JP4023710B2 - Aluminum-plated steel sheet for hot press with excellent corrosion resistance and heat resistance, and automotive parts using the same - Google Patents
Aluminum-plated steel sheet for hot press with excellent corrosion resistance and heat resistance, and automotive parts using the same Download PDFInfo
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- JP4023710B2 JP4023710B2 JP2001190707A JP2001190707A JP4023710B2 JP 4023710 B2 JP4023710 B2 JP 4023710B2 JP 2001190707 A JP2001190707 A JP 2001190707A JP 2001190707 A JP2001190707 A JP 2001190707A JP 4023710 B2 JP4023710 B2 JP 4023710B2
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Description
【0001】
【発明の属する技術分野】
本発明は、自動車の足回り等の高強度を要求される部品を製造するための鋼素材、及びそれを使用した自動車部品を提供するものである。
【0002】
【従来の技術】
近年、地球環境問題を発端とした低燃費化の動きから自動車用鋼板に対しては高強度化に対する要望が強い。しかし、一般に高強度化は加工性、成形性の低下を伴い、高強度,高成形性を両立する鋼板が要望されている。
これに対する一つの回答は、残留オーステナイトのマルテンサイト変態を利用したTRIP(TRansformation Induced Placiticity)鋼であり、近年用途が拡大しつつある。しかしこの鋼により、成形性の優れた1000MPa級の高強度鋼板は製造することは可能であるが、更に高強度、例えば1500MPaというような超高強度鋼で成形性を確保することは困難である。
【0003】
そこで、高強度、高成形性を両立する別の形として最近注目を浴びているのがホットプレスである。これは鋼板を800℃以上の高温に加熱した状態で成形することにより高強度鋼板の成形性の問題を無くし、成型後の冷却により所望の材質を得るというものである。しかし、大気中での加熱を伴うため、表面に酸化物が生成してこれを後工程で除去する必要がある。これを改善したものが特開2000−38640号公報であり、0.15〜0.5%の炭素を含有する鋼板にアルミめっきして加熱時の酸化抑制を図っている。
【0004】
【発明が解決しようとする課題】
この発明は高強度の成形部品を効率良く製造するのに有効であるが、アルミめっき層はクラックを生じやすく、また通常の腐食環境では地鉄よりも貴な電位を有し、クラックから地鉄の腐食が起こりやすいという欠点を有している。厳しい成形をした後には、クラック部からの短期間での腐食、あるいは塗装後耐食性の低下という問題が生じる。
【0005】
【課題を解決するための手段】
本発明者らは、上記のような課題を克服するためにアルミめっき鋼板の加工後の耐食性への影響因子を詳細に検討した結果、次の知見を得た。めっき層中にMgとSiを複合添加することにより、クラック自体の発生が大きく抑制され、またクラックが発生しても短期間でのクラックからの素地腐食は起こり難く、更に塗装後耐食性も大きく向上していた。Mg,Siを複合添加することにより、ホットプレスのための加熱時にこれら元素を含有する金属間化合物層が生成し、その加工性は通常のアルミめっきをベースとしたものよりも向上していたものと推察される。
【0006】
また、めっき層中にMg2 Siが生成し、これが腐食環境下でMgイオンを放出して地鉄、あるいはめっき層表面に皮膜を形成してクラック部位からの素地腐食を抑制する作用を持つ。更には、Mgの沸点は1090℃で900℃以上の高温域で表面から一部飛散して、表面に微細な凹凸が生じて、その結果塗料の密着性が向上して塗装後耐食性にも有利に働いたものと推定している。更に、Znを複合添加することで、Znの鋼素地の犠牲防食作用も発現し、更に安定した耐食性、塗装後耐食性が得られる。Mgを添加せず、Zn−Siを添加した系でも、Mg−Si添加系Mg−Si−Zn添加系ほどではないが、良好な耐食性、塗装後耐食性が得られる。
