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JP4613450B2 - Hydrophilic washing place - Google Patents
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JP4613450B2 - Hydrophilic washing place - Google Patents

Hydrophilic washing place Download PDF

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Publication number
JP4613450B2
JP4613450B2 JP2001184505A JP2001184505A JP4613450B2 JP 4613450 B2 JP4613450 B2 JP 4613450B2 JP 2001184505 A JP2001184505 A JP 2001184505A JP 2001184505 A JP2001184505 A JP 2001184505A JP 4613450 B2 JP4613450 B2 JP 4613450B2
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JP
Japan
Prior art keywords
hydrophilic
washing place
water
paint
coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP2001184505A
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Japanese (ja)
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JP2002371608A (en
Inventor
正明 米村
喜信 今坂
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Corp
Panasonic Electric Works Co Ltd
Original Assignee
Panasonic Corp
Matsushita Electric Works Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Panasonic Corp, Matsushita Electric Works Ltd filed Critical Panasonic Corp
Priority to JP2001184505A priority Critical patent/JP4613450B2/en
Publication of JP2002371608A publication Critical patent/JP2002371608A/en
Application granted granted Critical
Publication of JP4613450B2 publication Critical patent/JP4613450B2/en
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  • Sink And Installation For Waste Water (AREA)
  • Bathtubs, Showers, And Their Attachments (AREA)

