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JP3885341B2 - Method for removing oxide scale from silicon steel surface - Google Patents
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JP3885341B2 - Method for removing oxide scale from silicon steel surface - Google Patents

Method for removing oxide scale from silicon steel surface Download PDF

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Publication number
JP3885341B2
JP3885341B2 JP06853898A JP6853898A JP3885341B2 JP 3885341 B2 JP3885341 B2 JP 3885341B2 JP 06853898 A JP06853898 A JP 06853898A JP 6853898 A JP6853898 A JP 6853898A JP 3885341 B2 JP3885341 B2 JP 3885341B2
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Prior art keywords
silicon steel
sic
abrasive grains
grinding
oxide scale
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JPH11262847A (en
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誠英 安藤
典久 岡田
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JFE Steel Corp
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JFE Steel Corp
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Description

【0001】
【発明の属する技術分野】
本発明は、けい素鋼表面の酸化スケール除去方法に関し、特に方向性けい素鋼板の製造過程で形成された酸化スケールを効果的に研削除去するための方法を提案するものである。
【0002】
【従来の技術】
方向性珪素鋼板は、主として変圧器、発電機その他の電気機器の鉄芯材料として用いられ、優れた磁気特性のほか、金属光沢をもつ点状の被膜欠陥がないなどの表面性状にも優れていることが求められる。
さて、方向性珪素鋼板は、一般に、Siを2〜4wt%程度含有するけい素鋼スラブを熱間圧延し、1回または中間焼鈍を挟む2回以上の冷間圧延を行って最終冷延板とした後、脱炭焼鈍し、MgOを主成分とする焼鈍分離材を塗布してから仕上げ焼鈍することにより、二次再結晶によるゴス方位結晶粒の発達を促すとともに、表面にフォルステライト被膜を形成して製造される。その後、必要に応じて、平坦化焼鈍、絶縁コーティングを施して製造される。
このような製造工程において、仕上げ焼鈍に先立つ脱炭焼鈍時に生成する酸化被膜の性状は、最終製品の磁気特性およびグラス被膜特性に影響を及ぼすことが知られるようになってきた。そしてこのことは、脱炭焼鈍で生成した酸化被膜によっては、仕上げ焼鈍時における二次再結晶が不十分になったり、表面外観を低下したりすることを意味している。
【0003】
このため、脱炭焼鈍後に良好な酸化被膜を形成するための方法について、これまでにもいくつかの提案がなされてきた。例えば、特開昭61−96082 号公報には、脱炭焼鈍前の鋼帯表面をカーボランダム(SiC)砥粒またはアランダム(Al2O3 )砥粒を含む軟質材料からなる研削手段によって研削することを開示している。
【0004】
【発明が解決しようとする課題】
しかしながら、上記特開昭61−96082 号公報に開示の従来の方法では、酸化スケールの研削が必ずしも効率的に行えないばかりか、研削そのものを十分に行うことができなく、後工程に悪影響をもたらしていた。特に、中間焼鈍の焼鈍雰囲気や焼鈍後の冷却方法の変動などによっては、酸化スケール厚みが酸素目付量に換算して0.8 g/m2 程度にまで増加することがあり、このようなときにその悪影響は一層大きくあらわれていた。
【0005】
そこで、本発明は、けい素鋼表面の脱スケールにおいて、従来の既知技術が抱えていた上記問題点を解決することにあり、熱間圧延工程および/または焼鈍工程で鋼帯表面に生成した酸化スケール、とくに冷間圧延と冷間圧延の間に行う中間焼鈍で鋼帯表面に生成した酸化スケールを効果的に研削除去することを目的とする。
