発明の属する技術分野】
本発明は、切削性に優れたアルミニウム合金に関するもので、特に、自動車用制動部品等の油圧機能を有し、切削加工が必要とする分野に供される、アルミニウム押出成形形材に関するものである。
【0002】
一般に、切削性を目的として使用されている合金としては、AA2011合金やAA6262合金が広く知られている。
【0003】
しかし、AA2011合金にはCuが多く添加されていて、耐食性に劣る。
また、AA6262合金にはPb、Bi、Sn等の低融点金属が添加されているが、これら低融点金属は、アルミニウム中にほとんど固溶せず、アルミニウム合金中に粒状で存在する。
そして、切削加工時の加工熱により溶融して切粉を分断し、切削性を向上させる。
【0004】
例えば、特開平7−197165号には、Pb、Sn、Biの低融点金属を添加することで、切削性の向上を図った合金が開示されている。
【0005】
【発明が解決しようとする課題】
確かに、6262合金のようにPb、Bi、Snを添加することで、切削性を改善する効果は見られる。
【0006】
しかし、これらの低融点金属を含むアルミニウム合金は、熱脆性を引き起こす欠点があり、使用条件に充分な注意を払う必要があった。
【0007】
さらに、低融点金属を含むアルミニウム合金は、Pb、Bi等を含むため、リサイクル性に不利であるという課題も有している。
【0008】
また、自動車制御部品等においては、切削性のみならず、耐圧強度耐電位差腐食性等も要求され、さらには部品組付のための、かしめ時の材料ねばり性も必要とされる場合があり、係る要求特性を満足するアルミニウム合金材料が所望された。
【0009】
【課題を解決するための手段】
本発明は、まず、アルミニウム中に各種成分を添加し、押出加工により押出形材を成形し、各品質特性および押出成形について精意研究した。
【0010】
その結果、本発明に至ったものであり、以下実験により得られた知見とともに、課題を解決するための手段を述べる。
【0011】
自動車用制動部品には各種多くの部品があり、アンチロックブレーキシステムアクチュエーターボデー、ブレーキホイールシリンダー、クラッチマスターシリンダー、プロポーショニングバルブ等が代表例である。
【0012】
これらに供されるアルミニウム合金には、鋳造材、押出材があるが、本発明は、特に押出材についてのものである。
【0013】
AA6262合金等の快削性アルミニウム合金は、切削性を向上させる目的で、Pb、Bi、Sn等の低融点金属を添加しているが、本発明は、代わりにSi、Cu、Mn等を適正配合することで、上記目的を達成できることを見い出し、その知見を基に、本発明を完成するに至った。
【0014】
すなわち、本発明に関わる、切削性に優れるアルミニウム合金は、Si:0.5〜1.5質量%、Cu:0.4〜0.2質量%、Mn:0.5〜1.5質量%、Mg:0.5〜1.5質量%をそれぞれ有し、残部がAlおよび不可避不純物からなる。
【0015】
次に、上記アルミニウム合金における各元素の添加理由および添加量の限定理由を説明する。
【0016】
Siは0.5%以上添加することでMg2 Siの析出が促進され、自動車用制動部品に必要な強度が確保される。
【0017】
ただし、Siを1.5%以上添加した場合、アルミニウム中の固溶限を越えるため、Si系晶出物を生成する。
これにより、材料破断時の亀裂伝播速度が促進される欠点がある。
【0018】
Cuは、0.4%以上添加することで、アルミニウム中の固溶硬化に寄与するとともに、切削性も向上する。
【0019】
切削性を重視する場合には、AA2011合金のように、5.0〜6.0%の添加が良いが、Cuが多いと防食性が低下し、また、押出生産性も著しく悪くなる。
特に、防食効果を重視する場合には、2.0%以下に添加を抑える必要がある。
【0020】
従って、理想的には、Cu:0.4〜2.0%が係る品質特性を両立させるのに効果的である。
【0021】
Mnは、0.1%以上添加すると切削性および防食を向上できるが、1%以上添加すると粒界腐食が発生しやすくなる欠点がある。
【0022】
Tiは、結晶粒の微細化効果があり、必要に応じて添加される。
Tiが0.01%以下では、同様に微細化効果がなく、0.1%以上では、その効果が飽和するのみならず、切削時の工具寿命を低下させる。
【0023】
Fe:0.1〜1.0%は、結晶粒の微細化および被削性の改善効果があるが、1.0%を越えると、その効果が飽和し、0.1%以下では、その効果が不足する。
【0024】
【実施例】
表3、4に示す、合金NO.A〜Jの組成の合金鋳塊を調整した。
この8インチφの棒状鋳塊を420〜500℃で6時間以上均質化処理した後、420〜500℃に加熱して熱間押出加工を行った。
【0025】
押出形材は図2、3に示す、異形形材とした。
押出形材を100mmで切断後、溶体化を500〜560℃×2〜5時間保持後、30〜60℃水温に焼き入れを10分間行う。
その後、人工時効を170〜200℃×2〜6時間保持するT6処理を施した。
【0026】
このようにして得られた押出形材の押出加工性、機械的性質、耐食性、切削性を下記試験方法によって試験した。
