JP4800115B2 - Anti-shine agent and cosmetics containing the same - Google Patents

Description

  The present invention relates to an anti-shine agent, and more particularly, to an anti-shine agent that can be applied to the skin to prevent shine caused by excessive secretion of sebum.

Cosmetics, especially makeup cosmetics, are cosmetics for beautifully dressing the skin. For this purpose, the color rendering effect of powders and colorants is used to create color rendering properties on the actual skin. It creates a high makeup film and makes the skin look beautiful. What matters most in cosmetics intended for such a color rendering effect is the change over time of the cosmetic coating that embodies the color rendering effect. Examples of such a change with time include phenomena such as a dull makeup, a makeup makeup, and a bare background. Among these, it has been known that dullness can be considerably suppressed by using hydrophobic treatment of powder and the use of composite powder, and the exposure of the background can also be achieved by surface treatment of powder and the use of highly adhesive oil. It is being overcome. However, for the shine caused by the excessive presence of oily components on the skin due to excessive secretion of sebum, the countermeasures have not been sufficient so far.
In other words, the conventional technique for eliminating shine has been dealt with by suppressing sebum secretion and adsorbing / removing sebum (see, for example, Patent Documents 1 to 3). It was not enough.

JP 2004-182684 A JP 2002-187811 A JP 2004-346018 A

  Therefore, as a result of earnest research for the purpose of providing an anti-shine agent that maintains the anti-shine effect, the present inventor has prevented the use of a wax having a specific carbon number distribution without depriving sebum, The inventors have found that the effect is sustained and have arrived at the present invention.

The present invention is an anti-shine agent containing a hydrocarbon wax,
The hydrocarbon wax contains 20 to 95% by mass of a hydrocarbon wax part having 28 to 42 carbon atoms and 5 to 80% by mass of a hydrocarbon wax part having 43 or more carbon atoms, and has 27 or less carbon atoms. The content of the hydrocarbon-based wax part is 15% by mass or less.

  The present invention is a cosmetic for preventing shine, comprising 5 to 40% by mass of the above-mentioned shine prevention agent.

  The present invention is a method for using an anti-lipstick cosmetic, characterized by applying the anti-lipstick cosmetic described above before applying a foundation on the skin.

  The present invention is a shine prevention method characterized by preventing shine on the skin using the above-described anti-shine agent.

  In light of the problems of anti-shine protection cosmetics, the present inventors have intensively studied materials that enhance the anti-shine effect, and have found that wax is excellent as an anti-shine agent. In the process of studying the wax with high effect in more detail, the number of wax carbon in human sebum is about 28-42 (Haahti, E. & Horning, EC: Acta Chem. Scand. 15 (1961) No. As a result of examining waxes with different carbon number distributions, paying attention to 4), it was found that waxes having a specific carbon number distribution as described above have an excellent anti-shine function. We are investigating more details about the mechanism by which wax prevents shine, but the wax with the specific carbon number distribution used in the present invention prevents sebum from becoming liquefied by sufficiently mixing with sebum on the skin surface. However, it is thought that the shine is prevented by further promoting solidification.

According to the anti-shine agent of the present invention, shine is prevented without depriving sebum, and the effect is sustained.
According to the shine prevention method of the present invention, by using the above shine prevention agent, shine is prevented without depriving sebum, and the effect can be maintained.
In addition, the anti-glare cosmetic of the present invention is excellent in anti-shine, has color unevenness and uneven blurring effect, and has good formulation stability.
Furthermore, according to the method of using the anti-shine cosmetic of the present invention, the anti-shine effect of the anti-shine agent can be further exhibited.

The best mode of the present invention will be described below.
The hydrocarbon wax used for the anti-shine agent of the present invention comprises 20 to 95% by mass of a hydrocarbon wax having 28 to 42 carbon atoms and 5 to 80% by mass of a hydrocarbon wax having 43 or more carbon atoms. The content of the hydrocarbon wax having 27 or less carbon atoms is 15% by mass or less. Moreover, it is preferable that melting | fusing point is 60 degreeC or more, and it is preferable that a linear rate is 70% or more. Here, the straight chain ratio is defined by mass% of the straight chain saturated hydrocarbon with respect to the total amount.

  The hydrocarbon wax includes 20 to 95% by mass of a hydrocarbon wax having 28 to 42 carbon atoms and 5 to 80% by mass of a hydrocarbon wax having 43 or more carbon atoms, and having 27 or less carbon atoms. As long as the content of the hydrocarbon wax is 15% by mass or less, both natural products and synthetic products can be used. For example, Performalene 655 Polyethylene manufactured by New Phase Technology, New Phase Technology Performancealene PL Polyethylene, polyethylene wax such as Newphase Technology's Performalene 400 Polyethylene, Nippon Seiki FNP-0090, Nihon Seiki FNP-0080 (melting point 81 ° C.), CIREBELLE CIREBELLE109, etc. Fischer-Tropsch wax, Nippon Seisakusha HNP-9, Nihon Seiki Made in SP-0165 such as paraffin wax, and other ethylene-propylene copolymers also, ceresin, include ozokerite, these may be used singly or in combination. Of these, Fischer-Tropsch wax, polyethylene wax or paraffin wax is preferable, and FNP-0080 manufactured by Nippon Seiki Co., Ltd. and Performalene 655 Polyethylene manufactured by New Phase Technology are particularly preferable.

  In this invention, it can be set as the anti-shine cosmetic using the said anti-shine agent. The blending amount of the anti-shine agent in the anti-shine cosmetic is 5 to 40% by mass, more preferably 5 to 25% by mass. If the blending amount of the anti-shine agent is less than 5% by mass, the anti-shine effect is insufficient, and if it exceeds 40% by mass, it is too hard to be applied.

In the cosmetic for preventing shine of the present invention, it is preferable to use the shine prevention agent dissolved in an oil containing volatile silicone oil. Examples of the volatile silicone oil include chain polysiloxanes such as decamethyltetrasiloxane, hexamethyldisiloxane, and dodecamethylpentasiloxane, and cyclic polysiloxanes such as octamethylcyclotetrasiloxane and decamethylcyclopentasiloxane. . Of these, it is most preferable to use cyclic polysiloxane.
The preferable compounding quantity of volatile silicone oil is 20-95 mass%.

