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JP3784622B2 - Ring manufacturing method - Google Patents
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JP3784622B2 - Ring manufacturing method - Google Patents

Ring manufacturing method Download PDF

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Publication number
JP3784622B2
JP3784622B2 JP2000244202A JP2000244202A JP3784622B2 JP 3784622 B2 JP3784622 B2 JP 3784622B2 JP 2000244202 A JP2000244202 A JP 2000244202A JP 2000244202 A JP2000244202 A JP 2000244202A JP 3784622 B2 JP3784622 B2 JP 3784622B2
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Japan
Prior art keywords
ring
drum
solution
solution treatment
treatment
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JP2000244202A
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Japanese (ja)
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JP2002060846A (en
Inventor
仁司 今井
均 唐澤
克幸 中島
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Honda Motor Co Ltd
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Honda Motor Co Ltd
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Description

【0001】
【発明の属する技術分野】
本発明は、無段変速機用ベルト等に用いられるリングの製造方法に関するものである。
【0002】
【従来の技術】
従来、無段変速機用ベルト等に用いられるリングは次のような製造方法により製造されている。まず、超強力鋼であるマルエージング鋼の薄板の端部同士を溶接して円筒状のドラムを形成し、該ドラムに対して第1の溶体化処理を行う。次に、溶体化されたドラムを所定幅に裁断してリングを形成し、該リングを圧延した後、圧延されたリングに対して第2の溶体化処理を行う。そして、溶体化されたリングを所定の周長に補正したのち時効及び窒化処理して硬度を向上させた後、複数のリングを相互に積層して積層リングを形成し、無段変速機用ベルトとする。
【0003】
前記製造方法において、前記溶接後のドラムに対する第1の溶体化は、前記溶接時の熱により部分的に硬くなった硬度を均質化するために行うものであり、該溶体化を行うことにより、前記ドラムを所定幅に裁断する処理をしてリングを形成した後の圧延を容易に行うことができる。前記溶体化は、一般に前記マルエージング鋼の再結晶温度以上の温度にて加熱することにより行われるが、このとき前記マルエージング鋼は、時効析出強化元素としてTi,Mo等を含んでおり、これらの元素、特にTiが酸化されると、後続の時効処理によって所定の硬度が得られないことがある。そこで、前記溶体化処理は、前記時効析出強化元素の酸化を避けるために、真空炉内で行われる。
【0004】
一方、前記圧延されたリングは、前記圧延により金属結晶が潰された圧延組織が形成されており、そのままでは後続の窒化処理において窒素が浸透しにくく、窒化が均一に行われないことがある。そこで、前記圧延化後のリングに対して、変形された金属結晶の粒子形状を復元し、窒化処理を容易にするために、第2の溶体化を行う。
【0005】