【0007】
【発明の実施の形態】
次に、本発明の限定理由について説明する。まず、鋼成分の限定理由を以下に述べる。
C:本発明は成型後に1000MPa以上の高強度を有するものであり、ホットプレス後に急冷してマルテンサイトを主体とする組織に変態させるものであり、そのためにはC量0.1%が必要である。一方、C量を0.5%以上に増大させても強度が飽和してしまうことに加え、溶接割れを生じやすくするため、上限を0.5%に定める。
【0008】
Si:Siは低すぎると疲労特性の低下を惹起するため、0.05%以上の添加が必要である。また、SiはめっきのAlとFe間の反応を促進して鋼板の耐熱性を向上させる効果を有する。しかし、Siは再結晶焼鈍中に安定な酸化皮膜を鋼板表面に形成し、アルミめっき性を阻害する元素でもある。この意味からSiの上限を0.5%とする。
【0009】
Mn:この元素は鋼板の焼入れ性を高める元素としてよく知られている。また、不可避的に混入するSに起因する熱間脆性を防ぐために必要な元素でもある。この理由から0.5%以上の添加が必要である。また、Mnはアルミめっき後の耐熱性も向上させる。しかし、3%を超えてMnを添加すると焼入れ後の衝撃特性が低下するためここを上限とする。
B:この元素も鋼板の焼入れ性を向上させる元素としてよく知られている。本発明でもより焼入れ性を向上のため添加する。このとき焼入れ性の観点から下限を0.0003%に、また、過剰に添加すると鋼板の脆性を劣化させるため、上限を0.03%とする。
【0010】
Ti:Bは焼入れ性に効果が大きいが、鋼中に存在するNとBNを形成しやすい。これを防止してBの効果を十分発揮させるためにTiを添加する必要がある。このときNはTiNを形成する。この目的のため、0.01%以上必要である。また、Tiはアルミめっきの耐熱性への影響が最も大きい。本用途のような900℃を超すような高温域で使用するには、耐熱性という意味から0.1%以上の添加が望ましい。その効果は0.7%程度で飽和するため、ここを上限とする。
【0011】
さらに、本発明ではMo,Cr,Niの1種または2種以上を添加することも可能である。これらの元素はいずれも焼入れ性を向上させる元素である。これらの元素は0.02%以上の添加で焼入れ性を向上せしめる。また、Mo,Niは高価な元素であることから、Crは添加しすぎるとめっき性が低下することからそれぞれ0.5%を上限に定める。
【0012】
次に、めっき層の限定理由を述べる。
Si:Siはアルミ系めっきの合金層(めっき−鋼板界面に生じる金属間化合物の層)厚みを低減するために有効である。また、Mgと複合添加することでMg2 Siを形成し、耐食性向上効果も有する。このためには1%以上の添加が有効である。過剰の添加は融点上昇を伴い、またSi単相がめっき層に晶出すると耐食性を低下させる。このため15%を上限とする。
【0013】
Mg:この元素は特に塩害環境下での耐食性向上に有効であることが知られている。特に、Mg2 Siとすることで環境中への放出効率が高められ、耐食性向上に奏功する。耐食性のために0.5%以上の添加とする。過剰の添加はめっき浴面での激しい酸化を引起こし、まためっき浴の融点も上昇させるため、10%以下とする。Mgの浴面酸化を抑制するにはCaの微量(0.5%以下)の添加が有効で、この程度のCaを添加してもよい。
【0014】
Zn:ZnはAlあるいは鋼よりも卑な電位を有し、地鉄の腐食を抑制する作用を有する。Znの添加量は1%以上で効果を発揮し始め、Zn量が20〜60%で最も良好な特性を示し、60%超の添加量では寧ろ耐食性を害する。従って、Zn量の下限を1%に、上限を60%に定める。
本発明によるAl系めっき鋼板を使用して実際に部品を製造する際には、プレス後金型で急速に冷却して焼入れを行うものであり、その組織としてはマルテンサイトを主体とする組織を呈する。部材として十分な強度を確保するために、マルテンサイト比率が60体積%以上であるものとする。なお、マルテンサイトの存在比率は研磨、エッチング後に光学顕微鏡観察を行い画像解析することで計算するものとする。
【0015】
