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JP3756646B2 - Sound barrier - Google Patents
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JP3756646B2 - Sound barrier - Google Patents

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JP3756646B2
JP3756646B2 JP31164797A JP31164797A JP3756646B2 JP 3756646 B2 JP3756646 B2 JP 3756646B2 JP 31164797 A JP31164797 A JP 31164797A JP 31164797 A JP31164797 A JP 31164797A JP 3756646 B2 JP3756646 B2 JP 3756646B2
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Japan
Prior art keywords
sound absorbing
soundproof
titanium oxide
exhaust gas
porous material
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JP31164797A
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Japanese (ja)
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JPH10212771A (en
Inventor
純雄 国枝
正人 遠藤
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NGK Insulators Ltd
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NGK Insulators Ltd
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Description

【0001】
【発明の属する技術分野】
本発明は、自動車の騒音を防止するとともに、自動車の排気ガスによる空気汚染を抑制するために利用される防音壁に関するものである。
【0002】
【従来の技術】
自動車専用道路や自動車の通行量の多い道路には、自動車の騒音を防止するための防音壁が設置されている。この防音壁には、ガラスウール等の繊維質の吸音材料のほか、耐候性、耐久性に優れたセラミック多孔質の吸音材料も広く用いられている。
【0003】
一方、自動車からの排気ガス中には窒素酸化物(NO)や硫黄酸化物(SO)等の汚染物質が含まれており、通産省工業技術院資源環境総合研究所では特開平6-315614号公報に示されるように、酸化チタン光触媒をフッ素系樹脂シートやセメントの表面に固定化し、道路付近のビルの壁面に取り付けて排気ガスにより汚染された空気を浄化する研究を行っている。この酸化チタン光触媒は太陽光線中の300 〜400nm の波長の近紫外線により活性化され、その強い酸化力により空気浄化、水浄化、抗菌等の効果を発揮するものである。
【0004】
【発明が解決しようとする課題】
ところが上記した従来技術には、次のような問題があった。
[1] 酸化チタン光触媒はフッ素系樹脂シートやセメントの表面に固定化されているため、排気ガスとの接触効率が低い。
[2] 酸化チタン光触媒の脱落による劣化が進行し易く、耐久性に乏しい。
[3] 窒素酸化物や硫黄酸化物は酸化チタン光触媒により酸化されて硫酸イオンや硝酸イオンとなり、セメントなどの基材を浸食する。
[4] 酸化チタン光触媒の設置位置が排気ガスの発生源から離れているため、排気ガスとの接触効率が低い。
本発明は上記した従来の問題点を解決し、排気ガスとの接触効率が高く、耐久性に優れ、しかも排気ガス浄化効果と防音効果を併せ持った吸音材料及びこれを用いた防音壁を提供するためになされたものである。
【0005】
【課題を解決するための手段】
上記の課題を解決するためになされた本発明の防音壁は、多孔質材の表面に、酸化チタン光触媒をコーティングした吸音材料からなる吸音板を前面に備えた防音パネルで構成される防音壁であって、この防音パネルの内部を負圧にする手段を備え、排気ガスが前記吸音板を通過し防音パネルの内部に吸引されるようにしたことを特徴とするものである。また、本発明は、前記防音壁の上部に空気路を設け、自然の風がこの空気路を通り抜ける際に防音パネルの内部を負圧にすることにより、排気ガスが前記吸音板を通過し防音パネルの内部に吸引されるようにしたものが好ましい。この多孔質材としては粒子又は繊維の集合体からなるものが使用でき、その材質はセラミック質、ガラス質、金属質のいずれかよりなるものが好ましい。
