JP4970720B2 - Oil-in-water makeup cosmetics - Google Patents

Description

  The present invention relates to glittering powder, synthetic phlogopite having an average particle size of 15 to 50 μm and an aspect ratio of 60 to 100, an organic spherical powder, an oil-in-water cosmetic containing an oil agent and water. Even though it has a powdery finish that doesn't feel oily stickiness without spreading the powder on the skin at the time of application, the cosmetic film is uniform and excellent in transparency. The present invention relates to an oil-in-water makeup cosmetic that is excellent in the effect of giving a three-dimensional effect and making the eyes and the like three-dimensional (hereinafter abbreviated as “three-dimensional effect effect”).

Makeup cosmetics are required to have various functions, and one of the functions is to control the three-dimensional effect such as emphasizing the shadow of the face and making the face look sharper, or making it appear on a small face. In makeup cosmetics, a technique for producing a three-dimensional effect by blending glitter powder such as mica titanium, glass pearl, titanium oxide-coated synthetic phlogopite, and bismuth oxychloride is known. And in order to produce a more stereoscopic effect, a technique using a low-order titanium oxide-coated mica excellent in reflection contrast and transmittance ratio (for example, see Non-Patent Document 1) or titanium mica is coated with silica, and the reflection characteristics are improved. A control technique (for example, see Non-Patent Document 2) and the like are known. What is common to these conventional techniques is to produce a three-dimensional effect by utilizing the brightness difference between regular reflection and variable angle reflection of the glitter powder.
Toshihiro Tanaka and 4 others, "Development of Chiaroscuro 3D make-up product with low-order titanium oxide-coated mica", Cosmetic Technology, 1996, Vol. 9, No. 4, p. 353-371 Nao Nakamura, “R & D on Lift Makeup”, Fragrance Journal, 1996, No. 10, p. 64-68

  When producing a three-dimensional effect using the reflection characteristics of such glittering powder, it is necessary to uniformly deposit the glittering powder on the skin. It is also necessary to suppress the concealment derived from the thickness of the decorative film as much as possible, in other words, to increase the transparency. However, conventional oil-in-water cosmetics formulated with glittering powders use a relatively large amount of oil to improve the adhesion of the powder to the skin and prevent the powder from dripping during application. It was blended. However, when a large amount of the oil agent is blended, the spread at the time of application becomes heavy, and there may be a feeling of oily stickiness, and furthermore, since the makeup film becomes thick, there is a disadvantage that the transparency is lost.

  For this reason, in order to suppress the weight of the spread at the time of application and the oily stickiness, constitutional powders such as mica and talc have also been added. It is difficult to obtain a satisfactory three-dimensional effect effect because wrinkles occur, the decorative film becomes thick, the transparency is lowered, and the reflection characteristics of the glittering powder cannot be sufficiently obtained.

  For this reason, even though it has a powdery finish that does not feel oily stickiness without spreading the powder on the skin during application, the cosmetic film is uniform and highly transparent, The development of an oil-in-water makeup cosmetic that is excellent in the effect of feeling production has been desired.

  In view of this situation, the present inventors have intensively studied and as a result, incorporated a glittering powder, a synthetic phlogopite with an average particle diameter of 15 μm to 50 μm and an aspect ratio of 60 to 100, an organic spherical powder, an oil agent, and water. In addition, the oil-in-water makeup cosmetic in which the blending amount of the oil agent is 1 to 5% by mass and the [total powder blending amount] / [the blending amount of the oil agent] is 4 to 40 solves the above problems. As a result, the present invention has been completed.

  Although the oil-in-water makeup cosmetic of the present invention has a powdery finish that does not feel oily stickiness without spreading the powder on the skin during application, it has a powdery finish. It is a cosmetic that is uniform and highly transparent, and has an excellent effect for producing a three-dimensional effect.

  The glittering powder of the component (A) used in the present invention is a component that enhances the shadow and gives a stereoscopic effect by giving the skin shine and gloss. Such components (A) are bismuth oxychloride, titanium mica, iron oxide coated mica, iron oxide coated mica titanium, titanium oxide coated synthetic phlogopite, iron oxide / titanium oxide coated synthetic phlogopite, organic pigment coated mica titanium, Examples thereof include titanium oxide-coated glass powder, aluminum powder, and the like, and one or more of these can be appropriately used. Further, these powders may be those subjected to surface treatment by a generally known method using a treatment agent such as a fluorine compound, a silicone compound, metal soap, wax, a surfactant, oils and fats, hydrocarbons and the like. .

