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JP4368235B2 - Processed rice cracker and method for producing processed rice using the same - Google Patents
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JP4368235B2 - Processed rice cracker and method for producing processed rice using the same - Google Patents

Processed rice cracker and method for producing processed rice using the same Download PDF

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JP4368235B2
JP4368235B2 JP2004118871A JP2004118871A JP4368235B2 JP 4368235 B2 JP4368235 B2 JP 4368235B2 JP 2004118871 A JP2004118871 A JP 2004118871A JP 2004118871 A JP2004118871 A JP 2004118871A JP 4368235 B2 JP4368235 B2 JP 4368235B2
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rice
oil
carrageenan
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健史 野本
宏厚 葉桐
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J Oil Mills Inc
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Description

本発明は、加工米飯に関するもので、詳細には、加工時にほぐれ性が良好で、また、保存中に品質が劣化しにくい加工米飯用ほぐし剤及びそれを用いた加工米飯の製造方法に関するものである。   The present invention relates to processed cooked rice, and in particular, relates to a processed rice cooking agent that has good looseness during processing and is less susceptible to quality deterioration during storage, and a method for producing processed cooked rice using the same. is there.

近年、CVS、冷凍食品の伸展に伴い、これに対応した加工米飯類の生産量は飛躍的に増加している。こうした加工米飯類に対して要求される品質も次第に高くなっており、調理、製造から食するまで長時間が経過した状態でも、できたてに近い状態のものを供することが求められている。これら加工米飯類のうち、調理上の「炒め」工程を必要とする製品は、一般に製造量が多く機械で調理されるため、ご飯の「ほぐれやすさ」が生産性と品質を左右する重要な因子となる。さらに、その後の真空冷却、あるいは冷凍工程、計量工程等、保存を経て、製造から食されるまでの間に品質が変化するため、品質の経時変化を防止することについても、多岐にわたる取組みが続けられている。
一般的に炒め工程では、炒め油として離型油が用いられることが多いが(特許文献1)、離型油では、鉄板からの離型はある程度可能であるが、ご飯同士のほぐれが不充分という問題がある。また、ほぐれ性の優れた炊飯油も提案されているが(特許文献2)、炊飯油は、ご飯のほぐれ効果はある程度期待できるが、炒め工程では効果が不充分である。
一方、卵を主成分としたほぐし剤、調理工程が提案されている(特許文献3)。このように卵を使うとほぐし効果はある程度期待できるが、完全ではなく、また、調理上のレシピに制限が加わるという問題が発生する。
さらには、水溶性ヘミセルロースを主成分とした炊飯用、米飯用改質剤が提案されており(特許文献4〜6)、これによりほぐれはある程度良くなるが、完全ではなく、また、大豆由来の風味の悪さ、食感の悪さがあるといった課題が残されている。
このように従来提案されてきた方法には一長一短があるため、加工米飯の製造に際して、良好な風味・食感を保持しつつ、優れた離型、バラケ性能を発揮し得るほぐし剤の開発が切望されている。
In recent years, with the growth of CVS and frozen foods, the production of processed cooked rice corresponding to this has increased dramatically. The quality required for such processed cooked rice is gradually increasing, and even when a long time has elapsed from cooking to production to eating, it is required to provide a product that is almost fresh. Of these processed cooked rice, products that require a “stir-fry” process for cooking are generally produced in large quantities and are cooked by machines. Therefore, the “easy to loosen” of rice is an important factor that affects productivity and quality. It becomes a factor. Furthermore, since the quality changes from the time it is stored until it is eaten through storage, such as subsequent vacuum cooling, refrigeration processes, and weighing processes, various efforts continue to prevent changes in quality over time. It has been.
In general, in the stir-fry process, release oil is often used as the stir-fried oil (Patent Document 1). However, with the release oil, release from the iron plate is possible to some extent, but the loosening between the rice is insufficient. There is a problem. In addition, rice cooking oil having excellent loosening properties has also been proposed (Patent Document 2), but rice cooking oil can be expected to some extent to loosen rice, but the effect in the stir-fry process is insufficient.
On the other hand, a loosening agent mainly composed of eggs and a cooking process have been proposed (Patent Document 3). When eggs are used in this way, the effect of unraveling can be expected to some extent, but it is not perfect, and there is a problem that the recipe for cooking is restricted.
Furthermore, a rice cooker and a rice cooker based on water-soluble hemicellulose have been proposed (Patent Documents 4 to 6). This improves the loosening to some extent, but is not perfect and is derived from soybeans. There are still problems such as bad taste and bad texture.
As described above, since the methods proposed heretofore have advantages and disadvantages, it is eager to develop a loosening agent that can exhibit excellent mold release and flake performance while maintaining a good flavor and texture when producing processed cooked rice. Has been.

特開2003−265105号公報JP 2003-265105 A 特開2003−339317号公報JP 2003-339317 A 特開2003−18968号公報JP 2003-18968 A 特開平06−121647号公報Japanese Patent Laid-Open No. 06-121647 特開平11−285350号公報JP 11-285350 A 特開2000−316495号公報JP 2000-316495 A

本発明の目的は、炒め工程を要する加工米飯類の製造における上記の問題点を克服し、原料となる米飯類のほぐれ状態を改善すると共に、製造工程中、あるいは保存を経て、できあがった製品が食されるまでに起こる品質劣化、すなわち、加工米飯の物性変化、食感変化、くっつき、外観変化等を総合的に防止し得る加工米飯用ほぐし剤及びそれを用いた加工米飯の製造方法を提供することである。   The object of the present invention is to overcome the above-mentioned problems in the production of processed cooked rice requiring a frying process, improve the loosening state of cooked rice as a raw material, and produce a finished product during the production process or after storage. Providing processing rice cooker and a method for producing processed rice using the same, which can comprehensively prevent quality deterioration that occurs until it is eaten, that is, changes in physical properties, texture, stickiness, appearance change, etc. It is to be.

