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JP4354352B2 - Stabilizer for milk beverage and its application - Google Patents
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JP4354352B2 - Stabilizer for milk beverage and its application - Google Patents

Stabilizer for milk beverage and its application Download PDF

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JP4354352B2
JP4354352B2 JP2004202037A JP2004202037A JP4354352B2 JP 4354352 B2 JP4354352 B2 JP 4354352B2 JP 2004202037 A JP2004202037 A JP 2004202037A JP 2004202037 A JP2004202037 A JP 2004202037A JP 4354352 B2 JP4354352 B2 JP 4354352B2
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milk
cellulose
acid ester
fatty acid
uht
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誠治 笹田
三希 石橋
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San Ei Gen FFI Inc
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Description

本発明は、UHT殺菌により製造する常温流通可能な乳飲料に関する。更には、常温流通可能な乳飲料を製造する際、UHT殺菌機にて殺菌した場合のプレートへの乳飲料の焦げ付きを抑制する方法に関するものである。   The present invention relates to a milk beverage that is produced by UHT sterilization and that can be distributed at room temperature. Furthermore, when manufacturing the milk beverage which can distribute | circulate at normal temperature, it is related with the method of suppressing the burning of the milk beverage to a plate at the time of sterilizing with a UHT sterilizer.

従来、ココアや抹茶などの不溶性粉末を乳飲料中に分散するために、セルロース複合体、微結晶セルロースなどのセルロースを使用することは知られており、また、これら乳飲料に乳化剤を使用することやUHT殺菌により製造できることは知られている(特許文献1,特許文献2)。   Conventionally, it has been known to use cellulose such as cellulose composites and microcrystalline cellulose to disperse insoluble powders such as cocoa and matcha in milk beverages, and use emulsifiers in these milk beverages. It is known that it can be produced by UHT sterilization (Patent Document 1, Patent Document 2).

しかし、これらのUHT殺菌による製法は、140℃2秒間(特許文献1 実験例〔0011〕等参照)や、120℃10秒間(特許文献2 実施例〔0033〕等参照)など、チルド(冷蔵)流通のための殺菌条件であり、常温流通可能とするために殺菌強度を強くすると、UHT殺菌機のプレートへ乳飲料が焦げ付き、連続運転時間が制限され製造効率が悪化することが問題となっていた。   However, these UHT sterilization methods include chilled (refrigerated) such as 140 ° C. for 2 seconds (see Experimental Example [0011] of Patent Document 1), 120 ° C. for 10 seconds (see Example [0033] of Patent Document 2). It is a sterilization condition for distribution, and if the sterilization strength is increased so that it can be distributed at room temperature, the milk beverage is burned on the plate of the UHT sterilizer, the continuous operation time is limited, and the production efficiency deteriorates. It was.

更には、密封容器入りコーヒー飲料にもセルロース複合体などを添加することが検討されている。例えば、コーヒー豆由来の可溶性固形分を多量に含む密封容器入りコーヒー飲料であって、結晶セルロースやカルボキシメチルセルロース(CMC)などの繊維素系粘質を添加して、コーヒー成分に由来する沈澱の発生を防止すること(特許文献3)、食品用乳化剤及びセルロース複合体を含有することを特徴とする乳成分入りコーヒー飲料(特許文献4)、コーヒー抽出液に、生クリーム又はバターと、乳化剤と、微結晶セルロースとを添加し、pHを5.0〜6.5に調整して加熱殺菌することを特徴とするコーヒーの製造法(特許文献5)などがある。しかし、これら飲料は、120〜125℃で20〜25分程度のレトルト殺菌により製造しており、UHT殺菌により製造されたものではなく、前記の乳飲料と同じ課題が生じていた。   Furthermore, it has been studied to add a cellulose composite or the like to a sealed coffee beverage. For example, it is a coffee beverage in a sealed container containing a large amount of soluble solids derived from coffee beans, and the generation of precipitates derived from coffee components by adding fiber-based mucilage such as crystalline cellulose and carboxymethylcellulose (CMC) (Patent Document 3), a coffee beverage containing a milk ingredient characterized by containing a food emulsifier and a cellulose complex (Patent Document 4), a coffee extract, fresh cream or butter, an emulsifier, There is a coffee production method (Patent Document 5) characterized by adding microcrystalline cellulose, adjusting the pH to 5.0 to 6.5 and sterilizing by heating. However, these beverages are manufactured by retort sterilization at 120 to 125 ° C. for about 20 to 25 minutes, and are not manufactured by UHT sterilization.

特開平6−169737号公報JP-A-6-169737 特開2000−312572号公報JP 2000-31572 A 特開平6−205641号公報JP-A-6-205641 特開平6−335348号公報JP-A-6-335348 特開平6−245703号公報JP-A-6-245703

本発明は、上記の実情に鑑みなされたものであり、常温流通可能な乳飲料をUHT殺菌により製造する場合、UHT殺菌機のプレートに乳飲料が焦げ付くことなく製造できる方法を提供することを目的とする。   The present invention has been made in view of the above circumstances, and an object of the present invention is to provide a method capable of producing a milk beverage without burning on the plate of the UHT sterilizer when producing a milk beverage that can be distributed at room temperature by UHT sterilization. And

本発明者らは、上記課題を解決するために鋭意研究を行った結果、セルロースを含む乳飲料に、2種類以上の乳化剤を組み合わせて含むことで、常温流通可能な殺菌条件でUHT殺菌を行っても、UHT殺菌機のプレートへの焦げ付きを有意に抑制し、風味も良好な乳飲料を提供できることを見出した。   As a result of diligent research to solve the above-mentioned problems, the present inventors have performed UHT sterilization under sterilization conditions that allow circulation at room temperature by including a combination of two or more emulsifiers in a milk beverage containing cellulose. However, the present inventors have found that it is possible to provide a milk beverage that significantly suppresses scorching on the plate of the UHT sterilizer and also has a good flavor.

更に、2種類以上の乳化剤として、グリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、ユッカ抽出物、サポニン、レシチン、ポリソルベート、ステアロイル乳酸ナトリウム、ステアロイル乳酸カルシウムから選ばれる2種以上が好ましいことが判った。   Furthermore, as two or more kinds of emulsifiers, two or more kinds selected from glycerin fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, propylene glycol fatty acid ester, yucca extract, saponin, lecithin, polysorbate, sodium stearoyl lactate, calcium stearoyl lactate Was found to be preferable.

更に、乳飲料中にココアや抹茶などの不溶性粉末を含有しても、前記の通りUHT殺菌機のプレートへの焦げ付きを有意に抑制し、不溶性粉末を乳飲料中に良好に分散できることを見いだした。   Furthermore, it was found that even when insoluble powders such as cocoa and matcha were contained in the milk beverage, the burning of the UHT sterilizer was significantly suppressed, and the insoluble powder could be dispersed well in the milk beverage as described above. .