  In addition, the average particle size of the glitter powder of component (A) is not particularly limited as long as it is within the range normally used for cosmetics, but from the viewpoint of enhancing the stereoscopic effect by making use of reflection characteristics. The range of 10 to 120 μm is preferable, and the range of 20 to 80 μm is particularly preferable.

  Such components (A) are commercially available products such as “TIMIRON SUPER series (manufactured by MERCK)”, “TIMIRON SPLENDID series (manufactured by MERCK)”, “GEMTONE TAN OPAL (manufactured by ENGELHARD)”, “Prominence series ( Nippon Koken Kogyo Co., Ltd.), “DUOCROME Series (manufactured by ENGELHARD)”, “Metashine 1080RC Series (manufactured by Nippon Sheet Glass)”, “REFLEKSKS Series (manufactured by ENGELHARD)”, and the like can be used.

  The blending amount of the component (A) in the oil-in-water makeup cosmetic of the present invention is not particularly limited, but is preferably 1 to 30% by mass (hereinafter simply referred to as “%”). If the blending amount of component (A) is within this range, make-up makeup that makes it difficult for the powder to squeeze on the skin, provides a uniform cosmetic film even at the finish, is particularly excellent in transparency, and has a higher stereoscopic effect. You can get a fee.

The synthetic phlogopite with an average particle size of component (B) used in the present invention of 15 to 50 μm and an aspect ratio (average thickness / average major axis) of 60 to 100 is more suitable for water and oil than natural mica and talc. It is a component that enhances the effect of three-dimensional effect by having excellent transparency when wet and adhering uniformly on the skin. The synthetic phlogopite of component (B) is represented by Mg ₃ K [AlF ₂ O (SiO ₃ ) ₃ ] listed as SYNTHETIC FLUORPHLOGOPITE in INTERNATIONAL NOMENCLATURE OF COSMETIC INGREDIENTS (hereinafter abbreviated as INCI). It is a mineral. The average particle size of the synthetic mica of such component (B) needs to be in the range of 15 to 50 μm. If the average particle diameter is less than 15 μm, the spread of elongation at the time of coating is deteriorated. Moreover, the aspect ratio of the synthetic mica of the component (B) needs to be in the range of 60-100. If the aspect ratio is less than 60, the transparency when wet with water or an oil agent is inferior, and if it exceeds 100, glossy gloss is generated, which is not preferable. These powders may have been subjected to a surface treatment by a generally known method using a treatment agent such as a fluorine compound, a silicone compound, a metal soap, a wax, a surfactant, an oil or fat, and a hydrocarbon. .

  Such a component (B) is commercially available as “PDM-20L (Topy Industries, Ltd.): average particle size 17-22 μm, aspect ratio 60-80”, “PDM-40L (Topy Industries, Ltd.): Average A particle diameter of 35 to 44 μm, an aspect ratio of 70 to 100 ”, and the like can be used.

  Although the compounding quantity of the component (B) in the oil-in-water type makeup cosmetics of this invention is not specifically limited, It is preferable that it is 5 to 20%. When the blending amount of the component (B) is within this range, it is possible to obtain a makeup cosmetic that is difficult to drown at the time of application and has a higher stereoscopic effect.

  The organic spherical powder of the component (C) used in the present invention is a component for obtaining a uniform decorative film by improving elongation and spreading at the time of application since it has a spherical shape. Such organic spherical powders of component (C) are nylon powder, polymethylsilsesquioxane powder, silicone elastomer powder, cross-linked silicone / network silicone copolymer powder, polystyrene powder, polyurethane powder, polyethylene powder, Crystalline cellulose powder, polymethacrylic acid ester powder, polyacrylic acid ester powder, starch powder and the like can be mentioned, and one or more of these can be used as appropriate. Further, these powders may be those subjected to surface treatment by a generally known method using a treatment agent such as a fluorine compound, a silicone compound, metal soap, wax, a surfactant, oils and fats, hydrocarbons and the like. . Of these, silicone powders such as polymethylsilsesquioxane powder, silicone elastomer powder, and cross-linked silicone / network-type silicone copolymer powder are preferable because uniform and powdery finishes are particularly excellent.

