Deprecated: The each() function is deprecated. This message will be suppressed on further calls in /home/zhenxiangba/zhenxiangba.com/public_html/phproxy-improved-master/index.php on line 456
JP4881580B2 - Electrolyzed water generator - Google Patents
[go: Go Back, main page]

JP4881580B2 - Electrolyzed water generator - Google Patents

Electrolyzed water generator Download PDF

Info

Publication number
JP4881580B2
JP4881580B2 JP2005167929A JP2005167929A JP4881580B2 JP 4881580 B2 JP4881580 B2 JP 4881580B2 JP 2005167929 A JP2005167929 A JP 2005167929A JP 2005167929 A JP2005167929 A JP 2005167929A JP 4881580 B2 JP4881580 B2 JP 4881580B2
Authority
JP
Japan
Prior art keywords
water
electrolyzed water
electrolyzed
storage tank
water level
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2005167929A
Other languages
Japanese (ja)
Other versions
JP2006341169A (en
Inventor
義之 鵜飼
浩司 土川
美俊 清水
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoshizaki Electric Co Ltd
Original Assignee
Hoshizaki Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoshizaki Electric Co Ltd filed Critical Hoshizaki Electric Co Ltd
Priority to JP2005167929A priority Critical patent/JP4881580B2/en
Publication of JP2006341169A publication Critical patent/JP2006341169A/en
Application granted granted Critical
Publication of JP4881580B2 publication Critical patent/JP4881580B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Landscapes

  • Water Treatment By Electricity Or Magnetism (AREA)

Description

本発明は、被電解水を電解して、電解生成水を生成するための電解水生成装置に関する。   The present invention relates to an electrolyzed water generating apparatus for electrolyzing electrolyzed water to generate electrolyzed water.

電解水生成装置の一形式として、被電解水を電解する電解槽と、前記電解槽にて生成される電解生成水を受け入れて貯留する貯留タンクと、前記貯留タンク内に配設されて同貯留タンク内に収容されている電解生成水の予め設定された所定容量の水位(設定水位)を検出する水位センサを備え、前記貯留タンク内に収容されている電解生成水の水位が前記設定水位より低下したことを前記水位センサが検出したとき電解生成水の生成運転が再開されて、前記貯留タンク内に電解生成水が補給される電解運転方式を採る電解水生成装置がある(特許文献1を参照)。 As one type of electrolyzed water generating device, an electrolyzer that electrolyzes electrolyzed water, a storage tank that receives and stores electrolyzed water generated in the electrolyzer, and a storage tank disposed in the storage tank. A water level sensor for detecting a predetermined level of preset water volume (set water level) stored in the tank, and the level of the electrolyzed water stored in the storage tank is greater than the set water level; There is an electrolyzed water generating device that employs an electrolysis operation system in which electrolyzed water generation operation is resumed when the water level sensor detects a decrease , and electrolyzed water is replenished in the storage tank (see Patent Document 1). reference).

当該形式の電解水生成装置においては、電解生成水の生成運転にて生成された電解生成水は貯留タンク内に順次導入されて収容されるが、貯留タンク内に収容されている電解生成水の水位が設定水位に達したときには、水位センサが、貯留タンク内の電解生成水の水位が設定水位に達したことを検出して、電解生成水の生成運転を停止すべく機能する。すなわち、当該形式の電解水生成装置における電解生成水の生成運転の停止および再開は、水位センサの動作点水位での動作(ON,OFF動作)によって制御される。
特開2000−5750号公報
In the electrolyzed water generating apparatus of this type, the electrolyzed water generated in the electrolyzed water generating operation is sequentially introduced and stored in the storage tank, but the electrolyzed water stored in the storage tank When the water level reaches the set water level, the water level sensor functions to detect that the level of the electrolyzed water in the storage tank has reached the set water level and stop the electrolyzed water generation operation. That is, the stop and restart of the electrolyzed water generation operation in the electrolyzed water generator of this type are controlled by the operation at the operating point water level (ON / OFF operation) of the water level sensor.
JP 2000-5750 A

ところで、当該形式の電解水生成装置においては、貯留タンク内に収容されている電解生成水は、ユーザが貯留タンク内から所望量注出して消費されるが、この際、貯留タンク内に収容されている電解生成水の水位は一気に低下することから、電解生成水の生成運転が直ちに再開される。これにより、貯留タンク内には、生成される電解生成水が順次導入される結果、貯留タンク内に収容されている電解生成水の水位は漸次上昇し、設定水位に達した時点で、電解生成水の生成運転が停止されることになる。この場合、貯留タンク内の電解生成水の水位は水位センサの動作点付近にあり、電解生成水の水位が少しでも上下に変動すると水位センサは動作(ON,OFF動作)を繰り返すことになって、電解生成水の生成運転が短い時間に繰り返し行われることになる。   By the way, in the electrolyzed water generating device of this type, the electrolyzed water stored in the storage tank is consumed by the user by dispensing a desired amount from the storage tank. At this time, the electrolytic water is stored in the storage tank. Since the water level of the electrolytically generated water drops at a stretch, the electrolytically generated water generating operation is immediately resumed. As a result, the generated electrolyzed water is sequentially introduced into the storage tank. As a result, the water level of the electrolyzed water stored in the storage tank gradually rises and reaches the set water level. The water generation operation will be stopped. In this case, the electrolyzed water level in the storage tank is near the operating point of the water level sensor, and if the electrolyzed water level fluctuates up and down even slightly, the water level sensor repeats the operation (ON / OFF operation). In addition, the generation operation of electrolytically generated water is repeatedly performed in a short time.

当該形式の電解水生成装置の電解運転においては、電解生成水の生成初期にあっては、設定された特性より低い品質の電解生成水が生成され、時間の経過とともに設定された特性の品質の電解生成水となる。このため、電解生成水の生成運転が短時間に繰り返し行われる場合には、設定された特性より品質の低い電解生成水が多く補給されることになり、この結果、貯留タンク内に貯留されている電解生成水は、設定された十分な特性の電解生成水でなくなるおそれがある。本発明の目的は、このような問題に対処することにある。   In the electrolysis operation of the electrolyzed water generating device of this type, in the initial generation of the electrolyzed water, electrolyzed water having a quality lower than the set characteristic is generated, and the quality of the set characteristic is increased over time. It becomes electrolyzed water. For this reason, when the electrolyzed water generation operation is repeatedly performed in a short time, a large amount of electrolyzed water having a lower quality than the set characteristics is replenished, and as a result, the electrolyzed water is stored in the storage tank. There is a possibility that the electrolytically generated water that is set is not the electrolytically generated water having sufficient characteristics. The object of the present invention is to address such problems.