Description

【0001】
【発明の属する技術分野】
本発明は表面が親水性を有する洗い場に関する。
【0002】
【従来の技術】
従来の洗い場は、例えば不飽和ポリエステル樹脂のSMCや注型で成形されたままの、滑り止めのシボを有する表面を有するものであったり、ハンドレイアップ法による洗い場では、型にゲルコートを塗装し、その後ハンドレイアップ法やスプレイアップ法によりFRPを構成し、型から脱型してゲルコート層を表面に有するものであったりする。また、成形された洗い場の表面に樹脂ビーズを含む塗装を施すことによって着色およびビーズの凹凸で滑り止めとした表面を有する洗い場がある。
【0003】
【発明が解決しようとする課題】
しかしながら、SMCや注型による成形体の表面は、接触角で約75°を示すものであり、洗い場上の湯や水は、水切りのためのわずかな傾斜が設けられていても直径20mmを超える水溜まりとなって残り、完全に排水することは困難であった。さらに、滑り止めのため洗い場表面にシボを設けてあるので溜まる水の量はさらに多くなっていた。
【0004】
また、樹脂ビーズを添加した塗料を塗布した洗い場においても、塗料樹脂の接触角が約80°であり、樹脂ビーズによって表面に凹凸を構成して滑り止めとするものであるが、この無数の凹凸によって水の流れが阻害され、シボ付の洗い場よりも水が溜まり易くなる傾向を示していた。
【0005】
これら溜まった水は表面張力によって厚い水の膜となっており、そのためなかなか乾燥せずに翌日まで残ることが多く、浴室内の湿度を高めてカビの発生を助長したり、落ちにくい水垢を残したり、浴槽洗浄をするときには足を濡らして冷たい思いをさせたりする等の課題を残すものであった。
【0006】
【課題を解決するための手段】
上記課題に対し、洗い場の表面を親水性とすることによって解決を図った。すなわち、洗い場を親水性表面とすることで部分的な水の溜まりがなく乾燥が速い洗い場とすることができる。また、成型された洗い場の表面を親水性とするために、親水性塗料を塗布する工程からなる洗い場とする。これによって成形された洗い場の表面に容易に親水性を付与することができ、塗料に樹脂ビーズを添加して塗装することで入浴中に水や湯で濡れていても滑りにくいという性能を発揮できる洗い場を得ることができる。
【0007】
【発明の実施の形態】
本発明は、水の溜りを解消するために洗い場表面を水の接触角35°以下の親水性としたものである。接触角が35°以下である時に水は洗い場表面に薄い膜となって広がり、水の大きな溜りを造ることはなかった。
【0008】
また、本発明は、親水化剤としてシリカ粒子を含むアクリルウレタン系塗料を用いて、親水性を発揮できる塗料を、成形された洗い場表面に塗装して得られる親水性を有する洗い場であって、塗料を用いて表面のみを親水性とすることで容易に親水化が可能となり、また、洗い場の着色なども簡単に行えるものである。
【0009】
さらに、本発明は、親水性を発揮する塗料中に塗膜厚さより大きな粒子径を有するメタクリル酸メチル樹脂ビーズを添加することで、メタクリル酸メチル樹脂ビーズが塗膜表面より突出した状態となって表面に凹凸が形成され、それゆえ洗い場表面が濡れている場合でも入浴者が滑ることのない親水性の洗い場とすることができる。
【0010】
【実施例】
以下、本発明の一実施例について、図面を参照して説明する。
【0011】
図1に本発明の親水性塗装を施した洗い場の部分断面図を示す。基材1は、既知の方法で不飽和ポリエステル樹脂とガラス繊維、無機質充填材と着色材からなるSMC材料をプレス成形することによって得られる層である。洗い場の成形において、離型剤を用いずに成形し、塗装する前に溶剤で脱脂処理することとした。
【0012】
そこに、塗料Aを粒子状に噴霧して模様塗装する工程を設けて模様塗膜2を構成した。模様塗装は、塗装した状態の粒子の大きさが10mm程度以下の大きさになるように調整して表面にまばらに塗装し、SMC基材1の色(a)と模様塗膜2の色(b)とが両方見えるように塗装した。模様塗装した洗い場を80℃の乾燥炉に60分放置することにより、模様塗膜2を硬化させる乾燥工程を設けた。
【0013】
次に、乾燥炉より洗い場を取り出し、室温で冷却させた後、アクリルウレタン系の親水化剤としてシリカ粒子を含む半透明親水性塗料に平均直径20μmおよび40μmの樹脂ビーズ3を7:3に混合したものを8%添加分散させ塗料Bとし、塗装する工程を設けた。ここでは樹脂ビーズ3にメタクリル酸メチル樹脂ビーズを用いた。その後、塗装した洗い場を80℃の乾燥炉に60分放置することにより、アクリルウレタン系の半透明親水性塗料を硬化させる乾燥工程を設けた。その後、冷却することにより表面に平均塗膜厚20μmの半透明の親水性塗膜4を有する模様付き親水性洗い場を得た。
【0014】
このようにして得た親水性洗い場は、汎用のSMC材料を金型を用いて高温高圧で成形するFRPからなる洗い場に塗装を施して得られるもので、水の接触角26°の親水性を有するものであった。この洗い場に水を流すと、樹脂ビーズ3による凹凸が無数にあるにも関わらず、水は玉にならずに洗い場表面に広がって行き、薄い水の膜を形成した。そのまま放置するとほとんどの水は洗い場の勾配によって排水口に集まり排出された。その時洗い場表面上では勾配の高低によらず水の極めて薄い膜が広がって残っていた。この膜は極めて薄いので短時間のうちに蒸発乾燥するものであった。親水性表面の場合、表面にとどまっている水の量に対して、薄く広範囲に広がることで表面積が著しく大きくなり蒸発量をかせぐことができるのである。したがって、浴室内の湿度は低く保たれるのでカビの発生を予防することができる。
【0015】
ここで用いたアクリルウレタン系塗料は親水化剤としてシリカ微粒子を含むもので、その他親水化剤としてはシリカゲル微粒子、酸化チタン、酸化錫、酸化亜鉛などの金属酸化物微粒子、水酸基やアルコキシ基などを有する高分子有機化合物、カルボキシル基やスルホン基などのイオン性を有する高分子有機化合物であっても良い。
【0016】
ここでは半透明親水性塗料を用いたが、模様塗膜2の色(b)は親水性塗膜4を通して見ることができ、基材1の色(a)と対比されて意匠性の優れたものとすることができた。また、透明な親水性塗料であれば模様塗膜2および基材1の色がよりくっきりと見えるので意匠性においてシャープな感じの洗い場を得ることができる。透明な親水性塗料を得るには親水化剤として塗料樹脂との光の屈折率が近いシリカ微粒子を用いれば良い。
【0017】
一方、樹脂ビーズを添加していない親水性塗料を用いて塗装した親水性洗い場は、例えば入浴中で常に水や湯を流している時は表面の水の膜が切れることなく全面を覆っているので、入浴者にとっては表面にシボを設けてあっても滑りやすい状態となっていた。しかし本実施例においては、樹脂ビーズ3を親水性塗料に添加することによって親水性能を損なうことなく、洗い場としての対すべり性や耐摩耗性などの性能をも満足できる優れた親水性洗い場とすることができた。すなわち、一般のアクリルウレタン系塗料では水の接触角は約80°であり、その中に同様の接触角を有するメタクリル酸メチル樹脂ビーズを添加すると、塗膜から露頭を現した樹脂ビーズによって約80°のほぼ均質な接触角を有する凹凸表面となり、その形状効果で水は厚い大きな溜りを形成して流れずに留まるのである。しかし、接触角が26°の親水性塗料中にメタクリル酸メチル樹脂ビーズを添加した場合は接触角において不均質な表面となる。いわゆる親水性の海に接触角80°の島が所々に露頭を現している状態である。しかし、水は親水性の海に導かれて樹脂ビーズの島を覆って広がり、水の層が極めて薄くなってきた時に樹脂ビーズの島の部分から切れを生じるが、親水性塗料の海の部分では依然濡れた状態で広がっているのである。また、メタクリル酸メチル樹脂ビーズが塗膜より突出して露頭を現しているので、風呂椅子の足や洗面器の底などは直接塗膜を擦ることがないため耐摩耗性に優れたものとすることができた。
【0018】
このように、親水性塗料に樹脂ビーズを添加しても親水性能を損なうことなく塗膜としての対すべり性、耐摩耗性の向上を図ることができた。
【0019】
【発明の効果】
以上の説明から明らかなように本発明によれば、成形された洗い場の表面を親水性とすることによって表面の水の溜りが解消され、乾燥時間の短縮により、浴室内の湿度の低減によるカビ発生の予防ができる。
【0020】
また、本発明によれば、親水化剤としてシリカ粒子を含むアクリルウレタン系塗料を用いて、成形された洗い場の表面に親水性塗装を施すことによって、容易に親水性洗い場を構成でき、更に、塗装によって表面の着色、柄の付与をすることができる。
【0021】
さらに、本発明によれば、親水性塗装の塗膜内に塗膜厚さより大きい粒子径を有するメタクリル酸メチル樹脂ビーズを含有させることによって親水性を損なうことなく耐摩耗性を向上し、滑りにくい洗い場表面とすることができる。
【図面の簡単な説明】
【図1】本発明の洗い場の部分断面図
【符号の説明】
1 基材
2 模様塗膜
3 樹脂ビーズ
4 親水性塗膜
(a) 基材の色
(b) 模様塗膜の色
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a washing place having a hydrophilic surface.
[0002]
[Prior art]
For example, a conventional washing place has a surface having an anti-slip texture as it is formed by SMC or casting of unsaturated polyester resin, or in a washing place by the hand lay-up method, a gel coat is applied to the mold. Then, the FRP is constituted by a hand lay-up method or a spray-up method, and is removed from the mold and has a gel coat layer on the surface. In addition, there is a washing place having a surface that is made non-slip by coloring and unevenness of beads by applying a coating containing resin beads on the surface of the shaped washing place.
[0003]
[Problems to be solved by the invention]
However, the surface of the molded body by SMC or casting shows a contact angle of about 75 °, and the hot water or water on the washing place is a puddle with a diameter exceeding 20 mm even if a slight inclination for draining is provided. It remained and it was difficult to drain completely. Furthermore, since the surface of the washing place is provided with a grain to prevent slipping, the amount of accumulated water was further increased.