【0027】
〈試験方法〉
(1)熱間押出加工方法
押出形材の表面に割れを生じさせないで、押し出すことができる最大押出速度を測定し、これによって前記各合金の押出加工性を評価した。
その結果を表5、6に示す。
【0028】
(2)機械的性質
T6処理した押出形材よりJIS5号片相当の引張試験片を採取し、JISZ2241に準じ、試験を行った。
その結果を表5、6に示す。
【0029】
(3)耐食性
T6処理した押出形材を図4のように加工し、ネジ部にダクロボルトを組み付けした後、表1を基準サイクルとし、10サイクル繰り返した。
評価はダクロボルト接触面および近傍の腐食深さを測定した。
その結果を表5、6に示す。
【0030】
(4)切削性
T6処理した押出形材を図1の刃具を用い、表2の条件にて孔明け加工を行った。
評価は最大切り屑長さおよび加工孔粗さを測定した。
その結果を表7、8に示す。
【0031】
【表1】
【0032】
【表2】
【0033】
【表3】
【0034】
【表4】
【0035】
【表5】
【0036】
【表6】
【0037】
【表7】
【0038】
【表8】
【0039】
【発明の効果】
本発明によるアルミニウム合金を用いて、押出形材を成形したものを評価した表3〜8に示す結果を比較すると明らかなように、Pb、Biを添加しなくてもAA6262と同等の切削性を有し、AA2011よりも耐食性に優れる。
【図面の簡単な説明】
【図1】切削性評価に用いた刃具を示す。
【図2】
【図3】本発明合金による押出形材例を示す。
【図4】電位差腐食試験片の形状を示す。
【符号の説明】
1・・・アルミニウム合金押出形材
2・・・ダクロボルト[0001]
BACKGROUND OF THE INVENTION
The present invention relates to an aluminum alloy having excellent machinability, and more particularly, to an aluminum extrusion molding having a hydraulic function such as a braking part for an automobile and used in a field requiring cutting. .
[0002]
In general, AA2011 alloy and AA6262 alloy are widely known as alloys used for the purpose of machinability.
[0003]
However, a large amount of Cu is added to the AA2011 alloy, which is inferior in corrosion resistance.
Further, low melting point metals such as Pb, Bi, and Sn are added to the AA6262 alloy, but these low melting point metals are hardly dissolved in aluminum and exist in a granular form in the aluminum alloy.
And it melt | dissolves with the process heat at the time of cutting, and cuts a chip, and improves machinability.
[0004]
For example, Japanese Patent Application Laid-Open No. 7-197165 discloses an alloy in which machinability is improved by adding a low melting point metal such as Pb, Sn, or Bi.
[0005]
[Problems to be solved by the invention]
Certainly, the effect of improving machinability can be seen by adding Pb, Bi, and Sn as in 6262 alloy.
[0006]
However, aluminum alloys containing these low-melting metals have the drawback of causing thermal embrittlement, and it is necessary to pay sufficient attention to the use conditions.
[0007]
Furthermore, since the aluminum alloy containing a low melting point metal contains Pb, Bi, etc., it also has a problem that it is disadvantageous for recyclability.
