JP4819243B2 - Small surgical pad - Google Patents
Small surgical pad Download PDFInfo
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- JP4819243B2 JP4819243B2 JP2001135392A JP2001135392A JP4819243B2 JP 4819243 B2 JP4819243 B2 JP 4819243B2 JP 2001135392 A JP2001135392 A JP 2001135392A JP 2001135392 A JP2001135392 A JP 2001135392A JP 4819243 B2 JP4819243 B2 JP 4819243B2
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- thread
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- 230000002745 absorbent Effects 0.000 claims description 12
- 239000002250 absorbent Substances 0.000 claims description 12
- 239000000126 substance Substances 0.000 claims description 8
- 239000004745 nonwoven fabric Substances 0.000 description 17
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 8
- 229920000742 Cotton Polymers 0.000 description 6
- 238000001356 surgical procedure Methods 0.000 description 6
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 238000009958 sewing Methods 0.000 description 5
- 210000004556 brain Anatomy 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- -1 polypropylene Polymers 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 3
- 230000004927 fusion Effects 0.000 description 3
- 238000003384 imaging method Methods 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 230000000399 orthopedic effect Effects 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000012780 transparent material Substances 0.000 description 2
- 206010037660 Pyrexia Diseases 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- YPNVIBVEFVRZPJ-UHFFFAOYSA-L silver sulfate Chemical compound [Ag+].[Ag+].[O-]S([O-])(=O)=O YPNVIBVEFVRZPJ-UHFFFAOYSA-L 0.000 description 1
- 229910000367 silver sulfate Inorganic materials 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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- Materials For Medical Uses (AREA)
- Absorbent Articles And Supports Therefor (AREA)
Description
【0001】
【発明の属する技術分野】
本発明は、例えば脳外科手術や整形外科手術の際に用いる小型パッドであって、X線造影等により体内での存在を見出すことの可能な手術用小型パッドに関するものである。
【0002】
【従来の技術】
外科手術の際には、出血の吸収や術部廻り組織表面の保護等の目的で、また血液等の吸引時に吸引管先端のフィルターとして、多数のガーゼや手術用小型パッドが使用されている。特に脳外科手術や整形外科手術のように細かい部分に対して手術を行う場合等においては、専ら手術用小型パッドが利用されている。
【0003】
この様な手術用小型パッド等が体内に残ると、脳等を圧迫して障害を生じる恐れがあり、また痛みや違和感,或いは微熱等、様々な身体の不調をきたす恐れがあるから、手術終了に際しては全ての小型パッド等を体内から取り除く必要がある。
【0004】
殊に上記小型パッドは小さいから(例えば7mm×7mm,10mm×10mm,20mm×20mm,30mm×60mm等)見落としてしまいがちであり、完全に取り除ききれない懸念がある。そこで該小型パッドに糸を縫い付け(本明細書において、この糸を引出糸と称することがある)、この引出糸の他端を体外に長く引き延ばしておいて目印にするという手法が採られている。
【0005】