【0006】
【課題を解決するための手段】
中間焼鈍等の酸化雰囲気にさらされたけい素鋼の鋼帯表面には、特有の酸化スケールが生成する。そのスケール構造を詳細に観察すると、地鉄の上に、SiO2 −Feの混合層、SiO2 層、酸化鉄層の順に形成されている。
発明者らは、このような層からなる酸化スケールを効率的に研削する方法について、砥粒の成分が異なる弾性砥石を用いて検討を重ねた。その結果、以下の知見が得られた。
SiC砥粒のみの場合には、酸化鉄層およびSiO2 層は比較的容易に研削できるものの、SiO2 −Feの混合層の研削は困難である。また、Al2O3 砥粒のみの場合には、SiO2 −Feの混合層は比較的容易に研削できるが、酸化鉄層およびSiO2 層の研削は極めて困難である。
これに対して、SiC砥粒とAl2O3 砥粒とを適正範囲で混合した弾性研磨材を用いて研削すると、酸化鉄層、SiO2 層およびSiO2 −Feの混合層のすべてを効率的に除去することが可能となり、脱スケールを効率的に行うことが可能になる。しかも、これら砥粒のサイズを適正化することによって、一層効果的に脱スケールすることが可能になる。
本発明は上記知見に基づいて完成したものであり、その要旨構成は以下のとおりである。
【0008】
)けい素鋼スラブを熱間圧延し、中間焼鈍を挟んで2回以上冷間圧延して最終冷延板としたのち、脱炭焼鈍し、次いで仕上げ焼鈍する一連の工程により方向性けい素鋼板を製造する際に、前記中間焼鈍の工程で鋼帯表面に生成した酸化スケールを機械的に研削除去する方法において、砥粒がAlとSiCの混合物からなり、その混合割合がAl:30〜70重量%、SiC:70〜30重量%である、弾性研磨材を用いて中間焼鈍後の鋼帯表面の酸化スケールを研削除去し、研削後の酸素目付量を0.25g/m 以下とすることを特徴とする、けい素鋼表面の酸化スケール除去方法。
【0009】
)Al砥粒およびSiC砥粒のサイズが、#60〜#150(250μm〜75μm)であることを特徴とする上記(1)に記載のけい素鋼表面の酸化スケール除去方法。
【0010】
【発明の実施の形態】
酸化スケールの脱スケール方法については、従来から、酸洗による方法、ベルトサンダーによる方法、弾性研磨材による方法などが知られている。しかし、酸洗による脱スケール方法は、酸化スケール層を完全に取り去るには長時間を必要とし効率的ではない。
また、ベルトサンダーによる方法は、ベルトの変換頻度が多く、オペレータの負荷が甚大になるなど実用に耐えうるものではない。しかも、研磨の際に不必要な歪みを地鉄表面に加えてしまうという問題もある。
一方、弾性研磨材を用いる方法は、酸洗法やベルトサンダー法が抱えているような欠点もなく、けい素鋼の脱スケールに適した方法と言える。ここで、弾性研磨材を用いる方法とは、砥粒のバインダーとなる基材が弾性変形をする物質(不織布ロール、ポリウレタンロールなど)で作られた研磨材を用いる方法をいう。
【0011】
発明者ら、上述した弾性研磨材を用いる方法で、砥粒の種類、サイズ等について検討した。
図1は、酸化スケール厚みが酸素目付量で0.8 g/m2 のけい素鋼帯(Si:3wt%)を、 Al2O3砥粒のみ、SiC砥粒のみ、 Al2O3 50 重量%とSiC 50 重量%との混合砥粒の各弾性研磨材を用いて研削した場合の実験結果である。このとき、各研磨材の研削性能を、鋼帯表面の蛍光X線分析によるSi強度により比較した。Si強度が低いほど研削性能が高いことを意味する。なお、砥粒サイズは、いずれも#100(125 μm)とした。
図1から、 Al2O3とSiCの混合砥粒を用いると、それぞれ単独の砥粒では得られなかったような高い研削性能が発揮されることが確認された。
【0012】
図2は、中間焼鈍後の酸素目付量0.8 g/m2 のけい素鋼帯(Si:3wt%)を、図3に示す研削装置により、 Al2O3のみの砥粒、 Al2O3 50 重量%とSiC 50 重量%の混合砥粒(砥粒サイズはいずれも#100 )からなる弾性研磨材を用いて、研削時間を変えてスケールを除去した場合の研削性能を酸素目付量により比較したものである。図2からも、 Al2O3とSiCの混合砥粒の弾性研磨材を用いることにより、研削性能が著しく向上することがわかる。
【0013】
また、上記実験と同様に、中間焼鈍した酸素目付量0.8 g/m2 のけい素鋼帯を、2種類の砥粒(砥粒サイズはいずれも#100 )の弾性研磨材を用い、いずれの研磨材とも50w/mmの動力で研削し、その後、冷間圧延し、脱炭焼鈍、MgO塗布の後、仕上げ焼鈍した。図4は、このようにして得られたけい素鋼帯の表面外観を観察し、金属光沢をもつ点状の被膜欠陥の発生率(=コイル中の点状被膜欠陥長さ/コイル長さ×100 (%))を中間焼鈍後の酸素目付量と対応させてプロットしたものである。
図4から、 Al2O3とSiCの混合砥粒によれば、 Al2O3単独の場合よりも、酸素目付量の減少、すなわち脱スケール性の向上により、点状の被膜欠陥が格段に減少していることが認められる。
