JP4843527B2 - Hair composition - Google Patents

Description

  The present invention relates to a hair composition in which aggregation of powdery silicone is prevented by using powdered silicone and a specific cationic surfactant in combination.

In general, a composition in which powdered silicone is blended with a hair composition such as a shampoo or a hair conditioner is known. Powdered silicone is blended to provide wet hair with a good combing and conditioning effect after drying. Conventionally, the composition for hair disclosed by patent document 1 is known. Such a composition for hair contains a silicone elastomer powder as a powdery silicone and is blended with α-hydroxycarboxylic acid in order to impart a conditioning effect.
JP-A-10-203932

  However, the conventional hair cosmetic disclosed in Patent Document 1 has a problem that the powdery silicone compounded for imparting a conditioning effect or the like tends to aggregate during preparation or storage of the composition and is difficult to handle. It was. Therefore, it has not been easy to apply to hair cosmetics mainly used as a liquid or creamy agent.

  The present invention is based on the finding that as a result of diligent research by the present inventors, agglomeration of powdered silicone can be suppressed by using a specific cationic surfactant in combination with powdered silicone. is there.

  An object of the present invention is to provide a hair composition capable of suppressing aggregation of powdered silicone in a hair composition containing powdered silicone.

In order to achieve the above object, the hair composition according to claim 1 comprises the following components (A) and (B):
(A): Powdered silicone.
(B): An imidazoline type quaternary ammonium salt represented by the following general formula (1).

（式中、Ｒは炭素数１１〜２３のアルキル基又はアルケニル基を示し、Ｘはハロゲン原子、メチルサルフェート残基又はエチルサルフェート残基を示す。）
請求項２記載の発明は、請求項１記載の毛髪用組成物において、さらに（Ｃ）２５℃で液状のシリコーン類を配合することを特徴とする。

(In the formula, R represents an alkyl group or alkenyl group having 11 to 23 carbon atoms, and X represents a halogen atom, a methyl sulfate residue or an ethyl sulfate residue.)
The invention described in claim 2 is characterized in that, in the composition for hair according to claim 1, (C) a liquid silicone at 25 ° C. is further blended.

  The invention described in claim 3 is the hair composition according to claim 1 or 2, wherein the (A) powdery silicone is at least one selected from silicone resins, silicone elastomers, and composites thereof. It is characterized by that.

  The invention according to claim 4 is characterized in that in the hair composition according to any one of claims 1 to 3, (D) water is further blended.

  ADVANTAGE OF THE INVENTION According to this invention, in the composition for hair which mix | blends powdered silicone, the composition for hair which can suppress aggregation of powdered silicone can be provided.

Hereinafter, the embodiment which actualized the composition for hair of this invention as a hair treatment agent is described in detail.
The hair treatment agent as the hair composition of the present embodiment comprises an active ingredient (A) as a powdery silicone, and (B) as an imidazoline type quaternary ammonium salt represented by the following general formula (1). Contained. Furthermore, as other components, silicones which are liquid at 25 ° C. are preferably contained as component (C). The active ingredient consisting of the components (A) to (C) is the other component (D) dissolved or dispersed in water and in a liquid state such as an aqueous solution, dispersion or emulsion, gel, foam, or cream. Applied to hair.

（式中、Ｒは炭素数１１〜２３のアルキル基又はアルケニル基を示し、Ｘはハロゲン原子、メチルサルフェート残基又はエチルサルフェート残基を示す。）
本実施形態において（Ａ）粉末状シリコーンは、ぬれた髪にくし通りの良さや仕上がりの滑らかさ等のコンディショニング効果を付与するために配合される。（Ａ）粉末状シリコーンとして用いられるシリコーンとしては、水不溶性のシリコーン樹脂粉末、シリコーンエラストマー粉末、及びそれらの複合体が挙げられる。

(In the formula, R represents an alkyl group or alkenyl group having 11 to 23 carbon atoms, and X represents a halogen atom, a methyl sulfate residue or an ethyl sulfate residue.)
In this embodiment, (A) the powdery silicone is blended in order to impart conditioning effects such as combing quality and smooth finish to wet hair. (A) Examples of the silicone used as the powdery silicone include water-insoluble silicone resin powder, silicone elastomer powder, and composites thereof.

