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JP4103239B2 - Transfer sheet - Google Patents
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JP4103239B2 - Transfer sheet - Google Patents

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Publication number
JP4103239B2
JP4103239B2 JP10857299A JP10857299A JP4103239B2 JP 4103239 B2 JP4103239 B2 JP 4103239B2 JP 10857299 A JP10857299 A JP 10857299A JP 10857299 A JP10857299 A JP 10857299A JP 4103239 B2 JP4103239 B2 JP 4103239B2
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JP
Japan
Prior art keywords
layer
release
resin
transfer sheet
sheet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP10857299A
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Japanese (ja)
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JP2000296699A (en
Inventor
裕明 三角
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toppan Inc
Original Assignee
Toppan Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toppan Inc filed Critical Toppan Inc
Priority to JP10857299A priority Critical patent/JP4103239B2/en
Publication of JP2000296699A publication Critical patent/JP2000296699A/en
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Publication of JP4103239B2 publication Critical patent/JP4103239B2/en
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Description

【0001】
【発明の属する技術分野】
本発明は、家具用基材や建築部材などの住宅内装材外装材の表面に絵柄を形成するための転写シートに関する。
【0002】
【従来の技術】
従来、家具用基材や建築部材などの住宅内装材外装材の表面に印刷による絵柄を形成するために、転写シートを用いることがある。
転写シートは、剥離シートに剥離層/絵柄層または剥離層/絵柄層/接着剤層が順次積層された構成になっている。
なかでも熱と圧により転写できる転写シートが良く用いられるが、この方法は、先ず転写シートを製造して、この転写シートを被転写体である基材上に転写シートの絵柄側または接着剤層側を密着させ、熱と圧とで剥離層/絵柄層または剥離層/絵柄層/接着剤層を転写させ、剥離シートを剥ぎとるものである。
【0003】
剥離シートとして、ポリ塩化ビニル、ポリエチレン、ポリプロピレンなどの耐熱性のない樹脂シートの場合には、熱と圧により、樹脂を伸ばすことができるため、被転写体である基材は表面に細かい凹凸の有る基材に転写するのに有効である。
この時、剥離層、絵柄層、接着剤層も伸びる性質の有るものを使用する必要が出てくる。このため、剥離層を形成する樹脂として、ポリビニルブチラール樹脂が良く使用される。
一方、耐熱性の良い剥離紙、ポリエチレンテレフタレートシートを使用する場合は、熱により、紙や樹脂が伸びないために、被転写体である基材は表面の平滑な基材に転写するのに用いられる。
【0004】
転写紙の製造方法は、通常、グラビア多色印刷機を使用して、巻取り状の剥離シートを巻きだし、1色目で剥離層を印刷し、2色以降で絵柄層を印刷し(1〜3色)、必要であれば次に接着剤層を印刷して巻き取る。この間1色ずつ乾燥する。このように同じ印刷機で各層を積層するのにインラインで形成するのが良く行われる。
【0005】
しかしながら、剥離層を形成する樹脂としてポリビニルブチラール樹脂を使用し、グラビア多色印刷機でインラインで転写紙を製造するにおいて、剥離層上に絵柄層をグラビアインキで印刷して形成させる時、1色目のグラビアインキと剥離層とのなじみが悪く、剥離層にグラビアインキがうまく転移せず、版のほうにインキが残る、また2色目の印刷インキを印刷する時に1色目で印刷された印刷インキが版の方に転移して2色目の印刷インキが転移せず、絵柄に欠けができて、いわゆる「インキ取られ」現象が見られ、目的とする絵柄層が得られないと言う問題点が起こる。
【0006】
【発明が解決しようとする課題】
本発明は以上のような問題点を解決するためになされたものであり、剥離層を形成する樹脂、特にポリビニルブチラール樹脂を用いて、「インキ取られ」現象のない、目的とする絵柄層を有する転写シートを提供するものである。
【0007】
【発明を解決するための手段】
本発明において上記課題を達成するために、まず請求項1においては、
剥離シート上に剥離層/絵柄層/接着剤層を順次積層された転写シートであって、
前記剥離層はポリビニルブチラール樹脂中に少なくとも硫酸バリウムを10〜23重量%混合されたものからなり、かつ、該絵柄層はポリビニルブチラール樹脂を主体とする印刷インキよりなることを特徴とする転写シートとしたものである。
【0009】
剥離層は、樹脂中に特にポリビニルブチラール樹脂中に体質顔料を10〜30重量部混合されたものからなり、かくすることにより、層の表面に体質顔料が頭を出すものが有り、樹脂と体質顔料との境界ができ、この境界に印刷インキが沁みる込んで印刷インキの食いつきが良くなり、インキ取られが無くなるものと思われる。
【0010】
【発明の実施の形態】
以下本発明の実施の形態につき説明する。
剥離シートは、ポリ塩化ビニル、ポリエチレン、ポリプロピレン、ポリエチレンテレフタレートなどの合成樹脂フィルムや、紙、金属箔などの従来公知の材質を使用することができる。
耐熱性の良い剥離紙、ポリエチレンテレフタレートシートを使用する場合は、熱により紙や樹脂が伸びないために、被転写体である基材は表面の平滑な基材に転写するのに用いられる。
一方、ポリ塩化ビニル、ポリエチレン、ポリプロピレンなどの耐熱性のない樹脂シートの場合には、熱と圧により、樹脂を伸ばすことができるため、被転写体である基材は表面に細かい凹凸の有る基材に転写するのに用いられる。この時、剥離層、絵柄層、接着剤層も伸びる性質の有るものを使用する必要が出てくる。
【0011】
剥離層は、熱と圧により皮膜が伸びる性質を有するものが用いる時は、熱可塑性樹脂なかでもポリビニルブチラール樹脂が良い。
また、樹脂中には体質顔料を混ぜると良い。体質顔料は屈折率の小さい透明性顔料であり、印刷インキの性質を変える、あるいは増量剤として用いられ、無機質系のアルミナ白、炭酸カルシウム、炭酸マグネシウム、硫酸バリウムなどが用いられる。
その混合量は、樹脂100重量部に対して10〜30重量部が良い。
10重量部を下廻るとインキ取られに対して効果がなく、30重量部を上廻るとインキとして流動性が悪くなったり、皮膜が不透明になってくる。
その他、界面活性剤などを混ぜても良い。
【0012】
絵柄層はグラビア用の印刷インキで1色以上刷り重ねることにより形成される。
印刷インキは樹脂中に着色顔料を混ぜたものであり、その他界面活性剤が加えられている。
剥離層にポリビニルブチラール樹脂が用いられた時は、印刷インキの樹脂もポリビニルブチラール樹脂を用いると良い。剥離層とのなじみが良いことと、熱と圧により接着性が出てくるからである。
【0013】
必要により、更に接着剤層を絵柄層上に設けても良い。
【0014】
剥離シート上に設けられた各層は、通常、グラビア多色印刷機にて、インライン印刷して設けられる。
各層を別々に設けても良い。すなわち、剥離層を印刷機で印刷するまたはコーターで塗布して巻き取る。次にグラビア印刷機で絵柄層を印刷する。必要なら次に接着剤層を印刷機で印刷するまたはコーターで塗布して巻き取る。
【0018】
【発明の効果】
