JP4977827B2 - How to thaw frozen whale meat - Google Patents
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本発明は、凍結クジラ肉を、科学的知見をもとに設定した条件により解凍し、風味の優れたクジラ肉を得る方法に関するものである。 The present invention relates to a method of thawing frozen whale meat under conditions set based on scientific knowledge to obtain whale meat having an excellent flavor.
クジラは、捕獲されると高鮮度の状態で急速凍結されて輸送・保管され、市場に流通する直前に解凍されるのが一般的である。
クジラ肉は、多量のATPを含有しているため解凍時に硬直を起こし、大量のドリップを流出するとともに、肉の硬化と変形を起こすことはすでに経験的に知られている。すなわち、ATPが残存した状態で凍結した高鮮度クジラ肉を0℃以上の温度帯で解凍すると、解凍硬直を起こし、ドリップが多量に出て品質の低下をきたしてしまうといった問題があった。しかしながら、従来、凍結解凍前後のATP含量の変化など科学的な知見として把握しようとする試みはなされておらず、現在、クジラ肉の解凍は、クジラ肉を扱う業者がそれぞれ、経験に基づいて設定された解凍条件を用いているのが現状である。
When captured, whales are generally frozen in a fresh state, transported and stored, and thawed immediately before distribution to the market.
Since whale meat contains a large amount of ATP, it is already empirically known that it stiffens upon thawing, leaks a large amount of drip, and causes hardening and deformation of the meat. That is, when the fresh fresh whale meat frozen with ATP remaining is thawed in a temperature range of 0 ° C. or higher, the thaw becomes stiff and a large amount of drip is produced, resulting in a decrease in quality. However, no attempt has been made to grasp scientific knowledge such as changes in ATP content before and after freezing and thawing, and whale meat thawing is currently set by each company that handles whale meat based on experience. Currently, the decompression conditions are used.
このような状況下、特許文献には、氷温下で48〜120時間の解凍時間をかけて冷凍クジラ肉を熟成解凍した後、2工程でボイルし、解凍時や加熱加工の過程での脱血が少なくなるようにする方法が開示されている。 Under such circumstances, the patent literature describes that frozen whale meat is aged and thawed at a temperature of 48 to 120 hours under ice temperature, boiled in 2 steps, and then defrosted during thawing or heat processing. A method for reducing blood is disclosed.
上記の方法は、最終的にボイルされたクジラ肉を製造することを目的とするものであって、ボイル後において肉の柔らかさや旨みが保持されるものの、解凍は−1〜+2.5℃に温度管理された室内で行なわれるので、部分的に解凍してしまいドリップの発生は避けられず、生肉での利用も想定した解凍方法としては満足のいくものではない。 The above method is intended to produce the final boiled whale meat, which retains the tenderness and umami of the meat after boiling, but defrosts at -1 to + 2.5 ° C. Since it is carried out in a temperature-controlled room, partial thawing occurs and drips are unavoidable, and it is not satisfactory as a thawing method that assumes use in raw meat.
一方、調査捕鯨の捕獲頭数の増加および凍結技術の向上により、高鮮度の凍結クジラ肉の生産量は増加し、一般家庭などでの消費拡大で凍結クジラ肉の流通量の増加が見込まれる。クジラ肉の普及のためには、生肉での利用も含め、高品質冷凍肉を解凍する際に、解凍硬直を起こさないで高品質を維持できる解凍方法の開発が不可欠である。
本発明は、このような問題点を解決することを目的としたものであって、本発明の課題は、風味の好ましい解凍クジラ肉を得ることができる冷凍クジラ肉の解凍方法を提供することである。 The present invention aims to solve such problems, and an object of the present invention is to provide a method for thawing frozen whale meat that can obtain a thawing whale meat having a preferred flavor. is there.
本発明者らは、急速冷凍されたクジラ肉を、−10〜0℃で0〜10日間放置し、肉中のATPの変化とドリップ量等との関係について研究した結果、品温を−5〜−3℃の凍結状態のままで2〜7日間放置すると、ATP濃度が肉中に含まれるATP関連化合物の総量に対して10%以下まで低下し、このようにATPが低下したクジラ肉は、その後、急速解凍しても解凍硬直を起こさず、ドリップ発生も抑制し、テクスチャ、風味の好ましい解凍クジラ肉が得られることを見出し、本発明に至った。 The present inventors left the rapidly frozen whale meat at −10 to 0 ° C. for 0 to 10 days and studied the relationship between the ATP change in the meat and the drip amount, etc. When left in a frozen state at -3 ° C for 2-7 days, the ATP concentration decreases to 10% or less of the total amount of ATP-related compounds contained in the meat, and thus whale meat with reduced ATP is Then, even after rapid thawing, it has been found that thawing stiffness does not occur, drip generation is suppressed, and a thawing whale meat having a favorable texture and flavor can be obtained, leading to the present invention.
