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JP3826411B2 - Nitrification denitrification equipment - Google Patents
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JP3826411B2 - Nitrification denitrification equipment - Google Patents

Nitrification denitrification equipment Download PDF

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Publication number
JP3826411B2
JP3826411B2 JP13030195A JP13030195A JP3826411B2 JP 3826411 B2 JP3826411 B2 JP 3826411B2 JP 13030195 A JP13030195 A JP 13030195A JP 13030195 A JP13030195 A JP 13030195A JP 3826411 B2 JP3826411 B2 JP 3826411B2
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Prior art keywords
tank
denitrification
nitrification
sludge
granulation
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JP13030195A
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JPH08323395A (en
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敦 渡辺
哲朗 深瀬
倫明 田中
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Kurita Water Industries Ltd
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Kurita Water Industries Ltd
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Description

【0001】
【産業上の利用分野】
本発明は、都市下水等の、溶解性及び不溶性の有機物(BOD)を含む排水から、BOD、窒素、SS等を除去する硝化脱窒装置に関する。詳しくは、コンパクトな装置により、安定かつ効率的な脱窒処理を行える硝化脱窒装置に関する。
【0002】
【従来の技術】
従来、下水等の窒素除去を行う処理方式としては、一般に、浮遊式の微生物を用いた、いわゆる循環式活性汚泥法が採用されている。この処理方式は、図4に示す如く、最初沈殿池51、脱窒槽52、硝化槽53及び最終沈殿池54から構成される。原水は最初沈殿池51に導入されて固液分離される。上澄水が脱窒槽52を経て硝化槽53に導入され、硝化菌によりアンモニア性窒素や有機性窒素成分がNOX に硝化される。硝化槽53の流出水の一部が脱窒槽52に循環され、該脱窒槽52内において脱窒菌によりNOX 成分がN2 に還元され、大気に放出される。窒素濃度が十分に低くなった硝化槽53の流出水が最終沈澱池54に送られ、処理水と汚泥とに分離される、汚泥の一部は脱窒槽52に返送される。
【0003】
周知の通り、脱窒槽52の脱窒反応では、水素供与体として溶解性BODが消費される。
【0004】
【発明が解決しようとする課題】
上記従来の硝化脱窒装置には、次のような問題点がある。
【0005】
▲1▼ 装置設置面積が大きいため、設置スペースにゆとりのない都市部での設置は困難である。従来のBOD除去のための処理装置は、最初沈殿池、曝気槽及び最終沈殿池から構成され、このBOD除去装置であっても容量の大きい槽を3槽必要とするため設置面積は相当に大きいが、図4に示す窒素除去方式では、さらに脱窒槽も必要であり、BOD除去装置の2倍以上の設置面積を必要とする。
【0006】
▲2▼ 脱窒に必要な有機物源(溶解性のBOD成分)が不足すると窒素の除去が不十分になる場合がある。
【0007】
上記▲2▼のBODの不足の問題に対しては、最初沈殿池の分離汚泥中の有機物を嫌気処理して有機酸に変える有機酸化槽を設け、不溶性BODから脱窒に必要な溶解性BODを生成させるシステムも考案されている。しかし、この処理方式では、有機酸化槽が浮遊式反応槽であるため、比較的大きな設置面積を必要とするという欠点がある。
【0008】
本発明は上記従来の問題点を解決し、設置面積が小さくて足りるコンパクトな装置であって、しかも、原水の溶解性BOD濃度が低い場合であっても、不溶性の有機物を利用して脱窒に必要な有機物源を確保することにより、安定かつ効率的な脱窒を行うことができる硝化脱窒装置を提供することを目的とする。
【0009】
【課題を解決するための手段】
本発明の硝化脱窒装置は、排水中のSSを分離する固液分離手段と、該固液分離手段で分離された汚泥を造粒する造粒手段と、該固液分離手段で分離された分離水が導入されると共に、該造粒手段で造粒された造粒物が保持される脱窒槽と、該脱窒槽の流出水が導入される固定床式硝化槽と、該硝化槽の流出水の一部を脱窒槽に返送する手段と、該硝化槽の流出水の残部を処理水として系外へ排出する手段と、を備えてなる硝化脱窒装置であって、前記造粒手段は濾過部を有し、該造粒手段内の液体が該濾過部を通過して該造粒手段より排出されることを特徴とする。
【0010】
【作用】
本発明では、排水の固液分離手段で分離された汚泥を造粒して得られた造粒物、即ち、不性BODの造粒物を脱窒槽で保持して脱窒菌として使用する。このように汚泥を造粒して濃縮した造粒物を利用することにより、脱窒槽において汚泥を高濃度に保持することができるようになり、従来の浮遊方式のものに比べて脱窒槽の小型化が図れる。通常の場合、本発明に係る脱窒槽では、汚泥を10000〜50000ppmといった高濃度に保持することが可能である。
【0011】
また、汚泥を造粒することにより、スクリーン(多孔板、網、スリット等)等の簡易な手段で脱窒槽からの汚泥の流出を防止でき、脱窒槽での汚泥造粒物の滞留時間をHRT(水理的滞留時間)よりも長くすることができる。そして、脱窒槽内で不溶性BODの造粒物を長時間保持することにより、不溶性BODの可溶化が進行し、脱窒に必要なBOD成分が生成する。このため、排水中の溶解性BOD濃度が低い場合であっても、溶解性BODの不足分を、脱窒槽内における不溶性BODの可溶化で生成させたBOD成分を利用して、安定な窒素除去を行える。
