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JP3976463B2 - Endless belt manufacturing method, damming member correction method, and damming member correction jig - Google Patents
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JP3976463B2 - Endless belt manufacturing method, damming member correction method, and damming member correction jig - Google Patents

Endless belt manufacturing method, damming member correction method, and damming member correction jig Download PDF

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Publication number
JP3976463B2
JP3976463B2 JP2000041075A JP2000041075A JP3976463B2 JP 3976463 B2 JP3976463 B2 JP 3976463B2 JP 2000041075 A JP2000041075 A JP 2000041075A JP 2000041075 A JP2000041075 A JP 2000041075A JP 3976463 B2 JP3976463 B2 JP 3976463B2
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Prior art keywords
mold
endless belt
damming
peripheral surface
inner peripheral
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JP2001225334A (en
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稔 松尾
亜希子 田中
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Ricoh Co Ltd
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Ricoh Co Ltd
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Description

【0001】
【発明の属する技術分野】
本発明は無端状ベルトの製造技術に関し、より詳しくは無端状のシート状樹脂ベルトの製造方法および、この製造方法に用いる堰止め部材の矯正方法に関する。本発明は、電子写真方式の複写機等における定着ベルトや中間転写ベルトなどに広く、かつ有効に応用できるものである。
【0002】
【従来の技術】
上記無端状ベルトは、従来から遠心成形法によって製造されている。この遠心成形法は、例えば次にように行われる。まず、低速回転する円筒状の成形型内に原料液(例えば樹脂の溶剤溶液)を注入塗布する。ついで、成形型を高速回転させ、遠心力により樹脂液(塗布液)を成形型の内周面(成形面)上に流延させて均一膜厚に拡げる。その後、この塗布液を加熱乾燥・固化させることにより無端状でシート状のベルトとし、最後に成形型からこの無端状ベルトを剥離・脱型して取り出す。
【0003】
この無端状ベルトの製造方法では、
(1)原料液の塗布膜厚を、注入液量によって任意に調整することができる、
(2)原料液を必要量だけ塗布すれば良く、原料液の使用効率が良い、
(3)成形型内部は密閉空間となっており、塗布液からの溶剤除去の際には排気経路に溶剤トラップを設けることで、外部に排出される溶剤を効率良く回収することができる、などの優れた利点がある。
【0004】
しかしながら、この遠心成形法にあっては、樹脂液(塗布液)の膜厚を均一にするために成形型の回転を続行していると、これが成形型の端部まで流延し、ベルトの幅方向両端部が中央部に比べて薄くなり、しかも不規則な樹脂だれを起こすため、乾燥・固化後の剥離取り出しが困難になるだけでなく、成形型を固定しているチャック等の保持具を汚してしまうという問題があった。
【0005】
この問題を解決するためには、成形型内での樹脂液の流延を適当な箇所で止めることが必要となる。そのための手段として従来、フッ素系樹脂からなるテープ等を成形型の端部内周面に粘着剤で貼着し、これを樹脂液の堰止め部材として用いていた。
【0006】
しかし、このようなテープ状堰止め部材では、取り付けに手間がかかり、また上記粘着剤が樹脂液中の溶剤に溶けて堰止めの役目を果たさなくなったり、上記保持具を汚したりする。さらに、成形型の内径が小さい場合には、手作業によるテープ貼着が不可能になるという問題もあった。
【0007】
そこで本発明者らは、特願平11−20880号の明細書および図面において、上記従来の問題点を解決するための技術として、成形型の内周面に少なくとも2つのリング状堰止め部材を互いに離間して設け、2つの堰止め部材と成形型の内周面とにより成形キャビティを形成するようにした、遠心成形法による無端状樹脂ベルトの製造方法を提案した。
【0008】
【発明が解決しようとする課題】
ところが、その後の本発明者らの検討により、以下の不具合があることが判った。すなわち、上記特許出願に係る製造方法においては、成形型内周面と堰止め部材外周面との間に僅かでも隙間があると、樹脂液がこの隙間にしみ込んでゆき、溶剤蒸発による樹脂液固化時の乾燥が不充分となり、その後に行う加熱乾燥・固化時に成形膜が成形型内周面から浮き上がって収縮してしまうため、上記堰止め部材を成形型内周面に密着させておかなければならない。
【0009】
また、上記堰止め部材として耐熱性プラスチックであるフッ素系樹脂(例えばPTFE)からなるものを使用したところ、これを一旦加熱後に冷却すると収縮して加熱前よりも内外径が小さくなり、このまま再使用した場合には、成形型内周面と堰止め部材外周面との間に隙間が生じ、堰止めの役割を果たさなくなってしまうトラブルが頻発した。これは、堰止め部材を成形により作製した際に残っている応力が充分に解消されていないため、加熱・冷却のヒートサイクルで徐々に収縮したためであると推定される。
【0010】
本発明は、上記問題点に鑑みなされたもので、その目的は、使用後の堰止め部材を矯正して再使用する無端状ベルトの製造方法および、使用後の堰止め部材の矯正方法を簡単な構成で安価に提供することにある。
【0011】
【課題を解決するための手段】
請求項1に記載の無端状ベルトの製造方法は、成形型の円筒内周面に複数個のプラスチック製またはゴム製のリング状堰止め部材を所定間隔で密着状態に装着し、互いに対向する堰止め部材と前記円筒内周面とにより成形キャビティを形成した遠心成形型を用意し、該成形型を水平中心軸の周りに回転させ、この状態で溶剤を含む原料液を成形キャビティに注入塗布し、成形型の回転を継続しながら加熱により前記溶剤を蒸発させて前記塗布液を乾燥・固化させることにより無端状ベルトを成形する方法であって、使用後の直径が縮小した堰止め部材を加熱により拡径して遠心成形に再使用することを特徴とする。
【0012】
請求項2に記載の無端状ベルトの製造方法は、成形型の円筒内周面に複数個のプラスチック製またはゴム製のリング状堰止め部材を所定間隔で密着状態に装着し、互いに対向する堰止め部材と前記円筒内周面とにより成形キャビティを形成した遠心成形型を用意し、該成形型を水平中心軸の周りに回転させ、この状態で溶剤を含む原料液を成形キャビティに注入塗布し、成形型の回転を継続しながら加熱により前記溶剤を蒸発させて前記塗布液を指触乾燥させた後、この指触乾燥膜を加熱して乾燥・固化させることにより無端状ベルトを成形する方法であって、使用後の直径が縮小した堰止め部材を加熱により拡径して遠心成形に再使用することを特徴とする。
【0013】
請求項3に記載の無端状ベルトの製造方法は、請求項1または2において、堰止め部材を押圧して成形型の円筒内周面に摺動させることにより成形型に挿入して、成形キャビティを形成することを特徴とする。
【0014】
請求項4に記載の無端状ベルトの製造方法は、請求項1または2において、成形された無端状ベルトの走行時の寄りを防止するためのリング状寄り止め部材を成形キャビティ内に、かつ、堰止め部材の側面に接触させた状態で挿入することにより、無端状ベルトの幅方向両端部に寄り止め部材を一体成形することを特徴とする。
【0015】
請求項5に記載の無端状ベルトの製造方法は、請求項4において、寄り止め部材を押圧して成形型の円筒内周面に摺動させることにより成形型に挿入して、寄り止め部材を堰止め部材の側面に接触させることを特徴とする。
【0016】
請求項6に記載の無端状ベルトの製造方法は、請求項2において、堰止め部材として熱膨張係数が成形型のそれより大きいものを用いることにより、指触乾燥工程では熱膨張により当該堰止め部材の外周面が成形型の円筒内周面に圧接し、指触乾燥工程で得られた指触乾燥膜の乾燥・固化工程後には熱収縮により当該堰止め部材の外径が成形型の円筒内周面の直径より小さくなるようにしたことを特徴とする。
【0017】
請求項7に記載の無端状ベルトの製造方法は、請求項6において堰止め部材として、指触乾燥膜の乾燥・固化工程では熱収縮により当該堰止め部材の外径が成形型内における無端状ベルトの内径より小さくなるような、熱膨張係数が成形型のそれより大きいものを使用し、指触乾燥工程後の成形型を加熱乾燥炉に鉛直方向に入れ、指触乾燥膜を乾燥・固化させて無端状ベルトを得るとともに、堰止め部材を成形型から自然落下させて回収することを特徴とする。
【0018】
請求項8に記載の無端状ベルトの製造方法は、請求項1〜7のいずれかにおいて、堰止め部材がフッ素系樹脂、好ましくはPTFE(ポリテトラフルオロエチレン)からなることを特徴とする。
【0019】