本発明において、Al系めっきの付着量、めっき前処理,後処理等については特に限定するものではない。付着量は通常の片面30〜80g/m2 の範囲ではなんら問題ない。めっき後処理として一次防錆、潤滑性を目的としてクロメート処理、樹脂被覆処理等がありうるが、有機樹脂は加熱すると消失してしまうため好ましくない。クロメート処理も近年の6価クロム規制を考慮すると、電解クロメート等の3価の処理皮膜が好ましい。めっきへの添加元素として、上記した元素以外にMn,Cr,Ti,Sn,Sb,ミッシュメタル等ありうるが、これらを添加することも可能である。
めっき鋼板の製造法についても何ら限定するものではない。通常の製鋼、熱延条件が適用可能である。Al−Znめっきは通常溶融めっき法で施されるが、これに限定せず、非水溶媒からの電気めっき、蒸着処理等も使用可能である。めっき前処理としてNiプレめっき等もありうるが、これも適用可能である。
【0016】
【実施例】
次に、実施例で本発明をより詳細に説明する。
(実施例1)
通常の熱延、冷延工程を経た、表1に示すような鋼成分の酸洗鋼板(板厚1.8mm)、冷延鋼板(板厚1.2mm)を材料として、溶融Al−Si−Mgめっきを行った。表1の鋼種A,B,Dは冷延鋼板であり、残りは熱延鋼板である。溶融めっきは無酸化炉−還元炉タイプのラインを使用し、めっき後ガスワイピング法でめっき付着量を片面40g/m2 に調節し、その後冷却し、ゼロスパングル処理を施した。この際のめっき浴組成としてはAl−8%Si−6%Mg−1%Fe−0.1%Caとした。浴中のFeは浴中のめっき機器やストリップから供給される不可避のものである。めっき外観はスパングル模様を呈し、不めっき等なく良好であった。このときの製造条件を表2に示す。
【0017】
このようにして製造した溶融めっき鋼板の焼入れ性、耐食性を評価した。評価方法を以下に記す。溶融めっき鋼板に5%の引張り加工を付与し、その後950℃に5分間加熱した後、鋼板間に挟んで冷却した。冷却速度は約30℃/秒であった。冷却後の目視外観より耐熱性を評価した。次に、この鋼板の裸耐食性を湿気槽試験(相対湿度95%、温度40℃)3日で、また塗装後耐食性をクロスカットを施した後、塩水噴霧試験(JIS−Z2134)30日で評価した。このときの塗装はカチオン系電着塗装であり、膜厚は15μmとした。また鋼板のビッカース硬度を荷重100gで測定した。
【0018】
〔耐熱性の評価基準〕
○:良好
△:表面にクラック状の模様発生
×:赤スケール発生
〔裸耐食性の評価基準〕
○:良好
×:赤錆発生
〔塗装後耐食性の評価基準〕
◎:塗装膨れ1mm以内
○:塗装膨れ2mm以内
△:塗装膨れ2〜4mm
×:塗装膨れ4mm超
【0019】
【表1】
【0020】
【表2】
【0021】
No.4のようにCが低すぎると十分な強度が得られない。ビッカース硬度は一般に3倍するとその材料の強度(MPa)に近い値となるが、この場合、800MPaクラスの強度しか得られない。また、No.5のようにMn,B等の焼入れ元素が低いとCが高くても焼入れ効果が得られない。鋼中元素の添加量が適正に制御された、No.1〜3については、Mn−B系,Mo−Cr−Ni系いずれも強度,耐食性の双方とも良好な結果が得られた。
【0022】
(実施例2)
表1のAの鋼を使用して、溶融めっきラインのめっき組成を変化させてめっき組成と特性の関係を調査した。めっき後のめっき層組成と特性の関係を表3にまとめる。なお、ビッカース硬度はいずれも470〜510の間であった。
No.1の全くZnを含有しない系では、裸で短期で赤錆が発生しやすく、また塗装後でも膨れが発生しやすい。一方、Zn量が多すぎるNo.7においても塗装後耐食性に低下が認められる。Zn量を適正にすることで、優れた加工後耐食性が得られる。
【0023】
【表3】
【0024】
【発明の効果】
以上述べたように、本発明は、耐食性、特に加工後の耐食性に優れたホットプレス用Al−Zn系めっき鋼板を提供する。本発明は、今後の自動車軽量化に大きく寄与するものと思われ、産業上の寄与は大きい。
【図面の簡単な説明】
【図1】めっき層のZn量と塗装後のクロスカットからの塗装膨れの関係を示す図である。[0001]
BACKGROUND OF THE INVENTION
The present invention provides a steel material for producing a part requiring high strength such as an underbody of an automobile, and an automobile part using the same.