【0012】
また、本発明では、硝化槽として固定床式硝化槽を用いるため、装置のより一層の小型化を図れる。即ち、固定床式硝化槽は、汚泥分離のための沈殿池を必要とせず、硝化槽当りの汚泥濃度を高く維持できるため、浮遊式硝化槽に比べて槽容量を小さくすることができる。
【0013】
特に、硝化槽を、浮上性担体で濾材層を形成した上向流式生物濾過槽とする場合には、槽容量を従来の硝化槽容量の1/3〜1/5と、大幅に縮減することができる。
【0014】
なお、本発明においては、硝化槽の逆洗排水を固液分離手段の分離汚泥と共に造粒手段に送給し、逆洗排水中のSSも造粒して脱窒槽に保持させるようにしても良い。このように逆洗排水を造粒手段に送給することにより、併せて逆洗排水の処理を行える。
【0015】
【実施例】
以下、図面を参照して本発明の硝化脱窒装置の実施例について詳細に説明する。
【0016】
図1は本発明の硝化脱窒装置の一実施例を示す系統図である。
【0017】
図1において、1は沈殿槽(最初沈澱池)、2は脱窒槽、3は造粒槽、4は硝化槽であり、V1 ,V2 はバルブである。
【0018】
本実施例においては、原水は、まず、配管11より固液分離手段としての沈殿槽1に導入され、粗大なSSが除去された分離水は配管12より抜き出され、脱窒槽2に導入される。
【0019】
一方、沈殿槽1で分離された汚泥(初沈汚泥)は、配管17より抜き出され、添加手段18,19よりそれぞれ無機塩(無機凝集剤)、高分子凝集剤(以下「ポリマー」と称す。)が添加された後、造粒槽3に導入される。
【0020】
造粒槽3においては、回転羽根を備える撹拌機3aの回転により液が旋回されるのに伴って汚泥が造粒され造粒物(ペレット)となる。
【0021】
即ち、初沈汚泥に添加された無機塩は、マイナスに帯電しているSSの荷電を中和して凝集させ、この凝集フロックが、造粒槽3内で撹拌される間にポリマーにより粗大化及び緻密化し、水との分離性に優れた造粒粒子となる。
【0022】
なお、この造粒槽3における造粒に当り、後述の硝化槽4の逆洗排水を初沈汚泥に混合し、逆洗排水の処理を系内で行うようにすることもできる。
【0023】
造粒槽3内の液体は、スクリーン(濾過部)3bを通過し、配管21を経て沈殿槽1へ返送される。造粒物は、少量の液と共に配管20を経て脱窒槽2へ送られる。なお、この脱窒槽2への汚泥造粒物の供給は、連続的であっても間欠的であっても良い。
【0024】
造粒槽3では、上述の如く、濾過部3bで水抜きしながら凝集造粒反応を行うため、小型の造粒槽により、硬く、大きな凝集フロックを造粒することができる。
【0025】
汚泥に添加する無機塩としては、硫酸バンド、塩化第二鉄、塩化アルミニウム、ポリ塩化アルミニウム、ポリ硫酸鉄などを用いることができる。
【0026】
これらの無機塩は、通常、SS分に対して0.5〜5重量%程度添加される。
【0027】
一方、ポリマーとしては、カチオン構成単位とアニオン構成単位とを分子内に有する両性ポリマーが好適であり、さらにカチオン構成単位とアニオン構成単位とのモル比が1より大きい、特に、2〜5の両性高分子凝集剤が望ましい。
【0028】
この両性高分子凝集剤としては、例えばアニオン性のモノマー成分とカチオン性のモノマー成分との共重合体、アニオン性のモノマー成分とカチオン性のモノマー成分とノニオン性のモノマー成分との共重合体、或いはアニオン性のモノマー成分とノニオン性のモノマー成分との共重合体のマンニッヒ変性物又はホフマン分解物などを挙げることができる。
【0029】
ここで、アニオン性のモノマー成分としては、例えばアクリル酸(AA)、アクリル酸ナトリウム(NaA)、メタクリル酸、メタクリル酸ナトリウムなどが挙げられる。また、カチオン性のモノマー成分としては、例えばジメチルアミノエチルアクリレート(DAA)、ジメチルアミノエチルメタクリレート(DAM)、ジメチルアミノプロピルアクリレート、ジメチルアミノプロピルメタクリレート、ジメチルアミノプロピルアクリルアミド(DAPAAm)、ジメチルアミノプロピルメタクリレート及びこれらの四級化物などを挙げることができる。四級化物としては、例えばジメチルアミノエチルアクリレートメチルクロリド四級化物などを挙げることができる。また、ジメチルアミノプロピルアクリルアミドの炭酸塩なども用いることができる。ノニオン性のモノマー成分としては、例えばアクリルアミド(AAm)、メタクリルアミド、N,N−ジメチルアクリルアミド、N,N−ジメチルメタクリルアミドなどを挙げることができる。これらの化合物の共重合体として、具体的にはDAA四級化物/AA/AAm共重合体、DAM四級化物/AA/AAm共重合体、DAPAAm/AA/AAm共重合体、DAA四級化物/AA共重合体、又はNaA/AAm共重合体のマンニッヒ変性物などを挙げることができる。
【0030】
これらの両性高分子凝集剤の添加量は、通常、SS分に対して0.5〜2.5重量%の範囲とするのが好適である。
【0031】
なお、本発明においては、これら無機塩の添加混合は、別途凝集槽を設けて行っても良い。また、ポリマーについては、図示の如く、パイプライン注入を行う他、造粒槽3に直接注入したり、別途設けた凝集槽に添加したりすることができる。また、ポリマーを2種類使用し、一方を凝集槽内添加又はパイプライン注入、他方を造粒槽直接注入というように、各々別々の注入手段で添加するようにしても良い。
【0032】
脱窒槽2においては、配管20より送給される初沈汚泥の造粒物を沈澱槽1からの上澄水及び硝化槽4からの循環水と共に撹拌機2aで撹拌する。これにより、脱窒反応と、造粒物の可溶化によるBOD成分の生成とが進行する。
【0033】
即ち、沈殿槽1、配管12、脱窒槽2及び配管13を経て硝化槽4内に導入された水は、硝化槽4内で、好気条件下、硝化細菌により、含有されるアンモニア性窒素(NH4 −N)等が硝酸性窒素又は亜硝酸性窒素(NOx −N)に酸化される。この硝化槽4の流出水が配管15より循環水として脱窒槽2に循環され、脱窒槽2内でこれらNOx −Nが、嫌気条件下、脱窒細菌により窒素(N2 )に還元されて除去される。
【0034】
この脱窒槽2においては、初沈汚泥の造粒物中の不溶性BOD成分が酸化されて有機酸が生成しているので、原水中の溶解性BODの濃度が低い場合であっても、脱窒に必要な有機物を十分に確保することができ、安定な脱窒処理を行える。
【0035】
脱窒槽2の処理水は、スクリーン2bを通過して配管13より硝化槽4に送給されるが、この際に、脱窒槽2内の汚泥は造粒されたペレット状となっているため、多孔板、網、スリットなどのスクリーン2bよりなる簡易な濾過手段を設けることにより、汚泥が処理水と共に流出することを容易に防止することができる。
【0036】