本発明者らは、上記目的を達成するために鋭意研究した結果、硫酸基を含有する多糖類、特にカラギーナン、フコイダンを有効成分とする組成物が加工米飯類の炒め工程において、風味等に悪影響を及ぼすことなく非常に優れたほぐし効果を発揮すると同時に、品質劣化抑制効果を有することを見出し、本発明を完成するに至った。
すなわち、本発明は、ιカラギーナン、λカラギーナン及びフコイダンから選ばれた少なくとも一種の多糖類を配合してなる加工米飯用ほぐし剤である。また、本発明は、ιカラギーナン、λカラギーナン及びフコイダンから選ばれた少なくとも一種の多糖類を生米100重量部に対して0.05〜10重量部の割合で、炊飯前又は炊飯後に添加することを特徴とする加工米飯の製造方法である。
As a result of diligent research to achieve the above object, the present inventors have found that a composition containing a sulfate group-containing polysaccharide, particularly carrageenan or fucoidan, has an adverse effect on the flavor and the like in the process of cooking processed rice. The present invention has been completed by finding that it has a very excellent unraveling effect without affecting the quality and has an effect of suppressing quality deterioration.
That is, the present invention is a processed rice loosening agent comprising at least one polysaccharide selected from ι carrageenan, λ carrageenan and fucoidan . In the present invention, at least one polysaccharide selected from ι carrageenan, λ carrageenan and fucoidan is added at a ratio of 0.05 to 10 parts by weight with respect to 100 parts by weight of raw rice before or after cooking. Is a method for producing processed cooked rice.

チャーハン等の加工米飯製造に際して、本発明の加工米飯用ほぐし剤を使用すると、加工時にほぐれ性が良好で、また、保存中に品質が劣化しにくい加工米飯を提供できる。   When the processed rice cooker of the present invention is used in the production of processed cooked rice such as fried rice, it is possible to provide a cooked cooked rice that has good looseness during processing and is less likely to deteriorate during storage.

本発明における硫酸基を含有する多糖類には、カラギーナン、フコイダン、ファーセルラン、アガロペクチン、ポリフィラン、ヘパリン等があり、これらは1種単独で、あるいは2種以上を混合して使用できる。
これらの硫酸基を含有する多糖類のうち、カラギーナンとフコイダンが特に好ましい。
カラギーナンとは、主として紅藻類のイバラノリ、キリンサイ、ギンアンソウ、スギノリ、ツノマタより得られる多糖類である。Dガラクトースが基本骨格である直鎖状の多糖類であり、硫酸基の結合部位と構成糖により、κ、ι、λに大別されるが、本発明においては、特にι及び/又はλカラギーナンガムが好ましい。
フコイダンは、コンブ、アラメ、モズク、カジメ等の褐藻類中に存在する硫酸多糖で、水溶性で粘性と曳糸性を示す粘質物であり、L−フコースから成り、エステル結合した硫酸基を持つ酸性多糖である。
本発明の加工米飯用ほぐし剤が優れた効果を発揮する理由は定かではないが、硫酸基を含有する多糖類が、米内部へ浸透し保水効果を高めるためと推測される。
本発明における加工米飯用ほぐし剤は、硫酸基を含有する多糖類単独で構成する他に、必要に応じて澱粉等の穀物系粉体、油脂、乳化剤、香料、増粘剤などを配合した構成となってもよい。
Examples of the polysaccharide containing a sulfate group in the present invention include carrageenan, fucoidan, farcellulan, agaropectin, polyphyllan, heparin and the like, and these can be used alone or in combination of two or more.
Of these polysaccharides containing sulfate groups, carrageenan and fucoidan are particularly preferred.
Carrageenan is a polysaccharide mainly obtained from the red alga Ibaranori, Giraffe, Ginkgo biloba, Suginori, Tsunomata. D-galactose is a linear polysaccharide having a basic skeleton, and is roughly classified into κ, ι, and λ depending on the binding site of the sulfate group and the constituent sugar. In the present invention, in particular, ι and / or λ carrageenan Gum is preferred.
Fucoidan is a sulfated polysaccharide present in brown algae such as kombu, arame, mozuku, and kajime. It is a viscous substance that is water-soluble and exhibits viscosity and spinnability. It consists of L-fucose and has an ester-bonded sulfate group. It is an acidic polysaccharide.
The reason why the processed rice cracking agent of the present invention exhibits an excellent effect is not clear, but it is presumed that the polysaccharide containing sulfate groups penetrates into the interior of the rice and enhances the water retention effect.
The processed rice cooking loosening agent in the present invention is composed of a polysaccharide alone containing a sulfate group, and, if necessary, a grain-based powder such as starch, a fat, an emulsifier, a fragrance, a thickener, etc. It may be.