Examples of the silicone resin powder include fine powder of polymethylsilsesquioxane having a structure in which a siloxane bond is crosslinked in a three-dimensional network represented by (CH ₃ SiO _3/2 ) _n .
Examples of the silicone elastomer powder include fine powder of silicone rubber having a structure in which linear dimethicone (dimethylpolysiloxane) is crosslinked. Crosslinked dimethicone (dimethicone / vinyl dimethicone) crosspolymer, (dimethicone / vinyl dimethicone / methicone) crosspolymer, (dimethicone / phenyldimethicone) crosspolymer, (dimethicone / phenylvinyldimethicone / methicone) crosspolymer, (dimethicone / ( PEG-10 / 15)) crosspolymer and the like. These silicone powders may be blended singly or in combination of two or more. Among these, (dimethicone / vinyl dimethicone) crosspolymer and polymethylsilsesquioxane are preferable from the viewpoint of the conditioning effect and ease of washing.

  Moreover, you may use the composite_body | complex of 1 or 2 types or more of the powdery silicone illustrated above and water-insoluble particles. Examples of water-insoluble particles include inorganic particles such as silicon dioxide, and polymer particles such as polyethylene, polypropylene, polystyrene, polyamide, and polyester copolymers. Moreover, the silicone composite particle which coat | covered the surface of the spherical silicone rubber particle with the silicone resin can also be used.

  (A) Although the average particle diameter of powdery silicone is not specifically limited, 0.01-100 micrometers is preferable and it is more preferable that it is 0.1-30 micrometers. The particle shape may be any of spherical, elliptical, spindle shape, etc., but it is particularly preferable that it is spherical.

  (A) It is preferable to mix | blend 0.01-10 mass% of powdery silicone in a composition for hair, and 0.05-5 mass% is more preferable. When the amount is less than 0.01% by mass, the conditioning effect cannot be sufficiently obtained. On the other hand, when the amount exceeds 10% by mass, there is a risk of causing problems such as whitening of the powdered silicone remaining in excess after hair is treated.

  The imidazoline type quaternary ammonium salt as the component (B) is a kind of cationic surfactant, and is blended in order to prevent aggregation of the powdered silicone in the hair composition. As this (B) imidazoline type quaternary ammonium salt, for example, di-behenyl imidazolinium methosulfate is preferably used. In addition, International Nomenclature Cosmetic Ingredient name (INCI name) of the dibehenyl imidazolinium methosulphate is quaternium-91, R in the general formula (1) is an alkyl group having 21 carbon atoms, and X is methyl sulphate. It is a compound represented by the following formula (2) which is a residue.

このジベヘニルイミダゾリニウムメトサルフェートの市販品としては、例えばクローダ社のクロダゾソフト（商品名）ＤＢＱが挙げられる。この他のイミダゾリン型第四級アンモニウム塩としては、例えば一般式（１）のＲが炭素数１１、１５、１７又は１９であるとともにＸが塩素原子である化合物、及びＲが炭素数１５であるとともにＸがメチルサルフェート残基である化合物等が挙げられる。これらのイミダゾリン型第四級アンモニウム塩は、単独で配合してもよいし、複数種を組み合わせて配合してもよい。

As a commercial product of this dibehenyl imidazolinium methosulfate, for example, Kurodazosoft (trade name) DBQ manufactured by Croda is mentioned. Other examples of the imidazoline type quaternary ammonium salt include compounds in which R in the general formula (1) has 11, 15, 17 or 19 carbon atoms and X is a chlorine atom, and R has 15 carbon atoms. In addition, compounds in which X is a methyl sulfate residue can be mentioned. These imidazoline type quaternary ammonium salts may be blended singly or in combination.

  (B) The compounding quantity of an imidazoline type | mold quaternary ammonium salt becomes like this. Preferably it is 0.05-3 mass% in a composition for hair, More preferably, it is 0.1-2 mass%. When this blending amount is less than 0.05% by mass, it becomes difficult to obtain the effect of preventing aggregation of the powdery silicone (A). In addition, it is difficult to obtain the effect of improving the feeling after finishing. On the other hand, if it exceeds 3% by mass, irritation to the scalp may be felt, which may cause discomfort.