  It is preferable to add 0.01 to 5% by mass of a wax anti-caking agent that reduces the solidifying power of the wax to the shine preventing cosmetic of the present invention.

In the present invention, the wax anti-caking agent that lowers the solidification power of the anti-curing agent may be anything as long as it lowers the solidification power of the wax mixed at the same time, but metal soap, lipophilic bentonite, amino acid derivative, dextrin fatty acid Preference is given to using esters, sucrose fatty acid esters, benzylidene derivatives of sorbitol and the like.
As the metal soap, aluminum stearate having a hydroxyl group remaining is most desirable, followed by magnesium stearate and zinc myristate. As the lipophilic bentonite, dimethylbenzyl dodecyl ammonium montmorillonite clay and dimethyl dioctadecyl ammonium montmorillonite clay are preferable. As the amino acid derivatives, N-lauroyl-L-glutamic acid and α, γ-di-n-butylamine are the best. As dextrin fatty acid ester, dextrin palmitic acid ester, dextrin oleic acid ester and dextrin stearic acid ester are preferable. As the sucrose fatty acid ester, those in which 3 or less of 8 hydroxyl groups are esterified with a higher fatty acid and the higher fatty acid is stearic acid or palmitic acid are preferable. As the benzylidene derivative of sorbitol, monobenzylidene sorbitol and dibenzylidene sorbitol are preferable. Of these wax anti-caking agents, dextrin palmitate is particularly preferred.

  There is no particular limitation on the amount of the wax anti-caking agent added to the anti-shine cosmetic of the present invention, but it is generally 0.01 to 5.0% by mass, preferably 0.03 to 2.0% by mass. is there. If the blending amount of the wax anti-caking agent is less than 0.01% by mass, the wax tends to be in a solidified state. Conversely, if it exceeds 5% by mass, it will not be softer and the wax will not be solidified. The blending amount of the blending components other than the agent is relatively reduced, and it tends to be difficult to maintain the quality of the anti-shine cosmetic. These wax anti-caking agents may be dissolved or dispersed directly in the base, or may be previously dispersed with an oil or the like.

  The anti-liparis cosmetic of the present invention comprises a lipophilic gelling agent, and (dimethicone / vinyl dimethicone / methicone) crosspolymer, polymethyl methacrylate, (dimethicone / vinyl dimethicone) crosspolymer, and polymethylsilsesquioxane. It is preferable to blend 3 to 40% by mass of one or two or more selected powders. Here, examples of the (dimethicone / vinyl dimethicone / methicone) crosspolymer include KSP-100 manufactured by Shin-Etsu Chemical Co., Ltd. Examples of polymethyl methacrylate include Ganzpearl series manufactured by Ganz Kasei Co., Ltd. Examples of the (dimethicone / vinyl dimethicone) crosspolymer include Trefil E-506S manufactured by Toray Dow Corning. Examples of polymethylsilsesquioxane include Tospearl series manufactured by Toshiba Silicone.

  Lipophilic gelling agents include lysine derivative-modified silicones and silicone gel compositions.

  Among these, lysine derivative-modified silicones are represented by the following general formulas (I) to (III).

(Wherein, ^{R 1} and ^{R 2} may be the same or different, represents a group represented by the following formula (IV), x represents an integer of from 1 to 900.)

(Wherein, ^{R 3} represents an alkyl group having 2 to 30 carbon atoms, n and m represents an integer of 1 to 20.)

Among the above compounds, particularly preferable compounds are compounds in which x is 50 to 200, n and m are 10, and R ³ is an ethyl group or an isobutyl group in the structures of the general formulas (I) and (II). Specifically, it is a compound having a structure represented by the following formulas (V) to (VIII).

  In this invention, it is suitable that the compounding quantity of the lysine derivative modified silicone represented by the said general formula (I)-(III) is 0.5-20 mass% in the cosmetics for anti-shine. If it is less than 0.5% by mass, the emulsion stability may be poor, and if it exceeds 20% by mass, it is not preferable in terms of formulation.

  The silicone gel composition which is a lipophilic gelling agent in the present invention is an organopolysiloxane polymer having a three-dimensional cross-linking structure which is insoluble in benzene but can contain benzene of the same weight or more as its own weight. What is described in -6035 gazette etc. can use it conveniently. This is composed of a silicone polymer having a three-dimensional cross-linking structure that is insoluble in benzene but can contain benzene of the same weight or more as its own weight, and a low-viscosity silicone oil. Is mixed.

A silicone polymer having a three-dimensional cross-linking structure that is insoluble in benzene and can contain benzene of the same weight or more as its own weight is a polymer obtained by cross-linking organopolysiloxane, and partly has a three-dimensional cross-linking structure. It may be composed of R ₂ SiO units and RSiO _1.5 units, and may contain R ₃ SiO _0.5 units and / or SiO ₂ units. However, examples of R of each structural unit include a hydrogen atom, an alkyl group such as a methyl group, an ethyl group, and a propyl group, an aryl group such as a phenyl group and a tolyl group, and an aliphatic unsaturated group such as a vinyl group. It may be the same or different group. In such a silicone polymer, when the ratio of the R ₂ SiO unit to the RSiO _1.5 unit is 1 to 30: 1, the silicone polymer is sufficiently swollen when mixed with the low-viscosity silicone oil described later, and the stability is good. preferable.

  On the other hand, the low-viscosity silicone oil as the oil component of the present invention is not particularly limited, but any oil having a viscosity of about 50 cs or less can be suitably used. This is because as the viscosity becomes higher, the oily feeling is produced as a result of using it in a large amount, which is undesirable in terms of use.

  Examples of the low-viscosity silicone oil include dimethylpolysiloxane having a low polymerization degree, methylphenylpolysiloxane, cyclic octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, and the like. More than one species can be appropriately selected and used.

  The silicone gel composition used in the present invention can be easily prepared by sufficiently kneading and swelling the above-described silicone polymer and low-viscosity silicone oil. In this case, the mixing ratio of the silicone polymer and the low-viscosity silicone oil is preferably 5:95 to 30:70, more preferably 5:95 to 25:75, by weight.

