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JP4938508B2 - Α-ray emitter and apparatus for fluid treatment - Google Patents
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JP4938508B2 - Α-ray emitter and apparatus for fluid treatment - Google Patents

Α-ray emitter and apparatus for fluid treatment Download PDF

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JP4938508B2
JP4938508B2 JP2007058706A JP2007058706A JP4938508B2 JP 4938508 B2 JP4938508 B2 JP 4938508B2 JP 2007058706 A JP2007058706 A JP 2007058706A JP 2007058706 A JP2007058706 A JP 2007058706A JP 4938508 B2 JP4938508 B2 JP 4938508B2
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JP2008224233A (en
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徹 古谷
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徹 古谷
秋山 辰雄
橋本 浩
稲垣 元彦
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Description

この発明は、α線の電離作用を利用して水,空気,燃料用油等のような主として流体の殺菌,脱臭,低分子化,活性化,劣化防止等の処理を行うα線放射体及び装置に関する。   The present invention relates to an α-ray emitter that performs processing such as sterilization, deodorization, low molecular weight, activation, and deterioration prevention mainly of fluids such as water, air, and fuel oil using the ionizing action of α-rays. Relates to the device.

従来、空気又は燃料、燃料及び空気又は混合気に電離作用を有するα線を照射することにより燃焼効率を改善する内燃機関その他の燃焼装置の燃焼促進のために、特許文献1に示すように、α線放射材である酸化トリウムを表面に付着させた粒状体を金網等の保持材に所定間隔で保持させ、この保持材を自動車用エンジンのエアクリーナー内にエア流通方向と交差する方向に設置したものが知られている。   Conventionally, in order to promote combustion of an internal combustion engine and other combustion devices that improve combustion efficiency by irradiating air or fuel, fuel and air or air-fuel mixture with alpha rays having an ionizing action, as shown in Patent Document 1, A granular material with thorium oxide, which is an α-ray emitting material, attached to the surface is held by a holding material such as a wire mesh at predetermined intervals, and this holding material is installed in the direction of the air flow direction in the air cleaner of an automobile engine. Is known.

また一般に酸化トリウムはα線放射体として知られており、α線は他の放射線に比して物質を透過する能力(透過力)は最も弱いが、電離作用は最も強いことも広く知られている。
特開2005−9898号公報
Thorium oxide is generally known as an α-ray emitter, and it is widely known that α-rays have the weakest ionization effect, although they have the weakest ability to penetrate substances (penetration power) compared to other types of radiation. Yes.
Japanese Patent Laid-Open No. 2005-9898

しかし上記特許文献1に示されるもののように、酸化トリウムからなるα線放射材を含ませたものを粒状体表面に付着させて焼成したものを金網等に保持させるには、セラミック体の造粒や放射材のコーティング、さらには金網への保持加工等の加工工程が必要であるほか、金網への保持で表面の放射材が損傷するという欠点がある。   However, as shown in the above-mentioned Patent Document 1, in order to hold a material containing an α-ray emitting material made of thorium oxide attached to the surface of the granular material and fired, the wire mesh or the like is granulated. In addition, there is a disadvantage that the radiation material on the surface is damaged by holding on the wire mesh.

さらに上記のように粒状のセラミック処理材を使用する場合、粒状の放射材を保持するために、2枚の金網を重ねて粒状体をサンドイッチ状に挟持する必要があるほか、粒状体の粒径も5mm程度となり、金網固定のハンダ付部分も多く、処理筒の空間率も低下するため、大流量のものではその流通抵抗が大きくなる欠点がある。   Furthermore, when using a granular ceramic processing material as described above, in order to hold the granular radiation material, it is necessary to sandwich two granular metal nets and sandwich the granular material, and the particle size of the granular material Is about 5 mm, and there are many soldered portions fixed to the metal mesh, and the space ratio of the processing cylinder is reduced.

