JP4159305B2 - Method for forming anisotropic phase separation structure, film using anisotropic phase separation structure formed by the formation method, and display device to which the film is attached - Google Patents

Description

[0001]
BACKGROUND OF THE INVENTION
The present invention relates to an anisotropic phase separation structure usable as an anisotropic conductive material and an anisotropic optical material, a film using the anisotropic phase separation structure, and a display device on which the film is attached. About.
[0002]
[Prior art]
Conventionally, many anisotropic conductive materials and anisotropic optical materials used in display devices such as liquid crystal displays form an anisotropic structure by patterning by exposure or transfer, or by stretching. Was normal.
[0003]
However, according to such a method for forming an anisotropic structure, there is a problem that the processing size of the material is limited by the pattern forming means, or post-processing such as stretching or multilayer lamination cannot be performed depending on the physical properties of the material. there were.
[0004]
In addition, when forming an anisotropic structure by patterning by transfer or the like, since the regularity of the formed structure is high, the optical device having a regular structure such as a black matrix of a liquid crystal display or a shadow mask of a CRT is used. In some cases, interference fringes and moire fringes occurred. Furthermore, in addition to patterning by transfer or the like, shape imparting by etching or printing has periodicity, so when used for a display device having regularly arranged pixels, such as a liquid crystal display or a plasma display, There was a problem that interference fringes and moire fringes were likely to occur.
[0005]
In addition, interference fringes may occur even with regular structures that are usually difficult to visually recognize, such as an array pattern of ITO conductive films used in touch panels.
[0006]
[Problems to be solved by the invention]
The present invention has been made to solve such problems of the prior art, and has irregularity and non-periodicity to such an extent that interference fringes and moire fringes do not occur with the optical device constituting the display device. It is an object of the present invention to provide an anisotropic thin film element having the following.
[0007]
[Means for Solving the Problems]
In order to solve the above-mentioned problems, the inventors of the present invention have conducted intensive research. It was found that the pattern developed. Furthermore, by appropriately selecting the material system (nanoparticles and binder composition) to be phase-separated and manufacturing conditions, the refractive index, wettability, etching characteristics, conductivity, adhesion to other substrates, reflection characteristics, etc. It has been found that a phase separation structure that causes anisotropy can be formed. That is, it has been found that a thin film element having anisotropy in optical characteristics, mechanical characteristics, surface properties, conductivity, and the like can be provided by the phase separation structure. The present invention has been completed based on the discovery of the inventors.
[0008]
That is, the present invention comprises, as described in claim 1, a base material, and a coating part formed by thin-film coating nanoparticles with the binder composition on the base material,
In the method for forming an anisotropic phase separation structure in which the other structure formed in a stripe shape on the surface of the coating portion is formed using anisotropy due to the phase separation structure of the coating portion,
The coating part is a phase separation structure in which a region containing the nanoparticles and a region not containing the nanoparticles are formed in stripes, and has anisotropy by the phase separation structure ,
And using a resin as the previous SL other structures, the coated portion surface of the phase-separated structure having the phase separation structure, applying a weak resin adherence force to highly hydrophilic region (hydrophilic region) In addition, after applying a resin with strong adhesion to a highly hydrophobic area (hydrophobic area) and drying it, the adhesive tape is attached to the surface of the applied resin and peeled off. While the resin applied to the film is peeled off together with the adhesive tape, the resin applied on the hydrophobic region remains to provide a method of forming the resin in a stripe shape.
Further, as described in claim 2, comprising a base material, and a coating part formed by thin-film coating nanoparticles with the binder composition on the base material,
In the method for forming an anisotropic phase separation structure in which the other structure formed in a stripe shape on the surface of the coating portion is formed using anisotropy due to the phase separation structure of the coating portion,
The coating part is a phase separation structure in which a region containing the nanoparticles and a region not containing the nanoparticles are formed in stripes, and has anisotropy by the phase separation structure,
The refractive index difference between the nanoparticles and the binder composition is greater than 0.005, and the phase separation structure has a highly hydrophilic region (hydrophilic region) and a highly hydrophobic region (hydrophobic region). and is formed in stripes, the water-based paints as other structures is applied to the coated portion surface by a drying treatment, a water-based paint may be a method of forming the stripes.