尚、本発明の常温流通可能な乳飲料には、下記の態様が含まれる。
項1.セルロース及び2種類以上の乳化剤を組み合わせて含むことを特徴とする、常温流通可能な殺菌条件でUHT殺菌を行うための乳飲料用安定剤。
項2.乳化剤が、グリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、ユッカ抽出物、サポニン、レシチン、ポリソルベート、ステアロイル乳酸ナトリウム及びステアロイル乳酸カルシウムから選ばれる2種以上である、項1に記載の乳飲料用安定剤。
項3.項1又は2に記載の、常温流通可能な殺菌条件でUHT殺菌された乳飲料。
項4.更に、不溶性粉末を含有する項3に記載の乳飲料。
項5.セルロースを含む乳飲料において、2種類以上の乳化剤を組み合わせて含有することによる、常温流通可能な殺菌条件でUHT殺菌を行う場合のUHT殺菌機プレートへの焦げ付きを抑制する方法。
In addition, the following aspect is contained in the milk drink which can distribute | circulate at normal temperature of this invention.
Item 1. A stabilizer for milk beverages for performing UHT sterilization under sterilization conditions capable of circulating at normal temperature, comprising cellulose and a combination of two or more emulsifiers.
Item 2. Item 1. The emulsifier is two or more selected from glycerin fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, propylene glycol fatty acid ester, yucca extract, saponin, lecithin, polysorbate, sodium stearoyl lactate and calcium stearoyl lactate. The stabilizer for milk drinks as described.
Item 3. Item 3. A milk beverage that has been UHT sterilized under sterilization conditions that allow circulation at room temperature.
Item 4. Item 4. The milk beverage according to Item 3, further comprising an insoluble powder.
Item 5. A method for suppressing scorching on a UHT sterilizer plate when UHT sterilization is performed under sterilization conditions that allow circulation at room temperature by containing two or more types of emulsifiers in combination in a milk beverage containing cellulose.

本発明により、常温流通可能な乳飲料の製造方法において、UHT殺菌により製造する場合の、UHT殺菌機プレートへの焦げ付きを有意に抑制できる。   By this invention, in the manufacturing method of the milk beverage which can distribute | circulate at normal temperature, the burning to a UHT sterilizer plate at the time of manufacturing by UHT sterilization can be suppressed significantly.

本発明の乳飲料用安定剤は、セルロース及び2種類以上の乳化剤を組み合わせて含むことを特徴とする。   The stabilizer for milk drinks of this invention is characterized by including a combination of cellulose and two or more types of emulsifiers.

本発明におけるセルロースとは、木材パルプ、精製リンター、再生セルロース、穀物もしくは果実由来の食物繊維等のセルロース系素材、微生物由来のセルロースなどで、セルロース、結晶セルロース、微結晶セルロース、セルロース複合体、発酵セルロースとよばれるものも含み、食品、医薬品、化粧品をはじめ幅広い分野で使用されているものであれば良い。形状は液体、ペースト、粉末等何れの形状のものでもよい。具体的には、セルロースと親水性高分子とからなるセルロース複合体もしくは発酵セルロースが効果の上から好ましい。また、親水性高分子の異なるセルロース複合体同士の併用や水分散後の平均粒子径が異なるセルロース複合体同士の併用でもよい。   The cellulose in the present invention is a cellulose-based material such as wood pulp, refined linter, regenerated cellulose, cereal or fruit-derived dietary fiber, cellulose derived from microorganisms, cellulose, crystalline cellulose, microcrystalline cellulose, cellulose composite, fermentation What is called cellulose is sufficient, and what is used in a wide field including foods, medicines, and cosmetics may be used. The shape may be any shape such as liquid, paste, powder. Specifically, a cellulose composite composed of cellulose and a hydrophilic polymer or fermented cellulose is preferable in view of the effect. Moreover, the combined use of the cellulose composites from which hydrophilic polymer differs, and the combined use of the cellulose composites from which the average particle diameter after water dispersion differs may be sufficient.

セルロースの添加量としては、乳飲料に対して、0.1〜0.6重量%、より好ましくは、0.3〜0.5重量%が望ましい。0.1重量%よりも少ないと充分な効果を得ることができず、0.6重量%より多くしても更なる効果が望めないためである。   As addition amount of a cellulose, 0.1 to 0.6 weight% with respect to milk drink, More preferably, 0.3 to 0.5 weight% is desirable. If the amount is less than 0.1% by weight, a sufficient effect cannot be obtained, and if it exceeds 0.6% by weight, no further effect can be expected.

また、本発明では2種類以上の乳化剤を使用することを特徴とする。本発明で使用する乳化剤は、乳飲料に一般的に用いられている乳化剤であれば良い。具体的には、グリセリン脂肪酸エステル(モノグリセリン脂肪酸エステル、ジグリセリン脂肪酸エステル、有機酸モノグリセライド、ポリグリセリン脂肪酸エステル、ポリグリセリン縮合リシノレイン酸エステル)、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、ユッカ抽出物、サポニン、レシチン、ポリソルベート、ステアロイル乳酸ナトリウム、ステアロイル乳酸カルシウム等を挙げることができ、これらの2種以上の乳化剤を本発明の乳化剤として使用することが出来る。   In the present invention, two or more types of emulsifiers are used. The emulsifier used in the present invention may be any emulsifier generally used in milk beverages. Specifically, glycerin fatty acid ester (monoglycerin fatty acid ester, diglycerin fatty acid ester, organic acid monoglyceride, polyglycerin fatty acid ester, polyglycerin condensed ricinoleic acid ester), sucrose fatty acid ester, sorbitan fatty acid ester, propylene glycol fatty acid ester, Yucca extract, saponin, lecithin, polysorbate, sodium stearoyl lactate, calcium stearoyl lactate and the like can be mentioned, and two or more of these emulsifiers can be used as the emulsifier of the present invention.

これらの乳化剤の中でも、その効果の点より、特に、ショ糖脂肪酸エステル、グリセリン脂肪酸エステル及びプロピレングリコール脂肪酸エステルから選ばれる2種以上を使用するのが望ましく、更に好ましくは、ショ糖脂肪酸エステル、グリセリン脂肪酸エステル及びプロピレングリコール脂肪酸エステルの3種を併用するのが好ましい。
本発明で使用する2種類以上の乳化剤の添加量としては、用いる乳化剤の種類により一概には規定することが出来ないが、乳飲料に対して、乳化剤の合計量として、0.001〜0.2重量%、好ましくは、0.01〜0.1重量%、更に好ましくは、0.02〜0.07重量%である。0.001重量%よりも少ないと充分な効果を得ることができず、0.2重量%より多くしても更なる効果が望めないためである。更に、本発明で使用する乳化剤は一剤化してもよいし、別々に添加しても良い。
Among these emulsifiers, it is desirable to use two or more kinds selected from sucrose fatty acid ester, glycerin fatty acid ester and propylene glycol fatty acid ester, more preferably sucrose fatty acid ester and glycerin, from the viewpoint of the effect. It is preferable to use three types of fatty acid ester and propylene glycol fatty acid ester in combination.
The amount of the two or more emulsifiers used in the present invention cannot be generally defined depending on the type of the emulsifier used, but the total amount of the emulsifier is 0.001 to 0.00. It is 2% by weight, preferably 0.01 to 0.1% by weight, and more preferably 0.02 to 0.07% by weight. If the amount is less than 0.001% by weight, a sufficient effect cannot be obtained, and if the amount is more than 0.2% by weight, no further effect can be expected. Furthermore, the emulsifier used in the present invention may be made into one agent or may be added separately.