  As a commercial item, as what mix | blended silicone oil with the silicone gel composition, KSG-15, KSG-16, KSG-17, KSG-18 (above, all are the Shin-Etsu Chemical Co., Ltd. make) etc. are mentioned, for example. .

  As the silicone gel composition used in the present invention, an alkyl-crosslinked polymethylsiloxane different from the silicone gel composition described above can also be used. As the alkyl-crosslinked polymethylsiloxane in the present invention, an alkyl-crosslinked polymethylsiloxane in which a plurality of dimethylpolysiloxanes are bonded to an adjacent siloxane chain via hexadiene or the like can also be used. The alkyl-crosslinked polymethylsiloxane here is preferably blended in a state where it is swollen with a linear or cyclic silicone oil.

Commercially available raw materials include elastomer blend DC9040 ^TM swollen with decamethylcyclopentasiloxane, elastomer blend DC9045 ^TM (about 12% elastomer content manufactured by Toray Dow Corning), and elastomer blend DC9041 ^TM swollen with dimethylpolysiloxane ( Toray Dow Corning Elastomer content about 16%).

  Although content of the silicone gel composition in the cosmetics for anti-shine of this invention is not specifically limited, Preferably it is 0.05-50 mass%, More preferably, it is 0.25-40 mass%. If it is used within this range, the stability and feeling of use (non-stickiness) will be better than when only the wax anti-caking agent is added.

  The cosmetics for preventing shine of the present invention are (dimethicone / vinyl dimethicone / methicone) cross polymer, polymethyl methacrylate, (dimethicone / vinyl dimethicone) cloth instead of or together with the lipophilic gelling agent. It is also possible to use a powder selected from a polymer and polymethylsilsesquioxane. The blending amount when using the powder is preferably 1 to 60% by mass, and more preferably 5 to 40% by mass. By blending the powder, there is no stickiness and a refreshing anti-shine cosmetic is obtained.

  In the present invention, the anti-glare agent only needs to contain the hydrocarbon wax. Therefore, the wax-based anti-caking agent or the lipophilic gelling agent (dimethicone / vinyl dimethicone / methicone) is added to the hydrocarbon wax. ) Anti-anti-glare agent containing powder selected from cross polymer, polymethyl methacrylate, (dimethicone / vinyl dimethicone) cross-polymer, and polymethylsilsesquioxane. By doing so, it can be used as a cosmetic for preventing shine.

The shine prevention cosmetic of the present invention contains the above-mentioned essential components and is used for the purpose of preventing shine. The anti-shine cosmetic of the present invention can be used as an under-makeup under the make-up, or can be used as an over-make-up over the make-up. In any use, it is possible to prevent shine, but a particularly preferred use is as an under-makeup.
That is, according to the present invention, there is provided a method for using an anti-lipstick cosmetic, wherein the anti-lipstick cosmetic is applied before applying the foundation on the skin.

  Further, the anti-shine agent of the present invention is used as the above-described cosmetic for preventing anti-shine, as well as a foundation that does not collapse, a no-color foundation, a secondary adhesion-less foundation, a secondary-less foundation, a non-sticky hand cream, It can be applied as a foundation for new products, a new sunscreen protector, etc.

  The shine prevention cosmetic of the present invention can contain any component usually used in cosmetics as long as the effects of the present invention are not impaired. Examples of such optional components include hydrocarbons such as squalane, petrolatum and microcrystalline wax, esters such as jojoba oil, carnauba wax, octyldodecyl oleate, triglycerides such as olive oil, beef tallow and coconut oil, stearin Acids, fatty acids such as oleic acid and lithinolic acid, higher alcohols such as oleyl alcohol, stearyl alcohol and octyldodecanol, anionic surfactants such as sulfosuccinate and sodium polyoxyethylene alkylsulfate, and amphoteric interfaces such as alkylbetaine salts Activators, cationic surfactants such as dialkylammonium salts, sorbitan fatty acid esters, fatty acid monoglycerides, their polyoxyethylene adducts, polyoxyethylene alkyl ethers, polyoxyethylenes Nonionic surfactants such as len fatty acid esters, polyhydric alcohols such as polyethylene glycol, glycerin, and 1,3-butanediol, aqueous thickeners and gelling agents, antioxidants, ultraviolet absorbers, colorants, Contains preservatives, powders other than the above, hyaluronic acid and its salts, trehalose and its analogs, chondroitin sulfate and its salts, heparin-like substances, macromolecular compounds having sugar chains in their side chains or collagen and other moisturizing active ingredients can do.

As optional components, in addition to the above, anti-inflammatory agents (for example, glycyrrhizic acid derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokitiol, zinc oxide, allantoin, etc.); Kojic acid, Vitamin C, Magnesium ascorbate phosphate, Ascorbic acid glucoside, etc.); Various extracts (for example, agate, auren, shikon, peony, assembly, birch, sage, loquat, carrot, aloe, mallow, iris, grape, Yokuinin, Loofah, Lily, Saffron, Senkyu, Ginger, Hypericum, Onionis, Garlic, Pepper, Chimpi, Toki, Seaweed, etc.), Activator (eg, Royal Jelly, Photosensitizer, Cholesterol Derivative, etc.); Nonyl Valenylamide, nicotinic acid benzyl ester, nicotinic acid β-butoxyethyl ester, capsaicin, gingerone, cantalis tincture, ictamol, tannic acid, α-borneol, nicotinic acid tocopherol, inositol hexanicotinate, cyclandrate, cinnarizine, trazoline, acetylcholine , Verapamil, cephalanthin, γ-oryzanol, etc.); antiseborrheic agents (eg, sulfur, thianthol, etc.); anti-inflammatory agents (eg, tranexamic acid, thiotaurine, hypotaurine, etc.).
In selecting such an arbitrary component, it is preferable not to select a substance that increases shine or a substance that causes shine.

  By treating these essential components and optional components according to a conventional method, the anti-shine cosmetic of the present invention can be produced.

Next, examples of the present invention will be described.
Anti-kari test examples 1-12 (Examination of anti-glare agent)
Using various waxes shown in Table 1 below, a professional panel made visual judgment on the shine prevention effect according to the following evaluation criteria. The results are also shown in Table 1.