[0004]
In addition, even in a washing place where a paint with resin beads added is applied, the contact angle of the paint resin is about 80 °, and the resin beads form irregularities on the surface to prevent slipping. As a result, the flow of water was hindered, and the water tends to accumulate more easily than the washing place with a grain.
[0005]
These accumulated water forms a thick water film due to surface tension, so it often does not dry and remains until the next day, increasing the humidity in the bathroom to promote the generation of mold, and leaving hard-to-drop scales. Or, when washing the bathtub, the problem of leaving the feet wet and making them feel cold was left.
[0006]
[Means for Solving the Problems]
The above problem has been solved by making the surface of the washing place hydrophilic. In other words, by setting the washing area to a hydrophilic surface, it is possible to obtain a washing area where there is no partial accumulation of water and drying is fast. In addition, in order to make the surface of the molded washing place hydrophilic, the washing place includes a step of applying a hydrophilic paint. This makes it possible to easily impart hydrophilicity to the surface of the washing area that has been molded, and by adding resin beads to the paint and painting it, it can exhibit the performance of being slippery even when wet with water or hot water during bathing You can get a washing place.
[0007]
DETAILED DESCRIPTION OF THE INVENTION
This onset Ming is to a washing place surface was contact angle 35 ° or less hydrophilic water in order to eliminate the pool of water. When the contact angle was 35 ° or less, the water spread as a thin film on the surface of the washing place and did not create a large pool of water.
[0008]
Further, the present invention is a washing place having hydrophilicity obtained by applying a paint capable of exhibiting hydrophilicity to a molded washing place surface using an acrylic urethane-based paint containing silica particles as a hydrophilizing agent , By making the surface only hydrophilic using a paint, it is possible to easily make it hydrophilic, and it is also possible to easily color the wash area.
[0009]
Furthermore, the present invention adds a methyl methacrylate resin bead having a particle diameter larger than the coating thickness to a paint exhibiting hydrophilicity, so that the methyl methacrylate resin bead protrudes from the coating surface. Unevenness is formed on the surface. Therefore, even when the surface of the washing place is wet, it is possible to provide a hydrophilic washing place where the bather does not slip.
[0010]
【Example】
An embodiment of the present invention will be described below with reference to the drawings.
[0011]
FIG. 1 shows a partial cross-sectional view of a washing place to which the hydrophilic coating of the present invention is applied. The base material 1 is a layer obtained by press-molding an SMC material comprising an unsaturated polyester resin and glass fiber, an inorganic filler and a coloring material by a known method. In the washing area molding, molding was performed without using a release agent, and degreasing treatment with a solvent was performed before coating.
[0012]
The pattern coating film 2 was configured by providing a pattern coating process by spraying the paint A into particles. The pattern coating is sparsely applied on the surface so that the size of the coated particles is about 10 mm or less, and the color (a) of the SMC substrate 1 and the color of the pattern coating film 2 ( It painted so that both b) could be seen. A drying step for curing the pattern coating film 2 was provided by leaving the pattern-washed washing place in an oven at 80 ° C. for 60 minutes.
[0013]
Next, the washing place is taken out from the drying furnace, cooled at room temperature, and then mixed with 7: 3 resin beads 3 having an average diameter of 20 μm and 40 μm in a translucent hydrophilic paint containing silica particles as an acrylic urethane-based hydrophilizing agent. 8% was added and dispersed to form paint B, and a coating step was provided. Here, methyl methacrylate resin beads were used as the resin beads 3. Then, the drying step which hardens an acrylic urethane type translucent hydrophilic coating was provided by leaving the painted washing place in an 80 degreeC drying furnace for 60 minutes. Thereafter, by cooling, a patterned hydrophilic washing place having a translucent hydrophilic coating film 4 having an average coating film thickness of 20 μm on the surface was obtained.
[0014]