【0006】
【発明の実施の形態】
以下に本発明の好ましい実施の形態を説明する。
図1は本発明の実施形態に用いられる第1の吸音材料の断面図であり、1は多孔質材、2はその表面層の部分にコーティングされた酸化チタン光触媒である。この第1の実施形態の多孔質材1は直径が0.1mm 〜3mm程度のセラミック骨材3を釉薬等の無機質結合材により結合した粒子集合体からなるもので、従来から屋外用の吸音材料として用いられてきたものと同じでよい。
【0007】
酸化チタン光触媒2は、微細な粒径の酸化チタン粒子を適宜の結合材と混練し、多孔質材1のセラミック骨材3の表面を包み込むようにコーティングしたものである。コーティングの方法としては、多孔質材1の製造工程においてセラミック骨材3の表面に酸化チタン粒子を同時焼成し、焼き付けコーティングする方法や、焼成済みの多孔質材1の表面に酸化チタン粒子を焼き付けコーティングする方法や接着剤により固着させる方法等を取ることができる。酸化チタン光触媒2は多孔質材1の表面のみにコーティングしてもよいが、セラミック骨材3、3間の空隙においても触媒反応を進行させることができるように、表面からある程度の深さまでコーティングすることが好ましい。もっとも光線が到達しない内部にまで酸化チタン光触媒2をコーティングすることは意味がなく、表面からほぼ1〜10mm程度の深さまでコーティングすればよい。
【0008】
このように構成された吸音材料は、従来のセラミック多孔質材と同様の吸音性能を発揮するのみならず、太陽光線中の300 〜400nm の波長の近紫外線の存在下で自動車の排気ガスと接触すると、窒素酸化物や硫黄酸化物を酸化して硝酸イオンや硫酸イオンに変化させる。特に本発明の吸音材料は、空隙率の大きい多孔質材1の表面に酸化チタン光触媒2をコーティングしたため、酸化チタン光触媒2と排気ガスとの接触表面積が大きくなるうえ、セラミック骨材3の凹凸による乱流効果によって排気ガスとの接触効率も高まり、優れた浄化効果を発揮する。しかも酸化チタン光触媒2がセラミック質の多孔質材1と強固に接着されているため、従来品のように剥離・脱落するおそれもないものである。さらにこの吸音材料は耐薬品性に優れたセラミック質の多孔質材1の表面に酸化チタン光触媒2をコーティングしたものであるから、窒素酸化物や硫黄酸化物を酸化した結果生じる硝酸や硫酸による劣化のおそれもない。
【0009】
図2は本発明の実施形態に用いられる第2の吸音材料の断面図であり、1aは繊維質の多孔質材、2はその表面にコーティングされた酸化チタン光触媒である。第2の多孔質材1aとして耐蝕性に優れたアルミニウム繊維の集合体が用いられている。このアルミニウム繊維は例えば直径が5〜200 μm のものであってそれ単独で用いてもよいが、繊維集合体の外表面をアルミニウムやステンレスのパンチングメタルやエキスパンドメタルで挟むか、圧縮成形して用いてもよい。
【0010】
この第2の吸音材料も、第1の吸音材料と同様の作用効果を発揮するものであり、従来の繊維質の吸音材料と変わらない吸音性能を持ち、また太陽光線中の300 〜400nm の波長の近紫外線の存在下で自動車の排気ガスと接触すると、繊維質の多孔質材1aの表面にコーティングされた酸化チタン光触媒2が窒素酸化物や硫黄酸化物を酸化して、硝酸イオンや硫酸イオンに変化させることができる。なお、繊維質の多孔質材1aとしてはアルミニウム繊維のような耐食性に優れた金属繊維の他に、ガラス繊維やセラミック繊維を用いることもできる。
【0011】
記に示した吸音材料は、図3に示すような防音パネル4とされ、さらに多数の防音パネル4をH型鋼からなる支柱間に嵌めて防音壁が構成される。防音パネル4は図4に断面構造を示したように、鋼板製のボックス5の前面に前記の吸音材料からなる吸音板6を取付けたものである。吸音板6の厚さは一般に1〜50mm程度であり、その背後に50〜100mm 程度の空気層7を形成することが好ましい。このような構成を取ることにより、本発明の防音壁は従来と同様の防音機能を発揮するとともに、さらに、図4に示すように、防音パネルの内部を負圧にする手段を備え、排気ガスが前記吸音板を通過し防音パ ネルの内部に吸引されるようにしたので、優れた排気ガス浄化機能をも発揮することができる。以下に本発明の実施例を示す。
【0012】
【実施例】
(実施例1)
粒径が0.1mm 〜3mm のセラミック骨材3を釉薬により結合したセラミック質の多孔質材1の表面に、酸化チタン光触媒2をコーティングして本発明の吸音材料を製造した。フッ素系樹脂シートの表面に酸化チタン光触媒2をコーティングした従来品とこの吸音材料とを図5に示した反応器8の内部にセットし、窒素酸化物の除去率を測定した。測定は常温、常圧下で行われ、反応ガス組成はNO=5ppm、O=21%、N=バランスガス、反応ガス流量は500mL/min とした。また紫外線(320〜400nm)強度は昼間の太陽光と同程度の1000μW/cmとした。測定結果を表1に示した。このデータから明らかなように、本発明に用いられる吸音材料は従来品に比較して優れた窒素酸化物の除去性能を持つものである。