本発明は、電解水生成装置に関する。本発明が適用対象とする電解水生成装置は、被電解水を電解する電解槽と、前記電解槽にて生成される電解生成水を受け入れて収容する貯留タンクと、前記貯留タンク内に配設されて同貯留タンク内に収容されている電解生成水の予め設定された所定容量の水位(設定水位)を検出する水位センサを備え、前記貯留タンク内に収容されている電解生成水の水位が前記設定水位より低下したことを前記水位センサが検出したとき電解生成水の生成運転が再開されて、前記貯留タンク内に電解生成水が補給される電解運転方式を採る形式の電解水生成装置である。 The present invention relates to an electrolyzed water generating apparatus. An electrolyzed water generating apparatus to which the present invention is applied includes an electrolyzer that electrolyzes water to be electrolyzed, a storage tank that receives and stores electrolyzed water generated in the electrolyzer, and is disposed in the storage tank. And a water level sensor that detects a predetermined level of preset water volume (set water level) of the electrolyzed water stored in the storage tank, and the level of the electrolyzed water stored in the storage tank is When the water level sensor detects that the water level has fallen below the set water level, the electrolyzed water generation operation is resumed, and the electrolyzed water generating device adopts an electrolysis operation system in which the electrolyzed water is replenished in the storage tank. is there.

しかして、本発明に係る電解水生成装置においては、前記貯留タンク内の電解生成水が前記設定水位より低下したときに再開される電解生成水の生成運転は、前記貯留タンク内の電解生成水の水位が前記設定水位に達したことを前記水位センサが検出し、かつ、電解運転開始初期に生成される不安定な特性の電解生成水に比較して安定した特性の電解生成水の割合が十分に多くなるように予め設定された時間(設定時間)が経過するまで継続されることを特徴とするものである。 Therefore, in the electrolyzed water generating apparatus according to the present invention, the electrolyzed water generating operation resumed when the electrolyzed water in the storage tank is lowered from the set water level is the electrolyzed water in the storage tank. The water level sensor detects that the water level of the water has reached the set water level, and the ratio of the electrolytically generated water having stable characteristics compared to the electrolytically generated water having unstable characteristics generated at the beginning of the electrolysis operation is This is characterized in that the process is continued until a preset time (set time ) has passed so as to increase sufficiently.

本発明に係る電解水生成装置においては、前記貯留タンク内に配設される水位センサとして、電解生成水の設定水位で動作するフロートスイッチを採用することができ、また、再開される電解生成水の生成運転の前記設定時間を、電解運転開始初期の不安定な特性の電解生成水が生成される時間に対して5倍以上の時間とすることができる。また、本発明に係る電解水生成装置においては、電解生成水の生成運転中に電源からの電力の供給が一旦停止されて電解生成水の生成運転が一旦停止した場合には、その後に電力の供給が復帰した際には、一旦停止した電解生成水の生成運転は復帰させるようにすることができる。   In the electrolyzed water generating apparatus according to the present invention, a float switch that operates at a set water level of electrolyzed water can be employed as the water level sensor disposed in the storage tank, and the electrolyzed water that is resumed. The set time of the generating operation can be set to five times or more of the time during which electrolyzed water having unstable characteristics at the beginning of the electrolysis operation is generated. Further, in the electrolyzed water generating apparatus according to the present invention, when the supply of power from the power source is temporarily stopped during the electrolyzed water generating operation and the electrolyzed water generating operation is temporarily stopped, the power When the supply is restored, the production operation of electrolyzed water once stopped can be restored.

所望の場所に設置されている当該形式の電解水生成装置は、電源が投入されてユーザが使用し得る状態にあり、また、貯留タンク内には、設定された所定量の電解生成水が収容されている。このため、ユーザは所望量の電解生成水を採取すべく、電解生成水の注出操作(例えばスイッチ操作)を行うと、貯留タンク内に収容されている電解生成水は順次注出され、この際、貯留タンク内の電解生成水の水位は一気に低下する。このため、貯留タンク内に配設されている水位センサは、貯留タンク内の電解生成水の水位が設定水位より低下したことを検出して、電解生成水の生成運転を再開すべく機能し、電解生成水の生成運転が直ちに再開される。これにより、貯留タンク内には、生成される電解生成水が順次導入されて補給される結果、貯留タンク内に収容されている電解生成水の水位は漸次上昇し、設定水位に達すると、電解生成水の生成運転が停止されることになる。   The electrolyzed water generating device of this type installed at a desired location is in a state that can be used by the user when the power is turned on, and a predetermined amount of electrolyzed water is stored in the storage tank. Has been. For this reason, when the user performs an operation for pouring electrolyzed water (for example, a switch operation) in order to collect a desired amount of electrolyzed water, the electrolyzed water contained in the storage tank is sequentially poured out. At this time, the water level of the electrolyzed water in the storage tank drops at a stretch. For this reason, the water level sensor arranged in the storage tank detects that the electrolytic water level in the storage tank has dropped below the set water level, and functions to restart the electrolytic water generation operation. The production operation of electrolyzed water is immediately resumed. As a result, the generated electrolyzed water is sequentially introduced into the storage tank and replenished. As a result, the level of the electrolyzed water stored in the storage tank gradually rises and reaches the set water level. The generation operation of generated water will be stopped.

この場合、貯留タンク内の電解生成水の水位は水位センサの動作点付近にあり、電解生成水の水位が少しでも上下に変動すると水位センサは動作(ON,OFF動作)を繰り返すことになって、電解生成水の生成運転が短い時間に繰り返し行われることになる。しかしながら、本発明に係る電解水生成装置においては、貯留タンク内の電解生成水が設定水位より低下したときに再開される電解生成水の生成運転を、貯留タンク内の電解生成水の水位を前記水位センサが検出し、かつ、電解運転開始初期に生成される不安定な特性の電解生成水に比較して安定した特性の電解生成水の割合が十分多くなるように設定された設定時間が経過するまで継続させるようにしている。   In this case, the electrolyzed water level in the storage tank is near the operating point of the water level sensor, and if the electrolyzed water level fluctuates up and down even slightly, the water level sensor repeats the operation (ON / OFF operation). In addition, the generation operation of electrolytically generated water is repeatedly performed in a short time. However, in the electrolyzed water generating apparatus according to the present invention, the electrolyzed water generation operation resumed when the electrolyzed water in the storage tank drops below the set water level, and the level of the electrolyzed water in the storage tank is The set time has elapsed so that the ratio of electrolyzed water with stable characteristics is sufficiently high compared to the electrolyzed water with unstable characteristics that is detected by the water level sensor and generated at the beginning of electrolysis operation. I try to continue until.

