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JP4817707B2 - Etching jig - Google Patents
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JP4817707B2 - Etching jig - Google Patents

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JP4817707B2
JP4817707B2 JP2005131556A JP2005131556A JP4817707B2 JP 4817707 B2 JP4817707 B2 JP 4817707B2 JP 2005131556 A JP2005131556 A JP 2005131556A JP 2005131556 A JP2005131556 A JP 2005131556A JP 4817707 B2 JP4817707 B2 JP 4817707B2
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etching
piezoelectric element
jig
basket
element plate
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JP2006311228A (en
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恵一 遠田
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Kyocera Crystal Device Corp
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Description

本発明は、水晶板などの圧電素板をエッチング加工する際に使用する湿式のエッチング装置で、被加工物である水晶板などの圧電素板が均一にムラが無くエッチング処理ができるジグに関する。   The present invention relates to a jig that is a wet etching apparatus used for etching a piezoelectric element plate such as a crystal plate and that can uniformly etch a piezoelectric element plate such as a crystal plate that is a workpiece.

近年、圧電振動子や発振器の小型化に伴いこれらに搭載する圧電素子の形状や板厚みも小型化、薄型化の傾向が強まっている。通常の圧電素子の個片化の加工方法としては、例えば人工水晶の場合にあっては、人工育成炉で育成して得た人工水晶を切断加工と表面研磨加工とにより、外形寸法加工と所望の発振周波数を得るまでの板厚みを薄くする加工が行われている。   In recent years, with the miniaturization of piezoelectric vibrators and oscillators, the shape and plate thickness of the piezoelectric elements mounted on them have become increasingly smaller and thinner. For example, in the case of an artificial quartz, for example, in the case of an artificial quartz, the external quartz is obtained by cutting and surface polishing the artificial quartz obtained by growing it in an artificial growth furnace. Processing is performed to reduce the plate thickness until the oscillation frequency is obtained.

更に水晶素板の板厚みを微調整すること、すなわち所望の発振周波数を得るための板厚みを薄くする加工方法に湿式のエッチング加工を用いている。湿式のエッチング加工は、機械研磨加工では得られない、微小な水晶素板の板厚みを調整できることと、切断加工も含めた厚み加工(機械加工)で生じた水晶素板表面(主面)の状態(加工変質層の除去)をエッチング処理することにより滑らかな振動子主面を得ることで、水晶振動子あるいは水晶発振器に組み込んだときの水晶素板の持つ電気的特性や温度特性を良好にし異常発振などを起こさない水晶素板を得ることができる。   Furthermore, wet etching is used as a processing method for finely adjusting the plate thickness of the quartz base plate, that is, for reducing the plate thickness for obtaining a desired oscillation frequency. Wet etching processing can adjust the thickness of a fine quartz base plate that cannot be obtained by mechanical polishing, and the surface of the quartz base plate (main surface) generated by thickness processing (machining) including cutting processing. By etching the state (removal of the work-affected layer) to obtain a smooth resonator main surface, the electrical characteristics and temperature characteristics of the quartz base plate when incorporated in a quartz resonator or crystal oscillator are improved. A quartz base plate that does not cause abnormal oscillation can be obtained.

上述する湿式のエッチング方法の一例としては、エッチング加工する際には圧電素板が漏れ出さない程度の微細な孔で被われた加工カゴを、エッチング液であるフッ酸系のエッチャント液に浸し、エッチャントの中で適宜加工カゴ(ジグ)を揺動もしくは回転させてエッチング処理を行うものである。   As an example of the wet etching method described above, a processing basket covered with fine holes to the extent that the piezoelectric element plate does not leak out during etching is immersed in a hydrofluoric acid-based etchant solution that is an etching solution, Etching is performed by swinging or rotating a processing basket (jig) as appropriate in the etchant.