他方、手術用小型パッドのパッド部分がガーゼ製や脱脂綿製であると、その切断端部から糸屑等が脱落し易く、この糸屑等が体内に残ることは芳しくないから、次のようなパッド部が提案されている。即ち不織布を多数積層してこれらを厚み方向に交絡したもの(以下、積層不織布と称することがある)、またガーゼの表裏面に不織布を積層してこれらを厚み方向に交絡させたもの(以下、不織布積層ガーゼと称することがある)である。上記積層不織布は不織布であるから切り端が解けて糸屑を生じるということが殆どなく、上記不織布積層ガーゼについても、不織布層の端部が殆ど解けないことに加えて、この表裏の不織布層によってガーゼの解けも防止される。更に不織布が薄手の場合では強度不足となる懸念があるが、上記不織布積層ガーゼは中間層のガーゼによって十分な強度が確保できるという優れた特性を有する。
【0006】
図2は従来の手術用小型パッド60を示す斜視図である。該手術用小型パッド60は6枚の不織布からなる吸収性パッド部61と綿製引出糸62からなり、この引出糸62の一方端部分によって上記パッド部61をジグザグ縫いすることによって(ジグザグ縫い部62a)、パッド部61に引出糸62が取付けられている。尚このジグザグ縫い部62aは、上記パッド部61の各不織布がバラバラにならない様に止める役目も果たしている。
【0007】
【発明が解決しようとする課題】
上述の様に従来の手術用小型パッドは、縫い付けられた引出糸が目印となっているものの、該小型パッドが体内に残る懸念が完全に払拭された訳ではないから、より確実に取り除けるものが望まれている。
【0008】
そこで本発明者は、手術用小型パッドのパッド部にX線非透過性の糸を取り付け、手術終盤の手術部位を閉じる前にX線造影(レントゲン撮影)を行って、上記X線非透過性糸を手がかりに小型パッドの存在の有無を確認し、残っていれば取り除くという方法を思い至った。そして、上記X線非透過性糸としては硫酸バリウムを練り込んだポリプロピレン系樹脂のフィラメント、または硫酸バリウムを練り込んだ塩化ビニル樹脂やシリコン系樹脂のフィラメントが一般に用いられていることから、上記X線非透過性糸に用いられる熱融着性樹脂の性質を利用し、パッド部の表面に熱融着によりX線非透過性糸を取付けるという方法を考えた。
【0009】
しかし一旦融着固化した部分のX線非透過性糸は硬くなりがちであり、殊に脳外科手術のときのように微細な刺激も問題となる場合には、硬い塊部を生じる様な熱融着による取り付けは避ける方が良い。
【0010】
そこで本発明は、X線非透過性糸を用いつつも柔軟性を保ち、手術野からより確実に取り除くことの可能な手術用小型パッドを提供することを目的とする。
【0011】
【課題を解決するための手段】
本発明に係る手術用小型パッドは、複数枚積層構造の吸収性パッド部に引出糸を取り付けた手術用小型パッドであって、前記吸収性パッド部の層間にX線非透過性物質含有糸(以下、X線非透過性糸と称することがある)が挟み込まれたものであることを要旨とする。
【0012】
この様に積層構造のパッド部の層間に上記X線非透過性糸を挟み込むことによって、X線非透過性糸を溶融、固化することなく上記吸収性パッド部に取付けることができるから、X線非透過性糸は柔軟性が保たれたままであり、従って手術用小型パッド全体としての柔軟性も保持される。そして上述の様にX線造影を行ってこのX線非透過性糸を手がかりに小型パッドの有無を確認すると良い。
【0013】
尚X線非透過性物質としては前述の硫酸バリウムの他、硫酸銀,酸化チタン,シリコン等が挙げられ、このX線非透過性物質をポリプロピレン,ポリエチレンテレフタレート,塩化ビニル等の樹脂に含有させて糸状とすると良い。
【0014】
更に本発明に係る手術用小型パッドにおいては、前記X線非透過性物質含有糸を跨いで前記引出糸が縫い付けられたものであることが好ましい。なお上記「X線非透過性糸を跨いで引出糸が縫い付けられる」とは、X線非透過性糸全体を跨ぐ場合だけでなく、X線非透過性糸の一部を跨ぐ場合も含む。尚X線非透過性糸全体を跨いで引出糸で縫い付ける場合がより好ましい。
【0015】
X線非透過性糸は上記の如く一般に合成樹脂を主体としたフィラメントであるから、その表面は滑らかで滑りやすく、しかも上記吸収性パッド部は小さく、挟み込むX線非透過性糸の箇所も短いものとなるから、単に挟んだだけではX線非透過性糸がすり抜けてしまう懸念が多少ともある。しかし上記の様にこのX線非透過性糸を跨ぐように前記引出糸で縫い付けることによって、X線非透過性糸をパッド部にしっかりと固定でき、容易に抜け落ちることがなくなる。加えて熱融着で取付けるわけではないから、X線非透過性糸は柔軟性を保つことができ、手術用小型パッド全体としても柔軟性を保ち得る。
【0016】
上記X線非透過性糸としては、あまり細いものを用いるとX線造影において見付け難くなるから太めの糸を用いるのが良いが、この様な太めの糸を吸収性パッド部へ縫い付けるにあたり、必ずしも縫い目の1目がこの太めの糸の直径方向全体を跨ぐ必要はなく、X線非透過性糸を貫くように縫い付ける、即ちX線非透過性糸の一部を跨いで縫い付けても良い。この縫い付け方法としてはミシンを用いてのジグザグ縫い等が挙げられる。
【0017】
また本発明においては、X線非透過性物質含有糸が無撚りのマルチフィラメントであることが好ましい。
【0018】
無撚りのマルチフィラメントは柔軟性に優れるから、同じ太さ、即ちX線造影時の視認性の程度が同じであるモノフィラメントや撚糸と比べて、好ましい。
【0019】
【発明の実施の形態】
図1の(a)は本発明の一実施形態に係る手術用小型パッドを示す斜視図であり、(b)は(a)に示すB−B線断面図である。
【0020】
この手術用小型パッド10は吸収性パッド部11と綿製引出糸12からなり、上記吸収性パッド部11は、2枚のセルロース製不織布13,14上にX線非透過性糸18を載せ且つキュプラ製ワタ15を積層し、更にセルロース製不織布16を重ね、これを厚み方向に交絡して一体化したものである(図1(b))。上記X線非透過性糸18は、硫酸バリウムを練り込んだポリプロピレン製マルチフィラメントを無撚りで引き揃えたものである。