澱粉としては、コーンスターチ、ワキシーコーンスターチ、ハイアミロースコーンスターチ、馬鈴薯澱粉、小麦澱粉、タピオカ澱粉、緑豆澱粉、サゴ澱粉、米澱粉、えんどう豆澱粉、及びこれらにエステル化処理、エーテル化処理、架橋処理、酸処理、酸化処理、湿熱処理、α化等の物理的又は化学的処理を単独で、又は組み合わせて施した加工澱粉を挙げることができる。
油脂としては、大豆油、大豆胚芽油、菜種油、高オレイン酸菜種油、コーン油、ゴマ油、ゴマサラダ油、シソ油、亜麻仁油、落花生油、紅花油、高オレイン酸紅花油、ひまわり油、高オレイン酸ひまわり油、高リノール酸ひまわり油、ミッドオレイックひまわり油、綿実油、ブドウ種子油、マカデミアナッツ油、へーゼルナッツ油、カボチャ種子油、クルミ油、椿油、茶実油、エゴマ油、オリーブ油、米糠油、小麦胚芽油、パーム油、パームオレイン、パーム核油、ヤシ油、カカオ脂、藻類油およびこれらの分別油が挙げられる。
乳化剤としては、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、モノグリセライド有機酸エステル類、蔗糖脂肪酸エステル、ソルビタン脂肪酸エステル、レシチン、脂肪酸乳酸エステル類から選ばれる1種あるいは2種以上の混合物が挙げられる。
As starch, corn starch, waxy corn starch, high amylose corn starch, potato starch, wheat starch, tapioca starch, mung bean starch, sago starch, rice starch, pea starch, and esterification treatment, etherification treatment, crosslinking treatment, Mention may be made of processed starch that has been subjected to physical or chemical treatment such as acid treatment, oxidation treatment, wet heat treatment, and pregelatinization alone or in combination.
As fats and oils, soybean oil, soybean germ oil, rapeseed oil, oleic rapeseed oil, corn oil, sesame oil, sesame salad oil, perilla oil, linseed oil, peanut oil, safflower oil, safflower oil, safflower oil, sunflower oil, and high oleic acid Sunflower oil, high linoleic sunflower oil, mid oleic sunflower oil, cottonseed oil, grape seed oil, macadamia nut oil, hazelnut oil, pumpkin seed oil, walnut oil, camellia oil, tea seed oil, egoma oil, olive oil, rice bran oil, wheat Examples include germ oil, palm oil, palm olein, palm kernel oil, coconut oil, cocoa butter, algal oil and fractionated oils thereof.
Examples of the emulsifier include glycerin fatty acid ester, polyglycerin fatty acid ester, monoglyceride organic acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, lecithin, and a mixture of two or more kinds of fatty acid lactic acid esters.

香料としては通常、食品に使用される天然物系、合成系香料がいずれも使用できる。
増粘剤としては、水溶液にしたときに粘度を上昇させる多糖類、すなわち、アラビアガム、アラビノガラクタン、グァーガム、キサンタンガム、サイリウムシードガム、ジェランガム、タラガム、ローカストビーンガム、タマリンドシードガム、大豆水溶性多糖類(ヘミセルロース)、アルギン酸ナトリウム、プルラン、ペクチン、カラヤガム、ガッティガム、トラガントガム、カードラン、グルコマンナン、キチン、キトサン、微小繊維状セルロース、微結晶セルロース等が挙げられる。
この他にも、コラーゲンペプチド、乳タンパクペプチド、カゼインペプチド、オリゴペプチド、乳清タンパク濃縮物、えんどうタンパク、ゼラチン等の蛋白質由来の物、大豆ファイバー、えんどうファイバー等の繊維質、高度分岐環状デキストリン等のデキストリンも使用できる。
さらに、本発明の加工米飯用ほぐし剤には、pH調整剤や糖類を添加してもよい。pH調整剤としては、乳酸、グルコン酸、コハク酸、フマル酸、クエン酸、DL−リンゴ酸、氷酢酸、グルコノデルタラクトン、L−酒石酸、DL−酒石酸等があり、糖類としては、グルコース(ブドウ糖)、マルトース、フラクトース(果糖)、ガラクトース、トレハロース、オリゴ糖、蔗糖、ソルビット等が挙げられる。
As the fragrance, both natural products and synthetic fragrances usually used in foods can be used.
Thickeners include polysaccharides that increase viscosity when made into aqueous solutions, namely gum arabic, arabinogalactan, guar gum, xanthan gum, psyllium seed gum, gellan gum, tara gum, locust bean gum, tamarind seed gum, water soluble in soybeans Examples include polysaccharides (hemicellulose), sodium alginate, pullulan, pectin, karaya gum, gati gum, tragacanth gum, curdlan, glucomannan, chitin, chitosan, microfibrous cellulose, and microcrystalline cellulose.
In addition, collagen peptides, milk protein peptides, casein peptides, oligopeptides, whey protein concentrates, pea proteins, gelatin-derived products, soy fibers, pea fibers and other fibers, highly branched rings Dextrins such as dextrin can also be used.
Furthermore, you may add a pH adjuster and saccharides to the loosening agent for processed rice of this invention. Examples of pH adjusters include lactic acid, gluconic acid, succinic acid, fumaric acid, citric acid, DL-malic acid, glacial acetic acid, glucono delta lactone, L-tartaric acid, DL-tartaric acid, and sugars include glucose ( Glucose), maltose, fructose (fructose), galactose, trehalose, oligosaccharide, sucrose, sorbit and the like.