エッチング液はエッチング処理を重ねるごとに圧電素板と化学的反応の進行が低下するため、エッチャントを補充追加しながらエッチング処理効率が低下しないように注意しながら、適宜エッチング液の補充が行われる。   Since the progress of the chemical reaction with the piezoelectric element plate decreases each time the etching process is repeated, the etching liquid is appropriately replenished while taking care not to lower the etching process efficiency while supplementing the etchant.

このとき圧電素板が加工カゴ間で貼り付き現象が発生すると、圧電素板の表面にエッチング液が潤沢に供給されないために、貼り付いている圧電素板面のエッチング加工は進まず、更にはこの貼り付いている箇所にはその界面に段差が発生してしまう。   At this time, if a phenomenon occurs in which the piezoelectric element plate sticks between the processing baskets, the etching solution is not supplied to the surface of the piezoelectric element plate. A level difference occurs at the interface in the pasted portion.

また、エッチング工程は機械研磨工程による厚み落とし加工と比較して、厚みの微調整を行うことができるために、所望の周波数に追い込む工程でもあるために、一度に処理する複数枚の圧電素板を同一周波数に合せ込みを行った場合に、上述する貼り付き現象が圧電素板の片面で起きた場合には、その片面の加工変質層は除去されきれずもう一方の面が過剰にエッチングされてしまうこともある。
特開2003−110387号公報 なお、出願人は前記した先行技術文献情報で特定される先行技術文献以外には、本発明に関連する先行技術文献を、本件出願時までに発見するに至らなかった。
In addition, since the etching process can be finely adjusted in thickness compared to the thickness reduction process by the mechanical polishing process, it is also a process of driving to a desired frequency, so a plurality of piezoelectric element plates to be processed at a time If the above-mentioned sticking phenomenon occurs on one side of the piezoelectric element plate when the frequency is adjusted to the same frequency, the work-affected layer on one side cannot be removed, and the other side is excessively etched. Sometimes.
JP, 2003-110387, A In addition to the prior art document specified by prior art literature information mentioned above, the applicant did not find the prior art literature relevant to the present invention by the time of this application. .

従来技術に示すエッチング処理方法では、圧電素板が小型化・薄型化が急速に進んでいるために、従来のエッチング加工方法ではエッチング液中でエッチング加工カゴを揺動もしくは回転させても、その圧電素板の自重が軽いため、またエッチング加工カゴまたは圧電素板同士間での衝突による衝撃が小さいために前述の貼り付き現象が発生してしまう割合が増えることにより、エッチング加工によって圧電素子表面に段差を生じ、そのことがまた圧電素子のCIを悪化させてしまうという問題があった。   In the etching method shown in the prior art, since the piezoelectric element plate is rapidly becoming smaller and thinner, even if the etching basket is swung or rotated in the etching solution in the conventional etching method, Since the weight of the piezoelectric element plate is light and the impact caused by the collision between the etching process baskets or the piezoelectric element sheets is small, the rate of occurrence of the above-mentioned sticking phenomenon increases. There is a problem that a step is formed on the substrate, which deteriorates the CI of the piezoelectric element.

また、エッチング液の置換のためにエッチング加工カゴに多数個あける穴は、エッチングされる圧電素子が飛出すことのないような大きさとする必要があるが、圧電素板の小型、薄型化に伴いエッチング加工カゴの穴の大きさを小さくするとエッチング液の置換がスムーズに行えず、加えてエッチング加工カゴ内の空気が加工カゴ外に排出されずに、エッチング加工自体が実施できなくなるという問題があった。   In addition, many holes in the etching basket for replacement of the etching solution must be sized so that the piezoelectric element to be etched does not fly out, but as the piezoelectric element plate becomes smaller and thinner, When the hole size of the etching basket is reduced, the replacement of the etching solution cannot be performed smoothly. In addition, the air in the etching basket is not discharged outside the processing basket, and the etching process itself cannot be performed. It was.