Silicone that is liquid at 25 ° C. as component (C) is blended in order to further improve the effect of suppressing aggregation of (A) powdered silicone by component (B). As the component (C), silicone oil is preferably used, and specific examples include octamethyltrisiloxane, decamethyltetrasiloxane, decamethylcyclopentasiloxane and the like. In addition, methylpolysiloxane represented by the following general formula (3), methylphenylpolysiloxane represented by the following general formula (4) or general formula (5), cyclic silicone represented by the following general formula (6), and terminal hydroxyl group Examples include modified dimethylpolysiloxane. In the following general formula (3), n represents an integer of 3 to 650. Moreover, in following General formula (4) and General formula (5), n shows the integer of 1-410 and it is n = a + b. In General formula (6), n shows the integer of 3-7. The molecular weight of each silicone is preferably less than 150,000, and the viscosity is preferably in the range of 0.5 to 500,000 mm ² / s. The terminal hydroxyl group-modified dimethylpolysiloxane is a dimethylpolysiloxane having a hydroxyl group bonded to the terminal and having an INCI name of Dimethiconol described in ICID.

毛髪用組成物中の（Ｃ）成分の含有量は、好ましくは０．１〜３０質量％、より好ましくは０．５〜２０質量％、最も好ましくは１〜１５質量％である。０．１質量％未満では、（Ａ）粉末状シリコーンの凝集抑制効果を十分に向上させることができない。一方、３０質量％を超えると、仕上がり後の感触の低下を招くおそれがある。

The content of the component (C) in the hair composition is preferably 0.1 to 30% by mass, more preferably 0.5 to 20% by mass, and most preferably 1 to 15% by mass. If it is less than 0.1% by mass, the aggregation suppressing effect of the powdered silicone (A) cannot be sufficiently improved. On the other hand, when it exceeds 30 mass%, there is a possibility that the feeling after finishing may be lowered.

  (D) Water is contained as a solvent or dispersion medium of the active ingredients (A) to (C). (D) Content in the composition for hair of hair becomes like this. Preferably it is 40-95 mass%, More preferably, it is 50-90 mass%. (D) If the water content is less than 40% by mass, it may be difficult to stably form an aqueous solution, a dispersion or an emulsion. On the other hand, when the water content exceeds 95% by mass, it may be difficult to ensure the uniformity and stability of the hair composition.

In the hair treatment agent as the hair composition of the present embodiment, an oil component, a polyhydric alcohol, a surfactant and the like can be blended as other components.
The oil component is preferably blended from the viewpoint of imparting moisture to the hair. Examples of the oil component include fats and oils, waxes, higher alcohols, higher fatty acids, alkyl glyceryl ethers, esters, silicones other than the above, hydrocarbons, and the like.

  Oils include olive oil, rosehip oil, camellia oil, shea fat, macadamia nut oil, almond oil, tea seed oil, sasanqua oil, safflower oil, sunflower oil, soybean oil, cottonseed oil, sesame oil, beef fat, cocoa butter, corn oil , Peanut oil, rapeseed oil, rice bran oil, rice germ oil, wheat germ oil, pearl barley oil, grape seed oil, avocado oil, carrot oil, macadamia nut oil, castor oil, linseed oil, palm oil, mink oil, egg yolk oil, etc. Is mentioned. Examples of waxes include beeswax, candelilla wax, carnauba wax, jojoba oil, and lanolin.

  Higher alcohols include lauryl alcohol, myristyl alcohol, cetyl alcohol (cetanol), stearyl alcohol, cetostearyl alcohol, aralkyl alcohol, behenyl alcohol, 2-hexyldecanol, isostearyl alcohol, 2-octyldodecanol, decyltetradecanol, oleyl Alcohol, linoleyl alcohol, linolenyl alcohol, lanolin alcohol, etc. are mentioned. Examples of higher fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, isostearic acid, hydroxystearic acid, 12-hydroxystearic acid, oleic acid, undecylenic acid, linoleic acid, ricinoleic acid, and lanolin fatty acid. It is done.

  Examples of the alkyl glyceryl ether include batyl alcohol (monostearyl glyceryl ether), chimyl alcohol (monocetyl glyceryl ether), selachyl alcohol (monooleyl glyceryl ether), and isostearyl glyceryl ether.