本発明では常温流通可能とするためにUHT殺菌を行うが、本発明で行う殺菌条件について説明する。一般に、UHT(超高温;ultra high temperature)殺菌とは超高温殺菌のことであり、120℃以上、120〜150℃程度の高温温度で行う殺菌を指している。本発明では、このUHT殺菌で殺菌を行い、UHT殺菌機プレートを使用する。本発明で使用するUHT殺菌機プレートは、UHT殺菌機の熱交換部に使用されている波型あるいは半球凹凸をもつプレートであればよく、食品分野で使用されているものであれば良い。   In the present invention, UHT sterilization is performed in order to allow normal temperature distribution, but the sterilization conditions performed in the present invention will be described. In general, UHT (ultra high temperature) sterilization is ultra high temperature sterilization, and refers to sterilization performed at a high temperature of 120 ° C. or higher and about 120 to 150 ° C. In this invention, it sterilizes by this UHT sterilization and uses a UHT sterilizer plate. The UHT sterilizer plate used in the present invention may be a corrugated or hemispherical uneven plate used in the heat exchange part of the UHT sterilizer, and may be any plate used in the food field.

また、UHT殺菌の殺菌方法として、一般に、間接加熱方法と直接加熱方法がある。間接加熱方法は、プレート式熱交換、チューブラー式熱交換、かき取り式熱交換などがあり、直接加熱方法には、製品のなかに加圧蒸気を吹き込む方式(injection type)と蒸気の充満した容器のなかに製品を噴射する方式(infusion type)がある。本発明では間接加熱方式で行うのが好ましく、UHT殺菌機プレートは間接加熱方法のプレート式熱交換に使用されるものを使用するのが好ましい。   Further, as a sterilization method for UHT sterilization, there are generally an indirect heating method and a direct heating method. Indirect heating methods include plate heat exchange, tubular heat exchange, scraping heat exchange, etc. Direct heating methods include a method of blowing pressurized steam into the product (injection type) and steam filling. There is an infusion type that injects a product into a container. In this invention, it is preferable to carry out by an indirect heating system, and it is preferable to use what is used for the plate-type heat exchange of an indirect heating method as a UHT sterilizer plate.

更に、本発明では常温流通可能とするために、殺菌条件として、殺菌温度が140℃ならば30〜60秒間の殺菌を行うのが好ましい。   Further, in the present invention, it is preferable to perform sterilization for 30 to 60 seconds as long as the sterilization temperature is 140 ° C. in order to allow normal temperature circulation.

なお、本発明の乳飲料用安定剤には、前記に加えて、増粘多糖類、カゼインナトリウムから選ばれる1種以上の化合物を加えることが好ましい。   In addition to the above, it is preferable to add one or more compounds selected from thickening polysaccharides and sodium caseinate to the stabilizer for milk beverages of the present invention.

本発明で使用する増粘多糖類は、乳飲料に一般的に用いられている増粘多糖類であればよい。具体的には、カラギナン(イオタ、ラムダ、カッパ)、キサンタンガム、アラビアガム、グアーガム、ローカストビーンガム、タラガム、ジェランガム、カルボキシメチルセルロースナトリウム、水溶性大豆多糖類等を挙げることができ、これらから選ばれる1種又は2種以上の増粘多糖類を本発明の増粘多糖類として使用することが出来る。これらの増粘多糖類の中でも効果の点より、特に、イオタカラギナン又はジェランガムが望ましい。増粘多糖類の添加量としては、用いる増粘多糖類の種類により一概には規定することが出来ないが、一般的には、乳飲料に対して、0.001〜0.06重量%が望ましい。0.001重量%よりも少ないと充分な効果を得ることが出来ず、0.06重量%より多くしても乳飲料の調製における作業効率が悪くなるためである。   The thickening polysaccharide used in the present invention may be any thickening polysaccharide generally used in milk beverages. Specific examples include carrageenan (iota, lambda, kappa), xanthan gum, gum arabic, guar gum, locust bean gum, tara gum, gellan gum, sodium carboxymethylcellulose, water-soluble soybean polysaccharide, and the like. Species or two or more thickening polysaccharides can be used as the thickening polysaccharide of the present invention. Among these thickening polysaccharides, iota carrageenan or gellan gum is particularly desirable from the viewpoint of effect. The amount of thickening polysaccharide that can be unconditionally defined by the type of thickening polysaccharide to be used is generally 0.001 to 0.06% by weight based on the milk beverage. desirable. This is because if the amount is less than 0.001% by weight, a sufficient effect cannot be obtained, and if the amount is more than 0.06% by weight, the working efficiency in the preparation of the milk beverage is deteriorated.

本発明で使用するカゼインナトリウムは、タンパク質系の水溶性高分子で、脱脂乳に酸を加えて沈殿して得られたカゼインを水酸化ナトリウム、もしくは炭酸水素ナトリウムと反応させて製造したものである。カゼインナトリウムの添加量としては、乳飲料に対して0.005〜0.4重量%が望ましい。0.005重量%よりも少ないと充分な効果を得ることができず、0.4重量%より多くしても更なる効果が望めないためである。   The casein sodium used in the present invention is a protein-based water-soluble polymer, which is produced by reacting casein obtained by adding acid to skim milk and reacting with sodium hydroxide or sodium bicarbonate. . The amount of sodium caseinate added is preferably 0.005 to 0.4% by weight based on the milk beverage. If the amount is less than 0.005% by weight, a sufficient effect cannot be obtained, and if the amount is more than 0.4% by weight, no further effect can be expected.

なお、本発明の乳飲料用安定剤は、セルロース、前記2種類以上の乳化剤、及び必要に応じて増粘多糖類、カゼインナトリウムを一剤化して乳飲料に添加することも可能である。その形状として、粉末状、フレーク状、粒状、ペースト状、液状等いずれの形態でも用いることが出来る。一剤化製剤の製造方法としては、従来公知の方法をとることができる。例えば、セルロース及び乳化剤とその他の増粘多糖類やカゼインナトリウムを粉体混合したり、セルロース及び乳化剤とその他の増粘多糖類、カゼインナトリウムを水に撹拌分散させたり、ホモゲナイズ分散させたりすることにより調製することができる。   In addition, the stabilizer for milk drinks of this invention can also make cellulose, the said 2 or more types of emulsifier, thickening polysaccharide, and casein sodium into one agent, and can add it to milk drinks. The shape can be any form such as powder, flake, granule, paste, and liquid. A conventionally known method can be used as a method for producing a single preparation. For example, by mixing powders of cellulose and emulsifiers with other thickening polysaccharides and sodium caseinate, or by stirring and dispersing cellulose and emulsifiers with other thickening polysaccharides and sodium caseinate in water, or by homogenizing dispersion Can be prepared.