換言すれば、本発明に係る電解水生成装置では、再開される電解生成水の生成運転を、所定時間継続するように設定し、当該設定時間を、電解運転開始初期に生成される不安定な特性の電解生成水に比較して安定した特性の電解生成水の割合が十分多くなる時間としている。このため、貯留タンク内における電解生成水の水位の頻繁な変動に起因する、短時間における繰り返しの電解生成水の生成運転を防止することができる。これにより、一度の再開運転にて貯留タンクに補給される電解生成水では、安定した特性の電解生成水の割合が十分に多くなり、このため、貯留タンク内に貯留されている電解生成水は、設定された十分な特性の電解生成水となる。   In other words, in the electrolyzed water generating apparatus according to the present invention, the restarted electrolyzed water generation operation is set to continue for a predetermined time, and the set time is unstable generated at the beginning of electrolysis operation. It is set as the time when the ratio of the electrolytically generated water having the stable characteristics is sufficiently larger than the electrolytically generated water having the characteristics. For this reason, it is possible to prevent repeated generation of electrolyzed water in a short time due to frequent fluctuations in the level of electrolyzed water in the storage tank. As a result, in the electrolytically generated water that is replenished to the storage tank by a single restart operation, the proportion of the electrolytically generated water having a stable characteristic is sufficiently increased. Therefore, the electrolytically generated water stored in the storage tank is It becomes the electrolytically generated water with sufficient characteristics set.

また、従来のこの種形式の電解水生成装置においては、電解生成水の生成運転中に例えば停電等により、電源からの電力の供給が一旦停止された場合、停電の解除等により、電解水生成装置に対する電力の供給が復帰しても、電解生成水の生成運転の指令がない限り、電解生成水の生成運転の復帰はあり得ない。これに対して、本発明に係る電解水生成装置においては、停電等による電力の供給の停止により途中で停止された電解生成水の生成運転を、停電の解除等による電力の供給の復帰時に合わせて復帰させるようにしている。このため、当該電解水生成装置によれば、ユーザや保守管理者による電解生成水の生成運転の再開操作を要することなく、電解生成水の生成運転を再開して貯留タンク内への補給を行い、貯留タンク内の電解生成水を所定量確保することができる。   In addition, in the conventional electrolyzed water generating device of this type, when the supply of power from the power source is temporarily stopped due to, for example, a power failure during the electrolyzed water generating operation, the electrolyzed water is generated by releasing the power failure. Even if the supply of electric power to the apparatus is restored, the operation of generating electrolyzed water cannot be restored unless there is a command for the operation of generating electrolyzed water. On the other hand, in the electrolyzed water generating apparatus according to the present invention, the operation of generating electrolyzed water that has been stopped halfway due to the stoppage of power supply due to a power failure or the like is matched with the return of power supply due to the cancellation of power failure or the like To return. For this reason, according to the electrolyzed water generating apparatus, the electrolyzed water generation operation is restarted and replenished into the storage tank without requiring the user or the maintenance manager to restart the electrolyzed water generating operation. A predetermined amount of electrolytically generated water in the storage tank can be secured.

本発明は、被電解水を電解する電解槽と、電解槽にて生成された電解生成水を受け入れて収容する貯留タンクと、貯留タンク内に配設されて貯留タンク内に収容されている電解生成水の予め設定された所定容量の水位(設定水位)を検出する水位センサを備え、貯留タンク内に収容されている電解生成水の水位が設定水位より低下したことを水位センサが検出したとき電解生成水の生成運転が再開されて、貯留タンク内に電解生成水が補給される電解運転方式を採る形式の電解水生成装置である。図1には、本発明の一実施形態に係る電解水生成装置を模式的に示している。当該電解水生成装置は、有隔膜電解槽10a、貯留タンク10b、濃塩水タンク10c、および、これらを連結する水系回路20aを備えるとともに、図2に示す制御装置20bを備えている。制御装置20bは、当該電解水生成装置の電解運転を制御する。 The present invention relates to an electrolytic tank for electrolyzing water to be electrolyzed, a storage tank for receiving and storing electrolytically generated water generated in the electrolytic tank, and an electrolysis provided in the storage tank disposed in the storage tank. When the water level sensor detects that the water level of the electrolytically generated water stored in the storage tank is lower than the set water level, provided with a water level sensor that detects a preset water level (set water level) of the generated water. This is an electrolyzed water generating device that employs an electrolysis operation system in which the electrolyzed water generation operation is restarted and the electrolyzed water is replenished in the storage tank . In FIG. 1, the electrolyzed water generating apparatus which concerns on one Embodiment of this invention is shown typically. The electrolyzed water generating apparatus includes a diaphragm electrolyzer 10a, a storage tank 10b, a concentrated salt water tank 10c, and an aqueous circuit 20a connecting them, and a control device 20b shown in FIG. The control device 20b controls the electrolysis operation of the electrolyzed water generating device.

有隔膜電解槽10aは、槽本体11と、槽本体11内を2つの区画室に区画するイオン透過性の隔膜12と、各区画室に配設されて各区画室を各電解室R1,R2に形成する一対の電極13a,13bからなる。各電極13a,13bは、DC電源13cに接続されていて、各電極13a,13bには、制御装置20bにより、所定圧の電圧が印加されるように構成されている。また、電解運転時の電解電流については、制御装置20bは、電流センサ13dから出力される検出信号に基づいて、設定された一定電流になるように制御する。   The diaphragm electrolyzer 10a includes a tank body 11, an ion-permeable diaphragm 12 that divides the tank body 11 into two compartments, and each compartment is formed in each electrolytic chamber R1, R2. It consists of a pair of electrodes 13a and 13b. Each electrode 13a, 13b is connected to a DC power source 13c, and a voltage of a predetermined pressure is applied to each electrode 13a, 13b by the control device 20b. Moreover, about the electrolysis current at the time of electrolysis operation, the control apparatus 20b controls so that it may become the set constant current based on the detection signal output from the current sensor 13d.