[0008]
In addition, in automobile control parts and the like, not only machinability but also pressure resistance strength potential difference corrosion resistance and the like are required, and further, material stickiness for caulking may be required for parts assembly. An aluminum alloy material that satisfies the required characteristics has been desired.
[0009]
[Means for Solving the Problems]
In the present invention, first, various components were added to aluminum, an extruded shape was formed by extrusion processing, and each quality characteristic and extrusion molding were extensively studied.
[0010]
As a result, the present invention has been achieved, and the means for solving the problem will be described together with the knowledge obtained by the experiment.
[0011]
There are various types of brake parts for automobiles, and anti-lock brake system actuator bodies, brake wheel cylinders, clutch master cylinders, proportioning valves, etc. are representative examples.
[0012]
The aluminum alloy used for these includes a cast material and an extruded material, and the present invention particularly relates to the extruded material.
[0013]
Free-cutting aluminum alloys such as AA6262 alloy have low melting point metals such as Pb, Bi, and Sn added for the purpose of improving machinability, but the present invention uses Si, Cu, Mn, etc. instead. It has been found that the above object can be achieved by blending, and the present invention has been completed based on the findings.
[0014]
That is, the aluminum alloy having excellent machinability related to the present invention is Si: 0.5 to 1.5 mass%, Cu: 0.4 to 0.2 mass%, Mn: 0.5 to 1.5 mass%. Mg: 0.5 to 1.5% by mass, with the balance being Al and inevitable impurities.
[0015]
Next, the reason for addition of each element in the aluminum alloy and the reason for limiting the addition amount will be described.
[0016]
By adding 0.5% or more of Si, precipitation of Mg 2 Si is promoted, and the strength required for automobile braking parts is ensured.
[0017]
However, when Si is added in an amount of 1.5% or more, it exceeds the solid solubility limit in aluminum, so that a Si-based crystallized product is generated.
Thereby, there exists a fault by which the crack propagation speed at the time of material fracture | rupture is accelerated | stimulated.
[0018]
Adding 0.4% or more of Cu contributes to solid solution hardening in aluminum and also improves machinability.
[0019]
When emphasizing the machinability, 5.0% to 6.0% addition is good as in the case of AA2011 alloy, but if the amount of Cu is large, the anticorrosion property is lowered and the extrusion productivity is remarkably deteriorated.
In particular, when emphasizing the anticorrosion effect, it is necessary to suppress the addition to 2.0% or less.
[0020]
Therefore, ideally, Cu: 0.4 to 2.0 % is effective in achieving both the quality characteristics.
[0021]
When Mn is added in an amount of 0.1% or more, machinability and corrosion resistance can be improved, but if it is added in an amount of 1% or more, there is a drawback that intergranular corrosion is likely to occur.
[0022]
Ti has an effect of refining crystal grains and is added as necessary.
Similarly, when Ti is 0.01% or less, there is no effect of miniaturization, and when it is 0.1% or more, the effect is not only saturated but also the tool life during cutting is reduced.
[0023]
Fe: 0.1 to 1.0% has an effect of improving crystal grain refinement and machinability, but if it exceeds 1.0%, the effect is saturated. The effect is insufficient.
[0024]
【Example】
As shown in Tables 3 and 4, alloy NO. An alloy ingot having a composition of A to J was prepared.
This 8 inch φ ingot was homogenized at 420 to 500 ° C. for 6 hours or more, and then heated to 420 to 500 ° C. for hot extrusion.
[0025]
The extruded profile was a deformed profile shown in FIGS.
After the extruded profile is cut at 100 mm, the solution is kept at 500 to 560 ° C. for 2 to 5 hours, and then quenched at 30 to 60 ° C. for 10 minutes.
Then, the T6 process which hold | maintains artificial aging at 170-200 degreeC x 2 to 6 hours was performed.
[0026]
The extruded shape thus obtained was tested for extrudability, mechanical properties, corrosion resistance, and machinability by the following test methods.
[0027]
<Test method>
(1) Hot extrusion method The maximum extrusion speed that can be extruded without causing cracks on the surface of the extruded profile was measured, thereby evaluating the extrudability of each alloy.
The results are shown in Tables 5 and 6.