本発明は以上の構成であるから、インキ取られ現象のない目的とする絵柄を有する転写シートとすることができた。
従って 本発明は、家具用基材や建築部材などの住宅内装材外装材の表面に絵柄を形成するための転写シートとして、優れた実用上の効果を発揮する。
【図面の簡単な説明】
【図1】本発明の参考例1、2を示す転写シートの断面図である。
【符号の説明】
1…転写シート
2…剥離シート
3…剥離層
4…絵柄層
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a transfer sheet for forming a pattern on the surface of a housing interior material exterior material such as a furniture base material or a building member.
[0002]
[Prior art]
Conventionally, a transfer sheet is sometimes used to form a printed pattern on the surface of a housing interior material exterior material such as a furniture base material or a building member.
The transfer sheet has a structure in which a release layer / picture layer or a release layer / picture layer / adhesive layer is sequentially laminated on a release sheet.
Of these, a transfer sheet that can be transferred by heat and pressure is often used. In this method, first, a transfer sheet is manufactured, and the transfer sheet is formed on a substrate, which is a transfer target, on the pattern side or adhesive layer The release layer / pattern layer or release layer / pattern layer / adhesive layer is transferred with heat and pressure, and the release sheet is peeled off.
[0003]
In the case of a resin sheet having no heat resistance such as polyvinyl chloride, polyethylene, and polypropylene as the release sheet, the resin can be stretched by heat and pressure. It is effective for transferring to a certain substrate.
At this time, it is necessary to use a layer having a property of extending the peeling layer, the pattern layer, and the adhesive layer. For this reason, polyvinyl butyral resin is often used as the resin for forming the release layer.
On the other hand, when using release paper with good heat resistance and polyethylene terephthalate sheet, since the paper and resin do not stretch due to heat, the substrate to be transferred is used to transfer to a substrate with a smooth surface. It is done.
[0004]
The transfer paper manufacturing method usually uses a gravure multicolor printing machine to unwind a rolled release sheet, print a release layer with the first color, and print a pattern layer with two or more colors (1 to 1). (3 colors), if necessary, the adhesive layer is then printed and wound. During this time, each color is dried. In this way, the layers are often formed in-line for laminating the layers on the same printing press.
[0005]
However, when polyvinyl butyral resin is used as the resin for forming the release layer and a transfer paper is produced in-line with a gravure multicolor printer, when the pattern layer is formed by printing with a gravure ink on the release layer, the first color The gravure ink is not compatible with the release layer, the gravure ink does not transfer well to the release layer, the ink remains on the plate, and the printing ink printed in the first color when printing the second printing ink is The printing ink of the second color is not transferred to the plate, the pattern is chipped, the so-called “ink removal” phenomenon is observed, and the target pattern layer cannot be obtained. .
[0006]
[Problems to be solved by the invention]
The present invention has been made in order to solve the above-described problems. A resin layer forming a release layer, in particular, a polyvinyl butyral resin, is used to produce a desired pattern layer having no “ink removal” phenomenon. The transfer sheet is provided.
[0007]
[Means for Solving the Invention]
In order to achieve the above object in the present invention, first, in claim 1,
A transfer sheet in which a release layer / picture layer / adhesive layer are sequentially laminated on a release sheet,
The release layer is composed of a polyvinyl butyral resin mixed with at least 10 to 23 % by weight of barium sulfate, and the pattern layer is made of a printing ink mainly composed of polyvinyl butyral resin; It is a thing.