請求項9に記載の堰止め部材の矯正方法は、請求項1または2に記載の無端状ベルトの製造方法に再使用するために、使用後の直径が縮小した堰止め部材を加熱により拡径する方法であって、金属、ガラスまたはセラミックスからなり、外径が堰止め部材の内周面を挿入係止しうる大きさである第1円筒部と、この第1円筒部に連なり直径が漸増する中空円錐状のテーパ部と、該テーパ部に連なる第2円筒部とを備えてなる矯正ジグを用意し、第1円筒部の外周面に堰止め部材を挿入係止した矯正ジグを第2円筒部が下部となるように鉛直方向に沿わせた状態で堰止め部材を加熱し、膨張した堰止め部材を自重により前記テーパ部を介して第2円筒部の下端部に落下させ、この状態で堰止め部材を常温まで放冷して、矯正後の堰止め部材の内径を第2円筒部の外径と等しくすることにより、この堰止め部材の外径を使用前の堰止め部材の外径に戻すことを特徴とする。
【0020】
本発明に係る、堰止め部材の再使用のための基本的な原理は、プラスチックまたはゴムからなる堰止め部材が加熱/冷却により、それぞれ膨張/収縮する熱特性を利用した点にある。
【0021】
すなわち、
(1)収縮した堰止め部材を加熱して熱膨張させることで、収縮前の寸法に戻した後、この寸法を維持させることにより、次回使用する成形型の内周面に密着可能とする。
(2)そのためには、加熱膨張した堰止め部材を適宜の型に挿入し、収縮が進まないように堰止め部材の内周面を、上記型の外周面に当接させておけば良い。
(3)また、堰止め部材の温度が常温になっても内部応力緩和で更に収縮する可能性がある場合には、使用温度以下まで一旦冷却することで、到達温度からの逆過程(膨張)が起こるので、初期径以上の径(初期径:新品の堰止め部材の内外径)に維持することができる。
(4)以上の処理により矯正した堰止め部材は、成形型に適正に密着した状態で取り付けることができるので、堰止め部材本来の作用効果が得られる。
(5)なお、堰止め部材の熱分解温度等以上に加熱しなければ、堰止め部材を多数回、繰返し矯正処理することが可能である。
【0022】
【発明の実施の形態】
以下、本発明の実施の形態を、図面を基に説明する。
実施の形態1
図1は成形型および、成形キャビティ内で流延した原料液(例えば樹脂液:樹脂の溶剤溶液)を示す模式的断面図である。2個のプラスチック製またはゴム製のリング状堰止め部材2,2を遠心成形型1(以下、成形型呼ぶことがある)内に互いに所定間隔をあけて挿入するとともに、これら堰止め部材の外周面を成形型1の円筒内周面に密着状態とすることにより成形キャビティ1aを形成する。すなわち、この成形キャビティ1aを、互いに対向する堰止め部材2,2と上記円筒内周面とで形成する。
【0023】
無端状ベルトを成形するに際しては、成形型1を図略の遠心成形機にセットして水平中心軸の周りに回転させ、この状態で成形キャビティ1aに原料液3aを注入し、成形キャビティ内で流延させながら、この原料液を加熱して溶剤を蒸発させることにより指触乾燥膜を形成する。この成形型を遠心成形機から取り出し、図略の加熱乾燥炉にセットし、上記指触乾燥膜を加熱して乾燥・固化させることにより無端状ベルトを成形する。
【0024】
その後、成形型1を放冷し、これから無端状ベルトを剥離・回収するとともに、上記2つの堰止め部材を取り外す。これらの堰止め部材は加熱後の冷却により収縮しており、内外径が使用前に比べて縮小している。このため、この堰止め部材をそのまま再使用した場合には、図2に示すように、堰止め部材2の外周面と成形型1の円筒内周面との間に隙間ができ、原料液3aがこの隙間から外部に漏れ出る問題が発生する。そこで本発明では、使用後の直径が縮小した堰止め部材を加熱により矯正(拡径:直径を拡大する)して遠心成形に再使用する。これについては後記する。
【0025】
図1に示す堰止め部材2では、原料液に接触する側面がこの堰止め部材の中心軸と直交する平面になっていることが好ましい。また、成形工程においては堰止め部材の側面が原料液と接触していることから、この原料液中の溶剤に侵されないことが望ましい。また、高速回転の遠心成形中に堰止め部材が成形面(成形型の円筒内周面)から剥がれたり、位置ずれや脱落が発生したりしないように成形面に密着していることが望ましい。さらには、乾燥・固化工程(通常100℃〜200℃程度の温度範囲)において軟化することがない素材であることが重要である。
【0026】
本発明では、図1に示すように堰止め部材2が成形面に密着した状態で装着されているため、成形型両端部からの樹脂だれが防止され、均一膜厚の無端状ベルトを安定して成形することができる。
【0027】
堰止め部材2の素材としては、ポリテトラフルオロエチレン(PTFE)、ポリヘキサフルオロプロピレン(PHFP)、ポリクロロトリフロロエチレン(PCTFE)、ポリフルオロビニリデン(PVdF)、ポリフルオロビニル(PVF)及びポリフルオロエチレンプロピレン(PFEP)等のフッ素系樹脂が好適である。これらのうちでは、耐溶剤性・耐熱性・非粘着性・離型性等に優れているPTFEが特に好ましい。
【0028】
図3は、矯正ジグにより堰止め部材(の収縮)を矯正する方法およびその作用を説明する模式的断面図である。図3に示す金属製の矯正ジグ11は、熱膨張率が堰止め部材2のそれに比べてはるかに小さいもので、外径が堰止め部材2の内周面を挿入係止しうる大きさである第1円筒部11aと、この第1円筒部に連なり直径が漸増する中空円錐状のテーパ部11bと、このテーパ部に連なる第2円筒部11cとからなる。また、この第2円筒部11cの外径は、矯正後の堰止め部材の外径が使用前の堰止め部材の外径に戻すように設定されている。
【0029】
矯正に際しては、矯正ジグ11を図3に示すように、第2円筒部11cが下部となるように台座12上に鉛直方向に固定し、堰止め部材(矯正前)2を第1円筒部11aに挿入係止し、この矯正ジグ11を台座12と一体で加熱炉(図略)に挿入し、堰止め部材2および矯正ジグ11を適宜の温度に所定時間加熱する。これにより、膨張した堰止め部材2が自重によりテーパ部11bを介して第2円筒部11cの下端部に落下する。第2円筒部11cの下端部に落下した堰止め部材の内外径は、初期値と殆ど等しくなっている。この状態で矯正ジグおよび堰止め部材を常温まで放冷することにより、堰止め部材2の内外径は初期値に維持される。上記放冷後の堰止め部材2は、矯正ジグ11を台座12から取り外すことにより、第2円筒部11cの下端部から簡単に抜き取ることができる。
【0030】
実施の形態2
図4は成形型および、成形キャビティ内で流延した原料液(樹脂液)を示す模式的断面図である。4個のプラスチック製またはゴム製のリング状堰止め部材2を成形型1内に互いに所定間隔をあけて挿入するとともに、これら堰止め部材の外周面を成形型1の円筒内周面に密着状態とすることにより、成形キャビティ1aを3つ形成する。
【0031】
無端状ベルトを成形するに際しては、成形型1を図略の遠心成形機にセットして水平中心軸の周りに回転させ、この状態でそれぞれの成形キャビティに原料液を注入し、成形キャビティ内で流延させながら、この原料液を加熱して溶剤を蒸発させることにより指触乾燥膜を形成する。以下、実施の形態1と同じ要領によって、1回の成形で3本の無端状ベルトを得ることができる。
【0032】
実施の形態3
図5は成形型および、成形キャビティ内で流延した原料液を示す模式的断面図である。この成形型1は、4個の堰止め部材2を図4と同じ要領でセットするのに加えて、成形された無端状ベルトの走行時の寄りを防止するためのリング状の寄り止め部材4を、堰止め部材2の側面に接触させた状態で挿入したものである。この成形型によれば、無端状ベルトの幅方向両端部に寄り止め部材4を一体成形した3本の無端状ベルトを1回の成形で得ることができる。寄り止め部材4としては例えば、従来公知のステンレス製網状ベルトを使用することができる。
【0033】
実施の形態4
図6は、円筒型内に堰止め部材を挿入・セットして成形キャビティを形成することにより、図4の成形型を構成する場合の模式的断面図である。図6に示すように、外径が円筒型の内径D1より僅かに小さい堰止め部材2を挿入ジグ21で押圧し、円筒内周面に摺動させながら円筒型の所定位置に挿入・セットする。また、寄り止め部材4の挿入・セットは、堰止め部材2の場合と同じ要領で行うことができ、図5に示すように、寄り止め部材4を堰止め部材2の側面に接触させる。
【0034】
実施の形態5
無端状ベルトの成形後には、堰止め部材を成形型から簡便に取り出せることが重要である。そこで本実施の形態では、図7に示すように堰止め部材2として、成形時の原料液3aと接触しない部位に引き出し具(図略)用の引っかけ孔2aを形成したものを挿入して成形キャビティを形成する。図7(a)はこの堰止め部材2の断面図、図7(b)はその拡大平面図である。これにより、堰止め部材2を容易に、かつ薄膜状のベルトに触れることなく取り出すことができる。
【0035】
実施の形態6
本実施の形態に係る成形型1は、実施の形態5の引っかけ孔2aに代えて、図8に示すような、引っかけ突起2bを設けた堰止め部材2を挿入することにより、成形型1からの堰止め部材2の取り出し操作を簡便化したものである。図8(a)はこの堰止め部材2の断面図、図8(b)はその拡大平面図である。
【0036】
実施の形態7
図9は無端状ベルトの成形後に、堰止め部材を成形型から自然落下させて回収する方法を示すもので、図9(a)は指触乾燥膜を形成した成形型の断面図、図9(b)はこの成形型を加熱乾燥炉に鉛直方向にセットし、指触乾燥膜を乾燥・固化させて無端状ベルトを得るとともに、堰止め部材を成形型から自然落下させて回収する方法を示す断面図である。
【0037】
本実施の形態においても堰止め部材2として、熱膨張係数が成形型1のそれより大きいものを用いる。すなわち、成形工程では堰止め部材2の熱膨張により外周面が成形型1の円筒内周面に圧接し、成形工程後には熱収縮により堰止め部材の外径が成形型1の円筒内周面の直径より小さくなるようなものを用いる。これにより堰止め部材本来の作用が得られるだけでなく、成形工程後には該部材を、例えば以下のように容易に成形型から取り外すことができる。
【0038】
上記実施の形態7に従う堰止め部材の回収方法においては、堰止め部材として以下のものを使用する(図9を参照)。
(1)外径が成形型1の内径D1と等しいか、またはこれより僅かに小さく、成形型1に挿入した時点ではその円筒内周面に密着する。
(2)成形キャビティ内の注入原料液を指触乾燥させ、ついでこの指触乾燥膜3bを加熱により乾燥・固化させる工程では、この堰止め部材が熱膨張により外周面が成形型1の円筒内周面に圧接密着している。
