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JP4131886B2 - Ceramic - Google Patents
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JP4131886B2 - Ceramic - Google Patents

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Publication number
JP4131886B2
JP4131886B2 JP12181298A JP12181298A JP4131886B2 JP 4131886 B2 JP4131886 B2 JP 4131886B2 JP 12181298 A JP12181298 A JP 12181298A JP 12181298 A JP12181298 A JP 12181298A JP 4131886 B2 JP4131886 B2 JP 4131886B2
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JP
Japan
Prior art keywords
outer cylinder
pores
clay
mandrel
ceramic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP12181298A
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Japanese (ja)
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JPH11292652A (en
Inventor
善輝 松原
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
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Individual
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Filing date
Publication date
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Priority to JP12181298A priority Critical patent/JP4131886B2/en
Publication of JPH11292652A publication Critical patent/JPH11292652A/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Porous Artificial Stone Or Porous Ceramic Products (AREA)

Description

【0001】
【発明の属する技術分野】
【0002】
本発明は、人口骨などに利用できる多孔質陶磁器に関する。
【0003】
【従来の技術】
多孔質の陶磁器は、軽量である特長を有しており、次のようにして製造される。すなわち、粘土に数10μmの粒子からなる樹脂フィラーを混入して焼成すると、樹脂フィラーが燃えてなくなり、樹脂フィラーの部分に気孔が形成されるので、内部に数10μmの気孔が分散した多孔質の陶磁器を製造できる。
【0004】
【発明が解決しようとする課題】
しかしながら、上記多孔質の陶磁器は、内部に気孔が多数、分散して存在するため、軽量である反面、強度が劣る欠点があり、一部の用途に使用されているに過ぎない。
【0005】
本発明は以上に事情に鑑みてなされたものであって、強度を改善し、人口骨等に使用できるようにした多孔質の陶磁器を提供することにある。
【0006】
【課題を解決するための手段】
本発明は、心棒部分とその周りの外筒部分とで構成された棒状陶磁器であって、炭素繊維と気孔が前記心棒部分と外筒部分に分散しており、心棒部分は外筒部分に比べて炭素繊維の含有比率が高く、気孔の分散比率が低くなっており、外筒部分は心棒部分に比べて炭素繊維の含有比率が低く、気孔の分散比率が高くなっており、外周部に気孔が露出していることを特徴とする。
【0007】
【発明の実施の形態】
以下、本発明の一実施形態を説明する。
【0008】
は人口骨等に利用できる陶磁器を示している。この棒状陶磁器20は、数10μmの細かい気孔2が分散している多孔質の陶磁器であり、軽量である利点を有している。そして、この棒状陶磁器20は、炭素繊維3および気孔2の含有比率が相違する2つの部分、すなわち心棒部分21とその周りの外筒部分22とで構成されている。炭素繊維3および気孔2は心棒部分21および外筒部分22でそれぞれ均一に分散しているが、心棒部分21は、外筒部分22に比べて、炭素繊維3の含有比率が高く、気孔2の分散比率が低くなっており、外筒部分22は、心棒部分21に比べて、炭素繊維3の含有比率が低く、気孔2の分散比率が高くなっており、軽くて実用的にも充分な強度を備えている。
【0009】
人口骨は現在、セラミックや鉄、その他の材料で形成されている。しかしながら、いずれも骨と肉の組織が結合せず、骨の表面に肉が付着している状態である。しかしながら、上記で示した軽量で充分な強度を有している棒状陶磁器20を人口骨に利用すれば、外周部に多数の気孔2が分散して露出しているため、この気孔2部分に肉質が成長して入り込み、骨と筋肉とが一体結合する利点を有している。
【0010】
上記棒状陶磁器20の製造方法の一例を説明する。
【0011】
樹脂フィラーおよび炭素繊維の含有比率が相違する粘土を2種類用意する。一つは、樹脂フィラーの含有比率が低く、炭素繊維の含有比率が高い粘土であり、もう一つは、樹脂フィラーの含有比率が高く、炭素繊維の含有比率が低い粘土である。成形工程で、炭素繊維の含有比率が低い粘土を板状に成形し、炭素繊維の含有比率が高い粘土を円柱状に成形し、前記板状粘土23の上に円柱状粘土24を載せ、円柱状粘土24の周囲に板状粘土23を巻き付けて棒状成形品を作製する。
【0012】
製造は次の工程からなる。すなわち、粘土に樹脂フィラーと炭素繊維を混ぜて混練する工程と、混練後の粘土を成形する工程と、成形後、乾燥する工程と、乾燥後、素焼きする工程と、素焼き後、焼成する工程とからなる。
【0013】
上記乾燥工程、素焼き工程、および焼成工程は、通常の陶磁器の場合と同じ、温度、時間で行えばよい。例えば、乾燥工程は自然乾燥または強制乾燥で行えばよく、素焼き工程は550〜800℃で6〜8時間行えばよく、焼成工程は1150〜1300℃で13〜18時間行えばよい。
【0014】
上記工程で樹脂フィラーは燃えてなくなり、樹脂フィラーの部分に気孔が形成される。
【0015】
樹脂フィラーとしては、例えば中空樹脂フィラーが使用される。中空樹脂フィラーは、数10μmの樹脂の粒子の中に気体が含まれているもので、発泡インクや発泡途料の充填材に使用されている。
【0016】
中空樹脂フィラーの一例を下記に示す。
品名:マツモトマイクロスフェアー F−30
内容:塩化ビニリデン共重合物を殻壁として、低沸点、炭化水素を内包す
る熱膨張性マイクロカプセル
粒子径が10〜20μm
製造会社:松本油脂製薬株式会社
【0017】
【発明の効果】
以上説明したように本発明の多孔質陶磁器によれば、強度が優れた軽量陶磁器を提供でき、人口骨等に有効に利用できる
【図面の簡単な説明】
【図1】 本発明の一実施形態を示しており、(a)は棒状陶磁器の斜視図、(b)は棒状陶磁器の心棒部分の斜視図、(c)は板状粘土の上に円柱状粘土を載せた状態を示す側面図、(d)は同平面図である。
【符号の説明】
2 気孔
3 炭素繊維
20 棒状陶磁器
21 心棒部分
22 外筒部分
23 板状粘土
24 円柱状粘土
[0001]
BACKGROUND OF THE INVENTION
[0002]
The present invention relates to porous ceramics that can be used for artificial bones and the like.
[0003]
[Prior art]
Porous ceramics have the feature of being lightweight and are manufactured as follows. That is, when a resin filler composed of particles of several tens of μm is mixed with clay and baked, the resin filler does not burn, and pores are formed in the resin filler, so that a porous of several tens of μm pores dispersed therein is formed. Can produce ceramics.
[0004]
[Problems to be solved by the invention]
However, since the porous ceramics have a large number of pores dispersed therein, they are light in weight, but have the disadvantage of poor strength, and are only used for some applications.
[0005]
The present invention has been made in view of the above circumstances, and it is an object of the present invention to provide a porous ceramic that has improved strength and can be used for artificial bones and the like .
[0006]
[Means for Solving the Problems]