前記第2の溶体化も、一般に前記マルエージング鋼の再結晶温度以上の温度にて加熱することにより行われ、前記時効析出強化元素が酸化されないことが望ましい。しかし、真空炉は高価であるので、前記第2の溶体化は炉内を還元雰囲気とした加熱炉を用いて行われる。前記還元雰囲気としては、例えば1〜10%の水素を含む窒素雰囲気が用いられる。前記窒素雰囲気中には、僅かながら酸素が含まれているが、前記水素を酸素と反応させることにより、該酸素を除去し、前記時効析出強化元素の酸化を防止することができる。前記従来の製造方法によれば、前記2つの溶体化のうち第2の溶体化を加熱炉を用い還元雰囲気下で行うことにより真空炉の数を低減して、製造コストの低減を図ることができる。
【0006】
しかしながら、前記第1及び第2の溶体化にそれぞれ別の炉を用いたのでは、十分に製造コストを低減するものとはならないとの不都合がある。
【0007】
【発明が解決しようとする課題】
本発明は、かかる不都合を解消して、さらに製造コストを低減することができる積層リングの製造方法を提供することを目的とする。
【0008】
【課題を解決するための手段】
前記不都合を解消するために、本発明者らは溶接後のドラムと圧延後のリングとの溶体化の条件について検討を重ねた結果、前記マルエージング鋼に時効析出強化元素として含まれるTi,Mo等の酸化を防止するためには、必ずしも完全な真空を必要とせず、10-3Pa以下の圧力とすれば十分であることを見出し、本発明を完成した。
【0009】
そこで、本発明のリングの製造方法は、前記目的を達成するために、時効析出元素としてTi、Moを含むマルエージング鋼の薄板の端部同士を溶接してリング状のドラムを形成する工程と、溶接後のドラムに対する第1の溶体化を行う工程と、溶体化されたドラムを所定幅に裁断してリングを形成し、該リングを圧延する工程と、圧延されたリングに対する第2の溶体化を行う工程と、溶体化されたリングを所定の周長に補正したのち時効及び窒化処理する工程とを備えるリングの製造方法において、前記溶接後のドラムに対する第1の溶体化と、前記圧延後のリングに対する第2の溶体化とを、同一加熱炉を用い、10-3Pa以下の圧力下に同一温度条件で行うことを特徴とする。
【0010】
10-3Pa以下の圧力下では、前記マルエージング鋼の母材であるFeと、前記時効強化元素の1つであるMoは実質的に還元領域にある。また、Moと同様に前記時効強化元素の1つであるTiは、10-3Pa以下の圧力下では還元されることは無いが、少なくとも酸化されることは無い。
【0011】
従って、本発明の製造方法によれば、加熱炉中の雰囲気を10-3Pa以下の圧力とすることにより、前記溶接後のドラムに対する第1の溶体化と、前記圧延後のリングに対する第2の溶体化とを、同一加熱炉を用い同一条件で行うことができるので製造コストを大幅に低減することができる。
【0012】
【発明の実施の形態】
次に、添付の図面を参照しながら本発明の実施の形態についてさらに詳しく説明する。図1は本実施形態の製造方法を模式的に示す工程図、図2は溶接後のドラムに対して本発明の製造方法に従う溶体化を施す前後の硬度を示すグラフ、図3は溶接後のドラムと圧延後のリングとに対して本発明の製造方法に従う溶体化を施した後の硬度を示すグラフである。
【0013】
本実施形態の製造方法では、Cが0.03%以下、Siが0.10%以下、Mnが0.10%以下、Pが0.01%以下、Sが0.01%以下の低炭素鋼であり、18〜19%のNi、4.7〜5.2%のMo、0.05〜0.15%のAl、0.50〜0.70%のTi、8.5〜9.5%のCoを含む18%Ni鋼であるマルエージング鋼を用い、図1の工程に従って無段変速機用の積層リングを製造する。前記マルエージング鋼の組成のうち、Ti及びMoは時効析出強化元素であり、Ti及びMoが酸化されると、後続の時効処理において均一な時効硬度が得られなくなる。
【0014】
本実施形態の製造方法では、まず、図1に示すように前記組成を有するマルエージング鋼の薄板1をベンディングしてループ化したのち、端部同士を溶接して円筒状のドラム2を形成する。このとき、前記マルエージング鋼は溶接の熱により時効硬化を示し、ドラム2の溶接の中心2aから両側に1mm前後の部分に硬度の高い部分が出現する。
【0015】
そこで、次に、ドラム2を加熱炉3に収容して、10-3Pa以下の圧力下、前記マルエージング鋼の再結晶温度以上、850℃以下の温度で、第1の溶体化処理を行う。前記第1の溶体化において、加熱炉3の圧力は10-4Pa以下であってもよいが、通常の真空排気では達成が難しく、コストが高くなる。
【0016】
そして、前記第1の溶体化が終了したならば、ドラム2を加熱炉3から搬出し、所定幅に裁断してリング4を形成する。ドラム2は、前記第1の溶体化処理の結果、全体の硬度が均質化されているので、前記裁断を容易に行うことができ、圧延も容易となる。リング4は、次いで圧下率40〜50%で圧延される。
【0017】