Further, as described in claim 3, comprising a base material, and a coating part formed by thin-film coating nanoparticles with the binder composition on the base material,
In the method for forming an anisotropic phase separation structure in which the other structure formed in a stripe shape on the surface of the coating portion is formed using anisotropy due to the phase separation structure of the coating portion,
The coating part is a phase separation structure in which a region containing the nanoparticles and a region not containing the nanoparticles are formed in stripes, and has anisotropy by the phase separation structure,
After the refractive index difference between the nanoparticles and the binder composition is greater than 0.005 and the metal film as the other structure is formed in a striped pattern on the coated part surface, the metal remaining on the coated part surface A method may be used in which a metal film is sequentially laminated on the film to form a stripe-shaped metal plate .
Further, as described in claim 4, comprising a base material, and a coating part formed by thin-film coating nanoparticles with the binder composition on the base material,
In the method for forming an anisotropic phase separation structure in which the other structure formed in a stripe shape on the surface of the coating portion is formed using anisotropy due to the phase separation structure of the coating portion,
The coating part is a phase separation structure in which a region containing the nanoparticles and a region not containing the nanoparticles are formed in stripes, and has anisotropy by the phase separation structure,
Nanoparticles refractive index difference between the nanoparticle and the binder composition to form a large and the phase separation structure than 0.005, a low particle UV transmittance, ultraviolet curing said coated portion surface the resin was applied was irradiated with ultraviolet rays from the opposite side of the coated portion formation side of the substrate, by washing away the uncured resin, to form an ultraviolet curing resin as other structures in stripes different It may be a method of forming an isotropic phase separation structure.
Further, as described in claim 5, comprising a base material, and a coating portion formed by thin-film coating nanoparticles with the binder composition on the base material,
In the method for forming an anisotropic phase separation structure in which the other structure formed in a stripe shape on the surface of the coating portion is formed using anisotropy due to the phase separation structure of the coating portion,
The coating part is a phase separation structure in which a region containing the nanoparticles and a region not containing the nanoparticles are formed in stripes, and has anisotropy by the phase separation structure,
The refractive index difference between the nanoparticles and the binder composition is greater than 0.005,
While using resin as the other structure and applying a resin having low adhesion to a highly hydrophilic region (hydrophilic region) on the surface of the coated portion of the phase separation structure having the phase separation structure After applying a resin with strong adhesion to a highly hydrophobic area (hydrophobic area) and drying it, the adhesive tape is applied to the applied resin surface and peeled off, so that the hydrophilic area is covered. While the applied resin is peeled off together with the adhesive tape, the resin applied on the hydrophobic region remains and the resin is formed in a stripe shape to form an anisotropic phase separation structure.
[0009]
According to the invention which concerns on Claims 1-5 , the coating part formed by thin-film-coating a nanoparticle with a binder composition on a base material does not contain the area | region containing a nanoparticle, and the said nanoparticle. The region is a phase separation structure formed in a stripe shape, and has anisotropy due to the phase separation structure. Therefore, for example, by making the refractive index of the binder composition different from that of the nanoparticles, an anisotropic optical element that can perform the same function as an optical element such as a diffraction grating, a micro lenticular lens, and an anisotropic light scatterer can be easily obtained. In addition, it can be obtained at a low price. Moreover, the area | region where the content rate of a nanoparticle is large can control the surface uneven | corrugated shape according to a nanoparticle content rate, if there is little volume reduction after superposition | polymerization of a binder composition. Thus, the refraction, diffraction and scattering due to the refractive index difference and the refraction, diffraction and scattering due to the surface irregularity shape, the refractive index difference between the binder composition and the nanoparticles, the nanoparticle content, the shrinkage rate of the binder composition It is possible to design freely by setting these appropriately. Furthermore, according to the present invention, an irregular and non-periodic phase separation structure is obtained to such an extent that interference fringes and the like are not generated between the optical devices constituting the display device. There is an advantage that the problem of deterioration of display quality due to the stripes hardly occurs.
