JP4336534B2 - Heat transfer tube with corrosion resistance - Google Patents
Heat transfer tube with corrosion resistance Download PDFInfo
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- JP4336534B2 JP4336534B2 JP2003195667A JP2003195667A JP4336534B2 JP 4336534 B2 JP4336534 B2 JP 4336534B2 JP 2003195667 A JP2003195667 A JP 2003195667A JP 2003195667 A JP2003195667 A JP 2003195667A JP 4336534 B2 JP4336534 B2 JP 4336534B2
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- heat transfer
- outer peripheral
- resin coating
- peripheral surface
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- 238000005260 corrosion Methods 0.000 title claims description 35
- 230000007797 corrosion Effects 0.000 title claims description 32
- 229920005989 resin Polymers 0.000 claims description 131
- 239000011347 resin Substances 0.000 claims description 131
- 229910052751 metal Inorganic materials 0.000 claims description 121
- 239000002184 metal Substances 0.000 claims description 121
- 230000002093 peripheral effect Effects 0.000 claims description 105
- 239000011247 coating layer Substances 0.000 claims description 98
- 239000010410 layer Substances 0.000 claims description 85
- 238000007747 plating Methods 0.000 claims description 40
- 239000000463 material Substances 0.000 claims description 27
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 14
- 238000004804 winding Methods 0.000 claims description 13
- 239000002134 carbon nanofiber Substances 0.000 claims description 11
- 239000000835 fiber Substances 0.000 claims description 6
- 239000011521 glass Substances 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 230000017525 heat dissipation Effects 0.000 description 23
- 239000012530 fluid Substances 0.000 description 21
- 238000010521 absorption reaction Methods 0.000 description 18
- 239000004952 Polyamide Substances 0.000 description 16
- 229920002647 polyamide Polymers 0.000 description 16
- 239000004743 Polypropylene Substances 0.000 description 13
- 229920001155 polypropylene Polymers 0.000 description 13
- 239000004575 stone Substances 0.000 description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 10
- 229910052782 aluminium Inorganic materials 0.000 description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 10
- 239000000126 substance Substances 0.000 description 8
- 239000004698 Polyethylene Substances 0.000 description 7
- 229920000573 polyethylene Polymers 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 6
- 229910052802 copper Inorganic materials 0.000 description 6
- 239000010949 copper Substances 0.000 description 6
- 230000005855 radiation Effects 0.000 description 6
- 239000010959 steel Substances 0.000 description 6
- 238000004381 surface treatment Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 229910052759 nickel Inorganic materials 0.000 description 5
- 229910000990 Ni alloy Inorganic materials 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
- QELJHCBNGDEXLD-UHFFFAOYSA-N nickel zinc Chemical compound [Ni].[Zn] QELJHCBNGDEXLD-UHFFFAOYSA-N 0.000 description 4
- -1 polypropylene Polymers 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 229910021393 carbon nanotube Inorganic materials 0.000 description 3
- 239000002041 carbon nanotube Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000001771 impaired effect Effects 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- GZCWPZJOEIAXRU-UHFFFAOYSA-N tin zinc Chemical compound [Zn].[Sn] GZCWPZJOEIAXRU-UHFFFAOYSA-N 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- 229910001297 Zn alloy Inorganic materials 0.000 description 2
- 238000007743 anodising Methods 0.000 description 2
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- 229920000299 Nylon 12 Polymers 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
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- 238000005452 bending Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
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- 229920005992 thermoplastic resin Polymers 0.000 description 1
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- Laminated Bodies (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
Description
【0001】
【産業上の利用分野】
本発明は、自動車や建設機械の油冷却管、居住用空間の温湿度を調整する空調機、その他に於いて、腐食環境下で使用される耐食性を有する伝熱管に係るもので、耐食性は勿論、優れた放熱特性による効率的な熱交換が可能な伝熱管を得ようとするものである。
【0002】
【従来の技術】
従来、上述の如き耐食性を有する伝熱管として、特開平8−188884号公報記載の発明、特開平10−315295号公報記載の発明の如く、亜鉛メッキやクロメート被膜等の防食メッキを施した鋼管やアルミ管等の細径金属管の外周面に、押出成形法によりポリアミド(PA)、ポリプロピレン(PP)、ポリエチレン(PE)等の熱可塑性の樹脂被膜層を設けたものが存在する。この樹脂被膜層の衝撃吸収力や耐水性、耐薬品性等により、飛び石等による防食メッキ層、細径金属管の破損を防ぎ、泥はねや薬品等による細径金属管の酸化を防止し、伝熱管の耐食性を高めていた。