本発明の乳飲料用安定剤は、その効果を妨げない範囲において、クエン酸、クエン酸ナトリウム、クエン酸カリウム、コハク酸、コハク酸ナトリウム、乳酸、乳酸ナトリウム、塩酸、塩化ナトリウム、アスコルビン酸ナトリウム、エリソルビン酸ナトリウム、グルコン酸、グルコン酸ナトリウム、グルコン酸カリウム、フィチン酸等の有機酸、無機酸及び/又はその塩類、ショ糖、果糖、ぶどう糖、麦芽糖、デンプン糖化物、還元デンプン水飴、デキストリン、サイクロデキストリン、トレハロース等の糖類、エリスリトール、キシリトール、ソルビトール、マンニトール等の糖アルコール類、スクラロース、ステビア、アスパルテーム、アセスルファムK、ソーマチン等の高甘味度甘味料類等を添加することができる。   The stabilizer for milk drinks of the present invention is within the range not hindering its effect, citric acid, sodium citrate, potassium citrate, succinic acid, sodium succinate, lactic acid, sodium lactate, hydrochloric acid, sodium chloride, sodium ascorbate, Organic acids such as sodium erythorbate, gluconic acid, sodium gluconate, potassium gluconate, phytic acid, inorganic acids and / or their salts, sucrose, fructose, glucose, maltose, starch saccharified product, reduced starch syrup, dextrin, cyclo Sugars such as dextrin and trehalose, sugar alcohols such as erythritol, xylitol, sorbitol and mannitol, high-intensity sweeteners such as sucralose, stevia, aspartame, acesulfame K and thaumatin can be added.

更に、本発明でいう乳飲料とは、缶、瓶、ペットボトル、紙パック、ラミネートパック等の密封容器に充填されている乳飲料であれば良く、密封状態で流通、販売されるものである。また、常温で販売されるものであっても、ホットベンダーで販売されるものであっても、チルド流通されるものであっても良いが、常温流通可能とするための殺菌が施されたものである。   Furthermore, the milk beverage as used in the present invention may be a milk beverage filled in a sealed container such as a can, a bottle, a plastic bottle, a paper pack, or a laminate pack, and is distributed and sold in a sealed state. . In addition, it may be sold at room temperature, sold by a hot vendor, or chilled, but it has been sterilized so that it can be distributed at room temperature. It is.

一般に、乳飲料とは、乳及び乳製品の成分規格等に関する省令((昭和二十六年十二月二十七日)(厚生省令第五十二号);乳等省令)等により生乳、牛乳もしくは特別牛乳又はこれらを原料とした食品を加工し、または主要原料とした飲料と定められているが、本発明の乳飲料とは、牛乳、脱脂粉乳、全脂粉乳、濃縮乳、生クリーム、練乳等の乳成分が含有されている飲料であればよい。中でも、牛乳由来の乳成分を含有する乳入り飲料においては、UHTプレートへの焦げ付き抑制効果が高く、また風味も良好なため、特に望ましい。   In general, dairy drinks refer to raw milk according to the Ministerial Ordinance (December 27, 1951) (Ministry of Health and Welfare No. 52); Milk or special milk or foods made from these are processed or drinks made from the main ingredients, but the milk drinks of the present invention are milk, skim milk powder, whole milk powder, concentrated milk, fresh cream Any beverage containing milk components such as condensed milk may be used. Among these, milk-containing beverages containing milk components derived from milk are particularly desirable because they have a high effect of suppressing burning on the UHT plate and have a good flavor.

本発明の乳飲料の具体例としては、ミルク入りココア、抹茶ミルク、カルシウム強化乳飲料や、ミルク入りコーヒー、ミルク入り茶類、ミルクセーキ、ミルクシェイク、酸乳飲料、イチゴミルク等が挙げられる。   Specific examples of the milk drink of the present invention include cocoa with milk, matcha milk, calcium-enriched milk drink, coffee with milk, tea with milk, milk shake, milk shake, acid milk drink, strawberry milk and the like.

更に、本発明では、不溶性粉末を含む乳飲料にも適用可能である。特に、ミルク入りココア、抹茶ミルク、カルシウム強化乳飲料等の不溶性粉末を含む乳飲料は、通常、不溶性粉末を分散させるためにセルロースを併用することが多いが、特にUHT殺菌機プレートへの焦げ付きが問題となることがある。本発明は、この当該プレートの焦げ付きを有意に抑制できるものである。   Furthermore, the present invention is applicable to milk beverages containing insoluble powders. In particular, dairy drinks containing insoluble powders such as cocoa with milk, matcha milk, and calcium-enriched milk drinks usually use cellulose in combination to disperse the insoluble powders. May be a problem. The present invention can significantly suppress the burning of the plate.

本発明で言う不溶性粉末とは、飲料に添加可能な、不溶性の粉末成分で有れば特に限定はないが、ココア、抹茶、カルシウム等の金属塩、きなこや酵母などを挙げることができる。   The insoluble powder referred to in the present invention is not particularly limited as long as it is an insoluble powder component that can be added to beverages, and examples thereof include cocoa, green tea, metal salts such as calcium, kinako, and yeast.

本発明の乳飲料は、セルロース及び2種類以上の乳化剤を組み合わせて含み、常温流通可能な殺菌条件でUHT殺菌を行うことを特徴とするが、セルロース及び2種類以上の乳化剤の乳飲料への含有方法は、従来公知の方法をとることができる。例えば、湯または水にセルロースと乳化剤又はセルロースと乳化剤及び増粘多糖類、カゼインナトリウムを粉体及び液状等の形態で投入し、撹拌分散した後に、糖液、牛乳または牛乳及び他の乳成分(全脂粉乳、脱脂粉乳、濃縮乳、生クリームを含む)を加え、これに別途抽出したコーヒーエキス、紅茶エキス、果汁成分や、不溶性粉末を添加する場合は、ココア粉末、抹茶、炭酸カルシウム、乳清カルシウム、卵殻カルシウム、貝カルシウム等の不溶性粉末を添加し、必要であればpH調整した後ホモゲナイズし、瓶、缶、紙パック、ラミネートパック等の密閉容器に充填した後、UHT殺菌機による殺菌処理を行う方法や、ホモゲナイズした後にUHT殺菌機による殺菌処理を行い、ペットボトル、瓶、紙パック、ラミネートパック等の密閉容器に充填する方法を挙げることができる。   The milk beverage of the present invention comprises cellulose and two or more types of emulsifiers in combination, and is characterized by performing UHT sterilization under sterilization conditions that allow circulation at room temperature, but the inclusion of cellulose and two or more types of emulsifiers in the milk beverage A conventionally well-known method can be taken as the method. For example, cellulose and an emulsifier or cellulose and an emulsifier and a thickening polysaccharide and sodium caseinate are added to hot water or water in the form of powder and liquid, and after stirring and dispersing, sugar solution, milk or milk and other milk components ( (Including whole milk powder, skim milk powder, concentrated milk, and fresh cream), and when adding coffee extract, tea extract, fruit juice components, and insoluble powder separately, add cocoa powder, matcha tea, calcium carbonate, milk Add insoluble powders such as fresh calcium, eggshell calcium, shellfish calcium, etc., adjust the pH if necessary, homogenize, fill in sealed containers such as bottles, cans, paper packs, laminate packs, etc., then sterilize with UHT sterilizer Method of processing, sterilization with UHT sterilizer after homogenization, such as PET bottles, bottles, paper packs, laminate packs, etc. Method of filling a closed container can be cited.

