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JP4576487B2 - Breads using sweet potato shochu distilled liquor and method for producing the same - Google Patents
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JP4576487B2 - Breads using sweet potato shochu distilled liquor and method for producing the same - Google Patents

Breads using sweet potato shochu distilled liquor and method for producing the same Download PDF

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JP4576487B2
JP4576487B2 JP2006063434A JP2006063434A JP4576487B2 JP 4576487 B2 JP4576487 B2 JP 4576487B2 JP 2006063434 A JP2006063434 A JP 2006063434A JP 2006063434 A JP2006063434 A JP 2006063434A JP 4576487 B2 JP4576487 B2 JP 4576487B2
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超 章
誠 吉元
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本発明は、甘藷焼酎蒸留粕の液部を使用した栄養価が高く食感や風味に優れたパン類及びその製造方法に関するものである。   The present invention relates to breads having a high nutritional value and excellent texture and flavor using a liquid portion of sweet potato shochu distilled spirits and a method for producing the same.

わが国では、年間約85万トン(平成16年度調べ)の焼酎蒸留粕が排出され、このうち15万2千トンが海洋投棄されている。2000年4月からロンドン条約により、焼酎蒸留粕の海洋投棄が原則禁止され、海洋投棄に替わる経済的に環境低負荷型の陸上処理技術を開発しているが、コスト面から大規模処理プラントの建設とリサイクル品の販路開拓はなかなか進まないのが実情である。   In Japan, about 850,000 tons of shochu distillery is discharged annually (according to FY2004), of which 152,000 tons are dumped into the ocean. Since April 2000, the London Convention has prohibited the dumping of shochu distilleries into the ocean, and has been developing economically environmentally friendly land treatment technology to replace ocean dumping. The fact is that the development of sales channels for construction and recycled products has hardly progressed.

焼酎蒸留粕の水分量は95%以上、炭水化物2.5%前後、その他たんぱく質、脂質、ミネラル類(ナトリウム、カルシウム、カリウム、マグネシウム、リン、鉄、銅、亜鉛等)、ビタミン類(B1、B2、B6、C)、クエン酸、アミノ酸などを含む、機能性を持った有用な食材である。そこで、従来から固液分離した甘藷焼酎粕の固形分を健康食品素材として利用する方法が提案されている(例えば、特許文献1参照。)。   The water content of shochu distilled spirits is 95% or more, carbohydrates around 2.5%, other proteins, lipids, minerals (sodium, calcium, potassium, magnesium, phosphorus, iron, copper, zinc, etc.), vitamins (B1, B2) , B6, C), citric acid, amino acids and the like are useful foods with functionality. Then, the method of utilizing the solid content of the sweet potato shochu separated into solid and liquid as a health food material conventionally is proposed (for example, refer patent document 1).

特開2004−121221号公報JP 2004-121221 A

しかしながら、焼酎蒸留粕には特有の臭気(酸臭、もろみ臭、発酵臭)があり、食品素材として利用した場合、この臭気を除去することが最大の課題となっている。また、焼酎粕の液体部分の利用については、クエン酸飲料や酢酸飲料等が製造・販売されている。本発明では、固液分離した焼酎蒸留粕の液体部分をイースト発酵させるパン類の原料水として使用することで、焼酎蒸留粕の産業廃棄物処理上の問題を解決すると共に、焼酎蒸留粕特有の臭気を除去し、栄養価が高く、風味・食感ともに優れた甘藷焼酎蒸留粕液部を使用したパン類及びその製造方法を提供することを目的とする。   However, shochu distilled spirit has a characteristic odor (acid odor, moromi odor, fermentation odor), and when it is used as a food material, removal of this odor has become the biggest issue. In addition, citric acid beverages and acetic acid beverages are manufactured and sold for use of the liquid portion of shochu. In the present invention, the liquid portion of the shochu-distilled rice cake that has been separated into solid and liquid is used as raw material water for breads to be fermented with yeast, thereby solving the problems in the treatment of industrial waste of shochu-distilled rice cake and being unique to shochu-distilled rice cake. An object of the present invention is to provide breads using a sweet potato shochu distilled liquor that removes odor, has high nutritional value, and has excellent flavor and texture, and a method for producing the same.

