JP4878735B2 - Flat cable - Google Patents
Flat cable Download PDFInfo
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- JP4878735B2 JP4878735B2 JP2004013760A JP2004013760A JP4878735B2 JP 4878735 B2 JP4878735 B2 JP 4878735B2 JP 2004013760 A JP2004013760 A JP 2004013760A JP 2004013760 A JP2004013760 A JP 2004013760A JP 4878735 B2 JP4878735 B2 JP 4878735B2
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- flat cable
- tin plating
- tin
- conductor
- flat
- Prior art date
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- Expired - Lifetime
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- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 39
- 238000007747 plating Methods 0.000 claims description 33
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 12
- 230000008018 melting Effects 0.000 claims description 8
- 238000002844 melting Methods 0.000 claims description 8
- 239000010949 copper Substances 0.000 claims description 6
- 229910052802 copper Inorganic materials 0.000 claims description 6
- 239000004020 conductor Substances 0.000 description 27
- 239000012790 adhesive layer Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000009713 electroplating Methods 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 230000037431 insertion Effects 0.000 description 3
- 238000003780 insertion Methods 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 230000035882 stress Effects 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000006355 external stress Effects 0.000 description 2
- 229910000765 intermetallic Inorganic materials 0.000 description 2
- 230000003014 reinforcing effect Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000009429 electrical wiring Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 150000002611 lead compounds Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
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- Insulated Conductors (AREA)
- Electroplating Methods And Accessories (AREA)
Description
本発明は、電気接続部分を有するフラットケーブルに関する。 The present invention relates to a flat cable having electrical connecting portion.
電子機器の小形化、軽量化に伴い、これらに搭載される電子部品、配線用部品等の小形化が進んでいる。特に、電気配線のための配線部材は、限られたスペースで高密度の配線が可能なものが要望されている。このような配線部材としては、可撓性の回路基板や平型導体を用いたフラットケーブル、また、これらの接続に用いられる電気コネクタ等がある。これらの配線部材は、多数の電気導体が高密度に配され互いに電気的に絶縁されると共に、良好な電気接続の保証が求められている。 As electronic devices become smaller and lighter, electronic components and wiring components mounted on these devices are becoming smaller. In particular, wiring members for electrical wiring are required to be capable of high-density wiring in a limited space. Examples of such wiring members include a flexible circuit board, a flat cable using a flat conductor, and an electrical connector used for connecting these. These wiring members are required to have a large number of electrical conductors arranged at high density and electrically insulated from each other and to ensure good electrical connection.
これらの配線部材の電気導体には、通常、導電率がよく、延性に富み、適度な強度を有し、他の金属によるコーティングが容易である銅が用いられる。この銅を用いた配線部材には、一般に、耐腐食性、半田付け性を目的として錫メッキが施されている。錫メッキは、通常、電気メッキにより形成されるが、この電気錫メッキの表面に針状結晶体(以下、ホイスカという)が発生することが知られている。 For the electrical conductors of these wiring members, copper is usually used which has good electrical conductivity, is rich in ductility, has an appropriate strength, and can be easily coated with other metals. The wiring member using copper is generally tin-plated for the purpose of corrosion resistance and solderability. Tin plating is usually formed by electroplating, and it is known that acicular crystals (hereinafter referred to as whiskers) are generated on the surface of the electrotin plating.
特に、銅系の金属材料に錫メッキをすると、銅原子が錫メッキ膜中に拡散して、銅−錫金属間化合物を作る。この金属間化合物は、錫と結晶構造が異なり、格子間距離に歪ができるため、錫メッキ膜中に圧縮応力が生じる。この圧縮応力がホイスカ成長の駆動力となるので、銅系材料上に錫メッキを施した場合は、ホイスカが発生しやすいとも言われている。このホイスカは、導体間を電気的に短絡する原因となるため、今までに種々の改善策が提案されている。 In particular, when tin plating is performed on a copper-based metal material, copper atoms diffuse into the tin plating film to form a copper-tin intermetallic compound. Since this intermetallic compound has a crystal structure different from that of tin and can be distorted in the interstitial distance, compressive stress is generated in the tin plating film. Since this compressive stress is a driving force for whisker growth, it is said that whisker is likely to occur when tin plating is applied to a copper-based material. Since this whisker causes electrical short-circuiting between conductors, various improvement measures have been proposed so far.
