JP4953466B2 - Separate liquid seasoning - Google Patents
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- JP4953466B2 JP4953466B2 JP2008220755A JP2008220755A JP4953466B2 JP 4953466 B2 JP4953466 B2 JP 4953466B2 JP 2008220755 A JP2008220755 A JP 2008220755A JP 2008220755 A JP2008220755 A JP 2008220755A JP 4953466 B2 JP4953466 B2 JP 4953466B2
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Description
本発明は分離型液状調味料に関し、詳しくは油相と水相とからなる分離型液状調味料において、油相と水相の界面(以下、単に界面ということもある。)での白濁が生じにくい、分離型液状調味料に関する。 The present invention relates to a separation-type liquid seasoning, and in particular, in a separation-type liquid seasoning composed of an oil phase and an aqueous phase, white turbidity occurs at the interface between the oil phase and the water phase (hereinafter sometimes simply referred to as an interface). It is difficult and relates to a separate liquid seasoning.
油相と水相とからなる分離型液状調味料としては、例えばドレッシング、たれ、ソース、中華風調味料等があり、静置時に両相の界面が清澄であるものが商品価値が高い。
しかし、該液体調味料の原料とその使用量等によっては界面の清澄性が得られず、商品価値を著しく損うことがある。例えば、しょう油、果汁、ワインビネガー、米酢、ガム質、ごま加工品、味噌、梅肉などを使用した液体調味料は、振盪した後、静置しても2層にきれいに分離せず、界面が白濁することが多い。
Examples of the separation-type liquid seasoning composed of an oil phase and an aqueous phase include dressing, sauce, sauce, Chinese-style seasoning, etc., and those having a clear interface between both phases upon standing are high in commercial value.
However, depending on the raw material of the liquid seasoning and the amount used, the clarity of the interface cannot be obtained, and the commercial value may be significantly impaired. For example, liquid seasonings using soy sauce, fruit juice, wine vinegar, rice vinegar, gum quality, processed sesame seeds, miso, plum meat, etc., do not cleanly separate into two layers even if left standing after shaking. Often becomes cloudy.
そこで、従来から、分離型液状調味料について振とう後の界面の清澄性を得るために種々の方法が提案されている。例えば、柑橘オイルを添加する方法(特許文献1参照)、セロリシードを添加する方法(特許文献2参照)などがあり、これらは特定の原料との組合せにおいては効果をあげている。
しかし、これらの方法によると、界面の白濁を生じにくいレベルまで柑橘オイル等の素材を添加すると該素材特有の風味(味や香り)を感じるようになるため、調味料の種類によっては好ましくない場合があり、未だ改善の余地を多く残していた。
In view of this, various methods have been proposed in the past for obtaining the clarity of the interface after shaking for a separable liquid seasoning. For example, there are a method of adding citrus oil (see Patent Document 1), a method of adding celery seed (see Patent Document 2), etc., and these are effective in combination with specific raw materials.
However, according to these methods, when a material such as citrus oil is added to a level that does not easily cause white turbidity at the interface, the flavor (taste and aroma) peculiar to the material comes to be felt. There was still a lot of room for improvement.
本発明は、上記従来技術の課題を解決し、「油相と水相の界面での白濁が生じにくい(振盪後でも油相と水相の界面が清澄になりやすい)」分離型液状調味料を提供することを目的とするものである。
さらに本発明は、油相と水相の界面での白濁が生じにくく(振盪後でも油相と水相の界面が清澄になりやすく)、しかも「調味料の風味に悪影響がなく」、「調味料の種類に制限されない」、分離型液状調味料を提供することを目的とするものである。
The present invention solves the above-described problems of the prior art, and “separate liquid seasoning is less likely to cause white turbidity at the interface between the oil phase and the water phase (the interface between the oil phase and the water phase tends to become clear even after shaking)” Is intended to provide.
Furthermore, the present invention is less likely to cause white turbidity at the interface between the oil phase and the aqueous phase (the interface between the oil phase and the aqueous phase tends to become clear even after shaking), and “the flavor of the seasoning is not adversely affected” “It is not limited by the kind of the material”, and is intended to provide a separate liquid seasoning.
本発明者らは、上記課題を解消すべく鋭意検討を重ねた結果、通常は栄養強化目的や静菌目的で用いられる食品添加物のチアミンラウリル硫酸塩を、分離型液体調味料に添加することによって、振盪後(輸送による振動や手による振盪を受けた後)でも静置することで、油相と水相がきれいに分離し、界面が清澄になりやすい(界面での白濁が生じにくい)、分離型液体調味料が得られることを見出した。
さらに本発明者らは、分離型液状調味料全量に対する全窒素含有量が多い場合に、振盪後に界面に白濁が生じること、そして、全窒素含有量に対するチアミンラウリル硫酸塩含有量の割合が、白濁の生じにくさに顕著に影響すること、加えて、チアミンラウリル硫酸塩を入れ過ぎると、却って白濁の程度が大きくなることを見出し、チアミンラウリル硫酸塩の最適量を見出した。
As a result of intensive studies to solve the above problems, the present inventors have added thiamin lauryl sulfate, a food additive usually used for nutritional enhancement and bacteriostatic purposes, to a separate liquid seasoning. By leaving still after shaking (after shaking by transportation or shaking by hand), the oil phase and the aqueous phase are separated cleanly and the interface tends to become clear (white turbidity at the interface hardly occurs) It has been found that a separate liquid seasoning can be obtained.
Furthermore, the present inventors have found that when the total nitrogen content is large relative to the total amount of the separated liquid seasoning, white turbidity occurs at the interface after shaking, and the ratio of the thiamine lauryl sulfate content to the total nitrogen content is cloudy. It was found that the amount of thiamine lauryl sulfate was remarkably affected, and, in addition, when the amount of thiamine lauryl sulfate was excessively added, the degree of cloudiness increased.
即ち、本発明は以下のものである。
請求項1に記載の発明は、全窒素含有量が0.02w/w%以上である、油相と水相とからなる分離型液状調味料において、水相に、チアミンラウリル硫酸塩を、全窒素1重量部当たり0.00009重量部以上含有し、且つ、分離型液体調味料全重量当たり0.1w/w%以下含有することを特徴とする分離型液状調味料に関するものである。
請求項2に記載の発明は、前記油相と前記水相の界面での白濁が生じにくい、請求項1に記載の分離型液状調味料に関するものである。
That is, the present invention is as follows.