[0010]
Preferably, as described in claim 6 , the stripe has a shortest cycle length of 1000 μm or less along a direction orthogonal to the extending direction of the stripe.
[0011]
Preferably, as defined in claim 7 , the stripes extend substantially parallel to the coating direction of the thin film coating.
[0012]
Preferably, as described in claim 8 , the base material is a transparent resin plate or film, and has optical transparency.
[0013]
Alternatively, as described in claim 9 , the substrate may be a resin plate or film that scatters and transmits light, and may be configured to have light scatter transmittance.
[0014]
Alternatively, as described in claim 10 , the base material is an opaque metal thin film, or a resin plate or film having an opaque metal thin film formed on the surface thereof, and has a light scattering reflectivity. It is also possible to do.
[0015]
Preferably, as described in claim 10 , the difference in refractive index between the nanoparticles and the binder composition is greater than 0.005. The refractive index difference is more preferably greater than 0.01, and even more preferably greater than 0.1.
[0016]
Preferably, as described in claim 11 , the electrical resistance value of the coated portion is set to 10 ¹¹ Ω or less so as to have conductivity. The resistance value is more preferably 10 ¹⁰ Ω or less, further preferably 10 ⁹ Ω or less, and most preferably 10 ⁸ Ω or less.
[0017]
Preferably, as described in claim 12 , a mechanical or chemical protective layer is formed on the surface of the coated portion. As the mechanical or chemical protective layer, for example, a protective layer made of an organic resin material such as an acrylic resin or an epoxy resin, an inorganic thin film material by a sol-gel method, or an inorganic thin film material by vapor deposition is used. Applicable.
[0018]
Preferably, as described in claim 13 , a treatment for improving adhesion is performed on the surface of the base material on the coated part forming side. In addition, as a process for improving the adhesion, for example, an easy adhesion process such as a corona process, a saponification process, an ozone process, a UV process, and a solvent process is performed on the surface of the base material before forming the coating part. In addition, application of a coupling material or the like to increase the wettability of the substrate surface and increase the affinity when forming the coated portion is also included.
[0019]
When the phase separation structure according to the present invention is disposed on the display surface of the display device or the like, the phase separation structure may be rubbed with a human finger or a hard handkerchief or contaminated with sweat, oil, moisture, or the like. It is usually placed under various environments such as trying to wipe off the dirt with a detergent or the like. According to the invention of claim 13 , even in such an environment, since the treatment for improving the adhesion is performed on the coated part forming side surface of the base material, the base material and the coated part It has the advantage that the durability to the environment is improved.
[0020]
Further, the present invention provides an optical system characterized in that the anisotropic phase separation structure according to any one of claims 1 to 10 is adhered to a film substrate as described in claim 14. A film is also provided.
[0021]
In addition, the present invention provides an antistatic film formed by sticking the anisotropic phase separation structure according to claim 11 to a film substrate as described in claim 15 . Furthermore, as described in claim 16 , there is also provided an electromagnetic wave shielding film formed by sticking the anisotropic phase separation structure according to claim 11 to a film substrate. .