例えば、特許文献1には、長径/短径の比が3以上の結晶粒を有する錫メッキを施した平型導体が開示され、特許文献2には、導体表面に錫メッキを施し232℃〜350℃の温度で0.5秒〜3秒熱処理することが開示されている。また、この他に、錫メッキの厚さが小さい方がホイスカを発生しやすいこと、錫に微量の鉛を添加することによりホイスカ発生を抑制できること、等についても良く知られている。
錫メッキに鉛を添加することでホイスカ発生を抑制することはよく知られているが、鉛化合物には毒性があるため、環境対策の問題から好ましくなく、最近は、鉛を添加しない鉛フリーの配線部材が要望されている。電気接続部分に鉛フリーの錫メッキを施し、例えば、特許文献2に開示のように錫メッキを熱処理することにより、ある程度はホイスカの発生を抑制することは可能である。しかし、挿抜タイプの電気コネクタを用いた接点部分で、特異的にホイスカが発生しやすくなることがわかり、この部分でホイスカのショートによる不具合が生じている。これは、電気コネクタの接触片によって錫メッキの表面に外部応力を受けることに起因するものと思われる。
It is well known that whisker generation can be suppressed by adding lead to tin plating. However, lead compounds are toxic and are not preferred due to environmental problems. A wiring member is desired. It is possible to suppress the generation of whiskers to some extent by applying lead-free tin plating to the electrical connection portion and, for example, heat-treating the tin plating as disclosed in
本発明は上述した実情に鑑みてなされたもので、鉛フリーの錫メッキを施したフラットケーブルにおいて、電気コネクタの接触片による圧接等の外部応力を受ける部分でのホイスカの発生が防止されたフラットケーブルの提供を課題とする。 But the present invention has been made in view of the above, Oite flat cable subjected to tin plating lead-free, the occurrence of whiskers at a portion receiving external stress pressure due contact piece of an electrical connector anti The problem is to provide a flat cable .
本発明によるフラットケーブルは、フラットケーブルの少なくとも電気コネクタ接触片の圧接応力を受ける銅系の電気接続部分に、厚さ0.5μm以上1.0μm未満の錫メッキを施し、この錫メッキを錫の融点以上に加熱して再結晶化されていることを特徴とする。 In the flat cable according to the present invention, tin plating having a thickness of 0.5 μm or more and less than 1.0 μm is applied to at least a copper-based electrical connection portion that receives pressure stress of an electrical connector contact piece of the flat cable . It is characterized by being recrystallized by heating above its melting point.
メッキ厚さ1.0μm未満の極めて薄い錫メッキを施した場合、ホイスカが発生しやすいと言われているが、本発明の如く、錫メッキを錫の融点以上に加熱して再結晶化することにより、ホイスカの発生を抑制することができる。この結果、鉛フリーの薄い錫メッキが施された信頼性に優れたフラットケーブルを得ることができ、また、挿抜型の高密度コネクタで短絡事故発生を防止することができる。 It is said that whisker is likely to occur when an extremely thin tin plating with a plating thickness of less than 1.0 μm is applied. However, as in the present invention, the tin plating is heated above the melting point of tin and recrystallized. Thereby, generation | occurrence | production of a whisker can be suppressed. As a result, it is possible to obtain a flat cable excellent in reliability on which lead-free thin tin plating is applied, and it is possible to prevent occurrence of a short-circuit accident with an insertion / extraction type high-density connector.
