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JP4866564B2 - Cosmetic for salmon - Google Patents
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JP4866564B2 - Cosmetic for salmon - Google Patents

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JP4866564B2
JP4866564B2 JP2005098987A JP2005098987A JP4866564B2 JP 4866564 B2 JP4866564 B2 JP 4866564B2 JP 2005098987 A JP2005098987 A JP 2005098987A JP 2005098987 A JP2005098987 A JP 2005098987A JP 4866564 B2 JP4866564 B2 JP 4866564B2
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yellow
cosmetic
film
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雅樹 奥山
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Kose Corp
Teijin Frontier Co Ltd
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Teijin Fibers Ltd
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Description

本発明は、新規な外観及び化粧効果に優れた睫用化粧料に関し、さらに詳細には、彩度が高く、光輝性に優れた外観を有し、また、その使用により得られる化粧膜も、彩度が高く、睫の質感を光学的に変化させることにより、従来にない透明感や立体感を付与する効果に優れるとともに、睫を長く見せる効果(ロングラッシュ効果)があり、更にそれらの化粧効果の持続性に優れ、かつ使用性が良く、安定性も良好な睫用化粧料に関するものである。   The present invention relates to a cosmetic for vaginal skin having a novel appearance and cosmetic effect, and more specifically, has an appearance with high chroma and excellent luster, and a cosmetic film obtained by its use also includes: High saturation and optically changing the texture of wrinkles provide an unprecedented effect of adding transparency and stereoscopic effect, and has the effect of making wrinkles look longer (long lash effect). The present invention relates to a vaginal cosmetic that is excellent in durability, has good usability, and has good stability.

睫用化粧料における繊維の配合については、種々の剤型、他の化粧料用基剤との組み合わせが検討されており、例えば、合成樹脂エマルションと繊維を含有する睫用化粧料に平均分子量500以上のポリブテンを含有することで睫を長くする効果を向上させる技術(例えば特許文献1)や、ロジン酸系樹脂を含有することで繊維の付着性を向上させる技術(例えば特許文献2)、フッ素化合物により、繊維表面を処理することにより、繊維の分散性を向上させ、均一な化粧膜を形成させる技術(例えば特許文献3)等が報告されている。さらに、繊維を着色し用いる技術としては、水溶性高分子を用いた睫用化粧料に、カーボンブラック等の顔料で着色された繊維を用いることにより、自然な仕上がり感を与える技術(例えば特許文献4)や、高彩度着色剤により着色された繊維を用いることで、使用部位に高彩度な化粧膜を付与する技術(例えば特許文献5)等が知られている。   Various formulations and combinations with other cosmetic bases have been studied for the blending of fibers in the cosmetics for cocoons. For example, an average molecular weight of 500 is applied to cosmetics for cocoons containing synthetic resin emulsions and fibers. A technique for improving the effect of lengthening wrinkles by containing the above polybutene (for example, Patent Document 1), a technique for improving fiber adhesion by containing a rosin acid resin (for example, Patent Document 2), fluorine A technique for improving the dispersibility of the fiber by treating the fiber surface with a compound to form a uniform decorative film (for example, Patent Document 3) has been reported. Furthermore, as a technique for coloring and using the fiber, a technique for giving a natural finish feeling by using a fiber colored with a pigment such as carbon black in a vaginal cosmetic using a water-soluble polymer (for example, Patent Documents). 4) and a technique (for example, Patent Document 5) that imparts a high-saturation cosmetic film to a use site by using a fiber colored with a high-saturation colorant is known.

しかしながら、従来から使用されてきたナイロン等の繊維は透明〜白色を呈しており、特に外観が透明な化粧料剤型に配合すると色の彩度が低く、高彩度な化粧膜の付与といった化粧効果を充分に得ることができなかった。更に、ナイロン繊維にカーボンブラックや酸化チタン等の顔料を配合した繊維を使用しても、色の彩度に欠け、睫に高彩度な化粧膜を付与する効果を充分に得ることができなかった。また、天然系繊維には、原料に由来する彩度の低い着色があり、睫に高彩度な化粧膜を付与する点では、ナイロン繊維と同様、化粧効果を充分に得ることができなかった。   However, conventionally used fibers such as nylon have a clear to white color, especially when blended in a cosmetic formulation with a transparent appearance, and have a cosmetic effect such as imparting a highly saturated cosmetic film with low color saturation. It could not be obtained sufficiently. Furthermore, even when a fiber in which a pigment such as carbon black or titanium oxide is blended with nylon fiber is used, the effect of imparting a highly saturated decorative film to the eyelids cannot be obtained sufficiently. In addition, natural fibers are colored with low saturation derived from the raw materials, and the cosmetic effect cannot be sufficiently obtained in the same manner as nylon fibers in that a highly saturated makeup film is imparted to the eyelids.

そこで、繊維を染料等で着色することにより、高彩度な化粧膜を有する化粧料を得る試みが行われてはいるが、最近の睫用化粧料に要求される個性的な化粧膜、例えば、見る角度によって質感が変化するといった化粧効果を有する化粧膜を提供することは困難であり、市場のニーズを充分に満たす化粧効果を得ることができなかった。更に、得られた化粧膜は、水や油になじみやすく、化粧効果の持続性の点でも満足のいくものではなかった。   Thus, attempts have been made to obtain a cosmetic material having a highly saturated cosmetic film by coloring the fiber with a dye or the like. It has been difficult to provide a cosmetic film having a cosmetic effect in which the texture changes depending on the angle, and it has not been possible to obtain a cosmetic effect that sufficiently satisfies market needs. Furthermore, the obtained cosmetic film was easily compatible with water and oil, and was not satisfactory in terms of durability of the cosmetic effect.

更にまた、従来、繊維分野で知られている干渉光を呈する繊維を化粧料に用いることも行われており、水溶性高分子を用いたような透明タイプの剤型では、睫を際立たせるのに十分な質感の変化を与えることができるものの、O/W、W/Oといった乳化剤型では、化粧膜の透明性が低いため、質感の変化が見えづらく、十分な化粧効果を付与できるとは言い難かった。   Furthermore, conventionally, fibers that exhibit interference light, which are known in the fiber field, have been used in cosmetics, and in transparent dosage forms that use water-soluble polymers, wrinkles stand out. The emulsifier types such as O / W and W / O have a low transparency of the cosmetic film, making it difficult to see the change in texture and providing a sufficient cosmetic effect. It was hard to say.

特公平2−4572号公報Japanese Patent Publication No.2-4572 特開平9−263518号公報JP-A-9-263518 特許第3409192号公報Japanese Patent No. 3409192 特開平10−291917号公報Japanese Patent Laid-Open No. 10-291917 特開2000−319132号公報JP 2000-319132 A

従って、使用性、使用感、化粧膜の均一性を損なうことなく、市場のニーズを充分に満たすような高い化粧効果を有し、しかも得られた化粧膜が水や油になじみにくく、化粧効果の持続性の点でも満足のいくような睫用化粧料の提供が求められていた。   Therefore, it has a high makeup effect that fully satisfies the needs of the market without impairing the usability, feeling of use, and uniformity of the makeup film, and the obtained makeup film is not easily adapted to water and oil, and the makeup effect There was a need to provide vaginal cosmetics that are satisfactory in terms of sustainability.