【0021】
上記引出糸12はその一方端部分により上記X線非透過性糸18を跨ぐようにしてジグザグ縫いされ(ジグザグ縫い部12a)、パッド部11に縫い付けられている。
【0022】
この様に引出糸12のジグザグ縫い部12aによって上記X線非透過性糸18がパッド部11に押さえ付けられているから、X線非透過性糸18はしっかりと固定されて外れることが殆どない。
【0023】
加えてX線非透過性糸18は無撚りマルチフィラメントであるから柔軟であり、しかもこのX線非透過性糸18は融着されているわけではないから柔軟性を保っている。従って手術用小型パッド10全体もしなやかであり、手術の際に組織に損傷を与える恐れが小さい。
【0024】
以上の様に本発明に係る手術用小型パッドに関して、例を示す図面を参照しつつ具体的に説明したが、本発明はもとより図示例に限定される訳ではなく、前記の趣旨に適合し得る範囲で適当に変更を加えて実施することも可能であり、それらはいずれも本発明の技術的範囲に包含される。
【0025】
例えば上記パッド部として不織布やワタを積層したものを挙げたが、これに限るものではなく、ガーゼに不織布を積層し、この層間にX線非透過性糸を挟み込んだもの等であっても良い。また上記例では4層構造のパッド部の場合を示したが、2層や3層、或いは5層,6層構造のものであっても勿論良い。
【0026】
更に上記例では引出糸12がX線非透過性糸18を跨ぐように縫い付けたものを示したが、これに限るものではなく、X線非透過性糸18の存在しないパッド部11部分に引出糸12が縫い付けられたものであっても良い。また上記例では引出糸12のジグザグ縫い部12aの進行方向に沿ってX線非透過性糸18が配置されているものを示したが、これに限らず、例えばジグザグ縫い部12aの進行方向と直交してX線非透過性糸18が配置されたものであっても良く、X線非透過性糸18存在部分とジグザグ縫い部12aとを交叉させることによって、パッド部11にX線非透過性糸18をしっかりと縫い付けることが可能である。
【0027】
【発明の効果】
本発明に係る手術用小型パッドは、X線非透過性物質含有糸が取付けられたものであって、しかも柔軟性が良好であるから、手術野の組織に損傷を与える懸念が小さい。そして上記X線非透過性物質含有糸を目印としてX線造影によって手術用小型パッドの発見が可能である。
【図面の簡単な説明】
【図1】(a)は本発明の一実施形態に係る手術用小型パッドを示す斜視図、(b)は(a)に示すB−B線断面図。
【図2】従来の手術用小型パッドを示す斜視図。
【符号の説明】
10 手術用小型パッド
11 吸収性パッド部
12 引出糸
12a ジグザグ縫い部
13,14,16 不織布
15 ワタ
18 X線非透過性糸[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a small pad for use in, for example, brain surgery or orthopedic surgery, which can be found in the body by X-ray imaging or the like.
[0002]
[Prior art]
In surgical operations, many gauze and small surgical pads are used for the purpose of absorbing bleeding, protecting the tissue surface around the surgical site, and as a filter at the tip of the suction tube when sucking blood or the like. In particular, in the case of performing an operation on a fine part such as a brain surgery or an orthopedic surgery, a small surgical pad is exclusively used.
[0003]
If such a small surgical pad remains in the body, it may cause damage by pressing the brain, etc., and may cause various physical problems such as pain, discomfort, or slight fever. At that time, it is necessary to remove all small pads from the body.
[0004]
In particular, since the small pad is small (for example, 7 mm × 7 mm, 10 mm × 10 mm, 20 mm × 20 mm, 30 mm × 60 mm, etc.), there is a concern that it cannot be completely removed. Therefore, a technique is adopted in which a thread is sewn to the small pad (this thread may be referred to as a drawn thread in the present specification), and the other end of the drawn thread is extended outside the body for a mark. Yes.