  Esters include diisopropyl adipate, diisobutyl adipate, dioctyl adipate, dioctyl succinate, 2-hexyldecyl adipate, diisostearyl adipate, isopropyl myristate, cetyl octanoate, cetyl isooctanoate, isonononyl isononanoate , Isodecyl isononanoate, Isotridecyl isononanoate, Diisopropyl sebacate, Octyldodecyl myristate, Isopropyl palmitate, Butyl stearate, Stearyl stearate, Hexyl laurate, Myristyl myristate, Decyl oleate, Hexyldecyl dimethyloctanoate, Myristic acid Triisodecyl, isostearyl myristate, 2-ethylhexyl palmitate, octyldodecyl ricinoleate, fatty acid (C1 -30) (cholesteryl / lanosteryl), lauryl lactate, cetyl lactate, myristyl lactate, octyldodecyl lactate, lanolin acetate, isocetyl stearate, isocetyl isostearate, cholesteryl 12-hydroxystearate, ethylene glycol di-2-ethylhexanoate, Examples include dipentaerythritol fatty acid ester, N-alkyl glycol monoisostearate, cetyl caprate, glyceryl tricaprylate, neopentyl glycol dicaprate, diisostearyl malate, and lanolin derivatives.

  Examples of silicones include dimethylpolysiloxane other than the above components (A) and (C), methylphenylpolysiloxane, terminal hydroxyl group-modified dimethylpolysiloxane, fatty acid-modified polysiloxane, amino-modified silicone, alcohol-modified silicone, glycerin-modified silicone, Examples include aliphatic alcohol-modified polysiloxane, epoxy-modified silicone, fluorine-modified silicone, and alkyl-modified silicone.

  Examples of the hydrocarbon include α-olefin oligomer, light isoparaffin, light liquid isoparaffin, liquid isoparaffin, liquid paraffin, squalane, polybutene, paraffin, polyethylene powder, microcrystalline wax, petrolatum and the like. These oil components may be blended alone or in combination of two or more.

  Examples of the polyhydric alcohol include glycols and glycerins. Examples of glycols include ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, dipropylene glycol, isoprene glycol, and 1,3-butylene glycol. Examples of glycerins include glycerin, diglycerin, and polyglycerin.

  The surfactant is blended as an emulsifier or solubilizer to maintain the stability of the hair composition. Examples of the surfactant include nonionic surfactants, cationic surfactants other than those described above, anionic surfactants, and amphoteric surfactants.

  Specific examples of the nonionic surfactant include ether type nonionic surfactants and ester type nonionic surfactants. Specific examples of the ether type nonionic surfactant include polyoxyethylene (hereinafter referred to as POE) cetyl ether, POE stearyl ether, POE behenyl ether, POE oleyl ether, POE lauryl ether, POE octyldodecyl ether, POE hexyl. Examples include decyl ether, POE isostearyl ether, POE nonyl phenyl ether, POE octyl phenyl ether, and the like.

  Specific examples of the ester type nonionic surfactant include POE sorbitan monooleate, POE sorbitan monostearate, POE sorbitan monopalmitate, POE sorbitan monolaurate, POE sorbitan trioleate, POE glycerin monostearate, monoester Myristic acid POE glycerin, tetraoleic acid POE sorbite, hexastearic acid POE sorbit, monolauric acid POE sorbit, POE sorbit beeswax, monooleic acid polyethylene glycol, monostearic acid polyethylene glycol, monolauric acid polyethylene glycol, lipophilic monooleic acid glycerin , Lipophilic glyceryl monostearate, self-emulsifying glyceryl monostearate, sorbitan monooleate, sesquiolei Sorbitan acid, sorbitan trioleate, sorbitan monostearate, sorbitan monopalmitate, sorbitan monolaurate, sucrose fatty acid ester, decaglyceryl monolaurate, decaglyceryl monostearate, decaglyceryl monooleate, decaglyceryl monomyristate, etc. Is mentioned.

  Cationic surfactants include lauryl trimethyl ammonium chloride, cetyl trimethyl ammonium chloride, stearyl trimethyl ammonium chloride, alkyl trimethyl ammonium chloride, distearyl dimethyl ammonium chloride, cetyl trimethyl ammonium bromide, stearyl trimethyl ammonium bromide, ethyl lanolin sulfate fatty acid Examples thereof include aminopropylethyldimethylammonium, stearyltrimethylammonium saccharin, cetyltrimethylammonium saccharin, and methyl behenyltrimethylammonium sulfate.

