JP4500911B2 - Water shielding material and composite water shielding sheet using the same - Google Patents
Water shielding material and composite water shielding sheet using the same Download PDFInfo
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- JP4500911B2 JP4500911B2 JP2000227357A JP2000227357A JP4500911B2 JP 4500911 B2 JP4500911 B2 JP 4500911B2 JP 2000227357 A JP2000227357 A JP 2000227357A JP 2000227357 A JP2000227357 A JP 2000227357A JP 4500911 B2 JP4500911 B2 JP 4500911B2
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- water
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- impervious
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Description
【0001】
【発明の属する技術分野】
本発明は、遮水用材料、特に地中への透水を遮断するための遮水用材料及びそれを用いた複合遮水シートに関する。
【0002】
【従来技術】
廃棄物最終処分場、ラグーン、貯水池等に施される遮水工には、塩化ビニール、ゴム、高密度又は低密度ポリエチレン、エチレンビニルアセテート等の材料を用いた一重構造の遮水シートが使用されている。ところが、上記のような一重構造では、廃棄物に混じる鉄筋、鉄くず片、岩石等により遮水シートに穴が開き、遮水構造が破壊されるおそれがある。
【0003】
かかる問題を解消するために多重構造を採用することが提案されている。例えば、ベントナイト、ソイルセメント等の遮水性土質層で遮水層を形成して、その上から遮水シートを敷設する方法(特開平11−10105号)等が知られている。
【0004】
しかしながら、この方法では、遮水層の耐久性が不十分であり、改善の余地がある。すなわち、廃棄物の重量、地盤変動等により遮水層が部分的に加圧された場合、遮水層が変形して凹凸が生じたり、ひび割れが発生することによって遮水性土質層の遮水性破壊あるいは遮水シートの破断が起こりやすくなるという問題がある。
【0005】
この問題を回避するには、不陸がないように基礎地盤を均一に構築することが必要となるが、そのように施工しようとすると莫大な手間がかかる。特に、陸上よりも作業面で制約を受ける海洋処分場の遮水工において、遮水層を均一にすることは、施工性、経済性等の点からみて現実的に不可能である。
【0006】
【発明が解決しようとする課題】
以上のようなことから、部分的な加圧により容易に崩壊されない遮水層を形成できる材料の開発が切望されているのが現状である。
【0007】
従って、本発明の主たる目的は、特に、耐久性に優れた遮水層を与える遮水用材料を提供することにある。
【0008】
【課題を解決するための手段】
本発明者は、従来技術の問題に鑑み、鋭意研究を重ねた結果、特定の材料を遮水用材料として用いることにより、上記目的を達成できることを見出し、ついに本発明を完成するに至った。
【0009】
すなわち、本発明は、下記の遮水用材料及びそれを用いた複合遮水シートに係るものである。
【0010】
1.(1)厚さ方向の透水係数が10-6cm/sec以下であり、(2)5kgf/cm2での厚さ変形率が50〜98%であることを特徴とする遮水用材料。
【0011】
2.遮水性材料で形成された第1シート及び第2シートの間に中間層を有する複合遮水シートであって、中間層として上記第1項の遮水用材料を用いたことを特徴とする複合遮水シート。
【0012】
【発明の実施の形態】
1.遮水用材料
本発明の遮水用材料は、(1)厚さ方向の透水係数が10-6cm/sec以下であり、(2)5kgf/cm2での厚さ変形率が50〜98%であることを特徴とする。
【0013】
本発明材料の厚さ方向の透水係数は通常10-6cm/sec以下、好ましくは10-10cm/sec以下である。このような範囲に設定することによって、本発明材料が粘土層以上の高い遮水性能を発揮することができる。透水係数が10-6cm/secを超える場合は所望の遮水性能が得られなくなるおそれがある。なお、透水係数の下限は特に制限されないが通常10-10cm/sec程度とすれば良い。
【0014】