すなわち、本発明は、焼酎蒸留粕液部の持つ機能性を食品の材料として用いることで、焼酎粕に含まれる有効成分を活用し、健康に有益な食品を提供すると共に、焼酎蒸留粕の再資源化を図るものである。   That is, the present invention uses the functionality of the shochu-distilled liquid portion as a food material, thereby utilizing the active ingredients contained in the shochu to provide a food that is beneficial to health, and reusing the shochu-distilled rice cake. It is intended to recycle resources.

上記目的を達成するため、本発明によるパン類は、甘藷焼酎蒸留粕液部と穀物類粉末とを含有する生地を用いて製造されるパンにおいて、製パン水として甘藷焼酎蒸留粕液部を濃縮して使用することを第1の特徴とし、生地がイースト発酵されることを第2の特徴とする。 In order to achieve the above object, the bread according to the present invention concentrates the sweet potato shochu distilled liquor part as bread-making water in a bread produced using a dough containing the sweet potato shochu distilled liquor part and cereal powder. And the second feature is that the dough is yeast-fermented.

また、本発明によるパン類の製造方法は、甘藷焼酎蒸留粕を固液分離して得られた蒸留粕液部を濃縮し当該濃縮蒸留粕液部と穀物類粉末及びイースト菌と混練してパン生地を得、これを定法の温度にて一次発酵及び成形後二次発酵を行った後焼成してなることを特徴とする。 In addition, the method for producing bread according to the present invention comprises concentrating a distilled liquid portion obtained by solid-liquid separation of a sweet potato shochu distilled spirit, and kneading the concentrated distilled liquid portion with cereal powder and yeast. It is characterized in that it is fired after performing primary fermentation and post-molding secondary fermentation at a conventional temperature.

その場合、甘藷の品種がムラサキマサリ又はコガネセンガンであることが好ましい。   In that case, it is preferable that the varieties of sweet potato are Murasakimasari or Koganesengan.

本発明により得られたパン類は、水を原料として製造されたパン類と比較して、ミネラル類(ナトリウム、リン、鉄、カリウム、マグネシウム、亜鉛、マンガン)、ビタミンB1、ビタミンB2、ビタミンB6、葉酸、パントテン酸、ナイアシンなどが高かった。アミノ酸成分も若干増え、近年、その機能性が注目され出したγ−アミノ酪酸(GABA)は2倍以上含有される。また、機能性成分のクエン酸、ポリフェノールも著しく増加した。   The breads obtained according to the present invention are minerals (sodium, phosphorus, iron, potassium, magnesium, zinc, manganese), vitamin B1, vitamin B2, vitamin B6, compared with breads produced using water as a raw material. Folic acid, pantothenic acid, niacin, etc. were high. The amino acid component is also slightly increased, and γ-aminobutyric acid (GABA), whose functionality has been attracting attention in recent years, is contained twice or more. In addition, the functional components citric acid and polyphenols also increased significantly.

以下、本発明を実施例に基づいて更に詳細に説明する。 Hereinafter, the present invention will be described in more detail based on examples.

