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JP4837360B2 - Double-sided adhesive film - Google Patents
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JP4837360B2 - Double-sided adhesive film - Google Patents

Double-sided adhesive film Download PDF

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JP4837360B2
JP4837360B2 JP2005312125A JP2005312125A JP4837360B2 JP 4837360 B2 JP4837360 B2 JP 4837360B2 JP 2005312125 A JP2005312125 A JP 2005312125A JP 2005312125 A JP2005312125 A JP 2005312125A JP 4837360 B2 JP4837360 B2 JP 4837360B2
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sensitive adhesive
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adhesive
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JP2007119562A (en
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池 敏 浩 小
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Sun A Kaken Co Ltd
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Description

本発明は、両面粘着フィルに係り、特に、基材(芯材)を備えた両面粘着フィルに関する。
なお、特に、本発明の両面粘着フィルムを光学部材貼りあわせ用、さらには、液晶ディスプレイ(LCD)等、光学異方性を有する部材を含むユニットにかかわる部材の貼り合わせに使用すると、有用である。
The present invention relates to a double-sided pressure-sensitive adhesive fill beam, in particular, relates to double-sided pressure-sensitive adhesive fill beam with substrate (core material).
In particular, the double-sided pressure-sensitive adhesive film of the present invention is useful for laminating optical members, and also for laminating members related to units including optically anisotropic members such as liquid crystal displays (LCDs). .

近年、LCDやプラズマディスプレイ(PDP)などのフラットパネルディスプレイ(FPD)が広く用いられている。これらには種々の光学機能性をもつフィルムが積層されており、これらは透明性、耐久性、作業性などから粘着剤により貼り合わされている。
粘着層を形成するには、
1、部材に粘着剤溶液を直接塗布、乾燥する方法
2、離型フィルムに粘着剤溶液を塗布、乾燥して粘着層を形成し、部材を貼り合せる 方法
3、両面粘着フィルムを貼り合せる方法がある。
特に、基材レスの両面粘着フィルムを用いた貼り合わせによる方法は、生産対応が柔軟性に富み、少量多品種での生産にも向くことからよく用いられている。
In recent years, flat panel displays (FPD) such as LCD and plasma display (PDP) have been widely used. These are laminated with films having various optical functionalities, and these are bonded with an adhesive from the viewpoint of transparency, durability, workability and the like.
To form an adhesive layer,
1. Method of directly applying and drying a pressure-sensitive adhesive solution on a member 2. Method of applying a pressure-sensitive adhesive solution to a release film and drying to form a pressure-sensitive adhesive layer and bonding the members. Method 3. Method of bonding a double-sided pressure-sensitive adhesive film. is there.
In particular, the method of bonding using a double-sided adhesive film without a base material is often used because it is flexible in production and suitable for production in a small variety of products.

しかしながら、従来の基材レスの両面粘着フィルムを用いると端部からの粘着剤のはみ出しにより部材表面に汚染を生じ、これが作業性、良品製造率を損なっていた。
また、粘着剤の物性を堅くすることで、はみ出しの問題はある程度回避することができるが、堅くすることで耐久性等に問題を生じ、性能面で全てに満足のいくものは得られていなかった。
また、端部からの粘着剤のはみ出しが少ないものとしてPETフィルムを基材(芯材)とした両面粘着フィルムが知られているが、これは基材のPETフィルムに配向があるため、光学異方性を有する部材を用いている系では使用することが出来ないものである。また、基材のPETフィルムが持っている内部ヘイズが問題となる場合もあった。内部ヘイズとはフィルム内部に起因するヘイズ(濁度)のことで、この値が高いと視覚的に濁って見えてしまう。更に、基材(芯材)の伸縮性、柔軟性が十分でないために貼り合わせや温湿度変化に伴う部材の伸張に対応できずに不具合を生じることもあった。
また、近年製造コストを抑える目的でリワーク性を有する粘着剤が用いられている。これは貼り合わせに不具合を生じた場合に再剥離を行うことで特定の部位を再利用しようとするものであるが、基材レスの両面粘着フィルムを用いると粘着剤のみ取り除くことはできないため、片側の部材は再利用することができなかった。更に、リワーク性を持たせるために粘着力は低めであることから、粘着剤が残ってほしい部材から粘着剤がはがれて被着体に残るという所謂糊残りという現象が起こりがちであった。
本発明はこうした状況にかんがみなされたもので、光学的に無配向であり、端部からの粘着剤のはみ出しが少なく、また、選択する粘着剤により、貼り合わせた部材からの完全除去が可能で、特に、FPD用途に用いられる両面粘着フィルを提供することを課題としている。
However, when a conventional baseless double-sided pressure-sensitive adhesive film is used, the surface of the member is contaminated by the protrusion of the pressure-sensitive adhesive from the end, which impairs the workability and the good product production rate.
In addition, by sticking the physical properties of the adhesive, the problem of protrusion can be avoided to some extent, but by making it hard, problems such as durability have occurred, and satisfactory performance has not been obtained. It was.
In addition, a double-sided pressure-sensitive adhesive film using a PET film as a base material (core material) is known as an adhesive that does not protrude from the end part. It cannot be used in a system using a member having directionality. Moreover, the internal haze which the PET film of a base material has had a problem. The internal haze is haze (turbidity) due to the inside of the film, and when this value is high, it looks visually turbid. Further, since the stretchability and flexibility of the base material (core material) are not sufficient, it may not be able to cope with the stretching of the member accompanying the pasting or temperature / humidity change, resulting in a problem.
In recent years, pressure-sensitive adhesives having reworkability have been used for the purpose of reducing production costs. This is to try to reuse a specific part by performing re-peeling when there is a problem in bonding, but it is not possible to remove only the adhesive when using a baseless double-sided adhesive film, The member on one side could not be reused. Furthermore, since the adhesive strength is low in order to provide reworkability, a so-called adhesive residue phenomenon that the adhesive is peeled off from the member where the adhesive is desired to remain and remains on the adherend tends to occur.
The present invention has been considered under such circumstances, is optically non-oriented, has little protrusion of the adhesive from the end, and can be completely removed from the bonded member by the selected adhesive. , in particular, it has an object to provide a double-sided pressure-sensitive adhesive fill arm used for FPD applications.

本発明の両面粘着フィルムは、光学的に無配向でかつ透明なポリウレタン系樹脂からなる基材と、この基材の一方の面に設けられた透明な第1の粘着層と、前記基材の他方の面に設けられた透明な第2の粘着層とを有し、積層された3層の厚みが55μm以下で、かつ、前記基材の厚みが3μm〜20μmであり、内部HAZEが1以下である。
The double-sided pressure-sensitive adhesive film of the present invention comprises a base material made of an optically non-oriented and transparent polyurethane resin , a transparent first pressure-sensitive adhesive layer provided on one surface of the base material, A transparent second adhesive layer provided on the other surface, the thickness of the three laminated layers is 55 μm or less, the thickness of the substrate is 3 μm to 20 μm , and the internal HAZE is 1 %. It is as follows.