The invention according to claim 1 is a separable liquid seasoning composed of an oil phase and an aqueous phase, wherein the total nitrogen content is 0.02 w / w% or more, and thiamin lauryl sulfate is added to the aqueous phase. The present invention relates to a separable liquid seasoning containing 0.00009 parts by weight or more per 1 part by weight of nitrogen and 0.1 w / w% or less per total weight of the separable liquid seasoning.
The invention according to claim 2 relates to the separable liquid seasoning according to claim 1, in which white turbidity hardly occurs at the interface between the oil phase and the aqueous phase.
本発明によれば、「油相と水相の界面での白濁が生じにくい(振盪後でも油相と水相の界面が清澄になりやすい)」分離型液状調味料を提供することが可能となる。
さらに本発明によれば、油相と水相の界面での白濁が生じにくく、しかも「調味料の風味に悪影響がなく」、かつ、「調味料の種類に制限されない」、分離型液状調味料、を提供することが可能となる。
According to the present invention, it is possible to provide a separation-type liquid seasoning that “is less likely to cause white turbidity at the interface between the oil phase and the water phase (the interface between the oil phase and the water phase tends to become clear even after shaking)”. Become.
Furthermore, according to the present invention, white turbidity at the interface between the oil phase and the aqueous phase is unlikely to occur, and “there is no adverse effect on the flavor of the seasoning”, and “not limited by the type of seasoning”, the separation-type liquid seasoning , Can be provided.
本発明は、全窒素含有量が0.02w/w%以上である、油相と水相とからなる分離型液状調味料において、チアミンラウリル硫酸塩を、全窒素1重量部当たり0.00009重量部以上含有し、且つ、分離型液体調味料全重量当たり0.1w/w%以下含有することを特徴とする、界面での白濁が生じにくい分離型液状調味料、に関するものである。 The present invention relates to a separable liquid seasoning comprising an oil phase and an aqueous phase having a total nitrogen content of 0.02 w / w% or more, and thiamine lauryl sulfate is added to 0.00009 weight per 1 part by weight of total nitrogen. The present invention relates to a separable liquid seasoning that is less likely to cause white turbidity at the interface, and is contained in an amount of 0.1 w / w% or less per total weight of the separable liquid seasoning.
本発明において分離型液状調味料とは、「油相」と「水相」とからなる調味料であり、静置時には油相と水相がほぼ分離しており、使用時に手で振盪するなどして混ぜ合わせて用いられるものである。
具体的にはドレッシング、たれ、ソース、中華風調味料等が挙げられる。
In the present invention, the separation-type liquid seasoning is a seasoning composed of an “oil phase” and an “aqueous phase”, and the oil phase and the aqueous phase are substantially separated when standing, and shaken by hand when used, etc. It is used by mixing.
Specific examples include dressing, sauce, sauce, and Chinese-style seasonings.
油相と水相を構成する成分としては、液状調味料の使用目的等に応じて、通常使用されている成分の中から選択して用いればよく、特に制限されることはない。
ただし、本発明は、「全窒素含有量が0.02w/w%以上である」分離型液状調味料を対象にするものである。
本発明において、分離型液状調味料の全窒素含有量を上記範囲に限定している理由は、全窒素含有量がこの範囲にある分離型液状調味料は、振盪後に界面での白濁が生じ易く、界面が清澄になりにくいものだからである。
なお、分離型液状調味料の全窒素含有量が前記範囲より少ない場合には、振盪後の界面での白濁がほとんど生じないものとなるため、チアミンラウリル硫酸塩を含有させる必要はない。
The components constituting the oil phase and the aqueous phase may be selected and used from commonly used components according to the purpose of use of the liquid seasoning, and are not particularly limited.
However, the present invention is directed to a separate liquid seasoning whose total nitrogen content is 0.02 w / w% or more.
In the present invention, the reason why the total nitrogen content of the separable liquid seasoning is limited to the above range is that the separable liquid seasoning having the total nitrogen content in this range is likely to cause white turbidity at the interface after shaking. This is because the interface is difficult to clarify.
When the total nitrogen content of the separable liquid seasoning is less than the above range, white turbidity at the interface after shaking hardly occurs. Therefore, it is not necessary to contain thiamine lauryl sulfate.
なお、ここでの『界面での白濁が生じにくい』とは、「振盪後でも静置することで油相と水相がきれいに分離し、両者の界面が清澄になりやすい性質」を指すものである。この性質は、振盪後でも界面での‘白濁がほとんど生じない性質’と‘生じた白濁もすぐに消える性質’とによって、奏されるものである。
具体的には、振盪静置後に、界面がすぐに清澄になるものから、一定時間(例えば1時間程度)の静置を要するものまでを指す。
また、ここでの「振盪」とは、輸送による振動、手による振盪、攪拌、懸濁、など、油相と水相の界面が乱れる程度の物理的な衝撃を与えることを指す。
In addition, the phrase “difficult to cause white turbidity at the interface” here means “the property that the oil phase and the aqueous phase are separated cleanly by leaving it still after shaking, and the interface between the two tends to become clear”. is there. This property is exhibited by “a property that hardly causes white turbidity” at the interface even after shaking, and “a property that the generated white turbidity immediately disappears”.
Specifically, it refers to from the one where the interface becomes clear immediately after standing by shaking to the one requiring standing for a certain time (for example, about 1 hour).
The term “shaking” as used herein refers to giving a physical impact to such an extent that the interface between the oil phase and the water phase is disturbed, such as vibration due to transportation, shaking by hand, stirring, and suspension.
本発明では、分離型液状調味料に、界面での白濁が生じにくい性質を付与するために、チアミンラウリル硫酸塩を含有させるものである。
なお、チアミンラウリル硫酸塩は、少量であれば「調味料の風味に悪影響を与えるものではない」ため、「調味料の種類に制限されず」に、含有させることが可能である。
In the present invention, thiamine lauryl sulfate is added to the separable liquid seasoning in order to impart a property that hardly causes white turbidity at the interface.