本発明により、従来の乳飲料に掲げる問題点であった、ミルク浮き、白色浮遊物、オイルオフ、沈殿を抑制すると共に、本発明の目的である、UHT殺菌機プレートへの焦げ付き抑制、香味劣化抑制された、本発明の乳飲料を調製することができる。また、セルロース、乳化剤、増粘多糖類、カゼインナトリウム等の添加方法は限定されず、セルロース、乳化剤、増粘多糖類、カゼインナトリウム等をバラバラに添加することもできるが、セルロースと乳化剤又は、セルロースと乳化剤及び、増粘多糖類、カゼインナトリウムから選ばれる1種以上の化合物を混合して一剤化してから添加することが、品質の安定なものを得ることが出来ることから特に望ましい。   According to the present invention, milk floating, white floating, oil-off, precipitation, which are the problems raised in conventional milk beverages, are suppressed, and the purpose of the present invention is to suppress burning on the UHT sterilizer plate, flavor deterioration Inhibited milk beverages of the present invention can be prepared. In addition, the method of adding cellulose, emulsifier, thickening polysaccharide, sodium caseinate and the like is not limited, and cellulose, emulsifier, thickening polysaccharide, sodium caseinate and the like can be added separately. It is particularly desirable to add one or more compounds selected from emulsifier, emulsifying polysaccharide, thickening polysaccharide and sodium casein after mixing to make a single agent, since a stable product can be obtained.

本発明の乳飲料には、その効果を妨げない範囲において、乳飲料に一般的に使用される成分、天然香料、合成香料等の香料類、プロテアーゼ、セルラーゼ等の酵素、カラメル色素等の着色料、調味料、炭酸ナトリウム、炭酸水素ナトシウム、炭酸カリウム等のpH調整剤等を添加することが出来る。   In the milk beverage of the present invention, ingredients generally used in milk beverages, flavors such as natural flavors and synthetic flavors, enzymes such as proteases and cellulases, and colorants such as caramel pigments, as long as the effects are not hindered , PH adjusters such as seasonings, sodium carbonate, sodium hydrogen carbonate and potassium carbonate can be added.

本発明は、乳飲料のUHT殺菌機プレートへの焦げ付きを抑制する方法を提供するものである。当該方法は、前述するように乳飲料の製造工程に、セルロースと乳化剤又は、セルロースと乳化剤及び増粘多糖類、カゼインナトリウムから選ばれる化合物の1種以上を添加することにより実施することが出来る。当該方法の操作方法、条件、使用材料等については、前述の記載をそのまま援用することができる。例えば、湯にセルロースと乳化剤又は、セルロースと乳化剤、増粘多糖類又はカゼインナトリウムを撹拌分散し、これに糖液、牛乳又は他の乳成分(全脂粉乳、脱脂粉乳、濃縮乳、生クリーム含む)、必要に応じて、ココア粉末又は抹茶等の不溶性粉末を添加し、ホモゲナイズした後、UHT殺菌を行い、密閉容器に充填することにより、殺菌時のUHT殺菌機プレートへの焦げ付きを有意に抑制することができる。   The present invention provides a method for suppressing the scorching of milk beverages on UHT sterilizer plates. As described above, the method can be carried out by adding one or more compounds selected from cellulose and an emulsifier, or cellulose and an emulsifier, a thickening polysaccharide, and sodium caseinate to the milk beverage production process. Regarding the operation method, conditions, materials used, and the like of the method, the above description can be used as it is. For example, cellulose and emulsifier, or cellulose and emulsifier, thickening polysaccharide or sodium casein are stirred and dispersed in hot water, and sugar solution, milk or other milk components (including whole milk powder, skim milk powder, concentrated milk, and fresh cream) ) If necessary, insoluble powder such as cocoa powder or matcha tea is added, homogenized, UHT sterilized, and filled in a sealed container, which significantly suppresses burning to the UHT sterilizer plate during sterilization can do.

以下、本発明をより詳細に説明するために実験例、実施例を示すが、本発明はこれらの実施例によって何ら制限されるものではない。   EXAMPLES Hereinafter, experimental examples and examples will be shown to describe the present invention in more detail, but the present invention is not limited to these examples.

実験例1:セルロースと乳化剤を用いたミルク入りココアの調製
(1)乳飲料用安定剤の調製
表1に示す配合量に従いセルロース(セルロース複合体A:親水性高分子はカルボキシメチルセルロースナトリウムとキサンタンガム、セルロース複合体B:親水性高分子はキサンタンガム)及び各種乳化剤(ショ糖脂肪酸エステル:HLB16、モノグリセリン脂肪酸エステル:HLB3.8、プロピレングリコール脂肪酸エステル:HLB3.9)又はイオタカラギナンもしくはカゼインナトリウムを粉体混合し、実施例1〜6の乳飲料用安定剤を作成した。また比較として、セルロース、乳化剤(ショ糖脂肪酸エステル、モノグリセリン脂肪酸エステル、プロピレングリコール脂肪酸エステル)、イオタカラギナン、カゼインナトリウムのみ、又はセルロースと1種類の乳化剤を併用した組み合わせもしくは、セルロースと乳化剤を併用しない組み合わせの比較例1〜11を作成した。
Experimental Example 1: Preparation of Cocoa with Milk Using Cellulose and Emulsifier (1) Preparation of Stabilizer for Milk Beverage According to the blending amount shown in Table 1, cellulose (cellulose composite A: hydrophilic polymer is sodium carboxymethylcellulose and xanthan gum, Cellulose composite B: hydrophilic polymer is xanthan gum) and various emulsifiers (sucrose fatty acid ester: HLB16, monoglycerin fatty acid ester: HLB3.8, propylene glycol fatty acid ester: HLB3.9) or iota carrageenan or sodium caseinate It mixed and the stabilizer for milk drinks of Examples 1-6 was created. For comparison, cellulose, emulsifier (sucrose fatty acid ester, monoglycerin fatty acid ester, propylene glycol fatty acid ester), iota carrageenan, sodium caseinate alone, or a combination of cellulose and one emulsifier, or no combination of cellulose and emulsifier Combination Comparative Examples 1 to 11 were prepared.