本発明者は、上記課題を解決するために鋭意研究した結果、特定の繊維と、皮膜形成性成分を配合することにより得られた睫用化粧料は、高彩度で光輝性に優れる新規な質感が付与された外観と、睫に使用することにより、特定の繊維が睫に沿って均一な化粧膜を形成することで繊維のもつ干渉色がより強調され、高彩度で、見る角度によって質感が変化するという優れた化粧効果を有することを見出した。   As a result of intensive studies to solve the above-mentioned problems, the present inventor has a novel texture that is high in saturation and excellent in luster, obtained from blending specific fibers with a film-forming component. When used for wrinkles with a given appearance, the specific fibers form a uniform decorative film along the wrinkles, so that the interference color of the fibers is more emphasized, high saturation, and the texture changes depending on the viewing angle It has been found that it has an excellent makeup effect.

また、この睫用化粧料は、効果の持続性に優れるだけでなく、繊維を含んだ化粧膜が透明で均一な皮膜を形成することで化粧膜表面の光輝性が高まり、繊維のもつ外観色と干渉色とをさらに強調させ、従来にない奥深い透明感や立体感をより効果的に付与できることを見出した。その上このものは、睫用化粧料に要求される睫を長く見せる効果(ロングラッシュ効果)に優れ、使用性が良く、安定性も良好な睫用化粧料であることを見出し、本発明を完成するに至った。   In addition, this vaginal cosmetics is not only excellent in sustainability of the effect, but the cosmetic film containing fibers forms a transparent and uniform film, which increases the glitter of the cosmetic film surface, and the appearance color of the fibers And the interference color are further emphasized, and it has been found that deep transparency and three-dimensionality that are not possible in the past can be more effectively imparted. In addition, it has been found that this is a vaginal cosmetic that is excellent in the effect of long-lasting wrinkles required for vaginal cosmetics (long rush effect), has good usability, and has good stability. It came to be completed.

すなわち、本発明は、次の成分(A)および(B)
(A)着色された、屈折率の異なる2種類以上の高分子化合物を含む干渉繊維
(B)皮膜形成性成分
を含有することを特徴とする睫用化粧料である。
That is, the present invention provides the following components (A) and (B)
(A) Colored interference fiber containing two or more kinds of polymer compounds having different refractive indexes (B) A cosmetic for vaginal skin containing a film-forming component.

本発明の睫用化粧料は、化粧料自体の使用性、使用感、化粧膜の均一性等を損なうことなく、化粧料自体の外観や色調に高い彩度を付与することができ、また、使用部位である睫に光輝性を付与し、高い彩度を与えると共にその質感を光学的に変化させることにより、従来にない透明感や立体感を付与する効果等を発揮することができる優れたものである。   The vaginal cosmetics of the present invention can impart high saturation to the appearance and color tone of the cosmetics themselves, without impairing the usability of the cosmetics themselves, the feeling of use, the uniformity of the cosmetic film, etc. It is possible to demonstrate the effect of imparting unprecedented transparency and three-dimensional effect, etc. by giving glitter to the use part, giving high saturation and changing the texture optically. Is.

本発明の睫用化粧料の成分(A)である、着色された、屈折率の異なる2種以上の高分子化合物を含む干渉繊維(以下、「着色干渉繊維」と略す)は、少なくとも2種類以上の高分子化合物で構成される層状の断面構造(積層断面)を有する複合繊維を、着色剤で着色した繊維であり、この複合繊維は干渉色として、赤色、黄色、緑色、青色、紫色等を呈するものである。断面形状については、平行積層部を保護層でつつんだ扁平断面干渉繊維が、化粧料として睫等に付着しやすく、また一方向からの発色をより強くみせるためにも望ましい。この着色干渉繊維に使用される高分子化合物は、通常、化粧料に使用されるものであれば特に限定されないが、例えば、ナイロン、ポリエチレンテレフタレート、ポリプロピレン、ポリカーボネイト、ポリメチルメタクリレート、ポリエステル等があげられる。これらの高分子化合物のなかでも、ポリエチレンテレフタレートとナイロンの組み合わせは、干渉光を強く呈し、また繊維工程安定性も良好で、本願発明の効果がより顕著に現れるため好ましい。   At least two kinds of colored interference fibers (hereinafter abbreviated as “colored interference fibers”), which are two or more kinds of colored polymer compounds having different refractive indices, which are the component (A) of the cosmetic for cosmetics of the present invention. It is a fiber obtained by coloring a composite fiber having a layered cross-sectional structure (laminated cross section) composed of the above polymer compounds with a colorant, and this composite fiber has interference colors such as red, yellow, green, blue, purple, etc. It presents. As for the cross-sectional shape, the flat cross-section interference fiber in which the parallel laminated portion is sandwiched by the protective layer is desirable because it easily adheres to wrinkles and the like as a cosmetic, and more strongly develops color from one direction. The polymer compound used in the colored interference fiber is not particularly limited as long as it is usually used in cosmetics. Examples thereof include nylon, polyethylene terephthalate, polypropylene, polycarbonate, polymethyl methacrylate, and polyester. . Among these polymer compounds, a combination of polyethylene terephthalate and nylon is preferable because it strongly exhibits interference light and has good fiber process stability, and the effects of the present invention appear more remarkably.

一方、複合繊維の着色に使用される着色剤としては、通常化粧料に使用されるものであれば特に制限されず、いずれのものも使用できる。例えば、赤色2号、赤色3号、赤色102号、赤色104号(1)、赤色105号(1)、赤色106号、黄色4号、黄色5号、緑色3号、青色1号、青色2号、赤色201号、赤色213号、赤色214号、赤色215号、赤色227号、赤色230号(1)、赤色230号(2)、赤色231号、赤色232号、橙色205号、橙色207号、黄色203号、緑色201号、緑色204号、緑色205号、青色202号、青色203号、青色205号、かっ色201号、赤色401号、赤色502号、赤色503号、赤色504号、赤色506号、橙色402号、黄色402号、黄色403号(1)、黄色406号、黄色407号、緑色401号、緑色402号、紫色401号、黒色401号等の水溶性のタール系色素、赤色202号、赤色218号、赤色223号、赤色226号、赤色228号、橙色201号、黄色201号、黄色205号、青色201号、青色204号、紫色201号、赤色404号、赤色405号、橙色401号、黄色401号、黄色404号、黄色405号、青色403号、青色404号等の水不溶性のタール系色素、クチナシ色素、ベニバナ色素、ウコン色素、パプリカ色素、アナトー色素、コチニール色素等の天然色素、酸性、塩基性色素、及び分散染料等が挙げられるが、中でも水溶性のタール系色素は、着色性、安定性が高いため、顕著な化粧効果が得られ最も好ましい。また、これらの着色剤は、1種又は2種以上を使用することが可能であり、複合繊維に種々の色調を付与することができる。   On the other hand, the colorant used for coloring the composite fiber is not particularly limited as long as it is usually used in cosmetics, and any one can be used. For example, Red No. 2, Red No. 3, Red No. 102, Red No. 104 (1), Red No. 105 (1), Red No. 106, Yellow No. 4, Yellow No. 5, Green No. 3, Blue No. 1, Blue No. 2 No., Red 201, Red 213, Red 214, Red 215, Red 227, Red 230 (1), Red 230 (2), Red 231, Red 232, Orange 205, Orange 207 No., Yellow 203, Green 201, Green 204, Green 205, Blue 202, Blue 203, Blue 205, Brown 201, Red 401, Red 502, Red 503, Red 504 Red 506, orange 402, yellow 402, yellow 403 (1), yellow 406, yellow 407, green 401, green 402, purple 401, black 401, etc. Dye, red 202, Color 218, Red 223, Red 226, Red 228, Orange 201, Yellow 201, Yellow 205, Blue 201, Blue 204, Purple 201, Red 404, Red 405, Orange 401 No., yellow 401, yellow 404, yellow 405, blue 403, blue 404, etc. Examples thereof include dyes, acidic dyes, basic dyes, and disperse dyes. Among these, water-soluble tar-based dyes are most preferable because they have a high colorability and stability, and thus can provide a remarkable cosmetic effect. Moreover, these colorants can use 1 type (s) or 2 or more types, and can provide a various color tone to a composite fiber.