本発明では、このように、造粒汚泥を脱窒槽2内に滞留させるようにしているため、脱窒槽2内の汚泥濃度を、通常の場合、10000〜50000ppm程度と高く維持することができる。これにより、脱窒槽の小型化を図ることができる。
【0037】
脱窒槽2内の余剰汚泥は、配管22より連続的又は間欠的に引き抜かれ、脱水機により脱水処理される。
【0038】
脱窒槽2の流出水は、前述の如く、配管13を経て硝化槽4に導入されて硝化処理され、硝化槽4の流出水はその一部が配管15より脱窒槽2に循環され、残部は配管14より処理水として系外へ排出される。
【0039】
本実施例において、硝化槽4は、ポリスチレン、ポリプロピレンや、ウレタン樹脂等を直径3〜10mmの球状や、不定形状に発泡成形した、比重が極めて小さい浮上性の濾材を担体とする濾材層4aが形成された上向流式生物膜濾過槽であり、濾材層4aの下部に設けた散気管4bによる散気で硝化が行われる。
【0040】
本発明において、硝化槽は、固定床式であれば良く、このように浮上性濾材を担体とする上向流式生物膜濾過槽の他、砂、活性炭、合成樹脂などの沈降性濾材を担体とし、被処理水を下向流通水する下向流式生物膜濾過槽であっても良い。
【0041】
本発明では、このような固定床式硝化槽を用いるため、汚泥分離のための沈殿池が不要となり、また、硝化槽内の汚泥濃度を高く維持することにより、浮遊式の場合に比べて、硝化槽を小型化することができる。
【0042】
この硝化槽4から脱窒槽2に循環される循環水量は、通常の場合、装置に流入する原水量に対する循環水量の容量比(以下「循環比」と称す。)で、2〜4程度とするのが好ましい。
【0043】
本実施例の硝化脱窒装置によれば、沈殿槽1における固液分離処理と脱窒槽2及び硝化槽4による硝化脱窒処理で、BOD及び窒素が高度に除去された処理水が得られる。
【0044】
なお、本発明に好適な造粒槽(凝集濃縮装置)について図2,3を参照して説明する。
【0045】
図2,3において、31は円筒槽であり、該円筒槽31の中心部に前記撹拌機3aが設けられている。この撹拌機3aは、モータ、変速機により回転駆動される回転軸32、該回転軸32に対し上下二段に、夫々180°の位相で放射状に設けられた撹拌羽根33,34を備えている。前記濾過部3bは、円筒槽31の内周に同曲率の円弧部を沿わせて設置された半円形よりも少し小さい有底の濾過筒37と、該濾過筒37の底37’に、円筒層31と同心に設けられた多数の円弧形のスリット38とを備えてなる。
【0046】
濾過筒37にはフック35が設けられており、このフック35が円筒槽31の上縁に係止することにより濾過筒37が固定される。
【0047】
濾過筒37の上端と円筒槽31の上端とは同レベルである。濾過筒37の底37’は上段の撹拌羽根33の上縁から上に1〜10mm位しか離れて居らず、接近している。必要ならば、上記撹拌羽根33の上縁にゴム板を取付け、回転中はこのゴム板で濾過筒37の底37’を撫でるようにしても良い。スリット38の幅は5mm以下、好ましくは1〜2mm程度、スリットの円筒方向に隣接した間隔は2mm程度、相互に内外のスリットの半径方向の間隔は5mm程度である。
【0048】
なお、撹拌羽根の上段のもの33は、図示の如く回転軸32に固定された基部から先端までの全長にわたり上下方向の幅が一定な平板とすることが好ましい。
【0049】
円筒槽31には、また、その槽壁を貫いて濾過筒37内から濾過水を排出するための排水管21が設けてある。
【0050】
配管17から槽内底部の中心部に供給された初沈汚泥(無機塩及びポリマーを含む)は、回転軸32に取付けられた撹拌羽根33,34の撹拌作用で槽内に滞流する間に均一に混合されて反応する。濾過筒37の底のスリット38を通じて該濾過筒37内に注入した水(分離液)は配管21から槽外に排出される。この結果、連続して供給される汚泥は充分に濃縮され、強度の高い造粒物となる。この造粒物は配管20から排出される。
【0051】
この濾過筒37の底37’の直ぐ真下では、撹拌羽根33が旋回することにより水平な旋回流aが生じる。濾過筒の底37’に設けたスリット38はこの水平旋回流aに沿った同心の円弧形とされている。このため、液中の凝集フロックや繊維状物質は底37’の下をスリット38の延在方向と同方向に流れる。この結果、フロック等はスリット38に引っ掛かることがないと共に、凝集フロックは底37’の下を転がってより緻密で、強固な造粒物となる。
【0052】
なお、下段の撹拌翼34は、全長の約半分程の回転軸32に取付けられた側の基部40の上下方向の幅が狭く、残りの自由端部41の上下方向の幅が広い羽子板形とするのが好ましい。このようにすると、上段の撹拌羽根33によって生じる水平旋回流aの下で下段の羽子板形撹拌羽根34は幅広い自由端部41で外向きに水を押し、その流れは旋回しながら槽の内周付近では上昇流bと下降流b’に別れ、上昇流bは上の平板形撹拌羽根33による水平旋回流aと接触して中心部に向け下降し、又、下降流b’は槽の底面に沿って中心部で上昇し、かくして槽内の中心部と底部では旋回する上下の循環流が生じ、槽内底部の中心部に供給された汚泥と凝集剤はこの流れb,b’に乗って既に生じた凝集フロックと効率良く混合接触して良好に凝集する。そして、図示の如く幅広い自由端部41を羽根の旋回方向に対し後退するような角度(例えば45°)で屈曲させると、この自由端部が水を槽の内周に向かって押すことがより強まり、より強力な旋回循環流b,b’が得られるので混合、接触効率はより向上する。更に、円筒槽31の内周の下端部及び、上段の撹拌羽根33と下段の撹拌羽根34の中間部に位置して撹拌羽根の旋回方向に延長し、先端に向かって次第に内周から離れる直線状又は図示の如き弯曲した案内板42,43を設けると、上の循環流bが水平旋回流aの下に沿って流れたのち中心部で下向し、又、下の循環流b’が槽底に沿ったのち中心部で上向するのを夫々補助でき、同様に混合、接触効率を向上させることができる。
【0053】
濾過筒については、上述のように円筒槽内に設ける場合を説明したが、濾過筒は円筒槽外に設けても良い。その場合は、濾過筒を円筒槽の槽壁の上部外周の外に設け、濾過筒で囲まれた円筒槽の槽壁の上部に円筒槽内の液を濾過して濾過筒に入れるためのスリットを水平に設け、かつ、撹拌羽根の外縁を円筒槽の槽壁の上部内周に1〜10mmの間隔で近接させれば良い。必要ならば、上記撹拌羽根の外縁にゴム板を取付け、回転中はこのゴム板でスリットが設けられた円筒槽の槽壁の内周を撫でるようにしても良い。このような構造の造粒槽においても、円筒槽底部から供給された汚泥は、槽内で撹拌されて凝集し、その間、槽壁のスリットを通じ濾過筒に入る水はポンプ等で槽外に排水するため、連続して供給される汚泥は十分に濃縮され、強度の高いフロックに成長した後、排出される。スリットが設けられた円筒槽の槽壁上部内周に近接して水平に旋回する撹拌羽根により、円筒槽内に生じたフロックは押されてスリット沿いに槽壁内周を転がるので、フロックはスリットにひっかかって詰まることがないと共に、スリット沿いに槽壁内周を転がることによって緻密で強固なものとなる。