また、請求項2記載の両面粘着フィルムは、請求項1記載の両面粘着フィルムにおいて、第1の粘着層は、アクリル系粘着剤で形成され、前記第1の粘着層側をアクリル板に貼り合わせ、23℃で1日保持した後に、剥離速度300mm/分、180°剥離での粘着力が5N/25mm以下で、かつ、剥離の際に前記アクリル板に前記アクリル系粘着剤が残らないものである。
Moreover, the double-sided pressure-sensitive adhesive film according to claim 2 is the double-sided pressure-sensitive adhesive film according to claim 1 , wherein the first pressure-sensitive adhesive layer is formed of an acrylic pressure-sensitive adhesive, and the first pressure-sensitive adhesive layer side is bonded to an acrylic plate. After holding at 23 ° C. for 1 day, the peeling speed is 300 mm / min, the adhesive strength at 180 ° peeling is 5 N / 25 mm or less, and the acrylic adhesive does not remain on the acrylic plate at the time of peeling. is there.

また、請求項3記載の両面粘着フィルムは、請求項1または2記載の両面粘着フィル
ムにおいて、第1の粘着層及び第2の粘着層がアクリル系で、JIS K7127による引張強さが5MPa以上である。
The double-sided pressure-sensitive adhesive film according to claim 3 is the double-sided pressure-sensitive adhesive film according to claim 1 or 2, wherein the first pressure-sensitive adhesive layer and the second pressure-sensitive adhesive layer are acrylic, and the tensile strength according to JIS K7127 is 5 MPa or more. is there.

また、請求項記載の両面粘着フィルムは、請求項1または2記載の両面粘着フィルムにおいて、第1の粘着層と第2の粘着層とが異なるものである。
Moreover, the double-sided pressure-sensitive adhesive film according to claim 4 is the double-sided pressure-sensitive adhesive film according to claim 1 or 2 , wherein the first pressure-sensitive adhesive layer and the second pressure-sensitive adhesive layer are different.

本発明の両面粘着フィルムは、粘着剤の端面からのはみ出しが少なく、作業性、歩留まり良く加工することが可能となった。また、十分な柔軟性、伸縮性を有するために耐久試験においても良好な結果が得られた。また、リワーク性を有する粘着剤を用いることで、粘着フィルムのみを取り除くことが出来、貼り合わせに不具合を生じた場合にいずれの部材も再利用することができ、製造コストの削減に寄与することが出来た。更に、基材両面に積層する粘着剤の物性(第1の粘着層と第2の粘着層)を変えることで両面の被着体に対する粘着力をコントロールすることが出来、再剥離する際の糊残り防止を確実にすることが出来た。なお、特に、両面粘着フィルムを光学用両面粘着フィルムとして用いれば、光学部材の貼り合わせにおいても光学異方性に影響を与えず、有用である。   The double-sided pressure-sensitive adhesive film of the present invention has few protrusions from the end face of the pressure-sensitive adhesive, and can be processed with good workability and yield. Moreover, since it has sufficient softness | flexibility and a stretching property, the favorable result was obtained also in the endurance test. In addition, by using a reworkable pressure-sensitive adhesive, only the pressure-sensitive adhesive film can be removed, and any member can be reused when a problem occurs in bonding, contributing to a reduction in manufacturing costs. Was made. Furthermore, by changing the physical properties of the adhesive (first adhesive layer and second adhesive layer) laminated on both sides of the base material, the adhesive force on the adherends on both sides can be controlled, and the adhesive when re-peeling We were able to ensure the remaining prevention. In particular, if the double-sided pressure-sensitive adhesive film is used as an optical double-sided pressure-sensitive adhesive film, the optical anisotropy is not affected even when the optical member is bonded.

本発明の両面粘着フィルの一実施例を図面を参照して説明する。
図1において、1は両面粘着フィルムで、両面粘着フィルム1は、光学的に無配向でかつ透明な基材2と、この基材2の一方の面に設けられた透明な第1の粘着層3と、基材2の他方の面に設けられた透明な第2の粘着層4とを有し、積層された3層の厚みTが55μm以下で、内部HAZEが1以下となっている。
An example of a double-sided adhesive fill arm of the present invention will be described with reference to the drawings.
In FIG. 1, 1 is a double-sided pressure-sensitive adhesive film. The double-sided pressure-sensitive adhesive film 1 is an optically non-oriented and transparent base material 2 and a transparent first pressure-sensitive adhesive layer provided on one surface of the base material 2. 3 and the transparent second adhesive layer 4 provided on the other surface of the substrate 2, the thickness T of the laminated three layers is 55 μm or less, and the internal HAZE is 1 % or less. .

光学的に無配向でかつ透明な基材2を製造するのに用いられる樹脂は、ポリエステル系樹脂、ポリウレタン系樹脂、ナイロン系樹脂、ポリカーボネート系樹脂、セルロース系樹脂、シクロオレフィン系樹脂、ポリメチルメタクリレート系樹脂などである。加工方法としては押し出し成形、インフレーション成形、溶液のキャスト法などで製造することができるが、光学的な異方性を生じさせないためには各樹脂溶液のキャスト法により製造することが好ましい。上記樹脂の中では引張強さ、透明性の点からポリウレタンを用いることが特に好ましい。
ポリウレタンに関してはポリオールとイソシアネ−トの2液反応系の塗工液として塗工後に重合付加反応をさせることで、また、ポリウレタン樹脂溶液を塗工する事によっても得ることが出来る。更に密着性を向上させるためにポリウレタン樹脂にイソシアネートを添加することも出来る。これらは非黄変性のものを用いることが好ましい。なおポリオールとイソシアネートの反応には触媒を用いることもできる。基材2は各樹脂溶液のキャスト法により作成することが出来るが、離型処理されたフィルムの離型面に塗布、乾燥し、更に必要に応じてブロッキング防止の意味で離型フィルムの離型面を基材面に貼り合わせることで比較的容易に無配向の基材フィルムを作成することができる。
塗工方式は特に限定されるものではなく、公知の方式、たとえばグラビアコート、ワイヤーバーコート、ロールコート、エアナイフコート、リバースコート、キスコートなどを用いることが出来る。
基材2の厚みは2μm〜50μmで、これより低い場合は基材2を用いる効果が得られにくく、またこれより高くなると粘着フィルムとしての厚みが過多となり、実際に使用した場合の最終構成に不具合を生じるし不経済でもある。更に、好ましい厚みは3μm〜20μmである。
The resin used for producing the optically non-oriented and transparent substrate 2 is polyester resin, polyurethane resin, nylon resin, polycarbonate resin, cellulose resin, cycloolefin resin, polymethyl methacrylate. Resin. As a processing method, it can be produced by extrusion molding, inflation molding, solution casting method, etc., but in order not to cause optical anisotropy, it is preferable to produce by each resin solution casting method. Among the above resins, it is particularly preferable to use polyurethane from the viewpoint of tensile strength and transparency.
Polyurethane can also be obtained by applying a polymerization addition reaction after coating as a two-component coating solution of polyol and isocyanate, or by coating a polyurethane resin solution. Further, isocyanate can be added to the polyurethane resin in order to improve the adhesion. These are preferably non-yellowing ones. In addition, a catalyst can also be used for reaction of a polyol and isocyanate. The base material 2 can be prepared by a casting method of each resin solution, but is applied to the release surface of the release-treated film, dried, and then released from the release film as necessary to prevent blocking. A non-oriented base film can be produced relatively easily by laminating the surface to the base surface.
The coating method is not particularly limited, and known methods such as gravure coating, wire bar coating, roll coating, air knife coating, reverse coating, and kiss coating can be used.
The thickness of the base material 2 is 2 μm to 50 μm, and if it is lower than this, the effect of using the base material 2 is difficult to obtain, and if it is higher than this, the thickness as an adhesive film becomes excessive, and the final configuration when actually used It causes troubles and is also uneconomical. Furthermore, a preferable thickness is 3 μm to 20 μm.