コガネセンガン並びにムラサキマサリを原料とした焼酎もろみの蒸留後得られる甘藷焼酎蒸留粕を固液分離する。プレスフィルター等による圧搾濾過若しくは、デカンタ等の遠心分離による分離を行い液体部(以下、焼酎醪という)のみ得た。この焼酎醪を製パンの原料水の代わりとしてパン生地に練り込んだ。製パンでの材料の分量は、小麦粉(強力粉)400g、イースト菌(商品名:日清スーパーカメリヤドライイースト:日清フーズ株式会社 DON製)4g、焼酎醪300ccを用いて捏ねた。この生地を定法の温度にて一次発酵、成形後二次発酵と進め焼成してパンを得た。   Solid-liquid separation of the sweet potato shochu distilled spirit obtained after distillation of shochu moromi mash using Koganesengan and Murasakimasari. Only a liquid part (hereinafter referred to as shochu) was obtained by pressure filtration with a press filter or the like, or separation by centrifugal separation with a decanter or the like. This shochu was kneaded into bread dough instead of raw water for bread making. The amount of the material in breadmaking was kneaded using 400 g of wheat flour (strong flour), 4 g of yeast (trade name: Nisshin Super Camellia Dry Yeast: Nisshin Foods Co., Ltd., DON), and 300 cc of shochu. This dough was baked by proceeding with primary fermentation at a standard temperature, followed by secondary fermentation after molding, and bread was obtained.

こうして得られたパンを52名のパネラーに試食させ、パンの外観、味、匂いについて官能試験を実施した。良好、普通、良くないとして人数で表した。その結果を表1に示す。   The bread thus obtained was tasted by 52 panelists, and a sensory test was conducted on the appearance, taste and smell of the bread. Expressed by number of people as good, normal, or bad. The results are shown in Table 1.

Figure 0004576487
Figure 0004576487

表1から分かるように、焼酎醪パンは、外観、味、匂いともに普通のパンより良好で同等以上であるとの結果が得られた。また、コガネセンガン焼酎醪パンは甘味があり、香ばしい。ムラサキマサリ焼酎醪パンは、赤紫色で色彩は鮮やかで酸味があるとの感想が寄せられた。   As can be seen from Table 1, shochu bread was better than ordinary bread in terms of appearance, taste and smell, and the result was equivalent or better. Koganesengan shochu bread is sweet and fragrant. The impression that Murasakimasari shochu bread is reddish purple and the color is bright and sour.

廃棄物処理物としての焼酎蒸留粕液部の減容化を増加させるためには、焼酎醪の濃縮を図ることが望ましい。また、濃縮により、タンパク質、繊維質、色素などの成分値が高くなる。しかしながら、濃縮によるパン酵母の増殖阻害が発現するおそれが予測された。そこで、濃縮した焼酎醪によるパン酵母の培養試験を行った。その結果を表2に示す。試験は焼酎醪(原液、2.5倍、5.0倍、7.5倍、10倍濃縮液、また1%グルコースを添加した液)をSaccharomyces cerevisiae IFO.2044 30℃、48hrの条件にて培養した。   In order to increase the volume reduction of the shochu distilled liquor portion as a waste treatment product, it is desirable to concentrate the shochu. Moreover, component values, such as protein, a fiber, and a pigment | dye, become high by concentration. However, it was predicted that concentration of baker's yeast might be inhibited by concentration. Therefore, a baker's yeast culture test using concentrated shochu was conducted. The results are shown in Table 2. The test consisted of shochu (stock solution, 2.5-fold, 5.0-fold, 7.5-fold, 10-fold concentrated solution, and a solution containing 1% glucose) Saccharomyces cerevisiae IFO. 2044 Cultured at 30 ° C. for 48 hours.

Figure 0004576487
Figure 0004576487

表2から分かるように、1%グルコース添加液はムラサキマサリ焼酎醪では5倍濃縮まで、コガネセンガン焼酎醪では7.5倍濃縮までパン酵母を増殖した。それ以上濃縮すると阻害効果が見られた。すなわち、焼酎蒸留粕の液部の発酵については、イースト菌(パン酵母)の増殖阻害が起こることなく、また、液部のみでの増殖は見られなかった。このことは、パン生地を製造する際、通常使用する水の代用として、常法による配合と発酵時間でパンを焼成することが可能であることを示唆するものである。   As can be seen from Table 2, the 1% glucose-added solution grew baker's yeast up to 5-fold concentration in Murasakisaki shochu and 7.5-fold concentration in Koganesengan shochu. When it was further concentrated, an inhibitory effect was observed. That is, regarding the fermentation of the liquid part of the shochu distiller, the growth inhibition of yeast (baker's yeast) did not occur, and the growth only in the liquid part was not observed. This suggests that, when producing bread dough, bread can be baked with conventional blending and fermentation time as a substitute for normally used water.