【0003】
【発明が解決しようとする課題】
しかしながら、上述の如き従来技術の伝熱管は、耐衝撃性や耐食性を高めるために樹脂被膜層を肉厚に形成しているので、放熱特性の点で問題があり、伝熱管の内外を流通する流体同志の熱交換を効率的に行うのは困難であった。そこで、放熱特性の向上のため、特開平9−42573号公報記載の発明、特開平9−136111号公報記載の発明、特開平11−325778号公報記載の発明の如く、長尺な平板を螺旋状に巻回して、細径金属管の外周にフィン部材を設けて伝熱管を形成したものが存在する。このフィン部材により、伝熱管の放熱特性が高まり、伝熱管の内部を流動する流体と外部を流動する流体との熱交換効率を向上させる事ができる。しかしながら、飛び石等により細径金属管の表面の防食メッキ層が破損され易く、耐食性に問題があった。
【0004】
本発明は上述の如き課題を解決しようとするもので、細径金属管を耐衝撃性の高い樹脂被膜層で被覆して、耐食性を高めるとともに、樹脂被膜層の外周に熱伝導性に優れた金属製の伝熱体を設けて放熱特性や吸熱特性を高め、内部を流通する流体と外部を流通する流体との熱交換効率にも優れた伝熱管を得るものである。また、この耐食性と放熱特性又は吸熱特性に優れた伝熱管を、簡易な構造で廉価に形成可能とする。
【0005】
【課題を解決するための手段】
上述の如き課題を解決するため、第1の発明は、細径金属管と、この細径金属管の外周面に設けた少なくとも1層の樹脂被膜層と、この樹脂被膜層の最外層の外周面に密着させて装着した肉薄金属管で形成した金属製の伝熱体とから成るものである。
【0006】
また、第2の発明は、細径金属管と、この細径金属管の外周面に設けた少なくとも1層の樹脂被膜層と、この樹脂被膜層の最外層の外周面に密着させて螺旋状に巻き回した金属製の帯材で形成した金属製の伝熱体とから成るものである。
【0007】
また、第3の発明は、細径金属管と、この細径金属管の外周面に設けた少なくとも1層の樹脂被膜層と、この樹脂被膜層の最外層の外周面に密着させて螺旋状に巻き回した金属製のフィン部材で形成した金属製の伝熱体とから成るものである。
【0008】
また、第4の発明は、細径金属管と、この細径金属管の外周面に設けた少なくとも1層の樹脂被膜層と、この樹脂被膜層の最外層の外周面に密着させて螺旋状に巻き回した金属製の線材で形成した金属製の伝熱体とから成るものである。
【0009】
また、細径金属管は、外表面に少なくとも1層の防食メッキ層を設け、この防食メッキ層の外周面に少なくとも1層の樹脂被膜層を設けても良い。
【0010】
また、伝熱体は、外表面に少なくとも1層の防食メッキ層を設けても良い。
【0011】
また、伝熱体は、外周面に樹脂製の外周フィンを螺旋状に巻き回しても良い。
【0012】
また、樹脂被膜層及び/又は樹脂製の外周フィンは、該樹脂材よりも熱伝導性の高い金属製又はガラス製の粒子及び/又は繊維を含有しても良い。
【0013】
また、樹脂被膜層及び/又は樹脂製の外周フィンは、カーボンナノファイバーを含有させても良い。
【0014】
カーボンナノファイバーは、5wt%より多く30wt%より少ない含有量で含有させても良い。
【0015】
また、フィン部材及び/又は外周フィンは、ピン、突起、短冊状の板材、凹凸、貫通孔の何れか一つ又はこれらの組み合わせから成る乱流化手段を外周面に設けても良い。
【0016】
また、樹脂被膜層は、細径金属管の外周面に2層配設しても良い。
【0017】
【作用】
本発明は、上述の如く構成したものであるから、鋼管やアルミ管等の細径金属管の外周面に設ける樹脂被膜層は、押出成形法、その他の手法により、PE、PP、PA等の何れか1種の樹脂を用いて1層のみで形成しても良いし、2種以上の樹脂を用いて、複数層で形成しても良い。樹脂被膜層を1層としても、優れた耐衝撃性が得られるし、樹脂被膜層を設ける手数を少なくできる。
【0018】
また、複数層の場合、例えば細径金属管の外周面に金属との密着性に優れたPA層を配置し、このPA樹脂被膜層の外周面に耐水性や耐薬品性に優れたPP層を配置して、2層で形成すれば、各樹脂の特性の相乗効果で、伝熱管の耐食性を更に高める事ができる。また、2層とした樹脂被膜層は、100μm〜1mmとするのが好ましく、伝熱管の耐食性が得られ、且つ伝熱管の熱伝導性を損なう事のないものとなる。
【0019】
また、上記PA/PPの組み合わせの他にも、PA/PA、PP/PP、PA/PE等の組み合せとしても良い。このように、衝撃吸収力や耐水性、耐薬品性等、様々な特性に優れた樹脂の中から、使用環境や目的に応じて1種又は複数種の樹脂を選択し、細径金属管を1層又は複数層の樹脂被膜層で被覆する事により、細径金属管の飛び石等による破損や泥はね等による酸化等を防止して、伝熱管の耐食性及び耐熱性を向上させる事ができる。
【0020】
そして、上記1層又は複数層の樹脂被膜層の外周面に、金属製の伝熱体を設けているので、金属の優れた熱伝導性により、樹脂被膜層のみを設けた場合に比べて伝熱管の外部を流動する流体との熱交換効率を向上させる事が可能となる。また、従来技術では、伝熱管の耐食性を向上させるために樹脂被膜層を肉厚としていたので、伝熱管の放熱特性に乏しかった。しかし、本発明では、樹脂被膜層の外周面に設けた金属製の伝熱体も耐衝撃性を有し、樹脂被膜層による細径金属管の保護力を助長するので、従来に比べて樹脂被膜層を肉薄に形成でき、放熱の場合は伝熱管の放熱特性を、吸熱の場合は伝熱管の吸熱特性を更に向上して、伝熱管の内外を流動する流体間の熱交換効率を高める事ができる。
【0021】
また、弾力性及び柔軟性を有する樹脂被膜層の存在により、細径金属管への伝熱体のフィット性が高く、安定して密着配設させる事ができる。従って、伝熱体と樹脂被膜層との熱伝導性が高まり、伝熱管の放熱特性や吸熱特性が向上するとともに、伝熱管の振動や伝熱体の外周を流動する流体の流動圧などへの伝熱体の耐久性が向上し、優れた熱交換性能を持続させる事ができる。
【0022】
また、前記金属製の伝熱体は、樹脂被膜層の外周面に肉薄金属管を装着し、この肉薄金属管を伸管させて樹脂被膜層を介して細径金属管に密着させれば、樹脂被膜層の外周面全体を金属で被覆可能となり、高い放熱特性或いは吸熱特性を得て、効率的な熱交換が可能となる。
【0023】
また、伝熱体は、樹脂被膜層の外周面に金属製の帯材を螺旋状に巻き回して形成したり、断面円形、楕円形、三角形、四角形等の金属製の線材を螺旋状に巻き回して形成すれば、伝熱体を設ける作業をより容易とする事ができる。また、伝熱体は、樹脂被膜層の外周に巻き回した断面L字状、T字状、U字状等の金属製のフィン部材としても良く、外部を流通する流体と伝熱体との接触面積が増大し、伝熱管の放熱特性や吸熱特性が向上して、効率的な熱交換が可能となる。
【0024】
また、帯材、フィン部材、線材等を樹脂被膜層の外周面に巻き回す際は、隣接する端部を互いに隙間無く密着させて、樹脂被膜層の外周面全体を帯材、フィン部材、線材で被覆しても良いし、隣接する端部間に一定の間隔を介して帯材、フィン部材、線材を巻き回し、樹脂被膜層の一部を外部に露出させても良い。また、一定間隔で巻き回す場合には、間隔が広くて伝熱体の表面積が少ないと、伝熱管の高い熱伝導性を得る事が困難となるので、熱伝導性を損なう事がなく、飛び石を防げる間隔や角度で帯材、フィン部材、線材を配置する。
【0025】
また、伝熱体は、例えば、樹脂被膜層の外周面に金属製の帯材を巻き回し、この帯材の外表面に更に金属製のフィン部材を巻き回して形成する等、肉薄金属管、帯材、フィン部材、線材を複数組み合わせて形成しても良く、放熱特性或いは吸熱特性を更に向上させる事ができる。
【0026】
また、伝熱体を肉薄金属管、帯材、線材で形成した場合、当該伝熱体の外周面に断面L字状、T字状、U字状等の樹脂製の外周フィンを螺旋状に巻き回せば、樹脂の弾力性により飛び石等に対する伝熱管の耐衝撃性を高める事ができる。また、外周フィンを樹脂製としても、その広い表面積により良好な放熱特性や吸熱特性が得られ、熱交換器としての伝熱管の機能性を向上させる事ができる。
【0027】
また、上記金属製のフィン部材及び/又は樹脂製の外周フィンは、ピン、突起、短冊状の板材、凹凸、貫通孔の何れか1つ又はこれらの組み合わせから成る乱流化手段を外周面に設ければ、フィン部材や外周フィンの表面積を更に増す事ができ、伝熱管による熱交換効率を更に向上させる事ができる。また、これらの乱流化手段により、伝熱管の外部を流通する流体に渦巻状の乱流を発生させ、境界層の剥離により、熱交換効率を更に向上させる事ができる。
【0028】
また、細径金属管は、外表面に少なくとも1層の犠牲腐食性等の防食メッキ層を設け、この防食メッキ層の外周面に少なくとも1層の樹脂被膜層を設ければ、細径金属管及び防食メッキ層が樹脂被膜層により保護され、伝熱管の耐食性を高める事ができる。また、前記防食メッキ層は、亜鉛、錫、錫−亜鉛合金、ニッケル、亜鉛−ニッケル合金等を用いた1層構造であっても良いし、これらを組み合わせた2層以上の複数層構造であっても良い。
【0029】
また、上記肉薄金属管、金属製の帯材、金属製のフィン部材、金属製の線材等で形成した伝熱体に於いても、外表面に少なくとも1層の犠牲腐食性等の防食メッキ層を設ければ、伝熱管の防食性を更に高める事ができる。また、この伝熱体へのメッキ処理は、樹脂被膜層の外周面に、前記何れかの伝熱体を設けた後に行っても良いし、予めメッキ処理を施した肉薄金属管、帯材、フィン部材、線材等を樹脂被膜層の外周面に設けるものであっても良い。
【0030】
また、前記樹脂被膜層及び/又は樹脂製の外周フィンは、該樹脂材よりも熱伝導性の高い銅、アルミ、ステンレス等の金属製又はガラス製の粒子及び/又は繊維を含有すれば、樹脂被膜層や外周フィンの熱伝導性が高まり、放熱特性や吸熱特性に優れた伝熱管を得て、より効率的な熱交換が可能となる。
【0031】