この発明は上記の問題点を解決する流体処理用のα線放射体及びその放射体を用いた装置を提供するものである。そして特にα線のもつ大きな電離効果(イオン化)によって水,空気,油等の分子構造を変化させ、水にあっては強力なイオン化により効率のよい水の殺菌,脱臭,脱色等を行うものである。   The present invention provides an α-ray radiator for fluid processing and an apparatus using the radiator for solving the above-mentioned problems. In particular, the large ionization effect (ionization) of α rays changes the molecular structure of water, air, oil, etc., and in the case of water, sterilization, deodorization, decolorization, etc. of water is performed efficiently by strong ionization. is there.

また空気に対しては強力なイオン化によって空気分子の核の人工変換等を発生させ、燃焼効率の改善,脱臭,浮遊菌等の殺菌を行わせるものである。
さらに油類については強力なイオン化による活性化,劣化防止等を実現しようとするものである。このうち燃料油においては炭素分子結合の切断による小分子化及びラジカル化によって燃焼効率を改善する。
In addition, strong ionization generates artificial conversion of air molecule nuclei to improve combustion efficiency, deodorization, and sterilization of airborne bacteria.
Furthermore, oils are intended to be activated by strong ionization and to prevent deterioration. Of these, fuel oil improves combustion efficiency by making small molecules and radicals by breaking carbon molecular bonds.

上記課題を解決するための本発明は第1に、耐熱性を備えた材料で流体の流通が可能な所定の升目又は間隔で網状又は格子状に形成された保持芯材6の表面に、耐熱性の塗料又は接着剤よりなる固着材を塗布又は付着して固着層8を形成し、該固着層8に酸化トリウムを主材とする微細な粒体状又は粉体状のα線放射材7を付着させ、上記α線放射材7と固着層8を所定温度で焼成することにより保持芯材6に固定してなることを特徴としている。   In order to solve the above problems, the present invention firstly provides a heat-resistant material on the surface of the holding core material 6 formed in a net-like or lattice-like shape with predetermined meshes or intervals allowing fluid to flow with a material having heat resistance. A fixing layer 8 is formed by applying or adhering a fixing material made of a conductive paint or an adhesive, and a fine granular or powdery α-ray emitting material 7 containing thorium oxide as a main material is formed on the fixing layer 8. The α-ray emitting material 7 and the fixing layer 8 are fixed to the holding core material 6 by firing at a predetermined temperature.

第2に、保持芯材6が銅,ステンレス鋼その他の金属製の金網からなることを特徴としている。   Second, the holding core member 6 is characterized by comprising a metal mesh made of copper, stainless steel, or other metal.

第3に、網目又は格子の線材の間隔を5〜30mmとしたことを特徴としている。   3rdly, it is characterized by the interval of the wire of a mesh | network or a grating | lattice having been 5-30 mm.

第4に、固着材が珪素,チタン,炭素を主成分とするポリマーと無機化合物及び有機溶剤からなることを特徴としている。   Fourth, the fixing material is characterized by comprising a polymer mainly composed of silicon, titanium, and carbon, an inorganic compound, and an organic solvent.

第5に、内部空間を流体の流通路とする筒状の処理筒1内に、流体の流通方向を交差し処理筒1内の上流側と下流側を仕切るように前記α線放射体4を設置してなることを特徴としている。   Fifth, the α-ray radiator 4 is disposed in a cylindrical processing cylinder 1 having an internal space as a fluid flow path so as to intersect the fluid flow direction and partition the upstream side and the downstream side in the processing cylinder 1. It is characterized by being installed.

上記のように構成される本発明のα線放射体及び装置は、網目状又は格子状の保持芯材表面に微細な粉体又は粉状のα線放射材が固着層を介して略前面に付着されているので、保持芯材全体からα線の放射ができ、α線放射密度も高く、保持芯材を通過する流体へのα線放射量も多いという利点がある。その結果従来の放射体や放射装置に比してα線放射による処理性能も向上する。   The α-ray radiator and the device of the present invention configured as described above have a fine powder or powdery α-ray emitting material on a substantially front surface through a fixing layer on the surface of a mesh-like or lattice-like holding core material. Since they are attached, there is an advantage that α rays can be emitted from the entire holding core material, the α ray radiation density is high, and the amount of α ray radiation to the fluid passing through the holding core material is large. As a result, the processing performance by α-ray radiation is improved as compared with conventional radiators and radiation devices.