(3)上記乾燥・固化工程後に堰止め部材を冷却すると、熱収縮によりこの堰止め部材の外径D3が成形型1内における無端状ベルト3cの内径D2より小さくなる。
【0039】
つぎに、堰止め部材の回収方法を図面をもとに説明する。指触乾燥後の成形型1を加熱乾燥炉(図略)に鉛直方向にセットする。この場合、図9(b)に示すように、成形型1を適宜の型保持具31上に鉛直方向に固定し、このまま型保持具31を加熱乾燥炉に挿入する。ついで、指触乾燥膜3b〔図9(a)〕を乾燥・固化させて無端状ベルト3cとした後、成形型を加熱乾燥炉内で常温まで放冷する。
【0040】
成形工程では図9(a)に示すように堰止め部材2の外周面が成形型1の円筒内周面に圧接していたものが、成形工程終了後には、堰止め部材2が熱収縮し、その外径D3が無端状ベルト3cの内径D2より小さくなるため、図9(b)に示すように堰止め部材2が自然落下し、型保持具31に回収される。
【0041】
【実施例】
つぎに、本発明の実施例を説明する。
実施例1
図1に示すように、アルミニウム製の成形型(熱膨張係数2.5×10-5/℃)に、PTFE製の新品のリング状堰止め部材(熱膨張係数8×10-5〜12×10-5/℃)を2つ挿入・セットした後、成形型を遠心成形機に水平方向にセットした。成形型を水平中心軸の周りに低速回転させながら、原料液としてポリイミド前駆体ワニスを徐々に注入して塗布膜を形成した。ついで、成形型を高速回転させることにより、上記塗布膜の膜厚を均一にし、さらに成形型を高速回転させながら70℃で約30間分加熱することで、塗布液を乾燥・固化させて無端状ベルトを得た。成形型を遠心成形機から取り出し、成形型から堰止め部材を取り外した。その結果、堰止め部材を容易に取り外すことができた。また、成形型からの原料液の漏出はなく、成形型周辺の部材は汚れていなかった。
【0042】
取り外した堰止め部材を、上記成形型に再度挿入・セットしようとしたところ、堰止め部材が実施例1で使用する前に比べて収縮していたため、成形型の円筒内周面との間に隙間が生じてしまった。そこで、収縮した堰止め部材を、図3に示すアルミニウムからなる矯正ジグ11の第1円筒部11aに挿入係止入、これを加熱炉に入れて100℃以上で加熱した。
【0043】
観察していると、堰止め部材2は昇温にともない第1円筒部11a、ついでテーパ部11bを落下し、充分に昇温した時点で第2円筒部11cの下端部まで落下した。矯正ジグ11を台座12とともに加熱炉から取り出し、そのまま室温まで放冷した。これにより、堰止め部材2が徐々に収縮し、外径が第2円筒部11cの外径と殆ど等しくなったところで堰止め部材2の寸法・形態が安定した。
【0044】
その後、堰止め部材2を矯正ジグ11から取り外し、成形型に挿入したところ、新品の堰止め部材と同じく円筒内周面に密着した状態でセットすることができた。この成形型を用いて再度無端状ベルトの成形を行った結果、成形型からの原料液の漏出等はなく、良質の無端状ベルトが得られた。矯正後の堰止め部材をこのように成形型の円筒内周面に密着した状態でセットすることができたのは、第2円筒部11cの外径が適正な値に設定されていたためである。
【0045】
比較例1
実施例1において、矯正ジグ11を台座12とともに加熱炉から取り出してそのまま室温まで放冷するのに代えて、加熱炉から取り出した矯正ジグ11から、まだ充分に冷却していない状態の堰止め部材を取り外し、そのまま一晩室温まで放冷した。翌日この堰止め部材を成形型に取り付けようとしたところ、成形型の円筒内周面との間に隙間が生じた。この成形型をそのまま用いて、原料液の注入・塗布および加熱乾燥・固化を行った結果、堰止め部材の外周面と成形型の円筒内周面との間に原料液が流れ込んだ形跡が見られた。
【0046】
実施例2
実施例1において、矯正ジグ11を台座12とともに加熱炉から取り出してそのまま室温まで放冷するのに代えて、矯正ジグ11を台座12とともに加熱炉から取り出し、冷蔵庫に保管した。充分(3時間以上)に保冷した後、堰止め部材を矯正ジグから取り外した。そのまま1昼夜以上放置した後、成形型にセットしたところ、堰止め部材は成形型の円筒内周面に密着し、正常な成形操作を行うことができた。
【0047】
実施例3
実施例1のように堰止め部材の成形型へのセットと、矯正作業とを100回以上繰り返し行った。その結果、堰止め部材の適正な矯正作業を、再現性良く行うことができ、堰止め部材の内外径回復および、原料液塗布時の堰止め効果に劣化は認められなかった。
【0048】
比較例2
実施例1で使用した堰止め部材を矯正することなく再使用したところ、原料液が成形型の端部から漏れ出たため、遠心成形機の回転保持具を汚してしまい、清掃に多大な時間を要した。また、未乾燥状態の塗布液部分では、成形型の円筒内周面からの塗布膜の浮き・収縮が生じたため、良好な無端状ベルトが得られないトラブルが頻発した。
【0049】
実施例4
図4に示すように寸法の長い成形型に、実施例1と同じ要領で矯正した4つのPTFE製堰止め部材を互いに等間隔に、図6に示す挿入ジグ21を用いて挿入・セットした後、この成形型を遠心成形機にセットし、成形型を回転させながら原料液を注入した。さらに成形型を回転させながら加熱して塗布液を指触乾燥させた。成形型を遠心成型機から取り外し、加熱乾燥炉に鉛直方向に挿入し、100℃で30分間加熱した(図9を参照)。その後、加熱乾燥炉を冷却して常温に戻したところ、得られた無端状ベルトが成形型に付着したままで、堰止め部材を炉内の底部に落下・回収することができた。このため、堰止め部材を手作業で成形型から取り外す必要はなかった。
【0050】
【発明の効果】
以上の説明で明らかなように、本発明によれば以下の効果が得られる。
(1)請求項1,2に記載の無端状ベルトの製造方法
遠心成形型を用いて無端状ベルトを製造するに際して、所定構成の堰止め部材を成形型に密着挿入して成形キャビティを形成し、この成形キャビティに原料液を注入するようにしたので、従来問題になっていた樹脂だれを的確に防止することができ、高品質のベルトを安定して製造することができる。また、長尺の成形型に堰止め部材を多数セットすれば、1回の成形操作で多数本の無端状ベルトを得ることができる。
【0051】
本発明では特に、弾力性または可撓性のある熱可塑性有機高分子系樹脂からなる堰止め部材を用いるとともに、成形後の収縮した堰止め部材を、いわゆるヒートセット(Heat Setting)によって、使用前の寸法・形態に復元・安定化させて再使用するようにしたので、堰止め部材を有効に利用することができる。
【0052】
(2)請求項3に記載の無端状ベルトの製造方法
堰止め部材を押圧して成形型の円筒内周面に摺動させることにより成形型に挿入するようにしたので、その挿入・セットを簡便に行うことができる。
【0053】
(3)請求項4,5に記載の無端状ベルトの製造方法
成形型への寄り止め部材の挿入・セットを簡便に行うことができる。また、寄り止め部材を一体成形した無端状ベルトが得られるので、寄り止め部材付きベルトを簡単な工程で製造することが可能になる。
【0054】
(4)請求項6,7に記載の無端状ベルトの製造方法
無端状ベルト成形後に行う、成形型からの堰止め部材の取り外し・回収作業を簡便・能率的に行うことができる。特に請求項7の製造方法によれば、無端状ベルトを得た後、堰止め部材を成形型から自然落下で回収することできるという顕著な効果がある。
【0055】
(5)請求項8に記載の無端状ベルトの製造方法
耐熱性・耐溶剤性・剥離性に富むフッ素系樹脂からなる堰止め部材を用いるので取扱いが便利であり、堰止め部材としての機能を充分に発揮させることができるうえ、成形された無端状ベルトを堰止め部材から簡単に分離することが可能である。
【0056】
(6)請求項9に記載の堰止め部材の矯正方法
所定構成の矯正ジグの外周面に堰止め部材を挿入係止し、この矯正ジグを鉛直方向にしたまま堰止め部材を適宜温度に加熱して熱膨張させた後、上記挿入状態のまま堰止め部材を常温まで放冷するので、簡便な操作により堰止め部材を矯正することができる。
【図面の簡単な説明】
【図1】実施の形態1に係る成形型および、成形キャビティ内で流延した樹脂液を示す模式的断面図である。
【図2】使用後の堰止め部材を矯正することなく再使用したときの問題点を説明する模式的断面図である。
【図3】実施の形態1に係るもので、矯正ジグにより堰止め部材を矯正する方法および、その作用を説明する模式的断面図である。
【図4】実施の形態2に係る成形型および、成形キャビティ内で流延した樹脂液を示す模式的断面図である。
【図5】実施の形態3に係る成形型および、成形キャビティ内で流延した樹脂液を示す模式的断面図である。
【図6】実施の形態4に係るもので、成形型に堰止め部材を挿入して図4の遠心成形型を構成する場合の模式的断面図である。
【図7】実施の形態5に係るもので、(a)は引っかけ孔を形成した堰止め部材の断面図、(b)はその拡大平面図である。
【図8】実施の形態6に係るもので、(a)は引っかけ突起を設けた堰止め部材の断面図、(b)はその拡大平面図である。
【図9】実施の形態7に係るもので、(a)は指触乾燥膜を形成した成形型の模式的断面図、(b)はこの成形型を加熱乾燥炉に鉛直方向にセットし、指触乾燥膜を乾燥・固化させて無端状ベルトを得るとともに、堰止め部材を成形型から自然落下させて回収する方法を示す模式的断面図である。
【符号の説明】
1 遠心成形型(成形型)
1a 成形キャビティ
2 堰止め部材
2a 引っかけ孔
2b 引っかけ突起
3a 原料液(樹脂液)
3b 指触乾燥膜
3c 無端状ベルト
4 寄り止め部材
11 矯正ジグ
11a 第1円筒部
11b テーパ部
11c 第2円筒部
12 台座
21 挿入ジグ
31 型保持具
D1 成形型(円筒型)の内径
D2 無端状ベルトの内径
D3 堰止め部材の外径(熱収縮後)
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to an endless belt manufacturing technique, and more particularly to a method for manufacturing an endless sheet-shaped resin belt and a method for correcting a damming member used in the manufacturing method. The present invention can be widely and effectively applied to fixing belts and intermediate transfer belts in electrophotographic copying machines and the like.