[0002]
[Prior art]
In recent years, there has been a strong demand for higher strength for steel sheets for automobiles due to the trend toward lower fuel consumption due to global environmental problems. However, in general, the increase in strength is accompanied by a decrease in workability and formability, and a steel sheet having both high strength and high formability is desired.
One answer to this is TRIP (Transformation Induced Concrete) steel using martensitic transformation of retained austenite, and its use is expanding in recent years. However, with this steel, it is possible to produce a 1000 MPa class high strength steel plate with excellent formability, but it is difficult to ensure formability with a super high strength steel such as a higher strength, for example 1500 MPa. .
[0003]
Therefore, hot press is recently attracting attention as another form that achieves both high strength and high formability. This eliminates the problem of formability of a high-strength steel sheet by forming the steel sheet at a high temperature of 800 ° C. or higher, and obtains a desired material by cooling after forming. However, since it involves heating in the atmosphere, an oxide is generated on the surface and needs to be removed in a later step. Japanese Patent Laid-Open No. 2000-38640 has improved this, and is intended to suppress oxidation during heating by aluminizing a steel sheet containing 0.15-0.5% carbon.
[0004]
[Problems to be solved by the invention]
Although the present invention is effective for efficiently producing a high-strength molded part, the aluminum plating layer is prone to cracking, and has a noble potential in comparison with the ground iron in a normal corrosive environment. There is a drawback that corrosion of the metal tends to occur. After severe molding, there arises a problem of corrosion in a short period from the cracked portion or deterioration of corrosion resistance after painting.
[0005]
[Means for Solving the Problems]
In order to overcome the above-mentioned problems, the present inventors have studied in detail the influence factors on the corrosion resistance after processing of the aluminum-plated steel sheet, and as a result, have obtained the following knowledge. By adding Mg and Si in the plating layer, the occurrence of cracks is greatly suppressed, and even if cracks occur, the base corrosion from cracks is unlikely to occur in a short period of time, and the corrosion resistance after coating is greatly improved. Was. By adding Mg and Si in combination, an intermetallic compound layer containing these elements is formed during heating for hot pressing, and its workability is improved over that based on ordinary aluminum plating. It is guessed.
[0006]
In addition, Mg 2 Si is generated in the plating layer, and this releases Mg ions in a corrosive environment to form a coating on the surface of the base metal or the plating layer, thereby suppressing the base corrosion from the crack site. Furthermore, Mg has a boiling point of 1090 ° C. and is partially scattered from the surface in a high temperature range of 900 ° C. or more, resulting in fine irregularities on the surface. As a result, adhesion of the paint is improved, which is advantageous for corrosion resistance after coating. It is estimated that worked. Further, by adding Zn in combination, the sacrificial anticorrosive action of the Zn steel substrate is also exhibited, and further stable corrosion resistance and post-coating corrosion resistance can be obtained. Even in a system in which Mg is not added and Zn—Si is added, good corrosion resistance and post-coating corrosion resistance can be obtained, although not as much as the Mg—Si added system and Mg—Si—Zn added system.
[0007]
DETAILED DESCRIPTION OF THE INVENTION
Next, the reason for limitation of the present invention will be described. First, the reasons for limiting the steel components will be described below.
C: The present invention has a high strength of 1000 MPa or more after molding, and is rapidly cooled after hot pressing to transform into a structure mainly composed of martensite. For this purpose, a C content of 0.1% is required. is there. On the other hand, even if the amount of C is increased to 0.5% or more, the upper limit is set to 0.5% so that the strength is saturated and weld cracks are easily generated.