本発明材料は、5kgf/cm2での厚さ変形率が50〜98%(好ましくは60〜98%)である。変形率が50%未満である場合又は98%を超える場合は、投入される廃棄物の重み、地底の地盤変形等により変形・ひび割れして所望の遮水性能が発揮されなくなるおそれがある。
【0015】
本発明材料としては、上記の透水係数及び変形率を充足するものであれば特に限定されず、公知の材料を使用することができる。例えば、有機材料、無機材料及びこれらの混合物のいずれも使用することができる。有機材料としては、例えばポリエステル、ポリプロピレン、ポリエチレン、ポリウレタン等の樹脂類、天然ゴム、イソプレン、ブチルゴム、ネオプレン等のゴム類等を挙げることができる。これら有機材料はエラストマーを好適に使用することもできる。また、無機材料としては、例えばセメント・コンクリート、石膏、粘土類、珪酸及びその塩類等が挙げられる。これらは1種又は2種以上で用いることができる。特に、本発明では、樹脂類を使用することが好ましく、その中でもポリウレタンが好ましい。
【0016】
また、本発明材料の一部又は全部として、気孔率10%以上、好ましくは10〜50%の発泡体を好適に使用することができる。このような材料としては、例えば発泡ポリウレタン、発泡スチロール、発泡エポキシ樹脂等を挙げることができる。
【0017】
本発明材料では、上記透水係数及び厚さ変形率を維持できる範囲内において、増量材等を必要に応じて配合することもできる。例えば、金属系充填材(鉄球、鉄粉等)、無機系充填材(砂利、石膏、セメント、ベントナイト等)、有機系充填材(ポリマー塊、ポリマーパウダー等)を適宜配合することができる。これらは廃材等も使用することができる。配合量は、用いる増量材の種類等に応じて適宜設定すれば良いが、通常は本発明材料中10〜70体積%程度とすれば良い。
【0018】
増量材としては、特に、水膨潤性材料を使用することが好ましい。上記材料は、水分を吸収して体積膨張するものであれば特に限定されない。例えば、アクリル系高分子材料等の有機材料、ベントナイト等の無機材料を使用できる。これらは市販品を用いることもできる。本発明では、特にポリビニルアルコール系高分子材料及びアクリル系高分子材料の少なくとも1種を好適に用いることができる。ポリビニルアルコール系高分子材料としては、例えばポリビニルアルコール及びその誘導体が挙げられる。また、アクリル系高分子材料としては、例えばアクリル系樹脂、ポリメタクリル酸メチル等が挙げられる。
【0019】
本発明の遮水用材料の形態は特に限定的ではなく、使用目的等に応じて適宜設計すれば良い。特に、廃棄物最終処分場、ラグーン、貯水池等における施工のように、地中への透水を遮断するために基礎地盤上に敷設して施工する場合には、厚さ10mm以上(好ましくは10〜1000mm)のシート状とすることが好ましい。
【0020】
本発明の遮水用材料は、特に、遮水性材料で形成された第1シート及び第2シートの間に中間層を有する複合遮水シートの当該中間層として用いられることが好ましい。これによって、より優れた遮水性、施工性等を発揮することができる。
【0021】
上記の複合遮水シートについては、その型式、大きさ等は特に限定されない。第1シート及び第2シートを構成する遮水性材料自体も限定されず、公知のもの又は市販品を使用することができる。例えば、合成ゴム系遮水性シート、合成樹脂系遮水性シート、アスファルト系遮水シート、ベントナイト系遮水性シート等を使用することができる。なお、第1シートと第2シートの材質等は同一であっても良いし、あるいは互いに異なっていても良い。
【0022】
本発明材料は、予めシート状に成形したものも使用できるが、好ましくは本発明材料の液状原料を用い、現場で予め敷設された第1シート及び第2シートの間に液状原料を注入することによっても形成できる。すなわち、本発明材料は、液状原料から得られるものであることが好ましい。この場合、施工時における液状原料の粘度は通常1000ポイズ以下(20℃)、好ましくは100ポイズ以下(20℃)とする。液状原料としては、熱可塑性樹脂等のように遮水用材料そのものが液化しているもののほか、二液型ポリウレタン等のように反応等により遮水用材料を構成し得る成分からなるものであっても良い。例えば、遮水用材料の液状原料を用い、その液状原料を混合しながら注入することによりはじめて遮水用材料が第1シート及び第2シートの間で形成されるようにしても良い。遮水用材料の形成は、反応硬化、膨潤、結晶化、発泡、高粘度化等のいずれの形態によるものであっても良い。このように、本発明材料の原料として、液状原料を用いる場合には、施工性、経済性、作業性等の点で非常に有利になる。
2.複合遮水シート
本発明の複合遮水シートは、遮水性材料で形成された第1シート及び第2シートの間に中間層を有する複合遮水シートであって、中間層として本発明の遮水用材料を用いたことを特徴とする。
【0023】
遮水性材料で形成された第1シート及び第2シートは、前記1でも説明したとおり、公知のもの又は市販品を使用することができる。