【0014】
以上の実験事実に基づいて、本発明の酸化スケール除去方法には、 Al2O3砥粒とSiC砥粒からなる混合砥粒の弾性研磨材を用いることとした。また、発明者らはその混合割合についても検討を加え、 Al2O3:30〜70重量%、SiC:70〜30重量%とすることが必要であることを見いだした。ここに、 Al2O3:30重量%未満(SiC:70重量%超え)でも、 Al2O3:70重量%超え(SiC:30重量%未満)でも、けい素鋼表面の酸化スケールを十分かつ効率的に除去することができなくなる。
さらに、これら混合砥粒を構成する Al2O3砥粒およびSiC砥粒のサイズが研削性能に与える影響についても調査した。その結果、これら砥粒のサイズは、いずれも#60〜#150 (250 μm〜75μm)の範囲とすることにより、一層効果的な研削が可能であることもわかった。砥粒のサイズが、#60を超えると研削力は増えるが、長手、幅方向での研削の均一性が低下し、その結果酸素目付量が増え、また#150 に満たないと研削の均一性は向上するが、研削力が低下し、ライン速度一定とすると、結果的に酸素目付量が増すこととなるからである。
【0015】
【実施例】
以下、実施例によって本発明を具体的に説明する。
C:0.04wt%、Si:3.4 wt%、Mn:0.007 wt%、S:0.002 wt%、Al:0.0002wt%、N:0.002 wt%を含有する組成からなる2.0 mm厚の熱延板に、1000℃,0.5min の焼鈍を施したのち、酸洗し、冷間圧延により中間板厚0.6 mmとした。次いで、975 ℃、1min で中間焼鈍し、表1に示す条件でけい素鋼帯表面の酸化スケールを研削し、再度冷間圧延を行い、板厚0.23mmの最終冷延板とした。さらに、湿水素雰囲気中で880 ℃、2min の脱炭焼鈍を経て、MgOスラリーを塗布し、N2 50%、H2 50%の混合雰囲気中で800 〜1050℃間を20℃/hrで昇温後、H2 雰囲気に替えて1200℃で10hr仕上げ焼鈍し、張力コーティングを施し、600 ℃で1min の平坦化焼鈍を実施した。
【0016】
このようにして、得られたけい素鋼板について、表面外観を観察して、点状の被膜欠陥の発生状況を調査するとともに、被膜特性として剥離性を測定した。なお、中間焼鈍後および酸化スケール研削後の酸素目付量をそれぞれ分析した。これらの、結果を併せて表1に示す。
【表1】

Figure 0003885341
【0017】
表1から、Al2O3 とSiCを所定比率で混合した発明例は、比較例に比べて、中間焼鈍鋼帯のスケール研削後の酸素目付量を低くできるとともに、点状被膜欠陥の発生率も著しく低減できることがわかる。
【0018】
【発明の効果】
以上説明したように、本発明によれば、けい素鋼の製造工程、特に冷間圧延間に実施される中間焼鈍工程で生成する酸化スケールを、極めて効率的に研削除去することができる。このため、本発明によれば、仕上げ焼鈍後の最終的な製品の表面外観、剥離性などを、生産性の低下を伴うことなく、効果的に向上させることが可能になる。
【図面の簡単な説明】
【図1】酸化スケールの研削除去性能に及ぼす砥粒の種類の影響を示す図である。
【図2】砥粒の種類が異なる弾性研磨材を用いたときの、酸化スケールの研削除去性能と研削ロール磨耗量との関係を示す図である。
【図3】弾性研磨材を用いた研削装置を示す模式図である。
【図4】砥粒の種類が異なる弾性研磨材を用いたときの、点状欠陥被膜発生率と中間焼鈍後の酸素目付量との関係を示す図である。
【符号の説明】
1 けい素鋼帯
2 弾性研磨材を具えた研削ロール
3 補助ロール
4 水冷スプレー[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a method for removing oxide scale on the surface of silicon steel, and in particular, proposes a method for effectively grinding and removing oxide scale formed in the course of manufacturing a grain-oriented silicon steel sheet.
[0002]
[Prior art]
Directional silicon steel sheets are mainly used as iron core materials for transformers, generators and other electrical equipment, and have excellent magnetic properties and surface properties such as no point-like film defects with metallic luster. It is required to be.