さらにα線放射材は固着層の表面に付着させて焼成固着されるため、流体に接する表面側にはα線放射を妨げられることなく効率よく放射されるとともに、固定も安定し他の固定と接触しないので脱落や損傷もない。   Furthermore, since the α-ray emitting material adheres to the surface of the fixing layer and is fixed by firing, it is efficiently radiated to the surface side in contact with the fluid without hindering α-ray emission, and the fixing is stable and other fixings are also possible. There is no dropout or damage because there is no contact.

保持芯材は線材が網目状又は格子状に組合わされているだけであるため、流体に対する流通抵抗もなく、前記のようにα線放射量も多いために多数段に重ねて設置する必要がない。仮に複数段設置する場合でも従来のものより少ない枚数(段数)でより高い性能での流体処理ができる利点がある。   Since the holding core material is simply a combination of wires in a mesh or lattice shape, there is no flow resistance to the fluid, and there is a large amount of α-ray radiation as described above, so there is no need to install multiple layers. . Even if a plurality of stages are installed, there is an advantage that fluid processing can be performed with higher performance with a smaller number (stage number) than the conventional one.

放射材は金網等の表面に付着させて焼成するだけなので、従来のように造粒や表面コーティングや金網等に固定するための機械的加工も必要なく、製造コストも低減できるほか、金網で挟持する場合のように他の部材との表面接触がないため、放射材表面の損傷や劣化等の不都合も生じない。   Since the radiant material is only attached to the surface of the wire mesh and fired, there is no need for granulation, surface coating, or mechanical processing for fixing to the wire mesh as in the past, and the manufacturing cost can be reduced, and the material is sandwiched by the wire mesh. Since there is no surface contact with other members as in the case of doing, there is no inconvenience such as damage or deterioration of the surface of the radiation material.

以下図示する本発明の実施形態につき説明すると、図1〜3は本発明の装置の使用状態の全体断面とその要部である放射体を順次拡大表示した状態を示している。   The embodiment of the present invention shown in the drawings will be described below. FIGS. 1 to 3 show the entire section of the usage state of the apparatus of the present invention and the state in which the main part of the radiator is sequentially enlarged and displayed.

図1に示す装置は自動車用エンジン等の吸気側に取付けられる吸気処理装置の例を示し、筒状の処理筒1には吸入口2と排気口3とが付されており、処理筒1の内部には所定の間隔を介して2枚の通風可能な網状のα線放射体4を、エアの流通方向と交差しエア上流側と下流側を仕切るように内挿して設置している。この放射体4は内部のエア流通抵抗を少なくするために1枚にしても十分処理機能を発揮できるものである。   The apparatus shown in FIG. 1 shows an example of an intake air processing apparatus attached to the intake side of an automobile engine or the like. A cylindrical processing cylinder 1 is provided with an intake port 2 and an exhaust port 3. Inside, two mesh-like α-ray radiators 4 capable of passing air through a predetermined interval are installed so as to intersect the air flow direction and partition the air upstream side and the downstream side. Even if one radiator 4 is used in order to reduce the internal air flow resistance, a sufficient processing function can be exhibited.

上記放射体4は図2に示すように例えば線径0.5mm程度の銅又はステンレス鋼からなる線材を5mm程度の網目の金網からなる放射材保持用の芯材6を備えている。該芯材6の全表面には図3で示すように例えば粒径50μmの粒体又は粉体状で、少なくとも0.2〜5wt%の酸化トリウムを含むα線放射材7を付着させている。   As shown in FIG. 2, the radiator 4 includes a core material 6 for holding a radiation material made of a wire net made of copper or stainless steel having a wire diameter of about 0.5 mm and a wire mesh of about 5 mm. As shown in FIG. 3, an α-ray emitting material 7 containing at least 0.2 to 5 wt% thorium oxide is attached to the entire surface of the core material 6 as shown in FIG. .

