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JP3977682B2 - Quartz crystal resonator and its holding structure - Google Patents
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JP3977682B2 - Quartz crystal resonator and its holding structure - Google Patents

Quartz crystal resonator and its holding structure Download PDF

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Publication number
JP3977682B2
JP3977682B2 JP2002138441A JP2002138441A JP3977682B2 JP 3977682 B2 JP3977682 B2 JP 3977682B2 JP 2002138441 A JP2002138441 A JP 2002138441A JP 2002138441 A JP2002138441 A JP 2002138441A JP 3977682 B2 JP3977682 B2 JP 3977682B2
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Prior art keywords
electrode
layer
bonding
lead
crystal piece
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JP2003332876A (en
Inventor
精司 小田
博 上原
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Nihon Dempa Kogyo Co Ltd
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Nihon Dempa Kogyo Co Ltd
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Description

【0001】
【発明の属する技術分野】
本発明は水晶振動子を産業上の技術分野とし、特に表面実装用として共晶合金を用いた水晶振動子(表面実装振動子とする)の保持構造に関する。
【0002】
【従来の技術】
(発明の背景)表面実装振動子は小型・軽量であることから、特に携帯機器例えば携帯電話の周波数や時間の基準源として使用される。近年では、高信頼及び高周波化が一層求められ、これに起因して保持構造等の見直が求められている。
【0003】
(従来技術の一例)第3図及び第4図は一従来例を説明する図で、第3図は表面実装振動子の分解組立図、第4図は水晶片の断面図である。
表面実装振動子は、容器本体1に水晶片2を収容してカバー3を被せ、水晶片2を密閉封入してなる。容器本体1は例えば凹状とした積層セラミックからなり、内底面に水晶片2との接続端子としての一対のメタライズ層(水晶端子とする)4を有する。外表面(底面及び側面)には、水晶端子4と電気的に接続した表面実装用の図示しない実装電極を有する。
【0004】
水晶片2は両主面に励振電極5を有し、引出電極を経て一端部両側に外部接続用の導出電極6を形成する。導出電極6はそれぞれ角部の側面を経て反対面に折り返して形成される。そして、これらの各電極は、水晶片2の主面から、一層目を下地電極8、二層目を導通電極9として、蒸着等によって形成される。ここでは、一層目(下地電極8)をCr、二層目(導通電極9)をAuとする。なお、水晶片2と導通電極9としてのAuとは付着強度が低いため、両者間に馴染みのよい下地電極8としてCrを介在させる。
【0005】
そして、一端部両側の導出電極6が、これと対応して形成された内底面の水晶端子4に面対向して、導電性接着剤7によって固着される。そして、例えば容器本体1の開口端面に設けられた図示しない金属リングやメタライズ層に、金属としたカバー3をシームやビーム溶接によって接合してなる。
【0006】
【発明が解決しようとする課題】
(従来技術の問題点)しかしながら、上記構成の表面実装振動子では、導電性接着剤7によって水晶片2を固着する保持構造に起因して次の問題があった。すなわち、導電性接着剤7は、有機物としての高分子からなる例えばシリコン系の樹脂を母体とする。
【0007】
このため、例えば導電性接着剤7の硬化時に有機物から放出ガスが発生し、これが水晶片2に付着して経年変化特性を悪化させる問題があった。特に高周波化(例えば100MHz以上)が進み、水晶片2が薄くなるほど影響は大きく、問題は顕著になる。また、仕様等が厳しく高信頼を求められた場合も同様である。
【0008】
(発明の目的)本発明は経年変化特性を良好にして、高周波化及び高信頼性を促進する水晶振動子及びその保持構造を提供することを目的とする。
【0009】
【課題を解決するための手段】
(着目点及び適用)本発明は、金属サポータと水晶片とを共晶合金によって接合した既存の保持構造に着目して、表面実装振動子に適用したことを基本的な解決手段とする。本発明では、これにより、有機物からのガスの発生がなく経年変化特性を良好に維持した表面実装振動子を得られる。
【0010】