特に、樹脂被膜層及び/又は樹脂製の外周フィンは、カーボンナノファイバーを含有させれば、樹脂材の熱伝導性を向上させる事ができ、伝熱管の放熱特性或いは吸熱特性の高い向上が可能となる。また、カーボンナノファイバーは、5wt%より多く30wt%より少ない含有量で含有させれば、最良の放熱特性或いは吸熱特性を得る事ができる。このカーボンナノファイバーの含有量を5wt%以下とすると、伝熱効果の向上作用に乏しく、30wt%以上を樹脂材に含有させるのは困難で、生産性が低下するとともに高価で、伝熱効果に大きな差を生じない。尚、本明細書で言うカーボンナノファイバーとは、ナノテクノロジー分野に於いて、カーボンナノチューブ、カーボンナノホーン、その他ナノ単位のカーボン材料を全て含んだ総称を示すものである。
【0032】
【実施例】
以下、本発明の実施例を図面に於て詳細に説明すれば、図1は本発明の第1実施例の伝熱管の一部拡大断面図で、肉薄金属管を伝熱体とし、細径金属管と伝熱体の各々の外表面に防食メッキ層を施したものであり、図2に示す第2実施例は、金属製の帯材を伝熱体とした伝熱管で、図3に示す第3実施例は、断面L字状のフィン部材を伝熱体とした伝熱管である。また、図4に示す第4実施例は、断面T字状のフィン部材を伝熱体とした伝熱管で、図5に示す第5実施例は、断面T字状のフィン部材にピンを突設して乱流化手段を設けた伝熱管、図6に示す第6実施例は、断面U字状のフィン部材を伝熱体とした伝熱管、図7に示す第7実施例は、断面円形の金属製の線材を伝熱体とするとともに、樹脂被膜層を2層とした伝熱管である。また、図8に示す第8実施例は、肉薄金属管で形成した伝熱体の外周面に、樹脂製の外周フィンを螺旋状に巻き回した伝熱管である。また、図9に示す第9実施例は、樹脂被膜層の外周面に金属製の帯材を配設し、この帯材の外周面に、更に断面I字状の金属製のフィン部材を巻き回して伝熱体とした伝熱管である。
【0033】
まず、図1に示す第1実施例を詳細に説明すれば、(1)は細径金属管で、管径30mm以下の比較的細径の外表面に銅メッキの無い一重巻鋼管、外表面に銅メッキの有る二重巻鋼管、アルミ管等を用いている。そして、前記細径金属管(1)の外表面にメッキ処理を施し、犠牲腐食性等の防食メッキ層(2)を設けるが、この防食メッキ層(2)は、亜鉛、錫、錫−亜鉛合金、ニッケル、亜鉛−ニッケル合金等により1層で形成しても良いし、細径金属管(1)の外表面にニッケルをメッキし、このニッケルの外周面に亜鉛−ニッケル合金をメッキして2層構造とする等、複数層としても良い。また、複数層の防食メッキ層(2)の形成は、例えば特許第2750710号公報記載の発明、特許第2954555号公報記載の発明、特開平3−47987号公報記載の手法で行っても良い。
【0034】
次に、押出成形装置等を用いて、上述の如き防食メッキ層(2)の外周面に樹脂被膜層(3)を密着コーティングする。この樹脂被膜層(3)は、本実施例ではポリアミド12等のポリアミド(PA)、ポリプロピレン(PP)、ポリエチレン(PE)等により形成した1層のみで形成している。また、樹脂被膜層(3)は、前記樹脂材中に銅、アルミ、ステンレス等の金属やガラスで形成した粒子や繊維を含有させて形成しても良く、樹脂被膜層(3)の熱伝導性を高める事ができる。更に、樹脂被膜層(3)を黒色としても良く、放熱の場合は輻射熱の放射特性に優れ、吸熱の場合は熱吸収に優れたものとなり、熱交換効率の更なる向上が可能となる。
【0035】
また、上記樹脂被膜層(3)に含有させる繊維として、カーボンナノチューブ、カーボンナノホーン等のカーボンナノファイバーを使用する事により、樹脂被膜層(3)の放熱特性や吸熱特性を高く向上させる事ができる。また、このようなカーボンナノファイバーを、5wt%より多く30wt%より少ない含有量で含有させるのが好ましく、より良好な伝熱効果が得られるとともに伝熱管(7)の生産も容易である。
【0036】
そして、上記樹脂被膜層(3)の外周面に、金属製の伝熱体(5)を設けるが、図1に示す第1実施例では、樹脂被膜層(3)の外周面に、銅、アルミ、ステンレス等の金属製の肉薄金属管(4)を外装し、この肉薄金属管(4)を伸管する手法で樹脂被膜層(3)を介して細径金属管(1)の外周面に肉薄金属管(4)を密着させて伝熱体(5)を形成している。
【0037】
そして、上記伝熱体(5)の外周面にメッキ処理を施し、第2防食メッキ層(6)を設けている。この第2防食メッキ層(6)も、前記細径金属管(1)外周の防食メッキ層(2)の如く、亜鉛、錫、錫−亜鉛合金、ニッケル、亜鉛−ニッケル合金等により1層で形成しても良いし、これらを組み合わせて複数層で形成しても良い。この第2防食メッキ層(6)を設ける事により、伝熱体(5)の腐食を防ぎ、伝熱管(7)全体の耐食性を更に高める事が可能となる。
【0038】
上述の如く形成した伝熱管(7)では、細径金属管(1)及び防食メッキ層(2)を衝撃吸収性や耐水性、耐薬品性等を有する樹脂被膜層(3)で被覆保護する事で、鋼管やアルミ管等を用いた細径金属管(1)及び防食メッキ層(2)の、飛び石等による破損や泥はね等による酸化等の防止効果が高まり、耐食性に優れた製品を得る事ができる。また、従来技術では、樹脂被膜層(3)を設ける事により放熱特性が低下していたが、本発明では、樹脂被膜層(3)の外周面に金属製の伝熱体(5)を設けているので、伝熱管(7)の熱伝導性を向上させる事ができる。
【0039】
また、金属製の伝熱体(5)は耐衝撃性にも優れるので、樹脂被膜層(3)を従来に比べて肉薄に形成する事が可能となり、伝熱管(7)の放熱特性の向上を更に助長するものとなる。従って、放熱特性に優れた伝熱管(7)を介して、該伝熱管(7)の内部を流通する流体と外部を流通する流体との熱交換を効率的に行う事ができ、この伝熱管(7)を使用した自動車や建設機械の油冷却管、居住用空間の温湿度を調整する空調機等の製品の品質を向上させる事ができる。
【0040】
また、上記第1実施例では、細径金属管(1)の外表面に防食メッキ層(2)を設け、伝熱体(5)の外表面に第2防食メッキ層(6)を設ける事により、過酷な腐食環境下であっても優れた耐食性を持続可能となるが、本発明では、少なくとも細径金属管(1)の外周面に樹脂被膜層(3)を設け、その外周面に金属製の伝熱体(5)を設けた構造とすれば良く、前記防食メッキ層(2)や第2防食メッキ層(6)を設けずに伝熱管(7)を形成しても良い。このような伝熱管(7)でも、樹脂被膜層(3)及び伝熱体(5)により、耐食性、放熱特性に優れた製品を得る事ができる。また、メッキ処理に限らず、細径金属管(1)や伝熱体(5)に、陽極酸化処理等の他の表面処理を施しても良い。
【0041】
また、上記メッキ処理や陽極酸化処理等の表面処理作業は、伝熱管(7)の製作工程に組み込んでも良いが、予めこれらの表面処理の施された細径金属管(1)や伝熱体(5)用の肉薄金属管(4)を使用しても良く、表面処理の手間を省いて伝熱管(7)の生産性を高める事ができる。
【0042】
また、図2〜図7に示す第2〜第7実施例では、第1実施例と同様に、細径金属管(1)の外表面に防食メッキ層(2)、樹脂被膜層(3)を順次設けているが、この樹脂被膜層(3)の外周面に設ける伝熱体(5)を、後述の金属製の帯材(8)、フィン部材(10)、線材(13)等で形成している。
【0043】
まず、図2に示す第2実施例では、樹脂被膜層(3)の外周面に、平板状の長尺な金属製の帯材(8)を螺旋状に巻き回す事により、樹脂被膜層(3)の外周面に伝熱体(5)を形成している。このように帯材(8)を巻き回すだけの作業なので、樹脂被膜層(3)の外周面への伝熱体(5)の設置を簡易に行う事ができる。尚、図2では、帯材(8)の隣接する両端を隙間無く密着させて、樹脂被膜層(3)全体を帯材(8)で被覆しているが、一定の間隔を介して帯材(8)を巻き回し、樹脂被膜層(3)の一部を外部に露出させても良く、帯材(8)の節約と簡易な作業が可能となる。また、一定間隔で帯材(8)を巻き回す場合には、帯材(8)による熱伝導性を損なわず、かつ飛び石を防げる間隔や角度で帯材(8)を配置する。
【0044】
次に、図3に示す第3実施例では、長尺で平滑な金属板を断面L字状に折曲形成したフィン部材(10)を、樹脂被膜層(3)の外周面に螺旋状に巻き回す事により、伝熱体(5)を形成している。
【0045】
また、図4に示す第4実施例では、断面T字状のフィン部材(10)とし、このT字の横棒で表される平滑面を樹脂被膜層(3)に接触させながら、この樹脂被膜層(3)の外周面にフィン部材(10)を螺旋状に巻き回して伝熱体(5)を形成している。第3、第4実施例の如くフィン部材(10)にて伝熱体(5)を形成する事により、外部を流通する流体と伝熱体(5)との接触面積が増大し、熱交換効率を高める事ができる。
【0046】
また、図5に示す第5実施例では、第4実施例と同様に断面T字状のフィン部材(10)にて伝熱体(5)を形成し、更にこのフィン部材(10)の両側の外周面に、フィン部材(10)の表面と垂直方向にピン(11)を突出固定し、伝熱管(7)の外部を流通する流体を乱流化するための乱流化手段を設けている。この乱流化手段であるピン(11)は、樹脂被膜層(3)の外周面に固定する前のフィン部材(10)に予め固定し、このピン(11)を固定したフィン部材(10)を樹脂被膜層(3)の外周面に巻き付け固定している。また、ピン(11)のフィン部材(10)への固定手段は、図5に示す如く、フィン部材(10)に貫通孔(12)を開口し、この貫通孔(12)に挿通したピン(11)を、ろう付けまたは溶接によりフィン部材(10)に、一定間隔又はランダムに固定している。
【0047】
このように、フィン部材(10)にピン(11)を設ける事により、フィン部材(10)の表面積を増大し、外部を流通する流体との熱交換効率を向上させる事ができる。また、フィン部材(10)の平滑な外表面にピン(11)を突出することにより、フィン部材(10)の両表面に流体の渦巻状の乱流を発生させ、螺旋状に巻き回されたフィン部材(10)間に発生し易い境界層を剥離し、放熱特性により熱交換効率を更に向上させる事ができるものである。
【0048】