Figure 0004354352
Figure 0004354352

(2)ミルク入りココアの調製
得られた、実施例1〜6の乳飲料用安定剤及び比較例1〜11とをそれぞれ、下記処方の添加量に従い、砂糖と粉体混合し、この混合物をイオン交換水に加え、80℃10分間加熱溶解後、室温まで冷却し、牛乳、食塩、ココア粉末を添加し、水にて全量補正後、70℃まで加温し、1段目9.8×106Pa、2段目4.9×106Paの圧力でホモゲナイズ処理した。ホモゲナイズ後、UHT殺菌(140℃60秒)し、ペットボトルに充填、密閉し実施例1〜6及び比較例1〜11を含むミルク入りココアを調製した。
(2) Preparation of cocoa with milk The obtained stabilizers for milk beverages of Examples 1 to 6 and Comparative Examples 1 to 11 were mixed with sugar in accordance with the addition amount of the following formulation, and this mixture was mixed. Add to ion-exchanged water, heat and dissolve at 80 ° C for 10 minutes, cool to room temperature, add milk, salt, cocoa powder, correct to 100% with water, heat to 70 ° C, 1st stage 9.8 × 10 6 Homogenization was performed at a pressure of Pa, second stage 4.9 × 10 6 Pa. After homogenization, UHT sterilization (140 ° C., 60 seconds) was performed, filled in a plastic bottle and sealed, to prepare milk-containing cocoa containing Examples 1 to 6 and Comparative Examples 1 to 11.

<処方>
牛乳 23.0(重量%)
砂糖 6.2
ココア粉末 0.7
食塩 0.05
実施例1〜6、比較例1〜11 表1記載
イオン交換水にて全量 100とする
<Prescription>
Milk 23.0 (wt%)
Sugar 6.2
Cocoa powder 0.7
Salt 0.05
Examples 1 to 6 and Comparative Examples 1 to 11 Listed in Table 1 The total amount is set to 100 with ion-exchanged water.

得られた密封容器入りミルク入りココアを室温と60℃で4週間保存後、2℃で1晩保存後に、ミルク浮き、白色浮遊物、オイルオフ、沈殿について観察し、また、UHT殺菌時のプレートへの焦げ付きを観察した。結果を表2に示す。   The resulting cocoa in milk in a sealed container is stored at room temperature and 60 ° C for 4 weeks, and then stored at 2 ° C overnight, and then observed for milk floatation, white suspension, oil-off, precipitation, and plate during UHT sterilization Observed scorching to. The results are shown in Table 2.

Figure 0004354352
Figure 0004354352

表2中の符号の説明
++++:極めて多い、+++:多い、++:やや多い、+:少ない、±:極めて少ない、−:ない
Explanation of symbols in Table +++++: very large, +++: many, ++: slightly large, +: small, ±: very small, −: none

表2に示すように、実施例1〜6の乳飲料用安定剤を加えて調製したミルク入りココアにおいては、比較例1〜11に比して、ミルク浮き、白色浮遊物、オイルオフ、沈殿等の飲料の状態が良好で且つUHT殺菌機プレートへの焦げ付き抑制効果のいずれに関しても有意な効果がみられた。   As shown in Table 2, in the cocoa containing milk prepared by adding the stabilizers for milk beverages of Examples 1 to 6, compared to Comparative Examples 1 to 11, milk float, white float, oil-off, precipitation The beverage was in a good state, and a significant effect was observed with respect to any of the effects of suppressing burning on the UHT sterilizer plate.

実験例2:セルロースと乳化剤の含量の検討
(1)乳飲料用安定剤の調製
表3に示す配合量に従いセルロース(セルロース複合体A:親水性高分子はカルボキシメチルセルロースナトリウムとキサンタンガム)と乳化剤(ショ糖脂肪酸エステル:HLB16)を粉体混合し、実施例7〜10の乳飲料用安定剤を調製した。また、比較として比較例12〜18の乳飲料用安定剤を調製した。
Experimental Example 2: Examination of content of cellulose and emulsifier (1) Preparation of stabilizer for milk beverage According to the blending amount shown in Table 3, cellulose (cellulose complex A: hydrophilic polymer is sodium carboxymethylcellulose and xanthan gum) and emulsifier Sugar stabilizer: HLB16) was powder-mixed to prepare stabilizers for milk drinks of Examples 7-10. Moreover, the stabilizer for milk drinks of Comparative Examples 12-18 was prepared as a comparison.

Figure 0004354352
Figure 0004354352

(2)ミルク入りココアの調製
得られた、実施例7〜10の乳飲料用安定剤及び比較例12〜18とをそれぞれ、下記処方の添加量に従い、砂糖と粉体混合し、この混合物をイオン交換水に加え、80℃10分間加熱溶解後、室温まで冷却し、牛乳、食塩、ココア粉末を添加し、水にて全量補正後、70℃まで加温し、1段目9.8×106Pa、2段目4.9×106Paの圧力でホモゲナイズ処理した。ホモゲナイズ後、UHT殺菌(140℃60秒)し、ペットボトルに充填、密閉し、実施例7〜10及び比較例12〜18のミルク入りココアを調製した。
(2) Preparation of cocoa with milk The obtained stabilizers for milk beverages of Examples 7 to 10 and Comparative Examples 12 to 18 were mixed with sugar in accordance with the addition amount of the following formulation, and this mixture was mixed. Add to ion-exchanged water, heat and dissolve at 80 ° C for 10 minutes, cool to room temperature, add milk, salt, cocoa powder, correct to 100% with water, heat to 70 ° C, 1st stage 9.8 × 10 6 Homogenization was performed at a pressure of Pa, second stage 4.9 × 10 6 Pa. After homogenization, UHT sterilization (140 ° C. for 60 seconds), filling in a plastic bottle, and sealing were performed to prepare milk-containing cocoa of Examples 7 to 10 and Comparative Examples 12 to 18.

<処方>
牛乳 23.0(重量%)
砂糖 6.2
ココア粉末 0.7
食塩 0.05
実施例7〜10、比較例1〜13 表4記載
イオン交換水にて全量 100とする
<Prescription>
Milk 23.0 (wt%)
Sugar 6.2
Cocoa powder 0.7
Salt 0.05
Examples 7 to 10 and Comparative Examples 1 to 13 Listed in Table 4 Total amount of 100 with ion-exchanged water

得られた密封容器入りミルク入りココアを室温と60℃で4週間保存後、2℃で1晩保存後に、ミルク浮き、白色浮遊物、オイルオフ、沈殿について観察した。また、製造時UHT殺菌時のプレートへの焦げ付きを観察した。その結果を表4に記す。   The obtained cocoa containing milk in a sealed container was stored at room temperature and 60 ° C. for 4 weeks, and then stored at 2 ° C. overnight, and then observed for milk floating, white floating, oil-off, and precipitation. Moreover, the burning to the plate at the time of UHT sterilization at the time of manufacture was observed. The results are shown in Table 4.