上記放射材7は耐熱性の塗料又は接着剤を放射材7の固着材として予め芯材6の表面に浸漬(ディッピング),スプレー,はけ塗り等の方法により塗装して形成した下地材としての固着層8を介して付着固定される。この最終固着は放射材7を固着した後500〜600℃で加熱焼成することによって行われる。このとき放射材7の表面には、α線放射が妨げられないように塗料等で被覆されないようにする必要がある。   The radiant material 7 is a base material formed by previously coating the surface of the core material 6 with a heat-resistant paint or adhesive as a fixing material of the radiant material 7 by dipping, spraying, brushing, or the like. The adhesive layer 8 is adhered and fixed. This final fixing is performed by heating and baking at 500 to 600 ° C. after fixing the radiation material 7. At this time, it is necessary to prevent the surface of the radiation member 7 from being covered with a paint or the like so that the α-ray emission is not hindered.

α線放射による処理対象は、既述のように燃焼用エア以外に水,油,石油,ガス等の流体燃料その他α線の照射処理か有効な流体全般に及ぶものである。   As described above, the object to be treated by α-ray radiation covers not only combustion air but also fluid fuels such as water, oil, petroleum, gas, etc. and other α-ray irradiation treatments or effective fluids in general.

上記芯材6の金網の升目や線材径は使用する処理装置の大小や風量等によって選択されるが、升目はα線の飛程距離(25mm程度)と加工性,流体の流通抵抗等を考慮すると5〜30mm程度が望ましい。また流通路の断面全体にα線が放射されれば必ずしも網目である必要はなく、格子状であってもよいし、パンチで加工したものであってもよい。材料も焼成に耐え得る耐熱性があれば金属に限られない。   The mesh of the metal mesh of the core 6 and the wire diameter are selected according to the size of the processing apparatus used and the air volume, etc., but the mesh considers the range (about 25 mm) of α rays, workability, fluid flow resistance, etc. Then, about 5-30 mm is desirable. Further, if α rays are radiated to the entire cross section of the flow passage, it is not always necessary to have a mesh, and it may be a lattice or may be processed by a punch. The material is not limited to metal as long as it has heat resistance enough to withstand firing.

固着材(固着層8)の材料としては、炭素を主成分とするポリマー,有機化合物及び有機溶剤から構成された耐高温性,耐薬品性,耐酸化性に優れ、塗装後の焼成によってセラミックの薄膜を形成するもので、「チラノコート」等の商品名で市販されているもの,セラミック化できる薄膜用塗料等が使用可能である。またα線放射材7の粒径も装置の使用条件等によって異なるが40〜500μm(40〜400メッシュ)程度のものが使用可能である。   The material of the fixing material (adhesion layer 8) is excellent in high temperature resistance, chemical resistance and oxidation resistance composed of a polymer mainly composed of carbon, an organic compound and an organic solvent. For forming a thin film, it is possible to use a commercially available product with a trade name such as “Tyranno Coat”, or a paint for thin film that can be made into a ceramic. Further, the particle diameter of the α-ray radiation material 7 varies depending on the use conditions of the apparatus, but a particle having a size of about 40 to 500 μm (40 to 400 mesh) can be used.

次に図1以下に示す本発明の装置(但し、α線放射体4は1枚のみ)を自動車のエンジン吸気側に取付けて吸気エアをα線放射処理した場合と無装着の場合の排ガス組成の変化について示す。ちなみにテストに使用した自動車は、そのままでは州法の規定によりHC,CO値がオーバーしている(表1参照)ために使用(走行)できない状態であった。   Next, the exhaust gas composition in the case where the apparatus of the present invention shown in FIG. 1 and below (however, only one α-ray radiator 4) is attached to the engine intake side of an automobile and the intake air is subjected to α-ray emission treatment and when it is not installed is shown. It shows about the change of. By the way, the car used for the test was in a state where it could not be used (running) because the HC and CO values exceeded (see Table 1) according to the state law.