また、本発明は、基本的に、水晶振動子(水晶片)における電極導出部の電極構造は水晶片の主面から一層目を下地電極、二層目を導通電極、三層目を遮蔽電極、四層目を共晶合金からなる接合電極として、前記下地電極はCr、前記導通電極はAu、前記遮蔽電極はCr又はNi、前記接合電極はAuGeとし、前記遮蔽電極は前記接合電極の溶融時に前記導通電極の喰われを抑止した構成とする。
【0011】
【実施例】
第1図は本発明の一実施例を説明する表面実装振動子の図で、第1図は組立断面図、第2図は水晶片の断面図である。なお、前従来例と同一部分には同番号を付与してその説明は簡略又は省略する。
表面実装振動子は、前述したように容器本体1に水晶片2を収容してカバー3を被せ、密閉封入してなる。ここでは、容器本体1は凹部の内壁に段部を設け、一端側の段部両側に水晶端子4を設ける。そして、開口端面(枠壁上面)にAuからなるメタライズ層10を有する。
【0012】
水晶片2は前述同様に両主面に励振電極5を、これと接続した導出電極6を一端部両側に有する。ここでも、一層目の下地電極8をCr、二層目の導通電極9をAuとする。そして、二層目の導通電極9上に、三層目として遮蔽電極11を、さらにその上に四層目として接合電極12を蒸着等によって形成する。なお、遮蔽電極11は接合電極12よりも突出して形成される。
【0013】
この例では、三層目の遮蔽電極11はCrとし、四層目の接合電極12はAuGeからなる共晶合金とする。なお、図では各層の厚みは同程度にしたが、下地電極8のCrが約300オングストローム、導通電極9のAuが600オングストローム、遮蔽電極11のCrが1000オングストローム以上、接合電極12が1〜2μm程度とする。カバー3は金属からなり、周回する外周にAuSnの共晶合金からなる接合材13が圧接によって形成される。
【0014】
このようなものでは、水晶片2の一端部両側に形成された導出電極6と容器本体1の段部に形成された水晶端子4とを対面させて、水晶片2の両端部を両側の段部上に載置する。そして、図示しない治工具を用いて、水晶片2の一端部両側を加熱するとともに押圧する。要するに、熱圧着によって、四層目12の接合電極12(共晶合金AuGe)を溶融し、一端部両側を水晶端子4に電気的・機械的に接続する。
【0015】
次に、水晶片2の一端部両側を保持した後、例えば励振電極5にイオンビームを照射して振動周波数を調整する。そして、調整後、接合材13(共晶合金AuSn)の設けられたカバー3の外周を、容器本体1の開口端面に当接して、前述同様の熱圧着によって接合する。これにより、水晶片2を密閉封入する。
【0016】
このような構成であれば、従来例の導電性接着剤を使用することなく、共晶合金を用いた水晶片2の接合となり、容器本体1内には有機物の存在が殆どない。したがって、放出ガスが水晶片2に付着することもないので、経年変化特性を良好に維持して、表面実装振動子の高信頼性及び高周波化を促進する。
【0017】
また、この実施例例では、二層目の導通電極9(Au)と四層目の接合電極12(共晶合金AuGe)との間に遮蔽電極11(Cr)を介在させる。したがって、熱圧着時に、溶融した接合電極12が遮蔽電極11によって遮断されて、流出を抑止して導通電極9の喰われを防止する。
【0018】
なお、遮蔽電極11が無い場合には、接合電極12(AuGe)と導通電極9(Au)が融合して、導通電極9が接合電極12に吸引されて所謂喰われを生じて剥離する。これにより、導通不良を引き起こす。したがって、この実施例では、遮蔽電極11によって導通電極9の喰われを防止して、導通を確実に維持できる。
【0019】
さらに、この実施例では、容器本体1とカバー3をAuSnの共晶合金からなる接合材13を用いた熱圧着によって接合する。この場合、水晶片2を固着する接合電極12の共晶合金AuGeよりも、接合材13の溶融温度の方が低い。ちなみに、AuGeの溶融温度は約356℃であり、接合材13のそれは280℃である。したがって、カバー3の接合時に接合電極12(AuGe)が溶融することなく、保持状態を維持する。
【0020】
したがって、水晶片2の保持及びカバー3の接合をいずれも熱圧着による作業工程となるので、設備の管理を容易にする。また、例えばシーム溶接やビーム溶接による接合に比較して設備投資を抑制でき、安価にして経済性を高められる。
【0021】
【他の事項】
上記実施例では、一層目の下地電極8はCrとしたが、要は水晶片2と二層目の導通電極9との馴染みがよいものであればよい。また、導通電極9はAuとしたが、基本的には例えばAgやAlの導通度が良好なものであればよい。
【0022】
また、四層目の接合電極12はAuGeとしたが、例えばAuSi(溶融温度363℃)の適用も可能であり、基本的には無機物で溶融温度が回路基板に搭載時のクリーム半田の溶融温度220℃以上で、水晶の転移温度573℃以下とした共晶合金であればよい。また、三層目の遮蔽金属11はCrとしたが、例えばCrNiでもよく、これらは二層目の導通電極9及び四層目の接合電極12との兼ね合いから選択される。
【0023】
また、カバー3はAuSnの共晶合金を用いた熱圧着によって接合したが、これに限らず、シームやビーム溶接あるいはガラスや樹脂封止でもよい。そして、本発明の電極構造を有する水晶片2は必ずしも表面実装振動子のみならず、金属ホルダーに保持した場合でも適用可能である。
【0024】
また、水晶振動子として説明したが、他の回路素子とともに収容して発振器等を構成した場合での適用も可能である。そして、容器本体1は凹部内に段部を設けたが段部が無くとも内底面に直接に熱圧着してもよい。また、容器本体1は平板状として凹状のカバー3を接合してもよい。
【0025】
【発明の効果】