Figure 0004354352
Figure 0004354352

表4中の符号の説明
++++:極めて多い、+++:多い、++:やや多い、+:少ない、±:極めて少ない、−:ない
Explanation of symbols in Table +++++: very large, +++: many, ++: slightly large, +: small, ±: very small, −: none

表6に示すように、実施例7〜10の乳飲料用安定剤を加えて調製したミルク入りココアにおいては、比較例12〜18に比して、ミルク浮き、白色浮遊物、オイルオフ、沈殿、UHT殺菌機プレートへの焦げ付き抑制効果のいずれに関しても有意な効果がみられた。   As shown in Table 6, in the cocoa containing milk prepared by adding the stabilizers for milk beverages of Examples 7 to 10, milk floating, white floating, oil-off, precipitation compared to Comparative Examples 12 to 18 A significant effect was observed with respect to any of the effects of suppressing burning on the UHT sterilizer plate.

実験例3:抹茶ミルク
(1)乳飲料用安定剤の調製
表5に示す配合量に従いセルロース(セルロース複合体A:親水性高分子はカルボキシメチルセルロースナトリウムとキサンタンガム)と乳化剤(ショ糖脂肪酸エステル:HLB16、モノグリセリン脂肪酸エステル:HLB3.8、プロピレングリコール脂肪酸エステル:HLB3.9)、イオタカラギナンを粉体混合し、実施例11の乳飲料用安定剤を調製した。また、比較として、比較例19を調製した。
Experimental Example 3: Matcha Milk (1) Preparation of Stabilizer for Milk Beverage According to the blending amounts shown in Table 5, cellulose (cellulose complex A: hydrophilic polymer is sodium carboxymethylcellulose and xanthan gum) and emulsifier (sucrose fatty acid ester: HLB16 Monoglycerin fatty acid ester: HLB 3.8, propylene glycol fatty acid ester: HLB 3.9) and iota carrageenan were mixed with powder to prepare a stabilizer for milk beverage of Example 11. For comparison, Comparative Example 19 was prepared.

Figure 0004354352
Figure 0004354352

<処方>
牛乳 25.0(重量%)
砂糖 6.0
抹茶 0.5
本発明の安定剤 表5に記載
イオン交換水にて全量 100とする
<Prescription>
Milk 25.0 (wt%)
Sugar 6.0
Matcha 0.5
Stabilizer of the present invention described in Table 5 Total amount of 100 with ion-exchanged water

(2)抹茶ミルクの調製
得られた実施例11の乳飲料用安定剤及び比較例19とをそれぞれ、上記処方の添加量に従い、砂糖と粉体混合し、この粉体混合物をイオン交換水に加え、80℃10分間加熱撹拌後、室温まで冷却し、牛乳、抹茶を添加し、水にて全量補正後、70℃まで加温し、1段目9.8×106Pa、2段目4.9×106Paの圧力でホモゲナイズ処理した。ホモゲナイズ後、UHT殺菌(140℃60秒)し、ペットボトルに充填、密閉し、実施例11及び比較例19を含む抹茶ミルクを調製した。得られた抹茶ミルクのUHTプレートへの焦げ付きと、60℃にて4週間保存後のミルク浮き、白色浮遊物、オイルオフ、沈殿について観察した結果、UHTプレートへの焦げ付き、ミルク浮き、白色浮遊物、オイルオフ、沈殿において実施例11は比較例19と比較して良好で、有意差が認められた。
(2) Preparation of Matcha Milk The obtained milk beverage stabilizer of Example 11 and Comparative Example 19 were mixed with sugar in accordance with the amount added in the above formulation, and this powder mixture was made into ion-exchanged water. In addition, after heating and stirring at 80 ° C for 10 minutes, cool to room temperature, add milk and green tea, correct the total amount with water, warm to 70 ° C, 1st stage 9.8 × 10 6 Pa, 2nd stage 4.9 × Homogenization was performed at a pressure of 10 6 Pa. After homogenization, UHT sterilization (140 ° C. for 60 seconds) was filled in a PET bottle and sealed to prepare matcha milk containing Example 11 and Comparative Example 19. The resulting matcha milk was charred on the UHT plate, and after observing the milk floating, white float, oil-off, and precipitation after storage at 60 ° C for 4 weeks, the UHT plate was charred, milk floated, white float Example 11 was better than Comparative Example 19 in oil-off and precipitation, and a significant difference was observed.

実験例4:ミルク入りコーヒー
(1)乳飲料用安定剤の調製
表6に示す配合量に従いセルロース(セルロース複合体A:親水性高分子はカルボキシメチルセルロースナトリウムとキサンタンガム)と乳化剤(ショ糖脂肪酸エステル:HLB16、モノグリセリン脂肪酸エステル:HLB3.8、プロピレングリコール脂肪酸エステル:HLB3.9)、イオタカラギナンを粉体混合し、実施例12の乳飲料用安定剤を調製した。また、比較として、比較例20を調製した。
Experimental Example 4: Coffee with milk (1) Preparation of stabilizer for milk beverage According to the blending amount shown in Table 6, cellulose (cellulose complex A: hydrophilic polymer is sodium carboxymethylcellulose and xanthan gum) and emulsifier (sucrose fatty acid ester: HLB16, monoglycerin fatty acid ester: HLB3.8, propylene glycol fatty acid ester: HLB3.9) and iota carrageenan were mixed with powder to prepare a stabilizer for milk beverage of Example 12. For comparison, Comparative Example 20 was prepared.

Figure 0004354352
Figure 0004354352

<処方>
牛乳 15.0(重量%)
コーヒー生豆 6.5
砂糖 5.0
10%(w/v)重曹水溶液にてpH6.3に調整
本発明の安定剤 表6に記載
イオン交換水にて全量 100とする
<Prescription>
Milk 15.0 (wt%)
6.5 coffee beans
Sugar 5.0
Adjust to pH 6.3 with 10% (w / v) aqueous sodium bicarbonate solution
Stabilizer of the present invention described in Table 6 Total amount of 100 with ion-exchanged water