図により本発明の実施の形態を説明する。図1は複数本の平型導体からなるフラットケーブルの例を示し、図1(A)はその正面図、図1(B)はその側面図、図1(C)は電気コネクタへの接続例を示す図である。図中、1は電気導体、1aは電気接続部分、2は絶縁被覆、2a,2bは絶縁フィルム、2cは接着剤層、3は補強板、4はフラットケーブル、5は弾性接触片、6は電気コネクタを示す。 Embodiments of the present invention will be described with reference to the drawings. FIG. 1 shows an example of a flat cable composed of a plurality of flat conductors, FIG. 1 (A) is a front view thereof, FIG. 1 (B) is a side view thereof, and FIG. 1 (C) is an example of connection to an electrical connector. FIG. In the figure, 1 is an electrical conductor, 1a is an electrical connection part, 2 is an insulation coating, 2a and 2b are insulation films, 2c is an adhesive layer, 3 is a reinforcing plate, 4 is a flat cable, 5 is an elastic contact piece, 6 is An electrical connector is shown.
本発明は、例えば、図1に示すような平型導体からなる多数の電気導体1を高密度配列で絶縁フィルム2a,2bで挟み、接着剤層2cで接着一体化してなるフラットケーブルを対象とする。フラットケーブル4の電気導体1は、例えば、丸銅線に電気メッキによる錫メッキを施した後、延伸、圧延して、錫メッキ厚が0.5μm〜1.0μm未満の電気導体1とされる。
The present invention is, for example, subject the
圧延された平型の電気導体1には、例えば、導体に電流を流すことにより錫の融点(232℃)以上となるように加熱処理することにより、錫メッキを再結晶化する。この加熱処理された複数本の電気導体1は、所定の間隔で電気的に絶縁された状態に並べて、絶縁フィルム2aと2bの間に挟み、電気絶縁性の接着剤層2cで接着一体化して、絶縁被覆2で被覆されたフラットケーブル4とされる。
The rolled flat electrical conductor 1 is recrystallized by, for example, heat-treating the conductor to a melting point of tin (232 ° C.) or higher by passing an electric current through the conductor. The plurality of heat-treated electric conductors 1 are arranged in an electrically insulated state at a predetermined interval, sandwiched between
フラットケーブル4の少なくとも一方の端部は、電気接続部分1aとして、例えば、挿抜型の電気コネクタ6との接続が容易な形状とされる。このため、フラットケーブル4の端部において、ケーブル端部の一方の絶縁フィルム2b側を除去して電気導体1の表面を露出させ、他方の絶縁フィルム2a側の外側に補強板3を接着して、端部の強度と硬直度を高める。このように形成された、電気接続部分1aは、図1(C)に示すように、電気コネクタ6に高密度で配設されている弾性接触片5内に挿入され、その弾性により圧接されて電気接続が形成される。
At least one end of the
本発明の実施例として、丸銅線に電気メッキで錫メッキを施した後、この丸銅線を伸線、圧延して、幅0.3mm、厚さ35μm、錫メッキ厚さ0.9μmの平型導体を作製した。この平型導体に電流を流して錫の融点以上に加熱し、錫メッキを再結晶化させた。この平型導体を用いて導体間ピッチを0.5mm(導体間の間隙は0.2mmとなる)として、図1(A),(B)に示すようなフラットケーブルを作製した。このフラットケーブルの電気接続部分を、図1(C)に示すような鉛フリーの電気コネクタに挿入し、室温(22℃)で120時間放置した後、ホイスカ発生の有無を観察した。接点部分の70個所を電子顕微鏡にて観察したが、ホイスカが発生している個所はなかった。 As an example of the present invention, after applying tin plating to a round copper wire by electroplating, this round copper wire was drawn and rolled to obtain a width of 0.3 mm, a thickness of 35 μm, and a tin plating thickness of 0.9 μm. A flat conductor was produced. An electric current was passed through the flat conductor and heated above the melting point of tin to recrystallize the tin plating. Using this flat conductor, a flat cable as shown in FIGS. 1A and 1B was produced with an inter-conductor pitch of 0.5 mm (a gap between the conductors was 0.2 mm). The electrical connection portion of the flat cable was inserted into a lead-free electrical connector as shown in FIG. 1C and left at room temperature (22 ° C.) for 120 hours, and then the occurrence of whiskers was observed. Although 70 points of the contact portion were observed with an electron microscope, there were no places where whiskers were generated.