The grain-oriented silicon steel sheet is generally a final cold-rolled sheet obtained by hot-rolling a silicon steel slab containing about 2 to 4 wt% of Si and performing cold rolling twice or more with intermediate annealing. After decarburizing and annealing, applying an annealing separator mainly composed of MgO and then finishing annealing promotes the development of goth-oriented grains by secondary recrystallization and a forsterite coating on the surface. Formed and manufactured. Thereafter, it is manufactured by performing planarization annealing and insulating coating as necessary.
In such a manufacturing process, it has been known that the properties of the oxide film produced during decarburization annealing prior to finish annealing affect the magnetic properties and glass coating properties of the final product. This means that, depending on the oxide film produced by decarburization annealing, secondary recrystallization during finish annealing becomes insufficient or the surface appearance is deteriorated.
[0003]
For this reason, some proposals have been made so far for methods for forming a good oxide film after decarburization annealing. For example, JP-A-61-96082 discloses that the surface of a steel strip before decarburization annealing is ground by a grinding means made of a soft material containing carborundum (SiC) abrasive grains or alundum (Al 2 O 3 ) abrasive grains. Is disclosed.
[0004]
[Problems to be solved by the invention]
However, the conventional method disclosed in the above-mentioned JP-A-61-96082 not only does not necessarily efficiently grind oxide scale, but also does not grind itself sufficiently, and adversely affects subsequent processes. It was. In particular, depending on the annealing atmosphere of the intermediate annealing and the variation of the cooling method after annealing, the oxide scale thickness may increase to about 0.8 g / m 2 in terms of the oxygen basis weight. The adverse effects were even greater.
[0005]
Therefore, the present invention is to solve the above-mentioned problems that the conventional known techniques have in the descaling of the surface of silicon steel, and the oxidation generated on the surface of the steel strip in the hot rolling process and / or the annealing process. The purpose is to effectively grind and remove the scale, especially the oxidized scale formed on the surface of the steel strip by the intermediate annealing performed between cold rolling and cold rolling.
[0006]
[Means for Solving the Problems]
A specific oxide scale is formed on the surface of the steel strip exposed to an oxidizing atmosphere such as intermediate annealing. When observing the scale structure in detail, on the base steel, a mixed layer of SiO 2 -Fe, SiO 2 layer, it is formed in the order of the iron oxide layer.
Inventors repeated examination about the method of grinding the oxide scale which consists of such a layer efficiently using the elastic grindstone from which the component of an abrasive grain differs. As a result, the following knowledge was obtained.
In the case of only SiC abrasive grains, the iron oxide layer and the SiO 2 layer can be ground relatively easily, but grinding of the mixed layer of SiO 2 —Fe is difficult. Further, in the case of only Al 2 O 3 abrasive grains, the SiO 2 —Fe mixed layer can be ground relatively easily, but grinding of the iron oxide layer and the SiO 2 layer is extremely difficult.
On the other hand, when grinding is performed using an elastic abrasive in which SiC abrasive grains and Al 2 O 3 abrasive grains are mixed within an appropriate range, all of the iron oxide layer, the SiO 2 layer, and the mixed layer of SiO 2 —Fe are efficiently processed. Can be removed efficiently, and descaling can be performed efficiently. In addition, the scale can be more effectively descaled by optimizing the size of these abrasive grains.
This invention is completed based on the said knowledge, The summary structure is as follows.
[0008]
( 1 ) Hot-rolling a silicon steel slab, cold rolling more than twice with intermediate annealing to make the final cold-rolled sheet, decarburizing annealing, then finishing annealing In the method of mechanically grinding and removing the oxide scale formed on the surface of the steel strip in the intermediate annealing process when manufacturing the steel sheet, the abrasive grains are composed of a mixture of Al 2 O 3 and SiC, and the mixing ratio is al 2 O 3: 30~70 wt%, SiC: 70 to 30 wt%, the oxide scale of the steel strip surface after intermediate annealing by using an elastic abrasive grinding removed, oxygen basis weight after grinding 0 A method for removing oxide scale from the surface of silicon steel, characterized by being made 25 g / m 2 or less .
[0009]
( 2 ) The method for removing oxide scale from the silicon steel surface according to (1) above, wherein the sizes of the Al 2 O 3 abrasive grains and the SiC abrasive grains are # 60 to # 150 (250 μm to 75 μm). .
[0010]
DETAILED DESCRIPTION OF THE INVENTION
Conventionally known methods for descaling oxide scales include a pickling method, a belt sander method, and an elastic abrasive method. However, the descaling method by pickling requires a long time to completely remove the oxide scale layer and is not efficient.
