JP4887435B2 - High milk content milk beverage, method for producing the same, and method for stabilizing properties - Google Patents
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Description
本発明は、高乳分含有乳飲料、その製造方法、及び、高乳分含有乳飲料の性状安定化方法に関する。 The present invention relates to a high milk content milk beverage, a method for producing the same, and a method for stabilizing properties of a high milk content milk beverage.
乳成分を多く含む乳飲料は、安定性が悪く、製造工程における加熱殺菌後に乳成分の分離や凝集を生じることがあった。乳成分の分離や凝集が生じた場合、商品の安全性は全く問題が無くても、商品価値が大きく損われることが問題であった。 Milk beverages containing a large amount of milk components have poor stability, and may cause separation or aggregation of milk components after heat sterilization in the production process. When milk components are separated or agglomerated, even if there is no problem in the safety of the product, the value of the product is greatly impaired.
これらの問題を防ぐ手段として、特許文献1には、乳飲料中にポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステル、及び増粘多糖類を含有させることが開示されている。また、特許文献2には、乳成分含有コーヒー飲料に、クエン酸、リンゴ酸、酒石酸、乳酸、グルコン酸、コハク酸、アジピン酸、フマル酸、乳酸、イタコン酸、α−ケトグルタル酸、フィチン酸及びリン酸から選ばれる1種又は2種以上を0.005〜0.2重量%、及び炭酸水素ナトリウムを0.075〜0.25重量%含有させることにより、ゲル状沈殿の発生を防止することが開示されている。また、特許文献3では、コーヒー分に、強塩基性物質および/または塩基性アミノ酸を添加し、乳分と混合した後に加熱殺菌することにより、乳分混合時および加熱殺菌後の沈殿物の発生を防止することが開示されている。 As means for preventing these problems, Patent Document 1 discloses that a milk beverage contains a polyglycerin fatty acid ester, a sucrose fatty acid ester, and a thickening polysaccharide. Patent Document 2 discloses that dairy component-containing coffee beverages include citric acid, malic acid, tartaric acid, lactic acid, gluconic acid, succinic acid, adipic acid, fumaric acid, lactic acid, itaconic acid, α-ketoglutaric acid, phytic acid and Preventing the occurrence of gel-like precipitation by containing 0.005 to 0.2% by weight of one or more selected from phosphoric acid and 0.075 to 0.25% by weight of sodium bicarbonate. Is disclosed. Moreover, in patent document 3, generation | occurrence | production of the precipitate at the time of milk mixing and after heat sterilization is carried out by adding a strong basic substance and / or a basic amino acid to coffee, mixing with milk, and heat-sterilizing. Is disclosed.
しかしながら、従来の方法では、乳成分の分離及び凝集を防止する効果が不十分であった。 However, the conventional method is insufficient in the effect of preventing separation and aggregation of milk components.
本発明の目的は、乳成分の分離及び凝集を抑制することによって、性状が安定であり、且つ、色調を含む総合評価が良好である高乳分含有乳飲料、及びその製造方法、並びに高乳分含有乳飲料における性状安定化方法を提供することを目的とする。 An object of the present invention is to provide a high-milk-containing milk beverage that has stable properties and good overall evaluation including color tone by suppressing separation and aggregation of milk components, a method for producing the same, and high milk It is an object of the present invention to provide a method for stabilizing properties in a dairy-containing milk beverage.
本発明の第1実施形態において、乳分70重量%以上の高乳分含有乳飲料であって、ナトリウム濃度が、35mg/100g以上100mg/100g以下であり、炭酸水素ナトリウムに由来するナトリウム濃度が6.5mg/100g以上であり、且つ、粒度分布90%Dが3.1μm以下である缶入り高乳分含有乳飲料が提供される。
In 1st Embodiment of this invention, it is a high milk content milk drink 70% or more of milk content, Comprising: Sodium concentration is 35 mg / 100g or more and 100 mg / 100g or less, The sodium concentration derived from sodium hydrogencarbonate is A canned high-milk-containing milk beverage that is 6.5 mg / 100 g or more and that has a particle size distribution 90% D of 3.1 μm or less is provided.