前記圧延の結果、リング4には金属結晶が潰された圧延組織が形成されていて、このままでは後続の窒化処理において金属組織に窒素が浸透しにくい。そこで、次に、リング4を再び加熱炉3に収容して、10-3Pa以下の圧力下、前記第1の溶体化処理と同一温度条件で第2の溶体化処理を行う。
【0018】
前記第2の溶体化が終了したならば、リング4を加熱炉3から搬出し、所定の周長に補正する。前記周長の補正は、例えば前記リング4を図示しない駆動ローラ及び従動ローラに掛け回し、回転駆動させながら、前記リング4の走行方向と直交する方向に荷重を掛けることにより行う。
【0019】
次に、前記周長が補正されたリングに時効処理及び窒化処理を施す。前記時効処理は、例えば前記リングを図示しない加熱炉内で450〜530℃の範囲の温度に90〜240分保持することにより行う。また、前記窒化処理は、ガス窒化、ガス軟窒化、塩浴窒化等の方法により行う。
【0020】
そして、前記時効・窒化処理により所定の硬度とされた複数のリング4を相互に積層することにより、無段変速機の動力伝達ベルトとして好適な積層リングを形成する。
【0021】
前記ドラム2では、マルエージング鋼の薄板1の端部同士を溶接するときに、該溶接の熱による時効硬化のために、図2に示すように、溶接の中心2aから両側に1mm前後の部分に硬度の高い部分が出現する。そこで、本実施形態では、このようなドラム2を加熱炉3内に収容し、10-3Pa以下の圧力下、前記温度条件で第1の溶体化を行う。この結果、ドラム2では、前記時効強化元素であるMo及びTiとマルエージング鋼の母材であるFeとが酸化されることなく、硬度の高い部分が無くなり図2に示すように全体の硬度を均質化することができる。
【0022】
一方、前記圧延後のリング4は、前記圧延の結果、金属結晶が潰された圧延組織が形成されている。そこで、本実施形態では、このようなドラム2を加熱炉3内に収容し、10-3Pa以下の圧力下、前記第1の溶体化と同一温度条件で第2の溶体化を行う。この結果、リング4では、前記時効強化元素であるMo及びTiとマルエージング鋼の母材であるFeとが酸化されることなく、前記圧延組織の金属結晶の粒子形状を圧延前の状態に復元することができる。
【0023】
前記第2の溶体化後のリング4は、図3に示すように全体の硬度が均質化されており、金属結晶の粒子形状が圧延前の状態に復元されていることが明らかである。また、図3から、前記第2の溶体化後のリング4の硬度は、前記第1の溶体化処理後のドラム2の硬度と略同等となっており、両方の溶体化を10-3Pa以下の圧力下、同一温度条件で行うことにより同等の効果が得られることが明らかである。尚、前記第1の溶体化処理後のドラム2の硬度は図2示のものと同一データであるが、比較のために再掲したものである。
【0024】
本実施形態の製造方法において、リング4に対する第2の溶体化は、該リング4の後で溶接されたドラム2に対する第1の溶体化と独立に行ってもよく、同時に行ってもよい。リング4に対する第2の溶体化と、ドラム2に対する第1の溶体化とを同時に行う場合、リング4は圧延組織を復元するために時間がかかるので、ドラム2に対する第1の溶体化はリング4に対する第2の溶体化と同一の時間で行う。また、加熱炉3に図示しない隔壁を設けて炉内を2区画に分割し、それぞれの区画でリング4に対する第2の溶体化と、ドラム2に対する第1の溶体化とを独立に行うようにしてもよい。
【0025】
本実施形態の製造方法によれば、前記第1及び第2の溶体化において、時効析出強化元素の酸化が抑制されているので、前記周長補正されたリングの時効処理を均一に行うことができる。また、前記第2の溶体化において、前記圧延組織の金属結晶の粒子形状が圧延前の状態に復元されているので、窒素が金属組織に浸透しやすく、前記窒化処理を容易に行うことができる。
【0026】
本実施形態では、前記第1の溶体化と第2の溶体化とを同一の加熱炉3を用いて10-3Pa以下の圧力下、同一温度条件で行うことにより設備を共通化でき、製造コストを低減することができる。
【図面の簡単な説明】
【図1】本発明の製造方法の一実施形態を模式的に示す工程図。
【図2】溶接後のドラムに対して本発明の製造方法に従う溶体化を施す前後の硬度を示すグラフ。
【図3】溶接後のドラムと圧延後のリングとに対して本発明の製造方法に従う溶体化を施した後の硬度を示すグラフ。
【符号の説明】
1…マルエージング鋼の薄板、 2…ドラム、 3…加熱炉、 4…リング。
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a method of manufacturing a ring used for a continuously variable transmission belt or the like.