[0008]
Si: If Si is too low, the fatigue characteristics are deteriorated, so 0.05% or more must be added. Si also has the effect of promoting the reaction between Al and Fe in the plating to improve the heat resistance of the steel sheet. However, Si is also an element that forms a stable oxide film on the surface of the steel sheet during recrystallization annealing and inhibits aluminum plating properties. In this sense, the upper limit of Si is 0.5%.
[0009]
Mn: This element is well known as an element that enhances the hardenability of the steel sheet. It is also an element necessary for preventing hot brittleness due to S unavoidably mixed. For this reason, addition of 0.5% or more is necessary. Mn also improves heat resistance after aluminum plating. However, if Mn is added in excess of 3%, the impact properties after quenching are lowered, so this is the upper limit.
B: This element is also well known as an element for improving the hardenability of the steel sheet. Also in the present invention, it is added for improving hardenability. At this time, from the viewpoint of hardenability, the lower limit is set to 0.0003%, and if added excessively, the brittleness of the steel sheet is deteriorated, so the upper limit is set to 0.03%.
[0010]
Ti: B has a great effect on hardenability, but tends to form N and BN present in steel. In order to prevent this and to fully exhibit the effect of B, it is necessary to add Ti. At this time, N forms TiN. For this purpose, 0.01% or more is necessary. Ti has the greatest influence on the heat resistance of aluminum plating. For use in a high temperature range exceeding 900 ° C. as in this application, addition of 0.1% or more is desirable from the viewpoint of heat resistance. The effect is saturated at about 0.7%, so this is the upper limit.
[0011]
Furthermore, it is also possible to add M o, Cr, one or more of Ni in the present invention. These elements are all elements that improve hardenability. These elements improve hardenability by adding 0.02% or more. Moreover, since Mo and Ni are expensive elements, if too much Cr is added, the plating property is lowered.
[0012]
Next, the reason for limiting the plating layer will be described.
Si: Si is effective for reducing the thickness of an aluminum-based plating alloy layer (a layer of an intermetallic compound generated at the plating-steel plate interface). In addition, Mg 2 Si is formed by composite addition with Mg, and has an effect of improving corrosion resistance. For this purpose, addition of 1% or more is effective. Excess addition is accompanied by an increase in melting point, and when the Si single phase is crystallized in the plating layer, the corrosion resistance is lowered. Therefore, the upper limit is 15%.
[0013]
Mg: This element is known to be effective for improving the corrosion resistance especially in a salt damage environment. In particular, by using Mg 2 Si, the release efficiency into the environment is improved, and the corrosion resistance is improved. Add 0.5% or more for corrosion resistance. Excessive addition causes severe oxidation on the surface of the plating bath and also raises the melting point of the plating bath. Addition of a small amount of Ca (0.5% or less) is effective for suppressing Mg bath surface oxidation, and this amount of Ca may be added.
[0014]
Zn: Zn has a lower potential than Al or steel, and has the effect of suppressing corrosion of the base iron. When the added amount of Zn is 1% or more, the effect starts to be exhibited. When the added amount of Zn is 20 to 60%, the best characteristics are exhibited. When the added amount exceeds 60%, corrosion resistance is adversely affected. Therefore, the lower limit of the Zn content is set to 1% and the upper limit is set to 60%.
When actually producing parts using the Al-based plated steel sheet according to the present invention, quenching is performed by rapidly cooling with a die after pressing, and the structure mainly composed of martensite is used. Present. In order to ensure sufficient strength as a member, the martensite ratio is 60% by volume or more. In addition, the abundance ratio of martensite shall be calculated by observing with an optical microscope after polishing and etching and analyzing the image.