本発明の第2実施形態において、乳分を70重量%以上含む調製液に、炭酸水素ナトリウムを、ナトリウム換算で6.5mg/100g以上の量で添加して該調製液のナトリウム濃度を35mg/100g以上100mg/100g以下の範囲に調整する工程と、前記調製液をホモジナイズ処理及び加熱殺菌して、粒度分布90%Dを3.1μm以下に調整する工程とを含む缶入り高乳分含有乳飲料の製造方法が提供される。
In the second embodiment of the present invention , sodium bicarbonate is added to a preparation solution containing 70% by weight or more of milk in an amount of 6.5 mg / 100 g or more in terms of sodium, so that the sodium concentration of the preparation solution is 35 mg / Canned high milk-containing milk comprising a step of adjusting to a range of 100 g or more and 100 mg / 100 g or less, and a step of homogenizing and heat sterilizing the prepared liquid to adjust a particle size distribution 90% D to 3.1 μm or less. A method for producing a beverage is provided.
本発明の第3実施形態において、乳分を70重量%以上含む調製液に、炭酸水素ナトリウムを、ナトリウム換算で6.5mg/100g以上の量で添加して該調製液のナトリウム濃度を35mg/100g以上100mg/100g以下の範囲に調整する工程と、前記調製液をホモジナイズ処理及び加熱殺菌して、粒度分布90%Dを3.1μm以下に調整する工程とを含む缶入り高乳分含有乳飲料の性状安定化方法が提供される。 In a third embodiment of the present invention , sodium bicarbonate is added to a preparation solution containing 70% by weight or more of milk in an amount of 6.5 mg / 100 g or more in terms of sodium, and the sodium concentration of the preparation solution is 35 mg / Canned high milk-containing milk comprising a step of adjusting to a range of 100 g or more and 100 mg / 100 g or less, and a step of homogenizing and heat sterilizing the prepared liquid to adjust a particle size distribution 90% D to 3.1 μm or less. A method for stabilizing beverage properties is provided.
本発明によれば、乳成分の分離及び凝集を抑制することによって性状を安定させ、且つ、色調等の総合評価が良好である高乳分含有乳飲料、及びその製造方法、並びに高乳分含有乳飲料における性状安定化方法が提供される。 ADVANTAGE OF THE INVENTION According to this invention, the high milk content milk drink which stabilizes a property by suppressing isolation | separation and aggregation of milk components, and is good in comprehensive evaluation, such as a color tone, its manufacturing method, and high milk content A method for stabilizing properties in milk beverages is provided.
(第1実施形態)
本発明の第1の実施形態において、乳分50重量%以上の高乳分含有乳飲料であって、ナトリウム濃度が、35mg/100g以上100mg/100g以下であり、粒度分布90%Dが3.1μm以下である高乳分含有乳飲料が提供される。
(First embodiment)
In 1st Embodiment of this invention, it is a high milk containing milk drink 50 weight% or more of milk, Comprising: Sodium concentration is 35 mg / 100g or more and 100 mg / 100g or less, and the particle size distribution 90% D is 3. A high milk content milk beverage that is 1 μm or less is provided.
乳飲料とは、乳等省令第2条第40項に規定する乳飲料であって、重量百分率で乳固形分3.0%以上の成分を含有するものをいう。本実施形態においては、乳分を50重量%以上含む乳飲料、具体的には、乳脂肪分を1.5%以上3.5%未満、無脂乳固形分を4.0%以上8.5%未満含む飲料を、高乳分含有乳飲料とする。 A milk beverage is a milk beverage prescribed in Article 2, Paragraph 40 of the Ministerial Ordinance of Milk and the like, which contains a component having a milk solid content of 3.0% or more by weight percentage. In the present embodiment, the milk beverage containing 50% by weight or more of milk, specifically, the milk fat content is 1.5% or more and less than 3.5%, and the non-fat milk solid content is 4.0% or more and 8. A beverage containing less than 5% is referred to as a high milk content milk beverage.
本実施形態における高乳分含有乳飲料は、ナトリウム濃度が、乳飲料100g中に35mg以上100mg以下であり、粒度分布90%Dが3.1μm以下である。 The high milk content milk beverage in the present embodiment has a sodium concentration of 35 mg to 100 mg in 100 g of milk beverage, and a particle size distribution 90% D of 3.1 μm or less.