It should be noted that thiamine lauryl sulfate can be contained in a small amount because it does not have an adverse effect on the flavor of the seasoning and is not limited by the type of seasoning.
本発明における『チアミンラウリル硫酸塩』とは、食品添加物公定書第7版に記載されたチアミンラウリル硫酸塩を指すものである。
本発明において含有させるチアミンラウリル硫酸塩は、特に無臭化処理の有無は問わないものであるが、特には、無臭化されたものを用いることが、調味料の味に悪影響を及ぼし難いことからより好適である。チアミンラウリル硫酸塩として具体的には例えば、田辺製薬株式会社製「ビダゲンAS5号」などが好適である。
また、チアミンラウリル硫酸塩を無臭化する方法としては特に限定されず、濾過や高分子による吸着などの従来周知の手法を採用すればよい。
The “thiamine lauryl sulfate” in the present invention refers to the thiamine lauryl sulfate described in the 7th edition of the official food additive.
The thiamine lauryl sulfate to be contained in the present invention is not particularly limited whether or not it is subjected to a non-bromide treatment, but in particular, it is more preferable to use a non-bromide because it is difficult to adversely affect the taste of the seasoning. Is preferred. Specifically, for example, “Vidagen AS5” manufactured by Tanabe Seiyaku Co., Ltd. is suitable as the thiamine lauryl sulfate.
Moreover, it does not specifically limit as a method of debromating thiamine lauryl sulfate, What is necessary is just to employ | adopt conventionally well-known methods, such as filtration and adsorption | suction with a polymer | macromolecule.
本発明の分離型液状調味料を製造するにあたり、チアミンラウリル硫酸塩の添加方法は特に限定されない。例えば、一旦液体原料に溶解してから他の水相原料とブレンドする方法や、一旦粉末原料に混合した状態で他の水相原料とブレンドする方法、又は直接添加して他の水相原料とブレンドする方法などを採用することができる。
しかし、チアミンラウリル硫酸塩は、通常は水に難溶性であるため、例えば、お湯、アルコール、酢酸に溶解した状態で添加したり、また、砂糖など水溶性の粉末原料などと混合した状態で添加することが好ましい。具体的には、60〜80℃程度のお湯に溶解した状態で添加することが好ましい。
In producing the separation-type liquid seasoning of the present invention, the method for adding thiamine lauryl sulfate is not particularly limited. For example, once dissolved in a liquid raw material and then blended with another aqueous phase raw material, once mixed with a powder raw material and blended with another aqueous phase raw material, or directly added to another aqueous phase raw material and A blending method can be employed.
However, thiamine lauryl sulfate is usually poorly soluble in water. For example, it is added in a state dissolved in hot water, alcohol or acetic acid, or in a state mixed with a water-soluble powder raw material such as sugar. It is preferable to do. Specifically, it is preferable to add in a state dissolved in hot water of about 60 to 80 ° C.
チアミンラウリル硫酸塩の含有量の下限値としては、目的とする分離型液体調味料の種類により原料の種類、配合量などが異なるので一概には定め難いが、分離型液体調味料中の全窒素含有量1重量部当たりチアミンラウリル硫酸塩を0.00009重量部以上含有することが必要である。
さらに好ましくは、全窒素含有量1重量部当たりチアミンラウリル硫酸塩を0.00019重量部以上含有することが好適である。また、界面での白濁が生じにくくなる効果を安定して得ることを考慮すると、最も好ましくは0.00049重量部以上、を含有することが特に好適である。
チアミンラウリル硫酸塩の含有量が少なすぎると、分離型液体調味料の界面での白濁が生じにくくならないため(振盪後の界面が清澄になりやすくならないため)、好適でない。
The lower limit of the content of thiamine lauryl sulfate is difficult to determine because the type and blending amount of raw materials differ depending on the type of the target separation-type liquid seasoning, but the total nitrogen in the separation-type liquid seasoning It is necessary to contain 0.00009 parts by weight or more of thiamine lauryl sulfate per 1 part by weight of the content.
More preferably, 0.00019 parts by weight or more of thiamine lauryl sulfate is contained per 1 part by weight of the total nitrogen content. In view of stably obtaining the effect of preventing white turbidity at the interface, it is particularly preferable to contain 0.00049 parts by weight or more most preferably.
If the content of thiamine lauryl sulfate is too small, white turbidity at the interface of the separation-type liquid seasoning is not likely to occur (because the interface after shaking does not easily become clear), which is not suitable.
なお、ここで、「全窒素含有量」とは、無機性窒素と有機性窒素の総含有量を表したものである。食品である本発明においては、主にタンパク質やアミノ酸に含まれる窒素の含有量を表す。例えば、ケルダール法や燃焼法(改良デュマ法)やガスクロマトグラフィーによって測定することができる。 Here, the “total nitrogen content” represents the total content of inorganic nitrogen and organic nitrogen. In the present invention, which is a food, the content of nitrogen mainly contained in proteins and amino acids is represented. For example, it can be measured by Kjeldahl method, combustion method (modified Dumas method) or gas chromatography.
チアミンラウリル硫酸塩の含有量の上限値としては、分離型液状調味料当たり0.1w/w%以下の割合で含有することが必要である。好ましくは、0.05w/w%以下の割合で含有することが好適である。
チアミンラウリル硫酸塩の含有量が多すぎると、却って振盪後の界面での白濁の程度が大きくなる(白濁を生じにくくする効果が弱まる)傾向があり、好適でない。これは、チアミンラウリル硫酸塩の界面活性効果により油相と水相が混ざりやすくなることで、却って界面での白濁を生じさせてしまうためと推察される。
また、極端にチアミンラウリル硫酸塩の含有量が多すぎる場合(例えば、0.1w/w%より多い)、分離型液状調味料の種類によっては風味にも悪影響を及ぼす可能性があり、特に好ましくはない。
As the upper limit of the content of thiamine lauryl sulfate, it is necessary to contain it at a ratio of 0.1 w / w% or less per separable liquid seasoning. Preferably, it is contained at a ratio of 0.05 w / w% or less.