  Examples of anionic surfactants include alkyl sulfate salts such as sodium lauryl sulfate and triethanolamine lauryl sulfate, alkyl ether sulfate salts such as sodium POE lauryl ether sulfate, sodium stearoylmethyl taurate, triethanolamine dodecylbenzenesulfonate, Examples include sodium tetradecene sulfonate, POE lauryl ether phosphate and salts thereof, N-lauroyl glutamates, and N-lauroylmethyl-β-alanine salts.

  Examples of amphoteric surfactants include 2-undecyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine sodium, cocoamidopropyl betaine, lauryldimethylaminoacetic acid betaine.

  Furthermore, saccharides such as sorbitol and maltose, gum arabic, karaya gum, tragacanth gum, sodium alginate, xanthan gum, cellulose derivatives, cross-linked polyacrylic acid, polydimethylmethylenepiperidinium chloride, paraben, etc. Preservatives, chelating agents such as EDTA-2Na, phenacetin, 8-hydroxyquinoline, acetanilide, sodium pyrophosphate, barbituric acid, uric acid, tannic acid and other stabilizers, 2-amino-2-methyl-1-propanol, Examples include pH adjusters such as triethanolamine, sodium phosphate, sodium lactate, sodium acetate, and potassium glycolate, plant extracts, herbal extracts, vitamins, protein hydrolysates, fragrances, and UV absorbers. Moreover, you may mix | blend at least 1 type chosen from what is listed in "quasi-drug material standard" (June 1991 issue, Yakuji Nippo).

  The hair treatment agent of this embodiment can be manufactured by mixing each active ingredient according to a normal method. After being applied to the hair, it may be used by rinsing with water or warm water or leaving it without rinsing. Moreover, you may apply to the hair after shampoo, rinse, a hair dye, a decoloring agent, a permanent wave agent etc. are applied.

According to the hair treatment agent as the hair composition of the present embodiment, the following effects can be obtained.
(1) In the hair treatment agent of this embodiment, (A) powdery silicone and the above-mentioned (B) imidazoline type quaternary ammonium salt were used in combination. Therefore, the cohesiveness of the powdery silicone can be suppressed, and the handleability of the composition can be improved. In particular, since the cohesiveness of the powdery silicone can be suppressed even during storage, the dispersibility in the solvent can be improved even when the composition is prepared using (D) water, and the liquid composition can be easily prepared. Can be formulated into products.

  (2) Moreover, handling effects, such as applicability | paintability and rinse property, can be improved by combined use of (A) and (B) component. In addition, conditioning effects such as smoothness after finishing can be further improved.

  (3) In the hair treatment agent of this embodiment, (A) powdery silicone was used. Therefore, as compared with the case where other synthetic resin powders (nylon, polyethylene, etc.) are blended, conditioning effects such as smoothness after finishing are excellent and rinsing properties are excellent.

  (4) In the hair treatment agent of the present embodiment, (C) which is another component was blended with a liquid silicone at 25 ° C. Accordingly, (A) the aggregation suppression effect of the powdery silicone can be further improved.

In addition, you may change the said embodiment as follows.
-The composition for hair of the said embodiment can be filled and used for a well-known various container in forms, such as liquid form, gel form, foam form, and cream form. When the dosage form is mist, it is preferably filled in a hand pump spray container.

  -In the said embodiment, the composition for hair was applied as a hair treatment agent. However, the use is not limited, and it may be applied to hair conditioning agents such as rinses, hair washing compositions such as shampoos, hair packs and the like.

  -In the said embodiment, the solid composition formed by mix | blending said (A)-(C) component can be used as a raw material of liquid compositions, such as a hair treatment agent as a composition for hair.

Next, the embodiment will be described more specifically with reference to examples and comparative examples.
Hair treatment agents as hair compositions were prepared by blending the components shown in Tables 1 and 2, respectively. The unit of the numerical value which shows the compounding quantity of each component in a table | surface is the mass%. In addition, quaternium-91 in the table represents dibehenylimidazolinium methosulfate represented by the general formula (2). The hair treatment agent of each example was uniformly applied to a wet hair bundle and left for 3 minutes. The hair bundle was rinsed with warm water and then dried with a dryer to prepare a hair bundle treated with a hair treatment agent. The following evaluation was performed about the hair treatment agent of each case. The evaluation results are shown in Tables 1 and 2.