ここで、粒度分布90%Dが3.1μm以下であるとは、飲料中の分散する乳脂肪、たんぱく質など乳由来成分の粒子の分布において、粒子径の小さい粒子から分布%を算出する場合、全体の90%が分布する値が、3.1μm以下の範囲であることを意味する。 Here, when the particle size distribution 90% D is 3.1 μm or less, in the distribution of the particles of milk-derived components such as milk fat and protein dispersed in the beverage, when calculating the distribution% from the particles having a small particle diameter, It means that the value in which 90% of the whole is distributed is in a range of 3.1 μm or less.
本実施形態における高乳分含有乳飲料において、ナトリウム濃度が35mg/100g未満であると、製品の保管時に乳成分の分離凝集が発生しやすくなる。一方、ナトリウム濃度が100mg/100gを超えると、液色の褐変が強くなり、牛乳由来の白い色合いが損なわれ好ましくない。また、粒度分布90%Dが3.1μmを超えると、乳成分の分離凝集が発生しやすくなる。 In the high milk content milk beverage in the present embodiment, when the sodium concentration is less than 35 mg / 100 g, separation and aggregation of milk components are likely to occur during product storage. On the other hand, when the sodium concentration exceeds 100 mg / 100 g, the liquid color browning becomes strong, and the white color derived from milk is impaired. On the other hand, when the particle size distribution 90% D exceeds 3.1 μm, separation and aggregation of milk components are likely to occur.
本実施形態に従って、ナトリウム濃度及び粒度分布90%Dを上記範囲内にすることにより、高乳分含有乳飲料における乳成分の分離及び凝集が抑制され、性状が安定すると共に、色調が良好であり、総合評価が良好である乳高含有飲料を提供することが可能である。 According to the present embodiment, by setting the sodium concentration and the particle size distribution 90% D within the above ranges, the separation and aggregation of milk components in the high milk content milk beverage are suppressed, the properties are stabilized, and the color tone is good. It is possible to provide a high milk content beverage having a good overall evaluation.
(第2実施形態)
本発明の第2の実施形態において、乳成分の分離及び凝集が抑制され、性状が安定であると共に、色調が良好であり、総合評価が良好である乳高含有飲料の製造方法が提供される。
(Second Embodiment)
In the second embodiment of the present invention, there is provided a method for producing a milk-rich beverage that suppresses separation and aggregation of milk components, has stable properties, has a good color tone, and has a good overall evaluation. .
該方法においては、乳分を50重量%以上含む調製液に、ナトリウム塩を添加して該調製液のナトリウム濃度を調製液100gあたり35mg以上100mg以下の範囲に調整する。ナトリウム塩の添加は乳分の凝固を防ぐ効果を有する。また、ナトリウム塩の一種である重曹は無色無臭であり、味への影響が少ないため好適に用いられる。 In this method, a sodium salt is added to a preparation containing 50% by weight or more of milk to adjust the sodium concentration of the preparation to a range of 35 mg to 100 mg per 100 g of the preparation. The addition of sodium salt has the effect of preventing milk coagulation. Baking soda, which is a kind of sodium salt, is colorless and odorless, and is preferably used because it has little effect on taste.
調製液には、乳成分及び他の成分に由来するナトリウムが含まれる。よって、添加するナトリウム塩は、添加前の調製液のナトリウム濃度に依存して変化するが、35〜100mg/100gの範囲であることが好ましい。 The preparation solution contains sodium derived from milk components and other components. Therefore, although the sodium salt to add changes depending on the sodium concentration of the preparation liquid before addition, it is preferable that it is the range of 35-100 mg / 100g.