上述の点について発明者は日々の作業の中で次のような点で不具合を感じている。従来から使われているエッチングジグは、内カゴおよび内蓋にテーパ穴を開けたものを使用している関係で、
1.圧電素板であるエッチング対象物(ワーク)との接触面積が広く、ビ−カに移す際のワーク離れが悪く、ワークがカゴ内に残ってしまうために混入が発生していた。
2.カゴを液中に沈めた際、カゴ内エアー残留量が多く、攪拌スペースが狭くなる。
3.上記2番目を要因としたカゴ内水面にワーク浮遊が発生する。
4.カゴを液中から引き上げた際、カゴ内液切れまでに時間がかかる。
5.上記4より、洗浄槽への移送時間がかかるため、所望とする周波数より高めの処理結果となってしまう。などの問題が挙げられている。
Regarding the above-mentioned points, the inventor feels problems in the following points in daily work. Etching jigs that have been used in the past use a taper hole in the inner cage and inner lid.
1. The contact area with the etching object (workpiece), which is a piezoelectric element plate, is wide, the work separation when transferring to the beaker is poor, and the work remains in the basket, so that contamination occurs.
2. When the basket is submerged in the liquid, the amount of residual air in the basket is large and the stirring space is narrowed.
3. Work floating occurs on the water surface in the cage due to the second factor.
4). When the basket is pulled up from the liquid, it takes time until the liquid in the basket runs out.
5). From the above 4, since it takes time to transfer to the cleaning tank, the processing result is higher than the desired frequency. Such problems are mentioned.

上記の目的を達成するために本発明は、全体がエッチング溶液に浸る状態で回転運動させられて格納されている圧電素板をエッチング処理するエッチングジグであって、圧電素板が格納される凹状のカゴと、前記カゴに被せられ前記カゴと一体化する蓋と、を備えており、前記カゴの一部及び前記蓋の一部には、耐エッチング溶液の材質からなり且つ隙間間隔が、0.5mm〜0.9mmのメッシュ材料が用いられていることを特徴とする。 In order to achieve the above object, the present invention is an etching jig for etching a piezoelectric element plate that is rotated and stored while being immersed in an etching solution as a whole. and basket, a lid integral with the cage placed over the said basket is provided with a, in a part of a part and the lid of the basket, and a gap distance Do Ri of a material resistant etching solution, A mesh material of 0.5 mm to 0.9 mm is used.

要するに本発明のエッチングジグは、従来のエッチングジグの欠点を改善したもので、エッチングジグの全体がエッチング溶液に浸る状態で回転運動させられて格納されている圧電素板をエッチング処理するときに、エッチング溶液を十分にエッチングジグの中に取り込んで圧電素板がエッチング溶液の流れにより圧電素板を効率よくエッチング処理を行うものである。 In short, the etching jig of the present invention is an improvement of the disadvantages of the conventional etching jig, and when etching the piezoelectric element plate that is rotated and stored while the entire etching jig is immersed in the etching solution , The etching solution is sufficiently taken into the etching jig, and the piezoelectric element plate efficiently etches the piezoelectric element plate by the flow of the etching solution.

その結果、
1.圧電素板(ワーク)との接触面積が減り、ビーカーに移す際のワーク離れが良くなり、ワークを確実に排出することにより、ワーク寸法(仕様)のことなる別の圧電素板をエッチング処理する場合の混入を防止できる。
2.カゴを液中に沈めた際、カゴ内エアー残留量を低減でき、攪拌スペースが広くなる。
3.上記2番目の効果により、カゴ内水面にワーク浮遊が無くなる。
4.カゴを液中から引き上げた際、カゴ内液切れ時間が短縮できる。
5.上記4より洗浄槽への移送時間が短縮され、所望周波数まで完全に処理することができる。
などの従来で挙げる課題を解消し効率良くエッチング処理を行うことができる。
as a result,
1. The contact area with the piezoelectric element plate (workpiece) is reduced, the workpiece is separated when transferred to a beaker, and another piezoelectric element plate with different workpiece dimensions (specifications) is etched by reliably discharging the workpiece. Case contamination can be prevented.
2. When the basket is submerged in the liquid, the amount of residual air in the basket can be reduced, and the stirring space becomes wider.
3. The second effect eliminates work floating on the water surface in the cage.
4). When the basket is pulled up from the liquid, the time of running out of liquid in the basket can be shortened.
5). The transfer time to the washing tank is shortened from 4 above, and it is possible to completely process to a desired frequency.
Thus, the conventional problems such as the above can be solved and the etching process can be performed efficiently.