複合繊維を着色する場合の着色剤の量は、着色剤の量は、特に制限されず、目的に応じて決められるが、着色干渉繊維全体の0.01〜30質量%(以下、単に「%」と示す)が好ましく、さらに0.01〜10%が好ましい。この範囲であれば使用部位に高彩度な化粧膜を付与するといった化粧効果が充分に得られる。また、着色剤の色は、干渉色と同系色であると、光干渉に必要な波長を積層部に達することを阻害しないため、効果的である。干渉色と反対色で着色すると、干渉効果を発現する波長を着色剤が吸収してしまうため、干渉繊維の発色は減少してしまう場合がある。このため、干渉繊維の発色と同系色もしくは補色関係にない色で着色すると、干渉光を強く呈し、本願発明の効果がより顕著に現れるため、好ましい。なお、ここでいう同系色とは、P.C.C.S色彩体系の24色相環表上において、となりあう色相を意味し、例えば、干渉色が赤の場合は、赤紫〜橙を同系色とする。また、干渉色が黄色の時は、橙〜黄緑を、干渉色が緑の場合は、黄緑〜青を、干渉色が紫の場合は、青紫〜赤紫をそれぞれ同系色とする。   The amount of the colorant in the case of coloring the composite fiber is not particularly limited and is determined according to the purpose, but is 0.01 to 30% by mass (hereinafter simply referred to as “%”) of the entire colored interference fiber. ")" Is preferable, and 0.01 to 10% is more preferable. If it is this range, the cosmetic effect of providing a highly saturated decorative film to the use site can be sufficiently obtained. Further, if the color of the colorant is similar to the interference color, it is effective because it does not hinder the wavelength necessary for optical interference from reaching the laminated portion. When colored with an interference color opposite to the interference color, the colorant absorbs a wavelength that exhibits an interference effect, and thus the color of the interference fiber may be reduced. For this reason, it is preferable to color the interference fiber with a color that is similar to or not complementary to the color of the interference fiber, because the interference light is strongly exhibited and the effects of the present invention appear more remarkably. Here, the similar color means a hue that is adjacent on the 24-color ring table of the P.C.C.S. color system. For example, when the interference color is red, reddish purple to orange are similar. Color. Further, when the interference color is yellow, orange to yellow-green is used. When the interference color is green, yellow green to blue is used. When the interference color is purple, blue to purple is used.

本発明の成分(A)の着色干渉繊維の製造方法は、特に制限されず、従来の高分子化合物から繊維を得る方法が利用できるが、好ましい方法の例としては次の方法を挙げることができる。すなわち、特開平7−34324号公報、特開平11−1829号公報あるいはWO98/46815号パンフレットに記載の方法に従って屈折率の異なる高分子化合物を積層し、干渉光を呈する繊維(干渉繊維)を製造した後、それを常法に従って染料で着色する方法や、上記記載の方法中、繊維製造時にあらかじめ着色剤を高分子化合物に分散し、これをもちいて直接着色干渉繊維を製造する方法等があげられる。   The method for producing the colored interference fiber of the component (A) of the present invention is not particularly limited, and a conventional method for obtaining a fiber from a polymer compound can be used. Examples of preferred methods include the following methods. . That is, high-molecular compounds having different refractive indexes are laminated according to the methods described in JP-A-7-34324, JP-A-11-1829, or WO98 / 46815 to produce fibers that exhibit interference light (interference fibers). Then, a method of coloring it with a dye according to a conventional method, a method of dispersing a colorant in a polymer compound in advance at the time of fiber production, and directly producing a colored interference fiber using the method, etc. It is done.

本発明の睫用化粧料に配合される着色干渉繊維の長さ及び太さは、特に制限されないが、睫への化粧効果及び、良好な使用性と均一な化粧膜の形成の点において、長さは0.01〜5mmの範囲が好ましく、更に0.1〜3mmが好ましい。また、太さは、0.01〜20デニール(以下、単に「D」と示す)の範囲が好ましく、更には0.1〜13Dが好ましい。また、効果を顕著に発現させるためには、各々のポリマー成分で構成される層が、5層以上の交互積層し、かつ、それぞれの層の厚みが0.02〜0.3μmの範囲にあることが好ましい。これらの繊維は、材質、太さ、長さの異なる1種又は2種以上を用いることができる。   The length and thickness of the colored interference fibers blended in the cosmetics for wrinkles of the present invention are not particularly limited, but are long in terms of cosmetic effect on wrinkles and good usability and formation of a uniform decorative film. The thickness is preferably in the range of 0.01 to 5 mm, more preferably 0.1 to 3 mm. The thickness is preferably in the range of 0.01 to 20 denier (hereinafter simply referred to as “D”), more preferably 0.1 to 13D. Moreover, in order to express an effect notably, the layer comprised by each polymer component laminates | stacks five or more layers alternately, and the thickness of each layer exists in the range of 0.02-0.3 micrometer. It is preferable. These fibers can be used alone or in combination of two or more materials, thicknesses, and lengths.

本発明の成分(A)の着色干渉繊維は、そのままで本発明の睫用化粧料に使用することもできるが、更に表面処理することにより、化粧料中での分散性が向上し、化粧効果及びその持続性を更に向上させることができるので、表面処理したものを使用することがより好ましい。   The colored interference fiber of the component (A) of the present invention can be used as it is for the vaginal cosmetics of the present invention, but by further surface treatment, the dispersibility in the cosmetics is improved and the cosmetic effect is improved. In addition, it is more preferable to use a surface-treated product because the durability can be further improved.