本発明における加工米飯類とは、チャーハン、ピラフ等の炊飯した米を油で加熱調理する食品であり、本発明の加工米飯用ほぐし剤は、炒め工程でのほぐれ性向上を主目的とするため、炒め工程に先だって原料である米飯へ添加する。加工米飯はそのメニュー、製品によって工程は異なるが、例えば、CVS向けに作られる炒飯の場合、炊飯→炒め→真空冷却→充填→保管といった工程をとるため、炊飯時、あるいは炒め前、炒め中のいずれかに添加されることとなる。炒め前、炒め時であれば、直接添加してから均一に攪拌するか、あるいは副材にあらかじめ混合させた状態で添加するという方法を取ることも可能である。
本発明の加工米飯用ほぐし剤は、硫酸基を含有する多糖類として生米100重量部に対して0.05〜10重量部、好ましくは0.5〜1.0重量部の割合で添加する。0.05重量部未満では必要な効果が得られず、また、10重量部を越えると食感、風味に悪い影響を与える。
Processed cooked rice in the present invention is food that cooks cooked rice such as fried rice and pilaf with oil, and the processed rice cooker of the present invention is mainly intended to improve the looseness in the frying process. Prior to the frying process, add to the cooked rice. Processed cooked rice has different processes depending on the menu and product. For example, in the case of fried rice made for CVS, it takes a process of cooking rice → stir fry → vacuum cooling → filling → storage. It will be added to either. If it is before frying and during frying, it can be added directly and then stirred uniformly, or it can be added in a state of being mixed in advance with a secondary material.
The loosening agent for processed cooked rice of the present invention is added as a polysaccharide containing a sulfate group in a proportion of 0.05 to 10 parts by weight, preferably 0.5 to 1.0 parts by weight, based on 100 parts by weight of raw rice. . If it is less than 0.05 part by weight, the necessary effect cannot be obtained, and if it exceeds 10 parts by weight, the texture and flavor are adversely affected.

なお、カラギーナンを使用する際には、カラギーナンは通常粉末の状態となっており、加工米飯製造工程で使用する場合、生米に対する使用量は微量であるため、粉体をそのまま使用することは作業性や均一性にやや問題となる場合が多い。その際には、カラギーナンを水に均一に溶解した状態のものを調製することにより、作業性及び均一性を飛躍的に改善することができる。カラギーナンの水に対する添加量は、通常0.05〜10重量%が好ましい。5重量%を越えると、水溶液の粘度が高くなり、作業性に支障を来すことがある。こうした高濃度の水溶液調製に際しては、pH調整剤を添加してpHを下げて加熱混合すれば粘度が低下し、作業性にも問題がなくなる。   In addition, when using carrageenan, carrageenan is normally in the state of powder, and when used in the processed cooked rice manufacturing process, the amount used for raw rice is very small, so using powder as it is is a work In many cases, it is somewhat problematic in terms of uniformity and uniformity. In that case, workability and uniformity can be drastically improved by preparing a product in which carrageenan is uniformly dissolved in water. The amount of carrageenan added to water is usually preferably 0.05 to 10% by weight. If it exceeds 5% by weight, the viscosity of the aqueous solution increases, which may hinder workability. In preparing such a high-concentration aqueous solution, if a pH adjuster is added and the pH is lowered and mixed by heating, the viscosity decreases, and there is no problem in workability.

以下に本発明の実施例を示すが、本発明は、これらの実施例に限定されるものではない。
[実施例1〜4、比較例1]
小型ガス炊飯器の釜に生米400gを入れ洗米した後、米への付着水を含め、水を加え960gとした(1.4倍加水)。その後、1時間浸漬後に着火。炊飯直前に炊飯油2g(ホーネンコーポレーション製品 豊年炊飯油 対生米0.5%)を添加した。着火から45分後に、200gのご飯(ご飯温度70〜80℃)を取り出しすぐにフライパンで炒めた。フライパンは1KW電気コンロで加熱して150℃で炒め油(ホーネンコーポレーション製品 パンクリーンC)4g(対ご飯2%)を添加し、160℃でご飯200gを投入し500Wに変換し、フライパン温度を150℃に保つようにした。次に、ιカラギーナン粉末をご飯に対して、各々0.1g(対ご飯0.05%)、0.5g(対ご飯0.25%)、1.0g(対ご飯0.5%)、3.0g(対ご飯1.5%)ふりかけ、大スプーンを両手に持ち、お好み焼きをひっくり返す要領で6分間炒めた。ほぐれ度合いは、◎極めて良くほぐれる、〇良くほぐれる、△ややほぐれる、×全くほぐれない、で評価した。
その結果を表1に示す。ご飯に対して3%で極めてよくほぐれたが、白飯上に多糖類特有の着色が目立った。また、1%では良くほぐれたが、着色ムラが目だった。0.5%では振りかけても量が少ないためかほぐれが悪くなってしまい、0.1%では全くほぐれなかった。
Examples of the present invention are shown below, but the present invention is not limited to these examples.
[Examples 1 to 4, Comparative Example 1]
After putting 400 g of raw rice into a kettle of a small gas cooker and washing the rice, water including the water adhering to the rice was added to make 960 g (1.4 times water addition). Then ignited after immersion for 1 hour. Just before cooking, 2 g of cooking oil (Honen Corporation product rich rice cooking oil vs. 0.5% cooked rice) was added. 45 minutes after ignition, 200 g of rice (rice temperature 70-80 ° C.) was taken out and immediately fried in a frying pan. The frying pan is heated on a 1 KW electric stove and added with 4 g of fried oil (Honen Corporation product Panclean C) at 150 ° C. (2% of rice), 200 g of rice is added at 160 ° C. and converted to 500 W, and the frying pan temperature is 150 The temperature was kept at ° C. Next, 0.1 g (0.05% of rice), 0.5 g (0.25% of rice), 1.0 g (0.5% of rice) of ι carrageenan powder with respect to rice, 3 Sprinkle with 0.0 g (1.5% of rice), hold a large spoon in both hands, and fry for 6 minutes in the same way as turning over the okonomiyaki. The degree of unraveling was evaluated as: ◎ very well unraveled, 〇 well unraveled, △ slightly unraveled, x undissolved at all.
The results are shown in Table 1. Although it was very well loosened at 3% with respect to rice, the coloring peculiar to polysaccharides was conspicuous on white rice. Moreover, although 1% was well loosened, coloring unevenness was noticeable. At 0.5%, the amount of sprinkling was small even when sprinkled.