貯留タンク10bは、有隔膜電解槽10aの電解室R1で生成された電解生成水を受け入れて収容するもので、電解生成水を貯留するタンク本体14と、タンク本体14内に配設されているフロートスイッチ15を備えていて、タンク本体14には、タンク本体14内に収容されている電解生成水を注出するための注出パイプ16が設けられている。抽出パイプ16の途中には、手動の開閉バルブ16aが介装されていて、電解生成水のユーザは、開閉バルブ16aを開成操作することにより、タンク本体14内に貯留されている電解生成水を、注出パイプ16を通して採取し得るようになっている。   The storage tank 10b receives and stores the electrolyzed water generated in the electrolysis chamber R1 of the diaphragm electrolyzer 10a, and is disposed in the tank main body 14 and the tank main body 14 for storing the electrolyzed water. A float switch 15 is provided, and the tank body 14 is provided with a pouring pipe 16 for pouring electrolytically generated water contained in the tank body 14. A manual opening / closing valve 16a is interposed in the middle of the extraction pipe 16, and the user of the electrolytically generated water opens the opening / closing valve 16a, so that the electrolytically generated water stored in the tank main body 14 is stored. The sample can be collected through the extraction pipe 16.

フロートスイッチ15は、設定水位(L)を検出する水位せンサであって、貯留タンク10bのタンク本体内にて、その上方側部に配設されている。当該電解水生成装置においては、貯留タンク10b内に収容される電解生成水の上限の水位が設定されていて、この上限の水位を設定水位Lと称している。フロートスイッチ15は、電解生成水の設定水位Lの近傍に位置するように配設されていて、貯留タンク10b内に収容されている電解生成水の水位が設定水位Lに達するとON動作し、また、電解生成水の水位が設定水位Lを所定量下回るとOFF動作する。フロートスイッチ15は、これらのON−OFFの動作を検出信号として制御装置20bに出力する。制御装置20bは、これらの検出信号に基づいて、後述する電解生成水の生成運転を停止しまたは再開するように、当該電解水生成装置の電解運転を制御する。   The float switch 15 is a water level sensor that detects the set water level (L), and is disposed on the upper side of the tank body of the storage tank 10b. In the electrolyzed water generating apparatus, the upper limit water level of the electrolyzed water stored in the storage tank 10b is set, and this upper limit water level is referred to as a set water level L. The float switch 15 is disposed so as to be positioned in the vicinity of the set water level L of the electrolyzed water, and is turned ON when the water level of the electrolyzed water stored in the storage tank 10b reaches the set water level L. Further, when the level of the electrolyzed water falls below the set water level L by a predetermined amount, the operation is turned off. The float switch 15 outputs these ON-OFF operations to the control device 20b as detection signals. Based on these detection signals, the control device 20b controls the electrolysis operation of the electrolyzed water generation device so as to stop or restart the electrolysis water generation operation described later.

当該電解水生成装置を構成する濃塩水タンク10cは、食塩の飽和水溶液等、高濃度の食塩水を収容するものである。高濃度食塩水は、被電解水を調製する一原水であり、他の原水である水道水により希釈されて、被電解水である希薄食塩水を調製する。水系回路20aは、第1供給管路21a、第2供給管路21bおよび第3供給管路21cを備えている。第1供給管路21aは、水道管に連結されていて、水道水を第3供給管路21cに導入すべく機能する。また、第2供給管路21bは、濃塩水タンク10cに連結されていて、高濃度食塩水を第3供給管路21cに導入すべく機能する。   The concentrated salt water tank 10c which comprises the said electrolyzed water production | generation apparatus accommodates high concentration salt solutions, such as a saturated aqueous solution of salt. The high-concentration saline is one raw water for preparing the electrolyzed water, and diluted with tap water that is the other raw water to prepare dilute saline that is the electrolyzed water. The water system circuit 20a includes a first supply line 21a, a second supply line 21b, and a third supply line 21c. The first supply pipe 21a is connected to the water pipe and functions to introduce tap water into the third supply pipe 21c. The second supply line 21b is connected to the concentrated salt water tank 10c and functions to introduce high-concentration saline into the third supply line 21c.

第1供給管路21aは、その途中に介装されているウォータバルブ22aを備え、第2供給管路21bは、その途中に介装されている電磁定量ポンプ22bを備えていて、これら両供給管路21a,21bは第3供給管路21cに連結されている。また、第3供給管路21cは、下流側に一対の分岐管路部を備えていて、各分岐管路部にて槽本体11内に形成されている各電解室R1,R2の上流側に連結されている。   The first supply pipe 21a is provided with a water valve 22a interposed in the middle thereof, and the second supply pipe 21b is provided with an electromagnetic metering pump 22b interposed in the middle of the two supply pipes. The pipelines 21a and 21b are connected to the third supply pipeline 21c. The third supply pipe 21c has a pair of branch pipe sections on the downstream side, and is upstream of each electrolytic chamber R1, R2 formed in the tank body 11 at each branch pipe section. It is connected.

電磁定量ポンプ22bは、外部から付与されるパルスにより、高濃度食塩水を吐出すべく駆動するもので、パルスの周波数(ストローク)に応じて高濃度食塩水の吐出量が設定される。電磁定量ポンプ22bの駆動動作およびウォータバルブ22aの開閉動作は、制御装置20bにて制御される。当該電解水生成装置における電解生成水の生成運転では、ウォータバルブ22aが開成されるとともに、電磁定量ポンプ22bが駆動されて、第3供給管路21cへ所定量の水道水と高濃度食塩水とが継続して導入される。第3供給管路21c内では、導入された水道水と高濃度食塩水はその分岐管路部に達する間に均一に混合して、設定された希薄食塩水に調製され、調製された希薄食塩水は被電解水として、有隔膜電解槽10aの各電解室R1,R2に供給される。   The electromagnetic metering pump 22b is driven to discharge high-concentration saline by a pulse applied from the outside, and the discharge amount of the high-concentration saline is set according to the frequency (stroke) of the pulse. The driving operation of the electromagnetic metering pump 22b and the opening / closing operation of the water valve 22a are controlled by the control device 20b. In the electrolyzed water generating operation in the electrolyzed water generating device, the water valve 22a is opened and the electromagnetic metering pump 22b is driven to supply a predetermined amount of tap water and high-concentration saline to the third supply line 21c. Will continue to be introduced. In the third supply pipe 21c, the introduced tap water and the high-concentration saline are uniformly mixed while reaching the branch pipe section, and are prepared into a set diluted saline, and the prepared diluted saline is used. Water is supplied as electrolyzed water to the electrolysis chambers R1 and R2 of the diaphragm electrolyzer 10a.