着色干渉繊維に対する表面処理剤としては、通常化粧料に使用されるものであれば特に制限されず、いずれのものも使用できる。例えば、一般油剤、シリコーン油、フッ素化合物、界面活性剤、シリカ等が挙げられるが、特に、シリカ及び/又はフッ素化合物を表面処理剤として表面処理することが好ましい。   The surface treatment agent for the colored interference fiber is not particularly limited as long as it is usually used in cosmetics, and any one can be used. For example, general oil agents, silicone oils, fluorine compounds, surfactants, silicas and the like can be mentioned, and it is particularly preferable to perform surface treatment using silica and / or fluorine compounds as a surface treatment agent.

表面処理の方法は特に制限されないが、例えば、シリカの場合は、溶媒に表面処理剤としてのシリカと着色干渉繊維を入れ、この繊維にシリカを被覆又は付着させる方法や、溶媒に懸濁させた後、これを繊維に吹き付ける方法等が挙げられる。また、フッ素化合物の場合は、例えばフッ素化合物をアセトン、トルエン等の有機溶媒に加熱溶解せしめ、その中に繊維の1種又は2種以上の混合物を加え、撹拌後溶媒を留去して繊維上にフッ素化合物を被覆又は付着させ、場合によっては更に焼き付け処理をする方法がある。   The surface treatment method is not particularly limited. For example, in the case of silica, silica as a surface treatment agent and colored interference fiber are put in a solvent, and the silica is coated or adhered to the fiber, or suspended in a solvent. Thereafter, a method of spraying this on the fiber can be used. In the case of a fluorine compound, for example, the fluorine compound is heated and dissolved in an organic solvent such as acetone or toluene, and one or two or more mixtures of fibers are added to the mixture. There is a method in which a fluorine compound is coated or adhered to the substrate, and in some cases, a baking treatment is further performed.

着色干渉繊維に対する表面処理剤の使用量は、特に制限されず、目的に応じて決められるが、表面処理された着色干渉繊維全体の0.01〜30%が好ましく、更に0.1〜20%が好ましい。この範囲であれば繊維の分散性が向上し、化粧効果が顕著に現れ、その効果の持続性が充分に得られる。   The amount of the surface treatment agent used for the colored interference fibers is not particularly limited and is determined according to the purpose, but is preferably 0.01 to 30%, more preferably 0.1 to 20% of the entire surface-treated colored interference fibers. Is preferred. If it is this range, the dispersibility of a fiber will improve, a cosmetic effect will appear notably, and the sustainability of the effect will fully be acquired.

本発明の睫用化粧料における成分(A)の着色干渉繊維の配合量は、特に制限されないが、0.1〜50%が好ましく、0.5〜20%が更に好ましい。この範囲で用いれば、発明の効果が顕著に現れる。   Although the compounding quantity of the colored interference fiber of the component (A) in the cosmetics for wrinkles of the present invention is not particularly limited, it is preferably 0.1 to 50%, and more preferably 0.5 to 20%. If it is used within this range, the effect of the invention will be remarkable.

一方、本発明の睫用化粧料に使用される成分(B)の皮膜形成性成分は、化粧料を塗布した際に皮膜を形成するものであれば特に制限されず、油溶性樹脂成分、ポリマーエマルション、水溶性樹脂成分等、いずれのものも使用される。   On the other hand, the film-forming component of the component (B) used in the vaginal cosmetic of the present invention is not particularly limited as long as it forms a film when the cosmetic is applied, and it is an oil-soluble resin component, a polymer. Any of emulsions, water-soluble resin components and the like can be used.

具体的には、油溶性樹脂成分の例として、ロジン酸ペンタエリスリット等のロジン酸系樹脂、トリメチルシロキシケイ酸、キャンデリラレジン(ここで、キャンデリラレジンとは、キャンデリラワックスを有機溶剤にて分別抽出して得られる樹脂分で、樹脂分が好ましくは65%以上、更に好ましくは85%以上の割合で含有されるものである)、アクリル酸アルキル・アクリル酸ジメチコン共重合体、部分架橋オルガノポリシロキサン、ポリ酢酸ビニル系樹脂、ポリビニルイソブチルエーテル、ポリイソブチレン、等が挙げられ、これらを1種又は2種以上を使用することができる。   Specifically, examples of oil-soluble resin components include rosin acid-based resins such as rosin acid pentaerythritol, trimethylsiloxysilicic acid, and candelilla resin (here, candelilla resin uses candelilla wax as an organic solvent). Resin fraction obtained by fractional extraction, wherein the resin content is preferably 65% or more, more preferably 85% or more), alkyl acrylate / dimethicone acrylate copolymer, partially crosslinked Examples thereof include organopolysiloxane, polyvinyl acetate resin, polyvinyl isobutyl ether, polyisobutylene, and the like, and one or more of these can be used.

また、ポリマーエマルションとは、高分子化合物を水性溶媒に分散してあるものをいい、具体的な皮膜形成性ポリマーエマルションの例としては、例えば、(メタ)アクリル酸アルキル共重合体エマルション、(メタ)アクリル酸・(メタ)アクリル酸アルキル共重合体エマルション、(メタ)アクリル酸アルキル・スチレン共重合体エマルション、酢酸ビニル重合体エマルション、酢酸ビニル含有共重合体エマルション、ビニルピロリドン・スチレン共重合体エマルション、シリコーン含有(共)重合体エマルション等が挙げられ、これらを1種又は2種以上を使用することができる。   The polymer emulsion refers to a polymer compound dispersed in an aqueous solvent. Specific examples of the film-forming polymer emulsion include (meth) alkyl acrylate copolymer emulsion, (meta ) Acrylic acid / (meth) acrylate alkyl copolymer emulsion, (meth) alkyl acrylate / styrene copolymer emulsion, vinyl acetate polymer emulsion, vinyl acetate-containing copolymer emulsion, vinyl pyrrolidone / styrene copolymer emulsion , Silicone-containing (co) polymer emulsions, and the like, and one or more of them can be used.

更に、水溶性樹脂成分の例としては、ポリビニルアルコール、ポリビニルピロリドン、ビニルピロリドン・酢酸ビニル共重合体等が挙げられ、これらを1種又は2種以上を使用することができる。   Furthermore, examples of the water-soluble resin component include polyvinyl alcohol, polyvinyl pyrrolidone, vinyl pyrrolidone / vinyl acetate copolymer, etc., and one or more of them can be used.

これらの皮膜形成性成分のなかでも、油溶性樹脂成分として、ロジン酸系樹脂、トリメチルシロキシケイ酸、アクリル酸アルキル・アクリル酸ジメチコン共重合体、キャンデリラレジンが、またポリマーエマルションとして、アクリル酸エステルポリマーエマルション、酢酸ビニルポリマーエマルションが、睫を長く見せ、目元を際立たせるといった化粧効果及び化粧効果の持続性の点で特に好ましい。   Among these film-forming components, rosin acid resin, trimethylsiloxysilicic acid, alkyl acrylate / dimethicone acrylate copolymer, and candelilla resin are used as oil-soluble resin components, and acrylate esters are used as polymer emulsions. Polymer emulsions and vinyl acetate polymer emulsions are particularly preferred from the standpoint of cosmetic effects and long-lasting cosmetic effects that make wrinkles look longer and make the eyes stand out.