Figure 0004368235
Figure 0004368235

[実施例5,6、参考実施例7、実施例8〜13、比較例2〜6]
小型ガス炊飯器の釜に生米400gを入れ洗米し、その後、米への付着水と予め調整した1%カラギーナン(ιタイプ、λタイプ、κタイプそれぞれの)溶液400gを含め水を加え全量で960gとした(1.4倍加水)。生米に対して1%のカラギーナンを添加する場合は、この方法を用いた。0.5%添加の場合は1%カラギーナン溶液を200g、0.1%の場合は40g、0.05%の場合は20gをそれぞれ添加し、水を加え全量で960gとした。生米に対して5%、7.5%、10%のカラギーナンを添加する場合は、ビーカーを用い500W電熱ヒーター上で加熱し、溶液温度を70℃に保ち、加温しながら攪拌し、それぞれの濃度のゲルを調整し、そのゲル400gを含め水を加え全量で960gとした。
また、生米に対して1%のグァーガム、プルラン、アラビアガムを添加する場合は、予め調整した10%溶液40gを含め水を加え全量で960gとした(1.4倍加水)。その後、1時間浸漬後に着火。炊飯直前に炊飯油2g(ホーネンコーポレーション製品 豊年炊飯油 対生米0.5%)を添加した。その45分後に、200gのご飯(ご飯温度70〜80℃)を取り出しすぐにフライパンで炒めた。フライパンは1KW電気コンロで加熱してフライパン温度が150℃になったならば炒め油(ホーネンコーポレーション製品 パンクリーンC)4g(対ご飯2%)を添加し、160℃になったならばご飯200gを投入し、500Wに変換しフライパン温度を150℃に保つようにした。大スプーンを両手に持ち、お好み焼きをひっくり返す要領で6分間炒めた。
チャーハンを想定したほぐれ度合いは、◎極めて良くほぐれる、〇良くほぐれる、△ややほぐれる、×全くほぐれない、で評価した。
その結果を表2に示す。ιカラギーナン、λカラギーナンでは生米に対して1%が極めて良好にほぐれる結果を示し、κカラギーナンも生米に対して1%が良好にほぐれる結果を示した。
[Examples 5 and 6, Reference Example 7, Examples 8 to 13 and Comparative Examples 2 to 6]
Put 400g of raw rice in a small gas cooker kettle and wash, and then add water including 400g of 1% carrageenan (ι type, λ type, κ type) solution prepared in advance and water adhering to the rice. It was set to 960g (1.4 times water addition). This method was used when 1% carrageenan was added to fresh rice. In the case of 0.5% addition, 200 g of 1% carrageenan solution was added, 40 g in the case of 0.1%, 20 g in the case of 0.05%, and water was added to make a total amount of 960 g. When adding 5%, 7.5%, or 10% carrageenan to raw rice, heat on a 500W electric heater using a beaker, keep the solution temperature at 70 ° C, stir while warming, The gel was adjusted to a concentration of 1, and water including 400 g of the gel was added to make a total amount of 960 g.
Moreover, when adding 1% guar gum, pullulan, and gum arabic to the raw rice, water was added to make a total of 960 g (1.4 times water addition) including 40 g of a 10% solution prepared in advance. Then ignited after immersion for 1 hour. Just before cooking, 2 g of cooking oil (Honen Corporation product rich rice cooking oil vs. 0.5% cooked rice) was added. After 45 minutes, 200 g of rice (rice temperature 70-80 ° C.) was taken out and immediately fried in a frying pan. When the frying pan is heated with a 1KW electric stove and the frying temperature reaches 150 ° C, add 4g of stir-fried oil (Honen Corporation product Panclean C) (2% to rice), and when it reaches 160 ° C, add 200g of rice. And converted to 500 W to keep the frying pan temperature at 150 ° C. Hold a large spoon in both hands and fry for 6 minutes in the same way as turning okonomiyaki upside down.
The degree of loosening assuming fried rice was evaluated as ◎ very well loosened, ○ well loosened, △ somewhat loosened, and × not loosened at all.
The results are shown in Table 2. In ι carrageenan and λ carrageenan, 1% of raw rice was unraveled very well, and κ carrageenan was also unraveled 1% of fresh rice.

さらに、ιカラギーナンの添加量を0.05%から10%の範囲で同様に検討した。チャーハンを想定したほぐれ度合いに加え、チャーハンらしさの指標として食感を追加した。〔チャーハンを想定したほぐれ度合いを「ほぐれ」と「食感」の2項目で評価(7点法で判断)し、さらに、総合的に判断した。(7点非常に良好、6点かなり良好、5点やや良好、4点普通、3点やや悪い、2点かなり悪い、1点非常に悪い)〕
結果を表3に示す。添加量が極端に少ない0.05%ではある程度のほぐれは見られたが、チャーハンらしい食感が低下した。また、極端に多い10%では非常にほぐれたが、チャーハンらしい食感が低下した。
Further, the addition amount of ι carrageenan was similarly examined in the range of 0.05% to 10%. In addition to the degree of fraying that assumed fried rice, the texture was added as an index of fried rice character. [The degree of fraying that assumed fried rice was evaluated (judged by the 7-point method) based on two items, “fraying” and “texture”, and then comprehensively judged. (7 points are very good, 6 points are quite good, 5 points are slightly good, 4 points are normal, 3 points are slightly bad, 2 points are quite bad, 1 point is very bad)]
The results are shown in Table 3. When the addition amount was extremely small, 0.05%, a certain degree of loosening was seen, but the texture like fried rice was reduced. In addition, the extremely high 10% was very loose, but the texture like fried rice decreased.