[0002]
[Prior art]
The endless belt is conventionally manufactured by a centrifugal molding method. This centrifugal molding method is performed as follows, for example. First, a raw material liquid (for example, a resin solvent solution) is injected and applied into a cylindrical mold that rotates at a low speed. Next, the mold is rotated at a high speed, and the resin liquid (coating liquid) is cast on the inner peripheral surface (molded surface) of the mold by a centrifugal force to expand the film thickness to a uniform thickness. Thereafter, the coating solution is dried by heating and solidified to form an endless sheet-like belt, and finally, the endless belt is peeled and removed from the mold.
[0003]
In this endless belt manufacturing method,
(1) The coating thickness of the raw material liquid can be arbitrarily adjusted according to the amount of injected liquid.
(2) The required amount of raw material liquid may be applied, and the usage efficiency of the raw material liquid is good.
(3) The inside of the mold is a sealed space, and when removing the solvent from the coating solution, a solvent trap can be provided in the exhaust path to efficiently recover the solvent discharged to the outside. There are excellent benefits.
[0004]
However, in this centrifugal molding method, if rotation of the mold is continued in order to make the film thickness of the resin liquid (coating liquid) uniform, this is cast to the end of the mold, and the belt Both ends in the width direction are thinner than the central part, and irregular resin dripping occurs. Therefore, not only is it difficult to peel and take off after drying and solidification, but also a holder such as a chuck that holds the mold. There was a problem of getting dirty.
[0005]
In order to solve this problem, it is necessary to stop the casting of the resin liquid in the mold at an appropriate location. As a means for that purpose, a tape made of a fluororesin has been conventionally attached to the inner peripheral surface of the end portion of the mold with an adhesive, and this has been used as a blocking member for the resin liquid.
[0006]
However, such a tape-shaped damming member takes time and effort to mount, and the adhesive dissolves in the solvent in the resin liquid, so that it does not serve as a damming function, or the holder is soiled. Furthermore, when the inner diameter of the mold is small, there is also a problem that manual tape sticking becomes impossible.
[0007]
In view of this, the present inventors have disclosed, in the specification and drawings of Japanese Patent Application No. 11-20880, as a technique for solving the above-mentioned conventional problems, at least two ring-shaped damming members are provided on the inner peripheral surface of the mold. A method of manufacturing an endless resin belt by a centrifugal molding method was proposed in which a molding cavity is formed by two damming members and an inner peripheral surface of a molding die provided apart from each other.
[0008]
[Problems to be solved by the invention]
However, subsequent studies by the present inventors have revealed that there are the following problems. That is, in the manufacturing method according to the above patent application, if there is even a slight gap between the inner peripheral surface of the mold and the outer peripheral surface of the damming member, the resin liquid penetrates into the gap, and the resin liquid is solidified by solvent evaporation. When drying and solidification is performed afterwards, the molding film floats up and shrinks from the inner peripheral surface of the mold when it is heated and solidified, so the damming member must be in close contact with the inner peripheral surface of the mold Don't be.
[0009]
Moreover, when a material made of a fluororesin (for example, PTFE), which is a heat-resistant plastic, is used as the damming member, it shrinks when it is cooled after heating, and the inner and outer diameters become smaller than before heating, so that it can be reused as it is. In this case, a trouble occurred that a gap was generated between the inner peripheral surface of the mold and the outer peripheral surface of the damming member, so that the role of damming was not achieved. This is presumably because the stress remaining when the damming member was produced by molding was not sufficiently eliminated, so that it gradually contracted in the heating / cooling heat cycle.