本発明の睫用化粧料における皮膜形成性成分の配合量は、特に制限されないが、純分換算で、0.5〜25%が好ましく、更に好ましくは1〜15%である。この範囲であれば、睫を長く見せ、目元を際立たせるといった化粧効果の持続性の点で満足のいくものが得られる。   The blending amount of the film-forming component in the cosmetic for vaginal skin of the present invention is not particularly limited, but is preferably 0.5 to 25%, more preferably 1 to 15% in terms of pure content. If it is in this range, a satisfactory product can be obtained in terms of the durability of the makeup effect, such as making the eyelids look longer and making the eyes stand out.

本発明の睫用化粧料は、上記した着色干渉繊維(成分(A))と皮膜形成成分(成分(B))とを、通常化粧料に使用される成分と組み合わせ、適宜製剤化することにより調製される。   The vaginal cosmetics of the present invention are prepared by combining the above-described colored interference fibers (component (A)) and film-forming components (component (B)) with components usually used in cosmetics, and appropriately formulating them. Prepared.

本発明の睫用化粧料の製造にあたって使用される、通常化粧料に使用される成分の例としては、感触調整や着色の目的で配合される粉体成分、基材、エモリエント成分として配合される油性成分、保湿、粉体分散剤として配合される水性成分、粉体分散、感触調整の為に配合される界面活性剤等が挙げられる。更に、紫外線吸収剤、保湿剤、褪色防止剤、酸化防止剤、消泡剤、美容成分、防腐剤、香料などを本発明の効果を損なわない範囲で適宜配合することもできる。   Examples of components that are normally used in cosmetics used in the manufacture of the cosmetics for wrinkles of the present invention are blended as powder components, base materials, and emollient components that are blended for the purpose of feeling adjustment and coloring. Examples thereof include an oily component, a moisture component, an aqueous component blended as a powder dispersant, a powder dispersant, a surfactant blended for touch control, and the like. Furthermore, ultraviolet absorbers, humectants, anti-fading agents, antioxidants, antifoaming agents, cosmetic ingredients, preservatives, fragrances, and the like can be appropriately blended as long as the effects of the present invention are not impaired.

このようにして得られる本発明の睫用化粧料の好ましい剤型例としては、油性型、乳化型等のものが挙げられる。また、好ましい形態としては、クリーム状、ゲル状、液状等が挙げられるが、中でもゲル状が好ましい。更に、外観としては、透明、半透明、不透明のいずれの睫用化粧料であっても良い。   Examples of preferable dosage forms of the vaginal cosmetic of the present invention thus obtained include oil-based types and emulsified types. Moreover, as a preferable form, cream shape, gel shape, liquid state, etc. are mentioned, However, Gel shape is especially preferable. Furthermore, the appearance may be any transparent cosmetic, translucent or opaque cosmetic.

以下に実施例を挙げて本発明を詳細に説明する。尚、これらは本発明を何ら限定するものではない。   Hereinafter, the present invention will be described in detail with reference to examples. Note that these do not limit the present invention.

実 施 例 1
O/Wマスカラ:
表1に示す処方の、本発明品1〜5及び比較品1〜5のO/Wマスカラを下記製造方法にて調製した。得られた各マスカラについて、a.外観色調に高い彩度を付与する効果(外観の高彩度感)、b.外観に光輝性を付与する効果(外観の光輝性)、c.睫に高い彩度を付与する効果(化粧膜の高彩度感)、d.睫に透明感、立体感を付与する効果(化粧膜の質感改良効果)、e.睫を長く見せる効果(ロングラッシュ効果)、f.塗布時の化粧のしやすさ(使用性)、g.化粧膜の均一性、h.化粧効果の持続性について下記の方法により官能評価を行った。その結果もあわせて表1に示す。
Example 1
O / W mascara:
O / W mascara of the present invention products 1 to 5 and comparative products 1 to 5 having the formulations shown in Table 1 were prepared by the following production method. About each obtained mascara, a. The effect which gives high chroma to appearance color tone (high chroma feeling of appearance), b. The effect which gives glossiness to appearance (look glossiness), c. E. Effect (high-saturation feeling of makeup film), d. Effect of imparting transparency and stereoscopic effect to wrinkles (effect improving texture of makeup film), e. Effect of making wrinkles appear longer (long rush effect), f. Coating The following methods were used for sensory evaluation of ease of makeup (usability), g. Uniformity of makeup film, and h. The results are also shown in Table 1.

(処 方)

Figure 0004866564
(How to)
Figure 0004866564

※1 キャンデリラレジンの組成は、樹脂分90%、遊離アルコール5%、遊離脂肪酸
分2%、エステル分2%、炭化水素分1%であり、軟化点は47〜48℃である

※2 0.1%青色1号で着色した繊維(ポリエチレンテレフタレート、ナイロンを特開
平11−1829に従い、交互に51層積層したもの、6D、2mm)(青色の干
渉光を有する)
※3 0.1%青色1号で着色した繊維(6D、2mm)(干渉光を有しない)
※4 無着色繊維(6D、2mm)(干渉光を有しない)
※5 固形分20%
※6 丸型、1mm
* 1 The composition of candelilla resin is 90% resin, 5% free alcohol, 2% free fatty acid, 2% ester, 1% hydrocarbon, and softening point is 47-48 ° C.
* 2 Fiber colored with 0.1% blue No. 1 (Polyethylene terephthalate, nylon according to JP-A-11-1829, 51 layers stacked alternately, 6D, 2 mm) (with blue interference light)
* 3 Fiber colored with 0.1% blue No. 1 (6D, 2mm) (no interference light)
* 4 Uncolored fiber (6D, 2mm) (no interference light)
* 5 Solid content 20%
* 6 Round, 1mm

(製造方法)
A.成分(5)〜(17)を均一に混合し、80℃に加熱する。
B.成分(1)〜(4)を加熱溶解(80℃)する。
C.AにBを加え乳化する。
D.Cを容器に充填して製品とする。
(Production method)
A. Components (5) to (17) are uniformly mixed and heated to 80 ° C.
B. Components (1) to (4) are dissolved by heating (80 ° C.).
C. Add B to A and emulsify.
D.C is filled into a container to obtain a product.

(評価方法)
10名の官能検査パネルにより、各試料を下記a〜hについて、(1)絶対評価基準を用いて7段階に評価し、各試料の評点の平均値を(2)4段階判定基準を用いて評価した。評価項目hについては、試料を睫に塗布し、パネルに通常の生活をしてもらい、12時間後の化粧効果について評価した。
(Evaluation methods)
Using 10 sensory test panels, each sample was evaluated for the following a to h using (1) absolute evaluation criteria in 7 levels, and the average score of each sample was (2) using 4 levels determination criteria. evaluated. For the evaluation item h, the sample was applied to a bag and the panel was allowed to live a normal life, and the cosmetic effect after 12 hours was evaluated.