[0015]
In the present invention, the amount of Al-based plating attached, pre-plating treatment, post-treatment and the like are not particularly limited. There is no problem if the adhesion amount is in the range of 30 to 80 g / m 2 on a normal single side. As the post-plating treatment, there may be a chromate treatment, a resin coating treatment, etc. for the purpose of primary rust prevention and lubricity, but the organic resin disappears when heated, which is not preferable. In consideration of the recent hexavalent chromium regulation, the chromate treatment is preferably a trivalent treatment film such as electrolytic chromate. In addition to the elements described above, Mn, Cr, Ti, Sn, Sb, misch metal, and the like can be added as elements added to the plating, but these elements can also be added.
The manufacturing method of the plated steel sheet is not limited at all. Usual steelmaking and hot rolling conditions are applicable. Al—Zn plating is usually performed by a hot dipping method, but is not limited thereto, and electroplating from a non-aqueous solvent, vapor deposition, or the like can also be used. Ni pre-plating may be used as the plating pretreatment, but this is also applicable.
[0016]
【Example】
Next, an Example demonstrates this invention in detail.
Example 1
A normal hot-rolling and cold-rolling process, as shown in Table 1, pickled steel sheets (thickness of 1.8 mm) and cold-rolled steel sheets (thickness of 1.2 mm) are used as materials, and molten Al-Si- Mg plating was performed. Steel types A, B and D in Table 1 are cold-rolled steel sheets, and the rest are hot-rolled steel sheets. Hot dipping is a non-oxidizing furnace - by using a line of reduction furnace type, to adjust the coating weight on one side 40 g / m 2 by plating after gas wiping method, then cooled and subjected to a zero spangle treatment. The plating bath composition at this time was Al-8% Si-6% Mg-1% Fe-0.1% Ca. Fe in the bath is inevitable supplied from plating equipment or strips in the bath. The plating appearance had a spangle pattern and was good with no plating. The production conditions at this time are shown in Table 2.
[0017]
The hardenability and corrosion resistance of the hot-dip plated steel sheet thus manufactured were evaluated. The evaluation method is described below. The hot-dip plated steel sheet was given a 5% tensile process, then heated to 950 ° C. for 5 minutes, and then cooled by being sandwiched between the steel sheets. The cooling rate was about 30 ° C./second. The heat resistance was evaluated from the visual appearance after cooling. Next, the bare corrosion resistance of this steel sheet was evaluated in a humidity tank test (relative humidity 95%,
[0018]
[Evaluation criteria for heat resistance]
○: Good △: Crack-like pattern generated on the surface ×: Red scale generated [Evaluation criteria for bare corrosion resistance]
○: Good ×: Red rust generated [Evaluation criteria for corrosion resistance after painting]
◎: Paint swelling within 1 mm ○: Paint swelling within 2 mm △: Paint swelling 2-4 mm
×: Paint swelling over 4 mm [0019]
[Table 1]
[0020]
[Table 2]
[0021]
No. When C is too low as in 4 , sufficient strength cannot be obtained. In general, when the Vickers hardness is tripled, it becomes a value close to the strength (MPa) of the material, but in this case, only a strength of 800 MPa class can be obtained. No. If the quenching elements such as Mn and B are low as in 5, the quenching effect cannot be obtained even if C is high. The amount of element added in steel was properly controlled. As for 1-3 , good results were obtained in both strength and corrosion resistance in both Mn-B and Mo-Cr-Ni systems.
[0022]
(Example 2)
Using the steel of A in Table 1, the relationship between the plating composition and the characteristics was investigated by changing the plating composition of the hot dipping line. Table 3 summarizes the relationship between the plating layer composition after plating and the characteristics. The Vickers hardness was between 470 and 510.
No. In the system 1 which does not contain Zn at all, red rust is likely to occur in a short period of time, and blistering is likely to occur even after coating. On the other hand, no. 7 also shows a decrease in the corrosion resistance after coating. By making the amount of Zn appropriate, excellent post-processing corrosion resistance can be obtained.
[0023]
[Table 3]
[0024]
【The invention's effect】
As described above, the present invention provides an Al—Zn-based plated steel sheet for hot pressing, which is excellent in corrosion resistance, particularly after processing. The present invention is considered to greatly contribute to future weight reduction of automobiles, and the industrial contribution is great.