(1) Test for preventing shine The 0.01 g of 10% wax preparation (cyclopentasiloxane) was applied to the forehead 2 × 2 cm ² of the face after washing, and the shine condition after 3 hours was visually evaluated according to the following criteria.
(Evaluation criteria)
◎: Overall mat ○: Slightly less matte feeling but no shine △: Overall slightly shining (a degree of shine that cannot be seen from a distance)
×: Leverage (Leverage at a distance)

  Since the anti-shine test examples 1 to 10 use the wax of the present invention, it has an anti-shine effect as a whole. On the other hand, since the anti-shine test examples 11 to 14 use the non-wax of the present invention, the anti-shine effect is inferior.

Formulation Test Examples 1-14
About preparations using wax shown in Table 2 below, according to a specialized panel, (1) shine suppression effect, (2) color unevenness and uneven blurring effect, (3) familiarity, elongation, (4) stickiness, (5) formulation stability The visual evaluation was made on the following evaluation criteria. The results are also shown in Table 2.
Here, as the lysine derivative-modified silicone, the compound represented by the above general formula (I) was used.

(1) Effectiveness of shine prevention For 20 female panelists, the test sample was applied by hand to the full amount after face washing, a questionnaire was conducted about the effect of preventing skin shine after 3 hours of application, and the following criteria were evaluated.
A: More than 16 panelists replied that their faces are generally matte and they feel shine prevention.
○: 12 to 15 panelists who answered that the face is generally matte and feels shine prevention.
Δ: There are 8 to 11 panelists who answered that the face is generally matte and feels shining prevention.
X: Seven or fewer panelists answered that the face was generally matte and felt shine-proof.

(2) Color unevenness / unevenness blurring effect The test sample was applied by hand to the faces of 20 female panelists, a questionnaire was conducted to determine whether there was an unevenness of color unevenness / unevenness blurring, and the following criteria were evaluated.
A: More than 16 panelists answered that there was an uneven color and uneven blur effect.
○: 12 to 15 panelists answered that there was an effect of uneven color and uneven blurring.
Δ: There are 8 to 11 panelists who answered that there was a color unevenness / unevenness blurring effect.
×: Seven or fewer panelists answered that there was an effect of uneven color and uneven blurring.

(3) Familiarity and Elongation Test samples were manually applied to the face of 20 female panelists, a questionnaire was conducted on familiarity and elongation at the time of application, and the following criteria were evaluated.
A: More than 16 panelists answered that they were familiar and stretched well when applied.
○: 12 to 15 panelists who answered that they were familiar and had good elongation during application.
Δ: 8 to 11 panelists answered that they were familiar and stretched well when applied.
X: Seven or fewer panelists answered that they were familiar and stretched well during application.

(4) Stickiness The test sample was applied by hand to the upper arms of 20 female panelists, a questionnaire about stickiness after application was conducted, and the following criteria were evaluated.
A: More than 16 panelists answered that they were not sticky.
○: 12 to 15 panelists answered that they were not sticky.
Δ: 8 to 11 panelists answered that they were not sticky.
×: Seven or fewer panelists answered that they were not sticky.

(5) Formulation stability After storing a sample at 37 degreeC for one week, it returned to room temperature and observed the state.
○: No abnormality Δ: Slight separation of oil is observed ×: Separation of oil is observed

In Formulation Test Examples 1 to 10, since the wax of the present invention is blended, it has an excellent anti-shine effect, a color unevenness / unevenness blurring effect, and good formulation stability. Particularly in Test Example 2, since the wax solidification inhibitor is blended, the familiarity and elongation are improved. In Test Examples 3 and 4, since the lipophilic gelling agent is blended, the stickiness is also improved. . Furthermore, since the powders were blended in Test Examples 5 and 6, the stickiness was further improved as compared with Test Example 4.
On the other hand, in the preparation test examples 11 to 14, since the wax of the present invention was not blended, the result was inferior in the shine prevention effect.

Next, formulation examples of the external preparation for skin according to the present invention in various dosage forms will be described as examples.
Example 1
Raw material name Amount (% by mass)
Fischer-Tropsch wax 10.0
(FNP-0080: manufactured by Nippon Seiki Co., Ltd.)
Methylpolysiloxane 5.0
Decamethylcyclopentasiloxane Residual Octyl Methoxycinnamate 5.0
Dextrin palmitate 1.0
Isostearic acid 3.0
Lysine derivative-modified silicone 0.5
(Dimethicone / Vinyl Dimethicone) Cross Polymer 10.0
(KSG-15TM: manufactured by Shin-Etsu Chemical Co., Ltd.)
(Dimethicone / Vinyl Dimethicone / Methicone) Crosspolymer 5.0
Polymethyl methacrylate 5.0
Zinc oxide 10.0
Dimethyl distearyl ammonium hectorite 1.0
Poly (oxyethylene / oxypropylene) / methylpolysiloxane copolymer 1.0
Glycerin 1.0
Dipropylene glycol 2.0
Paraben Appropriate amount Phenoxyethanol Appropriate amount

(Manufacturing method and usage)
The raw materials are heated to 90 to 100 degrees, mixed and stirred at a high speed, and then filled into a container while slowly stirring.
As an example of the container to be filled, a container having the following characteristics can be used: (1) a feeding container, (2) a smooth coating part and a hole, and (3) a transparent coating part.
By using such a container, (1) the necessary amount can be obtained by unwinding, (2) it can be applied directly and easily to the skin, and (3) the application part is smooth, so the contents are hardly left behind and clean. (4) When transparent, it is possible to obtain the merit that the properties of the contents can be confirmed, and this embodiment can be used in a good state.