また、上記第5実施例では、フィン部材(10)の両面に一本のピン(11)を突設して乱流化手段としているが、他の異なる実施例として、片面のみにピン(11)を設けても良いし、両面又は片面に複数のピン(11)を突設しても良い。また、ピン(11)とは異なる形状の適宜の突起や凹凸を設けても良い。また、ピン(11)を突設せず、貫通孔(12)のみであっても流体の乱流化が可能となる。更に異なる乱流化手段として、ピン(11)に代えてフィン部材(10)に短冊状の板材を固定形成しても良く、ピン(11)に比べてフィン部材(10)の表面積が更に増大し、流体の渦巻状の乱流を大きく発生させ、境界層の剥離による放熱特性により、熱交換効率を向上させる事ができる。また、上記ピン(11)、貫通孔(12)、突起、凹凸、短冊状の板材等の何れか1種から成る乱流化手段であっても良いし、これらを複数種組み合わせて乱流化手段を形成しても良い。
【0049】
また、上記第3〜5実施例の伝熱体(5)用のフィン部材(10)を巻き回す場合でも、フィン部材(10)の隣接する両端を隙間無く密着させ、樹脂被膜層(3)の外周面全体を伝熱体(5)で被覆しても良いし、フィン部材(10)の隣接する両端との間に一定間隔を介在させ、樹脂被膜層(3)の外周面の一部を外部に露出させても良く、この場合もフィン部材(10)による熱伝導率を損なわない程度に、飛び石を防げる間隔や角度でフィン部材(10)を巻き回す。
【0050】
次に、図6に示す第6実施例では、断面U字状のフィン部材(10)を樹脂被膜層(3)の外周面に、伝熱体(5)による熱伝導性を損なう事なく、飛び石を防げる程度の一定の間隔を介して螺旋状に巻き回して伝熱体(5)を形成している。このように、フィン部材(10)を断面U字状とする事により、L字状やT字状としたフィン部材(10)に比べて、流体と伝熱体(5)との接触面積を更に増大させる事ができ、伝熱体(5)と流体との熱交換効率をより高める事ができる。
【0051】
また、上記第6実施例の断面U字状のフィン部材(10)及び前述の第3実施例の断面L字状、第4実施例の断面T字状の各フィン部材(10)は、外径方向への突出部の表面を平滑に形成しているが、表面を波状に形成して、フィン部材(10)の表面積を増大し、熱交換効率を更に高めるものとしても良い。
【0052】
また、図7に示す第7実施例では、アルミ管を使用した細径金属管(1)の外表面に、亜鉛メッキ及びクロメート被膜の2層から成る防食メッキ層(2)を形成するとともにこの防食メッキ層(2)の外周面に、金属との密着性に優れたPA12製の第1層(14)を設け、このPA12製の第1層(14)の外周面に耐水性や耐薬品性に優れたPP製の第2層(15)をコーティングし、2層構造の樹脂被膜層(3)としている。そして、この2層の樹脂被膜層(3)の肉厚を100μm〜1mmとする事で、耐水性や耐薬品性、及び耐衝撃性が高く、且つ熱伝導性を損なう事のないものとなる。この2層構造の樹脂の組み合わせは、上記PA/PPの他にも、PA/PA、PP/PP、PA/PE等が挙げられる。また、3層以上の樹脂被膜層(3)としても良い。
【0053】
そして、第1層(14)及び第2層(15)から成る樹脂被膜層(3)の外周面に、断面円形の金属製の線材(13)を螺旋状に巻き回す事により、樹脂被膜層(3)の外周面に伝熱体(5)を形成している。このように線材(13)を使用した場合でも、樹脂被膜層(3)の外周面への伝熱体(5)の設置を簡易に行う事ができる。また、図7に示す如く、線材(13)の隣接する外周面を隙間無く密着させて、樹脂被膜層(3)全体を線材(13)で被覆しても良いし、線材(13)による熱伝導性を損なう事がなく、飛び石を防げる程度の一定の間隔を介して線材(13)を巻き回し、樹脂被膜層(3)の一部を外部に露出させても良く、帯材(8)の節約と更なる簡易な作業が可能となる。また、本実施例では断面円形の線材(13)を使用しているが、断面が楕円形、三角形、四角形等、円形以外の任意の形状のものを用いても良い。
【0054】
また、第7実施例の如く、第1層(14)、第2層(15)から成る樹脂被膜層(3)又は3層以上の樹脂被膜層(3)は、1層のみで形成した第1〜第6実施例の樹脂被膜層(3)に適用しても良い。
【0055】
また、上記第2〜第7実施例で使用する帯材(8)、フィン部材(10)、線材(13)は、樹脂被膜層(3)の外周面への設置後に、メッキ処理や陽極酸化処理等の表面処理を施しても良いし、前記表面処理を予め施した帯材(8)、フィン部材(10)、線材(13)を使用しても良く、伝熱管(7)の耐食性を更に高める事ができる。また、帯材(8)、フィン部材(10)、線材(13)は、長尺なものを連続的に巻き回しても良いし、短尺又はリング状の帯材(8)、フィン部材(10)、線材(13)を互いに密着して、又は伝熱体(5)による熱伝導性を損なう事なく、飛び石を防げる程度の一定の間隔で樹脂被膜層(3)の外周面に設けても良い。また、第3実施例の断面L字状のフィン部材(10)及び第6実施例の断面U字状のフィン部材(10)に、第5実施例の如きピン(11)、突起、凹凸、貫通孔(12)等の、何れか1種又は複数種の組み合わせから成る乱流化手段を設けても良い。
【0056】
また、上記第3〜第7実施例では、金属製のフィン部材(10)を伝熱体(5)として使用しているが、図8に示す第8実施例では、伝熱体(5)とは別個に、伝熱管(7)に、樹脂製の外周フィン(16)を設け、樹脂の良好な弾性力により飛び石等に対する伝熱管(7)の耐衝撃性を高めている。即ち、図8に示す如く、細径金属管(1)の外周面に、亜鉛メッキ及び銅メッキを施して2層から成る防食メッキ層(2)を設け、その外周面にPA等の樹脂被膜層(3)をコーティングし、その外周面に肉薄金属管(4)から成る伝熱体(5)を設けている。そして、この伝熱体(5)の外周面に、前記樹脂製のL字状の外周フィン(16)を一定間隔を介して螺旋状に巻き回している。このような樹脂製の外周フィン(16)であっても、その広い表面積により放熱特性が良好で、耐衝撃性だけでなく熱交換効率にも優れた伝熱管(7)を得る事ができる。また、外周フィン(16)は、樹脂材中に銅、アルミ、ステンレス等の金属やガラスで形成した粒子や繊維を含有させて形成しても良いし、黒色の樹脂材で形成しても良く、外周フィン(16)の熱伝導性を高めて、より効率的な熱交換を可能とする事ができる。また、この外周フィン(16)の樹脂材に、カーボンナノチューブ、カーボンナノホーン等のカーボンナノファイバーを、5wt%より多く30wt%より少ない含有量で含有させても良い。
【0057】
また、上記第1〜第8実施例では、伝熱体(5)を金属管(4)、帯材(8)、フィン部材(10)、又は線材(13)の何れか一種のみで形成しているが、図9に示す第9実施例では、樹脂被膜層(3)の外周面に金属製の帯材(8)を配設し、更にこの帯材(8)の外周に断面I字状の金属製のフィン部材(10)を巻き回す事により、伝熱体(5)を形成している。このような伝熱体(5)とした場合でも、伝熱管(7)の伝熱面積を増大させる事ができ、伝熱管(7)の放熱特性や吸熱特性を向上させて、熱交換性能に優れる伝熱管(7)を得る事ができる。また、帯材(8)とフィン部材(10)との組み合わせだけでなく、他の異なる実施例として、金属管(4)と帯材(8)又は線材(13)又はフィン部材(10)とを組み合わせたり、帯材(8)と線材(13)とを組み合わせたり、線材(13)とフィン部材(10)とを組み合わせて伝熱体(5)を形成しても良い。
【0058】
【発明の効果】
本発明は上述の如く構成したもので、鋼管、アルミ管、その他の細径金属管の外周面に耐衝撃性や耐水性、耐薬品性等の高い樹脂被膜層を設け、この樹脂被膜層の外周面に熱伝導性に優れた金属製の伝熱体を設けているので、耐食性及び放熱特性或いは吸熱特性の高い伝熱管を得る事ができる。従って、伝熱管の耐久性が高まるとともに、伝熱管の内部を流動する流体と外部を流動する流体との効率的な熱交換を長期に行う事が可能となる。また、細径金属管の外周面に樹脂被膜層を押し出し成形等でコーティングし、この樹脂被膜層の外周面に金属性の伝熱体を設けるだけなので、伝熱管の構造が単純で製造も容易となり、生産性を高める事ができる。
【図面の簡単な説明】
【図1】 本発明の第1実施例の伝熱管の一部拡大断面図で、肉薄金属管で伝熱体を形成したものである。
【図2】 第2実施例の伝熱管の一部拡大断面図で、帯材で伝熱体を形成したものである。
【図3】 第3実施例の伝熱管の一部拡大断面図で、断面L字状のフィン部材で伝熱体を形成したものである。
【図4】 第4実施例の伝熱管の一部拡大断面図で、断面T字状のフィン部材で伝熱体を形成したものである。
【図5】 第5実施例の伝熱管の一部拡大断面図で、断面T字状のフィン部材の表面にピンを突設して乱流化手段を設けたものである。
【図6】 第6実施例の伝熱管の一部拡大断面図で、断面U字状のフィン部材で伝熱体を形成したものである。
【図7】 第7実施例の伝熱管の一部拡大断面図で、断面円形の線材で伝熱体を形成したものである。
【図8】 第8実施例の伝熱管の一部拡大断面図で、肉薄金属管で形成した伝熱体の外周面に樹脂製の外周フィンを螺旋状に巻き回したものである。
【図9】 第9実施例の伝熱管の一部拡大断面図で、金属製の帯材と、この帯材の外周に巻き回した断面I字状の金属製のフィン部材とで伝熱体を形成したものである。
【符号の説明】
1 細径金属管
2 防食メッキ層
3 樹脂被膜層
4 肉薄金属管
5 伝熱体
6 第2防食メッキ層
8 帯材
10 フィン部材
11 ピン
12 貫通孔
13 線材
16 外周フィン[0001]
[Industrial application fields]
The present invention relates to an oil cooling pipe for automobiles and construction machines, an air conditioner for adjusting the temperature and humidity of a living space, and the like, and relates to a heat transfer pipe having corrosion resistance used in a corrosive environment. An object of the present invention is to obtain a heat transfer tube capable of efficient heat exchange with excellent heat dissipation characteristics.