  The average particle size of the organic spherical powder of the component (C) is not particularly limited, but is preferably 0.5 to 30 μm and more preferably 2 to 15 μm from the viewpoint of usability. Further, the organic powder of component (C) may be not only a spherical shape but also a substantially spherical powder.

  Such components (C) are commercially available products such as “Nylon powder SP-500 (manufactured by Toray Industries, Inc.)”, “Tospearl series (manufactured by Toshiba Silicone)”, “Trefill series (manufactured by Toray Dow Corning Silicone). ) "," KSP series (manufactured by Shin-Etsu Chemical Co., Ltd.) "," Cell Flow Series (manufactured by Chisso Corporation) "," Matsumoto Microsphere Series (manufactured by Matsumoto Yushi Seiyaku Co., Ltd.) "and the like.

  Although the compounding quantity of the component (C) in the oil-in-water type makeup cosmetics of this invention is not specifically limited, It is preferable that it is 5 to 10%. When the blending amount of the component (C) is within this range, it is possible to obtain a makeup cosmetic with a more powdery finish and a more uniform three-dimensional effect with a more powdery finish without feeling oily stickiness. it can.

  The oil agent of component (D) used in the present invention is a component that prevents the powder from dripping at the time of application and adheres the powder uniformly on the skin. Such an ingredient (D) is an oil agent generally used in cosmetics, regardless of the origin, such as animal oil, vegetable oil, synthetic oil, and the properties of solid oil, semi-solid oil, liquid oil, etc., hydrocarbons Oils, waxes, waxes, hardened oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorine oils, lanolin derivatives, oily gelling agents, lipophilic surfactants, oil-soluble Examples include ultraviolet absorbers. Specifically, hydrocarbons such as liquid paraffin, squalane, petrolatum, polyisobutylene, polybutene, paraffin wax, ceresin wax, microcrystalline wax, montan wax, Fischer trops wax, molasses, olive oil, castor oil, mink oil, Fats and oils such as macadamian nut oil, beeswax, carnauba wax, candelilla wax, waxes such as gay wax, jojoba oil, cetyl isooctanoate, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, glyceryl trioctanoate, Polyglyceryl diisostearate, diglyceryl triisostearate, dialkyl carbonate, glyceryl tribehenate, rosin acid pentaerythritol ester, neopentyl dioctanoate Cole, cholesrelol fatty acid ester, esters such as N-lauroyl-L-glutamic acid di (cholesteryl, behenyl, octyldodecyl), stearic acid, lauric acid, myristic acid, behenic acid, isostearic acid, oleic acid, rosin acid, etc. Fatty acids, higher alcohols such as stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol, behenyl alcohol, low polymerization dimethylpolysiloxane, high polymerization dimethylpolysiloxane, methylphenylpolysiloxane, decamethylcyclopenta Siloxanes, octamethylcyclotetrasiloxanes, polyether-modified polysiloxanes, cross-linked organopolysiloxanes, silicones such as fluorine-modified silicones, perfluoropolyethylene Fluorine oils such as tellurium, perfluorodecane, perfluorooctane, lanolin, lanolin acetate, lanolin fatty acid isopropyl, lanolin derivatives such as lanolin alcohol, dextrin fatty acid ester, sucrose fatty acid ester, starch fatty acid ester, 12-hydroxystearic acid, Oily gelling agents such as calcium stearate, lipophilic surfactants such as sorbitan sesquioleate, glycerin monostearate, sorbitan tristearate, ethyl paraaminobenzoate, 2-ethylhexyl p-methoxycinnamate, 4 Examples thereof include oil-soluble ultraviolet absorbers such as -tert-butyl-4'-methoxydibenzoylmethane and oxybenzone, and one or more of these can be used as appropriate.

  The compounding amount of the component (D) in the oil-in-water makeup cosmetic of the present invention needs to be 1 to 5%. If the blending amount of component (D) is less than 1%, it is not possible to prevent the powder from curling at the time of application, and if it exceeds 5%, it is difficult to obtain a powdery finish.