[Brief description of the drawings]
FIG. 1 is a diagram showing the relationship between the amount of Zn in a plating layer and coating swelling from a crosscut after coating.
Claims (4)
C :0.1〜0.5%、
Si:0.05〜0.5%、
Mn:0.5〜3%、
B :0.0003〜0.03%、
Ti:0.01〜0.7%
Cr:0.02〜0.5%、
を含有し、残部Feおよび不可避的不純物よりなる鋼の表面に、Si:1〜15%、Mg:0.5〜10%、Ca:0.5%以下(0を含む)を含有し、残部Alおよび不可避的不純物よりなるAl金属被覆を有することを特徴とする、耐熱性、耐食性に優れたホットプレス用アルミ系めっき鋼板。% By mass
C: 0.1 to 0.5%
Si: 0.05 to 0.5%,
Mn: 0.5-3%,
B: 0.0003 to 0.03%,
Ti: 0.01 to 0.7%
Cr: 0.02 to 0.5%,
In the surface of the steel composed of the balance Fe and inevitable impurities, Si: 1 to 15%, Mg: 0.5 to 10% , Ca: 0.5% or less (including 0) , the balance An aluminum-based plated steel sheet for hot press excellent in heat resistance and corrosion resistance, characterized by having an Al metal coating composed of Al and inevitable impurities.
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001190707A JP4023710B2 (en) | 2001-06-25 | 2001-06-25 | Aluminum-plated steel sheet for hot press with excellent corrosion resistance and heat resistance, and automotive parts using the same |
| CNB028120361A CN100370054C (en) | 2001-06-15 | 2002-06-14 | High-strength steel plates coated with aluminum alloy systems and high-strength automotive parts with excellent heat resistance and corrosion resistance after painting |
| TW091113018A TWI317383B (en) | 2001-06-15 | 2002-06-14 | High-strength alloyed aluminum-system plated steel sheet and high-strength automotive part excellent in heat resistance and after-painting corrosion resistance |
| AU2002309283A AU2002309283B2 (en) | 2001-06-15 | 2002-06-14 | High-strength Alloyed Aluminum-system Plated Steel Sheet and High-strength Automotive Part Excellent in Heat Resistance and After-painting Corrosion Resistance |
| KR1020077027723A KR20070119096A (en) | 2001-06-15 | 2002-06-14 | High Strength Aluminum Based Alloy Plated Steel Sheet |
| KR1020037016351A KR100836282B1 (en) | 2001-06-15 | 2002-06-14 | High Strength Aluminum Based Alloy Plated Steel Sheet |
| KR1020087029007A KR20080108163A (en) | 2001-06-15 | 2002-06-14 | Hot press method of high strength aluminum alloy plating steel plate |
| KR1020077017549A KR20070087240A (en) | 2001-06-15 | 2002-06-14 | Hot press method of high strength aluminum alloy plating steel plate |
| PCT/JP2002/005978 WO2002103073A2 (en) | 2001-06-15 | 2002-06-14 | High-strength alloyed aluminum-system plated steel sheet and high-strength automotive part excellent in heat resistance and after-painting corrosion resistance |
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| JP2001190707A JP4023710B2 (en) | 2001-06-25 | 2001-06-25 | Aluminum-plated steel sheet for hot press with excellent corrosion resistance and heat resistance, and automotive parts using the same |
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| JP4495668B2 (en) * | 2004-11-19 | 2010-07-07 | 株式会社神戸製鋼所 | High corrosion resistance steel |
| JP5005254B2 (en) * | 2006-05-15 | 2012-08-22 | 新日本製鐵株式会社 | Al-plated steel for hot pressing with excellent temperature rise characteristics, workability, and post-coating corrosion resistance |
| BR112015026525B1 (en) | 2013-05-07 | 2021-08-31 | Nippon Steel Corporation | GALVANIZED STEEL MATERIAL WITH ALUMINUM-BASED ALLOY THAT HAS EXCELLENT RESISTANCE TO POST-COATING CORROSION |
| KR101585736B1 (en) * | 2013-12-25 | 2016-01-15 | 주식회사 포스코 | Steel sheet for hot press forming having high microcracking resistance and corrosion property and hot press formed article using the same and method for manufacturing the same |