[0002]
[Prior art]
Conventionally, as heat transfer tubes having corrosion resistance as described above, steel pipes subjected to anticorrosion plating such as galvanization and chromate coating, as disclosed in Japanese Patent Application Laid-Open No. 8-18884, and disclosed in Japanese Patent Application Laid-Open No. 10-315295, There is one in which a thermoplastic resin coating layer such as polyamide (PA), polypropylene (PP), polyethylene (PE) or the like is provided on the outer peripheral surface of a thin metal tube such as an aluminum tube by an extrusion molding method. The impact-absorbing power, water resistance, and chemical resistance of this resin coating layer prevent damage to the anti-corrosion plating layer and thin metal pipe due to stepping stones, and prevent oxidation of the thin metal pipe due to mud splashes and chemicals. , Increased the corrosion resistance of the heat transfer tube.
[0003]
[Problems to be solved by the invention]
However, the heat transfer tubes of the prior art as described above have a problem in terms of heat dissipation characteristics because the resin coating layer is formed thick in order to improve impact resistance and corrosion resistance, and circulate inside and outside the heat transfer tubes. It was difficult to efficiently exchange heat between the fluids. Therefore, in order to improve the heat dissipation characteristics, a long flat plate is spirally wound as in the invention described in JP-A-9-42573, the invention described in JP-A-9-136111, and the invention described in JP-A-11-325778. There is one in which a heat transfer tube is formed by winding in a shape and providing a fin member on the outer periphery of a thin metal tube. By this fin member, the heat dissipation characteristic of the heat transfer tube is enhanced, and the heat exchange efficiency between the fluid flowing inside the heat transfer tube and the fluid flowing outside can be improved. However, the anticorrosion plating layer on the surface of the small-diameter metal tube is easily damaged by stepping stones and the like, and there is a problem in corrosion resistance.
[0004]
The present invention is intended to solve the above-mentioned problems, and a thin metal tube is coated with a resin film layer having high impact resistance to enhance corrosion resistance and excellent in thermal conductivity on the outer periphery of the resin film layer. A heat exchanger tube made of metal is provided to improve heat dissipation characteristics and heat absorption characteristics, and a heat transfer tube excellent in heat exchange efficiency between a fluid flowing inside and a fluid flowing outside is obtained. Further, the heat transfer tube having excellent corrosion resistance and heat dissipation characteristics or heat absorption characteristics can be formed at a low cost with a simple structure.
[0005]
[Means for Solving the Problems]
In order to solve the above-mentioned problems, the first invention is a thin metal tube, at least one resin coating layer provided on the outer peripheral surface of the thin metal tube, and the outer periphery of the outermost layer of the resin coating layer. surface Formed with thin metal tube attached in close contact with It consists of a metal heat transfer body.
[0006]
Further, the second invention is a thin metal tube, at least one resin coating layer provided on the outer peripheral surface of the thin metal tube, and an outer peripheral surface of the outermost layer of the resin coating layer. It was made of a metal strip wound in a spiral shape in close contact with It consists of a metal heat transfer body.
[0007]
Further, the third invention is a thin metal tube, at least one resin coating layer provided on the outer peripheral surface of the thin metal tube, and an outer peripheral surface of the outermost layer of the resin coating layer. It was formed with a metal fin member that was closely attached to and wound in a spiral It consists of a metal heat transfer body.
[0008]
Further, the fourth invention is a thin metal tube, at least one resin coating layer provided on the outer peripheral surface of the thin metal tube, and an outer peripheral surface of the outermost layer of the resin coating layer. It was made of a metal wire wound in a spiral shape in close contact with It consists of a metal heat transfer body.
[0009]
The thin metal tube may be provided with at least one anticorrosion plating layer on the outer surface and at least one resin coating layer on the outer peripheral surface of the anticorrosion plating layer.
[0010]
The heat transfer body may be provided with at least one anticorrosion plating layer on the outer surface.
[0011]
The heat transfer body may be formed by spirally winding resin-made outer peripheral fins on the outer peripheral surface.
[0012]
Moreover, the resin coating layer and / or the resin-made outer peripheral fins may contain metal or glass particles and / or fibers having higher thermal conductivity than the resin material.
[0013]
The resin coating layer and / or the resin-made outer peripheral fins may contain carbon nanofibers.
[0014]
Carbon nanofibers may be contained in a content of more than 5 wt% and less than 30 wt%.
[0015]
Further, the fin member and / or the outer peripheral fin may be provided with a turbulent flow means including any one of a pin, a protrusion, a strip-shaped plate material, an unevenness, a through hole, or a combination thereof on the outer peripheral surface.
[0016]
Two resin coating layers may be disposed on the outer peripheral surface of the thin metal tube.
[0017]
[Action]
Since the present invention is configured as described above, the resin coating layer provided on the outer peripheral surface of a small-diameter metal tube such as a steel tube or an aluminum tube is made of PE, PP, PA, etc. by an extrusion method or other methods. Any one kind of resin may be used to form a single layer, or two or more kinds of resins may be used to form a plurality of layers. Even if only one resin coating layer is used, excellent impact resistance can be obtained, and the number of steps for providing the resin coating layer can be reduced.
[0018]
In the case of multiple layers, for example, a PA layer having excellent adhesion to metal is disposed on the outer peripheral surface of a thin metal tube, and a PP layer having excellent water resistance and chemical resistance is provided on the outer peripheral surface of this PA resin coating layer. If two layers are arranged, the corrosion resistance of the heat transfer tube can be further enhanced by the synergistic effect of the characteristics of each resin. Moreover, it is preferable that the resin coating layer made into two layers shall be 100 micrometers-1 mm, the corrosion resistance of a heat exchanger tube will be acquired, and the thermal conductivity of a heat exchanger tube will not be impaired.
[0019]
In addition to the above PA / PP combination, a combination of PA / PA, PP / PP, PA / PE, or the like may be used. In this way, one or more types of resins are selected from resins with excellent properties such as shock absorption, water resistance, and chemical resistance, depending on the usage environment and purpose. By coating with one or more resin coating layers, it is possible to prevent damage due to stepping stones of thin metal tubes and oxidation due to mud splash etc., and improve the corrosion resistance and heat resistance of heat transfer tubes. .
[0020]
And since the metal heat-transfer body is provided in the outer peripheral surface of the said 1 layer or multiple layers of resin film layer, it is compared with the case where only the resin film layer is provided by the metal's outstanding thermal conductivity. It is possible to improve the efficiency of heat exchange with the fluid flowing outside the heat pipe. Moreover, in the prior art, since the resin coating layer was made thick in order to improve the corrosion resistance of the heat transfer tube, the heat dissipation characteristics of the heat transfer tube were poor. However, in the present invention, the metal heat transfer body provided on the outer peripheral surface of the resin coating layer also has impact resistance and promotes the protective power of the thin metal tube by the resin coating layer. The coating layer can be formed thinly, and in the case of heat dissipation, the heat dissipation characteristics of the heat transfer tube are further improved, and in the case of heat absorption, the heat absorption characteristics of the heat transfer tube are further improved to increase the heat exchange efficiency between the fluid flowing inside and outside the heat transfer tube. Can do.
[0021]
In addition, the presence of the resin coating layer having elasticity and flexibility allows the heat transfer body to be fitted to the thin metal tube with high fit, and can be stably and closely disposed. Therefore, the thermal conductivity between the heat transfer body and the resin coating layer is improved, and the heat dissipation characteristics and heat absorption characteristics of the heat transfer pipe are improved, and the vibration of the heat transfer pipe and the flow pressure of the fluid flowing around the outer periphery of the heat transfer body are improved. The durability of the heat transfer body is improved and excellent heat exchange performance can be maintained.
[0022]
In addition, the metal heat transfer body, if a thin metal tube is attached to the outer peripheral surface of the resin coating layer, and the thin metal tube is stretched to be in close contact with the small diameter metal tube through the resin coating layer, The entire outer peripheral surface of the resin coating layer can be covered with metal, and high heat dissipation characteristics or heat absorption characteristics can be obtained, thereby enabling efficient heat exchange.
[0023]
The heat transfer body is formed by spirally winding a metal strip around the outer peripheral surface of the resin coating layer, or spirally winding a metal wire having a circular cross section, an ellipse, a triangle, a quadrilateral, or the like. If it is formed by turning, the operation of providing the heat transfer body can be made easier. Further, the heat transfer body may be a metal fin member having an L-shaped section, a T-shape, a U-shape or the like wound around the outer periphery of the resin coating layer. The contact area is increased, the heat dissipation characteristics and heat absorption characteristics of the heat transfer tube are improved, and efficient heat exchange becomes possible.
