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JP4932092B2 - Sealed battery - Google Patents
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JP4932092B2 - Sealed battery - Google Patents

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Publication number
JP4932092B2
JP4932092B2 JP2001169199A JP2001169199A JP4932092B2 JP 4932092 B2 JP4932092 B2 JP 4932092B2 JP 2001169199 A JP2001169199 A JP 2001169199A JP 2001169199 A JP2001169199 A JP 2001169199A JP 4932092 B2 JP4932092 B2 JP 4932092B2
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JP
Japan
Prior art keywords
battery
electrode terminal
insulating plate
lid
header
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP2001169199A
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Japanese (ja)
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JP2002367577A (en
Inventor
義朝 広田
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Envision AESC Energy Devices Ltd
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NEC Energy Devices Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Sealing Battery Cases Or Jackets (AREA)
  • Secondary Cells (AREA)

Description

【0001】
【発明の属する技術分野】
本発明は、密閉型電池に関し、特に封口特性が良好な小型のリチウムイオン電池等の密閉型電池に関する。
【0002】
【従来の技術】
携帯用の電子機器は、小型軽量化と共に機能の高度化が進んでいる。その結果、これらの電子機器に使用する電源用の電池には、小型、軽量で容積あたり容量が大きな電池が求められている。
リチウムイオンをドープ、および脱ドープする正極活物質と負極活物質を用いたリチウムイオン電池は、従来から用いられているニッケルカドミウム電池や鉛電池に比べて、容積あるいは質量当たりのエネルギー密度が大きな二次電池として小型の電子機器用の電源として利用されている。
リチウムイオン電池は、正極電極と負極電極をセパレータを介して巻回して製造した電池要素、あるいは正極電極と負極電極を積層した電池要素を金属缶に収納した後に、電池缶とは極性の異なる電極を絶縁性部材で絶縁した電極を備えた蓋体を取り付けて溶接によって封口をしている。
【0003】
図4は、電池ヘッダの一例を説明する図であり、図4(A)は、分解斜視図であり、図4(B)は、組み立てた電池ヘッダの断面を説明する図であり、アルミニウム製の電池缶に取り付けた電池ヘッダを説明する図である。
電池ヘッダ2は、電極端子を取り出すための貫通孔を設けた蓋体用金属板3に、ニッケル、ニッケル合金等からなる電極ピン4のフランジ4A上に、座金6およびポリプロピレン、フッ素樹脂等からなる内部絶縁板7を、蓋体用金属板3に設けた孔を貫通させ、蓋体用金属板3の上部から外部絶縁板8を取り付けて、電極ピン4の先端部4Bをかしめることによって、内部絶縁板、外部絶縁板を電極ピン4、蓋体用金属板3との間を密閉して固着している。また、蓋体用絶縁板3には、電解液の注液用の小孔9、および電池内部の圧力増大時に内部の圧力を開放する薄肉部からなる圧力開放弁10が設けられている。
【0004】
次いで、図5に、従来の電池の上部の厚み方向の断面図を示すように、電池缶の上部の開口部に電池ヘッダを嵌合した後に、電池缶の壁面と電池ヘッダの会合部にレーザー11を照射してレーザー溶接によって密閉を行っている。
ところが、電池缶1と蓋体用金属板3との会合部の溶接の際に加えられるレーザー11の熱12により外部絶縁板8の蓋体用金属板3の上部に突出している部分が収縮し、外部絶縁板8と電極ピン4との間、あるいは外部絶縁板8と蓋体用金属板との間に空隙を生じ封口の不良がおこり、電池内部への水分の浸入等によって電池が早期に劣化することがあった。