  Furthermore, the component (D) needs to be blended so that [total powder blending amount] / [component (D) blending amount] is in the range of 4-40. If this value is less than 4, it is difficult to obtain a powdery finish, and if it exceeds 40, it is not preferable because it cannot prevent the powder from curling at the time of application.

  The component (E) water used in the present invention is a component constituting the outer phase of the oil-in-water cosmetic, and is an essential component for obtaining a fresh feeling of use and a uniform cosmetic film. Although the compounding quantity of the component (E) in the oil-in-water type makeup cosmetics of this invention is not specifically limited, It is preferable that it is 30 to 80%. If the blending amount of component (E) is within this range, a makeup cosmetic with a fresh feeling of use can be obtained.

  In addition to the above components, the oil-in-water makeup cosmetic of the present invention can contain a component (F) water-soluble polymer for the purpose of imparting appropriate viscosity and improving adhesion to the skin. Such component (F) is not particularly limited as long as it is usually used in cosmetics, but it is agar, pectin, guar gum, sodium chondroitin sulfate, hyaluronic acid, gum arabic, sodium alginate, carrageenan, xanthan gum, locust bean. Examples include gum, methylcellulose, hydroxyethylcellulose, hydroxypropylmethylcellulose, carboxymethylcellulose, carboxyvinyl polymer, acrylic acid / alkyl methacrylate copolymer, polyvinyl alcohol, polyvinylpyrrolidone, sodium polyacrylate, and the like. Can be used as appropriate.

  Among the components (F), acrylic acid / alkyl methacrylate copolymer (INCI includes ACRYLATES / C10-30ACRYLATE CROSSPOLYMER as a copolymer of acrylic acid and alkyl methacrylate having 10 to 30 carbon atoms. When a combination bean and / or locust bean gum is selected, the transparency is particularly excellent, so that a makeup cosmetic with a higher stereoscopic effect can be obtained.

  Such a component (F) is a commercially available product such as “Carbomer 1342 (manufactured by BF GOODRICH)”, “PEMULEN TR-1 (manufactured by NOVEON)”, which is an acrylic acid / alkyl methacrylate copolymer. “GENU GUM TYPE RL-200J (manufactured by Copenhagen Pectin Factory)”, which is a locust bean gum, etc., such as “PEMULENTR-2 (manufactured by NOVEON)” can be used.

  Although the compounding quantity of the component (F) in the oil-in-water type makeup cosmetics of this invention is not specifically limited, It is preferable that it is 0.01 to 0.6%. When the blending amount of the component (F) is within this range, a makeup cosmetic with particularly good usability can be obtained due to moderate viscosity.

  In the oil-in-water makeup cosmetic of the present invention, a surfactant can be blended as an emulsifier or a powder dispersant. Examples of such surfactants include nonionic surfactants, anionic surfactants, cationic surfactants, and amphoteric surfactants that are commonly used in cosmetics. Nonionic surfactants include glycerin fatty acid esters and alkylene glycol adducts thereof, polyglycerin fatty acid esters and alkylene glycol adducts thereof, propylene glycol fatty acid esters and alkylene glycol adducts thereof, sorbitan fatty acid esters and alkylene glycol adducts thereof. , Fatty acid ester of sorbitol and its alkylene glycol adduct, polyalkylene glycol fatty acid ester, sucrose fatty acid ester, polyoxyalkylene alkyl ether, glycerin alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene hydrogenated castor oil, alkylene glycol of lanolin Adduct, polyoxyalkylene modified silicone, glycerin modified silicone, polyglycerin modified Silicone and the like, may be used either from these or two or more appropriately. Anionic surfactants include fatty acids such as stearic acid and lauric acid and their inorganic and organic salts, alkylbenzene sulfates, alkyl sulfonates, α-olefin sulfonates, dialkyl sulfosuccinates, α-sulfonates Fatty acid salt, acylmethyl taurine salt, N-methyl-N-alkyl taurine salt, polyoxyethylene alkyl ether sulfate, polyoxyethylene alkyl phenyl ether sulfate, alkyl phosphate, polyoxyethylene alkyl ether phosphate, polyoxyethylene Alkyl phenyl ether phosphates, N-acyl amino acid salts, N-acyl-N-alkyl amino acid salts, o-alkyl substituted malates, alkyl sulfosuccinates, etc. may be mentioned, and one or more of these may be used as appropriate. Can do. Examples of the cationic surfactant include alkylamine salts, polyamines and alkanolamine fatty acid derivatives, alkyl quaternary ammonium salts, cyclic quaternary ammonium salts, and the like. One or more of these can be used as appropriate. Examples of amphoteric surfactants include N, N-dimethyl-N-alkyl-N-carboxylmethyl ammonium betaine, N, N-dialkylaminoalkylene carboxylic acid, N, N, N-trialkyl-N-sulfoalkylene ammonium betaine. N, N-dialkyl-N, N-bis (polyoxyethylene sulfate) ammonium betaine, 2-alkyl-1-hydroxyethyl-1-carboxymethylimidazolinium betaine, and the like, and one or more of these Can be used as appropriate.