If the content of thiamine lauryl sulfate is too large, the degree of white turbidity at the interface after shaking tends to increase (the effect of making white turbidity less likely to occur), which is not suitable. This is presumably because the oily phase and the aqueous phase are likely to be mixed by the surface active effect of thiamine lauryl sulfate, thereby causing white turbidity at the interface.
In addition, when the content of thiamine lauryl sulfate is excessively large (for example, more than 0.1 w / w%), the flavor may be adversely affected depending on the type of the separable liquid seasoning, which is particularly preferable. There is no.
上記のように、本発明は、一般的に界面での白濁の程度を強める効果を有すると考えられる「界面活性剤」を用い、その種類と量を工夫することにより、逆に界面での白濁を生じにくくする(界面が清澄になりやすくする)、という思いも寄らない効果を見出して完成した発明である。
なお、他の種類である界面活性剤、具体的にはグリセリン脂肪酸エステルやショ糖脂肪酸エステル、を用いた場合は、(たとえ上記好適な範囲を含有させたとしても)本発明の効果を得ることはできない。
As described above, the present invention generally uses a “surfactant” that is considered to have an effect of increasing the degree of cloudiness at the interface, and by devising the type and amount thereof, the cloudiness at the interface is reversed. It is an invention that has been completed by finding an effect that makes it difficult to cause (the interface is easy to become clear).
When other types of surfactants, specifically, glycerin fatty acid esters and sucrose fatty acid esters are used, the effects of the present invention can be obtained (even if the preferred range is included). I can't.
なお、チアミンラウリル硫酸塩は、一般に栄養強化の目的で食品に用いられることが多い。また、静菌の目的で所定量(例えば、0.02〜0.1w/w%)添加することもある。
しかしながら、本発明の分離型液状調味料に含有させるチアミンラウリル硫酸塩は、栄養強化や静菌効果を目的としたものではない。
分離型液体調味料は、一般的には水相当たりの「有機酸」(主に酢酸やクエン酸)濃度が高く、また「pH」が低いため静菌されていることが多い。また、加熱や濾過などによって殺菌や除菌をすることも多いため微生物汚染の心配は少なく、チアミンラウリル硫酸塩による静菌効果を必要としないものである。
In general, thiamine lauryl sulfate is often used in foods for the purpose of enhancing nutrition. In addition, a predetermined amount (for example, 0.02 to 0.1 w / w%) may be added for bacteriostatic purposes.
However, the thiamine lauryl sulfate contained in the separation-type liquid seasoning of the present invention is not intended for nutritional enhancement or bacteriostatic effect.
Separation-type liquid seasonings are generally bacteriostatic because the concentration of “organic acid” (mainly acetic acid and citric acid) per aqueous phase is high and “pH” is low. In addition, since sterilization or sterilization is often performed by heating or filtration, there is little concern about microbial contamination, and the bacteriostatic effect of thiamine lauryl sulfate is not required.
つまり従来、分離型液状調味料にチアミンラウリル硫酸塩を用いる動機は存在しなかった。
従って現在までに、「チアミンラウリル硫酸塩を含有した分離型液状調味料」は、存在せず、当然に「調味料の風味に悪影響がなく、また調味料の種類に制限されず、界面での白濁が生じにくい分離型液状調味料」は、存在しなかった。
なお、静菌性(防腐効果)という観点からすれば、分離型液状調味料の有機酸濃度は高い方が好ましく、pHは低い方が好ましい。例えば、分離型液状調味料の水相重量当たり、有機酸を酢酸換算で0.5w/w%以上含有することが好ましい。また、分離型液状調味料の水相のpHが5.0以下であることが好ましく、4.5以下であることがさらに好ましい。
しかし、風味の観点からすると、例えば、水相重量当たり、有機酸を酢酸換算で10w/w%以下とすることが好ましく、また水相のpHは2.0以上であることが好ましい。
In other words, conventionally, there has been no motive for using thiamine lauryl sulfate in a separable liquid seasoning.
Therefore, to date, there is no “separable liquid seasoning containing thiamine lauryl sulfate” and, of course, “the flavor of the seasoning is not adversely affected and is not limited to the type of seasoning, There was no “separable liquid seasoning that hardly causes white turbidity”.
In addition, from the viewpoint of bacteriostatic (preservative effect), the organic acid concentration of the separable liquid seasoning is preferably high, and the pH is preferably low. For example, the organic acid is preferably contained in an amount of 0.5 w / w% or more in terms of acetic acid per weight of the aqueous phase of the separation type liquid seasoning. Moreover, it is preferable that pH of the water phase of a separation-type liquid seasoning is 5.0 or less, and it is further more preferable that it is 4.5 or less.
However, from the viewpoint of flavor, for example, the organic acid is preferably 10 w / w% or less in terms of acetic acid per weight of the aqueous phase, and the pH of the aqueous phase is preferably 2.0 or more.
ここで、有機酸としては、酢酸、クエン酸、リンゴ酸、乳酸、グルコン酸などの有機酸類が該当する。また、有機酸の由来としては、醸造酢、穀物酢、米酢、果実酢、黒酢などの食酢や果汁類などの原料が挙げられる。
有機酸の濃度は、例えば、滴定や高速液体クロマトグラフィーによって測定することができる。
pHの調整は、上記の有機酸などによっても調整できるし、クエン酸ナトリウムなどのpH調整剤によっても調整することができる。pHは、例えば市販のpHメーターによって測定することができる。
Here, organic acids such as acetic acid, citric acid, malic acid, lactic acid, and gluconic acid correspond to the organic acid. In addition, examples of the origin of the organic acid include raw materials such as brewed vinegar, cereal vinegar, rice vinegar, fruit vinegar, and black vinegar.
The concentration of the organic acid can be measured, for example, by titration or high performance liquid chromatography.
The pH can be adjusted by the above organic acid or the like, or by a pH adjusting agent such as sodium citrate. The pH can be measured, for example, with a commercially available pH meter.