【0054】
なお、この造粒槽における処理条件としては、槽内濃度が0.5〜3重量/容積%、撹拌羽根の周速5〜20m/分を採用するのが好ましい。
【0055】
以下に具体的な実施例及び比較例を挙げて、本発明をより詳細に説明する。
【0056】
実施例1
図1に示す本発明の硝化脱窒装置により、下記水質の排水を下記運転条件で処理した。
【0057】
なお、硝化槽としては、浮上性の合成濾材を装填した上向流式生物濾過槽を用いた。
【0058】
原水水質
T−BOD(全BOD):130mg/l
S−BOD(溶解性BOD):80mg/l
T−N(全窒素):30mg/l
SS:200mg/l
運転条件
沈殿槽表面積負荷:30m/day
沈殿槽滞留時間:2.4hr
脱窒槽からの余剰汚泥引き抜き率:造粒汚泥量の80%
脱窒槽汚泥濃度:15000ppm
脱窒槽滞留時間:0.7hr
硝化槽滞留時間:0.9hr
循環比:3
無機塩(ポリ塩化アルミニウム)添加量:SSに対して1重量%
両性ポリマー(商品名「クリベスト P702」栗田工業株式会社製)
添加量:SSに対して1.5重量%
得られた処理水の水質を表1に示す。また、表1には、装置の総滞留時間(沈殿槽、脱窒槽及び硝化槽の合計の滞留時間)を併記した。
【0059】
比較例1
図2に示す従来の装置により、実施例1で処理した排水と同水質の排水の処理を行った。運転条件は下記の通りとした。
【0060】
最初沈殿池表面積負荷率:30m/day
最終沈殿池表面積負荷率:20m/day
脱窒槽滞留時間:4.8hr
硝化槽滞留時間:2.2hr
循環比:3
得られた処理水の水質を表1に示す。また、表1には、装置の総滞留時間(最初沈殿池、脱窒槽、硝化槽及び最終沈殿池の合計の滞留時間)を併記した。
【0061】
【表1】

Figure 0003826411
【0062】
表1より次のことが明らかである。
【0063】
即ち、本発明によれば、従来に比べて約20%程度の滞留時間で窒素成分を十分に処理することが可能である。従って、装置を小型、小容量化できる。また、処理水についても、従来法では溶解性BODの不足により硝酸性窒素が残留し、全窒素濃度が高いのに対し、本発明によれば、脱窒が円滑に進行し、十分に窒素濃度の低い高水質処理水を得ることができる。
【0064】
【発明の効果】
以上詳述した通り、本発明の硝化脱窒装置によれば、
▲1▼ 装置の設置面積が大幅に低減される。
▲2▼ 流入溶解性BOD濃度が低下しても、安定して脱窒を行える。
▲3▼ 硝化、脱窒性能が向上する。
▲4▼ 流量変動に対する耐性が高くなり、運転管理が容易になる。
といった効果が奏され、コンパクトで管理が容易な装置により、排水中の窒素を効率的に処理して高水質処理水を安定に得ることができる。
【図面の簡単な説明】
【図1】本発明の硝化脱窒装置の一実施例を示す系統図である。
【図2】本発明に好適な造粒槽の一例を示す一部断面斜視図である。
【図3】図2に示す造粒槽の平面図である。
【図4】従来例を示す系統図である。
【符号の説明】
1 沈殿槽
2 脱窒槽
3 造粒槽
4 硝化槽[0001]
[Industrial application fields]
The present invention relates to a nitrification denitrification apparatus for removing BOD, nitrogen, SS, and the like from wastewater containing soluble and insoluble organic matter (BOD) such as municipal sewage. Specifically, the present invention relates to a nitrification denitrification apparatus that can perform a stable and efficient denitrification process with a compact apparatus.
[0002]
[Prior art]
Conventionally, as a treatment method for removing nitrogen from sewage or the like, a so-called circulating activated sludge method using floating microorganisms is generally employed. As shown in FIG. 4, this processing method is composed of an initial settling tank 51, a denitrification tank 52, a nitrification tank 53, and a final settling tank 54. The raw water is first introduced into the settling basin 51 and separated into solid and liquid. Supernatant water is introduced into the nitrification tank 53 through the denitrification tank 52, ammonia nitrogen and organic nitrogen components are nitrified in the NO X by the nitrifying bacteria. A part of the effluent water from the nitrification tank 53 is circulated to the denitrification tank 52, and the NO x component is reduced to N 2 by denitrifying bacteria in the denitrification tank 52 and released to the atmosphere. The effluent from the nitrification tank 53 with a sufficiently low nitrogen concentration is sent to the final sedimentation basin 54 and separated into treated water and sludge. A part of the sludge is returned to the denitrification tank 52.