[0010]
The present invention has been made in view of the above-mentioned problems, and its purpose is to simplify a method for manufacturing an endless belt that corrects and reuses a damming member after use, and a method for correcting a damming member after use. It is to be provided at a low cost with a simple configuration.
[0011]
[Means for Solving the Problems]
The endless belt manufacturing method according to claim 1, wherein a plurality of plastic or rubber ring-shaped damming members are attached in close contact with each other on a cylindrical inner peripheral surface of a mold, and the weirs facing each other. A centrifugal mold having a molding cavity formed by a stopper member and the inner peripheral surface of the cylinder is prepared, the mold is rotated around a horizontal central axis, and in this state, a raw material liquid containing a solvent is injected and applied to the molding cavity. , A method of forming an endless belt by evaporating the solvent by heating and drying and solidifying the coating liquid while continuing to rotate the mold, and heating the weir member whose diameter after use is reduced It is characterized by being expanded in diameter and reused for centrifugal molding.
[0012]
The endless belt manufacturing method according to claim 2, wherein a plurality of plastic or rubber ring-shaped damming members are mounted in close contact with each other on a cylindrical inner peripheral surface of a mold, and the weirs facing each other. A centrifugal mold having a molding cavity formed by a stopper member and the inner peripheral surface of the cylinder is prepared, the mold is rotated around a horizontal central axis, and in this state, a raw material liquid containing a solvent is injected and applied to the molding cavity. A method of forming an endless belt by evaporating the solvent by heating while continuing to rotate the molding die to dry the coating liquid by touch and then heating and drying and solidifying the dry touch film Then, the weir member whose diameter after use is reduced is expanded by heating and reused for centrifugal molding.
[0013]
A method for producing an endless belt according to claim 3 is the method according to claim 1 or 2, wherein the endless belt is inserted into the molding die by pressing the damming member and sliding it on the cylindrical inner peripheral surface of the molding die. It is characterized by forming.
[0014]
A method for producing an endless belt according to claim 4 is the method according to claim 1 or 2, wherein a ring-shaped detent member for preventing the molded endless belt from shifting when traveling is formed in the molding cavity, and By inserting the damming member in contact with the side surface of the damming member, a detenting member is integrally formed at both ends in the width direction of the endless belt.
[0015]
According to a fifth aspect of the present invention, there is provided a method for manufacturing an endless belt according to the fourth aspect, wherein the stopper member is inserted into the molding die by pressing the stopper member and sliding on the cylindrical inner peripheral surface of the molding die. It is made to contact the side surface of a dam member.
[0016]
According to a sixth aspect of the present invention, there is provided a method for producing an endless belt according to the second aspect of the present invention, wherein a weir member having a thermal expansion coefficient larger than that of the mold is used as the weir member. The outer peripheral surface of the member is in pressure contact with the inner peripheral surface of the cylinder of the mold, and the outer diameter of the blocking member is reduced by the heat shrinkage after the drying and solidification process of the dry touch film obtained in the touch drying process. It is characterized by being made smaller than the diameter of the inner peripheral surface.
[0017]
The manufacturing method of the endless belt according to claim 7 is the endless belt according to claim 6, wherein the outer diameter of the blocking member is an endless shape in the mold due to thermal contraction in the drying / solidifying process of the dry touch film. Use a thermal expansion coefficient that is smaller than the inner diameter of the belt and that has a coefficient of thermal expansion greater than that of the mold. Place the mold after the touch drying process vertically in a heating and drying oven to dry and solidify the dry touch film. Thus, an endless belt is obtained, and the damming member is naturally dropped from the mold and collected.
[0018]
An endless belt manufacturing method according to an eighth aspect is characterized in that, in any one of the first to seventh aspects, the damming member is made of a fluororesin, preferably PTFE (polytetrafluoroethylene).
[0019]
In order to reuse the damming member according to claim 9 in the manufacturing method of the endless belt according to claim 1 or 2, the damming member having a reduced diameter after use is expanded by heating. A first cylindrical portion made of metal, glass or ceramics and having an outer diameter that is large enough to insert and lock the inner peripheral surface of the damming member, and a diameter that increases continuously with the first cylindrical portion. A correction jig comprising a hollow conical taper portion and a second cylindrical portion connected to the taper portion is prepared, and a correction jig in which a weir member is inserted and locked to the outer peripheral surface of the first cylinder portion is The damming member is heated in a state in which the cylindrical portion is in the lower part so as to be the lower portion, and the expanded damming member is dropped by its own weight onto the lower end portion of the second cylindrical portion through the tapered portion. The damming member is allowed to cool to room temperature with By that equal to the outer diameter of the second cylindrical portion, the outer diameter of the dam member Return to the outer diameter of the blocking member before use It is characterized by that.
[0020]
The basic principle for reusing the damming member according to the present invention is that the damming member made of plastic or rubber utilizes thermal characteristics that expand / contract by heating / cooling.
[0021]
That is,
(1) By heating the contracted damming member to thermally expand it and returning it to the dimension before contraction, by maintaining this dimension, it is possible to adhere to the inner peripheral surface of the mold to be used next time.
(2) For this purpose, the heat-expanded damming member is inserted into an appropriate mold, and the inner peripheral surface of the damming member may be brought into contact with the outer peripheral surface of the mold so as not to shrink.
(3) Also, if there is a possibility of further shrinkage due to internal stress relaxation even when the temperature of the damming member reaches room temperature, the reverse process (expansion) from the ultimate temperature can be achieved by once cooling to below the operating temperature. Therefore, it can be maintained at a diameter larger than the initial diameter (initial diameter: inner and outer diameters of a new weir member).
(4) Since the weir member corrected by the above processing can be attached in a state of being in close contact with the molding die, the original function and effect of the weir member can be obtained.
(5) If the damming member is not heated to a thermal decomposition temperature or higher, the damming member can be repeatedly straightened many times.
[0022]
DETAILED DESCRIPTION OF THE INVENTION
Hereinafter, embodiments of the present invention will be described with reference to the drawings.
Embodiment 1
FIG. 1 is a schematic cross-sectional view showing a mold and a raw material liquid (for example, resin liquid: resin solvent solution) cast in the molding cavity. Two plastic or rubber ring-shaped weir members 2 and 2 are inserted into the centrifugal mold 1 (hereinafter sometimes referred to as a mold) at a predetermined interval, and the outer periphery of these weir members The molding cavity 1 a is formed by bringing the surface into close contact with the cylindrical inner peripheral surface of the mold 1. That is, the molding cavity 1a is formed by the weir members 2 and 2 facing each other and the cylindrical inner peripheral surface.
[0023]
When molding the endless belt, the mold 1 is set on a centrifugal molding machine (not shown) and rotated around the horizontal central axis. In this state, the raw material liquid 3a is injected into the molding cavity 1a, While casting, the raw material liquid is heated to evaporate the solvent, thereby forming a dry touch film. The molding die is taken out from the centrifugal molding machine, set in a heating and drying furnace (not shown), and the endless belt is molded by heating and drying and solidifying the touch-dried film.
[0024]
Thereafter, the mold 1 is allowed to cool, and the endless belt is peeled and collected from the mold 1 and the two damming members are removed. These damming members are contracted by cooling after heating, and the inner and outer diameters are reduced compared to before use. Therefore, when this damming member is reused as it is, a gap is formed between the outer peripheral surface of the damming member 2 and the cylindrical inner peripheral surface of the mold 1 as shown in FIG. This causes a problem of leaking outside through this gap. Therefore, in the present invention, the weir member whose diameter after use has been reduced is corrected by heating (expanding diameter: expanding the diameter) and reused for centrifugal molding. This will be described later.
[0025]
In the dam member 2 shown in FIG. 1, it is preferable that the side surface which contacts a raw material liquid becomes a plane orthogonal to the central axis of this dam member. Further, since the side surface of the weir member is in contact with the raw material liquid in the molding process, it is desirable that the solvent in the raw material liquid is not affected. Further, it is desirable that the damming member is in close contact with the molding surface so as not to be peeled off from the molding surface (cylindrical inner peripheral surface of the mold) or to be displaced or dropped during centrifugal molding at high speed. Furthermore, it is important that the material does not soften in the drying / solidification step (usually a temperature range of about 100 ° C. to 200 ° C.).