本発明は以上に説明した通りであり、基本的に共晶合金を用いた熱圧着によって水晶片を接合した表面実装振動子を得たので、有機物からの放出ガスによる特性劣化が殆どなく、高品質及び高信頼性の表面実装振動子を提供できる。また、導通電極と接合電極との間に遮蔽電極を介在させたので、接合電極の溶融時に導通電極が喰われることも無く、導通を良好にした例えば熱圧着による接合を可能にする。
【図面の簡単な説明】
【図1】本発明の一実施例を説明する表面実装振動子の組立断面図である。
【図2】本発明の一実施例を説明する水晶片の断面図である。
【図3】従来例を説明する表面実装振動子の組立図である。
【図4】従来例を説明する水晶片の断面図である。
【符号の説明】
1 容器本体、2 水晶片、3 カバー、4 水晶端子、5 励振電極、6 導出電極、7 導電性接着剤、8 下地電極、9 導通電極、10 メタライズ層、11 遮蔽電極、12 接合電極、13 接合材.
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a crystal resonator in an industrial technical field, and more particularly to a holding structure for a crystal resonator (a surface mount resonator) using a eutectic alloy for surface mounting.
[0002]
[Prior art]
(Background of the Invention) Surface mounted resonators are small and light, and are used as a reference source for frequency and time of mobile devices such as mobile phones. In recent years, higher reliability and higher frequency have been demanded, and due to this, a review of the holding structure and the like has been demanded.
[0003]
(Example of Prior Art) FIGS. 3 and 4 are diagrams for explaining one conventional example, FIG. 3 is an exploded view of a surface-mounted vibrator, and FIG. 4 is a sectional view of a crystal piece.
The surface-mounted vibrator is formed by housing a crystal piece 2 in a container body 1 and covering a cover 3, and sealing the crystal piece 2. The container main body 1 is made of, for example, a concave laminated ceramic, and has a pair of metallized layers (crystal terminals) 4 as connection terminals for the crystal piece 2 on the inner bottom surface. On the outer surface (bottom surface and side surface), there are mounting electrodes (not shown) for surface mounting electrically connected to the crystal terminals 4.
[0004]
The quartz crystal piece 2 has excitation electrodes 5 on both main surfaces, and leads electrodes 6 for external connection are formed on both sides of one end through extraction electrodes. The lead-out electrodes 6 are formed by folding back to the opposite surface through the side surfaces of the corners. Each of these electrodes is formed by vapor deposition or the like from the main surface of the crystal piece 2 with the first layer being the base electrode 8 and the second layer being the conduction electrode 9. Here, the first layer (base electrode 8) is Cr, and the second layer (conduction electrode 9) is Au. Since the crystal piece 2 and Au as the conductive electrode 9 have low adhesion strength, Cr is interposed as a base electrode 8 that is familiar to them.