【0013】
【表1】

Figure 0003756646
【0014】
またJIS に規定される方法により、本発明の吸音材料の垂直入射吸音率を測定した結果を図6に示す。この図に示されたように、酸化チタン光触媒2をコーティングしたことによる吸音率の変化はほとんどない。
【0015】
前記したように本発明に用いられる吸音材料は優れた排気ガス浄化機能を有するため、従来と同様に高速道路の高さ5mの両側の防音壁に用いれば、自動車走行による風や空気の流れによって排気ガスが酸化チタン光触媒2と接触し、窒素酸化物や硫黄酸化物を10%程度除去することができる。さらに吸音板6の背面を負圧にする手段を設け、排気ガスを防音パネル4の内部に吸引して吸音板4を強制的に透過させるよう構成しているから、窒素酸化物や硫黄酸化物の除去率をさらに向上させることができる。
【0016】
このためには例えば図4に示すように、防音パネル4に通気口9を設けておき、図7に示すように多段に積まれた防音パネル4の内部を連通させ、上部からファン10で吸引する構造とすることができる。これにより排気ガスは多孔質の吸音板6を通過して防音パネル4の内部に吸引されることとなり、酸化チタン光触媒2との接触機会が格段に増加する。このため単に防音パネル4の表面に沿って排気ガスが流れるだけの場合に比較して、浄化効率を向上させることができる。
【0017】
上記のファン10は通常の電力により駆動してもよいが、太陽電池と組み合わせた電動ファンを用いれば、太陽エネルギーを利用して経済的に排気ガスの浄化を図ることができる。この場合、夜間には太陽電池の出力が低下してファン10が停止することとなるが、太陽光線のない場合には酸化チタン光触媒2の触媒作用も停止するため、ファン10が停止しても支障はない。
【0018】
さらに図8、図9に示すように防音壁の上部に空気路11を取付け、自然の風が空気路11を通り抜ける際に防音パネル4の内部を負圧にすることにより吸引効果を発揮させることもできる。この構造の防音壁も太陽電池を用いたものと同様に電力を必要とせず、浄化効率を高めることができる利点がある。なお、空気路11を風向に応じて回転する構造としたり、空気路11の内部に絞りを加えて吸引効果を増せば、より好ましい結果が得られる。
【0019】
酸化チタン光触媒2は排ガス中の窒素酸化物や硫黄酸化物を酸化し、硝酸イオン、硫酸イオンに変化するが、両者が雨等の水分に溶け、硝酸、硫酸が生じても多孔質材1をセラミック質やガラス質としておけば、酸による劣化は生じない。また、定期的降雨により硝酸、硫酸は洗浄されるが前述の太陽電池等を利用した水洗装置を取り付けてもよい。
【0020】
(実施例2)
直径が5〜200 μm のアルミニウム繊維集合体の表面に、酸化チタン光触媒2をコーティングして吸音材料を製造した。この吸音材料を第1の実施例と同様に図5に示した反応器8の内部にセットし、窒素酸化物の除去率を測定した。その結果、この吸音材料の窒素酸化物除去性能は98%に達し、従来品に比較して優れた効果を持つことが確認された。
【0021】
【発明の効果】
以上に述べた本発明の効果を要約すると、次の通りである。
[1] 酸化チタン光触媒を多孔質材の表面にコーティングしたので、従来の酸化チタン光触媒を平板表面に固定化したものと比較して排気ガスとの接触効率が高く、優れた浄化効率を得ることができる。
[2] 酸化チタン光触媒が脱落しにくく、特にセラミック質、ガラス質の多孔質材を用いたものは、窒素酸化物や硫黄酸化物が酸化された硝酸や硫酸による浸食もないため、耐久性に優れる。
[3] 酸化チタン光触媒を排気ガスの発生源の至近位置に配置できるため、排気ガスとの接触効率が高い。
[4] 特に吸音板の背面を負圧にする手段を設け排気ガスが吸音板を強制的に透過させるので、窒素酸化物や硫黄酸化物の除去率をさらに向上させることができる。
【図面の簡単な説明】
【図1】第1の実施形態の吸音材料の断面図である。
【図2】第2の実施形態の吸音材料の断面図である。
【図3】本発明の吸音材料を用いた防音パネルの斜視図である。
【図4】防音パネルの断面図である。
【図5】窒素酸化物の除去率の測定装置を示すブロック図である。
【図6】垂直入射吸音率を示すグラフである。
【図7】防音壁の実施例を示す断面図である。
【図8】防音壁の他の実施例を示す断面図である。
【図9】防音壁の他の実施例を示す斜視図である。
【符号の説明】
1 多孔質材、1a 繊維質の多孔質材、2 酸化チタン光触媒、3 セラミック骨材、4 防音パネル、5 ボックス、6 吸音板、7 空気層、8 反応器、9 通気口、10 ファン、11 空気路[0001]
BACKGROUND OF THE INVENTION
The present invention is to prevent the noise of the automobile, to a soundproofing wall that will be utilized in order to suppress air pollution by exhaust gases of automobiles.