In addition, the belt sander method cannot withstand practical use because the belt conversion frequency is high and the load on the operator is enormous. Moreover, there is also a problem that unnecessary strain is applied to the surface of the ground iron during polishing.
On the other hand, the method using an elastic abrasive can be said to be a method suitable for descaling silicon steel without the disadvantages of the pickling method and the belt sander method. Here, the method using an elastic abrasive refers to a method using an abrasive made of a substance (nonwoven fabric roll, polyurethane roll, etc.) that elastically deforms a base material serving as an abrasive binder.
[0011]
The inventors studied the type and size of the abrasive grains by the method using the elastic abrasive described above.
Figure 1 shows a silicon steel strip (Si: 3 wt%) with an oxide scale thickness of 0.8 g / m 2 in terms of oxygen basis weight, Al 2 O 3 abrasive grains only, SiC abrasive grains only, Al 2 O 3 50 wt% It is an experimental result at the time of grinding using each elastic abrasive | polishing material of the mixed abrasive grain of SiC and SiC 50weight%. At this time, the grinding performance of each abrasive was compared by the Si intensity by fluorescent X-ray analysis of the steel strip surface. The lower the Si strength, the higher the grinding performance. The abrasive grain size was # 100 (125 μm) in all cases.
From Figure 1, the use of mixed abrasive grains Al 2 O 3 and SiC, that each abrasive with high grinding performance which could not be obtained alone can be exhibited was confirmed.
[0012]
Figure 2 is a silicon steel strip of oxygen basis weight 0.8 g / m 2 after intermediate annealing: the (Si 3 wt%), the grinding apparatus shown in FIG. 3, Al 2 O 3 only abrasive grains, Al 2 O 3 Comparison of grinding performance according to the amount of oxygen per unit area when using 50% by weight and 50% SiC mixed abrasive grains (abrasive grain size is # 100) and removing scales with varying grinding time It is a thing. FIG. 2 also shows that the grinding performance is remarkably improved by using an elastic abrasive of mixed abrasive grains of Al 2 O 3 and SiC.
[0013]
Similarly to the above-described experiment, an intermediate annealed silicon steel strip having an oxygen basis weight of 0.8 g / m 2 was used with two types of abrasive grains (the abrasive grain size was # 100), Both abrasives were ground with a power of 50 w / mm, then cold-rolled, decarburized annealed, MgO applied, and then finish annealed. FIG. 4 shows the surface appearance of the silicon steel strip obtained in this manner, and the occurrence rate of point-like film defects having a metallic luster (= point film defect length in the coil / coil length × 100 (%)) is plotted in correspondence with the oxygen basis weight after the intermediate annealing.
From FIG. 4, according to the mixed abrasive grains of Al 2 O 3 and SiC, the point-like film defects are markedly reduced by reducing the oxygen basis weight, that is, improving the descaling property, compared with the case of Al 2 O 3 alone. It is observed that it is decreasing.
[0014]
Based on the above experimental facts, the method for removing oxide scale of the present invention uses an elastic abrasive of mixed abrasive grains made of Al 2 O 3 abrasive grains and SiC abrasive grains. The inventors also examined the mixing ratio and found that Al 2 O 3 : 30 to 70% by weight and SiC: 70 to 30% by weight are necessary. Here, Al 2 O 3: less than 30 wt% (SiC: 70 exceeds wt%) But, Al 2 O 3: 70 wt% greater than (SiC: less than 30% by weight) But sufficient oxide scale of silicon steel surface And it cannot be removed efficiently.
Furthermore, the influence of the size of the Al 2 O 3 abrasive grains and SiC abrasive grains constituting the mixed abrasive grains on the grinding performance was also investigated. As a result, it was found that more effective grinding is possible by setting the size of these abrasive grains to a range of # 60 to # 150 (250 μm to 75 μm). If the abrasive grain size exceeds # 60, the grinding force increases, but the uniformity of grinding in the longitudinal and width directions decreases, resulting in an increase in the amount of oxygen per unit area. However, if the grinding force decreases and the line speed is constant, the oxygen basis weight increases as a result.
[0015]
【Example】
Hereinafter, the present invention will be described specifically by way of examples.