[0005]
Then, the lead-out electrodes 6 on both sides of the one end are fixed by the conductive adhesive 7 so as to face the crystal terminals 4 on the inner bottom surface corresponding to the lead electrodes 6. For example, a cover 3 made of metal is joined to a metal ring or metallization layer (not shown) provided on the opening end surface of the container body 1 by seam or beam welding.
[0006]
[Problems to be solved by the invention]
(Problems of the prior art) However, the surface mount resonator having the above-described configuration has the following problems due to the holding structure in which the crystal piece 2 is fixed by the conductive adhesive 7. That is, the conductive adhesive 7 is based on, for example, a silicon-based resin made of a polymer as an organic substance.
[0007]
For this reason, for example, when the conductive adhesive 7 is cured, an emitted gas is generated from the organic substance, which adheres to the crystal piece 2 and deteriorates the aging characteristics. In particular, as the frequency increases (for example, 100 MHz or more) and the crystal piece 2 becomes thinner, the influence becomes larger and the problem becomes more prominent. The same applies when the specifications are strict and high reliability is required.
[0008]
(Object of the Invention) An object of the present invention is to provide a quartz crystal unit and its holding structure that improve the secular change characteristic and promote high frequency and high reliability.
[0009]
[Means for Solving the Problems]
(Points of interest and application) The present invention focuses on an existing holding structure in which a metal supporter and a crystal piece are joined together by a eutectic alloy, and is applied to a surface mount vibrator as a basic solution. In the present invention, this makes it possible to obtain a surface-mount resonator that does not generate gas from organic substances and that maintains good aging characteristics.
[0010]
In addition, according to the present invention, basically, the electrode structure of the electrode lead-out portion in the crystal resonator (crystal piece) is the base electrode from the main surface of the crystal piece, the conductive electrode from the second layer, and the shielding electrode from the third layer. , and the bonding electrode comprising the fourth layer from the eutectic alloy, said base electrode is Cr, the conductive electrode is Au, the shielding electrode Cr and Ni, the bonding electrode is a AuGe, the shielding electrode of the bonding electrode The conductive electrode is prevented from being eaten at the time of melting.
[0011]
【Example】
FIG. 1 is a view of a surface-mounted vibrator for explaining an embodiment of the present invention, FIG. 1 is an assembled sectional view, and FIG. 2 is a sectional view of a crystal piece. In addition, the same number is attached | subjected to the same part as a prior art example, and the description is simplified or abbreviate | omitted.
As described above, the surface-mounted vibrator is formed by housing the crystal piece 2 in the container body 1 and covering the cover 3 and sealingly sealing it. Here, the container body 1 is provided with a step portion on the inner wall of the recess, and the crystal terminals 4 are provided on both sides of the step portion on one end side. And it has the metallization layer 10 which consists of Au in an opening end surface (frame wall upper surface).
[0012]
Similarly to the above, the crystal piece 2 has the excitation electrodes 5 on both main surfaces and the lead-out electrodes 6 connected to the excitation electrodes 5 on both sides of one end. Also here, the first base electrode 8 is Cr, and the second conductive electrode 9 is Au. Then, a shielding electrode 11 is formed as a third layer on the conductive electrode 9 of the second layer, and a bonding electrode 12 is formed thereon as a fourth layer by vapor deposition or the like. The shield electrode 11 is formed so as to protrude from the bonding electrode 12.
[0013]
In this example, the third-layer shielding electrode 11 is Cr, and the fourth-layer bonding electrode 12 is a eutectic alloy made of AuGe. In the figure, the thickness of each layer is the same, but the Cr of the base electrode 8 is about 300 Å, the Au of the conductive electrode 9 is 600 Å, the Cr of the shielding electrode 11 is 1000 Å or more, and the bonding electrode 12 is 1 to 2 μm. To the extent. The cover 3 is made of metal, and a bonding material 13 made of an eutectic alloy of AuSn is formed by pressure welding on the outer periphery that circulates.