The present invention is a rod-shaped ceramic composed of a mandrel part and an outer cylinder part around the mandrel part, wherein carbon fibers and pores are dispersed in the mandrel part and the outer cylinder part, and the mandrel part is compared with the outer cylinder part. The carbon fiber content ratio is high and the pore dispersion ratio is low, and the outer cylinder part has a lower carbon fiber content ratio than the mandrel part, and the pore dispersion ratio is high. Is exposed .
[0007]
DETAILED DESCRIPTION OF THE INVENTION
Hereinafter, an embodiment of the present invention will be described.
[0008]
FIG. 1 shows a ceramic that can be used for artificial bones and the like. This rod-shaped ceramic 20 is a porous ceramic in which fine pores 2 of several tens of μm are dispersed, and has an advantage of being lightweight. And this rod-shaped ceramic 20 is comprised by the two parts from which the content ratio of the carbon fiber 3 and the pore 2 differs, ie, the mandrel part 21, and the outer cylinder part 22 around it. The carbon fibers 3 and the pores 2 are uniformly dispersed in the mandrel portion 21 and the outer cylinder portion 22, respectively. The outer cylinder portion 22 has a lower content ratio of the carbon fiber 3 and a higher dispersion ratio of the pores 2 than the mandrel portion 21, and is light and practically strong enough. It has.
[0009]
Artificial bone is now made of ceramic, iron, and other materials. However, in both cases, the bone and meat tissue are not bonded, and the meat is attached to the surface of the bone. However, if the rod-shaped ceramic 20 having the light weight and sufficient strength shown above is used for artificial bone, a large number of pores 2 are dispersed and exposed on the outer peripheral portion, and therefore, the fleshy 2 portions are fleshy. Has the advantage that the bones and muscles join together.
[0010]
An example of the manufacturing method of the said rod-shaped ceramic 20 is demonstrated.
[0011]
Two types of clay having different resin filler and carbon fiber content ratios are prepared. One is a clay with a low resin filler content ratio and a high carbon fiber content ratio, and the other is a clay with a high resin filler content ratio and a low carbon fiber content ratio. In the molding step, a clay having a low carbon fiber content ratio is formed into a plate shape, a clay having a high carbon fiber content ratio is formed into a cylindrical shape, and the cylindrical clay 24 is placed on the plate clay 23 to obtain a circular shape. A plate-shaped clay 23 is wound around the columnar clay 24 to produce a rod-shaped molded product.
[0012]
Manufacturing consists of the following steps. That is, a step of kneading by mixing clay resin filler and carbon fibers, a step of forming the clay kneaded, after molding and drying, after drying, a step of biscuit, after bisque, the step of tempering formed It consists of.
[0013]
The drying step, unglazed step, and firing step may be performed at the same temperature and time as in the case of ordinary ceramics. For example, the drying process may be performed by natural drying or forced drying, the unglazed process may be performed at 550 to 800 ° C. for 6 to 8 hours, and the firing process may be performed at 1150 to 1300 ° C. for 13 to 18 hours.
[0014]
The resin filler does not burn in the above process, and pores are formed in the resin filler portion.
[0015]
As the resin filler, for example, a hollow resin filler is used. The hollow resin filler contains a gas in resin particles of several tens of μm and is used as a filler for foamed ink and foaming material.
[0016]
An example of the hollow resin filler is shown below.
Product name: Matsumoto Microsphere F-30
Contents: Low-boiling point, hydrocarbons included with vinylidene chloride copolymer as shell wall
Thermally expandable microcapsules
Particle size is 10-20μm
Manufacturing company: Matsumoto Yushi Pharmaceutical Co., Ltd. [0017]
【The invention's effect】
As described above, according to the porous ceramic of the present invention, a lightweight ceramic having excellent strength can be provided and can be effectively used for artificial bones and the like .
[Brief description of the drawings]
FIG. 1 shows an embodiment of the present invention, in which (a) is a perspective view of a rod-shaped ceramic, (b) is a perspective view of a mandrel portion of the rod-shaped ceramic, and (c) is a cylindrical shape on a plate-like clay. The side view which shows the state which mounted the clay, (d) is the same top view.
[Explanation of symbols]
2 Pore 3 Carbon fiber 20 Rod ceramic 21 Mandrel part 22 Outer cylinder part 23 Plated clay 24 Columnar clay