(テスト条件)
1.実験場所・・・アメリカ合衆国カリフォルニア州
(1)実験施設設置者 TE239417(州政府登録番号)
(2)実験施設 ES910594(州政府登録番号)
2.実験方法・・・カリフォルニア州法の規定に基く
3.実験日・・・2006年11月10日
4.使用自動車「NISSAN INFINITI 2002年型」、I−35(型式) 3500cc、6気筒、37029マイル走行車
(test conditions)
1. Experiment place: California, USA (1) Experiment facility founder TE239417 (Registered state number)
(2) Experimental facility ES910594 (Regional Government Registration Number)
2. Experimental method: Based on California law 3. Experiment date: November 10, 2006 4. Use car "NISSAN INFINITI 2002 type", I-35 (model) 3500cc, 6 cylinders, 37029 miles running car

Figure 0004938508
Figure 0004938508

表1の結果によれば本発明の装置を装着した場合、排ガス中のHC,CO,NOx含有量は、無装着の場合に比してカリフォルニア州の規則値をクリアするだけでなく、大幅に改善していることが明らかである。また上記測定結果は前記特許文献1中のHC,CO,NOxの改善成績と対比しても著しく向上している。   According to the results of Table 1, when the apparatus of the present invention is installed, the HC, CO, NOx content in the exhaust gas not only clears the California regulation values, but greatly It is clear that there is an improvement. Further, the measurement result is remarkably improved in comparison with the improvement results of HC, CO, and NOx in Patent Document 1.

本発明装置の1例を示す全体断面図である。It is a whole sectional view showing an example of the device of the present invention. 本発明のα線放射体の構造を示す説明図である。It is explanatory drawing which shows the structure of the alpha ray radiator of this invention. 本発明のα線放射体の部分拡大断面図である。It is a partial expanded sectional view of the alpha ray radiator of the present invention.

符号の説明Explanation of symbols

1 処理筒
4 α線放射体
6 保持芯材
7 α線放射材
8 固着層(固着材)
DESCRIPTION OF SYMBOLS 1 Processing cylinder 4 Alpha ray emitter 6 Holding core material 7 Alpha ray emission material 8 Adhesive layer (adhesive material)

Claims (5)

耐熱性を備えた材料で流体の流通が可能な所定の升目又は間隔で網状又は格子状に形成された保持芯材(6)の表面に、耐熱性の塗料又は接着剤よりなる固着材を塗布又は付着して固着層(8)を形成し、該固着層(8)に酸化トリウムを主材とする微細な粒体状又は粉体状のα線放射材(7)を付着させ、上記α線放射材(7)と固着層(8)を所定温度で焼成することにより保持芯材(6)に固定してなる流体処理用α線放射体。   A fixing material made of a heat-resistant paint or adhesive is applied to the surface of the holding core material (6) formed in a mesh or lattice pattern at a predetermined grid or interval that allows fluid to flow with a heat-resistant material. Alternatively, a fixed layer (8) is formed by adhesion, and a fine granular or powdery α-ray emitting material (7) mainly composed of thorium oxide is adhered to the fixed layer (8). An α-ray radiator for fluid treatment, which is formed by fixing the radiation member (7) and the fixing layer (8) to the holding core member (6) by firing at a predetermined temperature. 保持芯材(6)が銅,ステンレス鋼その他の金属製の金網からなる請求項1の流体処理用α線放射体。   The fluid processing α-ray radiator according to claim 1, wherein the holding core material (6) is made of a metal mesh made of copper, stainless steel or other metals. 網目又は格子の線材の間隔を5〜30mmとした請求項2の流体処理用α線放射体。   The alpha ray radiator for fluid treatment according to claim 2, wherein an interval between the wires of the mesh or lattice is 5 to 30 mm. 固着材が珪素,チタン,炭素を主成分とするポリマーと無機化合物及び有機溶剤からなる請求項1又は2又は3の流体処理用α線放射体。   The α-emitter for fluid treatment according to claim 1, 2 or 3, wherein the fixing material comprises a polymer mainly composed of silicon, titanium, and carbon, an inorganic compound, and an organic solvent. 内部空間を流体の流通路とする筒状の処理筒(1)内に、流体の流通方向を交差し処理筒(1)内の上流側と下流側を仕切るように請求項1,2,3又は4のα線放射体(4)を設置してなる流体処理用α線放射装置。   A cylindrical processing cylinder (1) having an internal space as a fluid flow passage intersects the fluid flow direction and partitions the upstream side and the downstream side in the processing cylinder (1). Or the alpha ray emission apparatus for fluid processing formed by installing 4 alpha ray radiators (4).
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WO2017098740A1 (en) * 2015-12-11 2017-06-15 芳信 林 Combustion improvement device

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