第1の粘着層3又は第2の粘着層4を構成する組成物は、(メタ)アクリル酸エステルを主成分とするポリマー、架橋剤、さらに必要に応じて粘着付与樹脂を含有することもできる。または、天然ゴムもしくは合成ゴム、シリコーンゴム、ウレタン樹脂からなるポリマーと、架橋剤、場合により粘着付与樹脂を含有することもできる。
本発明に使用する(メタ)アクリル酸エステルを主成分とするポリマーは、従来公知の重合法により、(メタ)アクリル酸エステルを主成分とする単量体混合物を重合して得られたポリマーである。この単量体混合物としては、(メタ)アクリル酸エステルを主成分とし、架橋剤と架橋反応する官能基を有する官能基含有モノマーを必須成分とする。またその他のビニル系モノマーを配合することもできる。
主成分として用いる(メタ)アクリル酸エステルの例としてはメチル(メタ)アクリレート、エチル(メタ)アクリレート、プロピル(メタ)アクリレート、n−ブチル(メタ)アクリレート、iso−ブチル(メタ)アクリレート、2エチルヘキシル(メタ)アクリレート、n−オクチル(メタ)アクリレート、iso−オクチル(メタ)アクリレート、ラウリル(メタ)アクリレート、ステアリル(メタ)アクリレート、メトキシエチル(メタ)アクリレート、エトキシメチル(メタ)アクリレートなどを挙げることができる。これらは単独でもしくは組み合わせて使用することができる。
また、官能基含有モノマーの例としては、(メタ)アクリル酸、イタコン酸、マレイン酸、フマル酸、無水マレイン酸、β−カルボキシエチルアクリレートなどのようにカルボキシル基を有するモノマー、2−ヒドロキシエチル(メタ)アクリレート、4−ヒドロキシブチル(メタ)アクリレート、ジエチレングリコールモノ(メタ)アクリレートなどのヒドリキシル基含有モノマー、グリシジル(メタ)アクリレートなどのエポキシ基含有モノマー、アミノメチル(メタ)アクリレート、ジメチルアミノエチル(メタ)アクリレートなどのアミノ基を有するモノマー、アクリルアミド、メチロール(メタ)アクリルアミドなどのアミド基含有のモノマーなどを挙げることができる。これらは単独でもしくは組み合わせて使用することができる。
更に、その他のモノマーとしては、スチレン、メチルスチレン及びビニルトルエン等の芳香族ビニルモノマー、酢酸ビニル、塩化ビニル、(メタ)アクリロニトリル等を単独であるいは組み合わせて共重合させてもよい。
The composition which comprises the 1st adhesion layer 3 or the 2nd adhesion layer 4 can also contain the polymer which has (meth) acrylic acid ester as a main component, a crosslinking agent, and also a tackifying resin as needed. . Alternatively, a polymer made of natural rubber or synthetic rubber, silicone rubber, urethane resin, a crosslinking agent, and optionally a tackifying resin may be contained.
The polymer mainly composed of (meth) acrylate used in the present invention is a polymer obtained by polymerizing a monomer mixture mainly composed of (meth) acrylate by a conventionally known polymerization method. is there. As the monomer mixture, a (meth) acrylic acid ester as a main component and a functional group-containing monomer having a functional group that undergoes a crosslinking reaction with a crosslinking agent as an essential component. Other vinyl monomers can also be blended.
Examples of (meth) acrylic acid esters used as the main component include methyl (meth) acrylate, ethyl (meth) acrylate, propyl (meth) acrylate, n-butyl (meth) acrylate, iso-butyl (meth) acrylate, and 2-ethylhexyl. (Meth) acrylate, n-octyl (meth) acrylate, iso-octyl (meth) acrylate, lauryl (meth) acrylate, stearyl (meth) acrylate, methoxyethyl (meth) acrylate, ethoxymethyl (meth) acrylate, etc. Can do. These can be used alone or in combination.
Examples of functional group-containing monomers include monomers having a carboxyl group such as (meth) acrylic acid, itaconic acid, maleic acid, fumaric acid, maleic anhydride, β-carboxyethyl acrylate, 2-hydroxyethyl ( Hydroxyl group-containing monomers such as meth) acrylate, 4-hydroxybutyl (meth) acrylate, diethylene glycol mono (meth) acrylate, epoxy group-containing monomers such as glycidyl (meth) acrylate, aminomethyl (meth) acrylate, dimethylaminoethyl (meth) ) Monomers having an amino group such as acrylate, and amide group-containing monomers such as acrylamide and methylol (meth) acrylamide. These can be used alone or in combination.
Furthermore, as other monomers, aromatic vinyl monomers such as styrene, methylstyrene and vinyltoluene, vinyl acetate, vinyl chloride, (meth) acrylonitrile and the like may be copolymerized alone or in combination.