Claims (2)

心棒部分とその周りの外筒部分とで構成された棒状陶磁器であって、炭素繊維と気孔が前記心棒部分と外筒部分に分散しており、心棒部分は外筒部分に比べて炭素繊維の含有比率が高く、気孔の分散比率が低くなっており、外筒部分は心棒部分に比べて炭素繊維の含有比率が低く、気孔の分散比率が高くなっており、外周部に気孔が露出していることを特徴とする陶磁器。  It is a rod-shaped ceramic composed of a mandrel part and an outer cylinder part around the mandrel part, and carbon fibers and pores are dispersed in the mandrel part and the outer cylinder part. The content ratio is high, the pore dispersion ratio is low, the outer cylinder part is lower in carbon fiber content than the mandrel part, the pore dispersion ratio is high, and the pores are exposed at the outer periphery. Ceramics characterized by being. 前記炭素繊維および気孔は、心棒部分、外筒部分のそれぞれの部分において均一に分散していることを特徴とする請求項1記載の陶磁器。 2. The ceramic according to claim 1, wherein the carbon fibers and the pores are uniformly dispersed in each of the mandrel part and the outer cylinder part .
JP12181298A 1998-04-15 1998-04-15 Ceramic Expired - Fee Related JP4131886B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP12181298A JP4131886B2 (en) 1998-04-15 1998-04-15 Ceramic

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP12181298A JP4131886B2 (en) 1998-04-15 1998-04-15 Ceramic

Publications (2)

Publication Number Publication Date
JPH11292652A JPH11292652A (en) 1999-10-26
JP4131886B2 true JP4131886B2 (en) 2008-08-13

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ID=14820549

Family Applications (1)

Application Number Title Priority Date Filing Date
JP12181298A Expired - Fee Related JP4131886B2 (en) 1998-04-15 1998-04-15 Ceramic

Country Status (1)

Country Link
JP (1) JP4131886B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0679087U (en) * 1993-04-16 1994-11-04 株式会社大洋工芸 Rail outlet

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4539871B2 (en) * 2006-04-25 2010-09-08 シャープ株式会社 Porous honeycomb structure having conductivity and method for manufacturing the same
JP2008105901A (en) * 2006-10-25 2008-05-08 Shinei Sangyo Kk Insulating material and method for producing the insulating material
JP2013220960A (en) * 2012-04-13 2013-10-28 Komatsu Seiren Co Ltd Porous ceramic sintered compact
JP2018052092A (en) * 2016-09-30 2018-04-05 めぐみ 稲田 Manufacturing method of three dimensional porcelain

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0679087U (en) * 1993-04-16 1994-11-04 株式会社大洋工芸 Rail outlet

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Publication number Publication date
JPH11292652A (en) 1999-10-26

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