(評価項目)
a.外観色調に高い彩度を付与する効果(外観の高彩度感)
b.外観に光輝性を付与する効果(外観の光輝性)
c.睫に高い彩度を付与する効果(化粧膜の高彩度感)
d.睫に透明感、立体感を付与する効果(化粧膜の質感改良効果)
e.睫を長く見せる効果(ロングラッシュ効果)
f.塗布時の化粧のしやすさ(使用性)
g.化粧膜の均一性
h.化粧効果の持続性
(Evaluation item)
a. Effect of adding high saturation to the appearance color tone (high saturation of appearance)
b. Effect of adding glitter to appearance (brightness of appearance)
c. Effect of imparting high saturation to the eyelids (high saturation of the makeup film)
d. Effect of imparting transparency and stereoscopic effect to the eyelids (effect of improving the texture of the decorative film)
e. Long-lasting effect (睫)
f. Ease of makeup when applied (usability)
g. Uniformity of makeup film h. Persistence of makeup effect

(1)絶対評価基準
評 点 : 評 価
6 : 非常に良い
5 : 良い
4 : やや良い
3 : 普通
2 : やや悪い
1 : 悪い
0 : 非常に悪い
(2)4段階判定基準
評点平均値 : 判 定
5点を超える : 非常に良好(◎)
3点を超えて5点以下 : 良 好 (○)
2点を超えて3点以下 : やや不良 (△)
2点以下 : 不 良 (×)
(1) Absolute Evaluation Criteria Rating: Evaluation 6: Very Good 5: Good 4: Somewhat Good 3: Normal 2: Somewhat Bad 1: Bad 0: Very Bad (2) Four-step Judgment Criteria Average Value: Judgment Constant
More than 5 points: Very good (◎)
Over 3 points and below 5 points: Good (○)
Over 2 points and under 3 points: Somewhat bad (△)
2 points or less: Bad (×)

表1の結果から明らかなように、本発明品である1〜5のマスカラは、比較品1〜5のマスカラと比較し、外観色調に高い彩度を付与する効果(外観の高彩度感)、外観に光輝性を付与する効果(外観の光輝性)、睫に高い彩度を付与する効果(化粧膜の高彩度感)、睫に透明感、立体感を付与する効果(化粧膜の質感改良効果)、睫を長く見せる効果(ロングラッシュ効果)、塗布時の化粧のしやすさ(使用性)、化粧膜の均一性、化粧効果の持続性のすべての面で、はるかに優れた特性を有していることがわかる。   As is clear from the results in Table 1, the mascara of 1 to 5 which is the product of the present invention has an effect of imparting high saturation to the appearance color tone (high saturation of appearance) compared to the mascara of comparative products 1 to 5. The effect of adding glitter to the appearance (brightness of appearance), the effect of adding high chroma to the eyelids (high chroma of the makeup film), the effect of adding transparency and three-dimensionality to the eyelids (effect of improving the texture of the makeup film) ), Long-lasting effect, long-lasting effect, ease of makeup application (usability), uniformity of makeup film, and long-lasting makeup effect. You can see that

一方、ナイロン繊維を着色した比較品1では睫に透明感、立体感を付与する効果(化粧膜の質感改良効果)の点で満足のいくものが得られなかった。また、着色していないナイロン繊維を用いた比較品2では、外観、化粧膜がうす白くボケた発色になり、外観色調に高い彩度を付与する効果(外観の高彩度感)、外観に光輝性を付与する効果(外観の光輝性)、睫に高い彩度を付与する効果(化粧膜の高彩度感)、睫に透明感、立体感を付与する効果(化粧膜の質感改良効果)の点で満足の行くものが得られなかった。さらに、皮膜形成性成分を含有しない、比較品3では、外観の光輝性を強く感じる効果(外観の光輝性)、睫に透明感、立体感を付与する効果(化粧膜の質感改良効果)、化粧膜の均一性及び化粧効果の持続性の点で満足の行くものが得られなかった。質感を変化させるものとしてコンジョウ被覆雲母チタン、ポリエチレンテレフタレート・アルミニウム・エポキシ積層末を用いた比較品4、5についても様々な化粧効果の点で満足のいくものが得られなかった。   On the other hand, the comparative product 1 colored with nylon fibers was not satisfactory in terms of the effect of imparting transparency and stereoscopic effect to the cocoon (effect of improving the texture of the decorative film). Moreover, in the comparative product 2 using a non-colored nylon fiber, the appearance and the decorative film have a faint white color, an effect of imparting a high saturation to the appearance color tone (high color saturation of the appearance), and a glossy appearance. In terms of the effect of imparting (sparkle appearance), the effect of imparting high saturation to the eyelids (high saturation of the makeup film), the effect of imparting transparency and stereoscopic effect to the eyelids (the effect of improving the texture of the makeup film) I couldn't get anything satisfactory. Furthermore, in Comparative Product 3, which does not contain a film-forming component, the effect of strongly feeling the glitter of the appearance (the glitter of the appearance), the effect of imparting transparency and a three-dimensional effect to the eyelids (the effect of improving the texture of the decorative film), What was satisfactory in terms of the uniformity of the cosmetic film and the durability of the cosmetic effect was not obtained. Comparative products 4 and 5 using koji mica-coated titanium mica and polyethylene terephthalate / aluminum / epoxy laminated powder as a material for changing the texture were not satisfactory in terms of various cosmetic effects.

実 施 例 2
油性マスカラ:
下記成分および製造方法により、油性マスカラを調製した。
(成 分) (%)
(1)ロジン酸ペンタエリスリット 9
(2)ポリイソブチレン※8 1
(3)軽質流動イソパラフィン 53.4
(4)ポリエチレンワックス 10
(5)デキストリン脂肪酸エステル 5
(6)着色干渉繊維※9 10
(7)ベンガラ 5
(8)タルク※10 5
(9)オランダカラシエキス 0.5
(10)フェノキシエタノール 1
(11)香料 0.1
※8 分子量10万
※9 0.5%黄色4号で着色した繊維(ポリエチレンテレフタレート、ナイロン
を特開平11−1829に従い、交互に30層積層したもの、3D、0.5
mm)(黄色の干渉光を有する)
※10 2%ジメチルポリシロキサン処理
Example 2
Oily mascara:
An oily mascara was prepared by the following components and production method.
(Component) (%)
(1) Pentaerythrosyl rosin acid 9
(2) Polyisobutylene * 8 1
(3) Light liquid isoparaffin 53.4
(4) Polyethylene wax 10
(5) Dextrin fatty acid ester 5
(6) Colored interference fiber * 9 10
(7) Bengala 5
(8) Talc * 10 5
(9) Dutch mustard extract 0.5
(10) Phenoxyethanol 1
(11) Fragrance 0.1
* 8 Molecular weight 100,000 * 9 Fiber colored with 0.5% yellow No. 4 (polyethylene terephthalate, nylon
In accordance with Japanese Patent Laid-Open No. 11-1829, 30 layers are alternately laminated, 3D, 0.5
mm) (with yellow interference light)
* 10 2% dimethylpolysiloxane treatment

(製造方法)
A.成分(1)〜(5)を加熱溶解し、成分(6)〜(11)を加えて均一に混合す
る。
B.Aを容器に充填して製品とする。
(Production method)
A. Components (1) to (5) are heated and dissolved, and components (6) to (11) are added and mixed uniformly.
B. A is filled into a container to obtain a product.