本発明に使用するゴム系粘着剤としては、天然ゴム、スチレン−イソプレン−スチレンブロック共重合、スチレン−ブタジエン−スチレンブロック共重合体、スチレン−エチレン・ブチレン−スチレンブロック共重合体、スチレンブタジエンゴム、ポリブタジエン、ポリイソプレン、ポリイソブチレン、ブチルゴム、クロロプレンゴム、シリコーンゴム、さらにはウレタン樹脂を単独もしくは組み合わせて使用することが出来る。
これらに加える粘着付与樹脂としては、テルペン樹脂、α−ピネン、テルペンフェノール共重合体、ロジンおよびロジン誘導体、クマロン−インデン樹脂、炭化水素樹脂、アルキルフェノール樹脂、キシレン樹脂、芳香族石油樹脂、脂肪族石油樹脂、脂環族石油樹脂などが上げられ、これらの一種もしくは数種の混合物を用いることができる。更に、アクリル樹脂を用いることも出来る。
架橋剤としては、イソシアネ−ト系化合物、エポキシ系化合物、アジリジン系化合物、金属キレート系化合物およびアミン系化合物等を挙げることができる。これらの架橋剤は単独で用いる事も2種類以上を併用して用いる事もできる。この架橋剤の添加量は、慎重に検討される必要がある。
Examples of the rubber-based pressure-sensitive adhesive used in the present invention include natural rubber, styrene-isoprene-styrene block copolymer, styrene-butadiene-styrene block copolymer, styrene-ethylene / butylene-styrene block copolymer, styrene-butadiene rubber, Polybutadiene, polyisoprene, polyisobutylene, butyl rubber, chloroprene rubber, silicone rubber, and urethane resin can be used alone or in combination.
Tackifying resins added to these include terpene resins, α-pinene, terpene phenol copolymers, rosin and rosin derivatives, coumarone-indene resins, hydrocarbon resins, alkylphenol resins, xylene resins, aromatic petroleum resins, aliphatic petroleum Resins, alicyclic petroleum resins and the like can be raised, and one or a mixture of these can be used. Furthermore, an acrylic resin can also be used.
Examples of the crosslinking agent include isocyanate compounds, epoxy compounds, aziridine compounds, metal chelate compounds, and amine compounds. These crosslinking agents can be used alone or in combination of two or more. The addition amount of this crosslinking agent needs to be carefully examined.

形成された第1の粘着層3又は第2の粘着層4には、離型フィルムを離型面が粘着層に合わさるようにして積層することができる。離型フィルムとしてはポリエチレン等粘着層に対して離型性を持つものを用いるほか、フィルムにシリコーン系、フッ素系等の離型剤を塗布したもの、離型性を持つフィルムを貼り合わせたものなどを用いることも出来る。合わせられる粘着層への影響を考慮して表面が平滑なものが好ましく、また第1の粘着層3又は第2の粘着層4表面への離型成分の移行がないものが好ましい。PETフィルムにシリコーン系の離型剤が塗工された物が一般的に用いられる。
第1の粘着層3又は第2の粘着層4の形成には、アクリル系粘着剤やゴム系粘着剤を有機溶剤に希釈して基材上に塗布、乾燥することで形成することが出来る。またエマルジョンタイプを用いることも出来る。さらに離型処理されたフィルムの離型面に粘着剤を塗工してから、基材フィルムを貼り合わせることで粘着剤を転写させる方法などを採ることもできる、
塗工方式は特に限定される物ではなく、公知の方式、たとえばグラビアコート、ワイヤーバーコート、ロールコート、エアナイフコート、リバースコート、キスコートなどを用いることが出来る。
A release film can be laminated on the first adhesive layer 3 or the second adhesive layer 4 so that the release surface is aligned with the adhesive layer. In addition to using a release film for the adhesive layer, such as polyethylene, a release film such as silicone or fluorine is applied to the film, or a film with a release film is bonded. Etc. can also be used. In consideration of the influence on the adhesive layer to be combined, those having a smooth surface are preferable, and those having no release component transfer to the surface of the first adhesive layer 3 or the second adhesive layer 4 are preferable. Generally, a PET film coated with a silicone release agent is used.
The first pressure-sensitive adhesive layer 3 or the second pressure-sensitive adhesive layer 4 can be formed by diluting an acrylic pressure-sensitive adhesive or a rubber-based pressure-sensitive adhesive in an organic solvent, and applying and drying the substrate. An emulsion type can also be used. Furthermore, after applying a pressure-sensitive adhesive to the release surface of the release-treated film, it is possible to adopt a method of transferring the pressure-sensitive adhesive by laminating the base film.
The coating method is not particularly limited, and known methods such as gravure coating, wire bar coating, roll coating, air knife coating, reverse coating, and kiss coating can be used.

基材片側の粘着層の厚みは1μmから40μmで好ましくは2μmから20μmである。薄すぎると十分な性能が得られず又厚すぎると不経済であるばかりでなく、端部からの粘着剤のはみ出しを生じやすくなり、また、粘着剤の凝集破壊を引き起こす場合もある。
なお、基材2の両側の第1の粘着層3又は第2の粘着層4は、組成、塗布厚みを変えることで物性を変化させることができる。こうしたことにより、両面粘着フィルム1の片側だけ粘着力を高めるなど種々の設計ができ、剥離時の糊残り防止などの効果を得ることができる。
The thickness of the pressure-sensitive adhesive layer on one side of the substrate is 1 μm to 40 μm, preferably 2 μm to 20 μm. If it is too thin, sufficient performance cannot be obtained, and if it is too thick, not only is it uneconomical, but it also tends to cause the adhesive to protrude from the end, and may cause cohesive failure of the adhesive.
In addition, the 1st adhesion layer 3 or the 2nd adhesion layer 4 of the both sides of the base material 2 can change a physical property by changing a composition and application | coating thickness. By doing so, various designs such as increasing the adhesive force only on one side of the double-sided pressure-sensitive adhesive film 1 can be performed, and effects such as prevention of adhesive residue at the time of peeling can be obtained.