Example 2 W / O cream
(Dimethicone / vinyl dimethicone) Cross polymer 40.0% by mass
(KSG-15 ^TM : manufactured by Shin-Etsu Chemical Co., Ltd.)
Decamethylcyclopentasiloxane 10.0
Fischer-Tropsch wax 10.0
(FNP-0080: Nippon Seiwa Co., Ltd.)
Polyoxyethylene / methylpolysiloxane copolymer 3.0
Trimethylsiloxysilicate 0.5
Glycerin 2.0
Dipropylene glycol 5.0
Dextrin palmitate 0.05
Aluminum stearate 0.1
Talc 5.0
Spherical silica 0.5
Palmitic acid dextrin coated fine particle titanium oxide (30 nm) 7.0
Spherical polyethylene powder 2.0
Poly (oxyethylene / oxypropylene) / methylpolysiloxane copolymer 1.0
Paraben appropriate amount phenoxyethanol appropriate amount edetate trisodium 0.02
Dimethyl distearyl ammonium hectorite 0.5
Purified water residue

Example 3 Dimethyl Polysiloxane Formulation of Two Layer Type W / O Cream Alkyl Crosslinked Polymethylsiloxane 5.0
(Dow Corning 9041 Silicone Elastomer Blend ^TM : manufactured by Dow Corning)
Lysine derivative-modified silicone 10.0
Fischer Tropsch Wax 5.0
(CIREBELLE109: CIREBELLE)
Polyethylene wax 15.0
(Performalene 655 Polyethylene: New Phase Technology)
Dimethylpolysiloxane 10.0
Decamethylcyclopentasiloxane 25.0
Trimethylsiloxysilicate 5.0
Polyoxyethylene / methylpolysiloxane copolymer 2.0
Dipropylene glycol 5.0
Dextrin palmitate coated fine particle zinc oxide (60nm) 1.0
Dextrin palmitate 0.01
Dipotassium glycyrrhizinate 0.02
Glutathione 1.0
Thiotaurine 0.05
Clara extract 1.0
Paraben appropriate amount phenoxyethanol appropriate amount edetate trisodium appropriate amount 2-methoxyhexyl paramethoxycinnamate 7.5
Dimethyl distearyl ammonium hectorite 0.5
Spherical polyalkyl acrylate powder 5.0
Butylethylpropanediol 0.5
Purified water Residual fragrance Appropriate amount

Example 4 Dimethyl Polysiloxane Formulation of Two Layer Type Oily Foundation Alkyl Crosslinked Polymethylsiloxane 5.0
(Dow Corning 9041 Silicone Elastomer Blend ^TM : manufactured by Dow Corning)
Lysine derivative-modified silicone 10.0
Paraffin wax 5.0
(HNP-9: Nippon Seiwa Co., Ltd.)
Polyethylene wax 15.0
(Performalene 655 Polyethylene: New Phase Technology)
(Dimethicone / Vinyl Dimethicone) Cross Polymer 5.0
^{(KSG-16 TM:} manufactured by Shin-Etsu Chemical Co., Ltd.)
Dodecamethylcyclohexasiloxane 15.0
Decamethylcyclopentasiloxane Residue
3-Tris (trimethylsiloxy) silylpropylcarbamic acid pullulan 3.0
Ethanol 10.0
Isostearic acid 0.5
Myristic acid-treated zinc oxide 0.5
Dextrin palmitate 2.0
Palmitic acid dextrin-coated titanium oxide 10.0
Palmitic acid dextrin-coated talc 7.0
Silicone surface-treated titanium oxide 30 nm) 5.0
Cross-linked silicone powder 1.0
Spherical silica 2.0
L-ascorbyl magnesium phosphate 0.2
DL-α-tocopherol acetate 0.1
D-δ-tocopherol 0.1
Glutathione 0.1
Clara extract 0.1
2-Ethylhexyl paramethoxycinnamate 5.0
Bengala coated with dextrin palmitate Appropriate amount Dextrin palmitate coated yellow iron oxide Appropriate amount Dextrin dextrin coated black iron oxide Appropriate amount Fragrance Suitable amount

Example 5 W / O Foundation Alkyl Crosslinked Polymethylsiloxane Dimethyl Polysiloxane Formulation 5.0
(Dow Corning 9041 Silicone Elastomer Blend ^TM : manufactured by Dow Corning)
Lysine derivative-modified silicone 5.0
Paraffin wax 5.0
(HNP-9: Nippon Seiwa Co., Ltd.)
Polyethylene wax 2.0
(Performalene PL Polyethylene: New Phase Technology)
(Dimethicone / Vinyl Dimethicone) Cross Polymer 5.0
(KSG-15 ^TM : manufactured by Shin-Etsu Chemical Co., Ltd.)
Dodecamethylcyclohexasiloxane 20.0
Trimethylsiloxysilicic acid 1.0
Poly (oxyethylene / oxypropylene) methylpolysiloxane copolymer 3.0
Ethanol 10.0
Isostearic acid 0.5
Alkyl-modified silicone resin-coated titanium oxide 10.0
Dextrin palmitate coated titanium oxide 5.0
Palmitic acid dextrin-coated talc 5.0
Acicular fine particle titanium oxide 1.0
Spherical silica 5.0
Silica-coated mica Appropriate amount Sodium citrate Appropriate amount N-lauroyl-L-lysine 0.5
DL-α-tocopherol acetate 0.1
D-δ-tocopherol 0.1
Clara extract 1.0
Bengala coated with dextrin palmitate Appropriate amount Dextrin palmitate coated yellow iron oxide Appropriate amount dextrin dextrin coated black iron oxide Appropriate amount Merirot extract 2.0
Purified water residue

Example 6 W / O cream (makeup base)
Decamethylcyclopentasiloxane blend of alkyl cross-linked polymethylsiloxane 5.0
(Dow Corning 9045 Silicone Elastomer Blend ^TM : manufactured by Dow Corning)
Lysine derivative-modified silicone 5.0
Paraffin wax 5.0
(HNP-9: Nippon Seiwa Co., Ltd.)
Polyethylene wax 2.0
(High Wax 720P: Mitsui Chemicals, Inc.)
Dextrin palmitate 0.5
Oxidized polypropylene wax 3.0
(LICOWAX371FP: Clariant Japan Co., Ltd.)
(Dimethicone / vinyl dimethicone) cross polymer 20.0
(KSG-15 ^TM : manufactured by Shin-Etsu Chemical Co., Ltd.)
Dimethylpolysiloxane 6mPas 5.0
Decamethylcyclopentasiloxane 25.0
Polyoxyethylene / methylpolysiloxane copolymer 3.0
Glycerin 1.0
1,3-butylene glycol 5.0
Xylit 0.5
Isostearic acid 0.5
Silica anhydride coated with alkyl-modified silicone resin 2.0
Talc 0.5
Aluminum stearate 1.0
Bengala-coated mica titanium 0.1
Sodium hexametaphosphate 0.05
Dipotassium glycyrrhizinate 0.1
L-serine 0.1
Hypericum extract 0.1
DL-α-tocopherol acetate 0.2
Thiotaurine 0.1
Togenashi extract 0.1
Peonies extract 0.1
Acetylated sodium hyaluronate 0.1
Yukinoshita extract 0.1
Paraoxybenzoic acid ester Appropriate amount Phenoxyethanol Appropriate amount Dextrate palmitate-coated yellow iron oxide 0.1
Dimethyl distearyl ammonium hectorite 1.0
Purified water Residual trimethylsiloxysilicic acid 1.5
Spherical silicic acid 1.0
Spherical polyethylene powder 5.0
Perfume