The hydrophilic washing place thus obtained is obtained by coating a washing place made of FRP which is formed from a general-purpose SMC material at a high temperature and high pressure using a mold, and has a hydrophilicity with a water contact angle of 26 °. I had it. When water was allowed to flow through the washing place, the water spread on the surface of the washing place without forming a ball despite the numerous irregularities caused by the resin beads 3, and a thin water film was formed. If left as it is, most of the water gathered at the drain outlet due to the gradient of the washing area and was discharged. At that time, a very thin film of water remained on the surface of the washroom regardless of the gradient. Since this film was very thin, it was evaporated and dried in a short time. In the case of a hydrophilic surface, the surface area is significantly increased by spreading thinly and widely with respect to the amount of water remaining on the surface, and the amount of evaporation can be earned. Therefore, since the humidity in the bathroom is kept low, generation of mold can be prevented.
[0015]
The acrylic urethane paint used here contains silica fine particles as a hydrophilizing agent, and other hydrophilizing agents include silica gel fine particles, metal oxide fine particles such as titanium oxide, tin oxide and zinc oxide, hydroxyl groups and alkoxy groups. It may be a polymer organic compound having an ionic property such as a carboxyl group or a sulfone group.
[0016]
Here, a semi-transparent hydrophilic paint was used, but the color (b) of the pattern coating film 2 can be seen through the hydrophilic coating film 4 and is excellent in design as compared with the color (a) of the substrate 1. I was able to. Moreover, since the color of the pattern coating film 2 and the base material 1 can be seen more clearly if it is a transparent hydrophilic paint, a washing place having a sharp feeling in design can be obtained. In order to obtain a transparent hydrophilic paint, silica fine particles having a light refractive index close to that of the paint resin may be used as a hydrophilic agent.
[0017]
On the other hand, a hydrophilic washing place coated with a hydrophilic paint to which resin beads have not been added covers the entire surface of the surface without being cut off, for example, when water or hot water is constantly flowing in a bath. As a result, the bather was slippery even if the surface was provided with a texture. However, in this embodiment, by adding the resin beads 3 to the hydrophilic paint, an excellent hydrophilic washing place that can satisfy the performance such as the sliding property and the wear resistance as a washing place without impairing the hydrophilic performance. I was able to. That is, in a general acrylic urethane-based paint, the contact angle of water is about 80 °, and when methyl methacrylate resin beads having the same contact angle are added therein, the resin beads that show outcrop from the coating film are about 80 ° C. The uneven surface has a substantially uniform contact angle of °, and the shape effect causes the water to form a thick large pool and stay without flowing. However, when methyl methacrylate resin beads are added to a hydrophilic paint having a contact angle of 26 °, a non-uniform surface is obtained at the contact angle. In this so-called hydrophilic sea, islands with a contact angle of 80 ° are exposed in some places. However, the water is led to the hydrophilic sea and spreads over the resin bead island, and when the water layer becomes extremely thin, the water is cut off from the resin bead island. Then it still spreads wet. In addition, since the methyl methacrylate resin beads protrude from the coating film and expose the outcrop, the feet of the bath chair and the bottom of the basin do not rub the coating film directly, so the wear resistance should be excellent. I was able to.
[0018]
As described above, even when resin beads were added to the hydrophilic paint, it was possible to improve the slipperiness and wear resistance as a coating film without impairing the hydrophilic performance.
[0019]
【The invention's effect】
According to the onset bright As apparent from the above description, the pool of water on the surface is eliminated by the surface of the washing place molded hydrophilic, by shortening the drying time, by reducing the humidity in the bathroom Prevention of mold.
[0020]
In addition, according to the present invention, a hydrophilic washing place can be easily configured by applying a hydrophilic coating to the surface of the molded washing place using an acrylic urethane-based paint containing silica particles as a hydrophilizing agent , The surface can be colored and patterned by painting.
[0021]
Furthermore, according to the present invention, by including methyl methacrylate resin beads having a particle diameter larger than the coating thickness in the coating film of the hydrophilic coating, the wear resistance is improved without impairing the hydrophilic property, and it is difficult to slip. It can be a wash surface.
[Brief description of the drawings]
FIG. 1 is a partial sectional view of a washing place of the present invention.
DESCRIPTION OF SYMBOLS 1 Base material 2 Pattern coating film 3 Resin bead 4 Hydrophilic coating film (a) Color of base material (b) Color of pattern coating film