  The blending amount when these surfactants are blended with the oil-in-water makeup cosmetic of the present invention is not particularly limited, but is preferably 0.01 to 5%.

  In the oil-in-water makeup cosmetic of the present invention, powders other than the components (A) to (C) can be blended. Such powders include talc, kaolin, sericite, mica, magnesium carbonate, calcium carbonate, aluminum silicate, magnesium silicate, magnesium magnesium silicate, calcium silicate, anhydrous silica, etc., titanium oxide , Inorganic white pigments such as zinc oxide, bengara, yellow iron oxide, black iron oxide, cerium oxide, gunjou, kongyou, carbon black and other inorganic color pigments, tar dyes, organic color pigments such as natural dyes, etc. One or more of these can be used as appropriate. Further, these powders may be those subjected to surface treatment by a generally known method using a treatment agent such as a fluorine compound, a silicone compound, metal soap, wax, a surfactant, oils and fats, hydrocarbons and the like. .

  In the oil-in-water makeup cosmetic of the present invention, in addition to the above-mentioned components, as components usually used in cosmetics, for example, glycols such as propylene glycol, 1,3-butylene glycol, dipropylene glycol, polyethylene glycol, Effects of the present invention include aqueous components such as glycerol such as glycerin, diglycerin and polyglycerin, UV absorbers, paraoxybenzoic acid derivatives, preservatives such as phenoxyethanol, vitamins, moisturizers, antioxidants, cosmetic ingredients, and fragrances. Can be suitably blended within a range not impairing the above.

  The form of the oil-in-water makeup cosmetic of the present invention may be any of liquid, emulsion, cream, gel, and solid. In addition, the oil-in-water makeup cosmetic of the present invention can be applied to foundations, white powders, makeup bases, concealers, teak colors, eye colors, eyeliners, lipsticks, etc. Among them, the effects of the present invention are exhibited. Easy cosmetics include creamy teak color, eye color and the like.

  The production method of the oil-in-water makeup of the present invention is not particularly limited, but after the powder is previously dispersed in an aqueous system and / or an oil system, a dispersion emulsification method, a phase inversion emulsification method, a non-aqueous gel emulsification method. And a method of producing using a generally known emulsification method such as a water-containing gel emulsification method.

  Hereinafter, the present invention will be described in more detail with reference to examples. Note that these do not limit the present invention.

Examples 1 to 7 and Comparative Examples 1 to 6: Oil-in-water emulsified cream eye colors Oil-in-water emulsified cream eye colors having the compositions shown in Tables 1 and 2 were produced by the production method shown below. Each item of “Elongation”, “Powder finish”, “Transparency of makeup film”, and “3D effect” is evaluated by the following evaluation method and criteria, and the results are shown in Table 1 and It is shown in Table 2.

(Production method)
A: Components 1 to 10 are dissolved by heating and kept at 70 ° C.
B: Components 24 to 26 are dissolved in Component 27, and components 21 to 23 and 28 are added and mixed.
C: Components 11 to 20 are added to B, uniformly dispersed, and kept at 70 ° C.
D: B is added to A and emulsified.
E: D is cooled to 30 ° C., components 29 to 30 are added, and mixed uniformly.
F: E was filled in a container to obtain an oil-in-water emulsified cream eye color.