[0002]
[Prior art]
Noise barriers are installed on automobile roads and roads where there is a large amount of automobile traffic to prevent automobile noise. In addition to fibrous sound-absorbing materials such as glass wool, ceramic porous sound-absorbing materials having excellent weather resistance and durability are widely used for the sound barrier.
[0003]
On the other hand, pollutants such as nitrogen oxides (NO x ) and sulfur oxides (SO x ) are contained in exhaust gas from automobiles. As shown in this publication, research has been conducted to purify air polluted with exhaust gas by fixing a titanium oxide photocatalyst to the surface of a fluororesin sheet or cement and attaching it to the wall of a building near the road. This titanium oxide photocatalyst is activated by near ultraviolet rays having a wavelength of 300 to 400 nm in sunlight, and exhibits its effects of air purification, water purification, antibacterial effect and the like by its strong oxidizing power.
[0004]
[Problems to be solved by the invention]
However, the above-described prior art has the following problems.
[1] Titanium oxide photocatalyst is immobilized on the surface of fluororesin sheet or cement, so its contact efficiency with exhaust gas is low.
[2] Titanium oxide photocatalyst is easily deteriorated due to falling off and lacks durability.
[3] Nitrogen oxides and sulfur oxides are oxidized by the titanium oxide photocatalyst to become sulfate ions and nitrate ions, which erode base materials such as cement.
[4] Since the location of the titanium oxide photocatalyst is far from the exhaust gas source, the contact efficiency with the exhaust gas is low.
The present invention solves the above-described conventional problems, and provides a sound-absorbing material having high contact efficiency with exhaust gas, excellent durability, and having both an exhaust gas purification effect and a soundproof effect, and a soundproof wall using the same. It was made for that purpose.
[0005]
[Means for Solving the Problems]
Sound barrier of the present invention has been made to solve the aforementioned problem, the surface of the porous material, soundproof composed soundproof panel with a sound absorbing plate made of a sound absorbing material coated with a titanium oxide photocatalyst in front A wall is provided with means for making the inside of the soundproof panel have a negative pressure, and exhaust gas passes through the sound absorbing plate and is sucked into the soundproof panel . In addition, the present invention provides an air passage in the upper part of the soundproof wall, and when natural wind passes through the air passage, negative pressure is applied to the inside of the soundproof panel, so that exhaust gas passes through the sound absorbing plate and is soundproofed. Those which are sucked into the panel are preferable. As the porous material, a material made of an aggregate of particles or fibers can be used, and the material is preferably made of any of ceramic, glass, and metal.
[0006]
DETAILED DESCRIPTION OF THE INVENTION
Hereinafter, preferred embodiments of the present invention will be described.
Figure 1 is a cross-sectional view of a first sound absorbing material used in the implementation form of the present invention, 1 porous material, 2 is a titanium oxide photocatalyst coated on part of its surface layer. The porous material 1 according to the first embodiment is composed of a particle aggregate in which a ceramic aggregate 3 having a diameter of about 0.1 mm to 3 mm is bonded by an inorganic binder such as glaze, and has been conventionally used as an outdoor sound absorbing material. It may be the same as that used.