有隔膜電解槽10aにおいては、各電解室R1,R2の下流側に第1流出管路23aおよび第2流出管路23bが連結されている。第1流出管路23aは、貯留タンク10bのタンク本体14内の上部に臨んでいて、電解室R1にて生成される電解生成水を貯留タンク10bのタンク本体14内に導入する。また、第2流出管路23bは、図示しない貯留タンクまたは排水溝に臨み、電解室R2で生成される電解生成水を系外へ流出させる。当該電解水生成装置においては、電解運転時には、制御装置20bは、ウォータバルブ22aの開閉制御、電磁定量ポンプ22bの駆動制御、各電極13a,13bに対する電圧の印加および電解電流の制御、フロートスイッチ15からの各検出信号に基づく電解生成水の生成運転の停止・再開の制御を行う。   In the diaphragm electrolyzer 10a, a first outflow conduit 23a and a second outflow conduit 23b are connected to the downstream side of the electrolysis chambers R1 and R2. The first outflow pipe 23a faces the upper part in the tank main body 14 of the storage tank 10b, and introduces the electrolyzed water generated in the electrolysis chamber R1 into the tank main body 14 of the storage tank 10b. The second outflow pipe 23b faces a storage tank or drainage groove (not shown), and causes the electrolytically generated water produced in the electrolysis chamber R2 to flow out of the system. In the electrolyzed water generating apparatus, during the electrolysis operation, the control device 20b controls the opening and closing of the water valve 22a, the drive control of the electromagnetic metering pump 22b, the application of voltage to the electrodes 13a and 13b and the control of the electrolysis current, the float switch 15 Control of stop / restart of the electrolyzed water generation operation based on the detection signals from.

当該電解水生成装置が所望の場所に設置されている状態では、電源が投入されてユーザが使用し得る状態にあり、また、貯留タンク10b内には、初期の電解運転によって、設定された所定容量の電解生成水が収容された状態にある。このため、ユーザは所望量の電解生成水を採取すべく、電解生成水の注出操作(例えば開閉バルブ16bの開放操作)を行うと、貯留タンク10b内に収容されている電解生成水は順次注出され、この際、貯留タンク10b内の電解生成水の水位は一気に低下する。このため、貯留タンク10b内に配設されているフロートスイッチ15は、貯留タンク10b内の電解生成水の水位が設定水位Lから低下したことを検出(OFF動作)し、これを検出信号として制御装置20bに出力する。 In a state where the electrolyzed water generating device is installed at a desired location, the power is turned on and the user can use it. In the storage tank 10b, a predetermined set by an initial electrolysis operation is set. A capacity of electrolytically generated water is accommodated. For this reason, when the user performs an extraction operation of the electrolysis water (for example, an opening operation of the opening / closing valve 16b) in order to collect a desired amount of electrolysis water, the electrolysis water stored in the storage tank 10b is sequentially. At this time, the water level of the electrolyzed water in the storage tank 10b is lowered at a stretch. For this reason, the float switch 15 disposed in the storage tank 10b detects that the level of electrolyzed water in the storage tank 10b has dropped from the set water level L (OFF operation), and controls this as a detection signal. Output to the device 20b.

これにより、制御装置20bは、電解生成水の生成運転を再開すべく機能し、電解生成水の生成運転が直ちに再開される。この結果、有隔膜電解槽10aでは電解生成水が継続して生成され、生成される電解生成水は継続して貯留タンク10b内に導入される。貯留タンク10b内では、電解生成水が順次導入されることにより電解生成水の水位が漸次上昇し、電解生成水の水位が設定水位Lに達すると、フロートスイッチ15がON動作してこれを検出して、これを検出信号として制御装置20bに出力される。このため、制御装置20bは、電解生成水の生成運転を停止すべき機能するが、当該電解水生成装置においては、再開される電解生成水の生成運転の時間を設定しているため、生成運転は設定された時間まで継続される。従って、電解生成水の生成運転は、貯留タンク10b内の電解生成水の水位が設定水位より所定量上回るまで継続した後に停止する。   As a result, the control device 20b functions to restart the electrolyzed water generation operation, and the electrolyzed water generation operation is immediately resumed. As a result, electrolytically generated water is continuously generated in the diaphragm membrane electrolytic cell 10a, and the generated electrolytically generated water is continuously introduced into the storage tank 10b. In the storage tank 10b, the electrolytically generated water is sequentially introduced to gradually increase the level of the electrolytically generated water. When the electrolytically generated water level reaches the set water level L, the float switch 15 is turned on to detect this. This is output as a detection signal to the control device 20b. For this reason, the control device 20b functions to stop the electrolyzed water generation operation, but the electrolyzed water generation device sets the time for the electrolyzed water generation operation to be resumed. Will continue until the set time. Therefore, the electrolytically generated water generation operation stops after the electrolytically generated water level in the storage tank 10b continues until a predetermined amount exceeds the set water level.

当該形式の電解水生成装置においては、貯留タンク10b内の電解生成水の水位が設定水位Lに達する直前では、電解生成水の導入等に起因して波打つ変動状態にあって、必ずしも静粛な状態にはない。貯留タンク10b内の電解生成水の設定水位Lを検出するフロートスイッチ15は、貯留タンク10b内の電解生成水の水位が静粛な状態では的確に動作するが、波打つ変動状態ではその動作が不安定となる。この場合、フロートスイッチ15には不安定な動作状態が発生する。すなわち、フロートスイッチ15は、電解生成水が設定水位Lに達する直前ではON−OFF動作を繰り返し、この結果、制御装置20bは、電解生成水の生成運転の停止および再開を短時間の間に繰り返し行うおそれがある。   In the electrolyzed water generating device of this type, immediately before the level of the electrolyzed water in the storage tank 10b reaches the set water level L, the electrolyzed water is in a fluctuating state due to the introduction of electrolyzed water and the like, and is not necessarily quiet. Not. The float switch 15 that detects the set water level L of the electrolyzed water in the storage tank 10b operates accurately when the water level of the electrolyzed water in the storage tank 10b is quiet, but the operation is unstable in a wavy fluctuation state. It becomes. In this case, an unstable operation state occurs in the float switch 15. That is, the float switch 15 repeats the ON-OFF operation immediately before the electrolytically generated water reaches the set water level L. As a result, the control device 20b repeatedly stops and restarts the electrolytically generated water generation operation in a short time. May be done.