すなわち、本発明は、−30℃以下で貯蔵されている凍結クジラ肉を解凍する前に、あらかじめ−5℃〜−3℃で2〜7日間放置し、肉中のATPを10%以下まで消失させ、その後0℃以上の温度帯で解凍するものである。 That is, in the present invention, before thawing frozen whale meat stored at −30 ° C. or lower, it is allowed to stand at −5 ° C. to −3 ° C. for 2-7 days in advance, and ATP in the meat disappears to 10% or lower. And then thawed in a temperature range of 0 ° C. or higher.
本発明によれば、高鮮度のクジラ肉に大量に含まれるATPが本発明の条件下で分解されるため、解凍硬直を抑制することが可能となり、ドリップの流出が少なく、やわらかく、美味しさを保持した肉に解凍でき、さらに、凍結保存中、ATPによるタンパク質の冷凍変性を抑制する効果が期待できる。 According to the present invention, since ATP contained in a large amount in the whale meat with high freshness is decomposed under the conditions of the present invention, it becomes possible to suppress thawing rigidity, there is little outflow of drip, and it is soft and delicious. It can be thawed into the preserved meat, and further, it can be expected to suppress the freezing of proteins by ATP during cryopreservation.
本発明が対象とするクジラの種類は、マッコウクジラ、ツチクジラ、イルカ類などのハクジラや、シロナガスクジラ、ナガスクジラ、イワシクジラ、ミンククジラなどのヒゲクジラなど、調査捕鯨および地域伝統捕鯨で対象となっている種全部を含む。 The types of whales targeted by the present invention are subject to research and local traditional whaling, including sperm whales, horn whales, dolphins and other whales, and blue whales, fin whales, sei whales, minke whales and other baleen whales. Includes all species.
本発明で使用される冷凍クジラ肉は、従来公知の方法で冷凍されたものでよいが、鮮度の維持の点から−30℃以下まで急速冷凍されたものが好ましい。この様に冷凍されたクジラ肉は、高濃度のATPを含有し、このATPが冷凍保存中のタンパク質変性抑制作用を果たすので、高鮮度を保ち得る。 The frozen whale meat used in the present invention may be frozen by a conventionally known method, but is preferably rapidly frozen to −30 ° C. or less from the viewpoint of maintaining freshness. The whale meat thus frozen contains a high concentration of ATP, and since this ATP functions to suppress protein denaturation during frozen storage, it can maintain high freshness.
冷凍クジラ肉を−5℃〜−3℃まで昇温させる手段は、公知のいずれの方法でもよいが、最終的に表面から肉塊の中心部まですべての部分を前記温度範囲内まで昇温させる必要がある。具体的には、−5℃〜−3℃に温度設定された恒温室内に冷凍クジラ肉を放置すればよい。 The means for raising the temperature of the frozen whale meat to −5 ° C. to −3 ° C. may be any known method, but finally raises all the portions from the surface to the center of the meat block to the temperature range. There is a need. Specifically, the frozen whale meat may be left in a temperature-controlled room set at -5 ° C to -3 ° C.
冷凍クジラ肉の放置は、ATPの濃度がすべての部位で10%以下となるまで行なう必要がある。ATPの濃度が10%以下まで低減されていれば、解凍時のドリップを5%未満に抑えることができる。 It is necessary to leave frozen whale meat until the ATP concentration is 10% or less at all sites. If the ATP concentration is reduced to 10% or less, the drip at the time of thawing can be suppressed to less than 5%.
ATP濃度を10%以下まで低減するための低減期間は、クジラ肉のATP濃度によって異なり、高濃度のクジラ肉ほど放置時間を長くする必要がある。通常、2日〜7日間を要する。 The period of reduction for reducing the ATP concentration to 10% or less depends on the ATP concentration of whale meat, and the higher the concentration of whale meat, the longer the standing time must be. Usually it takes 2-7 days.
上記の温度範囲での放置により、クジラ肉中のATPを10%以下まで分解消失させれば、その後の常温までの解凍は、いかなる方法でも構わない。
例えば、温水との接触による急速解凍により解凍することができ、得られた解凍クジラ肉は、風味が優れ、生食の利用が可能である。
As long as the ATP in the whale meat is decomposed and lost to 10% or less by being left in the above temperature range, any subsequent method for thawing to room temperature may be used.
For example, it can be thawed by rapid thawing by contact with warm water, and the obtained thawed whale meat has excellent flavor and can be used for raw food.
[実施例]
次に本発明の具体的な実施の実態を実施例として示す。
実施例において、ATP(%)pH、ドリップ量の測定は次の方法で行った。
ATP(%):まず、10%過塩素酸を用いて抽出した抽出物を水酸化カリウム水溶液で中和したものを、高速液体クロマトグラフィでATP関連化合物(ATP,ADP,AMP,IMP,HxR,Hx)を測定した。測定値を用いて以下の式で算出した。
ATP含量(%)=ATP/ATP+ADP+AMP +IMP+HxR+Hx x100
pH:肉5gに0.02Mモノヨード酢酸ナトリウム水溶液25mLを加え、ホモジナイズ後、pHメーターで測定した。
ドリップ量(%):解凍前と解凍後の肉の重量を測定し、その重量差(減少量)を計算し、減少量の解凍前肉の割合(%)を算出した。
[Example]
Next, the actual implementation of the present invention will be shown as examples.