以上のようにして得られたマスカラは、外観の高彩度感、外観の光輝性、化粧膜の高彩度感、化粧膜の質感改良効果、の全ての点に優れ、使用性、化粧膜の均一性、化粧効果の持続性も良好なものであった。   The mascara obtained as described above is excellent in all aspects of appearance, such as high chroma of appearance, glossiness of appearance, high chroma of cosmetic film, and texture improvement effect of cosmetic film, usability, uniformity of cosmetic film, The durability of the makeup effect was also good.

実 施 例 3
W/Oマスカラ:
下記成分および製造方法により、W/Oマスカラを調製した。
(成 分) (%)
(1)トリメチルシロキシケイ酸 20
(2)デカメチルシクロペンタシロキサン 42.3
(3)ポリオキシエチレン・メチルポリシロキサン共重合体※11 5
(4)精製水 15
(5)ポリプロピレン繊維※12 0.1
(6)着色干渉繊維※13 1
(7)チタン・酸化チタン焼結物 10
(8)ベンガラ被覆雲母チタン 5
(9)天然ビタミンE 0.5
(10)パラオキシ安息香酸エチル 1
(11)ポリビニルピロリドン 0.1
※11 KF−6017(信越化学工業社製)
※12 10D、3mm、未処理
※13 0.1%赤色106号で着色し、パーフルオロアルキルリン酸エステル
ジエタノールアミン塩5%処理した繊維(ポリエチレンテレフタレート
およびナイロンを特開平11−1829号公報に従い、交互に51層積層
したもの、0.05D、0.01mm)(赤色の干渉光を有する)
Example 3
W / O mascara:
W / O mascara was prepared by the following components and production method.
(Component) (%)
(1) Trimethylsiloxysilicic acid 20
(2) Decamethylcyclopentasiloxane 42.3
(3) Polyoxyethylene / methylpolysiloxane copolymer * 11 5
(4) Purified water 15
(5) Polypropylene fiber * 12 0.1
(6) Colored interference fiber * 13 1
(7) Titanium / titanium oxide sintered product 10
(8) Bengala-coated mica titanium 5
(9) Natural vitamin E 0.5
(10) Ethyl paraoxybenzoate 1
(11) Polyvinylpyrrolidone 0.1
* 11 KF-6017 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 12 10D, 3mm, untreated * 13 Perfluoroalkyl phosphate ester, colored with 0.1% red No. 106
Fiber treated with 5% diethanolamine salt (polyethylene terephthalate
51 layers of nylon and nylon alternately according to JP-A-11-1829
, 0.05D, 0.01 mm) (with red interference light)

(製造方法)
A.成分(1)〜(3)を混合し、成分(4)〜(11)を加えて均一に混合する。
B.Aを容器に充填して製品とする。
(Production method)
A. Components (1) to (3) are mixed, and components (4) to (11) are added and mixed uniformly.
B. A is filled into a container to obtain a product.

以上のようにして得られたマスカラは、外観の高彩度感、外観の光輝性、化粧膜の高彩度感、化粧膜の質感改良効果、の全ての点に優れ、使用性、化粧膜の均一性、化粧効果の持続性も良好なものであった。   The mascara obtained as described above is excellent in all points of high chroma of appearance, glitter of appearance, high chroma of cosmetic film, texture improvement effect of cosmetic film, usability, uniformity of cosmetic film, The durability of the makeup effect was also good.

実 施 例 4
水系マスカラ:
(成 分) (%)
(1)ヒドロキシプロピルセルロース 4
(2)精製水 34.9
(3)ジプロピレングリコール 2
(4)エタノール 40
(5)ポリビニルアルコール 0.5
(6)着色干渉繊維※13 15
(7)大豆リン脂質 0.1
(8)フェノキシエタノール 0.5
(9)硫酸バリウム※14 1
(10)シリル化処理無水ケイ酸※15 2
※14 5%シリカ処理
※15 AEROSIL R972(日本アエロジール社製)
Example 4
Aqueous mascara:
(Component) (%)
(1) Hydroxypropyl cellulose 4
(2) Purified water 34.9
(3) Dipropylene glycol 2
(4) Ethanol 40
(5) Polyvinyl alcohol 0.5
(6) Colored interference fiber * 13 15
(7) Soybean phospholipid 0.1
(8) Phenoxyethanol 0.5
(9) Barium sulfate * 14 1
(10) Silylated silica anhydride * 15 2
* 14 5% silica treatment * 15 AEROSIL R972 (manufactured by Nippon Aerology Co., Ltd.)

(製造方法)
A.成分(1)〜(5)を混合溶解し、成分(6)〜(10)を加えて均一に混合
する。
B.Aを容器に充填して製品とする。
(Production method)
A. Components (1) to (5) are mixed and dissolved, and components (6) to (10) are added and mixed uniformly.
B. A is filled into a container to obtain a product.

以上のようにして得られたマスカラは、外観の高彩度感、外観の光輝性、化粧膜の高彩度感、化粧膜の質感改良効果の全ての点に優れ、使用性、化粧膜の均一性、化粧効果の持続性も良好なものであった。   The mascara obtained as described above is excellent in all aspects such as high chroma of appearance, glitter of appearance, high chroma of cosmetic film, and texture improvement effect of cosmetic film, usability, uniformity of cosmetic film, makeup The sustainability of the effect was also good.

実 施 例 5
O/Wマスカラ:
着色干渉繊維※2を、下記の着色干渉繊維に代える以外は、実施例1の本発明品1と同様にしてO/Wマスカラを得た。
Example 5
O / W mascara:
An O / W mascara was obtained in the same manner as the inventive product 1 of Example 1 except that the colored interference fiber * 2 was replaced with the following colored interference fiber.

使用着色干渉繊維:
0.1%赤色202号で着色した繊維(ポリエチレンテレフタレートおよびナイロ
ンを特開平11−1829号公報に従い、ポリエチレンテレフタレート30層、
ナイロン31層で交互に61層積層した、断面が楕円形状のものを、2%のシリ
カで処理したもの。(9D(長軸70μm、短軸17μm)、2mm)(赤色の
干渉光を呈する)
Use colored interference fiber:
A fiber colored with 0.1% red 202 (polyethylene terephthalate and nylon according to JP-A-11-1829, 30 layers of polyethylene terephthalate,
61 layers of 31 nylon layers stacked alternately, with an elliptical cross section treated with 2% silica. (9D (major axis 70 μm, minor axis 17 μm), 2 mm) (presents red interference light)

以上のようにして得られたマスカラは、外観の高彩度感、外観の光輝性、化粧膜の高彩度感、化粧膜の質感改良効果の全ての点において極めて優れ、使用性、化粧膜の均一性、化粧効果の持続性においても優れたものであった。   The mascara obtained as described above is extremely excellent in all aspects of high chroma of appearance, glitter of appearance, high chroma of cosmetic film, and texture improvement effect of cosmetic film, usability, uniformity of cosmetic film, It was also excellent in the durability of the makeup effect.