【0024】
本発明複合遮水シートのシート全体としての比重は特に限定されず、製品の用途、使用目的等に応じて適宜設定すれば良い。例えば、海洋処分場を遮水施工する場合は、通常1以上、好ましくは1.3以上の比重であることが好ましい。比重の調整は、例えば前記の増量材の種類の選定等により実施できる。
【0025】
複合遮水シート1による施工は、例えば図1に示すように、廃棄物最終処分場に法面(基礎地盤)に第1シート及び第2シートを敷設する。各シートは、敷設の際に熱融着、高周波ウェルダー、接着、縫製等の公知の連結方法により複数連結することができる。また、この連結作業は、予め所定の長さになるように工場等において実施することもできる。次いで、中間層として遮水用材料の液状原料を注入装置用5から注入ホース6を経て注入される。水膨潤性材料を用いる場合は、例えば水膨潤性材料を予め水と混合し、これと液状原料とを混合し、得られた混合物を注入すれば良い。なお、第1シートと第2シートとの縁端部は注入された液状原料が漏れないように熱融着、接着等により接合する。液状原料を注入した後、注入ホースを取り出し、注入された液状原料により遮水用材料が形成(硬化)されることによって施工が完了する。
【0026】
【発明の効果】
本発明によれば、特定の物性をもつ材料を遮水用材料、特に地中への透水を遮断するために基礎地盤上に施工される遮水用材料として用いるので、優れた耐久性を発揮することができる。特に、遮水性材料で形成された第1シート及び第2シートの間に中間層を有する複合遮水シートの当該中間層という特定の用途に用いる場合には、より優れた遮水性を発揮することができる。
【0027】
また、20℃での粘度が1000ポイズ以下である液状原料から得られる遮水用材料を用いる場合には、現場での注入による遮水層の形成が可能となるので、作業性、施工性、経済性等の面においても非常に有利である。特に、作業面で多くの制約がある海洋処分場での遮水工事にとって有効である。
【0028】
【実施例】
以下、実施例を示し、本発明の特徴とするところをより一層明確にする。但し、本発明の範囲は、これら実施例に限定されるものではない。
【0029】
実施例1〜3
第1シート及び第2シートとして軟質PVC(塩化ビニル樹脂)シートを用い、両シートを積層した。両シートの縁端部は、液状原料の注入口以外の部分を熱融着して袋状とした。次いで、両シート間の距離(厚さ)が50mmとなるように、表1に示す遮水用材料(液状)を注入口から両シート間に注入し、この材料を硬化させた。
【0030】
遮水用材料の注入直前及び硬化後(注入後3日間経過後)の粘度(20℃)を測定した。また、硬化後の遮水用材料の厚さ方向の透水係数及び厚さ変形率を測定した。これらの結果を表1に示す。
【0031】
【表1】
【0032】
なお、エポキシ樹脂は商品名「ボンドE2420」(コニシ(株)製)、ポリウレタンは商品名「U−8000(二液タイプ)」(横浜ゴム製)をそれぞれ使用した。
【0033】
また、表1中の粘度、透水係数、厚さ変形率、ひび割れ発生の有無については以下の方法により測定した。
・粘度
20℃での粘度をB型粘度計で測定した。
・透水係数
遮水用材料の厚さ方向(50mm)の透水係数について、JIS−A−1218の規定に準じて測定した。
・厚さ変形率
遮水用材料に5kg/cm2の荷重を負荷し、1時間後の厚さを調べ、その値をもとの厚さで除した値を示した。
・ひび割れ発生の有無
1mの高さから遮水用材料上に10kg(直径約14cm)の鉄球を落下させ、材料表面のひび割れの発生の有無を肉眼で観察した。
【0034】
試験例1
実施例2において増量材を使用した場合の水膨潤性を調べた。
【0035】
まず、増量材として表2に示す材料を実施例2のエポキシ樹脂と同体積量用い、これと増量材の200%(重量比)の水とを混合した。次いで、この混合物とエポキシ樹脂とを混合して遮水用材料を調製した後、この遮水用材料(液状)を実施例2と同様にして注入し、硬化させた。
【0036】
水膨潤性は、各材料の体積増加率により評価した。なお、体積増加率は、下記式により求めた。
【0037】
体積増加率(%)=
[(材料及び水混合後の体積−エポキシ樹脂の体積)/材料体積]×100
【0038】
【表2】
【図面の簡単な説明】
【図1】本発明複合遮水シートを用いた施工方法の一例を示す図である。[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a water shielding material, in particular, a water shielding material for blocking water penetration into the ground and a composite water shielding sheet using the same.