[0014]
In such a case, the lead-out electrodes 6 formed on both sides of one end portion of the crystal piece 2 and the crystal terminals 4 formed on the step portion of the container body 1 face each other, and both end portions of the crystal piece 2 are stepped on both sides. Place on the club. Then, using a jig (not shown), both sides of one end of the crystal piece 2 are heated and pressed. In short, the bonding electrode 12 (eutectic alloy AuGe) of the fourth layer 12 is melted by thermocompression bonding, and both ends of one end are electrically and mechanically connected to the crystal terminal 4.
[0015]
Next, after holding both ends of one end of the crystal piece 2, for example, the excitation electrode 5 is irradiated with an ion beam to adjust the vibration frequency. After the adjustment, the outer periphery of the cover 3 provided with the bonding material 13 (eutectic alloy AuSn) is brought into contact with the opening end surface of the container body 1 and bonded by the same thermocompression bonding as described above. Thereby, the crystal piece 2 is hermetically sealed.
[0016]
With such a configuration, the crystal piece 2 using a eutectic alloy is joined without using the conventional conductive adhesive, and there is almost no organic substance in the container body 1. Therefore, since the emitted gas does not adhere to the crystal piece 2, the secular change characteristic is maintained well, and the high reliability and high frequency of the surface mount vibrator are promoted.
[0017]
In this embodiment, the shielding electrode 11 (Cr) is interposed between the second-layer conducting electrode 9 (Au) and the fourth-layer bonding electrode 12 (eutectic alloy AuGe). Therefore, at the time of thermocompression bonding, the molten bonding electrode 12 is blocked by the shielding electrode 11, and the outflow is suppressed to prevent the conduction electrode 9 from being eaten.
[0018]
In the case where the shielding electrode 11 is not provided, the bonding electrode 12 (AuGe) and the conductive electrode 9 (Au) are fused, and the conductive electrode 9 is attracted to the bonding electrode 12 to cause so-called biting and peeling. This causes poor conduction. Therefore, in this embodiment, the shielding electrode 11 prevents the conduction electrode 9 from being eaten, and the conduction can be reliably maintained.
[0019]
Furthermore, in this embodiment, the container body 1 and the cover 3 are joined by thermocompression using a joining material 13 made of an eutectic alloy of AuSn. In this case, the melting temperature of the bonding material 13 is lower than the eutectic alloy AuGe of the bonding electrode 12 to which the crystal piece 2 is fixed. Incidentally, the melting temperature of AuGe is about 356 ° C., and that of the bonding material 13 is 280 ° C. Therefore, the bonding electrode 12 (AuGe) is not melted when the cover 3 is bonded, and the holding state is maintained.
[0020]
Therefore, both the holding of the crystal piece 2 and the joining of the cover 3 are work steps by thermocompression, thereby facilitating management of equipment. In addition, for example, the equipment investment can be suppressed as compared with the joining by seam welding or beam welding, and the cost can be reduced and the economy can be improved.
[0021]
[Other matters]
In the above embodiment, the ground electrode 8 of the first layer is Cr, but the point is that the crystal piece 2 and the conductive electrode 9 of the second layer are familiar. Further, although the conductive electrode 9 is Au, basically, for example, any material having good conductivity of Ag or Al may be used.
[0022]
Further, although the bonding electrode 12 of the fourth layer is made of AuGe, for example, AuSi (melting temperature 363 ° C.) can also be applied, which is basically an inorganic substance and the melting temperature is the melting temperature of the cream solder when mounted on the circuit board. Any eutectic alloy having a crystal transition temperature of 573 ° C. or lower at 220 ° C. or higher may be used. Further, although the third-layer shielding metal 11 is Cr, it may be, for example, CrNi, which is selected from the balance between the second-layer conductive electrode 9 and the fourth-layer bonding electrode 12.
[0023]
The cover 3 is joined by thermocompression bonding using an eutectic alloy of AuSn. However, the cover 3 is not limited to this, and may be seam, beam welding, glass or resin sealing. The quartz crystal piece 2 having the electrode structure of the present invention can be applied not only to the surface mount vibrator but also to the case where it is held by a metal holder.
[0024]
Further, although described as a crystal resonator, the present invention can also be applied to a case where an oscillator or the like is accommodated together with other circuit elements. And although the container main body 1 provided the step part in the recessed part, even if there is no step part, you may thermocompression-bond directly to an inner bottom face. Moreover, the container main body 1 may be joined to the concave cover 3 as a flat plate shape.