[0007]
The titanium oxide photocatalyst 2 is obtained by kneading fine titanium oxide particles with an appropriate binder and coating the surface of the ceramic aggregate 3 of the porous material 1 so as to wrap. As a coating method, titanium oxide particles are simultaneously fired on the surface of the ceramic aggregate 3 in the manufacturing process of the porous material 1 and baked and coated, or titanium oxide particles are baked on the surface of the fired porous material 1. A method of coating, a method of fixing with an adhesive, or the like can be employed. Although the titanium oxide photocatalyst 2 may be coated only on the surface of the porous material 1, it is coated from the surface to a certain depth so that the catalytic reaction can proceed even in the gap between the ceramic aggregates 3 and 3. It is preferable. However, it is meaningless to coat the titanium oxide photocatalyst 2 to the inside where the light beam does not reach, and it may be coated to a depth of about 1 to 10 mm from the surface.
[0008]
Sound absorbing material configured in this way, not only exhibits the same sound absorbing performance as the conventional ceramic porous material, a motor vehicle exhaust gases in the presence of near-ultraviolet light of a wavelength of 300 to 400 nm in the sunlight When contacted, nitrogen oxides and sulfur oxides are oxidized and converted into nitrate ions and sulfate ions. In particular, the sound-absorbing material of the present invention is obtained by coating the surface of the porous material 1 having a large porosity with the titanium oxide photocatalyst 2, so that the contact surface area between the titanium oxide photocatalyst 2 and the exhaust gas is increased and the ceramic aggregate 3 is uneven. Due to the turbulent flow effect, the contact efficiency with the exhaust gas is increased, and an excellent purification effect is exhibited. In addition, since the titanium oxide photocatalyst 2 is firmly bonded to the ceramic porous material 1, there is no possibility of peeling and dropping as in the conventional product. Furthermore, since this sound-absorbing material is obtained by coating a titanium oxide photocatalyst 2 on the surface of a ceramic porous material 1 having excellent chemical resistance, deterioration due to nitric acid or sulfuric acid resulting from oxidation of nitrogen oxides or sulfur oxides. There is no fear of it.
[0009]
Figure 2 is a cross-sectional view of a second sound absorbing material used in the implementation of the invention, 1a porous material fiber, 2 is a titanium oxide photocatalyst coated on the surface thereof. Collection of excellent aluminum fibers in corrosion resistance is used as the second multi-porous material 1a. This aluminum fiber has a diameter of 5 to 200 μm, for example, and may be used alone. However, the outer surface of the fiber assembly is sandwiched between aluminum or stainless steel punching metal or expanded metal, or is used by compression molding. May be.
[0010]
The second sound absorbing materials also, which exhibits the same effects as the first sound absorbing material has a unchanged sound absorption performance and sound absorbing conventional fibrous and 300 in sunlight ~400nm When contacting with the exhaust gas of an automobile in the presence of near-ultraviolet light of the wavelength, the titanium oxide photocatalyst 2 coated on the surface of the fibrous porous material 1a oxidizes nitrogen oxide and sulfur oxide, It can be changed to sulfate ion. As the fibrous porous material 1a, glass fibers or ceramic fibers can be used in addition to metal fibers having excellent corrosion resistance such as aluminum fibers.
[0011]
Sound absorbing material shown above SL is the acoustic panel 4 as shown in FIG. 3, the sound barrier is constituted by fitting a larger number of acoustic panel 4 between posts consisting of H-section steel. As shown in the sectional structure of FIG. 4, the soundproof panel 4 is obtained by attaching a sound absorbing plate 6 made of the above sound absorbing material to the front surface of a steel plate box 5. The thickness of the sound absorbing plate 6 is generally about 1 to 50 mm, and it is preferable to form an air layer 7 of about 50 to 100 mm behind it. By adopting such a configuration, the soundproof wall of the present invention exhibits the same soundproofing function as that of the prior art, and further includes means for making the inside of the soundproof panel negative, as shown in FIG. since There were to be sucked into the soundproof panel passes through the sound absorbing plate it can be exhibited also excellent exhaust gas purifying function. Examples of the present invention are shown below.