【0005】
特に、小型軽量の電池用の電池缶材料として用いられているアルミニウムは、ニッケルめっき軟鋼等の材料に比べて熱伝導度が大きいために、溶接個所から周囲に失われる熱エネルギーが多い。このため、アルミニウムまたはその合金製の電池缶に電池ヘッダをレーザー溶接によって接合する際には、ニッケルめっき電池缶の溶接に比してより多くの加熱エネルギーを必要とするので、絶縁性部材への熱的な影響も大きくなる。
【0006】
【発明が解決しようとする課題】
本発明は,密閉型電池の電池蓋体に絶縁性部材を介して取り付けた電極端子と絶縁性部材、あるいは電池蓋体と絶縁性部材の間の封口不良が生じることがない密閉型電池を提供することを課題とするものである。
【0007】
【課題を解決するための手段】
本発明の課題は、絶縁性部材を介して電極端子を取りつけた電池蓋体を電池缶の開口部に溶接により接合した密閉型電池において、電極端子と電池蓋体との間に設けた絶縁性部材のうち、電池缶の外面に面する外部絶縁板は、電池蓋体の上面よりも上部には突出しない位置に装着され、外部絶縁板を貫通する電極端子形成部材のかしめによって外部絶縁板が固着されたものである密閉型電池であって、電極端子の外部絶縁板の外面に位置する部分には、電極端子あるいは電池蓋体の上面を保護する保護部材の係合部を有する前記の密閉型電池である。
保護部材は、電池蓋体と電池缶との溶接による接合の後に取り付けたものである前記の密閉型電池である。
前記保護部材が電極端子の短絡を防止する電極端子保護部材、または電池ヘッダを覆う電池ヘッダ絶縁板である前記の密閉型電池である。
【0008】
【発明の実施の形態】
本発明は、電池缶に電池蓋体をレーザー溶接によって接合して封口した密閉型電池において、電池蓋体の電極端子部における封口不良が電池蓋体を電池缶にレーザー溶接によって接合する際に、電極端子と電池蓋体との間に位置する絶縁体が熱的に損傷して封口不良等が生じることが原因であることを見いだし、本発明を想到したものである。
【0009】
以下に図面を参照して本発明を説明する。
図1は、本発明の密閉型電池を説明する図であり、密閉型電池の上部の電極端子部の断面を説明する図である。
本発明の電池は、アルミニウム、あるいはアルミニウム合金製の電池缶1に、電池ヘッダ2をレーザー溶接等によって接合したものであり、電極端子を取り出すための貫通孔を設けた蓋体用金属板3に、ニッケル、ニッケル合金等からなる電極端子形成部材である電極ピン4のフランジ4A上に、座金6およびポリプロピレン、フッ素樹脂等の合成樹脂からなる内部絶縁板7を蓋体用金属板3に設けた孔を貫通させ、蓋体用金属板3の上部から外部絶縁板8を取り付けて、電極ピン4の先端部4Bをかしめることによって、内部絶縁板、外部絶縁板を電極ピン、蓋体用金属板3との間を密閉した状態で固着されている。
【0010】
また、外部絶縁板8の上端部は、蓋体用金属板3の上面からは突出しておらず、外部絶縁板8の上端部8Aは、蓋体用金属板3の上面と同じであるか、上面よりも下部に位置している。
このため、電池ヘッダ2を電池缶1にレーザー溶接によって接合する際には、レーザーによる熱が直接的に外部絶縁板に照射されて熱によって変形等を生じて封口不良を起こすことを防止することが可能となる。
また、電極ピン4のフランジ部には、電池要素に接続したタブ(図示しない)が接続され導電接続が形成される。
また、本発明の電池においては、電極ピンの先端部のかしめによって形成された電極端子の側面方向が露出したものとなるが、電池の使用態様によっては、電極端子の側面方向を絶縁する必要が生じた場合には、電極端子に絶縁板を装着しても良い。
【0011】
図2は、電極端子に装着した絶縁板を説明する図であり、電池の電極端子部を説明する電池の厚み方向の断面図である。
図2(A)は、電池ヘッダ2をレーザー溶接等によって接合したものであり、電極端子には、係合部20が形成されており、電極端子保護材21が係合部20によって固着されている。このため、電極端子は短絡等の危険から保護されることとなる。
また、図2(B)は、電極端子に形成した係合部20に、電池上部の電池ヘッダ2を覆う電池ヘッダ絶縁板22を取り付けた例を示している。
これによって電池の上面が完全に覆われ、短絡等の危険から保護されることとなる。
図2(A)、および図2(B)に示した電極端子保護材および電池ヘッダ絶縁板は、いずれも電池ヘッダを接合した後に電池の洗浄等を行った後に、電極端子に設けた係合部に装着することができる。
【0012】
図3は、他の例を説明する図であり、電池の厚み方向を説明する図である。
図3(A)は、厚みが薄い電池に適用した例を説明する図である。
この例の電池では、外部絶縁板8の上端部8Aが、電池ヘッダ2の蓋体用金属板3の表面からは突出しておらず、外部絶縁板8が熱によって損傷を受けることが小さくなるので、電池缶1と電池ヘッダ2の会合部のレーザー溶接による接合個所と、電極端子4との間の距離dを小さくすることが可能となり、厚みの薄い電池においても封口特性の良好な電池を製造することが可能となる。