本構成の両面粘着フィルム1を製造するには、各界面での剥離力がコントロールされた離型フィルムを用いる方法が効率的である。
即ち、それぞれの界面での剥離力がA,D<B<Cである離型フィルムA、B、C、Dを用い、図2に示すように、離型フィルムBに基材樹脂溶液を塗布乾燥して基材2を形成し、該基材2に離型フィルムAをラミネートする(第1の工程)。
また、図3(a)に示すように、離型フィルムCに粘着剤溶液を塗布乾燥して第1の粘着層3を形成し、この第1の粘着層3に第1の工程で得られた基材2から離型フィルムAを剥がし、図3(b)に示すように、第1の粘着層3と基材2が合わさるようにして貼り合わせる(第2の工程)。
次に、図4(a)に示すように、離型フィルムDに粘着剤溶液を塗布乾燥して第2の粘着層4を形成し、この第2の粘着層4に第2の工程で得られた基材2から離型フィルムBを剥がし、図4(b)に示すように、第2の粘着層4と基材2が合わさるようにして貼り合わせを行い、順次、離型フィルムC、第1の粘着層3、基材2、第2の粘着層4、離型フィルムDが積層されて両面粘着フィルムを得る(第3の工程)。
この方法によれば均一な厚みを有する無配向の基材2を容易に得ることが出来、基材2にダメージを与えることがなく粘着層3、4を両面に積層することが出来る。
In order to manufacture the double-sided pressure-sensitive adhesive film 1 having this configuration, it is efficient to use a release film in which the peeling force at each interface is controlled.
That is, using the release films A, B, C, and D where the peel force at each interface is A and D <B <C, the base resin solution is applied to the release film B as shown in FIG. The substrate 2 is formed by drying, and the release film A is laminated on the substrate 2 (first step).
Moreover, as shown to Fig.3 (a), the adhesive solution is apply | coated and dried to the release film C, the 1st adhesion layer 3 is formed, and this 1st adhesion layer 3 is obtained at a 1st process. The release film A is peeled off from the base material 2 and bonded together so that the first adhesive layer 3 and the base material 2 are combined as shown in FIG. 3B (second step).
Next, as shown in FIG. 4A, a pressure-sensitive adhesive solution is applied to the release film D and dried to form a second pressure-sensitive adhesive layer 4, which is obtained in the second step. The release film B is peeled off from the obtained base material 2 and, as shown in FIG. 4 (b), the second adhesive layer 4 and the base material 2 are bonded together so that the release film C, The 1st adhesion layer 3, the base material 2, the 2nd adhesion layer 4, and the release film D are laminated | stacked, and a double-sided adhesion film is obtained (3rd process).
According to this method, the non-oriented substrate 2 having a uniform thickness can be easily obtained, and the adhesive layers 3 and 4 can be laminated on both surfaces without damaging the substrate 2.

以下、参考例、実施例および比較例により本発明を説明する。ただし、本発明は以下の実施例によって限定されるものではない。なお、参考例、実施例中に記載された軽剥離PETセパレータ(離型フィルムA、離型フィルムD)、中剥離PETセパレータ(離型フィルムB)、重剥離PETセパレータ(離型フィルムC)は、それぞれ対応する剥離力が0.1N/50mm以下、0.11〜0.17N/50mm、0.18〜0.4N/50mm(いずれも剥離速度は300mm/分)である。
Hereinafter, the present invention will be described by reference examples, examples and comparative examples. However, the present invention is not limited to the following examples. In addition, the light release PET separator (release film A, release film D), middle release PET separator (release film B), and heavy release PET separator (release film C) described in Reference Examples and Examples are as follows. The corresponding peeling forces are 0.1 N / 50 mm or less, 0.11 to 0.17 N / 50 mm, and 0.18 to 0.4 N / 50 mm (all peeling speed is 300 mm / min).

参考例1
ポリエステル樹脂(東洋紡績株式会社製 商品名バイロン200)をトルエン/メチルエチルケトン=1/1の溶液で固形分が25%になるまで希釈して基材樹脂塗工液とした。これを片面にシリコーン系離型処理がされた38μm厚の中剥離PETセパレータ(離型フィルムB)の離型面に塗工し、100℃で2分間乾燥させて厚さ9μmの基材層を形成した。更に片面にシリコーン系離型処理がされた25μm厚の軽剥離PETセパレータ(離型フィルムA)の離型面が合うようにして貼り合わせて基材フィルム(基材2)を得た。
( Reference Example 1 )
A polyester resin (trade name Byron 200, manufactured by Toyobo Co., Ltd.) was diluted with a solution of toluene / methyl ethyl ketone = 1/1 until the solid content became 25% to obtain a base resin coating solution. This was coated on the release surface of a 38 μm thick medium release PET separator (release film B) having a silicone release treatment on one side and dried at 100 ° C. for 2 minutes to form a 9 μm thick base material layer. Formed. Further, the base film (base material 2) was obtained by attaching the light-release PET separator (release film A) having a thickness of 25 μm having a silicone-type release treatment on one side so that the release faces were matched.

次に、強粘着タイプのアクリル系粘着剤(綜研化学株式会社製 商品名SKダイン1604N)を固形分として100重量部、硬化剤(日本ポリウレタン工業株式会社製 商品名コロネートL45)を固形分として2重量部の割合で調合し、トルエンで固形分が25%になるまで希釈して塗工液とした。片面にシリコーン系離型処理がされた50μm厚の重剥離PETセパレータ(離型フィルムC)の離型面に塗工し、100℃で2分間乾燥して、8μmの粘着層を形成し、前工程で作成した基材フィルムの軽剥離PETセパレータ(離型フィルムA)を剥がしながら粘着層と基材樹脂層が合わさるように貼り合わせ、基材(基材2)樹脂の片側に粘着層(第1の粘着層3)が積層された構成のフィルムを得た。   Next, 100 parts by weight of solid adhesive acrylic adhesive (trade name SK Dyne 1604N, manufactured by Soken Chemical Co., Ltd.) as solids and 2 hardener (trade name Coronate L45, manufactured by Nippon Polyurethane Industry Co., Ltd.) as solids The mixture was prepared in a proportion by weight, and diluted with toluene until the solid content became 25% to obtain a coating solution. It is applied to the release surface of a 50 μm thick heavy release PET separator (release film C) with a silicone release treatment on one side and dried at 100 ° C. for 2 minutes to form an 8 μm adhesive layer. While peeling off the lightly peeled PET separator (release film A) of the base film prepared in the process, the adhesive layer and the base resin layer are bonded together so that the base layer (base material 2) has an adhesive layer (first layer) on one side of the resin. A film having a structure in which 1 adhesive layer 3) was laminated was obtained.

更に、同様にアクリル系粘着剤塗工液を、片面にシリコーン系離型処理がされた25μm厚の軽剥離PETセパレータ(離型フィルムD)の離型面に塗工し、100℃で2分間乾燥して8μmの粘着層を形成し、前工程で得られた積層フィルムの中剥離PETセパレータ(離型フィルムB)を剥がしながら粘着層(第2の粘着層4)と基材(基材2)樹脂層が合わさるように貼り合わせ、この状態で常温7日間エージングを行うことにより、軽剥離PETセパレータ(離型フィルムD)と重剥離PETセパレータ(離型フィルムC)により挟まれた構成の両面粘着フィルム1を得た。   Further, similarly, an acrylic pressure-sensitive adhesive coating solution was applied to the release surface of a 25 μm-thick lightly peeled PET separator (release film D) having a silicone release treatment on one side, and the coating was performed at 100 ° C. for 2 minutes. The adhesive layer (second adhesive layer 4) and the base material (base material 2) were formed by drying to form an 8 μm adhesive layer, and peeling off the middle release PET separator (release film B) of the laminated film obtained in the previous step. ) Both sides of the structure sandwiched between the light release PET separator (release film D) and the heavy release PET separator (release film C) by pasting together so that the resin layers are combined and aging at room temperature for 7 days in this state An adhesive film 1 was obtained.