また、殺菌や除菌の方法は、特に限定されるものではないが、例えば、低温殺菌、高温短時間殺菌、高温殺菌、超高温瞬間殺菌、マイクロ波加熱殺菌、赤外線加熱殺菌、紫外線殺菌、超音波殺菌、濾過除菌、電気的除菌などから適宜選択して用いることができる。
殺菌方法の具体例を挙げると、高温殺菌としては、高温殺菌装置(レトルト)を用いて110〜125℃で数秒〜数分間加熱する方法などがある。低温殺菌は、熱交換器などを用いて55〜95℃で数秒〜数分間加熱する方法などがある。高温短時間殺菌としては、短時間調理殺菌装置を用いて120〜125℃で数秒間加熱する方法などがある。
なお、殺菌や除菌の工程は、水相単独で殺菌しても良いし、油相と混合してから殺菌してもよい。また、容器に水相、油相を充填して密栓した後、容器ごと熱水あるいは水蒸気等で殺菌しても良い。もちろん、容器自体を単独で殺菌することも除外されない。
The method of sterilization and sterilization is not particularly limited. For example, pasteurization, high temperature short time sterilization, high temperature sterilization, ultra high temperature flash sterilization, microwave heat sterilization, infrared heat sterilization, ultraviolet sterilization, It can be used by appropriately selecting from sonic sterilization, filtration sterilization, electric sterilization and the like.
As a specific example of the sterilization method, high-temperature sterilization includes a method of heating at 110 to 125 ° C. for several seconds to several minutes using a high-temperature sterilizer (retort). Pasteurization includes a method of heating at 55 to 95 ° C. for several seconds to several minutes using a heat exchanger or the like. As high temperature short time sterilization, there is a method of heating at 120 to 125 ° C. for several seconds using a short time cooking sterilizer.
In the sterilization and sterilization steps, the aqueous phase may be sterilized alone, or may be sterilized after mixing with the oil phase. Alternatively, the container may be sterilized with hot water or steam after the container is filled with an aqueous phase or an oil phase and sealed. Of course, sterilization of the container itself is not excluded.
分離型液体調味料の原料については、目的に応じて、従来より用いられている種々の原料を使い分ければよい。
例えば、「油相原料」は、食用植物油脂や精製魚油等の液状食用油脂であればよく、必要に応じてパプリカオレオレジン、マスタードオイル等を適宜添加すれば良い。
「水相原料」についても、味噌、しょう油、果汁、みりん、食酢(例えばワインビネガー,米酢など)、塩、ガム質、等が用いられる。
また、水相または油相に、野菜、胡麻、香辛料、梅肉、などの固形状の具材等を含有させてもよい。
なお、特には、窒素含量の高い原料である、味噌、しょう油、果汁、食酢、ガム質、胡麻、梅肉などを用いた分離型液体調味料を、本発明の対象とすることが好適である。
About the raw material of a separation-type liquid seasoning, what is necessary is just to use properly the various raw materials used conventionally according to the objective.
For example, the “oil phase raw material” may be liquid edible oils and fats such as edible vegetable oils and refined fish oils, and paprika oleoresin, mustard oil and the like may be added as necessary.
As for the “water phase raw material”, miso, soy sauce, fruit juice, mirin, vinegar (eg wine vinegar, rice vinegar, etc.), salt, gum, etc. are used.
In addition, solid ingredients such as vegetables, sesame seeds, spices, and plum meat may be included in the water phase or the oil phase.
In particular, it is preferable that the liquid-type seasonings using miso, soy sauce, fruit juice, vinegar, gum, sesame, plum meat, etc., which are raw materials with a high nitrogen content, be the subject of the present invention. .
また、本発明における分離型液状調味料としては、油相と水相の比率が特に制限されることはないが、特には水相を40〜97w/w%程度含むものを対象とするものである。 Moreover, as a separation-type liquid seasoning in this invention, although the ratio of an oil phase and an aqueous phase is not restrict | limited in particular, Especially it is intended for what contains about 40-97 w / w% of an aqueous phase. is there.
本発明に係る分離型液状調味料の製造は、その製造に際してチアミンラウリル硫酸塩を添加して含有させること以外は、従来より一般的に行なわれている方法を採用すればよい。
例えば、所定の容器に調味した水相を添加し、次いで調味した油相を添加するという方法で製造することができる。
The separation-type liquid seasoning according to the present invention may be produced by a conventional method except that thiamin lauryl sulfate is added and contained in the production.
For example, it can be produced by adding a seasoned aqueous phase to a predetermined container and then adding a seasoned oil phase.
ここで、チアミンラウリル硫酸塩を含有した分離型液体調味料の製造方法の一例を挙げる。まず、しょうゆ、砂糖、食酢、香辛料、ガム類、水等をブレンドする(これを調味酢と呼ぶ。)。チアミンラウリル硫酸塩を予めお湯(例えば60〜80℃)で希釈して前記調味酢にブレンドして「水相」を調製する(これをチアミンラウリル硫酸塩入り調味酢と呼ぶ。)。
これとは別に、菜種油、香味油(マスタードオイル等)などの原料をブレンドして「油相」を調製する(これを調味油と呼ぶ。)。
上記水相(チアミンラウリル硫酸塩入り調味酢)を必要に応じて殺菌(例えば70〜100℃で1〜30分間加熱)して、容器に必要量充填する(例えば、容器の5〜9割)。次いで、上記油相(調味油)を充填し、栓もしくは密封をする。
Here, an example of the manufacturing method of the separation-type liquid seasoning containing thiamine lauryl sulfate is given. First, blend soy sauce, sugar, vinegar, spices, gums, water, etc. (this is called seasoning vinegar). Thiamine lauryl sulfate is previously diluted with hot water (for example, 60 to 80 ° C.) and blended with the seasoned vinegar to prepare an “aqueous phase” (this is called seasoned vinegar with thiamin lauryl sulfate).
Separately, an “oil phase” is prepared by blending raw materials such as rapeseed oil and flavor oil (such as mustard oil) (this is called seasoning oil).
Sterilize the aqueous phase (seasoned vinegar containing thiamine lauryl sulfate) as necessary (for example, heat at 70 to 100 ° C. for 1 to 30 minutes), and fill the container with the required amount (for example, 50 to 90% of the container) . Next, the oil phase (seasoning oil) is filled and stoppered or sealed.