図3(B)は、外部絶縁板と電極端子との係合特性を高めた電池を説明する図である。
図3(B)に示した例では、外部絶縁板8には、電極端子を係合する凹部8Bが設けられている。これによって、電極端子4は、かしめとともに、外部絶縁板8の凹部8Bによる係合の作用も生じる結果、より充分な係合が得られる。
【0013】
【発明の効果】
本発明の密閉型電池では、電池の電極端子部を構成する絶縁板を蓋体用金属板の表面よりも突出しない構造としたので、電池ヘッダを電池缶に接合する場合には、レーザー溶接による熱によって絶縁板が悪影響を受けないので、封口特性が良好な電池を提供することができる。
【図面の簡単な説明】
【図1】図1は、本発明の密閉型電池を説明する図であり、密閉型電池の上部の電極端子部の断面を説明する図である。
【図2】図2は、電極端子に装着した絶縁板を説明する図であり、電池の電極端子部を説明する電池の厚み方向の断面図である。
【図3】図3は、他の例を説明する図であり、電池の厚み方向を説明する図である。
【図4】図4は、電池ヘッダの一例を説明する図である。
【図5】図5は、従来の電池の上部の厚み方向の断面図を説明する図である。
【符号の説明】
1…電池缶、2…電池ヘッダ、3…蓋体用金属板、4…電極ピン、4A…フランジ、4B…先端部、6…座金、7…内部絶縁板、8…外部絶縁板、8A…上端部、8B…凹部、9…小孔、10…圧力開放弁、11…レーザー、12…熱、20…係合部、21…電極端子保護材、22…電池ヘッダ絶縁板
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a sealed battery, and more particularly to a sealed battery such as a small lithium ion battery having good sealing properties.
[0002]
[Prior art]
Portable electronic devices are becoming smaller and lighter and have advanced functions. As a result, batteries for power supplies used in these electronic devices are required to be small, light and large in capacity per volume.
Lithium ion batteries using positive and negative active materials doped and dedoped with lithium ions have a higher energy density per volume or mass than conventional nickel cadmium and lead batteries. As a secondary battery, it is used as a power source for small electronic devices.
A lithium ion battery is a battery element manufactured by winding a positive electrode and a negative electrode through a separator, or a battery element in which a positive electrode and a negative electrode are stacked in a metal can, and then an electrode having a polarity different from that of the battery can A lid provided with an electrode insulated by an insulating member is attached and sealed by welding.
[0003]
FIG. 4 is a diagram illustrating an example of a battery header, FIG. 4 (A) is an exploded perspective view, and FIG. 4 (B) is a diagram illustrating a cross-section of the assembled battery header, which is made of aluminum. It is a figure explaining the battery header attached to the battery can.