[0024]
Moreover, when winding a strip, a fin member, a wire, etc. around the outer peripheral surface of the resin coating layer, the adjacent end portions are brought into close contact with each other without any gap, and the entire outer peripheral surface of the resin coating layer is adhered to the strip, fin member, wire. It may be covered with a belt, or a band material, a fin member, and a wire may be wound around a predetermined interval between adjacent end portions, and a part of the resin coating layer may be exposed to the outside. Also, when winding at regular intervals, if the spacing is wide and the surface area of the heat transfer body is small, it will be difficult to obtain high heat conductivity of the heat transfer tube, so there will be no loss of heat conductivity and stepping stones A strip, a fin member, and a wire are arranged at intervals and angles that can prevent the above.
[0025]
Further, the heat transfer body is formed by, for example, forming a metal strip around the outer peripheral surface of the resin coating layer and further winding a metal fin member around the outer surface of the strip, etc. A plurality of strips, fin members, and wires may be formed in combination, and the heat dissipation characteristics or the heat absorption characteristics can be further improved.
[0026]
In addition, when the heat transfer body is formed of a thin metal tube, a strip, or a wire, a resin outer peripheral fin having a L-shaped section, a T-shape, a U-shape, or the like is spirally formed on the outer peripheral surface of the heat transfer body. If it is wound, the impact resistance of the heat transfer tube against stepping stones can be enhanced by the elasticity of the resin. Further, even if the outer peripheral fin is made of resin, good heat dissipation characteristics and heat absorption characteristics can be obtained due to its large surface area, and the functionality of the heat transfer tube as a heat exchanger can be improved.
[0027]
Further, the metal fin member and / or the resin outer peripheral fin is provided with a turbulence generating means including any one of a pin, a protrusion, a strip-shaped plate material, an unevenness, a through hole, or a combination thereof on the outer peripheral surface. If provided, the surface area of the fin member and the outer peripheral fin can be further increased, and the heat exchange efficiency by the heat transfer tube can be further improved. Moreover, by these turbulent flow generating means, a spiral turbulent flow is generated in the fluid flowing outside the heat transfer tube, and the heat exchange efficiency can be further improved by peeling the boundary layer.
[0028]
In addition, the thin metal pipe can be obtained by providing at least one layer of an anticorrosive plating layer such as sacrificial corrosion on the outer surface and providing at least one resin coating layer on the outer peripheral surface of the anticorrosion plating layer. Further, the anticorrosion plating layer is protected by the resin coating layer, and the corrosion resistance of the heat transfer tube can be improved. Further, the anticorrosion plating layer may have a single layer structure using zinc, tin, tin-zinc alloy, nickel, zinc-nickel alloy, or the like, or a multilayer structure of two or more layers combining these. May be.
[0029]
In addition, in the heat transfer body formed of the above-mentioned thin metal tube, metal strip, metal fin member, metal wire, etc., at least one layer of sacrificial corrosion-resistant anticorrosion plating layer on the outer surface If it is provided, the corrosion resistance of the heat transfer tube can be further enhanced. Moreover, the plating process to the heat transfer body may be performed after providing any one of the heat transfer bodies on the outer peripheral surface of the resin coating layer, or a thin metal tube, a strip material, which has been previously plated. You may provide a fin member, a wire, etc. in the outer peripheral surface of a resin film layer.
[0030]
In addition, the resin coating layer and / or the resin-made outer peripheral fin may be made of resin if it contains particles and / or fibers made of metal or glass such as copper, aluminum, and stainless steel having higher thermal conductivity than the resin material. The heat conductivity of the coating layer and the outer peripheral fin is increased, and a heat transfer tube having excellent heat dissipation characteristics and heat absorption characteristics can be obtained, thereby enabling more efficient heat exchange.
[0031]
In particular, if the resin coating layer and / or the outer peripheral fin made of resin contain carbon nanofibers, the thermal conductivity of the resin material can be improved, and the heat dissipation characteristics or heat absorption characteristics of the heat transfer tube can be improved. It becomes. Moreover, the best heat dissipation characteristic or endothermic characteristic can be obtained if the carbon nanofiber is contained in an amount of more than 5 wt% and less than 30 wt%. If the carbon nanofiber content is 5 wt% or less, the heat transfer effect is not improved, and it is difficult to contain 30 wt% or more in the resin material. There is no big difference. The carbon nanofiber referred to in the present specification is a general term including all carbon materials of carbon nanotubes, carbon nanohorns, and other nano units in the nanotechnology field.
[0032]
【Example】
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Embodiments of the present invention will be described in detail with reference to the drawings. FIG. 1 is a partially enlarged sectional view of a heat transfer tube according to a first embodiment of the present invention. The outer surface of each of the metal tube and the heat transfer body is provided with an anticorrosion plating layer, and the second embodiment shown in FIG. 2 is a heat transfer tube using a metal strip as the heat transfer body. The third embodiment shown is a heat transfer tube using a fin member having an L-shaped cross section as a heat transfer body. The fourth embodiment shown in FIG. 4 is a heat transfer tube using a fin member having a T-shaped cross section as a heat transfer body, and the fifth embodiment shown in FIG. 5 projects a pin on the fin member having a T-shaped cross section. The heat transfer tube provided with turbulent flow means, the sixth embodiment shown in FIG. 6 is a heat transfer tube having a U-shaped fin member as a heat transfer body, and the seventh embodiment shown in FIG. A heat transfer tube having a circular metal wire as a heat transfer body and two resin coating layers. The eighth embodiment shown in FIG. 8 is a heat transfer tube in which a resin-made outer peripheral fin is spirally wound around the outer peripheral surface of a heat transfer body formed of a thin metal tube. In the ninth embodiment shown in FIG. 9, a metal strip is disposed on the outer peripheral surface of the resin coating layer, and a metal fin member having an I-shaped cross section is further wound around the outer peripheral surface of the strip. It is a heat transfer tube that is turned into a heat transfer body.
[0033]
First, the first embodiment shown in FIG. 1 will be described in detail. (1) is a thin metal tube having a relatively thin outer surface with a tube diameter of 30 mm or less, a single wound steel tube having no copper plating, and an outer surface. Double-rolled steel pipe with copper plating, aluminum pipe, etc. are used. Then, the outer surface of the thin metal tube (1) is plated to provide an anticorrosion plating layer (2) such as sacrificial corrosion. The anticorrosion plating layer (2) is made of zinc, tin, tin-zinc. An alloy, nickel, zinc-nickel alloy or the like may be formed in one layer, or nickel is plated on the outer surface of the thin metal tube (1), and a zinc-nickel alloy is plated on the outer peripheral surface of the nickel. A plurality of layers such as a two-layer structure may be used. The formation of a plurality of anticorrosion plating layers (2) may be performed, for example, by the invention described in Japanese Patent No. 2750710, the invention described in Japanese Patent No. 2945555, or the method described in Japanese Patent Application Laid-Open No. 3-47987.
[0034]
Next, the resin coating layer (3) is adhered and coated on the outer peripheral surface of the anticorrosion plating layer (2) as described above using an extrusion molding apparatus or the like. In this embodiment, the resin coating layer (3) is formed of only one layer made of polyamide (PA) such as
[0035]
In addition, by using carbon nanofibers such as carbon nanotubes and carbon nanohorns as fibers to be contained in the resin coating layer (3), the heat dissipation characteristics and the heat absorption characteristics of the resin coating layer (3) can be improved. . Moreover, it is preferable to contain such carbon nanofibers in a content of more than 5 wt% and less than 30 wt%, and a better heat transfer effect can be obtained and the heat transfer tube (7) can be easily produced.
[0036]
A metal heat transfer body (5) is provided on the outer peripheral surface of the resin coating layer (3). In the first embodiment shown in FIG. 1, the outer peripheral surface of the resin coating layer (3) is provided with copper, A thin metal tube (4) made of metal such as aluminum or stainless steel is packaged, and the outer peripheral surface of the thin metal tube (1) through the resin coating layer (3) by the method of extending the thin metal tube (4). A thin metal tube (4) is closely attached to the heat transfer body (5).
[0037]
And the outer peripheral surface of the said heat-transfer body (5) is plated, and the 2nd anti-corrosion plating layer (6) is provided. This second anticorrosion plating layer (6) is also composed of one layer of zinc, tin, tin-zinc alloy, nickel, zinc-nickel alloy, etc., like the anticorrosion plating layer (2) on the outer periphery of the thin metal pipe (1). They may be formed, or a combination of these layers may be formed. By providing the second anticorrosion plating layer (6), it is possible to prevent the heat transfer body (5) from being corroded and to further improve the corrosion resistance of the entire heat transfer tube (7).
[0038]
In the heat transfer tube (7) formed as described above, the thin metal tube (1) and the anticorrosion plating layer (2) are covered and protected with a resin coating layer (3) having shock absorption, water resistance, chemical resistance and the like. As a result, the metal pipe (1) and anti-corrosion plating layer (2) using steel pipes and aluminum pipes are more effective in preventing damage caused by stepping stones and oxidation due to mud splashes, etc., and have excellent corrosion resistance. Can be obtained. Further, in the prior art, the heat radiation characteristic is lowered by providing the resin coating layer (3). However, in the present invention, a metal heat transfer body (5) is provided on the outer peripheral surface of the resin coating layer (3). Therefore, the heat conductivity of the heat transfer tube (7) can be improved.