[0028]
(2) Mechanical properties Tensile test pieces corresponding to JIS No. 5 pieces were sampled from the extruded shapes treated with T6 and tested according to JIS Z2241.
The results are shown in Tables 5 and 6.
[0029]
(3) Corrosion resistance T6-treated extruded profile was processed as shown in FIG. 4 and assembled with dacro bolts on the threaded portion.
Evaluation was made by measuring the corrosion depth at and near the contact surface of the dacrobolt.
The results are shown in Tables 5 and 6.
[0030]
(4) Machinability T6-treated extruded shapes were punched under the conditions shown in Table 2 using the blade shown in FIG.
In the evaluation, the maximum chip length and the processed hole roughness were measured.
The results are shown in Tables 7 and 8.
[0031]
[Table 1]
[0032]
[Table 2]
[0033]
[Table 3]
[0034]
[Table 4]
[0035]
[Table 5]
[0036]
[Table 6]
[0037]
[Table 7]
[0038]
[Table 8]
[0039]
【The invention's effect】
As is apparent from comparison of the results shown in Tables 3 to 8 in which the extruded shapes were evaluated using the aluminum alloy according to the present invention, the machinability equivalent to that of AA6262 was obtained without adding Pb and Bi. And has better corrosion resistance than AA2011.
[Brief description of the drawings]
FIG. 1 shows a cutting tool used for machinability evaluation.
[Figure 2]
FIG. 3 shows an example of an extruded shape made of the alloy of the present invention.
FIG. 4 shows the shape of a potentiometric corrosion test piece.
[Explanation of symbols]
1 ...
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP36732097A JP3690630B2 (en) | 1997-12-25 | 1997-12-25 | Free-cutting aluminum alloy |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP36732097A JP3690630B2 (en) | 1997-12-25 | 1997-12-25 | Free-cutting aluminum alloy |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH11189837A JPH11189837A (en) | 1999-07-13 |
| JP3690630B2 true JP3690630B2 (en) | 2005-08-31 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP36732097A Expired - Lifetime JP3690630B2 (en) | 1997-12-25 | 1997-12-25 | Free-cutting aluminum alloy |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3690630B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107739931A (en) * | 2017-08-29 | 2018-02-27 | 宁波华源精特金属制品有限公司 | Tensile-strength-enhanced robot arm and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4537611B2 (en) * | 2001-04-17 | 2010-09-01 | 株式会社住軽テクノ | Automotive brake member and manufacturing method thereof |
| WO2007076980A1 (en) * | 2006-01-06 | 2007-07-12 | Aleris Aluminum Duffel Bvba | Aluminium alloy sheet for automotive applications and structural automobile body member provided with said aluminium alloy sheet |
| JP2009013503A (en) * | 2008-09-29 | 2009-01-22 | Showa Denko Kk | Aluminum alloy extruded material for machining, machined article made of aluminum alloy, and valve material for automotive part |
| JP2011074470A (en) * | 2009-09-30 | 2011-04-14 | Kobe Steel Ltd | Aluminum alloy extruded form with excellent bending crushability and corrosion resistance |
| JP5366748B2 (en) * | 2009-09-30 | 2013-12-11 | 株式会社神戸製鋼所 | Aluminum alloy extruded material with excellent bending crushability and corrosion resistance |
| JP5495183B2 (en) * | 2010-03-15 | 2014-05-21 | 日産自動車株式会社 | Aluminum alloy and high strength bolt made of aluminum alloy |
| CN103993208B (en) * | 2014-05-29 | 2015-12-30 | 合肥工业大学 | A kind of Al-Mg-Si-Cu-Mn-Er alloy material and preparation method thereof |
-
1997
- 1997-12-25 JP JP36732097A patent/JP3690630B2/en not_active Expired - Lifetime
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107739931A (en) * | 2017-08-29 | 2018-02-27 | 宁波华源精特金属制品有限公司 | Tensile-strength-enhanced robot arm and preparation method thereof |
| CN107739931B (en) * | 2017-08-29 | 2019-09-27 | 宁波华源精特金属制品有限公司 | Tensile-strength-enhanced robot arm and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| JPH11189837A (en) | 1999-07-13 |
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