Example 7 Two-layer type foundation (W / O)
Decamethylcyclopentasiloxane blend of alkyl cross-linked polymethylsiloxane 5.0
(Dow Corning 9045 Silicone Elastomer BlendTM: Dow Corning)
Lysine derivative-modified silicone 2.0
Fischer-Tropsch wax 15.0
(FNP-0090: Nippon Seiwa Co., Ltd.)
Polyethylene wax 2.0
(High Wax 720P: Mitsui Chemicals, Inc.)
Oxidized polypropylene wax 3.0
(LICOWAX371FP: Clariant Japan Co., Ltd.)
Dextrin palmitate 3.0
(Dimethicone / vinyl dimethicone) cross polymer 20.0
(KSG-15TM: manufactured by Shin-Etsu Chemical Co., Ltd.)
Dimethylpolysiloxane 6mPas 2.0
Decamethylcyclopentasiloxane 40.0
Polyoxyethylene / methylpolysiloxane copolymer 2.0
1,3-butylene glycol 5.0
Squalane 0.5
Isostearic acid 0.5
Stearic acid 0.5
Fine zinc oxide 50nm 0.5
Fine titanium oxide 30nm 15.0
Aluminum stearate 1.0
Dipotassium glycyrrhizinate 0.5
DL-α-tocopherol acetate 0.1
D-δ-tocopherol 0.1
Paraoxybenzoic acid ester Appropriate amount Phenoxyethanol Appropriate amount Sodium edetate Appropriate amount Dextrin palmitate-coated iron oxide 0.4
Dimethyl distearyl ammonium hectorite 0.3
Purified water Residual trimethylsiloxysilicic acid 1.5
Spherical polyethylene powder 5.0
Aluminum oxide 0.2

Example 8 Oily Cosmetic Alkyl Crosslinked Polymethylsiloxane Dimethyl Polysiloxane Formulation 5.0
(Dow Corning 9041 Silicone Elastomer BlendTM: Dow Corning)
Lysine derivative-modified silicone 2.0
Fischer-Tropsch wax 15.0
(FNP-0080: Nippon Seiwa Co., Ltd.)
Polyethylene wax 2.0
(High Wax 720P: Mitsui Chemicals, Inc.)
(Dimethicone / vinyl dimethicone) cross polymer 20.0
(KSG-15TM: manufactured by Shin-Etsu Chemical Co., Ltd.)
Palmiticin dextrin 0.1
Light isoparaffin remaining methyl hydrogen polysiloxane 1.0
Decamethylcyclopentasiloxane 15.0
Castor oil 2.0
Candelilla Row 5.0
Isostearic acid 3.0
Oleic acid 1.0
Glyceryl tri-2-ethylhexanoate 2.0
Mukuroji extract 0.1
Oat extract 0.1
Dextrin palmitate 13.0
Trimethylsiloxysilicic acid 15.0
Tetradecene 0.1
Polyethylene 5.0
Microcrystalline wax 5.0

EXAMPLE 9 Decamethylcyclopentasiloxane formulation of oily cosmetic alkyl cross-linked polymethylsiloxane 5.0
(Dow Corning 9045 Silicone Elastomer BlendTM: Dow Corning)
Lysine derivative-modified silicone 2.0
Fischer-Tropsch wax 15.0
(FNP-0090: Nippon Seiwa Co., Ltd.)
Polyethylene wax 2.0
(High Wax 720P: Mitsui Chemicals, Inc.)
Dextrin palmitate 3.0
(Dimethicone / vinyl dimethicone) cross polymer 20.0
(KSG-15TM: manufactured by Shin-Etsu Chemical Co., Ltd.)
Light isoparaffin Remaining decamethylcyclopentasiloxane 8.0
Trimethylsiloxysilicic acid 8.0
Polyoxyethylene / methylpolysiloxane copolymer 2.0
1,3-butylene glycol 2.0
Macadamia nut oil 1.0
Polyoxyethylene hydrogenated castor oil triisostearate 2.0
Acrylic resin coated aluminum powder 4.0
Dimethyl distearyl ammonium hectorite 5.0
Dextrin palmitate 2.0
Purified water 2.0

Example 10 Decamethylcyclopentasiloxane blend of oil-based solid cosmetic alkyl-crosslinked polymethylsiloxane 5.0
(Dow Corning 9040 Silicone Elastomer BlendTM: Dow Corning)
Lysine derivative-modified silicone 10.0
Fischer-Tropsch wax 15.0
(FNP-0090: Nippon Seiwa Co., Ltd.)
Polyethylene wax 2.0
(Performalene 655 Polyethylene: New Phase Technology)
Dextrin palmitate 3.0
(Dimethicone / vinyl dimethicone) cross polymer 20.0
(KSG-15TM: manufactured by Shin-Etsu Chemical Co., Ltd.)
Liquid paraffin Residual glyceryl tri-2-ethylhexanoate 10.0
Silicon coated pigment 0.1
(Bengara, iron oxide, titanium oxide, etc.)
Barium sulfate 0.1
Bengala-coated mica appropriate amount δ-tocopherol 0.1
Dye Appropriate amount Dextrin palmitate 15.0
Heavy liquid isoparaffin 40.0