これに対して、本発明に係る電解生成水装置においては、上記したように、貯留タンク10b内の電解生成水の水位が設定水位から低下して再開される電解生成水の生成運転の時間が設定されており、設定時間は、貯留タンク10b内の電解生成水の水位が設定水位に達し、かつ、電解運転開始初期に生成される不安定な特性の電解生成水に比較して安定した特性の電解生成水の割合が十分多くなるように設定されている。   On the other hand, in the electrolyzed water device according to the present invention, as described above, the time of the electrolyzed water generating operation in which the electrolyzed water level in the storage tank 10b is restarted after being lowered from the set water level. The set time is a stable characteristic as compared with the electrolyzed water having an unstable characteristic that is generated at the beginning of the electrolysis operation when the level of the electrolyzed water in the storage tank 10b reaches the set water level. The ratio of the electrolyzed water is set to be sufficiently large.

このため、本発明に係る電解水生成装置においては、貯留タンク10b内における電解生成水の水位の頻繁な変動に起因する、短時間における繰り返しの電解生成水の生成運転を防止することができ、これにより、一度の再開運転にて貯留タンクに補給される電解生成水を、安定した特性の電解生成水の割合が十分に多くすることができて、貯留タンク10b内に貯留される電解生成水を、設定された十分な特性の電解生成水とすることができる。 Therefore, the electrolytic water generation apparatus according to the present invention can prevent due to frequent fluctuations in the water level of the electrolytic water generated in the savings distillation tank 10b, and repeating generating operation of the electrolytic water generated in a short time , thereby, the electrolyzed water to be supplied to the storage tank at a time of restarting the operation, a stable ratio of electrolyzed water properties are able to sufficiently large, electrolytic generation is stored in the storage tank 10b The water can be electrolytically generated water with sufficient characteristics set.

また、従来のこの種形式の電解水生成装置においては、電解生成水の生成運転中に例えば停電等により、電源からの電力の供給が一旦停止されて電解生成水の生成運転が中断した場合、その後の停電の解除等により、電解水生成装置に対する電力の供給が復帰しても、電解生成水の生成運転の指令がない限り、電解生成水の生成運転の復帰はあり得ない。しかしながら、本発明に係る電解水生成装置においては、停電等による電力の供給の停止により中断された電解生成水の生成運転を、停電の解除等による電力の供給の復帰時に合わせて復帰させて、中断された電解生成水の生成運転を設定時間の残りの時間だけ継続するようにしている。このため、当該電解水生成装置によれば、停電等が解除された場合には、ユーザや保守管理者による電解生成水の生成運転の再開操作を要することなく、電解生成水の生成運転を再開して貯留タンク10b内に電解生成水の補給を行い、貯留タンク10b内の電解生成水を所定量確保することができる。   Also, in this type of electrolyzed water generating device of the prior art, when the supply of power from the power supply is temporarily stopped during the electrolyzed water generation operation, for example, due to a power failure, etc., and the electrolyzed water generation operation is interrupted, Even if the supply of electric power to the electrolyzed water generating device is restored due to the cancellation of the subsequent power failure or the like, the electrolyzed water generating operation cannot be restored unless there is a command for the electrolyzed water producing operation. However, in the electrolyzed water generating apparatus according to the present invention, the operation of generating electrolyzed water that has been interrupted due to the stop of the power supply due to a power failure or the like is returned in accordance with the return of power supply due to the cancellation of the power failure, etc. The generation operation of the interrupted electrolytically generated water is continued for the remaining time of the set time. For this reason, according to the electrolyzed water generating apparatus, when a power failure or the like is canceled, the electrolyzed water generating operation is resumed without requiring the user or a maintenance manager to restart the electrolyzed water generating operation. Then, the electrolytically generated water is replenished in the storage tank 10b, and a predetermined amount of electrolytically generated water in the storage tank 10b can be secured.

図3は、当該電解水生成装置の電解運転時における電解生成水の生成運転状態(状態遷移1)、生成運転の停止状態(状態遷移2)、および、停電状態(状態遷移3)を関連して示す状態遷移図である。当該電解水生成装置は、所望の場所に設置されている状態では、電源が投入されてユーザが使用し得る状態にあり、また、貯留タンク10b内には、設定された所定量の電解生成水が収容されていて、ユーザが貯留タンク10b内の電解生成水を採取するのを待機している状態にある。この待機状態は、電解生成水の生成運転が停止されている状態遷移2に相当し、ウオータバルブ22aは閉鎖(OFF)状態、電磁定量ポンプ22bは非駆動(OFF)状態、電極13a,13bは電圧印加停止(OFF)状態にある。   FIG. 3 relates to the electrolysis water generation operation state (state transition 1), the generation operation stop state (state transition 2), and the power failure state (state transition 3) during electrolysis operation of the electrolyzed water generation apparatus. FIG. When the electrolyzed water generating device is installed at a desired location, the power is turned on and the user can use the electrolyzed water generating device, and a predetermined amount of electrolyzed water is set in the storage tank 10b. Is in a state waiting for the user to collect electrolyzed water in the storage tank 10b. This standby state corresponds to the state transition 2 in which the operation of generating electrolyzed water is stopped, the water valve 22a is closed (OFF), the electromagnetic metering pump 22b is not driven (OFF), and the electrodes 13a and 13b are The voltage application is stopped (OFF).

当該電解水生成装置において、ユーザが貯留タンク10bに収容されている電解生成水を所望量採取すべく注出操作を行うと、貯留タンク10b内の電解生成水の水位は設定水位Lを一気に下回り、フロートスイッチ15は動作(OFF)してこれを検出し、これを検出信号として制御装置20bに出力する。これにより、制御装置20bは、当該電解水生成装置の状態を状態遷移1の状態に遷移して、電解生成水の生成運転を再開し、有隔膜電解槽10aにて継続して生成される電解生成水を、継続して貯留タンク10b内に導入する。状態遷移1においては、、ウオータバルブ22aは開放(ON)状態、電磁定量ポンプ22bは駆動(ON)状態、電極13a,13bは電圧印加(ON)状態にある。   In the electrolyzed water generating apparatus, when the user performs a pouring operation to collect a desired amount of electrolyzed water stored in the storage tank 10b, the level of the electrolyzed water in the storage tank 10b falls below the set water level L all at once. The float switch 15 operates (OFF) to detect this, and outputs this to the control device 20b as a detection signal. Thereby, the control apparatus 20b changes the state of the said electrolyzed water production | generation apparatus to the state of the state transition 1, restarts the electrolysis water production | generation operation, and is produced | generated continuously by the diaphragm electrolyzer 10a. The generated water is continuously introduced into the storage tank 10b. In state transition 1, the water valve 22a is in an open (ON) state, the electromagnetic metering pump 22b is in a driving (ON) state, and the electrodes 13a and 13b are in a voltage application (ON) state.