[0039]
In addition, since the metal heat transfer body (5) is also excellent in impact resistance, the resin coating layer (3) can be formed thinner than before, and the heat dissipation characteristics of the heat transfer tube (7) are improved. Will be further promoted. Therefore, heat exchange between the fluid flowing inside the heat transfer tube (7) and the fluid flowing outside can be efficiently performed via the heat transfer tube (7) having excellent heat radiation characteristics. It is possible to improve the quality of products such as oil cooling pipes of automobiles and construction machinery using (7), air conditioners that adjust the temperature and humidity of residential spaces.
[0040]
In the first embodiment, the anticorrosion plating layer (2) is provided on the outer surface of the thin metal pipe (1), and the second anticorrosion plating layer (6) is provided on the outer surface of the heat transfer body (5). This makes it possible to maintain excellent corrosion resistance even in a severe corrosive environment. However, in the present invention, a resin coating layer (3) is provided on at least the outer peripheral surface of the thin metal pipe (1), and the outer peripheral surface thereof is provided. A structure having a metal heat transfer body (5) may be provided, and the heat transfer tube (7) may be formed without providing the anticorrosion plating layer (2) or the second anticorrosion plating layer (6). Even in such a heat transfer tube (7), a product excellent in corrosion resistance and heat dissipation characteristics can be obtained by the resin coating layer (3) and the heat transfer body (5). In addition to the plating treatment, other surface treatments such as anodizing treatment may be applied to the thin metal tube (1) and the heat transfer body (5).
[0041]
In addition, the surface treatment operations such as plating and anodizing may be incorporated in the manufacturing process of the heat transfer tube (7). However, the small-diameter metal tube (1) or heat transfer body which has been subjected to the surface treatment in advance. The thin metal tube (4) for (5) may be used, and the productivity of the heat transfer tube (7) can be increased by omitting the surface treatment.
[0042]
In the second to seventh embodiments shown in FIGS. 2 to 7, as in the first embodiment, the anticorrosion plating layer (2) and the resin coating layer (3) are formed on the outer surface of the thin metal tube (1). The heat transfer body (5) provided on the outer peripheral surface of the resin coating layer (3) is made of a metal strip (8), a fin member (10), a wire (13), etc., which will be described later. Forming.
[0043]
First, in the second embodiment shown in FIG. 2, a flat plate-like long metal strip (8) is spirally wound around the outer peripheral surface of the resin coating layer (3). The heat transfer body (5) is formed on the outer peripheral surface of 3). Thus, since the work is simply to wind the strip (8), the heat transfer body (5) can be easily installed on the outer peripheral surface of the resin coating layer (3). In FIG. 2, the adjacent ends of the band material (8) are closely attached without any gap, and the entire resin coating layer (3) is covered with the band material (8). (8) may be wound and a part of the resin coating layer (3) may be exposed to the outside, so that the band material (8) can be saved and a simple operation can be performed. Moreover, when winding a strip | belt material (8) by a fixed space | interval, a strip | belt material (8) is arrange | positioned by the space | interval and angle which do not impair the thermal conductivity by a strip | belt material (8), and can prevent a stepping stone.
[0044]
Next, in the third embodiment shown in FIG. 3, a fin member (10) formed by bending a long and smooth metal plate into an L-shaped cross section is spirally formed on the outer peripheral surface of the resin coating layer (3). The heat transfer body (5) is formed by winding.
[0045]
Further, in the fourth embodiment shown in FIG. 4, a fin member (10) having a T-shaped cross section is used, and the smooth surface represented by the T-shaped horizontal bar is brought into contact with the resin coating layer (3) while this resin is being used. A fin member (10) is spirally wound around the outer peripheral surface of the coating layer (3) to form a heat transfer body (5). By forming the heat transfer body (5) with the fin member (10) as in the third and fourth embodiments, the contact area between the fluid flowing outside and the heat transfer body (5) is increased, and heat exchange is performed. Efficiency can be increased.
[0046]
Further, in the fifth embodiment shown in FIG. 5, similarly to the fourth embodiment, the heat transfer body (5) is formed by the fin member (10) having a T-shaped cross section, and both sides of the fin member (10) are further formed. A turbulent flow means for turbulent fluid flowing outside the heat transfer tube (7) is provided on the outer peripheral surface of the fin member (10) so as to project and fix in a direction perpendicular to the surface of the fin member (10). Yes. The pin (11) as the turbulent flow means is fixed in advance to the fin member (10) before being fixed to the outer peripheral surface of the resin coating layer (3), and the fin member (10) to which the pin (11) is fixed. Is wound and fixed around the outer peripheral surface of the resin coating layer (3). Further, as shown in FIG. 5, the pin (11) is fixed to the fin member (10) by opening a through hole (12) in the fin member (10) and inserting the pin (12) through the through hole (12). 11) is fixed to the fin member (10) at regular intervals or randomly by brazing or welding.
[0047]
Thus, by providing the pin (11) on the fin member (10), the surface area of the fin member (10) can be increased, and the heat exchange efficiency with the fluid flowing outside can be improved. Further, by projecting the pin (11) on the smooth outer surface of the fin member (10), a spiral turbulent flow of fluid is generated on both surfaces of the fin member (10), and the fin member (10) is spirally wound. The boundary layer that is likely to be generated between the fin members (10) is peeled off, and the heat exchange efficiency can be further improved by the heat radiation characteristics.
[0048]
In the fifth embodiment, one pin (11) is provided on both sides of the fin member (10) to serve as turbulent flow means. However, as another embodiment, the pin (11 ) Or a plurality of pins (11) on both sides or one side. Moreover, you may provide the appropriate protrusion and unevenness | corrugation of the shape different from a pin (11). Further, even if only the through hole (12) is provided without projecting the pin (11), the fluid can be turbulent. Further, as a different turbulent flow means, a strip-shaped plate material may be fixedly formed on the fin member (10) instead of the pin (11), and the surface area of the fin member (10) is further increased as compared with the pin (11). In addition, a large amount of spiral turbulence of the fluid is generated, and the heat exchange efficiency can be improved by the heat radiation characteristics due to the separation of the boundary layer. Further, it may be a turbulent flow means composed of any one of the pin (11), the through hole (12), the protrusion, the unevenness, a strip-shaped plate material, etc. Means may be formed.
[0049]
Further, even when the fin member (10) for the heat transfer body (5) of the third to fifth embodiments is wound, the adjacent ends of the fin member (10) are brought into close contact with each other so that the resin coating layer (3) A part of the outer peripheral surface of the resin coating layer (3) may be covered with the heat transfer body (5) or with a certain distance between the adjacent ends of the fin member (10). May be exposed to the outside, and in this case, the fin member (10) is wound at an interval and an angle at which stepping stones can be prevented to such an extent that the thermal conductivity of the fin member (10) is not impaired.
[0050]
Next, in the sixth embodiment shown in FIG. 6, a fin member (10) having a U-shaped cross section is placed on the outer peripheral surface of the resin coating layer (3) without impairing the thermal conductivity of the heat transfer body (5). The heat transfer body (5) is formed by spirally winding it at a certain interval to prevent stepping stones. Thus, by making the fin member (10) U-shaped in cross section, the contact area between the fluid and the heat transfer body (5) can be increased compared to the L-shaped or T-shaped fin member (10). Further, the heat exchange efficiency between the heat transfer body (5) and the fluid can be further increased.
[0051]
Further, the fin member (10) having a U-shaped cross section of the sixth embodiment and the fin members (10) having the L-shaped cross section of the third embodiment and the T-shaped cross section of the fourth embodiment are Although the surface of the projecting portion in the radial direction is formed smoothly, the surface may be formed in a wavy shape to increase the surface area of the fin member (10) and further increase the heat exchange efficiency.
[0052]
Further, in the seventh embodiment shown in FIG. 7, an anticorrosion plating layer (2) consisting of two layers of galvanization and chromate film is formed on the outer surface of a thin metal tube (1) using an aluminum tube. A PA12 first layer (14) having excellent adhesion to metal is provided on the outer peripheral surface of the anticorrosion plating layer (2), and the outer peripheral surface of the first layer (14) made of PA12 is water and chemical resistant. A second layer (15) made of PP having excellent properties is coated to form a resin film layer (3) having a two-layer structure. Then, by setting the thickness of the two resin coating layers (3) to 100 μm to 1 mm, the water resistance, chemical resistance, and impact resistance are high and the thermal conductivity is not impaired. . In addition to the above PA / PP, PA / PA, PP / PP, PA / PE, and the like can be given as examples of the combination of the resin having the two-layer structure Be . Moreover, it is good also as three or more resin film layers (3).