[0023]
Here, “using the anisotropy of the phase separation structure” means that the anisotropy of the phase separation structure is effectively used when another structure is laminated. For example, when the phase separation structure is a structure in which a highly hydrophilic region (hydrophilic region) and a highly hydrophobic region (hydrophobic region) are formed in stripes, for example. Furthermore, if a water-based paint as another structure is applied to the surface of the coating part having the phase separation structure, the paint is repelled from the hydrophobic region and concentrated in the hydrophilic region. If the drying treatment is performed in this state, the water-based paint can be efficiently formed in a striped shape. In addition, after applying and drying a resin having low adhesion to the hydrophilic region (strong adhesion to the hydrophobic region) on the surface of the coated portion of the phase separation structure having the phase separation structure If the adhesive tape is attached to the resin surface and peeled off, only the part with weak adhesion (resin applied on the hydrophilic area) will peel off with the adhesive tape, while the part with strong adhesion (hydrophobic area) The resin applied thereon remains, and the resin as another structure can be efficiently formed in stripes. Similarly to the above example, a metal film as another structure is applied to the surface of the coating part by utilizing the difference between the adhesion force to the region containing nanoparticles and the adhesion force to the region not containing nanoparticles. After forming the stripe, a metal film is sequentially laminated on the metal film remaining on the surface of the coating portion by plating or the like, so that a stripe-shaped metal braid can be efficiently formed. Furthermore, when the nanoparticles forming the phase separation structure are particles having a low ultraviolet transmittance, an ultraviolet curable resin is applied to the surface of the coated part, and ultraviolet light is applied from the side opposite to the coated part forming side of the substrate. , The resin applied on the area containing no nanoparticles proceeds with ultraviolet curing, whereas the resin applied on the area containing nanoparticles does not easily undergo ultraviolet curing. Therefore, if the uncured resin is washed away after the ultraviolet irradiation, the ultraviolet curable resin as another structure can be efficiently formed in a stripe shape.
[0024]
Furthermore, as described in claim 17 , the present invention is a display device including an optical device such as a polarizing plate, and the optical film according to claim 14 is attached to the optical device. A display device characterized by the above is also provided.
[0025]
Preferably, the display device is a liquid crystal display as claimed in claim 18 , a plasma display as claimed in claim 19 , or a field emission display as claimed in claim 20. Is done.
[0026]
DETAILED DESCRIPTION OF THE INVENTION
Hereinafter, an embodiment of the present invention will be described with reference to the accompanying drawings.
[0027]
FIG. 1 is a longitudinal sectional view showing a schematic configuration of an anisotropic phase separation structure according to an embodiment of the present invention. As shown in FIG. 1, the anisotropic phase separation structure 10 according to the present embodiment includes a base material 1 and a coating part 2 formed on the base material 1.
[0028]
The coating part 2 is formed by thin-film coating the nanoparticles together with the binder composition on the base material 1, and the region containing the nanoparticles and the region not containing the nanoparticles are formed in stripes. It becomes a phase-separated structure, and has anisotropy by the said phase-separated structure.
This phase separation structure is irregular to the extent that interference fringes or the like are not generated with an optical device (such as a black matrix) constituting a display device such as a liquid crystal display device in which the anisotropic phase separation structure 10 is used. It is supposed to have non-periodicity.
[0029]
Here, the material, size, secondary aggregation and other shapes of the nanoparticles constituting the coating part 2 are not particularly limited as long as a phase separation structure can be formed, but ZrO ₂ , SnO ₂ , ATO , AZO, TiO _{2 and} other nanoparticles having a diameter of about 1 nm to several hundreds nm can be suitably used for applications that impart high refractive index and conductivity.
[0030]
Moreover, the nanoparticle which has a diameter of about Φ1 nm to several hundred nm made of MgF ₂ , CaF ₂ , SiO ₂ or the like can be suitably used for applications that impart a low refractive index.
[0031]
Furthermore, nanoparticles having a diameter of Φ1 nm to several hundreds of nanometers made of silver, gold, Cr, platinum, or palladium can be suitably used for applications that impart light reflectivity and conductivity.
[0032]
Further, the type of the binder composition constituting the coating part 2 is not particularly limited as long as a phase separation structure can be formed, but an acrylic, epoxy, urethane, or polysiloxane sol-gel reaction is not limited. A membrane or the like can be preferably used.