Figure 0004368235
Figure 0004368235

Figure 0004368235
Figure 0004368235

[実施例14〜15、参考実施例16、比較例7〜10]
チャーハン大量調理試験(溶液を炊飯時に水と一緒に入れる方法)
業務用炒め機〔ホーネンコーポレーション製品 クックマスターHEI−50(製造能力1工程で30食)〕でカラギーナン種類別(ιタイプ、λタイプ、κタイプ)のほぐし効果を確認した。炊飯は業務用ガス釜を使用した。予めステンレス製ボール内で生米2.5Kgを洗米し1時間浸漬した後、釜に付着水とともに1%カラギーナン溶液を2.5Kg入れ、水を加え全量で6.0Kgとした(1.4倍加水)。炊飯直前に炊飯油12.5g(ホーネンコーポレーション製品 豊年炊飯油 対生米0.5%)を添加した。グァーガム、プルラン、アラビアガムは、予め調整した10%溶液250gを含め水を加え全量で6Kgとした(1.4倍加水)。その後、炊飯し45分後にしゃもじ(大)でご飯を壊さないように軽くかき混ぜ荒熱を取り、4Kgのご飯を保温コンテナで15分間保温した。
その後、業務用炒め機を約4分間加熱し、釜温度が220℃になった時点で消火し、炒め油(ホーネンコーポレーション製品 パンクリーンC)80g(対ご飯2%)を入れ、釜を2回転させ釜になじませた。その後、きざんだ長ネギ96g、チャーシュー192gを投入し、次いで、15分間保温しておいたご飯4Kgを投入し、再び着火し2分間炒め、消火。その後、塩32g、胡椒2g、グルソー8g、中華スープの素12gのミックスを投入し、再び着火し1分間炒め消火。さらに、液卵400gを投入し着火して2分間炒めた。その後、消火して醤油を40g投入し、30秒間余熱で炒めてバットに取り出した。その後、すぐに真空冷却機にて品温を25℃まで下げた。炒め工程ではご飯の塊にはいっさい手を入れずに行った。
真空冷却後の評価ではιカラギーナンとλカラギーナンが良好な結果を示したが、κカラギーナンでは多糖類特有の粘りが出てしまいほぐれにくくなってしまった。
上記実施例で調理したチャーハン250gを冷凍庫(−20℃)で1カ月間冷凍し、家庭用電子レンジにて600Wで5分間レンジアップし解凍した。
これらについての性能試験を上記と同様に行い、結果を表4に示す。
ιカラギーナン、λカラギーナンについては、レンジアップ後のほぐれは極めて良好な結果を示した。κカラギーナンについては、多糖類特有の粘りが出てしまった。
[Examples 14 to 15, Reference Example 16 and Comparative Examples 7 to 10]
Fried rice mass cooking test (method to put the solution with water when cooking rice)
The unraveling effect of each carrageenan type (ι type, λ type, κ type) was confirmed with a commercial stirrer [Hornen Corporation Cookmaster HEI-50 (30 meals in one production step)]. For cooking rice, a commercial gas kettle was used. After washing 2.5 kg of raw rice in a stainless steel ball and immersing it for 1 hour in advance, add 2.5 kg of 1% carrageenan solution together with the adhering water to the kettle and add water to make 6.0 kg in total (1.4 times increase) water). Immediately before cooking, 12.5 g of cooking oil (Honen Corporation product rich rice cooking oil vs. 0.5% cooked rice) was added. Guar gum, pullulan, and gum arabic were added to a total amount of 6 kg (1.4 times water) by adding water including 250 g of a 10% solution prepared in advance. Then, after cooking, 45 minutes later, rice was lightly agitated with rice paddles (large) so as not to break the rice, and then the heat was removed. 4 kg of rice was kept warm in a heat insulating container for 15 minutes.
Then, heat the stir-fry machine for about 4 minutes, extinguish the fire when the kettle temperature reaches 220 ° C, add 80 g of stir-fried oil (Honen Corporation product Panclean C) (2% to rice), and turn the kettle twice I was allowed to adjust to the kettle. Then, 96 g of chopped long onion and 192 g of char siu are added, and then 4 kg of rice that has been kept warm for 15 minutes is added, ignited again, fried for 2 minutes, and extinguished. Then, mix 32g of salt, 2g of pepper, 8g of gulso and 12g of Chinese soup, ignite again and stir for 1 minute. Furthermore, 400 g of liquid eggs were added, ignited and fried for 2 minutes. Thereafter, the fire was extinguished and 40 g of soy sauce was added, fried with preheat for 30 seconds, and taken out into a bat. Thereafter, the product temperature was immediately lowered to 25 ° C. with a vacuum cooler. In the stir-fry process, the rice lump was carried out without putting any hands.
In the evaluation after vacuum cooling, ι carrageenan and λ carrageenan showed good results, but κ carrageenan had a stickiness peculiar to polysaccharides and became difficult to loosen.
250 g of fried rice cooked in the above example was frozen in a freezer (−20 ° C.) for 1 month, and was raised in a microwave oven at 600 W for 5 minutes and thawed.
The performance test was conducted in the same manner as described above, and the results are shown in Table 4.
For ι carrageenan and λ carrageenan, the loosening after the range up showed very good results. About kappa carrageenan, the stickiness peculiar to polysaccharide has come out.