[0053]
Then, a resin wire layer is formed by spirally winding a metal wire (13) having a circular cross section around the outer peripheral surface of the resin layer (3) composed of the first layer (14) and the second layer (15). The heat transfer body (5) is formed on the outer peripheral surface of (3). Even when the wire (13) is used in this manner, the heat transfer body (5) can be easily installed on the outer peripheral surface of the resin coating layer (3). Moreover, as shown in FIG. 7, the resin film layer (3) may be entirely covered with the wire (13) by adhering the adjacent outer peripheral surface of the wire (13) without a gap, or the heat generated by the wire (13). The wire (13) may be wound around a certain distance so as to prevent stepping stones without impairing conductivity, and a part of the resin coating layer (3) may be exposed to the outside. Savings and more simple work. Further, although the wire rod (13) having a circular cross section is used in this embodiment, a cross section having an arbitrary shape other than a circle such as an ellipse, a triangle, a quadrangle, or the like may be used.
[0054]
Further, as in the seventh embodiment, the resin coating layer (3) composed of the first layer (14) and the second layer (15) or the resin coating layer (3) having three or more layers is formed by only one layer. You may apply to the resin film layer (3) of the 1st-6th Example.
[0055]
In addition, the strip material (8), the fin member (10), and the wire material (13) used in the second to seventh embodiments are plated or anodized after being placed on the outer peripheral surface of the resin coating layer (3). Surface treatment such as treatment may be performed, or the strip (8), fin member (10), wire (13) that has been subjected to the surface treatment may be used, and the heat resistance of the heat transfer tube (7) may be increased. It can be further increased. Further, the strip (8), the fin member (10), and the wire (13) may be wound continuously in a long length, or may be a short or ring-shaped strip (8) or fin member (10). ), The wire (13) may be provided on the outer peripheral surface of the resin coating layer (3) at a certain interval so as to prevent stepping stones without bringing the wire (13) into close contact with each other or without impairing the thermal conductivity of the heat transfer body (5). good. Further, a fin member (10) having an L-shaped cross section of the third embodiment and a fin member (10) having a U-shaped cross section of the sixth embodiment are provided with a pin (11), a protrusion, an unevenness, and the like as in the fifth embodiment. You may provide the turbulent flow means which consists of any 1 type or a combination of multiple types, such as a through-hole (12).
[0056]
In the third to seventh embodiments, the metal fin member (10) is used as the heat transfer body (5). However, in the eighth embodiment shown in FIG. 8, the heat transfer body (5) is used. Separately from this, the heat transfer tube (7) is provided with a resin outer peripheral fin (16), and the impact resistance of the heat transfer tube (7) against stepping stones and the like is enhanced by the good elastic force of the resin. That is, as shown in FIG. 8, the outer peripheral surface of the thin metal pipe (1) is galvanized and copper-plated to provide a two-layer anticorrosive plating layer (2), and the outer peripheral surface is coated with a resin coating such as PA. The layer (3) is coated, and a heat transfer body (5) composed of a thin metal tube (4) is provided on the outer peripheral surface thereof. The resin-made L-shaped outer peripheral fins (16) are spirally wound around the outer peripheral surface of the heat transfer body (5) at regular intervals. Even with such a resin-made outer peripheral fin (16), it is possible to obtain a heat transfer tube (7) which has good heat radiation characteristics due to its large surface area and is excellent not only in impact resistance but also in heat exchange efficiency. The outer peripheral fin (16) may be formed by containing particles or fibers formed of a metal such as copper, aluminum, stainless steel, or glass in the resin material, or may be formed of a black resin material. It is possible to increase the thermal conductivity of the outer peripheral fins (16) and enable more efficient heat exchange. Further, the resin material of the outer peripheral fin (16) may contain carbon nanofibers such as carbon nanotubes and carbon nanohorns in a content of more than 5 wt% and less than 30 wt%.
[0057]
In the first to eighth embodiments, the heat transfer body (5) is formed of only one of the metal pipe (4), the strip (8), the fin member (10), and the wire (13). However, in the ninth embodiment shown in FIG. 9, a metal strip (8) is disposed on the outer peripheral surface of the resin coating layer (3), and the cross section is I-shaped on the outer periphery of the strip (8). A heat transfer body (5) is formed by winding a metal-shaped fin member (10). Even in the case of such a heat transfer body (5), the heat transfer area of the heat transfer tube (7) can be increased, and the heat dissipation characteristics and heat absorption characteristics of the heat transfer tube (7) can be improved to improve the heat exchange performance. An excellent heat transfer tube (7) can be obtained. In addition to the combination of the strip (8) and the fin member (10), as another different embodiment, the metal pipe (4) and the strip (8) or the wire (13) or the fin member (10) The heat transfer body (5) may be formed by combining the strips (8) and the wire (13), or by combining the wire (13) and the fin member (10).
[0058]
【The invention's effect】
The present invention is configured as described above, and a resin coating layer having high impact resistance, water resistance, chemical resistance and the like is provided on the outer peripheral surface of a steel pipe, an aluminum pipe, and other small-diameter metal pipes. Since the metal heat transfer body having excellent heat conductivity is provided on the outer peripheral surface, a heat transfer tube having high corrosion resistance and heat dissipation characteristics or heat absorption characteristics can be obtained. Therefore, the durability of the heat transfer tube is enhanced, and efficient heat exchange between the fluid flowing inside the heat transfer tube and the fluid flowing outside can be performed for a long time. In addition, a resin coating layer is coated on the outer peripheral surface of a thin metal tube by extrusion molding, and a metallic heat transfer body is provided on the outer peripheral surface of the resin coating layer, so the structure of the heat transfer tube is simple and easy to manufacture. This can improve productivity.
[Brief description of the drawings]
FIG. 1 is a partially enlarged sectional view of a heat transfer tube according to a first embodiment of the present invention, in which a heat transfer body is formed by a thin metal tube.
FIG. 2 is a partially enlarged cross-sectional view of a heat transfer tube according to a second embodiment, in which a heat transfer body is formed of a band material.
FIG. 3 is a partially enlarged cross-sectional view of a heat transfer tube of a third embodiment, in which a heat transfer body is formed by a fin member having an L-shaped cross section.
FIG. 4 is a partially enlarged cross-sectional view of a heat transfer tube of a fourth embodiment, in which a heat transfer body is formed by a fin member having a T-shaped cross section.
FIG. 5 is a partially enlarged cross-sectional view of a heat transfer tube according to a fifth embodiment, in which a turbulent means is provided by projecting a pin on the surface of a fin member having a T-shaped cross section.
FIG. 6 is a partially enlarged cross-sectional view of a heat transfer tube according to a sixth embodiment, in which a heat transfer body is formed by a fin member having a U-shaped cross section.
FIG. 7 is a partially enlarged cross-sectional view of a heat transfer tube of a seventh embodiment, in which a heat transfer body is formed by a wire having a circular cross section.
FIG. 8 is a partially enlarged cross-sectional view of a heat transfer tube of an eighth embodiment, in which resin-made outer peripheral fins are spirally wound around the outer peripheral surface of a heat transfer body formed of a thin metal tube.
FIG. 9 is a partially enlarged cross-sectional view of a heat transfer tube of a ninth embodiment. Is formed.
[Explanation of symbols]
1 Small metal pipe
2 Anticorrosion plating layer
3 Resin coating layer
4 Thin metal pipe
5 Heat transfer body
6 Second anticorrosion plating layer
8 Band material
10 Fin member
11 pins
12 Through hole
13 Wire
16 peripheral fins
Claims (12)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003195667A JP4336534B2 (en) | 2002-07-19 | 2003-07-11 | Heat transfer tube with corrosion resistance |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002210621 | 2002-07-19 | ||
| JP2003195667A JP4336534B2 (en) | 2002-07-19 | 2003-07-11 | Heat transfer tube with corrosion resistance |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2004101168A JP2004101168A (en) | 2004-04-02 |
| JP2004101168A5 JP2004101168A5 (en) | 2006-08-24 |
| JP4336534B2 true JP4336534B2 (en) | 2009-09-30 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003195667A Expired - Fee Related JP4336534B2 (en) | 2002-07-19 | 2003-07-11 | Heat transfer tube with corrosion resistance |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4336534B2 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4724526B2 (en) * | 2005-10-19 | 2011-07-13 | 昭和電工株式会社 | Radiant panel suspension device and radiation cooling / heating unit |
| CN101799252B (en) * | 2010-03-24 | 2011-08-24 | 北京化工大学 | An enhanced heat transfer tube |
| JP6405914B2 (en) * | 2014-11-11 | 2018-10-17 | 株式会社デンソー | HEAT EXCHANGE DEVICE AND HEAT EXCHANGE DEVICE MANUFACTURING METHOD |
| JP7718798B2 (en) * | 2019-10-09 | 2025-08-05 | 株式会社巴川コーポレーション | Heat transfer body, heat exchange unit, and heat transfer body mounting method |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5919184Y2 (en) * | 1980-04-15 | 1984-06-02 | 臼井国際産業株式会社 | Thick-walled small-diameter polymeric metal tubing |
| JPS57190287U (en) * | 1981-05-29 | 1982-12-02 | ||
| JPH01151080U (en) * | 1988-04-05 | 1989-10-18 | ||
| JPH03121365U (en) * | 1990-03-27 | 1991-12-12 | ||
| JP4237381B2 (en) * | 2000-06-14 | 2009-03-11 | 日機装株式会社 | Vapor growth carbon fiber filling and method for producing vapor growth carbon fiber filling |
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2003
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| JP2004101168A (en) | 2004-04-02 |
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