[0009]
The release layer is composed of a resin in which 10 to 30 parts by weight of an extender pigment is mixed in a polyvinyl butyral resin, and in this way, an extender pigment is projected on the surface of the layer. It seems that there is a boundary with the pigment, the printing ink squeezes into this boundary, the biting of the printing ink is improved, and the ink is not removed.
[0010]
DETAILED DESCRIPTION OF THE INVENTION
Hereinafter, embodiments of the present invention will be described.
As the release sheet, a conventionally known material such as a synthetic resin film such as polyvinyl chloride, polyethylene, polypropylene, or polyethylene terephthalate, paper, or metal foil can be used.
When using release paper or polyethylene terephthalate sheet with good heat resistance, since the paper or resin does not stretch due to heat, the substrate to be transferred is used to transfer to a substrate having a smooth surface.
On the other hand, in the case of a resin sheet having no heat resistance such as polyvinyl chloride, polyethylene, and polypropylene, since the resin can be stretched by heat and pressure, the substrate to be transferred is a substrate having fine irregularities on the surface. Used to transfer to material. At this time, it is necessary to use a layer having a property of extending the peeling layer, the pattern layer, and the adhesive layer.
[0011]
When the release layer has a property that the film is extended by heat and pressure, polyvinyl butyral resin is preferable among thermoplastic resins.
In addition, extender pigments may be mixed in the resin. The extender pigment is a transparent pigment having a low refractive index, and is used as a filler for changing the properties of the printing ink or as an extender, and inorganic alumina white, calcium carbonate, magnesium carbonate, barium sulfate and the like are used.
The mixing amount is preferably 10 to 30 parts by weight with respect to 100 parts by weight of the resin.
When the amount is less than 10 parts by weight, there is no effect on ink removal, and when the amount exceeds 30 parts by weight, the fluidity of the ink is deteriorated or the film becomes opaque.
In addition, a surfactant or the like may be mixed.
[0012]
The pattern layer is formed by printing one or more colors with gravure printing ink.
Printing ink is a mixture of colored pigments in a resin, and other surfactants are added.
When a polyvinyl butyral resin is used for the release layer, a polyvinyl butyral resin may be used as the printing ink resin. This is because it is well-familiar with the release layer and the adhesiveness comes out by heat and pressure.
[0013]
If necessary, an adhesive layer may be further provided on the pattern layer.
[0014]
Each layer provided on the release sheet is usually provided by inline printing with a gravure multicolor printer.
Each layer may be provided separately. That is, the release layer is printed by a printing press or applied and wound by a coater. Next, the pattern layer is printed with a gravure printing machine. If necessary, the adhesive layer is then printed on a printing press or applied with a coater and wound up.
[0018]
【The invention's effect】
Since the present invention has the above-described configuration, it was possible to obtain a transfer sheet having a desired pattern without ink removal.
Therefore, the present invention exhibits an excellent practical effect as a transfer sheet for forming a pattern on the surface of a housing interior material exterior material such as a furniture base material or a building member.
[Brief description of the drawings]
FIG. 1 is a cross-sectional view of a transfer sheet showing Reference Examples 1 and 2 of the present invention.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1 ... Transfer sheet 2 ... Release sheet 3 ... Release layer 4 ... Picture layer