[0005]
On the other hand, if the pad portion of the small surgical pad is made of gauze or absorbent cotton, lint etc. easily fall off from the cut end, and it is not good that this lint etc. remains in the body. A pad section has been proposed. That is, a large number of nonwoven fabrics laminated and entangled in the thickness direction (hereinafter sometimes referred to as laminated nonwoven fabrics), and a nonwoven fabric laminated on the front and back surfaces of the gauze and entangled in the thickness direction (hereinafter referred to as the following) It may be referred to as a nonwoven fabric laminated gauze). Since the laminated nonwoven fabric is a nonwoven fabric, the cut ends are rarely broken and yarn waste is hardly generated, and the nonwoven fabric laminated gauze is hardly unwound at the end of the nonwoven fabric layer. It also prevents the gauze from dissolving. Furthermore, although there is a concern that the strength is insufficient when the nonwoven fabric is thin, the nonwoven fabric laminated gauze has an excellent characteristic that a sufficient strength can be secured by the gauze of the intermediate layer.
[0006]
FIG. 2 is a perspective view showing a conventional small surgical pad 60. The small surgical pad 60 is composed of an
[0007]
[Problems to be solved by the invention]
As described above, the conventional small surgical pad is marked by the sewn thread, but the concern that the small pad remains in the body has not been completely wiped out, so it can be removed more reliably. Is desired.
[0008]
Therefore, the present inventor attaches an X-ray impermeable thread to the pad portion of the small surgical pad, performs X-ray contrast (X-ray imaging) before closing the surgical site at the end of the operation, and performs the X-ray impermeable operation. Using the thread as a clue, I came up with a method of checking for the presence of a small pad and removing it if it remained. As the X-ray impermeable yarn, a polypropylene resin filament kneaded with barium sulfate or a vinyl chloride resin or silicon resin filament kneaded with barium sulfate is generally used. Using the property of the heat-fusible resin used for the radiopaque yarn, a method of attaching the radiopaque yarn to the surface of the pad portion by thermal fusion was considered.
[0009]
However, the X-ray-impermeable yarns once fused and solidified tend to be hard, and especially when microstimulation is also a problem, as in brain surgery, heat fusion is likely to produce a hard mass. It is better to avoid wearing by wearing.
[0010]
Accordingly, an object of the present invention is to provide a small surgical pad that can be removed from a surgical field more reliably while maintaining flexibility while using an X-ray impermeable thread.
[0011]
[Means for Solving the Problems]
The small surgical pad according to the present invention is a small surgical pad in which a drawn yarn is attached to an absorbent pad portion having a plurality of laminated structures, and an X-ray impermeable substance-containing yarn (between layers of the absorbent pad portion ( The gist of the present invention is that it is sandwiched between X-ray non-transparent yarns hereinafter.
[0012]
Since the X-ray impermeable yarn is sandwiched between the layers of the pad portion of the laminated structure in this way, the X-ray impermeable yarn can be attached to the absorbent pad portion without melting and solidifying. The non-permeable yarn remains flexible and therefore retains the flexibility of the entire surgical pad. And it is good to confirm the presence or absence of a small pad by performing X-ray contrast as described above and using this X-ray impermeable thread as a clue.
[0013]
In addition to the above-mentioned barium sulfate, examples of the X-ray non-transparent material include silver sulfate, titanium oxide, silicon, and the like. This X-ray non-transparent material is contained in a resin such as polypropylene, polyethylene terephthalate, and vinyl chloride. It is better to use a thread.
[0014]
Furthermore, in the small surgical pad according to the present invention, it is preferable that the drawn thread is sewn across the X-ray impermeable substance-containing thread. Note that “the drawn yarn is sewn across the X-ray impermeable thread” includes not only the case of straddling the entire X-ray impermeable thread but also the case of striding a part of the X-ray impermeable thread. . It is more preferable to sew the whole X-ray impermeable thread with the drawn thread.
[0015]
Since the X-ray impermeable yarn is generally a filament mainly composed of a synthetic resin as described above, the surface thereof is smooth and slippery, the absorbent pad portion is small, and the portion of the X-ray impermeable yarn to be sandwiched is also short. Therefore, there is some concern that the X-ray impermeable thread slips through the pinch. However, by sewing with the drawn-out thread so as to straddle the X-ray impermeable thread as described above, the X-ray impermeable thread can be firmly fixed to the pad portion and will not easily fall off. In addition, since it is not attached by heat fusion, the X-ray impermeable thread can maintain flexibility, and the entire surgical small pad can also maintain flexibility.
[0016]
As the X-ray impermeable thread, if a very thin thread is difficult to find in X-ray contrast, it is preferable to use a thick thread, but when sewing such a thick thread to the absorbent pad portion, It is not always necessary that the first seam crosses over the entire diameter direction of the thick thread. Even if it is sewn so as to penetrate the X-ray non-transparent thread, that is, even if it is sewed over a part of the X-ray non-transmissible thread good. Examples of the sewing method include zigzag sewing using a sewing machine.