本発明のエッチングジグを用いたエッチング装置によれば、小型化、薄型化で高周波化が進んだ圧電素板を効率よくエッチング加工することができることにより、エッチング工程を簡略化することができる。そして、圧電素板を使用する圧電振動子等の圧電部品として見た場合には、圧電素板の製造コストを低減することにより安価に提供できる効果を得るものである。 According to the etching apparatus using the etching jig of the present invention, the etching process can be simplified by efficiently etching the piezoelectric element plate which has been miniaturized and thinned and has a high frequency. And when it sees as piezoelectric components, such as a piezoelectric vibrator using a piezoelectric element board, the effect which can be provided cheaply by reducing the manufacturing cost of a piezoelectric element board is acquired.

また、本発明のエッチングジグは、従来と同様に社内の既存装置で使用することができるため新設の設備が不要である。 Moreover, since the etching jig of the present invention can be used with existing equipment in the company as in the prior art, no new equipment is required.

以下に本発明の一実施例を図面を参照しながら説明する。なお、各図においての同一の符号は同じ対象を示すものとする。図1は本発明におけるエッチングジグの概念を示した図である。なお、以下に記述するエッチングジグはエッチング溶液として使用するフッ酸系溶液に耐えうる材料を用いて構成されている。   An embodiment of the present invention will be described below with reference to the drawings. In addition, the same code | symbol in each figure shall show the same object. FIG. 1 is a view showing the concept of an etching jig in the present invention. Note that the etching jig described below is made of a material that can withstand a hydrofluoric acid solution used as an etching solution.

図1において容器1内に蓄えられるエッチング溶液として、例えばフッ酸系溶液としてフッ化アンモニウム溶液があり、そして容器1の中には圧電素板を格納し揺動、回転する耐溶液性の材料で作られたエッチングジグ2を配置し、エッチングジグ全体がエッチング溶液に浸る状態で圧電素板をエッチング処理するものである。図1では模式的な描写になっていが、容器1の中にエッチングジグ2を入れて回転運動させるものである。 As an etching solution stored in the container 1 in FIG. 1, for example, an ammonium fluoride solution is used as a hydrofluoric acid-based solution, and a piezoelectric element plate is housed in the container 1 and is made of a solution-resistant material that swings and rotates. The produced etching jig 2 is arranged, and the piezoelectric element plate is etched in a state where the entire etching jig 2 is immersed in the etching solution. That have been in FIG. 1, a schematic depiction, but is intended to rotate motion put etching jig 2 in the container 1.

図2はエッチングジグに着目した概念図であるが、ここで図示するのは一例であり形状などに特徴があるもでは無い。図2に描画する一例として、エッチングジグ2は圧電素板を格納できる凹状のカゴと、このカゴに蓋を被せることで、格納する圧電素板を漏れ出させないような格好となっている。従って、例えばカゴと蓋とはネジにより一体化する構造が取られている。図2(a)は正面図、図2(b)は側面図である。なお、図3は従来例で同様の描画方法で表現するものである。   FIG. 2 is a conceptual diagram paying attention to the etching jig, but the example shown here is an example, and the shape is not characteristic. As an example depicted in FIG. 2, the etching jig 2 is shaped so as not to leak out the piezoelectric element plate to be stored by covering the cage with a concave cage that can store the piezoelectric element plate and covering the cage. Therefore, for example, a structure is adopted in which the basket and the lid are integrated by screws. 2A is a front view, and FIG. 2B is a side view. Note that FIG. 3 is expressed by the same drawing method in the conventional example.