(実施例
ポリエステルポリオール(大日本インキ化学工業株式会社製 商品名バーノックD−161)を固形分として100重量部、ポリイソシアネート(大日本インキ化学工業株式会社製 商品名バーノックDN−950)を固形分として100重量部の割合で調合し、トルエン/メチルエチルケトン=1/1溶液で固形分が40%になるまで希釈して基材樹脂塗工液とした。この塗工液を用いた他は、参考例1と同様な作業を行ない、軽剥離PETセパレータ(離型フィルムD)と重剥離PETセパレータ(離型フィルムC)により挟まれた構成の両面粘着フィルム1を得た。
(Example 1 )
100 parts by weight of polyester polyol (Dainippon Ink Chemical Co., Ltd., trade name Vernock D-161) as solids and 100 parts by weight of polyisocyanate (Dainippon Ink Chemical Co., Ltd., trade name Vernock DN-950) as solids The base resin coating solution was prepared by diluting with a toluene / methyl ethyl ketone = 1/1 solution until the solid content was 40%. Other than using this coating solution, the same operation as in Reference Example 1 was performed, and the double-sided adhesive film was configured to be sandwiched between the light release PET separator (release film D) and the heavy release PET separator (release film C). 1 was obtained.

(実施例
ポリウレタン樹脂(日本ポリウレタン工業株式会社製 商品名ニッポラン5120)をトルエン/酢酸エチル/イソプロピルアルコール=4/2/4溶液で固形分が20%になるまで希釈して基材樹脂塗工液とした。この塗工液を用いた他は、参考例1と同様な作業を行ない、軽剥離PETセパレータ(離型フィルムD)と重剥離PETセパレータ(離型フィルムC)により挟まれた構成の両面粘着フィルム1を得た。
(Example 2 )
A polyurethane resin (trade name NIPPOLAN 5120 manufactured by Nippon Polyurethane Industry Co., Ltd.) was diluted with a toluene / ethyl acetate / isopropyl alcohol = 4/2/4 solution until the solid content became 20% to obtain a base resin coating solution. Other than using this coating solution, the same operation as in Reference Example 1 was performed, and the double-sided adhesive film was configured to be sandwiched between the light release PET separator (release film D) and the heavy release PET separator (release film C). 1 was obtained.

(実施例
リワーク性を有するアクリル系粘着剤として、綜研化学株式会社製 商品名SKダイン2137を固形分として100重量部、コロネートL45を固形分として0.5重量部の割合で調合し、トルエンで固形分が12%になるまで希釈し粘着剤塗工液とした他は、実施例と同様な作業を行ない、軽剥離PETセパレータ(離型フィルムD)と重剥離PETセパレータ(離型フィルムC)により挟まれた構成の両面粘着フィルム1を得た。
(Example 3 )
As an acrylic pressure-sensitive adhesive having reworkability, 100 parts by weight of SK Dyne 2137, manufactured by Soken Chemical Co., Ltd., and 0.5 parts by weight of coronate L45 as solids are prepared. Except for diluting to 12% to obtain an adhesive coating solution, the same operation as in Example 2 was performed, and sandwiched between a light release PET separator (release film D) and a heavy release PET separator (release film C). A double-sided pressure-sensitive adhesive film 1 having the above-described configuration was obtained.

(実施例
基材2片面第1の粘着層3として積層する粘着剤塗工液を、実施例のリワーク性を有するものを用い、基材2反対面第2の粘着層4として積層する粘着剤の塗工液として参考例1の強粘着タイプの物を用いた他は、実施例と同様な作業を行ない、軽剥離PETセパレータ(離型フィルムD)と重剥離PETセパレータ(離型フィルムC)により挟まれた構成の両面粘着フィルム1を得た。この両面粘着フィルム1においては、第1の粘着層3の粘着力と第2の粘着層4の粘着力とが異なり、第1の粘着層3の粘着力が第2の粘着層4の粘着力より小さくなっている。
(Example 4 )
The adhesive coating liquid to be laminated as the first adhesive layer 3 on one side of the base material 2 is the one having the reworkability of Example 3 , and the adhesive coating to be laminated as the second adhesive layer 4 on the opposite side of the base material 2 is applied. Except for using the strong adhesion type of Reference Example 1 as the working fluid, the same operation as in Example 2 was performed, and a lightly peeled PET separator (release film D) and a heavyly peeled PET separator (release film C) were used. A double-sided pressure-sensitive adhesive film 1 having a sandwiched structure was obtained. In this double-sided adhesive film 1, the adhesive force of the first adhesive layer 3 is different from the adhesive force of the second adhesive layer 4, and the adhesive force of the first adhesive layer 3 is the adhesive force of the second adhesive layer 4. It is getting smaller.

(比較例1)
参考例1で用いた粘着剤塗工液を、片面にシリコーン系離型処理がされた50μm厚の重剥離PETセパレータの離型面に塗工し、100℃で3分間乾燥して25μmの粘着層を形成し、25μm厚の軽剥離PETセパレータの離型面が合わさるようにして貼り合わせ、この状態で常温7日間エージングを行うことにより、基材レスの両面粘着フィルムを得た。
(Comparative Example 1)
The pressure-sensitive adhesive coating solution used in Reference Example 1 was applied to the release surface of a 50 μm-thick heavy release PET separator having a silicone release treatment on one side, dried at 100 ° C. for 3 minutes, and a 25 μm pressure-sensitive adhesive. A layer was formed and bonded so that the release surfaces of the 25 μm-thick lightly peeled PET separator were combined, and aging was performed for 7 days at room temperature in this state to obtain a substrateless double-sided adhesive film.

(比較例2)
参考例1で用いた粘着剤塗工液を、片面にシリコーン系離型処理がされた50μm厚の重剥離PETセパレータの離型面に塗工し、100℃で2分間乾燥して8μmの粘着層を形成し、芯基材として9μm厚のPET(東洋紡績株式会社製 商品名T4000)を貼り合わせた。更に、25μm厚の軽剥離PETセパレータの離型面に同じ粘着剤塗工液を塗工、100℃で2分間乾燥して8μmの粘着層を形成し、前工程で得られた積層フィルムの芯基材PET面に合わさるように貼り合わせ、この状態で常温7日間エージングを行うことにより、PETを芯基材とする両面粘着フィルムを得た。
(Comparative Example 2)
The pressure-sensitive adhesive coating solution used in Reference Example 1 was applied to the release surface of a 50 μm-thick heavy release PET separator having a silicone release treatment on one side, dried at 100 ° C. for 2 minutes, and 8 μm pressure-sensitive adhesive. A layer was formed, and 9 μm-thick PET (trade name T4000 manufactured by Toyobo Co., Ltd.) was bonded as a core substrate. Furthermore, the same adhesive coating liquid was applied to the release surface of a 25 μm-thick lightly peeled PET separator, dried at 100 ° C. for 2 minutes to form an 8 μm adhesive layer, and the core of the laminated film obtained in the previous step A double-sided pressure-sensitive adhesive film having PET as a core substrate was obtained by pasting together so as to match the PET surface of the substrate and performing aging at room temperature for 7 days in this state.