[0026]
In the present invention, as shown in FIG. 1, since the weir member 2 is mounted in close contact with the molding surface, resin dripping from both ends of the molding die is prevented, and an endless belt having a uniform film thickness is stabilized. Can be molded.
[0027]
As materials for the weir member 2, polytetrafluoroethylene (PTFE), polyhexafluoropropylene (PHFP), polychlorotrifluoroethylene (PCTFE), polyfluorovinylidene (PVdF), polyfluorovinyl (PVF) and polyfluoro A fluororesin such as ethylene propylene (PFEP) is preferred. Among these, PTFE which is excellent in solvent resistance, heat resistance, non-adhesiveness, releasability and the like is particularly preferable.
[0028]
FIG. 3 is a schematic cross-sectional view for explaining the method of correcting the damming member (contraction thereof) by the correction jig and the operation thereof. The metal straightening jig 11 shown in FIG. 3 has a coefficient of thermal expansion that is much smaller than that of the damming member 2 and has an outer diameter that allows the inner peripheral surface of the damming member 2 to be inserted and locked. It consists of a certain first cylindrical portion 11a, a hollow conical tapered portion 11b which is continuous with the first cylindrical portion and has a gradually increasing diameter, and a second cylindrical portion 11c which is continuous with the tapered portion. The outer diameter of the second cylindrical portion 11c is the same as that of the damming member after correction. Return to the outer diameter of the blocking member before use Is set to
[0029]
At the time of correction, as shown in FIG. 3, the correction jig 11 is fixed vertically on the pedestal 12 so that the second cylindrical portion 11c is at the lower portion, and the dam member (before correction) 2 is fixed to the first cylindrical portion 11a. The straightening jig 11 is inserted into a heating furnace (not shown) integrally with the base 12 and the damming member 2 and the straightening jig 11 are heated to appropriate temperatures for a predetermined time. Thereby, the expanded dam member 2 falls to the lower end portion of the second cylindrical portion 11c through the tapered portion 11b due to its own weight. The inner and outer diameters of the weir members that have dropped to the lower end of the second cylindrical portion 11c are almost equal to the initial values. In this state, by allowing the straightening jig and the damming member to cool to room temperature, the inner and outer diameters of the damming member 2 are maintained at the initial values. The dam member 2 after being allowed to cool can be easily extracted from the lower end of the second cylindrical portion 11c by removing the correction jig 11 from the pedestal 12.
[0030]
Embodiment 2
FIG. 4 is a schematic cross-sectional view showing a mold and a raw material liquid (resin liquid) cast in the molding cavity. Four plastic or rubber ring-shaped dam members 2 are inserted into the mold 1 at predetermined intervals, and the outer peripheral surfaces of these dam members are in close contact with the cylindrical inner surface of the mold 1 Thus, three molding cavities 1a are formed.
[0031]
When molding an endless belt, the mold 1 is set on a centrifugal molding machine (not shown) and rotated around a horizontal central axis. In this state, a raw material liquid is injected into each molding cavity, While casting, the raw material liquid is heated to evaporate the solvent, thereby forming a dry touch film. Hereinafter, three endless belts can be obtained by one molding in the same manner as in the first embodiment.
[0032]
Embodiment 3
FIG. 5 is a schematic cross-sectional view showing a molding die and a raw material liquid cast in the molding cavity. In addition to setting the four weiring members 2 in the same manner as in FIG. 4, the forming die 1 has a ring-shaped detent member 4 for preventing the formed endless belt from deviating during travel. Are inserted in contact with the side surface of the damming member 2. According to this mold, three endless belts in which the detent members 4 are integrally formed at both ends in the width direction of the endless belt can be obtained by one molding. As the stopper member 4, for example, a conventionally known stainless steel mesh belt can be used.
[0033]
Embodiment 4
FIG. 6 is a schematic cross-sectional view of the case where the molding die of FIG. 4 is configured by inserting and setting a damming member into a cylindrical mold to form a molding cavity. As shown in FIG. 6, the dam member 2 whose outer diameter is slightly smaller than the cylindrical inner diameter D1 is pressed by the insertion jig 21, and inserted and set at a predetermined position of the cylindrical type while sliding on the inner peripheral surface of the cylinder. . Further, the stopper member 4 can be inserted and set in the same manner as the dam member 2, and the keeper member 4 is brought into contact with the side surface of the dam member 2 as shown in FIG.
[0034]
Embodiment 5
After the endless belt is formed, it is important that the weir member can be easily taken out from the forming die. Therefore, in the present embodiment, as shown in FIG. 7, as the dam member 2, a member in which a hook hole 2a for a drawing tool (not shown) is formed in a portion that does not contact the raw material liquid 3a at the time of molding is molded. A cavity is formed. FIG. 7A is a sectional view of the damming member 2, and FIG. 7B is an enlarged plan view thereof. Thereby, the blocking member 2 can be taken out easily and without touching the thin film belt.
[0035]
Embodiment 6
The molding die 1 according to the present embodiment replaces the hooking hole 2a of the fifth embodiment with the damming member 2 provided with the hooking protrusion 2b as shown in FIG. The operation of taking out the damming member 2 is simplified. FIG. 8A is a sectional view of the damming member 2, and FIG. 8B is an enlarged plan view thereof.
[0036]
Embodiment 7
FIG. 9 shows a method for recovering the weir member by naturally dropping it from the mold after forming the endless belt. FIG. 9A is a cross-sectional view of the mold on which the dry touch film is formed. (B) is a method in which this mold is set in a heating / drying furnace in the vertical direction, the touch-dried film is dried and solidified to obtain an endless belt, and the weir member is naturally dropped from the mold and recovered. It is sectional drawing shown.
[0037]
Also in the present embodiment, the weir member 2 having a thermal expansion coefficient larger than that of the mold 1 is used. That is, in the molding process, the outer peripheral surface comes into pressure contact with the cylindrical inner peripheral surface of the mold 1 due to thermal expansion of the weir member 2, and after the molding process, the outer diameter of the weir member becomes the cylindrical inner peripheral surface of the mold 1 due to thermal contraction. Use one that is smaller than the diameter. Thereby, not only the original action of the damming member can be obtained, but also the member can be easily detached from the mold after the molding step, for example, as follows.
[0038]
In the recovery method of the dam member according to the seventh embodiment, the following is used as the dam member (see FIG. 9).
(1) The outer diameter is equal to or slightly smaller than the inner diameter D1 of the mold 1, and when it is inserted into the mold 1, it is in close contact with the inner peripheral surface of the cylinder.
(2) In the process of drying the injection raw material liquid in the molding cavity with the touch and then drying and solidifying the dry touch film 3b by heating, the outer peripheral surface of the blocking member is thermally expanded in the cylinder of the mold 1 It is in pressure contact with the peripheral surface.
(3) When the weir member is cooled after the drying / solidifying step, the outer diameter D3 of the weir member becomes smaller than the inner diameter D2 of the endless belt 3c in the mold 1 due to thermal contraction.
[0039]
Next, a method for collecting the weir member will be described with reference to the drawings. The mold 1 after the touch-drying is set in a heating and drying furnace (not shown) in the vertical direction. In this case, as shown in FIG. 9B, the mold 1 is fixed on the appropriate mold holder 31 in the vertical direction, and the mold holder 31 is inserted into the heating and drying furnace as it is. Subsequently, after drying and solidifying the dry touch film 3b [FIG. 9A] to form an endless belt 3c, the mold is allowed to cool to room temperature in a heating and drying furnace.
[0040]
In the molding process, as shown in FIG. 9A, the outer peripheral surface of the blocking member 2 is in pressure contact with the cylindrical inner peripheral surface of the mold 1, but after the molding process is completed, the blocking member 2 is thermally contracted. Since the outer diameter D3 is smaller than the inner diameter D2 of the endless belt 3c, the damming member 2 naturally falls and is collected by the mold holder 31 as shown in FIG.
[0041]
【Example】
Next, examples of the present invention will be described.