Example 11 Powdered solid foundation formulation (mass%)
Lysine derivative-modified silicone 1.0
Fischer-Tropsch wax 10.0
(FNP-0085: Nippon Seiwa Co., Ltd.)
Polyethylene wax 2.0
(Performalene 800 Polyethylene: New Phase Technology)
Dextrin palmitate 3.0
Dimethylpolysiloxane 5.0
Decamethylcyclopentasiloxane blend of alkyl cross-linked polymethylsiloxane 5.0
(Dow Corning 9045 Silicone Elastomer Blend ^TM : manufactured by Dow Corning)
3-Tris (trimethylsiloxy) silylpropylcarbamic acid pullulan 0.5
Isostearic acid 0.5
Diisostearyl malate 3.0
Tri-2-ethylhexane sanglyceryl 1.0
Sorbitan sesquiisostearate 1.0
Spherical PMMA-coated mica 6.0
Prism Tone Powder YR 1.0
Fine zinc oxide 0.5
Fine particle titanium oxide 2.0
Synthetic phlogopite 2.0
Metal soap treated talc 8.0
Spherical silica 5.0
Tocophenol acetate 0.1
δ-tocopherol 0.1
Isaiyo Rose Extract 0.1
Yeast extract 0.1
P-Hydroxybenzoate Appropriate amount Methyl bis (trimethylsiloxy) silylisopentyl trimethoxycinnamate 1.0
2-methoxyhexyl paramethoxycinnamate 3.0
Spherical polyalkyl acrylate powder 6.0
Methyl hydrogen polysiloxane-coated talc Residual methyl hydrogen polysiloxane-coated sericite 5.0
Methyl hydrogen polysiloxane-coated titanium oxide 15.0
Inorganic composite powder (Coverleaf AR-80 ^™ ; manufactured by Catalyst Kasei Kogyo Co., Ltd.) 10.0
Mica titanium 1.0
Methyl hydrogen polysiloxane coated pigment (colorant) 5.0

Example 12 Powdered solid foundation formulation (mass%)
Lysine derivative-modified silicone 10.0
Fischer Tropsch Wax 5.0
(CIREBELLE108: CIREBELLE)
Polyethylene wax 1.0
(Performalene PL Polyethylene: New Phase Technology)
Dextrin palmitate 1.0
Ceresin 0.5
Dimethylpolysiloxane 2.0
Methylphenylpolysiloxane 1.0
3-Tris (trimethylsiloxy) silylpropylcarbamic acid pullulan 5.0
Decamethylcyclopentasiloxane blend of alkyl cross-linked polymethylsiloxane 5.0
(Dow Corning 9040 Silicone Elastomer Blend ^TM : manufactured by Dow Corning)
Squalane 7.0
Squalane (vegetable) 1.0
Sorbitan sesquiisostearate 1.0
Glycerol-modified silicone resin-coated calcined sericite 16.0
Glycerol-modified silicone resin-coated sericite 7.0
Yellow iron oxide coated mica titanium 0.1
Fine particle titanium oxide 5.0
Talc 10.0
Titanium oxide coated sericite 0.1
Boron nitride 2.5
Bengala-coated mica titanium 0.1
Phytosterol 0.1
Ascorbyl dipalmitate 0.1
DL-α-tocopherol acetate 0.1
D-δ-tocopherol 0.1
Yeast extract 0.1
P-Hydroxybenzoate appropriate amount 2-methoxyhexyl paramethoxycinnamate 1.0
Inorganic composite powder (Coverleaf AR-80 ^™ ; manufactured by Catalyst Kasei Kogyo Co., Ltd.) 10.0
Spherical polyalkyl acrylate powder 8.0
Methyl hydrogen polysiloxane coated mica Residual methyl hydrogen polysiloxane coated iron oxide titanium oxide sintered product 5.0
Methyl hydrogen polysiloxane-coated sericite 5.0
Methyl hydrogen polysiloxane-coated titanium oxide 4.0
Methyl hydrogen polysiloxane coated flaky titanium oxide 5.0
Methyl hydrogen polysiloxane coated pigment (colorant) 5.0
Perfume

Example 13 Powdered solid foundation formulation (mass%)
Lysine derivative-modified silicone 5.0
Fischer-Tropsch wax 20.0
(FNP-0080: Nippon Seiwa Co., Ltd.)
Polyethylene wax 2.0
(Performalene 400 Polyethylene: New Phase Technology)
Dextrin palmitate 0.1
Aluminum stearate 1.0
α-olefin oligomer 3.0
Vaseline 3.0
3-Tris (trimethylsiloxy) silylpropylcarbamic acid pullulan 5.0
Decamethylcyclopentasiloxane blend of alkyl cross-linked polymethylsiloxane 3.0
(Dow Corning 9040 Silicone Elastomer Blend ^TM : manufactured by Dow Corning)
Macadamia nut oil 0.1
Sorbitan sesquiisostearate 1.0
Alkyl-modified silicone resin coated yellow iron oxide 2.0
Alkyl modified silicone resin coated bengara 1.0
Alkyl modified silicone resin coated black iron oxide 0.5
Yellow iron oxide coated mica titanium 5.0
Synthetic phlogopite 5.0
Titanium oxide 1.0
Zinc oxide 1.0
Low-temperature calcined zinc oxide 4.0
Firing sericite 10.0
Phlogopite 1.0
Aluminum oxide 1.0
Inorganic composite powder (Coverleaf AR-80 ^™ ; manufactured by Catalyst Kasei Kogyo Co., Ltd.) 15.0
Talc Residual synthetic phlogopite 5.0
Cross-linked silicone powder 10.0
(Trefill E-506 ^TM : Toray Dow Corning Silicone)
DL-α-tocopherol acetate 0.1
D-δ-tocopherol 0.1
Yeast extract 5.0
P-Hydroxybenzoate appropriate amount 2-methoxyhexyl paramethoxycinnamate 1.0
Calcium alginate powder 1.0
Perfume