[0002]
[Prior art]
Conventionally, a ring used for a continuously variable transmission belt or the like is manufactured by the following manufacturing method. First, end portions of a thin plate of maraging steel, which is super strong steel, are welded together to form a cylindrical drum, and a first solution treatment is performed on the drum. Next, the solutionized drum is cut into a predetermined width to form a ring, and after the ring is rolled, a second solution treatment is performed on the rolled ring. Then, after correcting the melted ring to a predetermined circumferential length and improving the hardness by aging and nitriding treatment, a plurality of rings are laminated together to form a laminated ring, and a continuously variable transmission belt And
[0003]
In the manufacturing method, the first solution formation on the drum after welding is performed in order to homogenize the hardness that has been partially hardened by the heat during the welding, and by performing the solution formation, Rolling after forming a ring by cutting the drum into a predetermined width can be easily performed. The solution treatment is generally performed by heating at a temperature equal to or higher than the recrystallization temperature of the maraging steel. At this time, the maraging steel contains Ti, Mo, etc. as aging precipitation strengthening elements. When these elements, particularly Ti, are oxidized, the predetermined hardness may not be obtained by the subsequent aging treatment. Therefore, the solution treatment is performed in a vacuum furnace in order to avoid oxidation of the aging precipitation strengthening element.
[0004]
On the other hand, the rolled ring has a rolled structure in which metal crystals are crushed by the rolling. Nitrogen does not easily penetrate in the subsequent nitriding treatment, and nitriding may not be performed uniformly. Therefore, in order to restore the deformed metal crystal particle shape and facilitate the nitriding treatment on the rolled ring, a second solution treatment is performed.
[0005]
The second solution treatment is also generally performed by heating at a temperature higher than the recrystallization temperature of the maraging steel, and it is desirable that the aging precipitation strengthening element is not oxidized. However, since the vacuum furnace is expensive, the second solution treatment is performed using a heating furnace in which the inside of the furnace is a reducing atmosphere. As the reducing atmosphere, for example, a nitrogen atmosphere containing 1 to 10% hydrogen is used. The nitrogen atmosphere contains a small amount of oxygen. However, by reacting the hydrogen with oxygen, the oxygen can be removed and oxidation of the aging precipitation strengthening element can be prevented. According to the conventional manufacturing method, the number of vacuum furnaces can be reduced by reducing the number of vacuum furnaces by performing the second solution out of the two solutions in a reducing atmosphere using a heating furnace. it can.
[0006]
However, if separate furnaces are used for the first and second solution treatments, there is an inconvenience that the production cost cannot be sufficiently reduced.
[0007]
[Problems to be solved by the invention]
An object of the present invention is to provide a method of manufacturing a laminated ring that can eliminate such inconvenience and further reduce the manufacturing cost.
[0008]
[Means for Solving the Problems]
In order to eliminate the inconvenience, the present inventors have repeatedly studied the conditions for solution treatment between the drum after welding and the ring after rolling, and as a result, Ti, Mo contained as an aging precipitation strengthening element in the maraging steel. In order to prevent such oxidation, it has been found that a complete vacuum is not necessarily required, and a pressure of 10 −3 Pa or less is sufficient, and the present invention has been completed.
[0009]
Therefore, in order to achieve the above object, the ring manufacturing method of the present invention includes a step of welding the ends of thin sheets of maraging steel containing Ti and Mo as aging precipitation elements to form a ring-shaped drum, and A first solution treatment for the drum after welding, a step of cutting the solution-formed drum into a predetermined width to form a ring, and rolling the ring; and a second solution for the rolled ring In a method for manufacturing a ring, comprising: a step of performing heat treatment; and a step of aging and nitriding after correcting the solutionized ring to a predetermined circumference, the first solution treatment on the drum after welding, and the rolling The second solution treatment for the subsequent ring is performed using the same heating furnace and under the same temperature condition under a pressure of 10 −3 Pa or less.
[0010]
Under a pressure of 10 −3 Pa or less, Fe that is the base material of the maraging steel and Mo that is one of the aging strengthening elements are substantially in the reduction region. Like Mo, Ti, which is one of the aging strengthening elements, is not reduced under a pressure of 10 −3 Pa or less, but is not at least oxidized.
[0011]
Therefore, according to the manufacturing method of the present invention, by the atmosphere during the heating furnace and 10 -3 Pa or less pressure, the first solution for the previous SL drum after welding, the relative ring after the rolling Since the solution treatment of 2 can be performed under the same conditions using the same heating furnace, the manufacturing cost can be greatly reduced.