[0002]
[Prior art]
Single-layer water-proof sheets using materials such as vinyl chloride, rubber, high-density or low-density polyethylene, and ethylene vinyl acetate are used for water-blocking works applied to waste final disposal sites, lagoons, and reservoirs. ing. However, in the single structure as described above, there is a possibility that a hole is opened in the water shielding sheet due to reinforcing bars, iron scraps, rocks and the like mixed in the waste, and the water shielding structure is destroyed.
[0003]
In order to solve this problem, it has been proposed to employ a multiple structure. For example, a method of forming a water-impervious layer with a water-impervious soil layer such as bentonite and soil cement and laying a water-impervious sheet thereon is known (Japanese Patent Laid-Open No. 11-10105).
[0004]
However, in this method, the durability of the water shielding layer is insufficient and there is room for improvement. In other words, if the impermeable layer is partially pressurized due to the weight of the waste, ground fluctuation, etc., the impermeable layer may be deformed to cause unevenness or cracks, resulting in impermeable destruction of the impermeable soil layer. Alternatively, there is a problem that the water shielding sheet is easily broken.
[0005]
In order to avoid this problem, it is necessary to uniformly construct the foundation ground so that there is no unevenness. In particular, it is practically impossible to make the water-impervious layer uniform from the viewpoint of workability, economy, and the like in a water-impervious construction at an ocean disposal site that is more restricted in terms of work than on land.
[0006]
[Problems to be solved by the invention]
In view of the above, there is an urgent need for the development of a material that can form a water shielding layer that is not easily destroyed by partial pressurization.
[0007]
Therefore, a main object of the present invention is to provide a water shielding material that provides a water shielding layer excellent in durability.
[0008]
[Means for Solving the Problems]
As a result of intensive studies in view of the problems of the prior art, the present inventor has found that the above object can be achieved by using a specific material as a water shielding material, and has finally completed the present invention.
[0009]
That is, the present invention relates to the following water shielding material and a composite water shielding sheet using the same.
[0010]
1. (1) hydraulic conductivity in the thickness direction is less than or equal 10 -6 cm / sec, (2 ) water-impervious material, wherein the thickness deformation rate at 5 kgf / cm 2 is 50 to 98%.
[0011]
2. A composite water-impervious sheet having an intermediate layer between a first sheet and a second sheet formed of a water-impervious material, wherein the water-impervious material according to the first item is used as an intermediate layer Water shielding sheet.
[0012]
DETAILED DESCRIPTION OF THE INVENTION
1. Water Impermeable Material The water impermeable material of the present invention has (1) a water permeability coefficient of 10 −6 cm / sec or less in the thickness direction, and (2) a thickness deformation rate of 50 to 98 at 5 kgf / cm 2. %.
[0013]
The water permeability coefficient in the thickness direction of the material of the present invention is usually 10 −6 cm / sec or less, preferably 10 −10 cm / sec or less. By setting to such a range, the material of the present invention can exhibit a high water shielding performance higher than that of the clay layer. If the water permeability exceeds 10-6 cm / sec, the desired water shielding performance may not be obtained. The lower limit of the water permeability coefficient is not particularly limited, but is usually about 10 −10 cm / sec.
[0014]
The material of the present invention has a thickness deformation rate of 50 to 98% (preferably 60 to 98%) at 5 kgf / cm 2 . When the deformation rate is less than 50% or exceeds 98%, there is a possibility that the desired water-insulating performance may not be exhibited due to deformation / cracking due to the weight of the waste to be input, ground deformation of the ground.
[0015]
The material of the present invention is not particularly limited as long as it satisfies the above water permeability coefficient and deformation rate, and a known material can be used. For example, any of organic materials, inorganic materials, and mixtures thereof can be used. Examples of the organic material include resins such as polyester, polypropylene, polyethylene, and polyurethane, and rubbers such as natural rubber, isoprene, butyl rubber, and neoprene. As these organic materials, elastomers can be preferably used. Examples of the inorganic material include cement / concrete, gypsum, clays, silicic acid and salts thereof. These can be used alone or in combination of two or more. In particular, in the present invention, it is preferable to use resins, and among them, polyurethane is preferable.