(比較例3)
実施例で用いたリワーク性を有する粘着剤塗工液を、片面にシリコーン系離型処理がされた50μm厚の重剥離PETセパレータの離型面に塗工し、100℃で3分間乾燥して25μmの粘着層を形成し、25μm厚の軽剥離PETセパレータの離型面が合わさるようにして貼り合わせ、この状態で常温7日間エージングを行うことにより、リワーク性を有する基材レスの両面粘着フィルムを得た。
(Comparative Example 3)
The pressure-sensitive adhesive coating liquid having reworkability used in Example 3 was applied to the release surface of a 50 μm-thick heavy release PET separator having a silicone release treatment on one side and dried at 100 ° C. for 3 minutes. A 25 μm thick adhesive layer is formed and bonded so that the release surfaces of 25 μm thick lightly peeled PET separators are combined, and in this state, aging is carried out at room temperature for 7 days, whereby a substrateless double-sided adhesive having reworkability A film was obtained.

(比較例4)
実施例で用いた粘着剤塗工液を用いる他は比較例2と同様な作業を行い、PETを芯基材としたリワーク性を有する両面粘着フィルムを得た。
(Comparative Example 4)
Except for using the pressure-sensitive adhesive coating solution used in Example 3 , the same operation as in Comparative Example 2 was performed to obtain a double-sided pressure-sensitive adhesive film having reworkability using PET as a core substrate.

得られた粘着フィルムについて、以下に示す評価を行った。得られた結果を図5に示し
た。
1、粘着層の内部HAZEの測定
参考例1、実施例1〜3、比較例1〜4の各粘着フィルムの両側の離型フィルムを剥
がし、代わりに70μmの厚みのポリカーボネートフィルム(ピュアエース:帝人株式会
社製)でサンドイッチした構成のフィルムを作り粘着層光学測定用のサンプルとした。こ
こでピュアエースに起因するHAZEは無視できるほど小さいとした。
このサンプルをヘイズメーターNDH2000(日本電色工業株式会社製)を用いてHA
ZE測定した。

2、配向の評価
上記光学測定用のサンプルを2枚の偏光板の間にはさみ回転させることで偏光の乱れ
を目視観察し、粘着フィルムの配向の有無を確認した。偏光の乱れがなかったものは○、
偏光の乱れが生じたものは×とした。

3、フィルム強度の測定
JIS K7127に従い引っ張り試験機で両面粘着フィルムの引張強さを測定した
。測定は両側のPETセパレータを剥がした状態で行った。

4、粘着剤による汚染の測定
両面粘着フィルムをカッターで断裁し、PETフィルムに90°の角度で両面粘着フ
ィルムの断裁面をこすりつけ、PETフィルムに付着した粘着剤の程度を目視で判断した

ほとんど付着せず・・○ かなりの量の粘着剤の付着が見られる・・×

5、リワーク性の評価
(その1)
両面粘着フィルムの第2の粘着層4側を100μm厚のPETフィルムに貼りあわせ
25mm巾の短冊になるように断裁した。次に、第1の粘着層3側をガラス板に貼り合わ
せ、23℃で1日保持した後に、粘着力を剥離速度300mm/分、180°剥離にて測
定した。ガラス板から剥がした後に、更に、PET基材から両面粘着フィルムを剥がすこ
とを試みた。
ガラス板から剥がす際の粘着力が5N/25mm以上のものは×、5N/25mm以
下で且つPETフィルムから粘着剤を剥がすことが出来たものは○、5N/25mm以下
でPETフィルムから粘着剤を剥がせなかったものに関しては△とした。
(その2)
両面粘着フィルムの第2の粘着層4側を100μm厚のPETフィルムに貼りあわせ2
5mm巾の短冊になるように断裁した。次に第1の粘着層3側をアクリル板に貼り合わせ
、23℃で1日保持した後に、粘着力を剥離速度300mm/分、180°剥離にて測定
した。さらに剥がした後のアクリル板表面に粘着剤が残っていないか目視確認した。
アクリル板から剥がす際の粘着力が5N/25mm以上のもの、アクリル板に粘着剤が
残ったものは×、粘着力が5N/25mm以下でアクリル板に粘着剤が残らなかったもの
は○とした。
About the obtained adhesive film, evaluation shown below was performed. The obtained results are shown in FIG.
1. Measurement of internal HAZE of adhesive layer Peel off the release films on both sides of each adhesive film of Reference Example 1, Examples 1 to 3 and Comparative Examples 1 to 4, and instead of a polycarbonate film of 70 μm thickness (Pure Ace: Teijin) A film having a sandwich structure was manufactured as a sample for optical measurement of the adhesive layer. Here, HAZE caused by Pure Ace is assumed to be negligibly small.
This sample was subjected to HA using a haze meter NDH2000 (Nippon Denshoku Industries Co., Ltd.).
ZE measurement was performed.

2. Evaluation of Orientation The sample for optical measurement was sandwiched between two polarizing plates and rotated to visually observe the disorder of polarization, and the presence or absence of the orientation of the adhesive film was confirmed. ○, where there was no polarization disturbance
The case where the polarization was disturbed was rated as x .

3. Measurement of film strength According to JIS K7127, the tensile strength of the double-sided adhesive film was measured with a tensile tester. The measurement was performed with the PET separators on both sides removed.