Example 1
As shown in FIG. 1, a mold made of aluminum (coefficient of thermal expansion 2.5 × 10 -Five / ° C), a new PTFE ring weir member (thermal expansion coefficient 8 × 10) -Five ~ 12x10 -Five / ° C.) were inserted and set, and then the mold was set in the centrifugal molding machine in the horizontal direction. While the mold was rotated at a low speed around the horizontal central axis, a polyimide precursor varnish was gradually injected as a raw material solution to form a coating film. Next, by rotating the mold at a high speed, the film thickness of the coating film is made uniform, and further, the coating liquid is dried and solidified by heating at 70 ° C. for about 30 minutes while rotating the mold at a high speed. A belt was obtained. The molding die was taken out from the centrifugal molding machine, and the damming member was removed from the molding die. As a result, the damming member could be easily removed. Further, the raw material liquid did not leak from the mold, and the members around the mold were not soiled.
[0042]
When the removed damming member was reinserted and set in the mold, the damming member was contracted compared to that before use in Example 1, so that the gap between the damming member and the cylindrical inner peripheral surface of the mold was reduced. A gap has occurred. Therefore, the shrunk damming member was inserted and locked into the first cylindrical portion 11a of the correction jig 11 made of aluminum shown in FIG. 3, and this was placed in a heating furnace and heated at 100 ° C. or higher.
[0043]
When observing, the damming member 2 dropped the first cylindrical portion 11a and then the tapered portion 11b as the temperature rose, and dropped to the lower end of the second cylindrical portion 11c when the temperature was sufficiently raised. The correction jig 11 was taken out of the heating furnace together with the base 12 and allowed to cool to room temperature. As a result, the weir member 2 gradually contracted, and the dimensions and form of the weir member 2 were stabilized when the outer diameter became almost equal to the outer diameter of the second cylindrical portion 11c.
[0044]
Thereafter, when the weir member 2 was removed from the correction jig 11 and inserted into the mold, it was able to be set in a state of being in close contact with the inner peripheral surface of the cylinder as with a new weir member. As a result of molding the endless belt again using this mold, there was no leakage of the raw material liquid from the mold and a good quality endless belt was obtained. The reason why the damming member after correction can be set in such a state that the damming member is in close contact with the cylindrical inner peripheral surface of the molding die is that the outer diameter of the second cylindrical portion 11c is set to an appropriate value. .
[0045]
Comparative Example 1
In Example 1, instead of taking out the correction jig 11 from the heating furnace together with the pedestal 12 and allowing it to cool to room temperature as it is, the damming member in a state where the correction jig 11 taken out of the heating furnace has not yet been sufficiently cooled. Was removed and allowed to cool to room temperature overnight. The next day, when this blocking member was to be attached to the mold, a gap was formed between the inner peripheral surface of the mold and the cylinder. As a result of injection, application, heat drying and solidification of the raw material liquid using this mold as it is, there is evidence that the raw material liquid has flowed between the outer peripheral surface of the blocking member and the inner peripheral surface of the mold. It was.
[0046]
Example 2
In Example 1, instead of taking out the correction jig 11 together with the pedestal 12 from the heating furnace and allowing it to cool to room temperature as it was, the correction jig 11 was taken out of the heating furnace together with the pedestal 12 and stored in the refrigerator. After being sufficiently cooled (for 3 hours or more), the weir member was removed from the correction jig. After leaving it for one day or more as it was, it was set in a mold, and the weiring member was in close contact with the inner circumferential surface of the cylinder of the mold, and a normal molding operation could be performed.
[0047]
Example 3
As in Example 1, the setting of the blocking member to the mold and the correction work were repeated 100 times or more. As a result, proper correction work of the damming member could be performed with good reproducibility, and no deterioration was found in the inner and outer diameter recovery of the damming member and the damming effect at the time of applying the raw material liquid.
[0048]
Comparative Example 2
When the damming member used in Example 1 was reused without correction, the raw material liquid leaked from the end of the mold, so that the rotating holder of the centrifugal molding machine was soiled, and a great deal of time was required for cleaning. It cost. Further, in the undried coating liquid portion, the coating film floated and contracted from the cylindrical inner peripheral surface of the mold, so that a trouble that a good endless belt could not be obtained frequently occurred.
[0049]
Example 4
As shown in FIG. 4, after inserting and setting four PTFE weir members corrected in the same manner as in the first embodiment at equal intervals using the insertion jig 21 shown in FIG. The mold was set in a centrifugal molding machine, and the raw material liquid was injected while rotating the mold. Further, the coating solution was heated by rotating the mold to dry the coating solution. The mold was removed from the centrifugal molding machine, inserted into a heating and drying furnace in the vertical direction, and heated at 100 ° C. for 30 minutes (see FIG. 9). Then, when the heating and drying furnace was cooled and returned to room temperature, the damming member could be dropped and collected at the bottom of the furnace while the obtained endless belt remained attached to the mold. For this reason, there was no need to manually remove the weir member from the mold.
[0050]
【The invention's effect】
As is apparent from the above description, the present invention provides the following effects.
(1) A method for producing an endless belt according to claims 1 and 2
When manufacturing an endless belt using a centrifugal mold, a weir member with a predetermined configuration is closely inserted into the mold to form a molding cavity, and the raw material liquid is injected into this molding cavity. Thus, it is possible to accurately prevent the resin dripping, and to manufacture a high-quality belt stably. Further, if a large number of weir members are set in a long mold, a large number of endless belts can be obtained by a single molding operation.
[0051]
In the present invention, in particular, a damming member made of an elastic or flexible thermoplastic organic polymer resin is used, and the damped member after shrinkage is molded before use by so-called heat setting. Since the size and shape are restored / stabilized and reused, the damming member can be used effectively.
[0052]
(2) The manufacturing method of the endless belt according to claim 3
Since the damming member is pressed and slid on the cylindrical inner peripheral surface of the mold, it is inserted into the mold, so that the insertion and setting can be performed easily.
[0053]
(3) A method for producing an endless belt according to claims 4 and 5
It is possible to simply insert and set the stopper member into the mold. In addition, since an endless belt in which the stopper member is integrally formed is obtained, the belt with the stopper member can be manufactured by a simple process.
[0054]
(4) A method for producing an endless belt according to claims 6 and 7
The removal / recovery operation of the damming member from the mold, which is performed after the endless belt molding, can be easily and efficiently performed. In particular, according to the manufacturing method of claim 7, after the endless belt is obtained, there is a remarkable effect that the damming member can be recovered from the mold by natural fall.
[0055]
(5) The manufacturing method of the endless belt according to claim 8
Uses a damming member made of a fluororesin that has excellent heat resistance, solvent resistance, and peelability, making it easy to handle, allowing it to fully function as a damming member, and a molded endless belt Can be easily separated from the damming member.
[0056]
(6) The correction method of the damming member according to claim 9
A damming member is inserted and locked to the outer peripheral surface of a straight jig having a predetermined configuration, and the damming member is heated to an appropriate temperature and thermally expanded while the straightening jig is kept in a vertical direction, and then dammed in the inserted state. Since the member is allowed to cool to room temperature, the damming member can be corrected by a simple operation.
[Brief description of the drawings]
FIG. 1 is a schematic cross-sectional view showing a molding die according to Embodiment 1 and a resin liquid cast in a molding cavity.
FIG. 2 is a schematic cross-sectional view illustrating a problem when a damming member after use is reused without being corrected.
FIGS. 3A and 3B are schematic cross-sectional views for explaining a method of correcting a damming member using a correction jig and its operation according to the first embodiment. FIGS.
4 is a schematic cross-sectional view showing a molding die according to Embodiment 2 and a resin liquid cast in the molding cavity. FIG.
5 is a schematic cross-sectional view showing a molding die according to Embodiment 3 and a resin liquid cast in the molding cavity. FIG.
6 relates to the fourth embodiment, and is a schematic cross-sectional view of the centrifugal mold shown in FIG. 4 when a dam member is inserted into the mold. FIG.
7A and 7B relate to the fifth embodiment, in which FIG. 7A is a cross-sectional view of a damming member in which a hook hole is formed, and FIG. 7B is an enlarged plan view thereof.
8A and 8B relate to the sixth embodiment, in which FIG. 8A is a cross-sectional view of a damming member provided with a hooking projection, and FIG. 8B is an enlarged plan view thereof.
FIG. 9 relates to Embodiment 7, wherein (a) is a schematic cross-sectional view of a molding die on which a dry touch film is formed, (b) is a vertical setting of this molding die in a heating and drying furnace, FIG. 3 is a schematic cross-sectional view showing a method for drying and solidifying a touch-sensitive dry film to obtain an endless belt, and a method for recovering a weir member by naturally dropping it from a mold.