[0012]
DETAILED DESCRIPTION OF THE INVENTION
Next, embodiments of the present invention will be described in more detail with reference to the accompanying drawings. FIG. 1 is a process diagram schematically showing the manufacturing method of the present embodiment, FIG. 2 is a graph showing hardness before and after solutionizing according to the manufacturing method of the present invention to a drum after welding, and FIG. 3 is a graph after welding. It is a graph which shows the hardness after performing solution treatment according to the manufacturing method of this invention with respect to the drum and the ring after rolling.
[0013]
In the production method of this embodiment, C is 0.03% or less, Si is 0.10% or less, Mn is 0.10% or less, P is 0.01% or less, and S is 0.01% or less. Steel, 18-19% Ni, 4.7-5.2% Mo, 0.05-0.15% Al, 0.50-0.70% Ti, 8.5-9. A laminated ring for a continuously variable transmission is manufactured in accordance with the process of FIG. 1 using maraging steel which is 18% Ni steel containing 5% Co. Of the maraging steel composition, Ti and Mo are aging precipitation strengthening elements. When Ti and Mo are oxidized, uniform aging hardness cannot be obtained in the subsequent aging treatment.
[0014]
In the manufacturing method of this embodiment, first, as shown in FIG. 1, a maraging steel thin plate 1 having the above composition is bent to form a loop, and then the ends are welded to form a cylindrical drum 2. . At this time, the maraging steel exhibits age hardening due to the heat of welding, and high hardness portions appear in portions around 1 mm on both sides from the welding center 2a of the drum 2.
[0015]
Then, next, the drum 2 is accommodated in the heating furnace 3, and the first solution treatment is performed at a temperature not lower than 10 −3 Pa and not lower than the recrystallization temperature of the maraging steel and not higher than 850 ° C. . In the first solution heat treatment, the pressure of the heating furnace 3 may be 10 −4 Pa or less, but it is difficult to achieve with normal vacuum evacuation, and the cost is increased.
[0016]
When the first solution is finished, the drum 2 is taken out of the heating furnace 3 and cut into a predetermined width to form a ring 4. Since the entire hardness of the drum 2 is homogenized as a result of the first solution treatment, the cutting can be easily performed and rolling is also facilitated. The ring 4 is then rolled at a rolling reduction of 40-50%.
[0017]
As a result of the rolling, a rolled structure in which metal crystals are crushed is formed in the ring 4, and in this state, nitrogen does not easily penetrate into the metal structure in the subsequent nitriding treatment. Then, next, the ring 4 is accommodated in the heating furnace 3 again, and the second solution treatment is performed under the same temperature condition as the first solution treatment under a pressure of 10 −3 Pa or less.
[0018]
When the second solution treatment is completed, the ring 4 is taken out of the heating furnace 3 and corrected to a predetermined circumference. The circumference correction is performed, for example, by applying a load in a direction perpendicular to the traveling direction of the ring 4 while rotating the ring 4 around a driving roller and a driven roller (not shown).
[0019]
Next, an aging treatment and a nitriding treatment are performed on the ring whose circumference has been corrected. The aging treatment is performed, for example, by holding the ring in a heating furnace (not shown) at a temperature in the range of 450 to 530 ° C. for 90 to 240 minutes. The nitriding treatment is performed by a method such as gas nitriding, gas soft nitriding, or salt bath nitriding.
[0020]
A plurality of rings 4 having a predetermined hardness by the aging / nitriding treatment are laminated together to form a laminated ring suitable as a power transmission belt for a continuously variable transmission.
[0021]
In the drum 2, when the ends of the maraging steel thin plates 1 are welded to each other, as shown in FIG. A portion with high hardness appears. Therefore, in the present embodiment, such a drum 2 is accommodated in the heating furnace 3, and the first solution treatment is performed under the temperature condition under a pressure of 10 −3 Pa or less. As a result, in the drum 2, Mo and Ti which are the aging strengthening elements and Fe which is the base material of the maraging steel are not oxidized, and the high hardness portion is eliminated, and the overall hardness is reduced as shown in FIG. It can be homogenized.
[0022]
On the other hand, the rolled ring 4 has a rolled structure in which metal crystals are crushed as a result of the rolling. Therefore, in this embodiment, such a drum 2 is accommodated in the heating furnace 3, and the second solution is formed under the same temperature condition as the first solution under a pressure of 10 −3 Pa or less. As a result, in the ring 4, the shape of the metal crystals in the rolled structure is restored to the state before rolling without oxidizing the Mo and Ti as the aging strengthening elements and Fe as the base material of the maraging steel. can do.