| KR101568549B1 (en) * | 2013-12-25 | 2015-11-11 | 주식회사 포스코 | Steel sheet for hot press formed product having high bendability and ultra high strength, hot press formed product using the same and method for manufacturing the same |
| KR101696121B1 (en) | 2015-12-23 | 2017-01-13 | 주식회사 포스코 | Al-Fe coated steel sheet having good hydrogen delayed fracture resistance property, anti-delamination property and spot weldability, and HPF parts obtained therefrom |
| RU2019142469A (en) | 2017-06-02 | 2021-07-09 | Ниппон Стил Корпорейшн | HOT STAMPED ELEMENT |
| KR102153172B1 (en) | 2018-08-30 | 2020-09-07 | 주식회사 포스코 | Aluminium-Zinc alloy plated steel sheet having excellent hot workabilities and corrosion resistance, and method for the same |
| MX2021006198A (en) | 2018-11-30 | 2021-07-16 | Posco | Steel sheet plated with al-fe for hot press forming having excellent corrosion resistance and spot weldability, and manufacturing method thereof. |
| JP6813133B2 (en) | 2018-11-30 | 2021-01-13 | 日本製鉄株式会社 | Manufacturing method of aluminum-plated steel sheet, hot stamping member and hot stamping member |
| US11491764B2 (en) | 2018-11-30 | 2022-11-08 | Posco | Iron-aluminum-based plated steel sheet for hot press forming, having excellent hydrogen delayed fracture properties and spot welding properties, and manufacturing method therefor |
| MX2021014851A (en) * | 2019-06-03 | 2022-01-18 | Thyssenkrupp Steel Europe Ag | METHOD OF MANUFACTURING A SHEET METAL COMPONENT FROM A FLAT STEEL PRODUCT PROVIDED WITH AN ANTICORROSIVE COATING. |
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| CN118284717A (en) | 2022-01-11 | 2024-07-02 | 杰富意钢铁株式会社 | Steel sheet for hot pressing, method for producing steel sheet for hot pressing, hot pressing component, and method for producing hot pressing component |
| CN118829742A (en) | 2022-03-14 | 2024-10-22 | 杰富意钢铁株式会社 | Hot-pressed component and hot-pressed steel sheet and method for producing the same |
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| EP4667600A4 (en) | 2023-02-16 | 2026-04-08 | Nippon Steel Corp | Hot stamp molded body, and aluminum-plated steel sheet for hot stamping |
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| JP3267325B2 (en) * | 1991-03-29 | 2002-03-18 | 日新製鋼株式会社 | Method for producing high-strength hot-dip aluminized steel sheet for fire resistance |
| JP3962186B2 (en) * | 1998-12-11 | 2007-08-22 | 新日本製鐵株式会社 | Thin steel plate excellent in heat treatment hardening ability and method for producing high-strength press-formed body using the steel plate |
| JP3473480B2 (en) * | 1999-03-18 | 2003-12-02 | 住友金属工業株式会社 | Hot-dip galvanized steel sheet excellent in strength and ductility and method for producing the same |
| JP4469030B2 (en) * | 1999-04-05 | 2010-05-26 | 新日本製鐵株式会社 | Aluminum plated steel plate for automobile fuel tank with excellent corrosion resistance |
| JP2000290764A (en) * | 1999-04-08 | 2000-10-17 | Nippon Steel Corp | Hot-dip aluminized steel sheet with excellent resistance to blackening by heating and its manufacturing method |
| JP4136286B2 (en) * | 1999-08-09 | 2008-08-20 | 新日本製鐵株式会社 | Zn-Al-Mg-Si alloy plated steel with excellent corrosion resistance and method for producing the same |
| JP2001131725A (en) * | 1999-11-08 | 2001-05-15 | Nippon Steel Corp | Hot-dip aluminized steel sheet with excellent heat resistance and corrosion resistance and its manufacturing method |
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