[0012]
【Example】
Example 1
The surface of the ceramic porous material 1 in which the ceramic aggregate 3 having a particle size of 0.1 mm to 3 mm was bonded by glaze was coated with the titanium oxide photocatalyst 2 to produce the sound absorbing material of the present invention. A conventional product in which the surface of the fluororesin sheet was coated with the titanium oxide photocatalyst 2 and this sound absorbing material were set in the reactor 8 shown in FIG. 5 and the nitrogen oxide removal rate was measured. The measurement was performed at normal temperature and normal pressure, the reaction gas composition was NO = 5 ppm, O 2 = 21%, N 2 = balance gas, and the reaction gas flow rate was 500 mL / min. The intensity of ultraviolet rays (320 to 400 nm) was set to 1000 μW / cm 2 which is the same level as daytime sunlight. The measurement results are shown in Table 1. As is apparent from this data, the sound-absorbing material used in the present invention has excellent nitrogen oxide removal performance as compared with conventional products.
[0013]
[Table 1]
Figure 0003756646
[0014]
In addition, FIG. 6 shows the results of measuring the normal incident sound absorption coefficient of the sound absorbing material of the present invention by the method defined in JIS. As shown in this figure, there is almost no change in the sound absorption rate due to the coating of the titanium oxide photocatalyst 2.
[0015]
As described above, the sound-absorbing material used in the present invention has an excellent exhaust gas purification function. Therefore, if used for soundproof walls on both sides of a 5 m highway on a highway as in the conventional case, it is caused by wind and air flow caused by driving a car. The exhaust gas comes into contact with the titanium oxide photocatalyst 2 and can remove about 10% of nitrogen oxides and sulfur oxides. Further provided with means for a negative pressure to the back of the sound absorbing plate 6, because by so that an exhaust gas is forcibly passed through the sound absorbing plate 4 by sucking the interior of the soundproofing panel 4, nitrogen oxide and sulfur oxide The removal rate of objects can be further improved.
[0016]
For this purpose, for example, as shown in FIG. 4, the soundproof panel 4 is provided with a vent hole 9, and the interior of the soundproof panel 4 stacked in multiple stages is communicated as shown in FIG. It can be set as a structure. As a result, the exhaust gas passes through the porous sound absorbing plate 6 and is sucked into the soundproof panel 4, and the chance of contact with the titanium oxide photocatalyst 2 is greatly increased. Therefore, the purification efficiency can be improved as compared with the case where the exhaust gas simply flows along the surface of the soundproof panel 4.
[0017]
The fan 10 may be driven by normal electric power, but if an electric fan combined with a solar battery is used, the exhaust gas can be purified economically using solar energy. In this case, the output of the solar cell decreases at night and the fan 10 stops, but the catalytic action of the titanium oxide photocatalyst 2 also stops when there is no sunlight, so even if the fan 10 stops. There is no hindrance.
[0018]
Further, as shown in FIGS. 8 and 9, an air passage 11 is attached to the upper portion of the soundproof wall, and when the natural wind passes through the air passage 11, the inside of the soundproof panel 4 is made negative pressure to exert a suction effect. You can also. The soundproof wall having this structure does not require electric power as in the case of using a solar cell, and has an advantage that the purification efficiency can be increased. A more preferable result can be obtained if the air passage 11 is structured to rotate in accordance with the wind direction, or if the suction effect is increased by adding a throttle inside the air passage 11.
[0019]
The titanium oxide photocatalyst 2 oxidizes nitrogen oxides and sulfur oxides in the exhaust gas and changes into nitrate ions and sulfate ions, but both of them dissolve in moisture such as rain, and even if nitric acid and sulfuric acid are generated, the porous material 1 is formed. If it is made of ceramic or glass, it will not be degraded by acid. Although nitric acid and sulfuric acid are washed by regular rainfall, a water washing device using the above-described solar cell or the like may be attached.
[0020]
(Example 2)
A titanium dioxide photocatalyst 2 was coated on the surface of an aluminum fiber aggregate having a diameter of 5 to 200 μm to produce a sound absorbing material. This sound absorbing material was set in the reactor 8 shown in FIG. 5 in the same manner as in the first embodiment, and the nitrogen oxide removal rate was measured. As a result, it was confirmed that the performance of removing the nitrogen oxides of this sound absorbing material reached 98%, which was superior to that of the conventional product.