本発明の睫用化粧料は、それ自体の外観や色調に高い彩度を付与することができ、また、使用部位である睫に光輝性を付与し、高い彩度を与えると共にその質感を光学的に変化させることにより、従来にない透明感や立体感を付与する効果等を発揮することができる優れたものである   The vase cosmetics of the present invention can impart high chroma to the appearance and color tone of the vase itself, and also to impart glaze to the vase that is the site of use, imparting high chroma and making the texture optical. It is an excellent one that can exhibit an effect of imparting a transparency and a three-dimensional feeling that have not been heretofore, by changing it periodically.

従って、市場のニーズを充分に満たす高い化粧効果を有し、しかも得られた化粧膜が、水や油になじみにくく、化粧効果の持続性の点でも満足のいく睫用化粧料として、利用することができるものである。   Therefore, it has a high cosmetic effect that fully satisfies the needs of the market, and the obtained cosmetic film is used as a vaginal cosmetic that is difficult to adapt to water and oil and is satisfactory in terms of the sustainability of the cosmetic effect. It is something that can be done.

Claims (5)

次の成分(A)および(B)
(A)赤色2号、赤色3号、赤色102号、赤色104号(1)、赤色105号(1)
、赤色106号、黄色4号、黄色5号、緑色3号、青色1号、青色2号、赤色201号
、赤色213号、赤色214号、赤色215号、赤色227号、赤色230号(1)
、赤色230号(2)、赤色231号、赤色232号、橙色205号、橙色207号
、黄色203号、緑色201号、緑色204号、緑色205号、青色202号、青色
203号、青色205号、かっ色201号、赤色401号、赤色502号、赤色50
3号、赤色504号、赤色506号、橙色402号、黄色402号、黄色403号(1
)、黄色406号、黄色407号、緑色401号、緑色402号、紫色401号および
黒色401よりなる群から選ばれた水溶性タール系色素で着色された、ナイロン、ポ
リエチレンテレフタレート、ポリプロピレン、ポリカーボネイト、ポリメチルメタク
リレートおよびポリエステルよりなる群から選ばれた屈折率の異なる2種類以上の
高分子化合物で構成される層が交互に積層した干渉繊維
(B)皮膜形成性成分
を含有することを特徴とする睫用化粧料。
The following components (A) and (B)
(A) Red No. 2, Red No. 3, Red No. 102, Red No. 104 (1), Red No. 105 (1)
, Red 106, Yellow 4, Yellow 5, Green 3, Blue 1, Blue 2, Red 201
Red 213, Red 214, Red 215, Red 227, Red 230 (1)
, Red 230 (2), Red 231, Red 232, Orange 205, Orange 207
, Yellow 203, Green 201, Green 204, Green 205, Blue 202, Blue
203, Blue 205, Brown 201, Red 401, Red 502, Red 50
No. 3, Red No. 504, Red No. 506, Orange No. 402, Yellow No. 402, Yellow No. 403 (1
), Yellow 406, yellow 407, green 401, green 402, purple 401 and
Nylon, colored with a water-soluble tar pigment selected from the group consisting of black 401
Reethylene terephthalate, polypropylene, polycarbonate, polymethyl methacrylate
The interference fiber (B) film-forming component in which layers composed of two or more kinds of polymer compounds having different refractive indexes selected from the group consisting of relate and polyester are alternately laminated . Cosmetics.
干渉繊維の長さが0.01mm以上5mm以下である請求項1に記載の睫用化粧料。   The vaginal cosmetic according to claim 1, wherein the length of the interference fiber is 0.01 mm or more and 5 mm or less. 干渉繊維の太さが0.01デニール以上20デニール以下である請求項1又は2のいずれかに記載の睫用化粧料。 The vaginal cosmetic according to claim 1 or 2 , wherein the thickness of the interference fiber is 0.01 denier or more and 20 denier or less. 皮膜形成性成分が、ロジン酸系樹脂、トリメチルシロキシケイ酸、アクリル変性シリコーンまたはキャンデリラレジンから選ばれる1種又は2種以上の油溶性樹脂である請求項1〜のいずれかに記載の睫用化粧料。 Film-forming component, a rosin acid resin, trimethylsiloxy silicic acid, eyelash according to any one of claims 1 to 3, one or more oil-soluble resin selected from acryl-modified silicone or candelilla Resin Cosmetics. 皮膜形成性成分が、アクリル酸エステルポリマーエマルション及び/又は酢酸ビニルポリマーエマルションである請求項1〜のいずれかに記載の睫用化粧料。

Film-forming component, eyelash cosmetic composition according to any one of claims 1 to 4, which is an ester polymer emulsion and / or vinyl acetate polymer emulsion acrylic.

JP2005098987A 2004-03-30 2005-03-30 Cosmetic for salmon Expired - Fee Related JP4866564B2 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4809177B2 (en) * 2006-09-29 2011-11-09 株式会社コーセー Cosmetics for eyelashes or eyebrows
JP2009040715A (en) * 2007-08-08 2009-02-26 Kose Corp Cosmetic for eyelashes
JP2009057308A (en) * 2007-08-31 2009-03-19 Shiseido Co Ltd Oily cosmetic
JP5213595B2 (en) * 2008-09-05 2013-06-19 株式会社コーセー Oily salmon cosmetic
JP5394168B2 (en) * 2009-08-27 2014-01-22 株式会社 資生堂 Mascara base cosmetic
FR2961396B1 (en) * 2010-06-16 2013-03-15 Oreal PROCESS FOR MAKE-UP OR CARE OF KERATIN FIBERS USING RETRACTABLE FIBERS AND USE THEREOF
JPWO2022092044A1 (en) * 2020-10-26 2022-05-05

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* Cited by examiner, † Cited by third party
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JP3409192B2 (en) * 1993-11-12 2003-05-26 株式会社コーセー Eye makeup cosmetics for eyelashes or eyebrows
JP3605938B2 (en) * 1996-03-29 2004-12-22 株式会社コーセー Eyelash cosmetics
US6430348B1 (en) * 1997-04-11 2002-08-06 Teijin Limited Fiber having optical interference function and use thereof
JPH10291917A (en) * 1997-04-17 1998-11-04 Kose Corp Cosmetic for eyelash
JP3672010B2 (en) * 1999-03-04 2005-07-13 株式会社コーセー Cosmetics for eyelashes or eyebrows
FR2816831B1 (en) * 2000-11-23 2002-12-27 Oreal COSMETIC COMPOSITION WITH LIPOPHILIC CONTINUOUS PHASE CONTAINING FIBERS
FR2816832B1 (en) * 2000-11-23 2003-09-26 Oreal COSMETIC COMPOSITION COMPRISING INTERFERENTIAL PARTICLES AND A COLORING MATERIAL
JP2005248369A (en) * 2004-03-04 2005-09-15 Teijin Fibers Ltd Composite fiber with optical interference coloring function with excellent aesthetics

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