[0023]
As shown in FIG. 3, the ring 4 after the second solution forming has a uniform overall hardness, and it is clear that the particle shape of the metal crystal is restored to the state before rolling. From FIG. 3, the hardness of the ring 4 after the second solution treatment is substantially equal to the hardness of the drum 2 after the first solution treatment, and both solution treatments are 10 −3 Pa. It is clear that an equivalent effect can be obtained by carrying out under the same temperature conditions under the following pressure. The hardness of the drum 2 after the first solution treatment is the same as that shown in FIG. 2, but is reprinted for comparison.
[0024]
In the manufacturing method of the present embodiment, the second solution treatment with respect to the ring 4 may be performed independently of or simultaneously with the first solution treatment with respect to the drum 2 welded after the ring 4. When the second solution treatment for the ring 4 and the first solution treatment for the drum 2 are performed at the same time, the ring 4 takes time to restore the rolling structure, so the first solution treatment for the drum 2 is performed by the ring 4. For the same time as the second solution treatment. Further, a partition wall (not shown) is provided in the heating furnace 3 to divide the inside of the furnace into two sections, and in each section, the second solution for the ring 4 and the first solution for the drum 2 are performed independently. May be.
[0025]
According to the manufacturing method of the present embodiment, since the oxidation of the aging precipitation strengthening element is suppressed in the first and second solution treatments, it is possible to uniformly perform the aging treatment of the circumferentially corrected ring. it can. Further, in the second solution heat treatment, the metal crystal particle shape of the rolled structure is restored to the state before rolling, so that nitrogen easily penetrates into the metal structure and the nitriding treatment can be easily performed. .
[0026]
In this embodiment, equipment can be made common by performing the first solution heat treatment and the second solution heat treatment under the same temperature condition under the pressure of 10 −3 Pa or less using the same heating furnace 3. Cost can be reduced.
[Brief description of the drawings]
FIG. 1 is a process chart schematically showing an embodiment of a production method of the present invention.
FIG. 2 is a graph showing the hardness before and after solution welding according to the manufacturing method of the present invention is applied to a drum after welding.
FIG. 3 is a graph showing hardness after solution welding according to the manufacturing method of the present invention is applied to a drum after welding and a ring after rolling.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1 ... Thin sheet of maraging steel, 2 ... Drum, 3 ... Heating furnace, 4 ... Ring.

Claims (1)

時効析出元素としてTi、Moを含むマルエージング鋼の薄板の端部同士を溶接してリング状のドラムを形成する工程と、溶接後のドラムに対する第1の溶体化を行う工程と、溶体化されたドラムを所定幅に裁断してリングを形成し、該リングを圧延する工程と、圧延されたリングに対する第2の溶体化を行う工程と、溶体化されたリングを所定の周長に補正したのち時効及び窒化処理する工程とを備えるリングの製造方法において、
前記溶接後のドラムに対する第1の溶体化と、前記圧延後のリングに対する第2の溶体化とを、同一加熱炉を用い、10-3Pa以下の圧力下に同一温度条件で行うことを特徴とするリングの製造方法。
A process of forming a ring-shaped drum by welding ends of thin sheets of maraging steel containing Ti and Mo as aging precipitation elements , a process of performing a first solution treatment on the drum after welding, and a solution treatment. The drum was cut into a predetermined width to form a ring, the step of rolling the ring, the step of performing a second solution treatment on the rolled ring, and the solution-formed ring was corrected to a predetermined circumference. In the manufacturing method of the ring comprising the step of aging and nitriding afterwards,
The first solution treatment for the drum after welding and the second solution treatment for the ring after rolling are performed in the same temperature condition under the pressure of 10 −3 Pa or less using the same heating furnace. A method for manufacturing a ring.
JP2000244202A 2000-06-07 2000-08-11 Ring manufacturing method Expired - Fee Related JP3784622B2 (en)

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JP2000-170220 2000-06-07
JP2000170220 2000-06-07
JP2000244202A JP3784622B2 (en) 2000-06-07 2000-08-11 Ring manufacturing method

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JP3784622B2 true JP3784622B2 (en) 2006-06-14

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