The battery header 2 is made of a cover metal plate 3 provided with a through hole for taking out an electrode terminal, a flange 4A of an electrode pin 4 made of nickel, nickel alloy or the like, a washer 6, polypropylene, fluororesin, or the like. By passing the internal insulating plate 7 through the hole provided in the lid metal plate 3, attaching the external insulating plate 8 from the upper part of the lid metal plate 3, and caulking the tip portion 4 </ b> B of the electrode pin 4, The inner insulating plate and the outer insulating plate are sealed and fixed between the electrode pin 4 and the lid metal plate 3. Further, the lid insulating plate 3 is provided with a small hole 9 for injecting an electrolytic solution and a pressure release valve 10 composed of a thin portion that releases the internal pressure when the pressure inside the battery increases.
[0004]
Next, as shown in a sectional view in the thickness direction of the upper part of the conventional battery in FIG. 5, after the battery header is fitted into the opening at the upper part of the battery can, the laser is applied to the wall of the battery can and the meeting part of the battery header. 11 is irradiated and sealed by laser welding.
However, the portion of the external insulating plate 8 protruding above the lid metal plate 3 contracts due to the heat 12 of the laser 11 applied during welding of the meeting portion between the battery can 1 and the lid metal plate 3. A gap is formed between the external insulating plate 8 and the electrode pin 4 or between the external insulating plate 8 and the metal plate for the lid, resulting in a defective sealing. It sometimes deteriorated.
[0005]
In particular, aluminum used as a battery can material for small and light batteries has a higher thermal conductivity than materials such as nickel-plated mild steel, and therefore, a large amount of heat energy is lost from the welded area to the surroundings. For this reason, when a battery header is joined to a battery can made of aluminum or an alloy thereof by laser welding, more heating energy is required compared to welding of a nickel-plated battery can. Thermal effects are also increased.
[0006]
[Problems to be solved by the invention]
The present invention provides a sealed battery that does not cause a sealing failure between an electrode terminal and an insulating member attached to the battery lid of the sealed battery via an insulating member, or between the battery lid and the insulating member. It is an object to do.
[0007]
[Means for Solving the Problems]
An object of the present invention is to provide an insulating battery provided between an electrode terminal and a battery lid body in a sealed battery in which a battery lid body to which an electrode terminal is attached via an insulating member is joined to an opening of a battery can by welding. Among the members, the external insulating plate facing the outer surface of the battery can is mounted at a position that does not protrude above the upper surface of the battery lid, and the external insulating plate is caulked by the electrode terminal forming member that penetrates the external insulating plate. a sealed battery in which is fixed, the portion located on the outer surface of the outer insulating plates of conductive terminal, said having an engagement portion of the protection member for protecting the upper surface of the electrode terminal or the battery lid It is a sealed battery.
The protective member is the above sealed battery that is attached after the battery lid and the battery can are joined by welding.
In the sealed battery, the protection member is an electrode terminal protection member that prevents a short circuit of the electrode terminal, or a battery header insulating plate that covers the battery header.
[0008]
DETAILED DESCRIPTION OF THE INVENTION
In the sealed battery in which the battery lid is joined and sealed to the battery can by laser welding, when the sealing failure in the electrode terminal portion of the battery lid is joined to the battery can by laser welding, The present invention has been conceived by discovering that the cause is that the insulator located between the electrode terminal and the battery lid is thermally damaged to cause a sealing failure.
[0009]
The present invention will be described below with reference to the drawings.
FIG. 1 is a diagram illustrating a sealed battery according to the present invention, and is a diagram illustrating a cross section of an electrode terminal portion on the upper side of the sealed battery.