[0033]
The type of the substrate 1 is not particularly limited, but polyethylene terephthalate, polycarbonate, polymethyl methacrylate, methacrylic resin, acrylic resin, cellulose triacetate, norbornene resin, epoxy resin and the like are preferably used. Can be used.
[0034]
The refractive index difference (Δnd) between the nanoparticles constituting the coating part 2 and the binder composition is not particularly limited, but in order to remarkably generate optical properties such as refraction, diffraction, and scattering, Δnd> 0.005, more preferably Δnd> 0.01, and even more preferably Δnd> 0.1.
[0035]
However, when the anisotropic phase separation structure 10 is used as a conductive film, the refractive index difference Δnd is desirably smaller.
[0036]
As described above, the coating part 2 has a phase separation structure in which a region containing nanoparticles and a region not containing nanoparticles are formed in stripes. Here, the shortest periodic length along the direction perpendicular to the extending direction of the stripes is desirably 1000 μm or less for use as an optical element that causes refraction, diffraction, scattering, and the like.
[0037]
In particular, in order not to generate interference fringes or moire fringes with the pixels of the liquid crystal cell, it is desirable that the shortest cycle length is not more than the pixel size (usually not more than 200 μm). Further, when it is desired to obtain a lens effect based on the uneven surface shape or the difference in refractive index, it is preferable that the range is about 200 μm to several μm. Furthermore, when the shortest cycle length is several μm or less, interference and diffraction are likely to occur. Thus, according to the use of the anisotropic phase separation structure 10, the shortest cycle length can be variously set.
[0038]
According to the anisotropic phase-separated structure 10 described above, the refractive index of the binder composition is different from that of the nanoparticles, so that it is equivalent to an optical element such as a diffraction grating, a microlenticular lens, and an anisotropic light scatterer. It is possible to easily and inexpensively obtain an anisotropic optical element that can function. Moreover, the area | region where the content rate of a nanoparticle is large can control the surface uneven | corrugated shape according to a nanoparticle content rate, if there is little volume reduction after superposition | polymerization of a binder composition. Thus, the refraction, diffraction and scattering due to the refractive index difference and the refraction, diffraction and scattering due to the surface irregularity shape, the refractive index difference between the binder composition and the nanoparticles, the nanoparticle content, the shrinkage rate of the binder composition It is possible to design freely by setting these appropriately. Furthermore, according to the anisotropic phase separation structure 10, an irregular and non-periodic phase separation structure is obtained to such an extent that interference fringes and the like are not generated between the optical device and the optical device constituting the display device. As described above, there is an advantage that the problem of deterioration of display quality due to interference fringes and moire fringes hardly occurs.
[0039]
Moreover, if the base material 1 is made into a smooth reflecting plate etc., the reflecting plate which controlled the directional characteristic by the phase-separation structure of the coating part 2 can be obtained. For example, it is possible to provide a light reflection characteristic suitable for a horizontally long screen and obtain a uniform reflection display.
[0040]
Further, if the base material 1 is a rough surface, the phase separation structure of the coating part 2 can impart anisotropy to the rough surface characteristics of the base material 1. If such an anisotropic phase separation structure 10 is attached to, for example, an antiglare layer of a display device, it is possible to strongly scatter light in a specific direction and reduce the influence on the visibility of the display screen. is there.
[0041]
Moreover, if the phase separation structure of the coating part 2 is formed so as to have anisotropy with respect to wettability, contaminants such as condensed water adhering to the surface of the coating part 2 are effectively removed in a specific direction. Or it can be wiped off. Moreover, when forming another thin film on the surface of the coating part 2 having anisotropy with respect to the wettability, the difference in wettability can be effectively utilized. Specifically, for example, if a water-based paint as another thin film is applied to the surface of the coating part 2, the paint is repelled from the hydrophobic area of the coating part 2 and concentrated in the hydrophilic area. Become. If the drying treatment is performed in this state, the water-based paint can be efficiently formed in a striped shape. Further, after applying and drying a resin having a weak adhesion to the hydrophilic region of the coating part 2 (strong adhesion to the hydrophobic region) on the surface of the coating part 2, an adhesive tape or the like If it is attached to the resin surface and peeled off, only the part with weak adhesion (resin applied on the hydrophilic area) will peel off with the adhesive tape, while the part with strong adhesion (applied on the hydrophobic area). In other words, the resin as another thin film can be efficiently formed in a stripe shape.