Figure 0004368235
Figure 0004368235

[実施例17〜19、比較例11]
カラギーナン溶液は、濃度が高くなればなるほど増粘し、ゲル状になり流動性がなくなってしまう。実施例5および6では流動性のある1%溶液を用い、生米に対しカラギーナンの粉末重量1%で良好なほぐし効果が認められた。しかし、かなりの量を炊飯時に入れることを考えると、システム化された大量炊飯装置では実用的ではない。カラギーナン溶液の必要最低限の量を大量炊飯ラインでポンプアップ式装置により自動添加をすることや、炊飯釜内での分散性をさらに向上させるために、高濃度(10〜15%)で流動性を保てるまで粘度を低下させることを考案した。
高濃度のカラギーナン溶液に流動性を持たせるには、pHを下げる、加熱するなど物理的処理を施す必要がある。そこで、500mlのセパラブルフラスコ(冷却管付き)内でpHを下げた水に、10〜15%濃度のιカラギーナンを分散させ、加熱処理することを試みた結果、pH=3の水にιカラギーナン粉末を10%分散させ90℃、40分加熱しつづけると、流動性が保てる溶液を調整できることがわかった(粘度3000cp以下)。さらに、90℃、80分処理したものは、水に近い粘度(20cp以下)まで落とせることがわかり、粘度が低いほどチャーハンのほぐれが良くなることもわかった。ιカラギーナン10%溶液であれば、2.5Kgの炊飯時に250gの少ない添加量で済む。
これら粘度調整したιカラギーナンを実施例14〜16と同じ方法(業務用炒め機)でチャーハンを実際に調理し、真空冷却後のほぐれ度合いを評価した。結果を表5に示す。
粘度が低くなるほどほぐれ度合いが良好な結果を示した。
[Examples 17 to 19, Comparative Example 11]
The carrageenan solution becomes thicker as the concentration becomes higher, becomes a gel, and loses its fluidity. In Examples 5 and 6, a 1% solution having fluidity was used, and a good unraveling effect was observed at 1% by weight of carrageenan powder on fresh rice. However, considering that a considerable amount is added at the time of cooking, it is not practical with a systemized mass cooking device. In order to automatically add the minimum amount of carrageenan solution with a pump-up type device in a large-scale rice cooking line and to further improve the dispersibility in the rice cooker, it is highly concentrated (10-15%) and fluid It was devised to reduce the viscosity until it was maintained.
In order to impart fluidity to a high-concentration carrageenan solution, it is necessary to perform physical treatment such as lowering the pH or heating. Therefore, as a result of dispersing and heating the 10-15% concentration of ι carrageenan in water having a reduced pH in a 500 ml separable flask (with a cooling tube), ι carrageenan was dissolved in pH = 3 water. It was found that a solution in which fluidity can be maintained can be prepared by dispersing 10% of the powder and heating at 90 ° C. for 40 minutes (viscosity 3000 cp or less). Furthermore, it turned out that what was processed at 90 degreeC for 80 minutes can drop to the viscosity (20 cp or less) close | similar to water, and it became clear that fried rice becomes looser, so that a viscosity is low. If it is a 10% carrageenan solution, a small addition amount of 250 g is required when cooking 2.5 kg of rice.
Fried rice was actually cooked with these viscosity-adjusted iota carrageenans by the same method (fryer for business use) as in Examples 14 to 16, and the degree of loosening after vacuum cooling was evaluated. The results are shown in Table 5.
The lower the viscosity, the better the degree of loosening.

Figure 0004368235
Figure 0004368235

[実施例20、21、比較例12]
無添加区は、小型ガス炊飯器の釜に生米300gを入れ洗米した後、米への付着水を含め水を加え全量で720gとした(1.4倍加水)。対生米カラギーナン粉末1%添加区は、同様に炊飯器の釜に生米300gを入れ洗米した後、米への付着水と、予め500mlセパラブルでpH=3、90℃で40分加熱し粘度を2400cpに調整した10%ιカラギーナン溶液30gを含め水を加え全量で720gとした(1.4倍加水)。市販もずく溶液(フコイダンを含有)添加区はフードカッターを用い、もずく200gをドロドロになるまで粉砕し、その後、濾布で目視できる固形物を取り除き得た溶液をほとんど水分と考え、同様に300gの生米洗米後に100gを含め水を加え全量で720gとした(1.4倍加水)。その後、それぞれ1時間浸漬後に着火。炊飯直前に豊年炊飯油1.5g(対生米0.5%)を添加した。その45分後に、200gのご飯(ご飯温度70〜80℃)を取り出しすぐにフライパンで炒めた。フライパンは1KW電気コンロで加熱して、フライパン温度が150℃になったならばパンクリーンC(炒め油)4g(対ご飯2%)を添加し、160℃になったならばご飯200gを投入し、500Wに変換しフライパン温度を150℃に保つようにした。大スプーンを両手に持ち、お好み焼きをひっくり返す要領で6分間炒めた。チャーハンを想定したほぐれ度合いは、◎極めて良くほぐれる、〇良くほぐれる、△ややほぐれる、×全くほぐれない、で評価し、その結果を表6に示した。無添加では団子状のご飯の塊になってしまったのに対して、もずく溶液添加区はιカラギーナン対生米1%添加区ほどではなかったが、良好にほぐれる結果を示した。
[Examples 20 and 21, Comparative Example 12]
In the additive-free zone, 300 g of fresh rice was put in a kettle of a small gas cooker and washed, and then water including the water adhering to the rice was added to a total amount of 720 g (1.4 times water addition). Similarly, after adding 300g of raw rice to the rice cooker's kettle and washing the rice, 500kg separable and pre-heated for 500 minutes at pH = 3 and 90 ° C for 40 minutes. Water including 30 g of 10% ι carrageenan solution adjusted to 2400 cp was added to a total amount of 720 g (1.4 times water addition). Commercial mozuku solution (containing fucoidan) was added using a food cutter, 200 g of mozuku was crushed until it became muddy, and then the solution from which the solids visible with a filter cloth could be removed was considered to be almost water, and 300 g After washing the raw rice, 100 g of water was added to make a total amount of 720 g (1.4 times water addition). After that, they were ignited after immersion for 1 hour. Just before cooking rice, 1.5 g of rich rice cooking oil (0.5% of fresh rice) was added. After 45 minutes, 200 g of rice (rice temperature 70-80 ° C.) was taken out and immediately fried in a frying pan. The frying pan is heated with a 1KW electric stove. When the frying pan temperature reaches 150 ° C, 4 g of pan clean C (fried oil) (2% to rice) is added, and when it reaches 160 ° C, 200 g of rice is added. , And the frying pan temperature was kept at 150 ° C. Hold a large spoon in both hands and fry for 6 minutes in the same way as turning okonomiyaki upside down. The degree of loosening assuming fried rice was evaluated as follows: ◎ very well loosened, ○ well loosened, △ somewhat loosened, and × not loosened at all, and the results are shown in Table 6. When it was not added, it became a dumpling-like lump of rice, while the mozuku solution-added group was not as good as ι carrageenan vs. 1% raw rice-added group, but showed a good loosening result.