The battery of the present invention is obtained by joining a battery header 2 to a battery can 1 made of aluminum or an aluminum alloy by laser welding or the like. The battery plate 3 is provided with a through hole for taking out an electrode terminal. On the flange 4A of the electrode pin 4 which is an electrode terminal forming member made of nickel, nickel alloy or the like, a washer 6 and an internal insulating plate 7 made of synthetic resin such as polypropylene or fluororesin are provided on the metal plate 3 for lid. By penetrating the hole, attaching the external insulating plate 8 from the upper part of the lid metal plate 3 and caulking the tip 4B of the electrode pin 4, the inner insulating plate and the external insulating plate are used as electrode pins and lid metal. The plate 3 is fixed in a sealed state.
[0010]
Further, the upper end portion of the external insulating plate 8 does not protrude from the upper surface of the lid metal plate 3, and the upper end portion 8A of the external insulating plate 8 is the same as the upper surface of the lid metal plate 3. It is located below the upper surface.
For this reason, when joining the battery header 2 to the battery can 1 by laser welding, it is possible to prevent the heat from the laser from being directly applied to the external insulating plate and causing deformation or the like due to the heat to cause a sealing failure. Is possible.
Further, a tab (not shown) connected to the battery element is connected to the flange portion of the electrode pin 4 to form a conductive connection.
Further, in the battery of the present invention, the side surface direction of the electrode terminal formed by caulking of the tip end portion of the electrode pin is exposed, but depending on the usage mode of the battery, it is necessary to insulate the side surface direction of the electrode terminal. If it occurs, an insulating plate may be attached to the electrode terminal.
[0011]
FIG. 2 is a view for explaining the insulating plate attached to the electrode terminal, and is a cross-sectional view in the thickness direction of the battery for explaining the electrode terminal portion of the battery.
FIG. 2A shows the battery header 2 joined by laser welding or the like. The electrode terminal has an engaging portion 20 formed thereon, and the electrode terminal protection member 21 is fixed by the engaging portion 20. Yes. For this reason, an electrode terminal will be protected from danger, such as a short circuit.
FIG. 2B shows an example in which a battery header insulating plate 22 that covers the battery header 2 on the upper side of the battery is attached to the engaging portion 20 formed on the electrode terminal.
This completely covers the top surface of the battery and protects it from dangers such as short circuits.
The electrode terminal protecting material and the battery header insulating plate shown in FIGS. 2 (A) and 2 (B) are both engaged with the electrode terminals after the battery header is joined and the battery is cleaned. Can be attached to the part.
[0012]
FIG. 3 is a diagram for explaining another example and explaining the thickness direction of the battery.
FIG. 3A illustrates an example in which the present invention is applied to a thin battery.
In the battery of this example, the upper end portion 8A of the external insulating plate 8 does not protrude from the surface of the lid metal plate 3 of the battery header 2, and the external insulating plate 8 is less likely to be damaged by heat. In addition, it becomes possible to reduce the distance d between the joining portion of the meeting portion of the battery can 1 and the battery header 2 by laser welding and the electrode terminal 4, and manufacture a battery having good sealing characteristics even in a thin battery. It becomes possible to do.
FIG. 3B is a diagram for explaining a battery with enhanced engagement characteristics between the external insulating plate and the electrode terminal.
In the example shown in FIG. 3B, the external insulating plate 8 is provided with a recess 8B for engaging the electrode terminal. As a result, the electrode terminal 4 is caulked, and the engagement of the recess 8B of the external insulating plate 8 is also produced. As a result, more sufficient engagement can be obtained.
[0013]
【Effect of the invention】
In the sealed battery of the present invention, since the insulating plate constituting the electrode terminal portion of the battery is structured not to protrude from the surface of the metal plate for the lid, laser welding is used when joining the battery header to the battery can. Since the insulating plate is not adversely affected by heat, a battery having good sealing properties can be provided.
[Brief description of the drawings]
FIG. 1 is a diagram illustrating a sealed battery according to the present invention, and is a diagram illustrating a cross-section of an electrode terminal portion on the top of the sealed battery.
FIG. 2 is a diagram illustrating an insulating plate attached to an electrode terminal, and is a cross-sectional view in the thickness direction of the battery illustrating an electrode terminal portion of the battery.