また、調製液をホモジナイズ処理して加熱殺菌することにより、該製品の粒度分布90%Dを3.1μm以下に調整する。なお、ホモジナイズ処理は、該調合液を60〜80℃で200kg/cm2の条件によって行うことができ、加熱処理は中性飲料や弱酸性飲料の場合には、115〜130℃、5〜40分でレトルト殺菌、若しくは、115〜150℃、30秒〜90秒でUHT殺菌することができる。 Moreover, the particle size distribution 90% D of the product is adjusted to 3.1 μm or less by homogenizing the prepared solution and sterilizing by heating. Incidentally, homogenization treatment, a該調if liquid can be carried out by the conditions of 200 kg / cm 2 at 60-80 ° C., when the heat treatment of the neutral beverages and weakly acidic beverages, 115 to 130 ° C., 5 to 40 Retort sterilization in minutes, or UHT sterilization at 115-150 ° C. for 30-90 seconds.
なお、本実施形態において調製液とは、製造途中の飲料を指し、50重量%以上の乳分と、果汁、野菜汁、コーヒー飲料及び茶飲料のような他の成分を含む液である。 In addition, in this embodiment, a preparation liquid refers to the drink in the middle of manufacture, and is a liquid containing 50 weight% or more of milk and other components like fruit juice, vegetable juice, coffee drink, and tea drink.
上記の調製液は、ナトリウム濃度の調整が終了した段階でホモジナイズ処理を行う。なお、調製液には、例えばpHを調整するためのさらなる成分を添加してもよく、また、味、香り、栄養機能成分等を調整するために、他の成分を添加してもよい。例えば、ビタミンC、クエン酸、各種ビタミン類や香料等を添加することができる。 The above preparation solution is homogenized at the stage where the adjustment of the sodium concentration is completed. In addition, the additional component for adjusting pH, for example may be added to a preparation liquid, and other components may be added in order to adjust a taste, fragrance, a nutrient functional component, etc. For example, vitamin C, citric acid, various vitamins, fragrances and the like can be added.
以上のように、本実施形態に従って、ナトリウム塩を添加してナトリウム濃度を上記の範囲内に調整し、また、ホモジナイズ処理を行い、加熱殺菌することで粒子径を上記の範囲内に調整することにより、乳成分の分離及び凝集が抑制され、性状が安定であると共に、色調が良好であり、総合評価が良好である乳高含有飲料を製造することが可能である。 As described above, according to the present embodiment, sodium salt is added to adjust the sodium concentration within the above range, and the particle size is adjusted within the above range by performing homogenization treatment and heat sterilization. Thus, it is possible to produce a milk-rich beverage having suppressed milk component separation and aggregation, stable properties, good color tone, and good overall evaluation.
(第3実施形態)
本発明の第3の実施形態において、高乳分含有乳飲料の性状安定化方法が提供される。上記第2の実施形態における製造方法と同様に、乳分を50重量%以上含む調製液にナトリウム塩を添加して、該調製液のナトリウム濃度を35〜100mg/100gの範囲に調整し、また、該調製液をホモジナイズ処理して加熱殺菌することで、該製品の粒度分布90%Dを3.1μm以下に調整することができ、高乳分含有乳飲料の性状を安定化させることができる。
(Third embodiment)
In the 3rd Embodiment of this invention, the property stabilization method of the high milk content milk drink is provided. Similar to the production method in the second embodiment, a sodium salt is added to a preparation containing 50% by weight or more of milk to adjust the sodium concentration of the preparation to a range of 35 to 100 mg / 100 g. , By homogenizing the prepared liquid and sterilizing by heating, the particle size distribution 90% D of the product can be adjusted to 3.1 μm or less, and the properties of the high milk content milk beverage can be stabilized. .
上記ナトリウム塩は、例えば、炭酸水素ナトリウム、塩化ナトリウム、クエン酸ナトリウム、リンゴ酸ナトリウム、乳酸ナトリウム、酒石酸ナトリウム、酢酸ナトリウム、コハク酸ナトリウム、グルコン酸ナトリウム、フマル酸ナトリウム、及びアスコルビン酸ナトリウムから選択することができ、単独でまたは組み合わせて用いることができるが、これらに限定されるものではない。 The sodium salt is selected from, for example, sodium bicarbonate, sodium chloride, sodium citrate, sodium malate, sodium lactate, sodium tartrate, sodium acetate, sodium succinate, sodium gluconate, sodium fumarate, and sodium ascorbate Can be used alone or in combination, but is not limited thereto.