〔Evaluation methods〕
Twenty cosmetic panel specialists used the oil-in-water emulsified cream eye color of the above-mentioned examples and comparative examples, and “uniform stretch spread”, “powder finish”, “transparency of makeup film”, “ Each “three-dimensional effect effect” was evaluated on a five-point scale according to the following criteria, given a score for each eye color, and the average score of all panels was determined according to the following criteria.
Evaluation criteria:
[Evaluation Result]: [Score]
Very good: 5 points Good: 4 points Normal: 3 points Somewhat bad: 2 points Bad: 1 point Criteria:
[Average score]: [Judgment]
4.5 or more: ◎
3.5 or more and less than 4.5: ○
1.5 or more and less than 3.5: △
Less than 1.5: ×

  As apparent from Table 1 and Table 2 above, the oil-in-water emulsified cream eye colors of Examples 1 to 7 are “uniform stretch spread”, “powder finish”, “transparency of cosmetic film”, “ It was an oil-in-water makeup cosmetic that was excellent in all items of the “three-dimensional effect”. On the other hand, in Comparative Examples 1 and 2 in which the [total powder blending amount] / [component (D) blending amount] exceeds 40, the transparency of the decorative film was not obtained and the stereoscopic effect effect was not good. Moreover, also in the comparative example 3 which does not mix | blend a component (A), the transparency of a decorative film was not acquired and the three-dimensional effect effect was not favorable. And in the comparative example 4 which does not mix | blend a component (C), it was inferior to uniform elongation spread and a powdery finish. Furthermore, in the comparative example 5 which does not mix | blend a component (B), the powdery finish and the three-dimensional effect provision effect were also not favorable. And in the comparative example 6 which mix | blended the synthetic phlogopite with an aspect ratio of 30-40 instead of a component (B), the translucency of a decorative film was not acquired and the three-dimensional effect effect was not favorable.

Example 8: Oil-in-water emulsion milk teak color (component)%
1. N-stearoyl-L-glutamate sodium 0.05
2. 1,3-butylene glycol 1
3. Behenyl alcohol 0.05
4). Polyoxyethylene hydrogenated castor oil (10E.O.) 0.05
5. Vaseline 0.05
6). Squalane 0.6
7). Cetyl isooctanoate 0.3
8). Dimethylpolysiloxane 0.02
9. Polyethylene glycol (molecular weight 400) 5
10.1,3-butylene glycol 5
11. Preservative appropriate amount 12. Carboxyvinyl polymer (Note 8) 0.2
13. Purified water 20
14 Polymethylmethacrylate (Note 9) 6
15. Titanium mica treated with dimethylpolysiloxane (Note 10) 12
16. Titanium oxide coated glass powder (Note 11) 2
17. Synthetic phlogopite (Note 3) 20
18. Red 226 0.02
19. Sodium hydroxide 0.06
20. Purified water remaining amount * Note 9: Matsumoto Microsphere M-305 (Matsumoto Yushi Seiyaku Co., Ltd.)
* Note 10: SA-TIMIRON SUPER RED (manufactured by Miyoshi Kasei)
* Note 11: Metashine 1080RC-R (Nippon Sheet Glass Co., Ltd.)

(Production method)
A: Components 1 to 8 are dissolved by heating and kept at 70 ° C.
B: Components 9 to 11 are dissolved, components 19 to 20 are added and mixed, and the mixture is kept at 70 ° C.
C: Components 12 to 18 are uniformly dispersed.
D: A is added to B and emulsified.
E: C is added to D and mixed uniformly.
F: E was filled in a container to obtain an oil-in-water emulsion milk teak color.
The oil-in-water emulsified milk teak color of Example 8 is an oil-in-water excellent in all items of “uniform spread and spread”, “powder finish”, “transparency of cosmetic film”, and “stereoscopic effect”. It was a type makeup cosmetic.