[0016]
Further, as part or all of the material of the present invention, a foam having a porosity of 10% or more, preferably 10 to 50% can be suitably used. Examples of such materials include foamed polyurethane, foamed polystyrene, and foamed epoxy resin.
[0017]
In the material of the present invention, an extender or the like can be blended as necessary within the range in which the water permeability coefficient and thickness deformation rate can be maintained. For example, a metallic filler (iron ball, iron powder, etc.), an inorganic filler (gravel, gypsum, cement, bentonite, etc.), and an organic filler (polymer lump, polymer powder, etc.) can be appropriately blended. These can also be used as waste materials. The blending amount may be appropriately set according to the type of the extender to be used, but is usually about 10 to 70% by volume in the material of the present invention.
[0018]
As the extender, it is particularly preferable to use a water-swellable material. The material is not particularly limited as long as it absorbs moisture and expands in volume. For example, an organic material such as an acrylic polymer material or an inorganic material such as bentonite can be used. A commercial item can also be used for these. In the present invention, at least one of a polyvinyl alcohol polymer material and an acrylic polymer material can be preferably used. Examples of the polyvinyl alcohol-based polymer material include polyvinyl alcohol and derivatives thereof. Examples of the acrylic polymer material include acrylic resin and polymethyl methacrylate.
[0019]
The form of the water shielding material of the present invention is not particularly limited, and may be appropriately designed according to the purpose of use. In particular, when constructing and laying on the foundation ground in order to block the water permeation into the ground, such as construction in waste final disposal sites, lagoons, reservoirs, etc., the thickness is 10 mm or more (preferably 10 to 10 mm). 1000 mm) is preferable.
[0020]
The water shielding material of the present invention is particularly preferably used as an intermediate layer of a composite water shielding sheet having an intermediate layer between a first sheet and a second sheet formed of a water shielding material. As a result, more excellent water shielding, workability and the like can be exhibited.
[0021]
About said composite water-proof sheet | seat, the model, a magnitude | size, etc. are not specifically limited. The water-impervious material itself that constitutes the first sheet and the second sheet is not limited, and a known or commercially available product can be used. For example, a synthetic rubber-based water-impervious sheet, a synthetic resin-based water-impervious sheet, an asphalt-based water-impervious sheet, a bentonite-based water-impervious sheet, and the like can be used. In addition, the material etc. of the 1st sheet | seat and the 2nd sheet | seat may be the same, and may mutually differ.
[0022]
The material of the present invention can be used in the form of a sheet in advance, but preferably the liquid material of the material of the present invention is used, and the liquid material is injected between the first sheet and the second sheet previously laid on site. Can also be formed. That is, the material of the present invention is preferably obtained from a liquid raw material. In this case, the viscosity of the liquid raw material at the time of construction is usually 1000 poise or less (20 ° C.), preferably 100 poise or less (20 ° C.). The liquid raw material includes components that can constitute the water shielding material by reaction or the like, such as a two-component polyurethane, in addition to those in which the water shielding material itself is liquefied, such as a thermoplastic resin. May be. For example, the water shielding material may be formed between the first sheet and the second sheet only by using a liquid raw material for the water shielding material and injecting the liquid raw material while mixing. The water shielding material may be formed in any form such as reaction hardening, swelling, crystallization, foaming, and increasing the viscosity. Thus, when a liquid raw material is used as the raw material for the material of the present invention, it is very advantageous in terms of workability, economy, workability, and the like.
2. The composite water-impervious sheet of the present invention is a composite water-impervious sheet having an intermediate layer between a first sheet and a second sheet formed of a water-impervious material, and the water-impervious sheet of the present invention is used as an intermediate layer. It is characterized by using a material.
[0023]
A well-known thing or a commercial item can be used for the 1st sheet | seat and 2nd sheet | seat which were formed with the water-impervious material as 1 said.
[0024]
The specific gravity of the composite water-impervious sheet of the present invention as a whole is not particularly limited, and may be set as appropriate according to the use of the product, the purpose of use, and the like. For example, when a marine disposal site is water-tightly constructed, the specific gravity is usually 1 or more, preferably 1.3 or more. The specific gravity can be adjusted, for example, by selecting the type of the weight increasing material.