[0021]
【The invention's effect】
The effects of the present invention described above are summarized as follows.
[1] Since the titanium oxide photocatalyst is coated on the surface of the porous material, the contact efficiency with the exhaust gas is higher than that obtained by immobilizing the conventional titanium oxide photocatalyst on the flat plate surface, and excellent purification efficiency is obtained. Can do.
[2] Titanium oxide photocatalysts do not easily fall off, especially those using porous materials such as ceramics and glassy materials because they are not eroded by nitric acid or sulfuric acid in which nitrogen oxides or sulfur oxides are oxidized. Excellent.
[3] Since the titanium oxide photocatalyst can be placed in the immediate vicinity of the exhaust gas source, the contact efficiency with the exhaust gas is high.
[4] In particular, since the exhaust gas is provided with means for the back of the sound absorbing plate into a negative pressure is forcibly passed through the sound absorbing plate, it is possible to further improve the removal of nitrogen oxides and sulfur oxides.
[Brief description of the drawings]
FIG. 1 is a cross-sectional view of a sound absorbing material according to a first embodiment.
FIG. 2 is a cross-sectional view of a sound absorbing material according to a second embodiment.
FIG. 3 is a perspective view of a soundproof panel using the sound absorbing material of the present invention.
FIG. 4 is a cross-sectional view of a soundproof panel.
FIG. 5 is a block diagram showing an apparatus for measuring a nitrogen oxide removal rate.
FIG. 6 is a graph showing normal incidence sound absorption coefficient.
FIG. 7 is a cross-sectional view showing an example of a soundproof wall.
FIG. 8 is a cross-sectional view showing another embodiment of the soundproof wall.
FIG. 9 is a perspective view showing another embodiment of the soundproof wall.
[Explanation of symbols]
1 Porous material, 1a Fibrous porous material, 2 Titanium oxide photocatalyst, 3 Ceramic aggregate, 4 Soundproof panel, 5 Box, 6 Sound absorbing plate, 7 Air layer, 8 Reactor, 9 Vent, 10 Fan, 11 Air passage

Claims (4)

多孔質材の表面に、酸化チタン光触媒をコーティングした吸音材料からなる吸音板を前面に備えた防音パネルで構成される防音壁であって、この防音パネルの内部を負圧にする手段を備え、排気ガスが前記吸音板を通過し防音パネルの内部に吸引されるようにしたことを特徴とする防音壁The surface of the porous material, a soundproofing wall consisting of sound absorbing plate made of a sound absorbing material coated with a titanium oxide photocatalyst soundproof panel having a front surface, a means for the inside of the acoustic panel to a negative pressure A soundproof wall comprising exhaust gas passing through the sound absorbing plate and sucked into the soundproof panel . 前記防音壁の上部に空気路を設け、自然の風がこの空気路を通り抜ける際に防音パネルの内部を負圧にすることにより、排気ガスが前記吸音板を通過し防音パネルの内部に吸引されるようにした請求項1に記載の防音壁 An air passage is provided in the upper part of the soundproof wall, and when natural wind passes through this air passage, the inside of the soundproof panel is made negative pressure, so that exhaust gas passes through the sound absorbing plate and is sucked into the soundproof panel. The soundproof wall according to claim 1, wherein the soundproof wall is configured as described above . 多孔質材が粒子又は繊維の集合体からなるものである請求項1また2に記載の防音壁The soundproof wall according to claim 1 or 2, wherein the porous material is composed of an aggregate of particles or fibers. 多孔質材がセラミック質、ガラス質、金属質のいずれかよりなるものである請求項3に記載の防音壁The soundproof wall according to claim 3, wherein the porous material is made of any of ceramic, glass, and metal.
JP31164797A 1996-11-27 1997-11-13 Sound barrier Expired - Fee Related JP3756646B2 (en)

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US7252890B1 (en) * 2004-03-01 2007-08-07 Lockheed Martin Corporation Anti-contamination coated multi-layer insulation
JP4674364B2 (en) * 2005-08-19 2011-04-20 学校法人近畿大学 Air pollutant-removing soundproof wall with airflow layer behind
KR100935155B1 (en) 2007-11-06 2010-01-27 메이저위드(주) Soundproof wall with rotating sound absorbing plate
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