Example 9: Oil-in-water emulsified emulsion foundation (component)%
1. N-stearoyl-N-methyltaurine sodium 0.03
2. Hydrogenated soybean lecithin 0.01
3. Glycerin 1
4). Cetanol 0.05
5. Hardened oil 0.05
6). Liquid paraffin 0.8
7). Glyceryl trioctanoate 0.5
8). Vitamin E 0.1
9. Perfume appropriate amount10. Dipropylene glycol 10
11. Preservative appropriate amount 12. Xanthan gum (Note 12) 0.3
13. Purified water 30
14 Nylon powder (Note 13) 8
15. Bengala-coated mica titanium (Note 14) 1
16. Bengala-coated mica titanium (Note 15) 2
17. Titanium oxide 2
18. Bengala 0.2
19. Yellow iron oxide 2
20. Black iron oxide 0.2
21. Synthetic phlogopite (Note 16) 5
22. Purified water remaining amount Note 12: RHODIGEL CLEAR (manufactured by RHODIA CHIMIE)
Note 13: Nylon powder SP-500 (manufactured by Toray Industries, Inc.)
Note 14: CLOISNE ROUGE FLAMBE (manufactured by ENGELHARD)
Note 15: TIMICA GOLD SPARKLE (manufactured by ENGELHARD)
Note 16: PDM-20L (Topy Industries, Ltd.)

(Production method)
A: Components 1 to 3 are heated and dissolved, and components 4 to 9 are added and kept at 70 ° C.
B: Components 10 to 21 are uniformly dispersed.
C: Component 22 heated to 70 ° C. is added to A and emulsified.
D: B is added to C and dispersed uniformly.
E: D was filled into a container to obtain an oil-in-water emulsion emulsion foundation.
The oil-in-water emulsified emulsion foundation of Example 9 is an oil-in-water type excellent in all items of “uniform stretching and spreading”, “powder finish”, “transparency of cosmetic film”, and “stereoscopic effect”. It was a makeup cosmetic.

Example 10: Oil-in-water emulsified cream base material (component)%
1. Polyethylene glycol monostearate (40 EO) 0.2
2. Glycerin 0.8
3. Dipropylene glycol 0.6
4). Glyceryl monostearate 0.1
5. Behenyl alcohol 0.1
6). Dipentaerythlit fatty acid ester (Note 17) 0.3
7). Squalane 1.8
8). Propylene glycol dicaprate 1.5
9. Decamethylcyclopentasiloxane 1
10. Perfume proper amount11. Polymethylsilsesquioxane (Note 18) 5
12 Fluorine-treated mica titanium (Note 19) 5
13. Synthetic phlogopite (Note 3) 5
14 Synthetic phlogopite (Note 16) 10
15. Dipropylene glycol 10
16. Preservative appropriate amount17. Hydroxypropyl methylcellulose (Note 20) 0.15
18. Purified water 15
19. Remaining amount of purified water * Note 17: Cosmol 168AR (Nisshin Oilio Co., Ltd.)
* Note 18: Tospearl 2000B (GE Toshiba Silicone)
* Note 19: PF-5 FLAMENCO SUPERPEARL (Daito Kasei Co., Ltd.)
* Note 20: Metroz 65SH4000 (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)
A: Components 1 to 3 are heated and dissolved, and components 4 to 10 are added and kept at 70 ° C.
B: Components 11 to 18 are uniformly dispersed.
C: Component 19 heated to 70 ° C. is added to A and emulsified.
D: B is added to C and dispersed uniformly.
E: D was filled in a container to obtain an oil-in-water emulsified cream base material.
The oil-in-water type emulsified cream base material of Example 10 is an oil-in-water excellent in all items of “uniform stretching and spreading”, “powder finish”, “transparency of cosmetic film”, and “steric effect production effect”. It was a type makeup cosmetic.
more than

Claims (3)

The following components (A) to (E);
(A) Bright powder (excluding the following component (B))
(B) A synthetic phlogopite with an average particle diameter of 15 to 50 μm and an aspect ratio of 60 to 100 (C) Organic spherical powder (D) Oil (E) Water is blended, and the blending amount of component (A) is 1 to 1. 30% by mass, 5% to 20% by mass of component (B), 5% to 10% by mass of component (C), 1% to 5% by mass of component (D), and [total An oil-in-water makeup cosmetic, wherein the amount of powder] / [the amount of component (D)] is 4 to 40. Furthermore, component (F) an oil-in-water makeup cosmetic of claim 1, wherein blending the water-soluble polymer as a. The oil-in-water makeup cosmetic according to claim 1 or 2, wherein the component (F) is an acrylic acid / alkyl methacrylate copolymer and / or locust bean gum.