[0003]
As is well known, the denitrification reaction in the denitrification tank 52 consumes soluble BOD as a hydrogen donor.
[0004]
[Problems to be solved by the invention]
The conventional nitrification denitrification apparatus has the following problems.
[0005]
(1) Since the installation area of the device is large, it is difficult to install it in urban areas where there is no room for installation space. A conventional processing apparatus for removing BOD is composed of a first sedimentation tank, an aeration tank, and a final sedimentation tank. Even this BOD removal apparatus requires three tanks with a large capacity, so the installation area is considerably large. However, the nitrogen removal method shown in FIG. 4 further requires a denitrification tank, and requires an installation area twice or more that of the BOD removal device.
[0006]
(2) If the organic substance source (soluble BOD component) necessary for denitrification is insufficient, nitrogen removal may be insufficient.
[0007]
To solve the problem of shortage of BOD in (2) above, an organic oxidation tank that converts the organic matter in the separated sludge of the sedimentation basin to an organic acid by anaerobic treatment is provided, and soluble BOD required for denitrification from insoluble BOD There is also a system for generating the. However, this processing method has a drawback that a relatively large installation area is required because the organic oxidation tank is a floating reaction tank.
[0008]
The present invention solves the above-mentioned conventional problems and is a compact apparatus that requires a small installation area, and even if the soluble BOD concentration of raw water is low, denitrification is performed using insoluble organic matter. It is an object of the present invention to provide a nitrification / denitrification apparatus capable of performing denitrification stably and efficiently by securing a necessary organic material source.
[0009]
[Means for Solving the Problems]
The nitrification denitrification apparatus of the present invention is separated by solid-liquid separation means for separating SS in waste water, granulation means for granulating sludge separated by the solid-liquid separation means, and solid-liquid separation means. A denitrification tank in which the separated water is introduced and the granulated product granulated by the granulation means is held, a fixed bed nitrification tank into which the outflow water of the denitrification tank is introduced, and an outflow of the nitrification tank A nitrification denitrification apparatus comprising: means for returning a part of water to a denitrification tank; and means for discharging the remainder of the effluent of the nitrification tank as treated water to the outside of the system. It has a filtration part, The liquid in this granulation means passes through this filtration part, and is discharged | emitted from this granulation means, It is characterized by the above-mentioned.
[0010]
[Action]
In the present invention, it granules obtained by granulating the separated sludge in waste water solid-liquid separation means, i.e., the granulated product not soluble soluble BOD held in denitrification used as denitrifying bacteria. By using the granulated product that is obtained by granulating and concentrating sludge in this way, it becomes possible to keep the sludge at a high concentration in the denitrification tank, and the denitrification tank is smaller than the conventional floating system. Can be achieved. Normally, in the denitrification tank according to the present invention, sludge can be maintained at a high concentration of 10,000 to 50,000 ppm.
[0011]
In addition, by granulating sludge, it is possible to prevent sludge from flowing out of the denitrification tank with simple means such as screens (perforated plates, nets, slits, etc.), and the residence time of sludge granules in the denitrification tank is reduced to HRT. It can be made longer than (hydraulic residence time). And the insoluble BOD granule is kept for a long time in the denitrification tank, solubilization of the insoluble BOD proceeds, and a BOD component necessary for denitrification is generated. For this reason, even when the soluble BOD concentration in the waste water is low, stable nitrogen removal is performed by using the BOD component generated by solubilization of the insoluble BOD in the denitrification tank. Can be done.
[0012]
In the present invention, since the use of fixed bed nitrification reactor as a nitrification tank, thereby to further miniaturization of the apparatus. That is, the fixed bed type nitrification tank does not require a sedimentation basin for separating sludge and can maintain a high sludge concentration per nitrification tank, so that the tank capacity can be reduced as compared with the floating type nitrification tank.
[0013]
In particular, when the nitrification tank is an upward flow type biological filtration tank in which a filter medium layer is formed with a floating carrier, the tank capacity is greatly reduced to 1/3 to 1/5 of the conventional nitrification tank capacity. be able to.
[0014]
In the present invention, the backwash wastewater from the nitrification tank is fed to the granulation means together with the separated sludge from the solid-liquid separation means, and the SS in the backwash wastewater is also granulated and held in the denitrification tank. good. Thus, by supplying backwash wastewater to the granulating means, the backwash wastewater can be treated together.
[0015]
【Example】
Hereinafter, embodiments of the nitrification denitrification apparatus of the present invention will be described in detail with reference to the drawings.
[0016]
FIG. 1 is a system diagram showing an embodiment of the nitrification denitrification apparatus of the present invention.
[0017]
In Figure 1, 1 is a sedimentation tank (first sedimentation basin), 2 denitrification tank, 3 granulating vessel, 4 is a nitrification tank, V 1, V 2 is a valve.
[0018]
In this embodiment, the raw water is first introduced into the sedimentation tank 1 as solid-liquid separation means from the pipe 11, and the separated water from which coarse SS has been removed is extracted from the pipe 12 and introduced into the denitrification tank 2. The
[0019]
On the other hand, the sludge (primary sludge) separated in the sedimentation tank 1 is extracted from the pipe 17 and is added with an inorganic salt (inorganic flocculant) and a polymer flocculant (hereinafter referred to as “polymer”) from the adding means 18 and 19, respectively. .) Is added to the granulation tank 3.
[0020]
In the granulation tank 3, sludge is granulated into a granulated product (pellet) as the liquid is swirled by the rotation of the agitator 3 a having rotating blades.
[0021]
That is, the inorganic salt added to the initial sedimentation sludge is aggregated by neutralizing the negatively charged SS charge, and this aggregated floc is coarsened by the polymer while being stirred in the granulating tank 3. And it becomes densified and becomes a granulated particle excellent in separability from water.
[0022]
In addition, in granulation in this granulation tank 3, the backwash waste water of the below-mentioned nitrification tank 4 can be mixed with the initial sedimentation sludge, and the process of backwash waste water can also be performed in a system.
[0023]
The liquid in the granulation tank 3 passes through the screen (filter unit) 3b, and is returned to the precipitation tank 1 through the pipe 21. The granulated product is sent to the denitrification tank 2 through the pipe 20 together with a small amount of liquid. The supply of sludge granules to the denitrification tank 2 may be continuous or intermittent.