(2)ミルク入りコーヒーの調製
得られた実施例12の乳飲料用安定剤及び比較例20とをそれぞれ、上記処方の添加量に従い、砂糖と粉体混合し、この粉体混合物をイオン交換水に加え、80℃10分間加熱撹拌後、室温まで冷却し、牛乳、重曹溶液を添加した。コーヒー生豆を粉砕し、豆量の7倍量熱湯を加え、40分間浸漬後ろ過し、20℃まで冷却した抽出液を更に添加し、水にて全量補正後、70℃まで加温し、1段目14.7×106Pa、2段目4.9×106Paの圧力でホモゲナイズ処理した。ホモゲナイズ後、UHT殺菌(143℃30 秒)し、ペットボトルに充填、密閉し、実施例12及び比較例20を含むミルク入りコーヒーを調製した。得られたミルク入りコーヒーのUHTプレートへの焦げ付きと、60℃にて4週間保存後のミルク浮き、白色浮遊物、オイルオフ、沈殿について観察した結果、UHTプレートへの焦げ付き、ミルク浮き、白色浮遊物、オイルオフ、沈殿において実施例12は比較例20と比較して良好で、有意差が認められた。
(2) Preparation of coffee with milk The obtained stabilizer for milk beverage of Example 12 and Comparative Example 20 were each mixed with sugar and powder according to the addition amount of the above formulation, and this powder mixture was ion-exchanged water. In addition, the mixture was heated and stirred at 80 ° C. for 10 minutes, cooled to room temperature, and added with milk and a sodium bicarbonate solution. Crush green coffee beans, add 7 times hot water of the amount of beans, soak for 40 minutes, filter, add additional extract cooled to 20 ° C, correct all the amount with water, warm to 70 ° C, Homogenization was performed at a pressure of 14.7 × 10 6 Pa in the first stage and 4.9 × 10 6 Pa in the second stage. After homogenization, UHT sterilization (143 ° C. for 30 seconds), filling in a plastic bottle, and sealing were performed to prepare coffee with milk containing Example 12 and Comparative Example 20. As a result of observing the charcoal of the obtained coffee with milk on the UHT plate and the milk floating, white floating matter, oil-off and precipitation after storage at 60 ° C for 4 weeks, the UHT plate was charred, milk floating, white floating In Example, oil-off, and precipitation, Example 12 was better than Comparative Example 20, and a significant difference was observed.

実験例5:ミルク入り茶飲料
(1)乳飲料用安定剤の調製
表7に示す配合量に従いセルロース(セルロース複合体A:親水性高分子はカルボキシメチルセルロースナトリウムとキサンタンガム)と乳化剤(ショ糖脂肪酸エステル:HLB16、モノグリセリン脂肪酸エステル:HLB3.8、プロピレングリコール脂肪酸エステル:HLB3.9)、イオタカラギナンを粉体混合し、実施例13の乳飲料用安定剤を調製した。また、比較として、比較例21を調製した。
Experimental Example 5: Tea drink with milk (1) Preparation of stabilizer for milk drink According to the blending amount shown in Table 7, cellulose (cellulose composite A: hydrophilic polymer is sodium carboxymethylcellulose and xanthan gum) and emulsifier (sucrose fatty acid ester) : HLB16, monoglycerin fatty acid ester: HLB3.8, propylene glycol fatty acid ester: HLB3.9) and iota carrageenan were mixed with powder to prepare a stabilizer for milk beverage of Example 13. For comparison, Comparative Example 21 was prepared.

Figure 0004354352
Figure 0004354352

<処方>
牛乳 20.0(重量%)
紅茶葉(セイロン) 0.8
砂糖 5.5
10%(w/v)重曹水溶液にてpH6.8に調整
本発明の安定剤 表6に記載
イオン交換水にて全量 100とする
<Prescription>
Milk 20.0 (% by weight)
Tea leaves (Ceylon) 0.8
5.5 sugar
Adjusted to pH 6.8 with 10% (w / v) aqueous sodium bicarbonate solution
Stabilizer of the present invention described in Table 6 Total amount of 100 with ion-exchanged water

(2)ミルク入り茶飲料の調製
得られた実施例13の乳飲料用安定剤及び比較例21とをそれぞれ、上記処方の添加量に従い、砂糖と粉体混合し、この粉体混合物をイオン交換水に加え、80℃10分間加熱撹拌後、室温まで冷却し、牛乳、重曹溶液を添加した。茶葉に茶葉量の35倍量の90℃〜95℃のお湯を加え、90℃〜95℃で10分間攪拌浸漬した後ろ紙ろ過し、室温まで冷却した抽出液を更に添加し、イオン交換水にて全量補正後、70℃まで加温し、1段目9.8×106 Pa 、2段目4.9×106Paの圧力でホモゲナイズ処理した。ホモゲナイズ後容器に充填し、UHT殺菌(143℃30 秒)を行いミルク入り茶飲料を調製した。得られたミルク入り茶飲料のUHTプレートへの焦げ付きと、60℃にて4週間保存後のミルク浮き、白色浮遊物、オイルオフ、沈殿について観察した結果、UHTプレートへの焦げ付き、ミルク浮き、白色浮遊物、オイルオフ、沈殿において実施例13は比較例21と比較して良好で、有意差が認められた。

(2) Preparation of tea drink with milk The obtained stabilizer for milk drink of Example 13 and Comparative Example 21 were mixed with sugar in accordance with the amount of the above formulation, and this powder mixture was subjected to ion exchange. In addition to water, the mixture was heated and stirred at 80 ° C. for 10 minutes, cooled to room temperature, and added with milk and sodium bicarbonate solution. Add hot water of 90 ° C to 95 ° C, 35 times the amount of tea leaves to the tea leaf, filter by back paper soaked for 10 minutes at 90 ° C to 95 ° C, add the extract cooled to room temperature, and add to ion-exchanged water. After correcting the total amount, the mixture was heated to 70 ° C. and homogenized at a pressure of 9.8 × 10 6 Pa in the first stage and 4.9 × 10 6 Pa in the second stage. After homogenization, the container was filled and UHT sterilization (143 ° C., 30 seconds) was performed to prepare a tea beverage containing milk. As a result of observing the charcoal of the obtained tea drink with milk on the UHT plate and the milk floating, white floating matter, oil-off, precipitation after storage at 60 ° C. for 4 weeks, the UHT plate was charred, milk floating, white In the suspended matter, oil-off, and precipitation, Example 13 was better than Comparative Example 21 and significant differences were observed.

Claims (2)

セルロースを含む乳飲料において、2種類以上の乳化剤を組み合わせて含有することによる、常温流通可能な殺菌条件でUHT殺菌を行う場合のUHT殺菌機プレートへの焦げ付きを抑制する方法。 A method for suppressing scorching on a UHT sterilizer plate when UHT sterilization is performed under sterilization conditions that allow circulation at room temperature by containing two or more types of emulsifiers in combination in a milk beverage containing cellulose. 乳化剤が、グリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、ユッカ抽出物、サポニン、レシチン、ポリソルベート、ステアロイル乳酸ナトリウム及びステアロイル乳酸カルシウムから選ばれる2種以上である、請求項1に記載のUHT殺菌機プレートへの焦げ付きを抑制する方法。 The emulsifier is at least two selected from glycerin fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, propylene glycol fatty acid ester, yucca extract, saponin, lecithin, polysorbate, sodium stearoyl lactate and calcium stearoyl lactate. A method for suppressing scorching on the UHT sterilizer plate according to claim 1.
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