以下、本発明を実施例によって詳細に説明するが、これらは本発明を限定するものではない。
なお、ここで示した「%」は、全て分離型液体調味料当たりの割合「w/w%」を表す。
EXAMPLES Hereinafter, although an Example demonstrates this invention in detail, these do not limit this invention.
The “%” shown here represents the ratio “w / w%” per separable liquid seasoning.
実施例1(チアミンラウリル硫酸塩の効果)
(1)分離型液状調味料の製造
表1の処方の原料を混合することにより水相原料及び油相原料を調製した。
なお、チアミンラウリル硫酸塩は、予めお湯(原料としての水の一部)に希釈したものを0.001〜1%程度の希釈倍率になるように数種類用意しておき、最終的なチアミンラウリル硫酸塩の使用割合に応じて適宜選択しながら調製した。
調製した水相原料を容器に入れ、続いて油相原料を加えて分離型液状調味料(調味料1〜4)を製造した(各調味料は300gずつ製造した。また、300mL用のプラスチック容器を用いた)。
(2)白濁の生じにくさの評価
製造した調味料1〜5について、手で上下に激しく10回振盪した。そして、1時間静置した後における界面の状態を肉眼で観察した。
評価は、「×:界面が不鮮明であり、白濁が認められる。△:界面に僅かに白濁が認められる。○:界面が清澄で白濁がない。」として結果を表1に示す。
なお、本実施例で製造した調味料の全窒素含有量としては、醤油の全窒素含有量(ケルダール法にて測定)から換算した値を用いた。ただし、調味料1については実際にケルダール法にて全窒素含有量を測定し、醤油量からの換算値にほとんど誤差がないことを確認した。
さらに、「全窒素含有量(TN)1重量部当たりの、チアミンラウリル硫酸塩(THI)の含有量の割合」(=THI/TN)を算出した。結果を表1に示す。
Example 1 (Effect of thiamine lauryl sulfate)
(1) Manufacture of separation-type liquid seasoning The water phase raw material and the oil phase raw material were prepared by mixing the raw material of the prescription of Table 1.
Several types of thiamine lauryl sulfate are prepared in advance so that they are diluted in hot water (a part of water as a raw material) to a dilution ratio of about 0.001 to 1%. It prepared, selecting suitably according to the use ratio of a salt.
The prepared aqueous phase raw material was put in a container, and then an oil phase raw material was added to produce separate liquid seasonings (condiments 1 to 4) (each seasoning was manufactured in an amount of 300 g. Also, a 300 mL plastic container Was used).
(2) Evaluation of resistance to cloudiness The produced seasonings 1 to 5 were vigorously shaken up and down 10 times by hand. And the state of the interface after leaving still for 1 hour was observed with the naked eye.
The evaluation is shown in Table 1 as “X: the interface is unclear and white turbidity is observed. Δ: slight white turbidity is observed at the interface. ◯: the interface is clear and free of white turbidity.”
In addition, as the total nitrogen content of the seasoning produced in this example, a value converted from the total nitrogen content of soy sauce (measured by Kjeldahl method) was used. However, for seasoning 1, the total nitrogen content was actually measured by the Kjeldahl method, and it was confirmed that there was almost no error in the converted value from the soy sauce amount.
Furthermore, “the ratio of the content of thiamine lauryl sulfate (THI) per 1 part by weight of the total nitrogen content (TN)” (= THI / TN) was calculated. The results are shown in Table 1.
表1の結果(界面状態)より、全窒素含有量が0.51w/w%の分離型液状調味料においても、チアミンラウリル硫酸塩を含有することで(調味料2〜4)、振盪後の界面での白濁が生じず、界面が清澄になることが示された。 From the results shown in Table 1 (interface state), the separation-type liquid seasoning having a total nitrogen content of 0.51 w / w% also contains thiamine lauryl sulfate (seasoning 2 to 4), and after shaking. It was shown that there was no white turbidity at the interface and the interface became clear.
実施例2(チアミンラウリル硫酸塩と全窒素含有量の関係)
(1)分離型液状調味料の製造
処方を表2〜6のようにした以外は、実施例1と同様にして、分離型液状調味料(調味料5〜34)を製造した。
本実施例は、全窒素含有量の主要因である醤油、水、界面活性剤、食酢、砂糖、油のみの簡易的な処方の分離型液状調味料を製造して行った。
なお、本実施例においては、醤油量を79%(表2:全窒素含有量1.73%)、67%(表3:全窒素含有量1.36%)、50%(表4:全窒素含有量1.02%)、26%(表5:全窒素含有量0.53%)、6%(表6:全窒素含有量0.12%)の5段階に変化させ、そしてさらに、チアミンラウリル硫酸塩の濃度を0〜0.01%の間で6段階に変化させたものを、製造した。
(2)白濁の生じにくさの評価
製造した調味料5〜34について、実施例1と同様にして振盪静置し、界面の状態を肉眼で観察して評価した。また、実施例1と同様にして、全窒素含有量およびTHI/TNを算出した。結果を表2〜6に示す。
なお、調味料23,27については、振盪静置後の状態を図1,2に示す。
Example 2 (Relationship between thiamine lauryl sulfate and total nitrogen content)
(1) Production of separation-type liquid seasoning A separation-type liquid seasoning (condiments 5-34) was produced in the same manner as in Example 1 except that the formulations were as shown in Tables 2-6.
In this example, a separation-type liquid seasoning having a simple formulation of only soy sauce, water, surfactant, vinegar, sugar, and oil, which are the main factors of the total nitrogen content, was produced.
In this example, the soy sauce amount was 79% (Table 2: total nitrogen content 1.73%), 67% (Table 3: total nitrogen content 1.36%), 50% (Table 4: total nitrogen content). Nitrogen content 1.02%), 26% (Table 5: Total nitrogen content 0.53%), 6% (Table 6: Total nitrogen content 0.12%) What changed the density | concentration of thiamin lauryl sulfate in 6 steps between 0-0.01% was manufactured.
(2) Evaluation of difficulty in producing white turbidity The produced seasonings 5 to 34 were shaken and allowed to stand in the same manner as in Example 1, and the state of the interface was visually observed and evaluated. Further, in the same manner as in Example 1, the total nitrogen content and THI / TN were calculated. The results are shown in Tables 2-6.