[0024]
In the granulation tank 3, as described above, the aggregation granulation reaction is performed while draining with the filtration unit 3 b, and thus a hard and large aggregation floc can be granulated with a small granulation tank.
[0025]
As the inorganic salt added to the sludge, sulfuric acid band, ferric chloride, aluminum chloride, polyaluminum chloride, polyiron sulfate and the like can be used.
[0026]
These inorganic salts are usually added in an amount of about 0.5 to 5% by weight based on the SS content.
[0027]
On the other hand, the polymer is preferably an amphoteric polymer having a cation constituent unit and an anion constituent unit in the molecule, and the molar ratio of the cation constituent unit to the anion constituent unit is greater than 1, particularly 2 to 5 amphoteric. Polymer flocculants are desirable.
[0028]
Examples of the amphoteric polymer flocculant include a copolymer of an anionic monomer component and a cationic monomer component, a copolymer of an anionic monomer component, a cationic monomer component, and a nonionic monomer component, Alternatively, a Mannich modified product or a Hoffmann decomposition product of a copolymer of an anionic monomer component and a nonionic monomer component can be used.
[0029]
Here, examples of the anionic monomer component include acrylic acid (AA), sodium acrylate (NaA), methacrylic acid, and sodium methacrylate. Examples of the cationic monomer component include dimethylaminoethyl acrylate (DAA), dimethylaminoethyl methacrylate (DAM), dimethylaminopropyl acrylate, dimethylaminopropyl methacrylate, dimethylaminopropyl acrylamide (DAPAAm), dimethylaminopropyl methacrylate, and These quaternized compounds can be mentioned. Examples of the quaternized product include dimethylaminoethyl acrylate methyl chloride quaternized product. Further, dimethylaminopropylacrylamide carbonate and the like can also be used. Examples of the nonionic monomer component include acrylamide (AAm), methacrylamide, N, N-dimethylacrylamide, N, N-dimethylmethacrylamide and the like. As a copolymer of these compounds, specifically, DAA quaternized product / AA / AAm copolymer, DAM quaternized product / AA / AAm copolymer, DAPAAm / AA / AAm copolymer, DAA quaternized product / AAA copolymer or Mannich modified product of NaA / AAm copolymer.
[0030]
The amount of these amphoteric polymer flocculants added is usually preferably in the range of 0.5 to 2.5% by weight relative to the SS content.
[0031]
In the present invention, the addition and mixing of these inorganic salts may be performed by providing a separate agglomeration tank. As shown in the figure, the polymer can be injected directly into the granulation tank 3 or added to a separately provided agglomeration tank. Further, two types of polymers may be used, and one may be added by separate injection means such that one is added in the coagulation tank or pipeline injection, and the other is directly injected into the granulation tank.
[0032]
In the denitrification tank 2, the granulated material of the first settling sludge fed from the pipe 20 is stirred by the stirrer 2 a together with the supernatant water from the precipitation tank 1 and the circulating water from the nitrification tank 4. Thereby, a denitrification reaction and the production | generation of the BOD component by solubilization of a granulated material progress.
[0033]
That is, water introduced into the nitrification tank 4 through the precipitation tank 1, the pipe 12, the denitrification tank 2 and the pipe 13 is ammonia nitrogen (which is contained in the nitrification tank 4 by nitrifying bacteria under aerobic conditions. NH 4 —N) and the like are oxidized to nitrate nitrogen or nitrite nitrogen (NO x —N). The effluent nitrification tank 4 is circulated to the denitrification tank 2 as circulating water from the pipe 15, these NO x -N in denitrification within 2, anaerobic conditions are reduced to nitrogen (N 2) by denitrifying bacteria Removed.
[0034]
In this denitrification tank 2, since the insoluble BOD component in the granulated product of the first settling sludge is oxidized to produce an organic acid, denitrification is performed even when the concentration of soluble BOD in the raw water is low. It is possible to secure sufficient organic substances necessary for the stable denitrification treatment.
[0035]
The treated water in the denitrification tank 2 passes through the screen 2b and is fed from the pipe 13 to the nitrification tank 4, but at this time, the sludge in the denitrification tank 2 is in the form of granulated pellets, By providing a simple filtration means comprising a screen 2b such as a perforated plate, a net, and a slit, it is possible to easily prevent sludge from flowing out together with the treated water.
[0036]
In this invention, since the granulated sludge is made to stay in the denitrification tank 2 in this way, the sludge concentration in the denitrification tank 2 can be normally maintained as high as about 10,000 to 50,000 ppm. Thereby, size reduction of a denitrification tank can be achieved.
[0037]
Excess sludge in the denitrification tank 2 is withdrawn continuously or intermittently from the pipe 22 and dehydrated by a dehydrator.
[0038]
As described above, the effluent from the denitrification tank 2 is introduced into the nitrification tank 4 via the pipe 13 and subjected to nitrification treatment. A part of the effluent from the nitrification tank 4 is circulated from the pipe 15 to the denitrification tank 2, and the remainder is It is discharged out of the system as treated water from the pipe 14.
[0039]
In the present embodiment, the nitrification tank 4 has a filter medium layer 4a in which polystyrene, polypropylene, urethane resin or the like is foamed into a spherical shape with a diameter of 3 to 10 mm or an indefinite shape, and a floatable filter medium having a very small specific gravity is used as a carrier. It is the formed upward flow type biofilm filtration tank, and nitrification is performed by aeration by the aeration tube 4b provided in the lower part of the filter medium layer 4a.
[0040]
In the present invention, the nitrification tank may be a fixed bed type, and in addition to the upward flow type biofilm filtration tank using the floatable filter medium as a carrier, sedimentary filter medium such as sand, activated carbon and synthetic resin is supported as a carrier. And it may be a downward flow type biofilm filtration tank in which the treated water flows downward.
[0041]
In the present invention, since such a fixed bed type nitrification tank is used, a sedimentation basin for separating sludge becomes unnecessary, and by maintaining a high sludge concentration in the nitrification tank, compared to a floating type, The nitrification tank can be downsized.
[0042]
The amount of circulating water circulated from the nitrification tank 4 to the denitrification tank 2 is usually about 2 to 4 in volume ratio of the circulating water amount to the raw water amount flowing into the apparatus (hereinafter referred to as “circulation ratio”). Is preferred.