電解生成水の生成運転において、貯留タンク10b内に導入される電解生成水の導入量が注出量を上回ると、貯留タンク10b内に収容されている電解生成水の水位が漸次上昇して、電解生成水の水位が設定水位Lに達すると、フロートスイッチ15は動作(ON)してこれを検出し、これを検出信号として制御装置20bに出力するが、制御装置20bは、電解生成水の生成運転をさらに継続する。当該電解水生成装置では、再開される電解生成水の生成運転の運転時間を、例えば3分間に設定している。このため、制御装置20bは、生成運転が3分経過した時点で、当該電解水生成装置の状態を状態遷移2の状態に遷移させて、電解生成水の生成運転を停止し、電解生成水の貯留タンク10b内への導入を停止する。   In the electrolytically generated water generation operation, when the amount of electrolytically generated water introduced into the storage tank 10b exceeds the amount dispensed, the water level of the electrolytically generated water stored in the storage tank 10b gradually increases, When the electrolyzed water level reaches the set water level L, the float switch 15 operates (ON) to detect this, and outputs this to the control device 20b as a detection signal. The control device 20b The generation operation is further continued. In the electrolyzed water generating apparatus, the operation time of the electrolyzed water generating operation to be resumed is set to 3 minutes, for example. For this reason, the control device 20b changes the state of the electrolyzed water generating device to the state of state transition 2 when the generating operation has passed for 3 minutes, stops the electrolyzed water generating operation, and electrolyzed water is generated. The introduction into the storage tank 10b is stopped.

当該電解水生成装置においては、電解生成水の生成運転中や停止中に停電等により、電解水生成装置に対する電力供給が停止され、その後に停電等の解除により、電解水生成装置に対する電力供給が復帰した場合の対策を採っている。図3に示す状態遷移3は、当該電解水生成装置の停電状態における状態である。当該電解水生成装置の電解運転時、停電等が発生して電源がOFF状態となると、当該電解水生成装置は状態遷移3に移行して電解運転停止状態となる。当該電解水生成装置においては、電解生成水の生成運転中に停電等が発生した場合(電源OFF)にあっても、また、電解生成水の生成運転停止中に停電等が発生した場合にあっても同様に状態遷移3に移行し、停電等が解除された場合(電源ON)には、前者にあっては状態遷移1に復帰する。   In the electrolyzed water generating device, the power supply to the electrolyzed water generating device is stopped due to a power failure or the like during the electrolyzed water generating operation or is stopped, and then the power supply to the electrolyzed water generating device is stopped by the cancellation of the power failure or the like. Measures are taken when returning. The state transition 3 shown in FIG. 3 is a state in the power failure state of the electrolyzed water generating device. When a power failure occurs during the electrolytic operation of the electrolyzed water generating device and the power supply is turned off, the electrolyzed water generating device shifts to the state transition 3 and enters the electrolysis operation stopped state. In the electrolyzed water generating apparatus, there is a case where a power failure occurs during the electrolyzed water generation operation (power OFF), or when a power failure occurs while the electrolyzed water generation operation is stopped. In the same manner, the state transitions to 3, and when the power failure is canceled (power ON), the former returns to the state transition 1.

従って、特に前者にあっては、停電等で一旦中断した電解生成水の生成運転は、停電の解除に連動して再開される。このため、当該電解水生成装置によれば、停電等が解除された場合には、ユーザや保守管理者による電解生成水の生成運転の再開操作を要することなく、電解生成水の生成運転を再開させることができて、貯留タンク10b内に収容されている電解生成水を所定量に保持することができる。   Therefore, especially in the former case, the operation of generating electrolyzed water once interrupted due to a power failure or the like is resumed in conjunction with the cancellation of the power failure. For this reason, according to the electrolyzed water generating apparatus, when a power failure or the like is canceled, the electrolyzed water generating operation is resumed without requiring the user or a maintenance manager to restart the electrolyzed water generating operation. The electrolytically generated water stored in the storage tank 10b can be held at a predetermined amount.

本発明の一実施形態に係る電解水生成装置を概略的に示す模式図である。It is a mimetic diagram showing roughly the electrolyzed water generating device concerning one embodiment of the present invention. 同電解水生成装置が有する制御装置と各電気部品との関係を示すブロック図である。It is a block diagram which shows the relationship between the control apparatus which the same electrolyzed water generating apparatus has, and each electric component. 同電解水生成装置における電解運転時における、電解生成水の生成運転状態、生成運転停止状態、停電による生成運転停止状態を関連して示す状態遷移図である。It is a state transition diagram which shows in relation to the production | generation operation state of electrolysis water, the production | generation operation stop state, and the production | generation operation stop state by a power failure at the time of the electrolysis operation in the electrolyzed water production | generation apparatus.

符号の説明Explanation of symbols

10a…有隔膜電解槽、10b…貯留タンク、10c…塩水タンク、11…槽本体、12…隔膜、13a,13b…電極、13c…電源、13d…電流センサ、14…タンク本体、15…フロートスイッチ、16…抽出パイプ、16b…開閉バルブ、20a…水系回路、20b…制御装置、21a…第1供給管路、21b…第2供給管路、21c…第3供給管路、22a…ウォータバルブ、22b…電磁定量ポンプ、23a…第1流出管路、23b…第2流出管路、R1,R2…電解室、L…設定水位。 DESCRIPTION OF SYMBOLS 10a ... Separator membrane electrolytic cell, 10b ... Storage tank, 10c ... Salt water tank, 11 ... Tank main body, 12 ... Diaphragm, 13a, 13b ... Electrode, 13c ... Power supply, 13d ... Current sensor, 14 ... Tank main body, 15 ... Float switch , 16 ... extraction pipe, 16b ... open / close valve, 20a ... water circuit, 20b ... control device, 21a ... first supply line, 21b ... second supply line, 21c ... third supply line, 22a ... water valve, 22b ... electromagnetic metering pump, 23a ... first outflow line, 23b ... second outflow line, R1, R2 ... electrolytic chamber, L ... set water level.