また、本発明の比較例として、実施例と同様に丸銅線に電気メッキで錫メッキを施した後、この丸銅線を伸線、圧延して幅0.3mm、厚さ35μmの平型導体を作製した。但し、錫メッキ厚さを2.5μmとした。そして、実施例と同様に平型導体に電流を流して錫の融点以上に加熱し、錫メッキを再結晶化させた。この平型導体を用いて導体間ピッチを0.5mm(導体間の間隙は0.2mmとなる)として、図1(A),(B)に示すようなフラットケーブルを作製した。このフラットケーブルの電気接続部分を、図1(C)に示すような鉛フリーの電気コネクタに挿入し、室温(22℃)で120時間放置した後、ホイスカ発生の有無を観察した。接点部分の70個所を電子顕微鏡にて観察したが、3箇所において、長さ20μmのホイスカが発生していた。 As a comparative example of the present invention, a round copper wire was electroplated and tin-plated in the same manner as in the examples, and then this round copper wire was drawn and rolled to obtain a flat type having a width of 0.3 mm and a thickness of 35 μm. A conductor was produced. However, the tin plating thickness was 2.5 μm. Then, in the same manner as in the example, an electric current was passed through the flat conductor and heated above the melting point of tin to recrystallize the tin plating. Using this flat conductor, a flat cable as shown in FIGS. 1A and 1B was produced with an inter-conductor pitch of 0.5 mm (a gap between the conductors was 0.2 mm). The electrical connection portion of the flat cable was inserted into a lead-free electrical connector as shown in FIG. 1C and left at room temperature (22 ° C.) for 120 hours, and then the occurrence of whiskers was observed. Although 70 points of the contact portion were observed with an electron microscope, whiskers having a length of 20 μm were generated at three points.
以上の結果から、メッキ厚さ1.0μm未満の極めて薄い錫メッキを施した場合、錫メッキを錫の融点以上に加熱して再結晶化することにより、ホイスカの発生を抑制することができた。なお、錫メッキの厚さが1μm以上であると、錫メッキを錫の融点以上に加熱して再結晶化しても、ホイスカの発生を完全には抑制することはできないことも判明した。また、0.5μm未満の薄い厚さの錫メッキでは、メッキがされない部分が生じる可能性があり、半田濡れ性や耐食性が損なわれる恐れがある。 From the above results, when an extremely thin tin plating having a plating thickness of less than 1.0 μm was applied, the generation of whiskers could be suppressed by heating the tin plating to a temperature higher than the melting point of tin and recrystallization. . It has also been found that if the thickness of the tin plating is 1 μm or more, whisker generation cannot be completely suppressed even if the tin plating is heated above the melting point of tin and recrystallized. Further, in the case of tin plating with a thin thickness of less than 0.5 μm, there is a possibility that an unplated portion may occur, and solder wettability and corrosion resistance may be impaired.
1…電気導体、1a…電気接続部分、2…絶縁被覆、2a,2b…絶縁フィルム、2c…接着剤層、3…補強板、4…フラットケーブル、5…弾性接触片、6…電気コネクタ。 DESCRIPTION OF SYMBOLS 1 ... Electric conductor, 1a ... Electrical connection part, 2 ... Insulation coating, 2a, 2b ... Insulating film, 2c ... Adhesive layer, 3 ... Reinforcement plate, 4 ... Flat cable, 5 ... Elastic contact piece, 6 ... Electrical connector.