4. Measurement of contamination with adhesive The double-sided adhesive film was cut with a cutter, the cut surface of the double-sided adhesive film was rubbed against the PET film at an angle of 90 °, and the degree of the adhesive attached to the PET film was judged visually.
Almost no adhesion ・ ○ Adhesion of a considerable amount of adhesive is seen ・×

5. Evaluation of reworkability (part 1)
The second pressure-sensitive adhesive layer 4 side of the double-sided pressure-sensitive adhesive film was bonded to a 100 μm thick PET film and cut into a 25 mm wide strip. Next, after sticking the 1st adhesion layer 3 side to the glass plate and hold | maintaining at 23 degreeC for 1 day, the adhesive force was measured by peeling rate 300mm / min and 180 degree peeling. After peeling from the glass plate, an attempt was made to peel the double-sided adhesive film from the PET substrate.
Those having an adhesive strength of 5 N / 25 mm or more when peeled from the glass plate are x 5 N / 25 mm or less, and those that were able to peel the adhesive from the PET film are ○ 5 N / 25 mm or less, and the adhesive is removed from the PET film. For those that could not be peeled, △ was given.
(Part 2)
Adhering the second adhesive layer 4 side of the double-sided adhesive film to a 100 μm thick PET film 2
Trimmed to a strip with a width of 5 mm. Next, after sticking the 1st adhesion layer 3 side to an acrylic board and hold | maintaining at 23 degreeC for 1 day, the adhesive force was measured by the peeling rate of 300 mm / min and 180 degree peeling. Furthermore, it was visually confirmed whether the pressure-sensitive adhesive remained on the acrylic plate surface after peeling.
When the adhesive strength is 5N / 25mm or more when peeled off from the acrylic plate, when the adhesive remains on the acrylic plate, x, when the adhesive strength is 5N / 25mm or less and no adhesive remains on the acrylic plate, the result is ○. .

図1は、本発明の一実施例の両面粘着フィルムの概略的断面図である。FIG. 1 is a schematic cross-sectional view of a double-sided pressure-sensitive adhesive film according to an embodiment of the present invention. 図2は、図1の両面粘着フィルムの製造方法の第1の工程の概略的図である。FIG. 2 is a schematic view of a first step of the method for producing the double-sided pressure-sensitive adhesive film of FIG. 図3(a)(b)は、図1の両面粘着フィルムの製造方法の第2の工程の概略的図である。3A and 3B are schematic views of a second step of the method for producing the double-sided pressure-sensitive adhesive film of FIG. 図4(a)(b)は、図1の両面粘着フィルムの製造方法の第3の工程の概略的図である。4 (a) and 4 (b) are schematic views of a third step of the method for producing the double-sided pressure-sensitive adhesive film of FIG. 図5は、参考例1、実施例1〜、比較例1〜4の粘着フィルムについての評価を示したものである。FIG. 5 shows the evaluation of the pressure-sensitive adhesive films of Reference Example 1, Examples 1 to 3 and Comparative Examples 1 to 4.

符号の説明Explanation of symbols

1 両面粘着フィルム
2 基材
3 第1の粘着層
4 第2の粘着層
DESCRIPTION OF SYMBOLS 1 Double-sided adhesive film 2 Base material 3 1st adhesion layer 4 2nd adhesion layer

Claims (4)

光学的に無配向でかつ透明なポリウレタン系樹脂からなる基材と、この基材の一方の
面に設けられた透明な第1の粘着層と、前記基材の他方の面に設けられた透明な第2の粘
着層とを有し、積層された3層の厚みが55μm以下で、かつ、前記基材の厚みが3μm
〜20μmであり、内部HAZEが1%以下である
ことを特徴とする両面粘着フィルム。
A base material made of optically non-oriented and transparent polyurethane resin, a transparent first adhesive layer provided on one surface of the base material, and a transparent material provided on the other surface of the base material And the thickness of the laminated three layers is 55 μm or less, and the thickness of the substrate is 3 μm.
A double-sided pressure-sensitive adhesive film having a thickness of ˜20 μm and an internal HAZE of 1% or less.
第1の粘着層は、アクリル系粘着剤で形成され、前記第1の粘着層側をアクリル板に
貼り合わせ、23℃で1日保持した後に、剥離速度300mm/分、180°剥離での粘
着力が5N/25mm以下で、かつ、剥離の際に前記アクリル板に前記アクリル系粘着剤
が残らない
ことを特徴とする請求項1記載の両面粘着フィルム。
The first pressure-sensitive adhesive layer is formed of an acrylic pressure-sensitive adhesive, and the first pressure-sensitive adhesive layer side is bonded to an acrylic plate and held at 23 ° C. for 1 day, and then peeled at 300 mm / min and pressure-sensitive at 180 ° peeling. 2. The double-sided pressure-sensitive adhesive film according to claim 1, wherein the force is 5 N / 25 mm or less, and the acrylic pressure-sensitive adhesive does not remain on the acrylic plate upon peeling.
第1の粘着層及び第2の粘着層がアクリル系で、JIS K7127による引張強さが5MPa以上である
ことを特徴とする請求項1または2記載の両面粘着フィルム。
The double-sided pressure-sensitive adhesive film according to claim 1 or 2, wherein the first pressure-sensitive adhesive layer and the second pressure-sensitive adhesive layer are acrylic and have a tensile strength of 5 MPa or more according to JIS K7127.
第1の粘着層と第2の粘着層とが異なる
ことを特徴とする請求項1または2記載の両面粘着フィルム。
The double-sided pressure-sensitive adhesive film according to claim 1 or 2, wherein the first pressure-sensitive adhesive layer and the second pressure-sensitive adhesive layer are different.
JP2005312125A 2005-10-27 2005-10-27 Double-sided adhesive film Expired - Lifetime JP4837360B2 (en)

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JP5845591B2 (en) * 2010-02-17 2016-01-20 Dic株式会社 Double-sided adhesive tape for bonding rigid bodies
JP5662866B2 (en) * 2011-03-31 2015-02-04 積水化学工業株式会社 Adhesive sheet
JP2013155313A (en) * 2012-01-31 2013-08-15 Mitsubishi Plastics Inc Adhesive sheet for optical base material
JP6168106B2 (en) * 2015-06-13 2017-07-26 三菱ケミカル株式会社 Laminated film
JP6350623B2 (en) * 2016-09-26 2018-07-04 三菱ケミカル株式会社 Laminated film
JP6296129B2 (en) * 2016-09-26 2018-03-20 三菱ケミカル株式会社 Method for producing laminated film
JP6510736B1 (en) * 2017-08-02 2019-05-08 バンドー化学株式会社 Optically transparent pressure-sensitive adhesive sheet, laminate, and bonded structure
JP6592070B2 (en) * 2017-12-20 2019-10-16 日東電工株式会社 Adhesive sheet, electronic device member laminate, and optical member laminate
JP2020125431A (en) * 2019-02-06 2020-08-20 バンドー化学株式会社 Optically transparent adhesive sheet, laminated sheet and laminated structure
JP7141346B2 (en) * 2019-02-06 2022-09-22 バンドー化学株式会社 laminated structure
JP7203624B2 (en) * 2019-02-06 2023-01-13 バンドー化学株式会社 Optically transparent adhesive sheet, laminate sheet and laminated structure
WO2020162439A1 (en) * 2019-02-06 2020-08-13 バンドー化学株式会社 Optical transparent adhesive sheet, laminate sheet, and adhered structure
JP2022156962A (en) * 2021-03-31 2022-10-14 リンテック株式会社 Adhesive sheets and laminates
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