[0043]
According to the nitrification denitrification apparatus of the present embodiment, treated water from which BOD and nitrogen are highly removed can be obtained by solid-liquid separation treatment in the precipitation tank 1 and nitrification denitrification treatment by the denitrification tank 2 and the nitrification tank 4.
[0044]
In addition, the granulation tank (coagulation concentration apparatus) suitable for this invention is demonstrated with reference to FIG.
[0045]
2 and 3, reference numeral 31 denotes a cylindrical tank, and the agitator 3 a is provided at the center of the cylindrical tank 31. The stirrer 3a includes a rotating shaft 32 that is rotationally driven by a motor and a transmission, and stirrer blades 33 and 34 that are provided in two upper and lower stages with respect to the rotating shaft 32 and are radially provided with a phase of 180 °. . The filtration part 3b is a cylinder having a bottomed filter cylinder 37 slightly smaller than a semicircular shape installed along an arc part of the same curvature along the inner periphery of the cylindrical tank 31, and a bottom 37 ′ of the filter cylinder 37. A plurality of arc-shaped slits 38 provided concentrically with the layer 31 are provided.
[0046]
The filter tube 37 is provided with a hook 35, and the filter tube 37 is fixed by the hook 35 engaging with the upper edge of the cylindrical tank 31.
[0047]
The upper end of the filter cylinder 37 and the upper end of the cylindrical tank 31 are at the same level. The bottom 37 ′ of the filter cylinder 37 is only about 1 to 10 mm away from the upper edge of the upper stirring blade 33 and is approaching. If necessary, a rubber plate may be attached to the upper edge of the stirring blade 33, and the bottom 37 'of the filter cylinder 37 may be stroked with this rubber plate during rotation. The width of the slit 38 is 5 mm or less, preferably about 1 to 2 mm, the distance between adjacent slits in the cylindrical direction is about 2 mm, and the distance between the inner and outer slits in the radial direction is about 5 mm.
[0048]
Note that the upper one 33 of the stirring blade is preferably a flat plate having a constant vertical width over the entire length from the base fixed to the rotating shaft 32 to the tip as shown.
[0049]
The cylindrical tank 31 is also provided with a drain pipe 21 for discharging filtered water from the filter cylinder 37 through the tank wall.
[0050]
While the first settling sludge (including inorganic salt and polymer) supplied from the pipe 17 to the center of the bottom of the tank is stagnating in the tank by the stirring action of the stirring blades 33 and 34 attached to the rotary shaft 32. Reacts evenly mixed. Water (separated liquid) injected into the filter cylinder 37 through the slit 38 at the bottom of the filter cylinder 37 is discharged from the pipe 21 to the outside of the tank. As a result, the continuously supplied sludge is sufficiently concentrated and becomes a granulated product having high strength. This granulated material is discharged from the pipe 20.
[0051]
Just below the bottom 37 ′ of the filter cylinder 37, a horizontal swirling flow a is generated by the swirling of the stirring blade 33. The slit 38 provided in the bottom 37 'of the filter cylinder has a concentric arc shape along the horizontal swirling flow a. For this reason, the aggregated floc and the fibrous substance in the liquid flow under the bottom 37 ′ in the same direction as the extending direction of the slit 38. As a result, flocs and the like are not caught by the slits 38, and the aggregated floc rolls under the bottom 37 'to become a denser and stronger granulated product.
[0052]
The lower agitating blade 34 has a wing plate shape in which the vertical width of the base 40 on the side attached to the rotary shaft 32, which is about half the total length, is narrow and the vertical width of the remaining free end 41 is wide. It is preferable to do this. In this way, the lower blade-shaped stirring blade 34 pushes water outward at the wide free end 41 under the horizontal swirling flow a generated by the upper stirring blade 33, and the flow is swirling while the inner periphery of the tank is swung. In the vicinity, it is divided into an upward flow b and a downward flow b ′, the upward flow b comes into contact with the horizontal swirling flow a by the flat plate-shaped stirring blade 33 and descends toward the center, and the downward flow b ′ is the bottom surface of the tank. Thus, the upper and lower circulation flows swirling at the center and bottom of the tank, and the sludge and the flocculant supplied to the center of the tank bottom ride on the flows b and b ′. Thus, the agglomeration flocs already produced are efficiently mixed and brought into contact with each other for good aggregation. Then, as shown in the figure, when the wide free end 41 is bent at an angle (for example, 45 °) so as to recede with respect to the swirling direction of the blade, the free end pushes water toward the inner periphery of the tank. Strengthening and stronger swirl circulation flows b and b 'are obtained, so that the mixing and contact efficiency is further improved. Furthermore, it is located at the lower end portion of the inner periphery of the cylindrical tank 31 and at the intermediate portion between the upper stirring blade 33 and the lower stirring blade 34, extends in the turning direction of the stirring blade, and gradually moves away from the inner periphery toward the tip. If the curved guide plates 42 and 43 as shown in the figure or the figure are provided, the upper circulating flow b flows along the lower side of the horizontal swirling flow a and then goes down at the center, and the lower circulating flow b ' It is possible to assist in the upward movement at the center along the tank bottom, and the mixing and contact efficiency can be improved in the same manner.
[0053]
Although the case where the filter cylinder is provided in the cylindrical tank as described above has been described, the filter cylinder may be provided outside the cylindrical tank. In that case, a filter cylinder is provided outside the upper outer periphery of the tank wall of the cylindrical tank, and a slit for filtering the liquid in the cylindrical tank into the upper part of the tank wall of the cylindrical tank surrounded by the filter cylinder Is provided horizontally, and the outer edge of the stirring blade may be brought close to the upper inner periphery of the tank wall of the cylindrical tank at an interval of 1 to 10 mm. If necessary, a rubber plate may be attached to the outer edge of the stirring blade, and during rotation, the inner periphery of the tank wall of the cylindrical tank provided with a slit may be stroked with this rubber plate. Even in the granulation tank having such a structure, the sludge supplied from the bottom of the cylindrical tank is agitated and aggregated in the tank, while the water entering the filter cylinder through the slit in the tank wall is drained outside the tank by a pump or the like. Therefore, the continuously supplied sludge is sufficiently concentrated and is discharged after growing into a floc with high strength. The floc generated in the cylindrical tank is pushed by the stirring blade that rotates horizontally close to the inner periphery of the tank wall upper part of the cylindrical tank provided with the slit, and the floc is slit along the inner periphery of the tank wall along the slit. In addition to being clogged with water, it is dense and strong by rolling along the inner periphery of the tank wall along the slit.