[0025]
For example, as shown in FIG. 1, the composite water-impervious sheet 1 is constructed by laying the first sheet and the second sheet on the slope (foundation ground) at the waste final disposal site. When laying, a plurality of sheets can be connected by a known connection method such as heat fusion, high frequency welder, adhesion, and sewing. In addition, this connecting operation can be performed in a factory or the like so as to have a predetermined length in advance. Next, a liquid material of a water shielding material is injected as an intermediate layer from the
[0026]
【The invention's effect】
According to the present invention, a material having specific physical properties is used as a water shielding material, in particular, as a water shielding material to be constructed on the foundation ground in order to block water penetration into the ground, so that it exhibits excellent durability. can do. In particular, when used for a specific application of the intermediate layer of the composite water-impervious sheet having an intermediate layer between the first sheet and the second sheet formed of the water-impervious material, exhibit better water-impervious property. Can do.
[0027]
In addition, when using a water shielding material obtained from a liquid raw material having a viscosity at 20 ° C. of 1000 poise or less, it becomes possible to form a water shielding layer by injection on site, workability, workability, It is very advantageous in terms of economy and the like. In particular, it is effective for water-blocking work at marine disposal sites where there are many restrictions on work.
[0028]
【Example】
Hereinafter, examples will be shown to further clarify the features of the present invention. However, the scope of the present invention is not limited to these examples.
[0029]
Examples 1-3
A soft PVC (vinyl chloride resin) sheet was used as the first sheet and the second sheet, and both sheets were laminated. The edge portions of both sheets were formed into a bag shape by thermally fusing portions other than the liquid material inlet. Next, a water shielding material (liquid) shown in Table 1 was injected between the two sheets from the injection port so that the distance (thickness) between the two sheets was 50 mm, and the material was cured.
[0030]
The viscosity (20 ° C.) immediately before injection of the water shielding material and after curing (after 3 days from injection) was measured. Further, the water permeability coefficient and thickness deformation rate in the thickness direction of the water shielding material after curing were measured. These results are shown in Table 1.
[0031]
[Table 1]
[0032]
In addition, the brand name "Bond E 2420" (made by Konishi Co., Ltd.) was used for the epoxy resin, and the brand name "U-8000 (two-component type)" (manufactured by Yokohama Rubber) was used for the polyurethane.
[0033]
The viscosity, water permeability, thickness deformation rate, and presence / absence of cracks in Table 1 were measured by the following methods.
-Viscosity at 20 ° C was measured with a B-type viscometer.
-Water permeability coefficient The water permeability coefficient in the thickness direction (50 mm) of the water-impervious material was measured in accordance with JIS-A-1218.
-Thickness deformation rate A load of 5 kg / cm 2 was applied to the water shielding material, the thickness after 1 hour was examined, and the value obtained by dividing the value by the original thickness was shown.
-Whether or not cracking occurred A 10-kg (about 14 cm in diameter) iron ball was dropped on the water shielding material from a height of 1 m, and the presence or absence of cracking on the surface of the material was observed with the naked eye.
[0034]
Test example 1
In Example 2, the water swellability when the extender was used was examined.
[0035]
First, the material shown in Table 2 as an extender was used in the same volume as the epoxy resin of Example 2, and this was mixed with 200% (weight ratio) of the extender. Next, the mixture and the epoxy resin were mixed to prepare a water shielding material, and then the water shielding material (liquid) was injected and cured in the same manner as in Example 2.
[0036]
The water swellability was evaluated by the volume increase rate of each material. In addition, the volume increase rate was calculated | required by the following formula.
[0037]
Volume increase rate (%) =
[(Volume after mixing of material and water-volume of epoxy resin) / material volume] × 100
[0038]
[Table 2]
[Brief description of the drawings]
FIG. 1 is a diagram showing an example of a construction method using a composite water shielding sheet of the present invention.
Claims (4)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000227357A JP4500911B2 (en) | 2000-07-27 | 2000-07-27 | Water shielding material and composite water shielding sheet using the same |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000227357A JP4500911B2 (en) | 2000-07-27 | 2000-07-27 | Water shielding material and composite water shielding sheet using the same |
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| Publication Number | Publication Date |
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| JP2002035711A JP2002035711A (en) | 2002-02-05 |
| JP4500911B2 true JP4500911B2 (en) | 2010-07-14 |
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| JP2000227357A Expired - Lifetime JP4500911B2 (en) | 2000-07-27 | 2000-07-27 | Water shielding material and composite water shielding sheet using the same |
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| JP2006026930A (en) * | 2004-07-12 | 2006-02-02 | Okumura Corp | Double impermeable sheet and method for producing the same |
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