[0042]
Further, if a material having light reflectivity is used as the nanoparticles constituting the coating part 2, the anisotropic phase separation structure 10 functions as a reflector, while the region having a low nanoparticle content is light transmissive. It is possible to get sex. As a result, it is possible to obtain a neutral semi-transmissive semi-reflective plate that is not subjected to absorption loss generated in the conventional metal thin film during transmission and has no difference in the spectrum of reflected light and transmitted light. Such an anisotropic phase separation structure 10 is extremely effective for colorization of a transflective liquid crystal display device.
[0043]
In addition, when a conductive material is used as the nanoparticles, unlike the conventional metal thin film, the transmitted light does not include the metal absorption spectrum, so that a conductive thin film having neutral transmission characteristics can be obtained. Such an anisotropic phase separation structure 10 can be suitably used, for example, for electromagnetic wave shielding in a plasma display. In addition, since no interference fringes or moire fringes occur between the pixels constituting the plasma display, a good display quality can be easily obtained.
[0044]
Hereinafter, the features of the present invention will be further clarified by showing examples.
[0045]
(Example 1)
ATO ultrafine particles (primary particle diameter φ1 to 5 nm, secondary particle diameter φ80 to 90 μm) as nanoparticles are dispersed in a siloxane-based sol-gel reaction hard coat binder as a binder composition by 90% by weight, and a wire bar coder is used. Then, an anisotropic phase separation structure was formed by coating a film on polyethylene terephthalate having a thickness of 50 μm as a base material.
[0046]
The thickness of the coated part (thin film) of the anisotropic phase separation structure of this example was 0.1 μm. The refractive index of the ATO ultrafine particles was about 2.0, and the refractive index of the binder composition was about 1.5.
[0047]
As shown in FIG. 2, the phase separation structure of the coating part in this example is formed in a stripe shape extending substantially parallel to the coating direction, and is a region containing a high concentration of ATO ultrafine particles at a pitch of about 10 μm. And the non-containing region.
[0048]
When the anisotropic phase separation structure of this example was irradiated with laser light, a diffraction image as shown in FIG. 3 was formed, and it was found that the anisotropic phase separation structure functions as a diffraction grating.
[0049]
Moreover, the electrical resistance value of the coating part of the anisotropic phase-separated structure of the present Example was 6 × 10 ¹⁰ Ω, which proved to be conductive.
[0050]
The haze of the anisotropic phase-separated structure of this example is about 10% and has anisotropy. When pasted on an isotropic light diffusing material (haze 30%), the spread of these transmitted rays becomes an elliptical shape. I understood that.
[0051]
Furthermore, it was found that even when the anisotropic phase separation structure of this example is arranged with respect to an optical device having a regular pattern constituting the display device, moire fringes do not occur between the two.
[0052]
(Example 2)
Aluminum coating with a thickness of 0.1 μm was applied to the coated portion of the anisotropic phase separation structure of Example 1. Furthermore, the aluminum vapor deposition film was peeled by sticking a light peeling adhesive tape on the surface of the aluminum vapor deposition film and peeling it.
[0053]
Thereby, an aluminum vapor deposition film remained only in the area | region where there was much content of ATO ultrafine particle in the coating part, the surface was rough, and it was excellent in wettability, and it peeled in another area | region. It turned out that the aluminum reflecting plate obtained by the present Example has translucency (reflectance 30%, transmittance about 30%).
[0054]
(Comparative example)
A lenticular lens patterned with a 100 μm pitch and a focal length of 1 mm was prepared by a mask exposure method. It was confirmed that moire fringes were generated between the lenticular lens and the black matrix of the liquid crystal display device.