高乳分含有乳飲料を調製し、分離凝集、色調及び総合評価について試験した。 High milk content milk beverages were prepared and tested for separation flocculation, color tone and overall evaluation.
(実施例1) 生乳7000gに予めイオン交換水で溶解した乳化剤18gを加え、さらに、イオン交換水で溶解したグラニュー糖550gとトレハロース(林原製)300gを混合した後、バナナ果汁100gにビタミンC5gを混合した溶液を加え、さらに、イオン交換水を加えながら重曹を2.4g添加した。この調製液に適量の香料を添加して10000gまでメスアップして高乳分含有乳飲料を得た。 (Example 1) 18 g of emulsifier previously dissolved in ion-exchanged water was added to 7000 g of raw milk, 550 g of granulated sugar dissolved in ion-exchanged water and 300 g of trehalose (manufactured by Hayashibara) were mixed, and then 5 g of vitamin C was added to 100 g of banana juice. The mixed solution was added, and 2.4 g of sodium bicarbonate was added while adding ion exchange water. An appropriate amount of fragrance was added to this preparation solution, and the volume was increased to 10,000 g to obtain a milk drink containing a high milk content.
次いで、該調製液を濾過した後、ホモジナイズ処理した。ホモジナイズ処理は、三和機械(株)製ホモジナイザーを用いて、該調製液を65℃まで昇温させた後、200kg/cm2の条件で均質化した。さらに、その後85℃まで昇温させ190g缶に充填して124℃20分の条件でレトルト殺菌を行い、冷却させることにより、高乳分含有乳飲料を作成した。なお、この製品における粒度分布90%Dは3.1μmであった。 Next, the prepared solution was filtered and then homogenized. In the homogenization treatment, the prepared solution was heated to 65 ° C. using a homogenizer manufactured by Sanwa Kikai Co., Ltd. and then homogenized under the condition of 200 kg / cm 2 . Furthermore, it heated up to 85 degreeC after that, and filled into a 190-g can, retort-sterilized on condition of 124 degreeC for 20 minutes, and was made to cool, and the high milk containing milk drink was created. The 90% D particle size distribution in this product was 3.1 μm.
実施例1の高乳分含有乳飲料の生乳含有率、粒度分布90%D及びナトリウム濃度などを表1に示し、ホモジナイズ処理や分離凝集の有無、色調及び総合評価などを表2に示した。 Table 1 shows the raw milk content, particle size distribution 90% D, sodium concentration, and the like of the high milk content milk beverage of Example 1, and Table 2 shows the presence / absence of homogenization treatment, separation / aggregation, color tone, and overall evaluation.
(実施例2〜7)
重曹の添加量とホモジナイズ処理によって、ナトリウム濃度及び粒度分布90%Dを表1に示すようにした以外は、実施例1と同様に高乳分含有乳飲料を作製した。但し、実施例6は生乳含有率が50重量%であり、実施例7は生乳含有率が90重量%である。
(Examples 2 to 7)
A high-milk-containing milk beverage was prepared in the same manner as in Example 1 except that the sodium concentration and the particle size distribution 90% D were as shown in Table 1 by the addition amount of sodium bicarbonate and the homogenization treatment. However, Example 6 has a raw milk content of 50% by weight, and Example 7 has a raw milk content of 90% by weight.
(比較例1〜3)
重曹の添加量とホモジナイズ処理によって、ナトリウム濃度及び粒度分布90%Dを表1に示すようにした以外は、実施例1と同様に高乳分含有乳飲料を作製した。但し、比較例2は、ホモジナイズ処理を行わなかった。
(Comparative Examples 1-3)
A high-milk-containing milk beverage was prepared in the same manner as in Example 1 except that the sodium concentration and the particle size distribution 90% D were as shown in Table 1 by the addition amount of sodium bicarbonate and the homogenization treatment. However, the comparative example 2 did not perform the homogenization process.