[0017]
In the present invention, the X-ray non-transparent substance-containing yarn is preferably a non-twisted multifilament.
[0018]
Non-twisted multifilaments are excellent in flexibility, and are preferable compared to monofilaments and twisted yarns having the same thickness, that is, the same degree of visibility during X-ray imaging.
[0019]
DETAILED DESCRIPTION OF THE INVENTION
FIG. 1A is a perspective view showing a small surgical pad according to an embodiment of the present invention, and FIG. 1B is a cross-sectional view taken along line B-B shown in FIG.
[0020]
The small
[0021]
The drawn
[0022]
Since the X-ray
[0023]
In addition, the X-ray
[0024]
As described above, the small surgical pad according to the present invention has been specifically described with reference to the drawings showing examples. However, the present invention is not limited to the illustrated examples but can be adapted to the above-described purpose. It is also possible to carry out by appropriately changing the range, and all of them are included in the technical scope of the present invention.
[0025]
For example, although the nonwoven fabric or cotton laminated as the pad portion is mentioned, the present invention is not limited to this, and a nonwoven fabric laminated on gauze and an X-ray impermeable thread sandwiched between the layers may be used. . In the above example, the case of a pad portion having a four-layer structure is shown, but it is of course possible to have a two-layer, three-layer, or five-layer or six-layer structure.
[0026]
Further, in the above example, the drawn
[0027]
【The invention's effect】
The small surgical pad according to the present invention is provided with a non-radiation-impervious substance-containing yarn and has good flexibility, so that there is little fear of damaging the tissue in the surgical field. A small surgical pad can be found by X-ray contrast using the X-ray impermeable substance-containing yarn as a mark.
[Brief description of the drawings]
FIG. 1A is a perspective view showing a small surgical pad according to an embodiment of the present invention, and FIG. 1B is a sectional view taken along line BB shown in FIG.
FIG. 2 is a perspective view showing a conventional small surgical pad.
[Explanation of symbols]
DESCRIPTION OF
Claims (2)
前記吸収性パッド部の層間にX線非透過性物質含有糸が挟み込まれ、前記引出糸が前記X線非透過性物質含有糸を跨いで前記吸収性パッド部に縫い付けられたものであることを特徴とする手術用小型パッド。In a small surgical pad with a drawn thread attached to an absorbent pad portion of a multi-layer structure,
X-ray impermeable substance-containing yarn is sandwiched between layers of the absorbent pad portion, and the drawn yarn is sewn to the absorbent pad portion across the X-ray impermeable substance-containing yarn. A small surgical pad characterized by
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001135392A JP4819243B2 (en) | 2001-05-02 | 2001-05-02 | Small surgical pad |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001135392A JP4819243B2 (en) | 2001-05-02 | 2001-05-02 | Small surgical pad |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2002325774A JP2002325774A (en) | 2002-11-12 |
| JP4819243B2 true JP4819243B2 (en) | 2011-11-24 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001135392A Expired - Lifetime JP4819243B2 (en) | 2001-05-02 | 2001-05-02 | Small surgical pad |
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| Country | Link |
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| JP (1) | JP4819243B2 (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20120071846A1 (en) * | 2010-09-22 | 2012-03-22 | American Surgical Sponges, Llc | Medical Tool Deflection and Resistant Surgical Sponge |
| WO2012066932A1 (en) | 2010-11-18 | 2012-05-24 | 日本エー・シー・ピー株式会社 | Surgical pad |
| JP2013094257A (en) * | 2011-10-28 | 2013-05-20 | Kawamoto Sangyo Kk | Small surgical pad |
| JP6026114B2 (en) * | 2012-03-02 | 2016-11-16 | 株式会社リブドゥコーポレーション | Protection sheet holding member and disposable medical device set |
| WO2014084146A1 (en) * | 2012-11-28 | 2014-06-05 | 川本産業株式会社 | Surgical thread, surgical small pad and blood vessel tape that use the thread |
| JP2016163696A (en) * | 2015-02-27 | 2016-09-08 | 大日精化工業株式会社 | Medical material and adhesion prevention material |
| JP7317280B2 (en) * | 2019-12-05 | 2023-07-31 | 有限会社Ems | Surgical absorbent pad, its manufacturing method and manufacturing device |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54125896A (en) * | 1978-03-23 | 1979-09-29 | Kuraray Co | Absorbing body that have excellent water absorbing capacity |
| JPS61185406U (en) * | 1985-05-10 | 1986-11-19 |
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2001
- 2001-05-02 JP JP2001135392A patent/JP4819243B2/en not_active Expired - Lifetime
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| Publication number | Publication date |
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| JP2002325774A (en) | 2002-11-12 |
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