図2に示すエッチングジグは、例えば多面体の構造を示しており、カゴの底の面と各面と蓋の一部とには、エッチング溶液の流れが円滑に行えるように隙間距離で0.5mm〜0.9mmのメッシュ材料を用いたことに特徴がある。なお、図2では6面体で説明している。   The etching jig shown in FIG. 2 shows, for example, a polyhedral structure, and a gap distance of 0.5 mm is provided on the bottom surface of the cage, each surface, and a part of the lid so that the etching solution can flow smoothly. It is characterized by using a mesh material of ˜0.9 mm. In FIG. 2, a hexahedron is used for explanation.

このメッシュに代えた特徴としては、従来エッチングジグは、内カゴおよび内蓋にテーパ穴を開けたものを使用している関係で、圧電素板であるエッチング対象物(ワーク)との接触面積が多く、例えばエッチング処理後に圧電素板をワークに移す際のワーク離れ悪く、ワークがカゴ内に残ってしまうために、他の仕様のエッチング処理をする場合に混入が発生してしまう場合がある。 Contact area as the feature in place of the mesh, conventional etching jig in relation using those in the inner cage and the inner lid opened tapered hole, the etching object is a piezoelectric element plate (the workpiece) In many cases, for example, when the piezoelectric element plate is transferred to the workpiece after the etching process, the workpiece is not separated from the workpiece, and the workpiece remains in the basket. .

また、カゴを液中に沈めた際、カゴ内エアー残留量が多く、攪拌スペースが狭くなり、カゴ内水面にワークが浮遊することもある。このようにテーパ穴によるエッチングジグでは、エッチング溶液からジグを引き上げたときに、カゴ内液切れまでに時間がかかったり、エッチングムラによる十分なエッチング処理ができないという問題があったが、本発明のメッシュ材料に代えることで、エッチング溶液の流れを円滑にすることで解消するものである。   Further, when the cage is submerged in the liquid, the amount of air remaining in the cage is large, the stirring space is narrowed, and the workpiece may float on the water surface in the cage. As described above, the etching jig with the tapered hole has a problem that when the jig is pulled up from the etching solution, it takes time until the liquid in the cage runs out, or sufficient etching processing due to etching unevenness cannot be performed. By replacing with a mesh material, the flow of the etching solution is made smooth to eliminate the problem.

本発明のエッチング容器全体の概念を示す斜視図である。It is a perspective view which shows the concept of the whole etching container of this invention. 本発明のエッチングジグに注目した概念図である。It is the conceptual diagram which paid its attention to the etching jig of this invention. 従来から用いるエッチングジグの穴加工の様子を示した概念図である。It is the conceptual diagram which showed the mode of the hole processing of the etching jig used conventionally.

符号の説明Explanation of symbols

1 容器
2 エッチングジグ
1 container 2 etching jig

Claims (1)

全体がエッチング溶液に浸る状態で回転運動させられて格納されている圧電素板をエッチング処理するエッチングジグであって、
圧電素板が格納される凹状のカゴと、
前記カゴに被せられ前記カゴと一体化する蓋と、
を備えており、
前記カゴの一部及び前記蓋の一部には、耐エッチング溶液の材質からなり且つ隙間間隔が、0.5mm〜0.9mmのメッシュ材料が用いられている
ことを特徴とするエッチングジグ。
An etching jig for etching a piezoelectric element plate that is rotated and stored while being entirely immersed in an etching solution,
A concave basket in which the piezoelectric element plate is stored;
A lid that covers the cage and is integrated with the cage;
With
Etching jig to a part of a part and the lid of the basket, the and gap distance Do Ri of a material resistant etching solution, characterized in that the mesh material of 0.5mm~0.9mm are used.
JP2005131556A 2005-04-28 2005-04-28 Etching jig Expired - Fee Related JP4817707B2 (en)

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