Claims (4)

被電解水を電解する電解槽と、前記電解槽にて生成される電解生成水を受け入れて収容する貯留タンクと、前記貯留タンク内に配設されて同貯留タンク内に収容されている電解生成水の予め設定された所定容量の水位(設定水位)を検出する水位センサを備え、前記貯留タンク内に収容されている電解生成水の水位が前記設定水位より低下したことを前記水位センサが検出したとき電解生成水の生成運転が再開されて、前記貯留タンク内に電解生成水が補給される電解運転方式を採る電解水生成装置であり、
前記貯留タンク内の電解生成水が前記設定水位より低下したときに再開される電解生成水の生成運転は、前記貯留タンク内の電解生成水の水位が前記設定水位に達したことを前記水位センサが検出し、かつ、電解運転開始初期に生成される不安定な特性の電解生成水に比較して安定した特性の電解生成水の割合が十分に多くなるように予め設定された時間(設定時間)が経過するまで継続されることを特徴とする電解水生成装置。
An electrolytic cell for electrolyzing water to be electrolyzed, a storage tank for receiving and storing electrolytically generated water generated in the electrolytic cell, and an electrolytic generation disposed in the storage tank disposed in the storage tank A water level sensor for detecting a predetermined water level (set water level) of water set in advance is provided, and the water level sensor detects that the level of electrolyzed water stored in the storage tank has dropped below the set water level. The electrolyzed water generation apparatus adopts an electrolysis operation method in which the electrolyzed water generation operation is restarted and the electrolyzed water is replenished in the storage tank,
The electrolysis water generation operation resumed when the electrolysis water in the storage tank drops below the set water level, the water level sensor indicating that the electrolysis water level in the storage tank has reached the set water level. Is set in advance so that the ratio of the electrolyzed water having stable characteristics is sufficiently larger than the electrolyzed water having unstable characteristics generated at the beginning of electrolysis operation. ) Is continued until a lapse of time.
請求項1に記載の電解水生成装置において、前記貯留タンク内に配設される前記水位センサは、電解生成水の前記設定水位で動作するフロートスイッチであることを特徴とする電解水生成装置。 In the electrolytic water generation apparatus according to claim 1, wherein the water level sensor disposed in the reservoir tank is electrolytic water generation apparatus, characterized in that the float switch to operate in the set water level of the electrolytic water produced. 請求項1に記載の電解水生成装置において、再開される電解生成水の生成運転の前記設定時間は、電解運転開始初期の不安定な特性の電解生成水が生成される時間に対して5倍以上の時間に設定されていることを特徴とする電解水生成装置。 2. The electrolyzed water generating apparatus according to claim 1, wherein the set time for restarting electrolyzed water generation operation is five times as long as electrolyzed water having unstable characteristics at the beginning of electrolysis operation is generated. The electrolyzed water generating apparatus is characterized by being set to the above time. 請求項1〜3のいずれか一項に記載の電解水生成装置において、電解生成水の生成運転中に電源からの電力の供給が一旦停止されて電解生成水の生成運転が一旦停止した場合には、その後に電力の供給が復帰した際には、一旦停止した電解生成水の生成運転が復帰されることを特徴とする電解水生成装置。 In the electrolyzed water generating apparatus according to any one of claims 1 to 3, when the supply of electric power from the power source is temporarily stopped during the electrolyzed water generating operation, and the electrolyzed water generating operation is temporarily stopped. The electrolyzed water generating device is characterized in that when the supply of electric power is subsequently restored, the operation of generating electrolyzed water that has been stopped once is restored .
JP2005167929A 2005-06-08 2005-06-08 Electrolyzed water generator Expired - Fee Related JP4881580B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2005167929A JP4881580B2 (en) 2005-06-08 2005-06-08 Electrolyzed water generator

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2005167929A JP4881580B2 (en) 2005-06-08 2005-06-08 Electrolyzed water generator

Publications (2)

Publication Number Publication Date
JP2006341169A JP2006341169A (en) 2006-12-21
JP4881580B2 true JP4881580B2 (en) 2012-02-22

Family

ID=37638529

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2005167929A Expired - Fee Related JP4881580B2 (en) 2005-06-08 2005-06-08 Electrolyzed water generator

Country Status (1)

Country Link
JP (1) JP4881580B2 (en)

Also Published As

Publication number Publication date
JP2006341169A (en) 2006-12-21

Similar Documents

Publication Publication Date Title
JP4696276B2 (en) Electrolyzed water generation method and apparatus
JP3896210B2 (en) Electrolyzed water generator
JP2000218271A (en) Electrolysis equipment
JP4881580B2 (en) Electrolyzed water generator
US20130199928A1 (en) Device for producing an electrochemically activated solution by means of an electrolysis process
JP3432123B2 (en) Electrolyzed water generator
JP2001327968A (en) Electrolytic water generating device
JP4904721B2 (en) Electrolyte solution supply device
JP7165119B2 (en) Electrolyzed water generation method and electrolyzed water generator
JP4415444B2 (en) Electrolyzer
JP3579498B2 (en) Electrolyzed water generator
JPH10468A (en) Electrolytic water-producing apparatus
JP2009131812A (en) Electrolytic water generating apparatus
JPH09308885A (en) Electrolytic water making apparatus
JPH0985245A (en) Electrolyzed water generator
JP7218024B1 (en) generator
JP3767983B2 (en) Electrolyzed water generator
JP3299644B2 (en) Electrolyzed water generator
JP4881581B2 (en) Electrolyzed water generator
JPH07328634A (en) Ion water generator and pH sensor cleaning method
JP2010194408A (en) Electrolytic water generator
JP2005334723A (en) Electrolytic water dispenser
JPH07265858A (en) Electrolytic ionized water generator
JPH09234467A (en) Electrolyzed water generator
KR101625463B1 (en) Method for producting electrolytic water for PCB development

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20080521

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20090814

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20110823

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20111020

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20111108

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20111205

R150 Certificate of patent or registration of utility model

Ref document number: 4881580

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20141209

Year of fee payment: 3

S533 Written request for registration of change of name

Free format text: JAPANESE INTERMEDIATE CODE: R313533

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

LAPS Cancellation because of no payment of annual fees