In the examples, ATP (%) pH and the amount of drip were measured by the following method.
ATP (%): First, an extract extracted with 10% perchloric acid was neutralized with an aqueous potassium hydroxide solution, and then ATP-related compounds (ATP, ADP, AMP, IMP, HxR, Hx) were analyzed by high performance liquid chromatography. ) Was measured. It calculated with the following formula | equation using the measured value.
ATP content (%) = ATP / ATP + ADP + AMP + IMP + HxR + Hx x100
pH: 25 mL of 0.02M sodium monoiodoacetate aqueous solution was added to 5 g of meat, homogenized, and measured with a pH meter.
Drip amount (%): The weight of meat before and after thawing was measured, the difference in weight (decrease amount) was calculated, and the ratio (%) of meat before thawing of the decrease amount was calculated.
凍結時のATP含量が60%の200〜300gクジラ肉を−5℃、−10℃、−15℃ で10日間放置後のATP(%)とpHの測定を行った。次にそれぞれにおいて急速解凍(ビニール袋に入れ、ドリップが漏れないようにして流水(18~27℃)で中心温度が2℃になるまで解凍)および緩慢解凍(ビニール袋に入れ、5℃で中心温度が2℃なるまで解凍)を行い解凍肉のドリップ量およびATP含量とpHを測定した。その結果を図1〜図3に示す。ATPおよびpHは−5℃、10日間の凍結保存において減少が見られ、急速解凍時におけるドリップ量も肉中心温度が2℃の段階で約10%と他の条件にくらべ少なかった。 ATP (%) and pH were measured after leaving 200-300 g whale meat having an ATP content of 60% when frozen at −5 ° C., −10 ° C., and −15 ° C. for 10 days. Next, in each case, quickly thawed (put in a plastic bag, thawed with flowing water (18-27 ° C) until the center temperature reaches 2 ° C so that the drip does not leak) and slowly thawed (put in a plastic bag, centered at 5 ° C) Thawed until the temperature reached 2 ° C.) and the drip amount, ATP content and pH of the thawed meat were measured. The results are shown in FIGS. ATP and pH decreased at −5 ° C. for 10 days of cryopreservation, and the amount of drip at the time of rapid thawing was about 10% when the meat center temperature was 2 ° C., which was less than other conditions.
凍結時のATP含量が70%の150gクジラ肉を−1℃、−3℃ で1、2、3、5、7日間放置後のATP(%)とpHの測定を行った。次にそれぞれにおいて25度の恒温室に放置して中心温度2℃になるまで急速解凍を行い解凍肉のドリップ量およびATP含量とpHを測定した。また、その際に2℃の冷蔵庫で中心温度2℃になるまで放置し、同様にドリップ量およびATP含量とpHを測定した。また、食味試験も行った。その結果を図4〜6示す。−3℃、2〜7日間の凍結保存においてATPおよびpHの減少が見られ、ドリップ量も5%以下に抑えることができた。また、食味試験の結果(表1)、美味しくテクスチャも良好であるという評価が得られた。 ATP (%) and pH were measured after leaving 150 g whale meat with 70% ATP content at freezing at -1 ° C and -3 ° C for 1, 2, 3, 5 and 7 days. Next, each sample was left in a constant temperature room at 25 ° C. and rapidly thawed until the center temperature reached 2 ° C., and the drip amount, ATP content and pH of the thawed meat were measured. At that time, the product was left in a 2 ° C. refrigerator until the center temperature reached 2 ° C., and the drip amount, ATP content and pH were measured in the same manner. A taste test was also conducted. The results are shown in FIGS. ATP and pH were decreased in frozen storage at -3 ° C for 2-7 days, and the drip amount could be suppressed to 5% or less. In addition, as a result of the taste test (Table 1), it was evaluated that it was delicious and the texture was good.
本発明の方法によると、ATP含量が60%以上の高鮮度クジラ肉を−5〜−3℃、2〜7日間の凍結保存することによりドリップ量を5%以下に抑えることができ、美味しくテクスチャも良好な解凍クジラ肉を得ることができる。本発明の方法により、クジラ肉の普及が進むことが期待される。 According to the method of the present invention, a high freshness whale meat having an ATP content of 60% or more can be cryopreserved at -5 to -3 ° C for 2 to 7 days, and the drip amount can be suppressed to 5% or less. Even good thawed whale meat can be obtained. By the method of the present invention, it is expected that the spread of whale meat will proceed.
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