[0025]
【The invention's effect】
The present invention is as described above, and basically obtained a surface-mount resonator in which crystal pieces are bonded by thermocompression bonding using a eutectic alloy. It is possible to provide a surface mount resonator with high quality and high reliability. Further, since the shielding electrode is interposed between the conduction electrode and the bonding electrode, the conduction electrode is not eroded when the bonding electrode is melted, and bonding by, for example, thermocompression bonding with good conduction is enabled.
[Brief description of the drawings]
FIG. 1 is an assembled cross-sectional view of a surface-mounted vibrator for explaining an embodiment of the present invention.
FIG. 2 is a cross-sectional view of a crystal piece for explaining an embodiment of the present invention.
FIG. 3 is an assembly diagram of a surface-mount vibrator for explaining a conventional example.
FIG. 4 is a cross-sectional view of a crystal piece for explaining a conventional example.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1 Container body, 2 Crystal piece, 3 Cover, 4 Crystal terminal, 5 Excitation electrode, 6 Derivation electrode, 7 Conductive adhesive, 8 Ground electrode, 9 Conduction electrode, 10 Metallization layer, 11 Shielding electrode, 12 Joining electrode, 13 Bonding material.

Claims (2)

水晶片の両主面に形成された励振電極から引出電極を延出して接続端子としての電極導出部を設け、前記電極導出部を保持してなる水晶振動子において、前記電極導出部の電極構造は前記水晶片の主面から一層目を下地電極、二層目を導通電極、三層目を遮蔽電極、四層目を共晶合金からなる接合電極として、前記下地電極はCr、前記導通電極はAu、前記遮蔽電極はCr又はNi、前記接合電極はAuGeとし、前記遮蔽電極は前記接合電極の溶融時に前記導通電極の喰われを抑止したことを特徴とする水晶振動子。An electrode structure of the electrode lead-out part in the crystal resonator in which the lead-out electrode is extended from the excitation electrodes formed on both main surfaces of the crystal piece to provide an electrode lead-out part as a connection terminal and holds the electrode lead-out part Is the ground electrode from the main surface of the crystal piece, the second layer is a conductive electrode, the third layer is a shielding electrode, the fourth layer is a bonding electrode made of a eutectic alloy , the ground electrode is Cr, the conductive electrode Is a quartz crystal resonator , wherein the shielding electrode is Cr or Ni, the bonding electrode is AuGe, and the shielding electrode prevents the conduction electrode from being eaten when the bonding electrode is melted. 両主面の励振電極から引出電極を延出してなる電極導出部を有する水晶片と、前記電極導出部に対応してメタライズ層を有する容器本体とを備え、前記電極導出部と前記メタライズ層とを接合してなる水晶振動子の保持構造において、前記電極導出部と前記メタライズ層とを共晶合金を用いた熱圧着によって接合し、前記電極導出部の電極構造は前記水晶片の主面から一層目を下地電極、二層目を導通電極、三層目を遮蔽電極、四層目を共晶合金からなる接合電極として、前記下地電極はCr、前記導通電極はAu、前記遮蔽電極はCr又はNi、前記接合電極はAuGeとし、前記遮蔽電極は前記接合電極の溶融時に前記導通電極への流出を抑止したことを特徴とする水晶振動子の保持構造。A quartz crystal piece having an electrode lead-out portion formed by extending an extraction electrode from excitation electrodes on both main surfaces, and a container body having a metallization layer corresponding to the electrode lead-out portion, the electrode lead-out portion and the metallization layer; In the crystal resonator holding structure formed by bonding, the electrode lead-out part and the metallized layer are joined by thermocompression bonding using a eutectic alloy, and the electrode structure of the electrode lead-out part is from the main surface of the crystal piece. The first layer is a ground electrode, the second layer is a conductive electrode, the third layer is a shield electrode, and the fourth layer is a bonding electrode made of a eutectic alloy. The ground electrode is Cr, the conductive electrode is Au, and the shield electrode is Cr. Alternatively, Ni, the bonding electrode is AuGe, and the shielding electrode suppresses the outflow to the conduction electrode when the bonding electrode is melted .
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JP4451219B2 (en) * 2004-06-03 2010-04-14 日本電波工業株式会社 Crystal oscillator
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