In addition, about the seasonings 23 and 27, the state after shaking stationary is shown to FIG.
表2〜6の結果から、全窒素含有量が0.12%以上の液体分離型液状調味料は、振盪後に界面に白濁が生じることが示されたが、所定量のチアミンラウリル硫酸塩を添加することで白濁が生じにくくなることがわかった。
そこで、表2〜6の調味料の結果を、「全窒素含有量(TN)1重量部当たりの、チアミンラウリル硫酸塩(THI)の含有量の割合」(=THI/TN)を基準として並べなおした結果を表7に示す。
From the results of Tables 2 to 6, it was shown that the liquid-separated liquid seasoning having a total nitrogen content of 0.12% or more was clouded at the interface after shaking, but a predetermined amount of thiamine lauryl sulfate was added. It was found that white turbidity is less likely to occur.
Therefore, the results of the seasonings in Tables 2 to 6 are arranged on the basis of “the ratio of the content of thiamine lauryl sulfate (THI) per 1 part by weight of the total nitrogen content (TN)” (= THI / TN). Table 7 shows the result.
その結果、表7が示すように、白濁を抑えるためにはチアミンラウリル硫酸塩の絶対量ではなく、「全窒素含有量1重量部当たりの、チアミンラウリル硫酸塩の含有量の割合」(=THI/TN)が影響していることがわかった。
つまり、全窒素1重量部当たりチアミンラウリル硫酸塩を0.00009重量部含有することで白濁が生じにくくなる効果が出始めることが分かった。そして、0.00019重量部以上含有することで、白濁が生じにくくなる効果が調味料に十分に付与されることがわかった。
As a result, as shown in Table 7, in order to suppress white turbidity, not the absolute amount of thiamine lauryl sulfate but “the ratio of the content of thiamine lauryl sulfate per 1 part by weight of the total nitrogen” (= THI / TN) was found to be affected.
That is, it turned out that the effect which becomes difficult to produce white turbidity begins to appear by containing 0.00009 weight part thiamine lauryl sulfate per 1 weight part of total nitrogen. And it turned out that the effect which becomes difficult to produce cloudiness is fully provided to a seasoning by containing 0.00019 weight part or more.
実施例3(チアミンラウリル硫酸塩の含有量の上限量の検討)
実施例2より、分離型液状調味料へのチアミンラウリル硫酸塩の含有量として、適切な下限値は定まった。そこで、本実施例では、チアミンラウリル硫酸塩の添加量を増やしていき、上限値について検討した。
(1)分離型液状調味料の製造
処方を表8〜10のようにした以外は実施例1と同様にして、分離型液状調味料(調味料35〜46)を製造した。
本実施例は、全窒素含有量の主要因である醤油、水、界面活性剤、食酢、砂糖、油のみの簡易的な処方の分離型液状調味料を製造して行った。
なお、本実施例においては、醤油量を67%(表8:全窒素含有量1.36%)、26%(表9:全窒素含有量0.53%)、6%(表10:全窒素含有量0.12%)の3段階に変化させ、そしてさらに、チアミンラウリル硫酸塩の濃度を0.03〜0.5%の間で4段階に変化させたものを、製造した。
(2)白濁の生じにくさの評価
製造した調味料35〜46について、実施例1と同様にして振盪静置し、界面の状態を肉眼で観察して評価した。また、評価に当たり、特筆すべきことがある場合は備考欄に記載した。また、実施例1と同様にして、全窒素含有量およびTHI/TNを算出した。結果を表2〜6に示す。結果を表8〜10に示す。
なお、調味料42については、振盪静置後の状態を図3に示す。
Example 3 (Examination of upper limit of content of thiamine lauryl sulfate)
From Example 2, an appropriate lower limit was determined as the content of thiamine lauryl sulfate in the separable liquid seasoning. Therefore, in this example, the addition amount of thiamine lauryl sulfate was increased and the upper limit value was examined.
(1) Production of separation-type liquid seasoning A separation-type liquid seasoning (condiments 35 to 46) was produced in the same manner as in Example 1 except that the formulations were as shown in Tables 8 to 10.
In this example, a separation-type liquid seasoning having a simple formulation of only soy sauce, water, surfactant, vinegar, sugar, and oil, which are the main factors of the total nitrogen content, was produced.
In this example, the soy sauce amount was 67% (Table 8: total nitrogen content 1.36%), 26% (Table 9: total nitrogen content 0.53%), 6% (Table 10: total nitrogen content). The content was changed to 3 steps with a nitrogen content of 0.12%, and further the thiamine lauryl sulfate concentration was changed between 0.03 and 0.5% in 4 steps.
(2) Evaluation of resistance to white turbidity The produced seasonings 35 to 46 were shaken and allowed to stand in the same manner as in Example 1, and the state of the interface was visually observed and evaluated. In addition, in the evaluation, if there is something to be noted, it is described in the remarks column. Further, in the same manner as in Example 1, the total nitrogen content and THI / TN were calculated. The results are shown in Tables 2-6. The results are shown in Tables 8-10.
In addition, about the seasoning 42, the state after shaking stationary is shown in FIG.
また、表8〜10の調味料の結果を、チアミンラウリル硫酸塩の含有量を基準として並べなおした結果を表11に示す。 Moreover, the result of having rearranged the result of the seasoning of Tables 8-10 on the basis of content of thiamine lauryl sulfate is shown in Table 11.
表8〜10および11が示すように、分離型液状調味料に含有するチアミンラウリル硫酸塩を、0.1%含有させた場合に「若干の白濁」が認められた。そして、0.5%含有させた場合には、界面が不鮮明となって「かなりの白濁」が認められた。そして、白濁の量と比例するように泡立ちが認められた。
また、上限値に関しては、「全窒素含有量1重量部当たりの、チアミンラウリル硫酸塩の含有量の割合」(=THI/TN)の値と、白濁の発生状況との間に、関連が認められなかった。
このことから、上限値に関しては、チアミンラウリル硫酸塩の含有量の割合(=THI/TN)ではなく、チアミンラウリル硫酸塩の「絶対量」が影響していることがわかった。
この結果は、チアミンラウリル硫酸塩の含有量が増えると界面活性効果により泡立ちを生じてしまい、油相と水相が混ざりやすくなることで白濁を生じてしまうと推察される。
As Tables 8 to 10 and 11 show, “slight cloudiness” was observed when 0.1% of thiamine lauryl sulfate contained in the separated liquid seasoning was contained. When the content was 0.5%, the interface became unclear and "substantial cloudiness" was observed. And foaming was recognized so that it might be proportional to the amount of cloudiness.