[Explanation of symbols]
1 Centrifugal mold (mold)
1a Molding cavity
2 Damping member
2a hook hole
2b hook projection
3a Raw material liquid (resin liquid)
3b Dry touch film
3c endless belt
4 Locking member
11 Straightening jig
11a 1st cylindrical part
11b Taper part
11c 2nd cylindrical part
12 pedestal
21 Insertion jig
31 type holder
D1 Inner diameter of mold (cylindrical)
D2 Inside diameter of endless belt
D3 Outside diameter of weir member (after heat shrink)

Claims (9)

成形型の円筒内周面に複数個のプラスチック製またはゴム製のリング状堰止め部材を所定間隔で密着状態に装着し、互いに対向する堰止め部材と前記円筒内周面とにより成形キャビティを形成した遠心成形型を用意し、該成形型を水平中心軸の周りに回転させ、この状態で溶剤を含む原料液を成形キャビティに注入塗布し、成形型の回転を継続しながら加熱により前記溶剤を蒸発させて前記塗布液を乾燥・固化させることにより無端状ベルトを成形する方法であって、使用後の直径が縮小した堰止め部材を加熱により拡径して遠心成形に再使用することを特徴とする無端状ベルトの製造方法。 A plurality of plastic or rubber ring-shaped damming members are attached in close contact with the inner peripheral surface of the molding die at predetermined intervals, and a molding cavity is formed by the damming members facing each other and the inner peripheral surface of the cylinder A centrifugal mold is prepared, the mold is rotated around a horizontal central axis, and in this state, a raw material liquid containing a solvent is injected and applied to the molding cavity, and the solvent is removed by heating while continuing to rotate the mold. A method of forming an endless belt by evaporating and drying and solidifying the coating solution, wherein a weir member whose diameter has been reduced after use is expanded by heating and reused for centrifugal molding A method for producing an endless belt. 成形型の円筒内周面に複数個のプラスチック製またはゴム製のリング状堰止め部材を所定間隔で密着状態に装着し、互いに対向する堰止め部材と前記円筒内周面とにより成形キャビティを形成した遠心成形型を用意し、該成形型を水平中心軸の周りに回転させ、この状態で溶剤を含む原料液を成形キャビティに注入塗布し、成形型の回転を継続しながら加熱により前記溶剤を蒸発させて前記塗布液を指触乾燥させた後、この指触乾燥膜を加熱して乾燥・固化させることにより無端状ベルトを成形する方法であって、使用後の直径が縮小した堰止め部材を加熱により拡径して遠心成形に再使用することを特徴とする無端状ベルトの製造方法。 A plurality of plastic or rubber ring-shaped damming members are attached in close contact with the inner peripheral surface of the molding die at predetermined intervals, and a molding cavity is formed by the damming members facing each other and the inner peripheral surface of the cylinder A centrifugal mold is prepared, the mold is rotated around a horizontal central axis, and in this state, a raw material liquid containing a solvent is injected and applied to the molding cavity, and the solvent is removed by heating while continuing to rotate the mold. A method of forming an endless belt by evaporating and drying the coating liquid to the touch and then drying and solidifying the touch-dried film, wherein the weir member has a reduced diameter after use. A method for producing an endless belt, wherein the diameter is expanded by heating and reused in centrifugal molding. 堰止め部材を押圧して成形型の円筒内周面に摺動させることにより成形型に挿入して、成形キャビティを形成することを特徴とする請求項1または2に記載の無端状ベルトの製造方法。 The endless belt according to claim 1 or 2, wherein the dam member is pressed and slid on the cylindrical inner peripheral surface of the mold to be inserted into the mold to form a molding cavity. Method. 成形された無端状ベルトの走行時の寄りを防止するためのリング状寄り止め部材を成形キャビティ内に、かつ、堰止め部材の側面に接触させた状態で挿入することにより、無端状ベルトの幅方向両端部に寄り止め部材を一体成形することを特徴とする請求項1または2に記載の無端状ベルトの製造方法。 By inserting a ring-shaped detent member for preventing the molded endless belt from shifting during running into the molding cavity and in contact with the side surface of the weir member, the width of the endless belt The method for producing an endless belt according to claim 1 or 2, wherein a detent member is integrally formed at both ends in the direction. 寄り止め部材を押圧して成形型の円筒内周面に摺動させることにより成形型に挿入して、寄り止め部材を堰止め部材の側面に接触させることを特徴とする請求項4に記載の無端状ベルトの製造方法。 5. The stopper according to claim 4, wherein the stopper member is pressed and slid on the cylindrical inner peripheral surface of the molding die to be inserted into the molding die, and the stopper member is brought into contact with a side surface of the damming member. A method for producing an endless belt. 堰止め部材として熱膨張係数が成形型のそれより大きいものを用いることにより、指触乾燥工程では熱膨張により当該堰止め部材の外周面が成形型の円筒内周面に圧接し、指触乾燥工程で得られた指触乾燥膜の乾燥・固化工程後には熱収縮により当該堰止め部材の外径が成形型の円筒内周面の直径より小さくなるようにしたことを特徴とする請求項2に記載の無端状ベルトの製造方法。 By using a weir member with a coefficient of thermal expansion greater than that of the mold, the outer surface of the weir member is pressed against the inner surface of the cylinder of the mold by thermal expansion in the touch drying process, and the touch is dried. The outer diameter of the damming member is made smaller than the diameter of the cylindrical inner peripheral surface of the mold by heat shrinkage after the drying and solidification step of the dry touch film obtained in the step. A process for producing an endless belt as described in 1. 堰止め部材として、指触乾燥膜の乾燥・固化工程では熱収縮により当該堰止め部材の外径が成形型内における無端状ベルトの内径より小さくなるような、熱膨張係数が成形型のそれより大きいものを使用し、指触乾燥工程後の成形型を加熱乾燥炉に鉛直方向に入れ、指触乾燥膜を乾燥・固化させて無端状ベルトを得るとともに、堰止め部材を成形型から自然落下させて回収することを特徴とする請求項6に記載の無端状ベルトの製造方法。 As a weir member, the thermal expansion coefficient is smaller than that of the mold so that the outer diameter of the weir member is smaller than the inner diameter of the endless belt in the mold due to thermal contraction in the drying / solidification process of the dry touch film. Use a large one, put the mold after the touch drying process vertically in the heating drying oven, dry and solidify the touch drying film to obtain an endless belt, and let the weir member fall naturally from the mold And collecting the endless belt according to claim 6. 堰止め部材がフッ素系樹脂からなることを特徴とする請求項1〜7のいずれかに記載の無端状ベルトの製造方法。 The method for producing an endless belt according to any one of claims 1 to 7, wherein the damming member is made of a fluororesin. 請求項1または2に記載の無端状ベルトの製造方法に再使用するために、使用後の直径が縮小した堰止め部材を加熱により拡径する方法であって、金属、ガラスまたはセラミックスからなり、外径が堰止め部材の内周面を挿入係止しうる大きさである第1円筒部と、この第1円筒部に連なり直径が漸増する中空円錐状のテーパ部と、該テーパ部に連なる第2円筒部とを備えてなる矯正ジグを用意し、第1円筒部の外周面に堰止め部材を挿入係止した矯正ジグを第2円筒部が下部となるように鉛直方向に沿わせた状態で堰止め部材を加熱し、膨張した堰止め部材を自重により前記テーパ部を介して第2円筒部の下端部に落下させ、この状態で堰止め部材を常温まで放冷して、矯正後の堰止め部材の内径を第2円筒部の外径と等しくすることにより、この堰止め部材の外径を使用前の堰止め部材の外径に戻すことを特徴とする堰止め部材の矯正方法。 In order to reuse the endless belt manufacturing method according to claim 1 or 2, it is a method of expanding a weir member whose diameter after use is reduced by heating, and is made of metal, glass or ceramics, A first cylindrical portion having an outer diameter that is large enough to insert and lock the inner peripheral surface of the damming member, a hollow conical tapered portion that is continuous with the first cylindrical portion, and that gradually increases in diameter, and is continuous with the tapered portion A straightening jig comprising a second cylindrical portion was prepared, and the straightening jig in which a damming member was inserted and locked on the outer peripheral surface of the first cylindrical portion was aligned along the vertical direction so that the second cylindrical portion was at the bottom. The dam member is heated in this state, and the expanded dam member is dropped to the lower end of the second cylindrical portion through the taper portion by its own weight. By making the inner diameter of the weir member equal to the outer diameter of the second cylindrical portion Straightening method of dam members and returning to the outer diameter of the dam member before using the outer diameter of the dam member.
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