Claims (1)
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004013760A JP4878735B2 (en) | 2004-01-22 | 2004-01-22 | Flat cable |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004013760A JP4878735B2 (en) | 2004-01-22 | 2004-01-22 | Flat cable |
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| Publication Number | Publication Date |
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| JP2005206869A JP2005206869A (en) | 2005-08-04 |
| JP4878735B2 true JP4878735B2 (en) | 2012-02-15 |
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| JP2004013760A Expired - Lifetime JP4878735B2 (en) | 2004-01-22 | 2004-01-22 | Flat cable |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP5119591B2 (en) * | 2005-12-05 | 2013-01-16 | 住友電気工業株式会社 | Flat cable manufacturing method |
| JP4904953B2 (en) | 2006-04-06 | 2012-03-28 | 日立電線株式会社 | WIRING CONDUCTOR, MANUFACTURING METHOD THEREOF, TERMINAL CONNECTION UNIT AND Pb FREE SOLDER ALLOY |
| JP4856745B2 (en) * | 2006-10-17 | 2012-01-18 | 日立電線株式会社 | Conductor for flexible substrate, method for producing the same, and flexible substrate |
| US8907226B2 (en) | 2008-03-11 | 2014-12-09 | Hitachi Metals, Ltd. | Conductor for flexible substrate and fabrication method of same, and flexible substrate using same |
| DE102015004651B4 (en) * | 2015-04-15 | 2018-09-27 | Diehl Metal Applications Gmbh | Method for coating a component and use of the method |
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| JPS5299934A (en) * | 1976-02-17 | 1977-08-22 | Mitsubishi Heavy Ind Ltd | Method of treating plated layer |
| JPS61266597A (en) * | 1985-05-22 | 1986-11-26 | Mitsubishi Electric Corp | Film treatment of copper alloy rod for contactor |
| JPH02173294A (en) * | 1988-12-26 | 1990-07-04 | Nippon Mining Co Ltd | Reflow treatment of tin or tin alloy plated material |
| JP2693347B2 (en) * | 1992-10-02 | 1997-12-24 | 日立電線加工株式会社 | A flat cable with a connector connection terminal disconnection prevention structure |
| JP2942458B2 (en) * | 1993-04-16 | 1999-08-30 | 住友電気工業株式会社 | Manufacturing method and manufacturing equipment for conductor for flat cable |
| JP2975246B2 (en) * | 1993-12-08 | 1999-11-10 | 古河電気工業株式会社 | Sn-plated wire for electrical contact and method of manufacturing the same |
| JP3378717B2 (en) * | 1995-01-19 | 2003-02-17 | 古河電気工業株式会社 | Method for manufacturing reflow plated member |
| JP3582549B2 (en) * | 1996-03-01 | 2004-10-27 | 住友電気工業株式会社 | Flat cable |
| JPH1145621A (en) * | 1997-07-28 | 1999-02-16 | Canon Inc | Flexible flat cable and electronic equipment using the flexible flat cable |
| JP4269374B2 (en) * | 1998-12-09 | 2009-05-27 | 住友電気工業株式会社 | Tin-plated flat conductor manufacturing method and flat cable manufacturing method |
| JP4489232B2 (en) * | 1999-06-14 | 2010-06-23 | 日鉱金属株式会社 | Plating material for connectors |
| JP2001043744A (en) * | 1999-07-29 | 2001-02-16 | Totoku Electric Co Ltd | Flat cable |
| JP2001043743A (en) * | 1999-07-29 | 2001-02-16 | Totoku Electric Co Ltd | Flat cable |
| JP2001073186A (en) * | 1999-08-31 | 2001-03-21 | Fujikura Ltd | Method of manufacturing wiring component laminated with insulating film |
| JP2001181888A (en) * | 1999-12-17 | 2001-07-03 | Nippon Mining & Metals Co Ltd | Plating material for connectors |
| JP2002175727A (en) * | 2000-12-08 | 2002-06-21 | Auto Network Gijutsu Kenkyusho:Kk | Flat cable |
| JP2003086024A (en) * | 2001-09-13 | 2003-03-20 | Hitachi Cable Ltd | Sn-based plated rectangular conductor and flat cable using the same |
| JP3878057B2 (en) * | 2002-05-23 | 2007-02-07 | 冨士電子工業株式会社 | Striped plating strip and striped plating method |
| JP2005048205A (en) * | 2003-07-29 | 2005-02-24 | Fujikura Ltd | Heat treatment method for electroplating terminal parts and connector fitting parts such as flexible flat cables and flexible printed circuit boards |
| JP2005056605A (en) * | 2003-08-06 | 2005-03-03 | Molex Japan Co Ltd | Connector, cable connected to connector or wiring board |
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2004
- 2004-01-22 JP JP2004013760A patent/JP4878735B2/en not_active Expired - Lifetime
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| JP2005206869A (en) | 2005-08-04 |
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