実際に濃縮した焼酎醪を用いてパン生地の発酵を行った。結果を表3に示す。   Bread dough was fermented using actually concentrated shochu. The results are shown in Table 3.

Figure 0004576487
Figure 0004576487

表3から分かるように、コガネセンガン焼酎醪、ムラサキマサリ焼酎醪共に、7.5倍以上の濃縮率では、パンの発酵を阻害することが分かった。そして、コガネセンガン焼酎醪では5.0倍濃縮以下、ムラサキマサリ焼酎醪では2.5倍濃縮以下であれば、順調にパン生地の発酵が行われるこという結果が得られた。   As can be seen from Table 3, it was found that both the Koganesengan shochu and the purple shochu shochu inhibited the fermentation of bread at a concentration rate of 7.5 times or more. The result showed that the bread dough was smoothly fermented if it was 5.0 times or less concentrated in Koganesengan shochu and 2.5 times or less concentrated in Murasaki shochu shochu.

また、客観的なパンの品質評価法として、焼成後の新鮮なパンであれば、体積と重量から比容積を算出し、この値からパンの品質を評価することができる。貯蔵中におけるパンの場合には、パンを押し潰したとき、つまり圧縮したときの硬度あるいは軟度の変化を老化度として測定する方法と、貯蔵(老化)に伴って認められる各種成分の変化、とくにデンプンの老化、あるいは再結晶化の程度を物理化学的に測定する方法がある。   As an objective bread quality evaluation method, if the bread is fresh bread after baking, the specific volume can be calculated from the volume and weight, and the quality of the bread can be evaluated from this value. In the case of bread during storage, when the bread is crushed, that is, the method of measuring the change in hardness or softness when compressed as a degree of aging, and changes in various components observed with storage (aging), In particular, there is a method of physicochemically measuring the degree of starch aging or recrystallization.

そこで、パン内相部分から25mm四方に切り取ったダイス(25×25×20mm)計12個(12点測定、最大値、最小値は捨てる)を測定試料として老化度試験を行った。AACC法においては厚さに対し25%圧縮した時の荷重値がパンの老化を表すのに最も適正であると報告されている。そこで、焼成直後から保存期間5日経過後までの試料の硬度をFUDOHレシオメター(RHEOTECH FUDOH RHEO METER)にて測定した。その結果を図1のグラフに示す。   Therefore, an aging test was conducted using 12 dies (25 × 25 × 20 mm) cut from a bread inner phase portion (25 × 25 × 20 mm) in total (12-point measurement, maximum value and minimum value were discarded) as measurement samples. In the AACC method, it is reported that the load value when compressed by 25% with respect to the thickness is most appropriate to represent the aging of bread. Therefore, the hardness of the sample from immediately after firing to 5 days after the storage period was measured with a FUDOH ratio meter (RHEOTECH FUDOH RHEO METER). The result is shown in the graph of FIG.

図1の結果から分かるように、普通パンと比較して焼酎醪パンの内相の硬さの差から、焼酎醪パンでは、日数が経ってもデンプンの老化が遅い。これは、焼酎醪に含まれる糖アルコール及びトレハロース等のオリゴ糖による保水性の増加作用であると考えられる。これにより、パンのふかふかとした食感が長期間持続する。   As can be seen from the results in FIG. 1, starch aging is slow in shochu bread even after days, due to the difference in hardness of the inner phase of shochu bread compared to ordinary bread. This is considered to be an effect of increasing water retention by oligosaccharides such as sugar alcohol and trehalose contained in shochu. Thereby, the soft texture of bread lasts for a long time.