<Less agglomeration of powder during preparation>
Each component of each example was emulsified for 1 minute under the conditions of a homogenizer 3000 rpm, a paddle mixer 45 rpm, and 80 ° C. using a desktop homogenizer (TK Aji homomixer 2M-03, manufactured by Tokushu Kika Kogyo Co., Ltd.) Each composition was cooled and evaluated visually. ◎: Aggregation component is not recognized at all and formulation is easy, ○: Aggregation component is slightly observed but does not affect formulation, △: Aggregation affecting formulation is recognized to some extent, × : It was set as the evaluation result that many aggregation components were recognized.

<Good elongation during application>
When an appropriate amount of each hair treatment agent was taken in the palm of the hand and applied to the hair with a hand comb, the ease of application was evaluated. ◎: Can be easily applied with a hand comb, ◯: Can be applied with a hand comb, △: Poor elongation and difficult to apply with a hand comb, ×: Poor elongation and cannot be applied with a hand comb.

<Ease of rinsing>
Each hair treatment agent shown in Tables 1 and 2 is applied to the hair. After 20 minutes, wash away. The ease of washing of each hair treatment agent was evaluated according to the following criteria. A: Easily rinsed in a short time; O: Easily washed; Δ: Slightly time required for cleaning; X: Long time required for cleaning;

<Smoothness after finishing>
The hair bundles before treatment with each hair treatment agent and the hair bundles treated with each hair treatment agent were compared in terms of the touch of the panelist's finger through the hair bundle, and evaluated according to the following criteria. A: The improvement of smoothness is remarkable, B: The improvement of smoothness is recognized, Δ: The improvement of smoothness is slightly recognized, and X: The improvement of smoothness is not recognized.

表１の実施例１〜７に示されるように、（Ａ）粉末状シリコーンと（Ｂ）クオタニウム−９１を併用する場合には調製時の粒子の凝集を抑制することができることが示される。また、仕上がり後の滑らかさ等のコンディショニング効果が向上するとともに塗布性及びすすぎ性等のハンドリング性が向上することが確認される。特に実施例１〜３，５〜７の（Ｃ）シリコーン類をさらに併用する場合には粒子の凝集抑制効果をさらに向上させることができる。

As shown in Examples 1 to 7 in Table 1, when (A) powdery silicone and (B) quaternium-91 are used in combination, aggregation of particles during preparation can be suppressed. It is also confirmed that conditioning effects such as smoothness after finishing are improved and handling properties such as coating properties and rinsing properties are improved. In particular, when (C) silicones of Examples 1 to 3 and 5 to 7 are further used in combination, the effect of suppressing aggregation of particles can be further improved.

  On the other hand, as shown in Comparative Examples 7 to 13 in Table 2, when only a cationic surfactant other than the component (B) is used in combination, it is confirmed that aggregation of the powdery silicone cannot be suppressed. Moreover, it is shown that the smoothness after finishing is also lower than in each example. Further, as shown in Comparative Examples 1 to 3, when (A) nylon powder or the like is used in combination with (B) quaternium-91 instead of powdered silicone, the cohesiveness of the powder cannot be sufficiently suppressed. Is shown. It is confirmed that the aggregation suppression effect of the powder can be obtained only when (A) the powdery silicone and the (B) component are used in combination.

Next, the technical idea that can be grasped from the above embodiment will be described below.
(A) The method for producing a hair composition to be formulated by mixing the components (A) and (B) or the components (A) to (C) and then dissolving the mixture in water (D).

Claims (4)

A hair composition comprising the following components (A) and (B):
(A): Powdered silicone.
(B): An imidazoline type quaternary ammonium salt represented by the following general formula (1).

(In the formula, R represents an alkyl group or alkenyl group having 11 to 23 carbon atoms, and X represents a halogen atom, a methyl sulfate residue or an ethyl sulfate residue.) The hair composition according to claim 1, further comprising (C) a liquid silicone compound at 25 ° C. The hair composition according to claim 1 or 2, wherein the (A) powdery silicone is at least one selected from silicone resins, silicone elastomers, and composites thereof. The hair composition according to any one of claims 1 to 3, further comprising (D) water.