(評価)
実施例1〜7及び比較例1〜3の高乳分含有乳飲料について、分離及び凝集の発生と色調を観察し、総合評価を行った。その結果を表2に示す。分離及び凝集の発生の判定は、190g缶を振とうさせた後、内容液を網に空け、分離及び凝集の発生があるかないかを目視により行った。色調は、色差計による測定結果(L,a及びb)と目視による観察から判定した。
(Evaluation)
About the high milk content milk drink of Examples 1-7 and Comparative Examples 1-3, generation | occurrence | production and color tone of isolation | separation and aggregation were observed, and comprehensive evaluation was performed. The results are shown in Table 2. The occurrence of separation and aggregation was determined by shaking a 190 g can and then emptying the content liquid in a net to visually check whether separation and aggregation occurred. The color tone was determined from the measurement results (L, a and b) using a color difference meter and visual observation.
表1に示したように、ナトリウム濃度が35mg/100g以上100mg/100gの範囲内であり、且つ、粒度分布90%Dが3.1μm以下の範囲内である実施例1〜7は何れも、分離凝集が認められず、且つ、色調も良く、総合評価が良好であった。一方、粒度分布90%Dが3.1μmを超える比較例1は、分離凝集が発生した。また、ホモジナイズ処理を行わなかった比較例2は、粒度分布90%Dが極めて高く、分離凝集が発生した。ナトリウム濃度が100mg/100gを超える比較例3は、分離凝集は認められなかったものの、色調の評価が低かった。 As shown in Table 1, each of Examples 1 to 7 in which the sodium concentration is in the range of 35 mg / 100 g or more and 100 mg / 100 g, and the particle size distribution 90% D is in the range of 3.1 μm or less, Separation and aggregation were not recognized, the color tone was good, and the overall evaluation was good. On the other hand, in Comparative Example 1 in which the particle size distribution 90% D exceeds 3.1 μm, separation and aggregation occurred. Further, in Comparative Example 2 in which the homogenization treatment was not performed, the particle size distribution 90% D was extremely high, and separation and aggregation occurred. In Comparative Example 3 in which the sodium concentration exceeded 100 mg / 100 g, although separation and aggregation were not observed, the evaluation of the color tone was low.
以上のことから、ナトリウム濃度が、35mg/100g以上100mg/100g以下であり、粒度分布90%Dが3.1μm以下である高乳分含有乳飲料は、乳成分の分離及び凝集が抑制されて性状が安定であり、色調が良好であり、総合評価が優れていることが示された。
Claims (5)
ナトリウム濃度が、35mg/100g以上100mg/100g以下であり、
炭酸水素ナトリウムに由来するナトリウム濃度が6.5mg/100g以上であり、且つ、
粒度分布90%Dが3.1μm以下であることを特徴とする、缶入り高乳分含有乳飲料。 A milk beverage containing a high milk content with a milk content of 70% by weight or more,
The sodium concentration is 35 mg / 100 g or more and 100 mg / 100 g or less,
The sodium concentration derived from sodium bicarbonate is 6.5 mg / 100 g or more, and
A canned high milk content milk beverage characterized by having a particle size distribution 90% D of 3.1 μm or less.
前記調製液をホモジナイズ処理及び加熱殺菌して、粒度分布90%Dを3.1μm以下に調整する工程とを含むことを特徴とする、缶入り高乳分含有乳飲料の製造方法。 Sodium bicarbonate is added to a preparation containing 70% by weight or more of milk in an amount of 6.5 mg / 100 g or more in terms of sodium, so that the sodium concentration of the preparation is in the range of 35 mg / 100 g to 100 mg / 100 g. Adjusting, and
And homogenized and heat sterilization the preparation, characterized in that it comprises a step of adjusting the particle size distribution 90% D below 3.1 .mu.m, a manufacturing method of canned high milk content containing milk beverage.
前記調製液をホモジナイズ処理及び加熱殺菌して、粒度分布90%Dを3.1μm以下に調整する工程とを含むことを特徴とする、缶入り高乳分含有乳飲料の性状安定化方法。 Sodium bicarbonate is added to a preparation containing 70% by weight or more of milk in an amount of 6.5 mg / 100 g or more in terms of sodium, so that the sodium concentration of the preparation is in the range of 35 mg / 100 g to 100 mg / 100 g. Adjusting, and
And homogenized and heat sterilization the preparation, characterized in that it comprises a step of adjusting the particle size distribution 90% D below 3.1 .mu.m, property stabilization method of canned high milk content containing milk beverage.
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