A hot rolled sheet 2.0 mm thick having a composition containing C: 0.04 wt%, Si: 3.4 wt%, Mn: 0.007 wt%, S: 0.002 wt%, Al: 0.0002 wt%, N: 0.002 wt%, After annealing at 1000 ° C. for 0.5 min, pickling was performed, and the intermediate plate thickness was 0.6 mm by cold rolling. Next, intermediate annealing was performed at 975 ° C. for 1 min, the oxidized scale on the surface of the silicon steel strip was ground under the conditions shown in Table 1, and cold rolled again to obtain a final cold rolled sheet having a sheet thickness of 0.23 mm. Furthermore, after decarburization annealing at 880 ° C. for 2 minutes in a wet hydrogen atmosphere, an MgO slurry was applied, and the temperature was increased from 800 to 1050 ° C. at 20 ° C./hr in a mixed atmosphere of N 2 50% and H 2 50%. after warm, subjected 10hr finish annealing, tension coated with 1200 ° C. instead of an H 2 atmosphere, was carried out flattening annealing of 1min at 600 ° C..
[0016]
Thus, about the obtained silicon steel plate, the surface external appearance was observed, the occurrence state of a point-like film defect was investigated, and peelability was measured as a film characteristic. The oxygen basis weight after intermediate annealing and after oxide scale grinding was analyzed. The results are also shown in Table 1.
[Table 1]
Figure 0003885341
[0017]
From Table 1, the inventive example in which Al 2 O 3 and SiC are mixed at a predetermined ratio can lower the oxygen basis weight after scale grinding of the intermediate annealed steel strip and the incidence of point film defects. It can also be seen that it can be significantly reduced.
[0018]
【The invention's effect】
As described above, according to the present invention, it is possible to grind and remove the oxide scale generated in the manufacturing process of silicon steel, in particular, the intermediate annealing process performed during cold rolling. For this reason, according to the present invention, it is possible to effectively improve the surface appearance, peelability, and the like of the final product after finish annealing without being accompanied by a decrease in productivity.
[Brief description of the drawings]
FIG. 1 is a diagram showing the influence of the type of abrasive grains on the grinding removal performance of an oxide scale.
FIG. 2 is a diagram showing a relationship between oxide scale grinding removal performance and grinding roll wear when using an elastic abrasive with different types of abrasive grains.
FIG. 3 is a schematic view showing a grinding apparatus using an elastic abrasive.
FIG. 4 is a diagram showing a relationship between a point defect film generation rate and an oxygen basis weight after intermediate annealing when elastic abrasives having different types of abrasive grains are used.
[Explanation of symbols]
1 Silicon steel strip 2 Grinding roll with elastic abrasive 3 Auxiliary roll 4 Water-cooled spray

Claims (2)

けい素鋼スラブを熱間圧延し、中間焼鈍を挟んで2回以上冷間圧延して最終冷延板としたのち、脱炭焼鈍し、次いで仕上げ焼鈍する一連の工程により方向性けい素鋼板を製造する際に、前記中間焼鈍の工程で鋼帯表面に生成した酸化スケールを機械的に研削除去する方法において、砥粒がAlとSiCの混合物からなり、その混合割合がAl:30〜70重量%、SiC:70〜30重量%である、弾性研磨材を用いて中間焼鈍後の鋼帯表面の酸化スケールを研削除去し、研削後の酸素目付量を0.25g/m 以下とすることを特徴とする、けい素鋼表面の酸化スケール除去方法。A silicon steel slab is hot-rolled, cold-rolled at least twice with intermediate annealing to make the final cold-rolled sheet, then decarburized and then finish-annealed to produce a grain-oriented silicon steel sheet. In manufacturing, in the method of mechanically grinding and removing the oxide scale formed on the steel strip surface in the intermediate annealing step, the abrasive grains are made of a mixture of Al 2 O 3 and SiC, and the mixing ratio is Al 2 O. 3 : 30 to 70% by weight of SiC and 70 to 30% by weight of SiC, using an elastic abrasive material, the oxidized scale on the surface of the steel strip after intermediate annealing is ground and removed, and the oxygen basis weight after grinding is 0.25 g / A method for removing oxide scale from a silicon steel surface, characterized by being m 2 or less . Al砥粒およびSiC砥粒のサイズが、#60〜#150であることを特徴とする請求項1に記載のけい素鋼表面の酸化スケール除去方法。The method for removing oxide scale from the surface of silicon steel according to claim 1, wherein the sizes of the Al 2 O 3 abrasive grains and the SiC abrasive grains are # 60 to # 150.
JP06853898A 1998-03-18 1998-03-18 Method for removing oxide scale from silicon steel surface Expired - Fee Related JP3885341B2 (en)

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