As for the upper limit, there is a relationship between the value of “the ratio of thiamine lauryl sulfate content per 1 part by weight of total nitrogen” (= THI / TN) and the occurrence of cloudiness. I couldn't.
From this, it was found that the “absolute amount” of thiamine lauryl sulfate had an influence on the upper limit value, not the content ratio of thiamine lauryl sulfate (= THI / TN).
This result is presumed that when the content of thiamine lauryl sulfate increases, foaming occurs due to the surface-active effect, and the oily phase and the aqueous phase are likely to be mixed, resulting in white turbidity.
以上より、分離型液状調味料の全重量当たりチアミンラウリル硫酸塩を0.1w/w%以下で含有しないと、却って「界面での白濁が生じにくくなる」効果を発揮しにくいことがわかった。 From the above, it has been found that unless the thiamine lauryl sulfate is contained at 0.1 w / w% or less per total weight of the separation type liquid seasoning, it is difficult to exert the effect of “not easily causing white turbidity at the interface”.
比較例1(他の界面活性剤による界面白濁の検証)
次に、チアミンラウリル硫酸塩以外の界面活性剤について、分離型液状調味料の「界面での白濁を生じにくくする」効果を調べた。
(1)分離型液状調味料の製造
処方を表12、表13のようにした以外は実施例1と同様にして、分離型液状調味料(調味料47〜58)を作製した。
本実施例は、全窒素含有量の主要因である醤油、水、界面活性剤、食酢、砂糖、油のみの簡易的な処方の分離型液状調味料を製造して行った。
界面活性剤としては、食品への添加において安全性の高い素材として知られる「グリセリン脂肪酸エステル」(表12)と「ショ糖脂肪酸エステル」(表13)を選定した。
(2)白濁の生じにくさの評価
製造した調味料47〜58について、実施例1と同様にして界面の状態を肉眼で観察した。また、評価に当たり、特筆すべきことがある場合は備考欄に記載した。また、実施例1と同様にして、全窒素含有量を算出した。なお、上記実施例1〜4における「THI/TN」に相当する値として、「全窒素含有量(TN)1重量部当たりの、界面活性剤(SA)の含有量の割合」(=SA/TN)を算出した。結果を表12、表13に示す。
Comparative Example 1 (Verification of interfacial turbidity with other surfactant)
Next, with respect to surfactants other than thiamine lauryl sulfate, the effect of “reducing white turbidity at the interface” of the separated liquid seasoning was examined.
(1) Production of separation-type liquid seasoning A separation-type liquid seasoning (condiments 47 to 58) was prepared in the same manner as in Example 1 except that the formulations were as shown in Tables 12 and 13.
In this example, a separation-type liquid seasoning having a simple formulation of only soy sauce, water, surfactant, vinegar, sugar, and oil, which are the main factors of the total nitrogen content, was produced.
As the surfactant, “glycerin fatty acid ester” (Table 12) and “sucrose fatty acid ester” (Table 13), which are known as highly safe materials in addition to foods, were selected.
(2) Evaluation of difficulty in generating white turbidity For the seasonings 47 to 58 produced, the state of the interface was observed with the naked eye in the same manner as in Example 1. In addition, in the evaluation, if there is something to be noted, it is described in the remarks column. Further, the total nitrogen content was calculated in the same manner as in Example 1. In addition, as a value corresponding to “THI / TN” in Examples 1 to 4, “the ratio of the content of the surfactant (SA) per 1 part by weight of the total nitrogen content (TN)” (= SA / TN) was calculated. The results are shown in Tables 12 and 13.
表12、表13の結果より、界面活性剤のグリセリン脂肪酸エステル又はショ糖脂肪酸エステルを用いても、界面の白濁を抑えることはできなかった。
なお、グリセリン脂肪酸エステル又はショ糖脂肪酸エステルを0.5%より多く含有させる実験は行っていないが、これ以上含有したとしても泡立ちが激しくなるため「界面での白濁を生じにくくする」効果は発揮されないと予想された。
From the results of Tables 12 and 13, even when the glycerin fatty acid ester or sucrose fatty acid ester of the surfactant was used, the cloudiness at the interface could not be suppressed.
Although no experiment was made to contain more than 0.5% glycerin fatty acid ester or sucrose fatty acid ester, even if it is contained more than this, foaming becomes intense, so the effect of “reducing white turbidity at the interface” is exhibited. It was not expected.
以上の実施例および比較例より、チアミンラウリル硫酸塩による白濁を生じにくくする効果(界面清澄の効果)は、界面活性剤特有の効果ではなく、チアミンラウリル硫酸塩特有の効果であることがわかった。 From the above Examples and Comparative Examples, it was found that the effect of preventing white turbidity caused by thiamine lauryl sulfate (effect of interfacial clarification) is not an effect specific to surfactants but an effect specific to thiamine lauryl sulfate. .
本発明によれば、分離型液状調味料の風味等に悪影響を与えず、また、調味料の種類に制限されずに、界面での白濁を生じにくくした(振盪後でも界面が清澄になりやすい)分離型液状調味料を提供することが可能となる。
従って本発明によれば、界面の清澄性が優れた商品価値の高い、様々な種類の分離型液状調味料を提供することが可能となる。
According to the present invention, it does not adversely affect the flavor and the like of the separation-type liquid seasoning, and is not limited to the type of seasoning, and hardly causes white turbidity at the interface (the interface tends to become clear even after shaking). ) It becomes possible to provide a separable liquid seasoning.
Therefore, according to the present invention, it is possible to provide various types of separation-type liquid seasonings with excellent interface clarity and high commercial value.
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