Figure 0004368235
Figure 0004368235

[実施例22〜25、比較例13]
業務用炒め機〔ホ−ネンコーポレーション製品 クックマスターHEI−50(製造能力1工程で30食)〕で、もずく由来のフコイダンが入ったご飯を炒めた。炊飯は業務用ガス釜を使用した。予めステンレス製ボール内で生米2.5Kgを洗米し1時間浸漬した後、釜に付着水とともに10%フコイダン溶液250gを入れ、水を加え全量で5.8Kgとした(1.32倍加水)。炊飯直前にホーネンコーポレーション製品 豊年炊飯油12.5g(対生米0.5%)を添加した。その後、炊飯し45分後にしゃもじ(大)でご飯を壊さないように軽くかき混ぜ荒熱を取り、4Kgのご飯を保温コンテナで15分間保温した。
その後、業務用炒め機(クックマスターHEI−50)を約4分間加熱し、釜温度が220℃になった時点で消火し、炒め油(ホーネンコーポレーション製品 パンクリーンC)80g(対ご飯2%)を入れ、釜を2回転させ釜になじませた。その後、15分間保温しておいたご飯4Kgを投入し、再び着火し4分間炒め、消火しすぐに炒めたご飯を特大バットに移し取り、ほぐれ度合いを評価した。その後、すぐに真空冷却機にて品温を25℃まで下げ、ほぐれ度合いを評価した。炒め工程ではご飯の塊にはいっさい手を入れずに行った。
[Examples 22 to 25, Comparative Example 13]
The rice containing fucoidan derived from mozuku was fried with a commercial stirrer [Honen Corporation Cook Master HEI-50 (30 meals per process)]. For cooking rice, a commercial gas kettle was used. After washing 2.5Kg of raw rice in a stainless steel ball and immersing for 1 hour in advance, 250g of 10% fucoidan solution was added to the kettle together with adhering water, and water was added to make a total amount of 5.8Kg (1.32 times water addition) . Immediately before cooking, 12.5 g of rich rice cooking oil (0.5% of fresh rice) was added. Then, after cooking, 45 minutes later, rice was lightly agitated with rice paddles (large) so as not to break the rice, and then the heat was removed. 4 kg of rice was kept warm in a heat insulating container for 15 minutes.
Then, heat the stir-fry machine for commercial use (Cookmaster HEI-50) for about 4 minutes, extinguish the fire when the kettle temperature reaches 220 ° C, and stir-fried oil (Honen Corporation product Panclean C) 80g (2% to rice) Was put in, and the kettle was rotated twice to fit into the kettle. Thereafter, 4 kg of rice that had been kept warm for 15 minutes was added, ignited again, fried for 4 minutes, fire extinguished and immediately fried rice was transferred to an oversized bat, and the degree of loosening was evaluated. Thereafter, the product temperature was immediately lowered to 25 ° C. with a vacuum cooler, and the degree of loosening was evaluated. In the stir-fry process, the rice lump was carried out without putting any hands.

Figure 0004368235
Figure 0004368235

本発明の加工米飯用ほぐし剤を使用すると、加工時にほぐれ性が良好で、また保存中に品質が劣化しにくい加工米飯が得られるので、チャーハン等の加工米飯の製造に利用できる。   When the processing rice cracking agent of the present invention is used, it is possible to obtain processed cooked rice that has good looseness during processing and that does not easily deteriorate in quality during storage, and can be used for the production of cooked rice such as fried rice.

Claims (2)

ιカラギーナン、λカラギーナン及びフコイダンから選ばれた少なくとも一種の多糖類を配合してなる加工米飯用ほぐし剤。 A loosening agent for processed rice, comprising at least one polysaccharide selected from ι carrageenan, λ carrageenan and fucoidan . ιカラギーナン、λカラギーナン及びフコイダンから選ばれた少なくとも一種の多糖類を生米100重量部に対して0.05〜10重量部の割合で、炊飯前又は炊飯後に添加することを特徴とする加工米飯の製造方法。 Processed cooked rice characterized by adding at least one polysaccharide selected from ι carrageenan, λ carrageenan and fucoidan at a ratio of 0.05 to 10 parts by weight with respect to 100 parts by weight of raw rice before or after cooking. Manufacturing method.
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