Claims (1)

成形された洗い場の表面に親水化剤としてシリカ粒子を含むアクリルウレタン系塗料とメタクリル酸メチル樹脂ビーズからなる親水性塗料を施した滑りにくい表面とした親水性洗い場であって、メタクリル酸メチル樹脂ビーズは親水性塗装の塗膜内に塗膜厚さより大きい粒子径を有するものである親水性洗い場。 A hydrophilic wash place with a non-slip surface, which is made of a hydrophilic paint composed of acrylic urethane-based paint containing silica particles as a hydrophilizing agent and a methyl methacrylate resin bead on the surface of the molded wash place. Is a hydrophilic washing place that has a particle size larger than the coating thickness in the coating film of hydrophilic coating .
JP2001184505A 2001-06-19 2001-06-19 Hydrophilic washing place Expired - Lifetime JP4613450B2 (en)

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JP2001184505A JP4613450B2 (en) 2001-06-19 2001-06-19 Hydrophilic washing place

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JP2002371608A JP2002371608A (en) 2002-12-26
JP4613450B2 true JP4613450B2 (en) 2011-01-19

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JP2010144489A (en) * 2008-12-22 2010-07-01 Panasonic Electric Works Co Ltd Floor pan
JP5861101B2 (en) * 2009-02-24 2016-02-16 パナソニックIpマネジメント株式会社 Painted
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