Example 14 Solid Foundation Formulation (mass%)
Lysine derivative-modified silicone 5.0
Paraffin wax 15.0
(SP-0165: Nippon Seiwa Co., Ltd.)
Polyethylene wax 2.0
(Performalene 655 Polyethylene: New Phase Technology)
Dextrin palmitate 5.0
α-olefin oligomer 10.0
Microcrystalline wax 0.5
Dimethylpolysiloxane blend of alkyl-crosslinked polymethylsiloxane 3.0
(Dow Corning 9041 Silicone Elastomer Blend ^TM : Dow Corning)
3-Tris (trimethylsiloxy) silylpropylcarbamic acid pullulan 1.0
Ceresin 5.0
Dimethylpolysiloxane 15.0
Methylphenyl polysiloxane 10.0
Macadamia nut oil 0.1
Carnauba 0.1
Glyceryl tri-2-ethylhexanoate 7.0
Cetyl 2-ethylhexanoate 10.0
Sorbitan sesquiisostearate 1.5
Mica 0.5
Aluminum stearate 1.0
Inorganic composite powder (Coverleaf AR-80 ^™ ; manufactured by Catalyst Kasei Kogyo Co., Ltd.) 3.0
Cross-linked silicone powder 8.0
(Trefill E-506 ^TM : Toray Dow Corning Silicone)
N-lauroyl-L-lysine 0.1
D-δ-tocopherol appropriate amount yeast extract 0.1
Bengala appropriate amount yellow iron oxide appropriate amount calcium alginate powder 1.0
Nylon powder Residual spherical silica 1.0
Titanium oxide 1.0

Example 15 Emulsion foundation formulation (mass%)
Lysine derivative-modified silicone 1.0
Fischer-Tropsch wax 15.0
(FNP-0080: Nippon Seiwa Co., Ltd.)
Fischer-Tropsch wax 15.0
(CIREBELLE109: CIREBELLE)
Dextrin palmitate 2.0
Microcrystalline wax 1.0
Dimethylpolysiloxane 15.0
Decamethylcyclopentasiloxane 2.0
Decamethylcyclopentasiloxane blend of alkyl cross-linked polymethylsiloxane 3.0
(Dow Corning 9045 Silicone Elastomer Blend ^TM : manufactured by Dow Corning)
3-Tris (trimethylsiloxy) silylpropylcarbamic acid pullulan 0.5
1,3-butylene glycol 6.0
Candelilla Row 3.0
Isostearic acid 1.0
Ethylene glycol fatty acid ester 0.1
Lanolin fatty acid octyldodecyl 0.5
2-alkyl-N-carboxymethyl
-N-Hydroxyethylimidazolinium betaine 4.0
Titanium oxide 7.5
Barium sulfate 5.0
Titanium oxide 7.0
Talc 3.0
Silicic anhydride 4.0
Cross-linked silicone powder 0.1
(Trefill E-506 ^TM : Toray Dow Corning Silicone)
Sodium metaphosphate 0.1
Hydroxypropyl-β-cyclodextrin 0.1
DL-α-tocopherol acetate 0.1
Hamamelis extract 0.1
Peonies extract 0.1
Sodium chondroitin sulfate 0.1
Sodium hyaluronate 0.1
Yeast extract 0.1
Asenyaku extract 0.1
Paraoxybenzoic acid ester Appropriate amount Bengala Appropriate amount Yellow iron oxide Appropriate amount Black iron oxide Appropriate amount Inorganic composite powder (Coverleaf AR-80 ^™ ; manufactured by Catalytic Chemical Industry Co., Ltd.) 1.0
Xanthan gum 0.1
Sodium carboxymethylcellulose 0.1
Sodium acrylate / 2-acrylamido-2-methylpropanesulfonic acid copolymer
(SIMULGEL EG ^TM ; manufactured by SEPPIC) 0.5
Merirot Extract 2.0
Purified water residue

Example 16 W / O foundation formulation (mass%)
Lysine derivative-modified silicone 1.0
Fischer-Tropsch wax 15.0
(FNP-0080: Nippon Seiwa Co., Ltd.)
Dextrin palmitate 2.0
Dimethylpolysiloxane 3.0
Decamethylcyclopentasiloxane 10.0
Polyoxyethylene / methylpolysiloxane copolymer 3.0
Palmitic acid 0.5
Distearyldimethylammonium chloride 0.2
Metal soap treated talc 2.0
Cross-linked silicone powder 0.1
(Trefill E-506 ^TM : Toray Dow Corning Silicone)
Bengala-coated mica titanium 0.5
N-lauroyl-L-lysine 2.0
Sodium L-glutamate 2.0
Tocopherol acetate 0.1
δ-tocopherol 0.1
P-Hydroxybenzoate appropriate amount Phenoxyethanol 0.2
Spherical nylon powder 1.0
Spherical polyalkyl acrylate powder 3.0
Purified water residue

Claims (8)

5-40 % by mass of an anti-shine agent containing a hydrocarbon wax and a lipophilic gelling agent are blended,
The hydrocarbon wax contains 20 to 95% by mass of a hydrocarbon wax part having 28 to 42 carbon atoms and 5 to 80% by mass of a hydrocarbon wax part having 43 or more carbon atoms, and has 27 or less carbon atoms. The content of the hydrocarbon wax part is 15% by mass or less ,
The lipophilic gelling agent is a lysine derivative-modified silicone or a silicone gel composition;
A cosmetic for preventing shine. 2. The shine prevention cosmetic according to claim 1, wherein the hydrocarbon wax is Fischer-Tropsch wax, polyethylene wax or paraffin wax. The anti-shine cosmetic according to claim 1, wherein the hydrocarbon wax has a melting point of 60 ° C or higher. The shine prevention cosmetic according to claim 1, wherein the linearity of the hydrocarbon wax is 70% or more. Further blending 0.01 to 5% by weight of a wax anti-caking agent that reduces the solidifying power of the wax, the wax anti-caking agent is metal soap, lipophilic bentonite, amino acid derivative, dextrin fatty acid ester, sucrose fatty acid ester and sorbitol those selected from the benzylidene derivative,
5. The shine prevention cosmetic according to claim 1, wherein the amino acid derivative is selected from N-lauroyl-L-glutamic acid and α, γ-di-n-butylamine . 6. The anti-lipstick cosmetic according to claim 5 , wherein the wax solidification inhibitor is dextrin palmitate. Furthermore, it comprises one or more of powders selected from (dimethicone / vinyl dimethicone / methicone) crosspolymer, polymethyl methacrylate, (dimethicone / vinyl dimethicone) crosspolymer, and polymethylsilsesquioxane. The cosmetic for preventing shine according to any one of claims 1 to 6 . A method for using an anti-lipstick cosmetic, wherein the anti-lipstick cosmetic according to any one of claims 1 to 7 is applied before applying the foundation on the skin.