[0055]
【The invention's effect】
According to the present invention, the coating part formed by thin-film coating the nanoparticles together with the binder composition on the substrate has a region containing the nanoparticles and a region not containing the nanoparticles in stripes. The formed phase separation structure has anisotropy due to the phase separation structure. Therefore, for example, by making the refractive index of the binder composition different from that of the nanoparticles, an anisotropic optical element that can perform the same function as an optical element such as a diffraction grating, a micro lenticular lens, and an anisotropic light scatterer can be easily obtained. In addition, it can be obtained at a low price. In addition, an irregular and non-periodic phase separation structure is obtained to such an extent that interference fringes and the like are not generated between the optical devices constituting the display device, and the display quality is degraded by interference fringes and moire fringes as in the past. The advantage that it is difficult to cause the problem is obtained.
[Brief description of the drawings]
FIG. 1 is a longitudinal sectional view showing a schematic configuration of an anisotropic phase separation structure according to an embodiment of the present invention.
FIG. 2 is a diagram showing a phase separation structure of a coating part according to Example 1 of the present invention.
FIG. 3 shows a diffraction image generated when the anisotropic phase separation structure according to Example 1 of the present invention is irradiated with laser light.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1 ... Base material 2 ... Coating part (nanoparticle, binder composition)
10: Anisotropic phase separation structure

Claims (20)

A substrate, and a coating portion formed by thin-film coating nanoparticles with the binder composition on the substrate;
In the method for forming an anisotropic phase separation structure in which the other structure formed in a stripe shape on the surface of the coating portion is formed using anisotropy due to the phase separation structure of the coating portion,
The coating part is a phase separation structure in which a region containing the nanoparticles and a region not containing the nanoparticles are formed in stripes, and has anisotropy by the phase separation structure ,
And using a resin as the previous SL other structures, the coated portion surface of the phase-separated structure having the phase separation structure, applying a weak resin adherence force to highly hydrophilic region (hydrophilic region) In addition, after applying a resin with strong adhesion to a highly hydrophobic area (hydrophobic area) and drying it, the adhesive tape is attached to the surface of the applied resin and peeled off. A method in which an anisotropic phase separation structure is formed by peeling off the resin applied to the substrate together with the adhesive tape while the resin applied on the hydrophobic region remains and forms the resin in a stripe shape. A substrate, and a coating portion formed by thin-film coating nanoparticles with the binder composition on the substrate;
In the method for forming an anisotropic phase separation structure in which the other structure formed in a stripe shape on the surface of the coating portion is formed using anisotropy due to the phase separation structure of the coating portion,
The coating part is a phase separation structure in which a region containing the nanoparticles and a region not containing the nanoparticles are formed in stripes, and has anisotropy by the phase separation structure,
The refractive index difference between the nanoparticles and the binder composition is greater than 0.005, and the phase separation structure has a highly hydrophilic region (hydrophilic region) and a highly hydrophobic region (hydrophobic region). Formed in stripes, and by applying a water-based paint as another structure on the surface of the coating part and drying, the water-based paint is formed in stripes to form an anisotropic phase separation structure. Method. A substrate, and a coating portion formed by thin-film coating nanoparticles with the binder composition on the substrate;
In the method for forming an anisotropic phase separation structure in which the other structure formed in a stripe shape on the surface of the coating portion is formed using anisotropy due to the phase separation structure of the coating portion,
The coating part is a phase separation structure in which a region containing the nanoparticles and a region not containing the nanoparticles are formed in stripes, and has anisotropy by the phase separation structure,
After the refractive index difference between the nanoparticles and the binder composition is greater than 0.005 and the metal film as the other structure is formed in a striped pattern on the coated part surface, the metal remaining on the coated part surface A method of forming an anisotropic phase-separated structure by forming a striped metal plate by sequentially laminating a metal film on a film. A substrate, and a coating portion formed by thin-film coating nanoparticles with the binder composition on the substrate;