Claims (1)

剥離シート上に剥離層/絵柄層/接着剤層を順次積層された転写シートであって、
前記剥離層はポリビニルブチラール樹脂中に少なくとも硫酸バリウムを10〜23重量%混合されたものからなり、かつ、該絵柄層はポリビニルブチラール樹脂を主体とする印刷インキよりなることを特徴とする転写シート。
A transfer sheet in which a release layer / picture layer / adhesive layer are sequentially laminated on a release sheet,
The transfer sheet is characterized in that the release layer is made of a polyvinyl butyral resin mixed with at least 10 to 23 % by weight of barium sulfate, and the pattern layer is made of a printing ink mainly composed of polyvinyl butyral resin.
JP10857299A 1999-04-15 1999-04-15 Transfer sheet Expired - Fee Related JP4103239B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10857299A JP4103239B2 (en) 1999-04-15 1999-04-15 Transfer sheet

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10857299A JP4103239B2 (en) 1999-04-15 1999-04-15 Transfer sheet

Publications (2)

Publication Number Publication Date
JP2000296699A JP2000296699A (en) 2000-10-24
JP4103239B2 true JP4103239B2 (en) 2008-06-18

Family

ID=14488224

Family Applications (1)

Application Number Title Priority Date Filing Date
JP10857299A Expired - Fee Related JP4103239B2 (en) 1999-04-15 1999-04-15 Transfer sheet

Country Status (1)

Country Link
JP (1) JP4103239B2 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100402291B1 (en) * 2000-12-14 2003-10-22 (주)현대특수나염 Oily transfer ink, and oily transfer ink for producing oily gravure transfer paper and oily gravure transfer paper produced using the same
KR100444128B1 (en) * 2002-01-28 2004-08-09 (주)현대특수나염 Oily transfer ink, and oily transfer ink for producing oily gravure transfer PET paper and oily gravure transfer PET paper produced using the same
JP2006347890A (en) * 2005-06-13 2006-12-28 Tayca Corp Cosmetics
CN110936762A (en) * 2019-10-18 2020-03-31 卓比(东莞)精密科技有限公司 Novel gold stamping processing method

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0745279B2 (en) * 1988-10-19 1995-05-17 大日本印刷株式会社 Transfer foil
JPH0780693B2 (en) * 1990-02-14 1995-08-30 大日本印刷株式会社 Transfer foil for glass and glass painting method
JPH09142094A (en) * 1995-11-17 1997-06-03 Sintokogio Ltd Transfer material with antibacterial, antifungal, stain decomposition, and antistatic functions
JPH105372A (en) * 1996-06-26 1998-01-13 Sumitomo Rubber Ind Ltd Transfer foil for golf balls
JPH1170796A (en) * 1997-08-29 1999-03-16 Dainippon Printing Co Ltd Transfer sheet and method of manufacturing decorative board using the same

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