本発明の対象とするパン類とは、小麦粉、米粉、そば粉、大麦粉、ライ麦粉、トウモロコシ粉、あわ粉、きび粉、ひえ粉などの穀粉を主原料とする生地を、必要に応じて発酵させ、成形し、焼成、蒸煮等の手段によって加熱処理して得られるものであり、例えば、食パン、コッペパン、ロールパン、フランスパン等のパンの他、あんパン、ジャムパン、クリームパン等の菓子パン、カレーパン、ドーナツ等の揚げパン、さらには中華饅頭等の蒸パン、ピザシート、マフィン等を含むものである。   The breads that are the subject of the present invention are, as necessary, doughs mainly composed of flour such as wheat flour, rice flour, buckwheat flour, barley flour, rye flour, corn flour, crumb flour, millet flour, and millet flour. Fermented, shaped, obtained by heat treatment by means such as baking, steaming, etc., for example, bread such as bread, copper bread, roll bread, French bread, sweet bread such as bread, jam bread, cream bread, It includes curry bread, fried bread such as donuts, steamed bread such as Chinese buns, pizza sheets, muffins and the like.

パン類の原料としては、小麦粉、米粉等、そば粉、大麦粉、ライ麦粉、トウモロコシ粉、あわ粉、きび粉、ひえ粉等の穀粉と、食塩と、水とを基本原料とするが、必要に応じて副原料として、砂糖、ブドウ糖、異性化糖等の糖類、バター、マーガリン、ラード、ショートニング等の油脂、全乳、全粉乳、加糖練乳、無糖練乳、ホエイなどの乳原料を添加してもよい。また、膨化手段として、イースト、イーストフード等の発酵原料や、膨脹剤等を添加してもよい。本発明の対象とするパンは、イーストにより発酵をさせたパンだけでなく、膨脹剤による膨脹パンであってもよい。   As raw materials for breads, wheat flour, rice flour, etc., buckwheat flour, barley flour, rye flour, corn flour, foam flour, acne flour, millet flour, etc., but basic ingredients are necessary. Depending on the ingredients, sugars such as sugar, glucose, isomerized sugar, fats and oils such as butter, margarine, lard, and shortening, and milk ingredients such as whole milk, whole milk powder, sweetened condensed milk, sugar-free condensed milk, and whey are added. May be. Moreover, you may add fermentation raw materials, such as yeast and yeast food, a swelling agent, etc. as a swelling means. The bread targeted by the present invention is not limited to bread fermented with yeast, but may be expanded bread using a swelling agent.

イーストを含有するパン生地の場合は、上記のようにして調製したパン生地を直捏法、中種法、液種法、サワー種法、酒種法、ホップス種法、中麺法、チョリーウッド法、連続製パン法、冷蔵生地法などによって発酵させ、分割、丸目、ねかし、整形、型詰、焙炉、焼成などの工程を経てパンを製造する。これらのパン製造工程は、定法に従って行えばよく、本発明において特に限定されるものではない。   In the case of bread dough containing yeast, the bread dough prepared as described above is a direct method, medium seed method, liquid seed method, sour seed method, liquor seed method, Hops seed method, medium noodle method, chorywood method, It is fermented by a continuous bread making method, a refrigerated dough method, and the like, and bread is produced through processes such as division, rounding, neglect, shaping, mold filling, roasting, and baking. These bread manufacturing steps may be performed according to a conventional method, and are not particularly limited in the present invention.

また、膨脹剤を使用し、イーストを含有しないパン生地の場合は、適宜形状に成形し、焼成、油ちょう、蒸煮などの加熱処理を行うことにより、パン類を製造することができる。   In addition, in the case of bread dough that uses a swelling agent and does not contain yeast, breads can be produced by appropriately forming the bread dough and performing heat treatment such as baking, oil frying, and steaming.

こうして得られた本発明のパン類は、焼酎醪の特有の臭気がなくなり風味が改善され、パンの老化がしにくいなどの優れた特性を有している。   The breads of the present invention thus obtained have excellent characteristics such as the characteristic odor of shochu is eliminated, the flavor is improved, and bread aging is difficult.