FIG. 3 is a diagram for explaining another example and explaining the thickness direction of the battery.
FIG. 4 is a diagram illustrating an example of a battery header.
FIG. 5 is a diagram illustrating a cross-sectional view in the thickness direction of the upper part of a conventional battery.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1 ... Battery can, 2 ... Battery header, 3 ... Metal plate for lid bodies, 4 ... Electrode pin, 4A ... Flange, 4B ... Tip part, 6 ... Washer, 7 ... Internal insulating plate, 8 ... External insulating plate, 8A ... Upper end portion, 8B ... concave portion, 9 ... small hole, 10 ... pressure release valve, 11 ... laser, 12 ... heat, 20 ... engagement portion, 21 ... electrode terminal protection material, 22 ... battery header insulating plate

Claims (2)

絶縁性部材を介して電極端子を取りつけた電池蓋体を電池缶の開口部に溶接により接合した密閉型電池において、電極端子と電池蓋体との間に設けた絶縁性部材のうち、電池缶の外面に面する外部絶縁板は、電池蓋体の上面よりも上部には突出しない位置に装着され、外部絶縁板を貫通する電極端子形成部材のかしめによって前記外部絶縁板が固着されたものであって、前記電極端子形成部材の外部絶縁板の外面に位置する部分に、電極端子あるいは電池蓋体の上面を保護する保護部材の係合部を形成したことを特徴とする密閉型電池。In a sealed battery in which a battery lid having an electrode terminal attached thereto via an insulating member is joined to an opening of the battery can by welding, among the insulating members provided between the electrode terminal and the battery lid, the battery can faces the outer surface outside the insulating plate, the upper surface of the battery lid on the top is mounted at a position not projecting, in which the outer insulating plates are fixed by caulking of the electrode terminal forming member passing through the outer insulating plate A sealed battery characterized in that an engaging portion of a protective member for protecting the electrode terminal or the upper surface of the battery lid is formed on a portion of the electrode terminal forming member located on the outer surface of the external insulating plate . 前記保護部材が電極端子の短絡を防止する電極端子保護部材、または電池ヘッダを覆う電池ヘッダ絶縁板であることを特徴とする請求項1記載の密閉型電池。The sealed battery according to claim 1, wherein the protective member is an electrode terminal protective member that prevents a short circuit of the electrode terminal, or a battery header insulating plate that covers the battery header.
JP2001169199A 2001-06-05 2001-06-05 Sealed battery Expired - Lifetime JP4932092B2 (en)

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KR100467703B1 (en) * 2002-10-21 2005-01-24 삼성에스디아이 주식회사 Cap assembly and secondary battery applying the same
JP5053036B2 (en) * 2007-10-25 2012-10-17 睦月電機株式会社 Sealed battery
CN210110860U (en) * 2019-09-11 2020-02-21 宁德时代新能源科技股份有限公司 Top cover assembly and secondary battery
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JPH0799045A (en) * 1993-09-29 1995-04-11 Hitachi Maxell Ltd Square sealed storage battery
JP2897104B2 (en) * 1994-06-03 1999-05-31 古河電池株式会社 Manufacturing method of sealed alkaline storage battery
JPH08171898A (en) * 1994-12-16 1996-07-02 Fuji Elelctrochem Co Ltd Rectangular electrochemical device with explosion-proof safety device and method of manufacturing the same
JPH097558A (en) * 1995-06-16 1997-01-10 Furukawa Battery Co Ltd:The Method for manufacturing sealed battery
JP3594404B2 (en) * 1996-05-28 2004-12-02 三洋電機株式会社 Sealed battery
JP3584656B2 (en) * 1996-12-25 2004-11-04 松下電器産業株式会社 Method of manufacturing sealing plate for prismatic nonaqueous electrolyte battery
JP3550953B2 (en) * 1997-06-30 2004-08-04 松下電器産業株式会社 Non-aqueous electrolyte battery

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