In the method for forming an anisotropic phase separation structure in which the other structure formed in a stripe shape on the surface of the coating portion is formed using anisotropy due to the phase separation structure of the coating portion,
The coating part is a phase separation structure in which a region containing the nanoparticles and a region not containing the nanoparticles are formed in stripes, and has anisotropy by the phase separation structure,
Nanoparticles refractive index difference between the nanoparticle and the binder composition to form a large and the phase separation structure than 0.005, a low particle UV transmittance, ultraviolet curing said coated portion surface After applying the resin and irradiating ultraviolet rays from the side opposite to the coated part forming side of the base material, the uncured resin is washed away, thereby forming an ultraviolet curable resin as another structure in a stripe shape. A method of forming an isotropic phase separation structure. A substrate, and a coating portion formed by thin-film coating nanoparticles with the binder composition on the substrate;
In the method for forming an anisotropic phase separation structure in which the other structure formed in a stripe shape on the surface of the coating portion is formed using anisotropy due to the phase separation structure of the coating portion,
The coating part is a phase separation structure in which a region containing the nanoparticles and a region not containing the nanoparticles are formed in stripes, and has anisotropy by the phase separation structure,
The refractive index difference between the nanoparticles and the binder composition is greater than 0.005,
While using resin as the other structure and applying a resin having low adhesion to a highly hydrophilic region (hydrophilic region) on the surface of the coated portion of the phase separation structure having the phase separation structure After applying a resin with strong adhesion to a highly hydrophobic area (hydrophobic area) and drying it, the adhesive tape is applied to the applied resin surface and peeled off, so that the hydrophilic area is covered. A method in which the applied resin is peeled off together with the adhesive tape, while the applied resin remains on the hydrophobic region and the resin is striped to form an anisotropic phase separation structure. The stripes may form an anisotropic phase separation structure according to any one of claims 1 to 5, the shortest period length along the direction perpendicular to the extending direction of the stripe is equal to or is 1000μm or less Method. Wherein the fringes of forming the anisotropic phase separation structure according to claim 1, wherein the 5 in that the relative coating direction of the thin film coating, is substantially parallel elongated . The method for forming an anisotropic phase separation structure according to any one of claims 1 to 7 , wherein the base material is a transparent resin plate or film, and has optical transparency. Said substrate is a resin sheet or film which scatters transmitted light, form an anisotropic phase separation structure according to claim 1, characterized in that it comprises a light-scattering transparent 7 how to. The substrate is opaque metal thin film, or an opaque metal thin film is a sheet or film made of formed resin on the surface, any of claims 1, characterized in that it has a light scattering reflecting 7 The method of forming the anisotropic phase-separation structure as described in 2. The method for forming an anisotropic phase separation structure according to any one of claims 1 to 10, wherein an electric resistance value of the coated portion is 10 ¹¹ Ω or less.  The method for forming an anisotropic phase separation structure according to any one of claims 1 to 11, wherein a mechanical or chemical protective layer is formed on a surface of the coating part.  The method for forming an anisotropic phase separation structure according to any one of claims 1 to 12, wherein a treatment for improving adhesion is performed on a surface of the substrate on which the coating part is formed. .  An optical film formed by adhering an anisotropic phase separation structure formed by the method according to claim 1 to a film substrate.  An antistatic film formed by adhering an anisotropic phase separation structure formed by the method according to claim 11 to a film substrate.  An electromagnetic wave shielding film formed by sticking an anisotropic phase separation structure formed by the method of claim 11 to a film substrate.  It is a display apparatus provided with the optical device, Comprising: The optical film of Claim 14 is affixed on the said optical device, The display apparatus characterized by the above-mentioned.  The display device according to claim 17, wherein the display device is a liquid crystal display.  The display device according to claim 17, wherein the display device is a plasma display.  The display device according to claim 17, wherein the display device is a field emission display.

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