また、表4に示すように、焼酎醪にはビフィズス菌(Bifidobacterium breve)の増殖効果が見られると共に、表5に示すように、焼酎醪パンの成分は、普通パンに比較して一般栄養成分、例えば、ミネラル類(ナトリウム、リン、鉄、カリウム、マグネシウム、亜鉛、マンガン等)、ビタミンB1、ビタミンB2、ビタミンB6、葉酸、パントテン酸、ナイアシンの含有量が高い。アミノ酸成分も若干増え、その中でγ−アミノ酪酸(GABA)は2倍以上に増加した。また、機能性成分のクエン酸、ポリフェノールも著しく増加し、表6に示すように、抗酸化能力(DPPH)ラジカル消却能も普通パンに比して高く、これらの栄養成分による各種生理活性効果がもたらされると考えられる。   In addition, as shown in Table 4, while shochu has a growth effect of Bifidobacterium breve, as shown in Table 5, the ingredients of shochu bread are general nutritional ingredients as compared to ordinary bread. For example, the content of minerals (sodium, phosphorus, iron, potassium, magnesium, zinc, manganese, etc.), vitamin B1, vitamin B2, vitamin B6, folic acid, pantothenic acid, niacin is high. Amino acid components also increased slightly, and γ-aminobutyric acid (GABA) increased more than twice. In addition, the functional components citric acid and polyphenols are remarkably increased, and as shown in Table 6, the antioxidant capacity (DPPH) radical scavenging ability is higher than that of ordinary bread, and various physiologically active effects of these nutritional ingredients are obtained. It is thought to be brought about.

Figure 0004576487
Figure 0004576487

Figure 0004576487
Figure 0004576487

Figure 0004576487
Figure 0004576487

普通パンと焼酎醪パンの内相の硬さ(老化度)を示すグラフである。It is a graph which shows the hardness (aging degree) of the internal phase of normal bread and shochu bread.

Claims (5)

甘藷焼酎蒸留粕液部と穀物類粉末とを含有する生地を用いて製造されるパンにおいて、製パン水として甘藷焼酎蒸留粕液部を濃縮して使用することを特徴とするパン類。 A bread produced by using a dough containing a sweet potato shochu distilled liquor portion and a cereal powder, and using the concentrated sweet potato shochu distillate portion as bread-making water . 生地がイースト発酵されることを特徴とする請求項1記載のパン類。 The bread according to claim 1, wherein the dough is yeast-fermented. 甘藷焼酎蒸留粕を固液分離して得られた蒸留粕液部を濃縮し、当該濃縮蒸留粕液部と穀物類粉末及びイースト菌と混練してパン生地を得、これを定法の温度にて一次発酵及び成形後二次発酵を行った後焼成してなることを特徴とするパン類の製造方法 Concentrate the distillate portion obtained by solid-liquid separation of the sweet potato shochu distiller, knead with the concentrated distillate portion, cereal powder and yeast to obtain bread dough, which is subjected to primary fermentation at the usual temperature and method for producing bread characterized by baking to a Rukoto after secondary fermentation after molding. 甘藷の品種がムラサキマサリ又はコガネセンガンであることを特徴とする請求項1又は請求項に記載のパン類及び請求項記載のパン類の製造方法。 Breads and manufacturing method of claim 3 bread according to claim 1 or claim 2 varieties of sweet potato is characterized Murasakimasari or Koganesengan der Rukoto. 穀物類粉末が、小麦粉、米粉、そば粉、大麦粉、ライ麦粉、トウモロコシ粉、あわ粉、きび粉、ひえ粉の中から選択される少なくとも一つであることを特徴とする請求項1又は請求項に記載のパン類及び請求項3又は請求項記載のパン類の製造方法。 Cereals powder, wheat flour, rice flour, buckwheat flour, barley flour, rye flour, corn flour, Awako, Kibiko claim 1 or claim, wherein the at least one selected from among millet flour The bread of Claim 2 and the manufacturing method of bread of Claim 3 or Claim 4 .
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