[0054]
In addition, as processing conditions in this granulation tank, it is preferable to employ | adopt the density | concentration in a tank 0.5-3 weight / volume% and the peripheral speed 5-20 m / min of a stirring blade.
[0055]
Hereinafter, the present invention will be described in more detail with reference to specific examples and comparative examples.
[0056]
Example 1
With the nitrification / denitrification apparatus of the present invention shown in FIG.
[0057]
As the nitrification tank, an upward flow type biological filtration tank loaded with a floating synthetic filter medium was used.
[0058]
Raw water quality T-BOD (total BOD): 130 mg / l
S-BOD (soluble BOD): 80 mg / l
TN (total nitrogen): 30 mg / l
SS: 200 mg / l
Operating conditions Precipitation tank surface area load: 30 m / day
Settling tank residence time: 2.4 hr
Excess sludge extraction rate from denitrification tank: 80% of granulated sludge
Denitrification tank sludge concentration: 15000ppm
Denitrification tank residence time: 0.7 hr
Nitrification tank residence time: 0.9 hr
Circulation ratio: 3
Addition amount of inorganic salt (polyaluminum chloride): 1% by weight with respect to SS
Amphoteric polymer (trade name “Clibest P702” manufactured by Kurita Kogyo Co., Ltd.)
Addition amount: 1.5% by weight with respect to SS
Table 1 shows the quality of the treated water obtained. Table 1 also shows the total residence time of the apparatus (total residence time of the precipitation tank, denitrification tank and nitrification tank).
[0059]
Comparative Example 1
The wastewater having the same water quality as the wastewater treated in Example 1 was treated by the conventional apparatus shown in FIG. The operating conditions were as follows.
[0060]
Initial sedimentation basin surface area load factor: 30 m / day
Final sedimentation basin surface area load factor: 20 m / day
Denitrification tank residence time: 4.8 hr
Nitrification tank residence time: 2.2 hr
Circulation ratio: 3
Table 1 shows the quality of the treated water obtained. Table 1 also shows the total residence time of the apparatus (total residence time of the first sedimentation tank, denitrification tank, nitrification tank, and final sedimentation tank).
[0061]
[Table 1]
Figure 0003826411
[0062]
From Table 1, the following is clear.
[0063]
That is, according to the present invention, it is possible to sufficiently treat the nitrogen component with a residence time of about 20% compared to the conventional case. Therefore, the apparatus can be reduced in size and capacity. Also, in the case of treated water, nitrate nitrogen remains due to a lack of soluble BOD in the conventional method, and the total nitrogen concentration is high. However, according to the present invention, denitrification proceeds smoothly and the nitrogen concentration is sufficiently high. Can be obtained.
[0064]
【The invention's effect】
As detailed above, according to the nitrification denitrification apparatus of the present invention,
(1) The installation area of the device is greatly reduced.
(2) Even if the inflow soluble BOD concentration decreases, denitrification can be performed stably.
(3) Nitrification and denitrification performance is improved.
(4) Resistance to flow fluctuations is increased and operation management is facilitated.
With such an effect, a compact and easy-to-manage apparatus can efficiently treat nitrogen in the wastewater and stably obtain high-quality treated water.
[Brief description of the drawings]
FIG. 1 is a system diagram showing an embodiment of a nitrification denitrification apparatus of the present invention.
FIG. 2 is a partial cross-sectional perspective view showing an example of a granulation tank suitable for the present invention.
FIG. 3 is a plan view of the granulation tank shown in FIG.
FIG. 4 is a system diagram showing a conventional example.
[Explanation of symbols]
1 Precipitation tank 2 Denitrification tank 3 Granulation tank 4 Nitrification tank

Claims (3)

排水中のSSを分離する固液分離手段と、
該固液分離手段で分離された汚泥を造粒する造粒手段と、
該固液分離手段で分離された分離水が導入されると共に、該造粒手段で造粒された造粒物が保持される脱窒槽と、
該脱窒槽の流出水が導入される固定床式硝化槽と、
該硝化槽の流出水の一部を脱窒槽に返送する手段と、
該硝化槽の流出水の残部を処理水として系外へ排出する手段と、
を備えてなる硝化脱窒装置であって、
前記造粒手段は濾過部を有し、該造粒手段内の液体が該濾過部を通過して該造粒手段より排出されることを特徴とする硝化脱窒装置。
Solid-liquid separation means for separating SS in the waste water;
A granulating means for granulating the sludge separated by the solid-liquid separating means;
A denitrification tank in which the separated water separated by the solid-liquid separation means is introduced and the granulated product granulated by the granulation means is held;
A fixed bed nitrification tank into which the outflow water of the denitrification tank is introduced;
Means for returning a part of the effluent of the nitrification tank to the denitrification tank;
Means for discharging the remaining effluent of the nitrification tank out of the system as treated water;
A nitrification denitrification device comprising:
The nitrification denitrification apparatus, wherein the granulation means has a filtration part, and the liquid in the granulation means passes through the filtration part and is discharged from the granulation means.
請求項において、前記固定床式硝化槽は逆洗手段を有し、該硝化槽の逆洗排水を前記固液分離手段の分離汚泥と共に前記造粒手段に送給するようにしたことを特徴とする硝化脱窒装置。2. The fixed bed type nitrification tank according to claim 1 , wherein the fixed bed type nitrification tank has back washing means, and the back washing waste water from the nitrification tank is fed to the granulation means together with the separated sludge of the solid-liquid separation means. Nitrification denitrification equipment. 請求項1又は2において、前記濾過部を通過した前記造粒手段からの排水は、前記固液分離手段へ返送されることを特徴とする硝化脱窒装置。 3. The nitrification / denitrification apparatus according to claim 1, wherein the waste water from the granulation means that has passed through the filtration unit is returned to the solid-liquid separation means.
JP13030195A 1995-05-29 1995-05-29 Nitrification denitrification equipment Expired - Fee Related JP3826411B2 (en)

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